WO2009069311A1 - ３－メルカプトアニリン化合物の製造法 - Google Patents

３－メルカプトアニリン化合物の製造法 Download PDF

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Publication number
WO2009069311A1
WO2009069311A1 PCT/JP2008/003519 JP2008003519W WO2009069311A1 WO 2009069311 A1 WO2009069311 A1 WO 2009069311A1 JP 2008003519 W JP2008003519 W JP 2008003519W WO 2009069311 A1 WO2009069311 A1 WO 2009069311A1
Authority
WO
WIPO (PCT)
Prior art keywords
producing
compound
mercaptoaniline
general formula
disclosed
Prior art date
Application number
PCT/JP2008/003519
Other languages
English (en)
French (fr)
Inventor
Kentaro Kawazoe
Original Assignee
Ihara Chemical Industry Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ihara Chemical Industry Co., Ltd. filed Critical Ihara Chemical Industry Co., Ltd.
Priority to US12/743,389 priority Critical patent/US8334410B2/en
Priority to CN200880118411.3A priority patent/CN101878197B/zh
Priority to EP08854991.0A priority patent/EP2226312A4/en
Priority to BRPI0819712A priority patent/BRPI0819712A2/pt
Priority to JP2009543674A priority patent/JP5498798B2/ja
Publication of WO2009069311A1 publication Critical patent/WO2009069311A1/ja

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
    • C07C303/22—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids, by reactions not involving the formation of sulfo or halosulfonyl groups; from sulfonic halides by reactions not involving the formation of halosulfonyl groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

【課題】本発明は、殺虫等として有用な３－（１Ｈ－１，２，４－トリアゾール－１－イル）フェニルスルフィド誘導体の中間体として知られる３－メルカプトアニリン化合物を効率よく簡便に製造する方法及び原料となる化合物を簡便に製造する方法に関するものである。 【解決手段】一般式（１）（式中、Ｒはアルキル基又は環状アルキル基を示し、Ｘはハロゲン原子を示す。）で表される３－ニトロベンゼンスルホニルクロリド化合物のニトロ基及びクロロスルホニル基を、酸触媒存在下、還元することを特徴とする、一般式（２）（式中、Ｒ及びＸは前記と同じ意味を示す。）で表される３－メルカプトアニリン化合物の製造方法、及び、該製造方法において原料となる化合物の製造方法。
PCT/JP2008/003519 2007-11-30 2008-11-28 ３－メルカプトアニリン化合物の製造法 WO2009069311A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US12/743,389 US8334410B2 (en) 2007-11-30 2008-11-28 Method for producing 3-mercaptoaniline compound
CN200880118411.3A CN101878197B (zh) 2007-11-30 2008-11-28 3-巯基苯胺化合物的制备方法
EP08854991.0A EP2226312A4 (en) 2007-11-30 2008-11-28 PROCESS FOR PRODUCING 3-MERCAPTOANILINE COMPOUND
BRPI0819712A BRPI0819712A2 (pt) 2007-11-30 2008-11-28 processo para a produção de composto de 3-mercaptolanilina
JP2009543674A JP5498798B2 (ja) 2007-11-30 2008-11-28 ３−メルカプトアニリン化合物の製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-310536 2007-11-30
JP2007310536 2007-11-30

Publications (1)

Publication Number Publication Date
WO2009069311A1 true WO2009069311A1 (ja) 2009-06-04

Family

ID=40678223

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/003519 WO2009069311A1 (ja) 2007-11-30 2008-11-28 ３－メルカプトアニリン化合物の製造法

Country Status (7)

Country Link
US (1) US8334410B2 (ja)
EP (1) EP2226312A4 (ja)
JP (1) JP5498798B2 (ja)
KR (1) KR101587438B1 (ja)
CN (1) CN101878197B (ja)
BR (1) BRPI0819712A2 (ja)
WO (1) WO2009069311A1 (ja)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015537053A (ja) * 2012-12-12 2015-12-24 バイエル・クロップサイエンス・アクチェンゲゼルシャフト ビス（３−アミノフェニル）ジスルフィド類及び３−アミノチオール類を製造する方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104497307B (zh) * 2014-12-11 2017-07-14 扬州工业职业技术学院 一种苯胺与邻巯基苯胺共聚物的合成的制备方法
CN114555555B (zh) * 2019-10-16 2024-03-01 拜耳公司 制备1，1’-二硫烷二基双(4-氟-2-甲基-5-硝基苯)的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01168662A (ja) * 1987-12-24 1989-07-04 Nippon Soda Co Ltd ２―クロル―４―フルオロ―５―ニトロベンゼンスルホニルクロライドの製造法
WO2006043635A1 (ja) 2004-10-20 2006-04-27 Kumiai Chemical Industry Co., Ltd. ３－トリアゾリルフェニルスルフィド誘導体及びそれを有効成分として含有する殺虫・殺ダニ・殺線虫剤

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01168662A (ja) * 1987-12-24 1989-07-04 Nippon Soda Co Ltd ２―クロル―４―フルオロ―５―ニトロベンゼンスルホニルクロライドの製造法
WO2006043635A1 (ja) 2004-10-20 2006-04-27 Kumiai Chemical Industry Co., Ltd. ３－トリアゾリルフェニルスルフィド誘導体及びそれを有効成分として含有する殺虫・殺ダニ・殺線虫剤

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
LOUIS A. CARPINO ET AL.: "The 2-Chloro-3- indenylmethyloxycarbonyl and Benz[f]inden -3-ylmethyloxycarbonyl Base-Sensitive Amino-Protecting Groups.", APPLOCATION TO AN INVERSE MERRIFIELD APPROACH TO PEPTIDE SYNTHESIS, J. ORG. CHEM., vol. 55, no. 1, 1990, pages 251 - 259, XP008135982 *
See also references of EP2226312A4 *
V. PETROW ET AL.: "A New Route to Disulphamyl Derivatives of Benzene", J. PHARM. PHARMACOL., vol. 12, no. 12, 1960, pages 705 - 719, XP009174102 *
W. PALMER WYNNE: "Studies in the Toluene Series. Part VI. Nitration of the 4-Chloro-toluene-2- and -3-sulphonic Acid, 3-Chlorotoluene-6- sulphonic Acid and their Sulphonyl Chlorides.", JOURNAL OF THE CHEMICAL SOCIETY, 1936, pages 696 - 707, XP008135937 *
WILLIAM O. KERMACK ET AL.: "3-Nitro- and 3-Amino-4-hydroxybenzenesulphonamide", JOURNAL OF THE CHEMICAL SOCIETY, 1939, pages 608 - 610, XP008135943 *
XIAO-HUA DU ET AL.: "A Novel Synthesis of 2-Chloro-4-Fluoro-5-Nitrobenzenesulfonyl Chloride", ORG. PREP. PROCED. INT., vol. 37, no. 6, 2005, pages 566 - 569, XP008135936 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015537053A (ja) * 2012-12-12 2015-12-24 バイエル・クロップサイエンス・アクチェンゲゼルシャフト ビス（３−アミノフェニル）ジスルフィド類及び３−アミノチオール類を製造する方法

Also Published As

Publication number Publication date
JPWO2009069311A1 (ja) 2011-04-07
BRPI0819712A2 (pt) 2015-09-08
US20100249462A1 (en) 2010-09-30
US8334410B2 (en) 2012-12-18
EP2226312A1 (en) 2010-09-08
JP5498798B2 (ja) 2014-05-21
KR101587438B1 (ko) 2016-01-21
EP2226312A4 (en) 2014-04-02
CN101878197A (zh) 2010-11-03
CN101878197B (zh) 2015-01-07
KR20100092942A (ko) 2010-08-23

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