WO2009136809A1 - Способ переработки угля и устройство для осуществления способа - Google Patents
Способ переработки угля и устройство для осуществления способа Download PDFInfo
- Publication number
- WO2009136809A1 WO2009136809A1 PCT/RU2008/000340 RU2008000340W WO2009136809A1 WO 2009136809 A1 WO2009136809 A1 WO 2009136809A1 RU 2008000340 W RU2008000340 W RU 2008000340W WO 2009136809 A1 WO2009136809 A1 WO 2009136809A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coal
- sections
- section
- fluidized bed
- barrier
- Prior art date
Links
- 239000003245 coal Substances 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 24
- 238000003672 processing method Methods 0.000 title abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000004888 barrier function Effects 0.000 claims abstract description 9
- 238000009835 boiling Methods 0.000 claims abstract description 6
- 239000003546 flue gas Substances 0.000 claims description 6
- 235000013162 Cocos nucifera Nutrition 0.000 claims 1
- 244000060011 Cocos nucifera Species 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000000571 coke Substances 0.000 abstract description 17
- 239000004449 solid propellant Substances 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000005272 metallurgy Methods 0.000 abstract description 2
- 239000003517 fume Substances 0.000 abstract 2
- 239000000779 smoke Substances 0.000 abstract 2
- 239000002994 raw material Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 238000004939 coking Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
- C10B49/04—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated
- C10B49/08—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form
- C10B49/10—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge while moving the solid material to be treated in dispersed form according to the "fluidised bed" technique
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B1/00—Retorts
- C10B1/02—Stationary retorts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B39/00—Cooling or quenching coke
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B39/00—Cooling or quenching coke
- C10B39/10—Cooling or quenching coke combined with agitating means, e.g. rotating tables or drums
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
- C10L9/08—Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
Definitions
- the invention relates to the field of energy technological processing of coal, in particular to the production of thermal energy from coal and high-calorie solid fuel (coke) for metallurgy, energy and other industries.
- the supply of heat to the fluidized bed is ensured by an intermediate heat carrier, the role of which is formed in the coke process.
- the recirculated part of the coke is heated in the coke heater due to is the combustion of pyrolysis gas generated during the carbonization of coal.
- the main product of this method is fine-grained coke (particle size 0-3 mm). Steam-gas products of thermal decomposition of coal undergo condensation with the release of tar and pyrolysis gas.
- SUBSTITUTE SHEET (RULE 26) environmental hazard technology due to toxicity and carcinogenic activity of a number of substances (phenols, polyaromatic hydrocarbons, etc.) contained in the products of thermal decomposition of coal.
- a known method of producing metallurgical medium-temperature coke (RU 22857515 according to class ClO B49 / 10 from 07.29.2005). The method involves the production of coke by thermo-oxidative treatment of coal in a fluidized bed, and coal with a fractional composition of 0-15 mm is used as a coal layer, and air is supplied through a coal layer at a temperature of 800-900 0 C.
- a device for processing solid fuel is known, which is a layer apparatus of a shaft type, made combined from the upper, middle and lower zones.
- the upper belt consists of a loading hatch, a gas outlet pipe, a water seal and an electrothermal device.
- the middle belt consists of a cylindrical body and a water jacket, and the lower belt is made in the form of a truncated cone and consists of a discharge device, a grate, a device for supplying air and / or cooling gas and thermoelectric sensors.
- this boiler unit is designed to produce only thermal energy with minimal mechanical underburning of solid fuel.
- Another disadvantage is the need for disposal of ash and slag waste, which leads to environmental pollution.
- the objective of the invention is to increase the efficiency and simplify the method of thermal processing of coal, as well as improving environmental safety.
- the technical result of the invention is the production of high-calorie solid fuel and thermal energy from coal.
- the specified technical result is achieved by the fact that as the feedstock, coal fractions of 0-35 mm are used, and coal processing is carried out sequentially in two sections of a fluidized bed separated by a barrier, and in the first section thermo-oxidative treatment is carried out at a temperature of 650-800 0 C with air supply and in the second section, the resulting coke is cooled by supplying water vapor or chilled flue gases.
- the device for implementing the method is made in the form of a boiler unit, in which the furnace consists of two sections of a fluidized bed, separated
- FIG. 1 schematically shows a device for implementing a method of processing coal. It contains a boiler unit 1 with a furnace, divided by a barrier 2 into two sections of the fluidized bed 3 and 4. Subsections 5 are used to supply air to section 3, and channels 6 are used to supply a cooling agent.
- Coal in section 3 is fed through a feeder 7.
- a method of processing coal into high-calorie technological solid fuel is as follows.
- a fluidized (boiling) layer of coal which, depending on the prescribed mode, determined by the ratio of air blast to coal consumption, has a temperature of 650 to 800 0 C
- pre-crushed coal of fraction 0-35 mm is continuously fed by feeder 7.
- crushing of large fractions of coal as a result of thermal shock when it enters the fluidized bed with high temperature occurs.
- Larger coal particles, heated to the temperature of the layer and moving horizontally along the first section of the fluidized bed 3 pass through the stages of drying and pyrolysis and partial gasification, Air into the first section 3 is supplied through independently adjustable subsections 5 along the length of the fluidized bed.
- SUBSTITUTE SHEET (RULE 26) sections does not exceed 10 seconds, which leads to high specific productivity of the installation.
- Finely dispersed coal, vapor-gas products of thermal decomposition of coal, as well as coke gasification products are partially burned in the first section of the fluidized bed 3, ensuring its working temperature, are removed from the fluidized bed and burn out in the superlayer space by supplying a secondary air blast.
- the resulting combustion products and the emitting surface of the fluidized bed, as well as heated gases from the second section of the boiling gas 4 give heat to the heating surfaces of the boiler unit 1 to generate thermal energy in the form of hot water or water vapor.
- Heat from the combustion products and from the radiating surface of the fluidized bed is transferred to the heating surfaces of the boiler unit 1 to generate thermal energy - hot water or water vapor with specified parameters.
- Table 1 shows the technical performance of the modernized KBTC-20 boiler unit, in tables 2-3 the characteristics of the used coal fraction 0-35mm grade 2B grade "Berezovsky-1" Kansko-Achinsk coal basin and the product obtained from it - high-calorie solid fuel - coke .
- the proposed method and device for its implementation allows you to process coal fraction 0-35 mm into high-calorie solid fuel with the simultaneous production of thermal energy.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Conductive Materials (AREA)
- Coke Industry (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/990,548 US20110056127A1 (en) | 2008-05-05 | 2008-06-02 | Method for coal conversion and apparatus for implementation thereof |
| CN200880129059.3A CN102099439B (zh) | 2008-05-05 | 2008-06-02 | 煤加工方法及其用于进行该方法的设备 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2008117266/15A RU2359006C1 (ru) | 2008-05-05 | 2008-05-05 | Способ переработки угля |
| RU2008117266 | 2008-05-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2009136809A1 true WO2009136809A1 (ru) | 2009-11-12 |
Family
ID=41025895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/RU2008/000340 WO2009136809A1 (ru) | 2008-05-05 | 2008-06-02 | Способ переработки угля и устройство для осуществления способа |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20110056127A1 (uk) |
| KR (1) | KR20110006709A (uk) |
| CN (1) | CN102099439B (uk) |
| RU (1) | RU2359006C1 (uk) |
| TR (1) | TR201009065T1 (uk) |
| UA (1) | UA96880C2 (uk) |
| WO (1) | WO2009136809A1 (uk) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014049587A1 (en) * | 2012-09-25 | 2014-04-03 | Pt Total Sinergy International | Device for upgrading solid organic materials |
| RU2665409C2 (ru) * | 2016-08-02 | 2018-08-29 | Общество с ограниченной ответственностью "Сибнииуглеобогащение" | Способ получения металлургического среднетемпературного кокса в кипящем слое |
| RU2687411C1 (ru) * | 2018-10-31 | 2019-05-13 | Общество с ограниченной ответственностью "Сибнииуглеобогащение" | Способ получения среднетемпературного кокса |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1500451A (en) * | 1975-01-21 | 1978-02-08 | Centro Speriment Metallurg | Process for the production of carbonaceous material |
| JPS58219291A (ja) * | 1982-06-15 | 1983-12-20 | Ishikawajima Harima Heavy Ind Co Ltd | コ−クス乾式消火設備 |
| RU2073061C1 (ru) * | 1992-06-05 | 1997-02-10 | Рейнгольд Христианович Мерц | Способ получения полукокса из бурых и каменных углей |
| RU2288937C1 (ru) * | 2005-10-24 | 2006-12-10 | Общество С Ограниченной Ответственностью "Сибтермо" | Способ получения металлургического среднетемпературного кокса |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5510085A (en) * | 1992-10-26 | 1996-04-23 | Foster Wheeler Energy Corporation | Fluidized bed reactor including a stripper-cooler and method of operating same |
| BR9815349B1 (pt) * | 1997-12-18 | 2010-02-09 | sistema de gaseificaÇço de combustÍvel. | |
| DE10260734B4 (de) * | 2002-12-23 | 2005-05-04 | Outokumpu Oyj | Verfahren und Anlage zur Herstellung von Schwelkoks |
| US20070000177A1 (en) * | 2005-07-01 | 2007-01-04 | Hippo Edwin J | Mild catalytic steam gasification process |
-
2008
- 2008-05-05 RU RU2008117266/15A patent/RU2359006C1/ru not_active IP Right Cessation
- 2008-06-02 CN CN200880129059.3A patent/CN102099439B/zh active Active
- 2008-06-02 UA UAA201013329A patent/UA96880C2/uk unknown
- 2008-06-02 KR KR1020107027348A patent/KR20110006709A/ko not_active Application Discontinuation
- 2008-06-02 US US12/990,548 patent/US20110056127A1/en not_active Abandoned
- 2008-06-02 TR TR2010/09065T patent/TR201009065T1/xx unknown
- 2008-06-02 WO PCT/RU2008/000340 patent/WO2009136809A1/ru active Application Filing
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1500451A (en) * | 1975-01-21 | 1978-02-08 | Centro Speriment Metallurg | Process for the production of carbonaceous material |
| JPS58219291A (ja) * | 1982-06-15 | 1983-12-20 | Ishikawajima Harima Heavy Ind Co Ltd | コ−クス乾式消火設備 |
| RU2073061C1 (ru) * | 1992-06-05 | 1997-02-10 | Рейнгольд Христианович Мерц | Способ получения полукокса из бурых и каменных углей |
| RU2288937C1 (ru) * | 2005-10-24 | 2006-12-10 | Общество С Ограниченной Ответственностью "Сибтермо" | Способ получения металлургического среднетемпературного кокса |
Also Published As
| Publication number | Publication date |
|---|---|
| US20110056127A1 (en) | 2011-03-10 |
| KR20110006709A (ko) | 2011-01-20 |
| CN102099439B (zh) | 2015-05-06 |
| TR201009065T1 (tr) | 2011-05-23 |
| CN102099439A (zh) | 2011-06-15 |
| UA96880C2 (uk) | 2011-12-12 |
| RU2359006C1 (ru) | 2009-06-20 |
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