WO2009057473A1 - プラズマリアクタ - Google Patents

プラズマリアクタ Download PDF

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Publication number
WO2009057473A1
WO2009057473A1 PCT/JP2008/068957 JP2008068957W WO2009057473A1 WO 2009057473 A1 WO2009057473 A1 WO 2009057473A1 JP 2008068957 W JP2008068957 W JP 2008068957W WO 2009057473 A1 WO2009057473 A1 WO 2009057473A1
Authority
WO
WIPO (PCT)
Prior art keywords
electrodes
plasma reactor
reformed
gas
reactor
Prior art date
Application number
PCT/JP2008/068957
Other languages
English (en)
French (fr)
Inventor
Michio Takahashi
Takeshi Sakuma
Original Assignee
Ngk Insulators, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ngk Insulators, Ltd. filed Critical Ngk Insulators, Ltd.
Priority to EP08843861A priority Critical patent/EP2213618B1/en
Priority to JP2009539014A priority patent/JPWO2009057473A1/ja
Publication of WO2009057473A1 publication Critical patent/WO2009057473A1/ja
Priority to US12/759,022 priority patent/US20100196224A1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/342—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents with the aid of electrical means, electromagnetic or mechanical vibrations, or particle radiations
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00—Generating plasma; Handling plasma
    • H05H1/24—Generating plasma
    • H05H1/47—Generating plasma using corona discharges
    • H05H1/471—Pointed electrodes
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00—Generating plasma; Handling plasma
    • H05H1/24—Generating plasma
    • H05H1/48—Generating plasma using an arc
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/0805—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B01J2219/0807—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes
    • B01J2219/0809—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes employing two or more electrodes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/0805—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B01J2219/0807—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes
    • B01J2219/0809—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes employing two or more electrodes
    • B01J2219/0811—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes employing two or more electrodes employing three electrodes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/0805—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B01J2219/0807—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes
    • B01J2219/0824—Details relating to the shape of the electrodes
    • B01J2219/0826—Details relating to the shape of the electrodes essentially linear
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/0805—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B01J2219/0807—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes
    • B01J2219/0824—Details relating to the shape of the electrodes
    • B01J2219/0832—Details relating to the shape of the electrodes essentially toroidal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0803—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J2219/0805—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B01J2219/0807—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges involving electrodes
    • B01J2219/0824—Details relating to the shape of the electrodes
    • B01J2219/0835—Details relating to the shape of the electrodes substantially flat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0875—Gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0892—Materials to be treated involving catalytically active material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0861—Methods of heating the process for making hydrogen or synthesis gas by plasma
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00—Generating plasma; Handling plasma
    • H05H1/24—Generating plasma
    • H05H1/47—Generating plasma using corona discharges
    • H05H1/475—Filamentary electrodes
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H2245/00—Applications of plasma devices
    • H05H2245/10—Treatment of gases
    • H05H2245/17—Exhaust gases

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Electromagnetism (AREA)
  • Mechanical Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Catalysts (AREA)

Abstract

　被改質ガスの導入口４及び改質ガスの排出口８が形成された改質反応器１０と、改質反応器１０の内部空間に、相対向するように配置された一対の電極１２と、一対の電極１２に対してパルス電圧を印加するパルス電源１４とを備え、一対の電極１２の一方が線状電極１２ａであるとともに、一対の電極１２の他方は導電性セラミックスからなり、隔壁によってガスの流路となる複数のセル１６が区画形成されたハニカム電極１２ｂであるプラズマリアクタ１Ａ。
PCT/JP2008/068957 2007-10-30 2008-10-20 プラズマリアクタ WO2009057473A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP08843861A EP2213618B1 (en) 2007-10-30 2008-10-20 Plasma reactor
JP2009539014A JPWO2009057473A1 (ja) 2007-10-30 2008-10-20 プラズマリアクタ
US12/759,022 US20100196224A1 (en) 2007-10-30 2010-04-13 Plasma reactor

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007281415 2007-10-30
JP2007-281415 2007-10-30

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/759,022 Continuation US20100196224A1 (en) 2007-10-30 2010-04-13 Plasma reactor

Publications (1)

Publication Number Publication Date
WO2009057473A1 true WO2009057473A1 (ja) 2009-05-07

Family

ID=40590865

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/068957 WO2009057473A1 (ja) 2007-10-30 2008-10-20 プラズマリアクタ

Country Status (5)

Country Link
US (1) US20100196224A1 (ja)
EP (1) EP2213618B1 (ja)
JP (1) JPWO2009057473A1 (ja)
KR (1) KR20100098505A (ja)
WO (1) WO2009057473A1 (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2272586A1 (en) 2009-06-25 2011-01-12 NGK Insulators, Ltd. Plasma reactor
JP2012067610A (ja) * 2010-09-21 2012-04-05 Ngk Insulators Ltd 排気ガス浄化装置
RU2454044C2 (ru) * 2010-05-05 2012-06-20 Учреждение Российской Академии наук Институт теплофизики им. С.С. Кутателадзе Сибирского отделения РАН (ИТ СО РАН) Электродуговой нагреватель газа
EP2234462A3 (en) * 2009-03-25 2013-02-27 NGK Insulators, Ltd. Reactor for reforming reactions
CN106438112A (zh) * 2016-10-09 2017-02-22 吉林大学 一种车载在线重整催化制氢装置
CN107079574A (zh) * 2014-10-21 2017-08-18 爱德华多·L·科班基亚特 用于提高燃烧效率并使燃烧污染物最小化的氧激发系统
WO2020076186A1 (en) * 2018-10-12 2020-04-16 Mislavskij Boris Vladlenovich A method and device for plasma-chemical gas/gas mixture conversion

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010132482A (ja) * 2008-12-03 2010-06-17 Ngk Insulators Ltd リアクタ
WO2012112065A1 (ru) * 2011-02-18 2012-08-23 "Крено Инвест Са" Способ и устройство для получения синтез - газа
AT514283B1 (de) * 2013-04-19 2015-09-15 Tannpapier Gmbh Plasmaperforation
US10280821B2 (en) * 2013-09-18 2019-05-07 Advanced Technology Emission Solutions Inc. Gaseous emissions treatment structures with electrohydrodynamic heat and mass transfer
US11291102B2 (en) 2017-04-20 2022-03-29 Airinspace S.E. Corona effect plasma device and plasma reactor
FR3087677B1 (fr) * 2018-10-25 2022-12-16 Airinspace Nouveau dispositif d’epuration d’air par plasma
FR3065615B1 (fr) * 2017-04-20 2022-12-16 Airinspace Dispositif plasma a effet corona et reacteur plasma
CN110562917A (zh) * 2019-10-18 2019-12-13 翁幼云 微型重整装置以及微型重整系统

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JP2003073103A (ja) 2001-09-04 2003-03-12 Yasushi Sekine アルコールを原料とする水素の生成方法、及び装置
JP2004345879A (ja) 2003-05-20 2004-12-09 Toyota Motor Corp 炭化水素改質装置
JP2005098134A (ja) * 2003-09-22 2005-04-14 Toyota Motor Corp 排気浄化装置
JP2006056748A (ja) 2004-08-20 2006-03-02 Nissan Motor Co Ltd 燃料改質装置及び燃料の改質方法
JP2006255064A (ja) * 2005-03-16 2006-09-28 Gunma Prefecture 臭気分解装置およびそれを用いた臭気分解方法

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JP4074997B2 (ja) * 2003-09-24 2008-04-16 トヨタ自動車株式会社 排ガス浄化装置
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Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003073103A (ja) 2001-09-04 2003-03-12 Yasushi Sekine アルコールを原料とする水素の生成方法、及び装置
JP2004345879A (ja) 2003-05-20 2004-12-09 Toyota Motor Corp 炭化水素改質装置
JP2005098134A (ja) * 2003-09-22 2005-04-14 Toyota Motor Corp 排気浄化装置
JP2006056748A (ja) 2004-08-20 2006-03-02 Nissan Motor Co Ltd 燃料改質装置及び燃料の改質方法
JP2006255064A (ja) * 2005-03-16 2006-09-28 Gunma Prefecture 臭気分解装置およびそれを用いた臭気分解方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2213618A4

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2234462A3 (en) * 2009-03-25 2013-02-27 NGK Insulators, Ltd. Reactor for reforming reactions
EP2272586A1 (en) 2009-06-25 2011-01-12 NGK Insulators, Ltd. Plasma reactor
JP2011005418A (ja) * 2009-06-25 2011-01-13 Ngk Insulators Ltd プラズマリアクタ
RU2454044C2 (ru) * 2010-05-05 2012-06-20 Учреждение Российской Академии наук Институт теплофизики им. С.С. Кутателадзе Сибирского отделения РАН (ИТ СО РАН) Электродуговой нагреватель газа
JP2012067610A (ja) * 2010-09-21 2012-04-05 Ngk Insulators Ltd 排気ガス浄化装置
CN107079574A (zh) * 2014-10-21 2017-08-18 爱德华多·L·科班基亚特 用于提高燃烧效率并使燃烧污染物最小化的氧激发系统
CN106438112A (zh) * 2016-10-09 2017-02-22 吉林大学 一种车载在线重整催化制氢装置
WO2020076186A1 (en) * 2018-10-12 2020-04-16 Mislavskij Boris Vladlenovich A method and device for plasma-chemical gas/gas mixture conversion
JP2022508750A (ja) * 2018-10-12 2022-01-19 ヴラドレノヴィッチ ミスラフスキー，ボリス プラズマ化学ガス／ガス混合物変換のための方法および装置

Also Published As

Publication number Publication date
US20100196224A1 (en) 2010-08-05
EP2213618B1 (en) 2013-04-03
EP2213618A4 (en) 2011-12-21
EP2213618A1 (en) 2010-08-04
JPWO2009057473A1 (ja) 2011-03-10
KR20100098505A (ko) 2010-09-07

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