CN104497307B - 一种苯胺与邻巯基苯胺共聚物的合成的制备方法 - Google Patents
一种苯胺与邻巯基苯胺共聚物的合成的制备方法 Download PDFInfo
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- CN104497307B CN104497307B CN201410756846.8A CN201410756846A CN104497307B CN 104497307 B CN104497307 B CN 104497307B CN 201410756846 A CN201410756846 A CN 201410756846A CN 104497307 B CN104497307 B CN 104497307B
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- Prior art keywords
- aniline
- copolymer
- mercaptoaniline
- adjacent mercaptoaniline
- preparation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 229920001577 copolymer Polymers 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 230000015572 biosynthetic process Effects 0.000 title abstract description 7
- 238000003786 synthesis reaction Methods 0.000 title description 5
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- GDJYIXGPYCKDOV-UHFFFAOYSA-N n-phenylthiohydroxylamine Chemical group SNC1=CC=CC=C1 GDJYIXGPYCKDOV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002253 acid Substances 0.000 claims abstract description 8
- 239000007800 oxidant agent Substances 0.000 claims abstract description 6
- 230000001590 oxidative effect Effects 0.000 claims abstract description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 9
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 239000002121 nanofiber Substances 0.000 claims description 8
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims 1
- 238000005119 centrifugation Methods 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 239000000178 monomer Substances 0.000 abstract description 8
- 229920000767 polyaniline Polymers 0.000 abstract description 6
- 239000002086 nanomaterial Substances 0.000 abstract description 5
- 238000006116 polymerization reaction Methods 0.000 abstract description 4
- 238000010189 synthetic method Methods 0.000 abstract description 3
- 238000007334 copolymerization reaction Methods 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical group [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 206010070834 Sensitisation Diseases 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000002070 nanowire Substances 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Abstract
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CN201410756846.8A CN104497307B (zh) | 2014-12-11 | 2014-12-11 | 一种苯胺与邻巯基苯胺共聚物的合成的制备方法 |
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CN201410756846.8A CN104497307B (zh) | 2014-12-11 | 2014-12-11 | 一种苯胺与邻巯基苯胺共聚物的合成的制备方法 |
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CN104497307A CN104497307A (zh) | 2015-04-08 |
CN104497307B true CN104497307B (zh) | 2017-07-14 |
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CN201410756846.8A Expired - Fee Related CN104497307B (zh) | 2014-12-11 | 2014-12-11 | 一种苯胺与邻巯基苯胺共聚物的合成的制备方法 |
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Families Citing this family (1)
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CN105622935B (zh) * | 2016-03-30 | 2018-08-07 | 常州工程职业技术学院 | 一种可溶性取代苯胺聚合物的合成方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101878197A (zh) * | 2007-11-30 | 2010-11-03 | 庵原化学工业株式会社 | 3-巯基苯胺化合物的制备方法 |
CN102250345A (zh) * | 2011-06-17 | 2011-11-23 | 上海理工大学 | 一种纳米结构可控的磺酸基掺杂苯胺共聚物及其合成方法 |
CN103570944A (zh) * | 2013-10-18 | 2014-02-12 | 中国科学院长春应用化学研究所 | 含有巯基的聚苯胺及其制备方法 |
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2014
- 2014-12-11 CN CN201410756846.8A patent/CN104497307B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101878197A (zh) * | 2007-11-30 | 2010-11-03 | 庵原化学工业株式会社 | 3-巯基苯胺化合物的制备方法 |
CN102250345A (zh) * | 2011-06-17 | 2011-11-23 | 上海理工大学 | 一种纳米结构可控的磺酸基掺杂苯胺共聚物及其合成方法 |
CN103570944A (zh) * | 2013-10-18 | 2014-02-12 | 中国科学院长春应用化学研究所 | 含有巯基的聚苯胺及其制备方法 |
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Effective date of registration: 20211119 Address after: 225000 Xiaoci village, Tianshan Town, Gaoyou, Yangzhou City, Jiangsu Province Patentee after: YANGZHOU LIDA RESIN Co.,Ltd. Address before: 424, building C, Xingyao Tiandi, 525 Wenchang West Road, Hanjiang District, Yangzhou City, Jiangsu Province, 225000 Patentee before: Yangzhou yuanzhuo Technology Service Co.,Ltd. |
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Granted publication date: 20170714 |