Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
  • C10M169/04—Mixtures of base-materials and additives
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
  • C10M2205/17—Fisher Tropsch reaction products
  • C10M2205/173—Fisher Tropsch reaction products used as base material
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
  • C10N2020/01—Physico-chemical properties
  • C10N2020/02—Viscosity; Viscosity index
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
  • C10N2020/01—Physico-chemical properties
  • C10N2020/04—Molecular weight; Molecular weight distribution
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
  • C10N2020/01—Physico-chemical properties
  • C10N2020/081—Biodegradable compounds
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
  • C10N2020/01—Physico-chemical properties
  • C10N2020/085—Non-volatile compounds
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
  • C10N2030/02—Pour-point; Viscosity index
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
  • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
  • C10N2030/74—Noack Volatility
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/08—Hydraulic fluids, e.g. brake-fluids

Definitions

• the invention relates generally to hydraulic fluid compositions, and more specifically to hydraulic fluid compositions having excellent oxidation stability.
• Hydraulic fluids serve as the power transmission medium in a hydraulic system. They are designed to transmit force and motion in industrial, mobile and non- mobile hydraulic systems such as automobiles, tractors, earthmovers, construction machinery, and hydraulic pumps, etc. In one particular application in recent years, e.g., hydraulic systems in construction machinery, higher pressure is applied with smaller sizes of hydraulic pumps and motors to increase the system efficiency. The reduced capacity of the reservoir tank for hydraulic fluid and less ventilation at the engine / pump room for noise protection accelerates oxidation and thermal degradation of hydraulic fluids.
• JCMA Fuels and Lubricants Technical Committee of Japan Construction Mechanization Association
• the references disclose a Fischer Tropsch base oil produced from a process in which the feed is a waxy feed recovered from a Fischer-Tropsch synthesis.
• the process comprises a complete or partial hydroisomerization dewaxing step, using a dual-functional catalyst or a catalyst that can isomerize paraffins selectively.
• Hydroisomerization dewaxing is achieved by contacting the waxy feed with a hydroisomerization catalyst in an isomerization zone under hydroisomerizing conditions.
• Fischer-Tropsch synthesis products can also be obtained by well-known processes such as, for example, the commercial SASOL® Slurry Phase Fischer-Tropsch technology, the commercial SHELL® Middle Distillate Synthesis (SMDS) Process, or by the non-commercial EXXON® Advanced Gas Conversion (AGC-21) process.
• SMDS Synthesis
• AGAC-21 EXXON® Advanced Gas Conversion
• a hydraulic fluid composition comprising (i) a lubricating base oil having consecutive numbers of carbon atoms, less than 10 wt% naphthenic carbon by n-d-M, less than 0.10 wt. % olefins and less than 0.05 wt. % aromatics; (ii) 0.001-20 wt % of at least an additive package; wherein the hydraulic fluid composition meets at least one of JACMAS HK and JCMAS HKB specification standards.
• a method to minimize oxidative degradation of hydraulic fluids for use in construction machinery comprising using a hydraulic fluid composition comprising a lubricating base oil having consecutive numbers of carbon atoms, less than 10 wt% naphthenic carbon by n-d-M, less than 0.10 wt. % olefins and less than 0.05 wt. % aromatics; (ii) 0.001-20 wt % of at least an additive package; wherein the hydraulic fluid composition meets at least one of JACMAS HK and JCMAS HKB specification standards.
• Figure 1 is a graph comparing the change in the kinematic viscosity at 40 0 C. of a hydraulic fluid in the prior art with an embodiment of the hydraulic fluid of the invention in a piston pump test.
• Figure 2 is a graph comparing the change in the acid number of a hydraulic fluid in the prior art with an embodiment of the hydraulic fluid of the invention in a piston pump test.
• hydroaulic fluid is used interchangeably with “functional fluid,” denoting a fluid for use in the transmission of energy in industrial applications as well as mobile and non-mobile vehicles and equipment, as a lubricant, hydraulic fluid, automatic transmission fluid, heat exchange medium or the like.
• Fischer-Tropsch derived means that the product, fraction, or feed originates from or is produced at some stage by a Fischer-Tropsch process.
• Fischer-Tropsch base oil may be used interchangeably with “FT base oil,” “FTBO,” “GTL base oil” (GTL: gas-to-liquid), or “Fischer-Tropsch derived base oil.”
• isomerized base oil refers to a base oil made by isomerization of a waxy feed.
• a "waxy feed" comprises at least 40 wt% n-paraffins. In one embodiment, the waxy feed comprises greater than 50 wt% n-paraffins. In another embodiment, greater than 75 wt% n-paraffins. In one embodiment, the waxy feed also has very low levels of nitrogen and sulphur, e.g., less than 25 ppm total combined nitrogen and sulfur, or in other embodiments less than 20 ppm.
• waxy feeds examples include slack waxes, deoiled slack waxes, refined foots oils, waxy lubricant raffinates, n- paraffin waxes, NAO waxes, waxes produced in chemical plant processes, deoiled petroleum derived waxes, microcrystalline waxes, Fischer-Tropsch waxes, and mixtures thereof.
• the waxy feeds have a pour point of greater than 5O 0 C. In another embodiment, greater than 60 0 C.
• Pour Point Reducing Blend Component refers to an isomerized waxy product with relatively high molecular weights and a specified degree of alkyl branching in the molecule, such that it reduces the pour point of lubricating base oil blends containing it.
• Examples of a Pour Point Reducing Blend Component are disclosed in U.S. Patent Nos. 6,150,577 and 7,053,254, and Patent Publication No. US 2005-0247600 Al .
• a Pour Point Reducing Blend Component can be: 1) an isomerized Fischer-Tropsch derived bottoms product; 2) a bottoms product prepared from an isomerized highly waxy mineral oil, or 3) an isomerized oil having a kinematic viscosity at 100 0 C of at least about 8 mm 2 /s made from polyethylene plastic.
• the "10 percent point" of the boiling range of a Pour Point Reducing Blend Component refers to the temperature at which 10 weight percent of the hydrocarbons present within that cut will vaporize at atmospheric pressure.
• the 90 percent point of the respective boiling ranges refers to the temperature at which 90 weight percent of the hydrocarbons present within that cut will vaporize at atmospheric pressure.
• the boiling range can be measured using the standard analytical method D-6352-04 or its equivalent.
• the boiling range distributions in this disclosure can be measured using the standard analytical method D-2887-06 or its equivalent.
• Kinematic viscosity is a measurement in mm 2 /s of the resistance to flow of a fluid under gravity, determined by ASTM D445-06.
• Viscosity index (VI) is an empirical, unit-less number indicating the effect of temperature change on the kinematic viscosity of the oil. The higher the VI of an oil, the lower its tendency to change viscosity with temperature. Viscosity index is measured according to ASTM D 2270-04.
• Cold-cranking simulator apparent viscosity (CCS VIS) is a measurement in millipascal seconds, mPa.s to measure the viscometric properties of lubricating base oils under low temperature and high shear. CCS VIS is determined by ASTM D 5293-04.
• Brookfield viscosity is used to determine the internal fluid-friction of a lubricant during cold temperature operation, which can be measured by ASTM D 2983- 04.
• "Pour point” is a measurement of the temperature at which a sample of base oil will begin to flow under certain carefully controlled conditions, which can be determined as described in ASTM D 5950-02.
• "Auto ignition temperature” is the temperature at which a fluid will ignite spontaneously in contact with air, which can be determined according to ASTM 659-78.
• "Ln” refers to natural logarithm with base “e.”
• Traction coefficient is an indicator of intrinsic lubricant properties, expressed as the dimensionless ratio of the friction force F and the normal force N, where friction is the mechanical force which resists movement or hinders movement between sliding or rolling surfaces. Traction coefficient can be measured with an MTM Traction Measurement System from PCS Instruments, Ltd.
• the steel ball and disk are independently measured at an average rolling speed of 3 meters per second, a slide to roll ratio of 40 percent, and a load of 20 Newtons.
• consecutive numbers of carbon atoms means that the base oil has a distribution of hydrocarbon molecules over a range of carbon numbers, with every number of carbon numbers in-between.
• the base oil may have hydrocarbon molecules ranging from C22 to C36 or from C30 to C60 with every carbon number in-between.
• the hydrocarbon molecules of the base oil differ from each other by consecutive numbers of carbon atoms, as a consequence of the waxy feed also having consecutive numbers of carbon atoms.
• the source of carbon atoms is CO and the hydrocarbon molecules are built up one carbon atom at a time. Petroleum-derived waxy feeds have consecutive numbers of carbon atoms.
• PAO poly-alpha-olefm
• the molecules of an isomerized base oil have a more linear structure, comprising a relatively long backbone with short branches.
• the classic textbook description of a PAO is a star- shaped molecule, and in particular tridecane, which is illustrated as three decane molecules attached at a central point. While a star-shaped molecules is theoretical, nevertheless PAO molecules have fewer and longer branches that the hydrocarbon molecules that make up the isomerized base oil disclosed herein.
• Molecules with cycloparaffinic functionality mean any molecule that is, or contains as one or more substituents, a monocyclic or a fused multicyclic saturated hydrocarbon group.
• Molecules with monocycloparaffinic functionality mean any molecule that is a monocyclic saturated hydrocarbon group of three to seven ring carbons or any molecule that is substituted with a single monocyclic saturated hydrocarbon group of three to seven ring carbons.
• Molecules with multicycloparaffinic functionality mean any molecule that is a fused multicyclic saturated hydrocarbon ring group of two or more fused rings, any molecule that is substituted with one or more fused multicyclic saturated hydrocarbon ring groups of two or more fused rings, or any molecule that is substituted with more than one monocyclic saturated hydrocarbon group of three to seven ring carbons.
• Oxidator BN measures the response of a lubricating oil in a simulated application. High values, or long times to adsorb one liter of oxygen, indicate good stability. Oxidator BN can be measured via a Dornte-type oxygen absorption apparatus (R. W. Dornte "Oxidation of White Oils," Industrial and Engineering Chemistry, Vol. 28, page 26, 1936), under 1 atmosphere of pure oxygen at 34O 0 F., time to absorb 1000 ml of O 2 by 100 g. of oil is reported. In the Oxidator BN test, 0.8 ml of catalyst is used per 100 grams of oil.
• the catalyst is a mixture of soluble metal-naphthenates simulating the average metal analysis of used crankcase oil.
• the additive package is 80 millimoles of zinc bispolypropylenephenyldithiophosphate per 100 grams of oil.
• Molecular characterizations can be performed by methods known in the art, including Field Ionization Mass Spectroscopy (FIMS) and n-d-M analysis (ASTM D 3238-95 (Re-approved 2005)).
• FIMS Field Ionization Mass Spectroscopy
• ASTM D 3238-95 Re-approved 2005
• aromatics are present in significant amount, they would be identified as 4-unsaturations. When olefins are present in significant amounts, they would be identified as 1 - unsaturations.
• the total of the 1 -unsaturations, 2-unsaturations, 3-unsaturations, 4- unsaturations, 5-unsaturations, and 6-unsaturations from the FIMS analysis, minus the wt % olefins by proton NMR, and minus the wt % aromatics by HPLC-UV is the total weight percent of molecules with cycloparaffinic functionality. If the aromatics content was not measured, it was assumed to be less than 0.1 wt % and not included in the calculation for total weight percent of molecules with cycloparaffinic functionality.
• the total weight percent of molecules with cycloparaffinic functionality is the sum of the weight percent of molecules with monocyclopraffinic functionality and the weight percent of molecules with multicycloparaffinic functionality.
• Molecular weights are determined by ASTM D2503-92(Reapproved 2002). The method uses thermoelectric measurement of vapour pressure (VPO). In circumstances where there is insufficient sample volume, an alternative method of ASTM D2502-94 may be used; and where this has been used it is indicated.
• VPO vapour pressure
• ASTM D4052-96 Density is determined by ASTM D4052-96 (Reapproved 2002). The sample is introduced into an oscillating sample tube and the change in oscillating frequency caused by the change in the mass of the tube is used in conjunction with calibration data to determine the density of the sample.
• Weight percent olefins can be determined by proton-NMR according to the steps specified herein.
• the olefins are conventional olefins, i.e. a distributed mixture of those olefin types having hydrogens attached to the double bond carbons such as: alpha, vinylidene, cis, trans, and trisubstituted, with a detectable allylic to olefin integral ratio between 1 and 2.5. When this ratio exceeds 3, it indicates a higher percentage of tri or tetra substituted olefins being present, thus other assumptions known in the analytical art can be made to calculate the number of double bonds in the sample.
• the steps are as follows: A) Prepare a solution of 5-10% of the test hydrocarbon in deuterochloroform. B) Acquire a normal proton spectrum of at least 12 ppm spectral width and accurately reference the chemical shift (ppm) axis, with the instrument having sufficient gain range to acquire a signal without overloading the receiver/ADC, e.g., when a 30 degree pulse is applied, the instrument having a minimum signal digitization dynamic range of 65,000. In one embodiment, the instrument has a dynamic range of at least 260,000. C) Measure the integral intensities between: 6.0-4.5 ppm (olefin); 2.2-1.9 ppm (allylic); and 1.9-0.5 ppm (saturate).
• the wt% olefins by proton NMR 100 times the number of double bonds times the number of hydrogens in a typical olefin molecule divided by the number of hydrogens in a typical test substance molecule.
• the wt% olefins by proton NMR calculation procedure, D works particularly well when the percent olefins result is low, less than 15 wt%.
• Weight percent aromatics in one embodiment can be measured by HPLC- UV. In one embodiment, the test is conducted using a Hewlett Packard 1050 Series
• HPLC Quaternary Gradient High Performance Liquid Chromatography
• HP 1050 Diode-Array UV-Vis detector interfaced to an HP Chem-station.
• Identification of the individual aromatic classes in the highly saturated base oil can be made on the basis of the UV spectral pattern and the elution time.
• the amino column used for this analysis differentiates aromatic molecules largely on the basis of their ring- number (or double-bond number).
• the single ring aromatic containing molecules elute first, followed by the polycyclic aromatics in order of increasing double bond number per molecule.
• those with only alkyl substitution on the ring elute sooner than those with naphthenic substitution.
• Unequivocal identification of the various base oil aromatic hydrocarbons from their UV absorbance spectra can be accomplished recognizing that their peak electronic transitions are all red-shifted relative to the pure model compound analogs to a degree dependent on the amount of alkyl and naphthenic substitution on the ring system.
• Quantification of the eluting aromatic compounds can be made by integrating chromatograms made from wavelengths optimized for each general class of compounds over the appropriate retention time window for that aromatic.
• Retention time window limits for each aromatic class can be determined by manually evaluating the individual absorbance spectra of eluting compounds at different times and assigning them to the appropriate aromatic class based on their qualitative similarity to model compound absorption spectra.
• HPLC-UV Calibration can be used for identifying classes of aromatic compounds even at very low levels, e.g., multi-ring aromatics typically absorb 10 to 200 times more strongly than single-ring aromatics. Alkyl-substitution affects absorption by 20%. Integration limits for the co-eluting 1-ring and 2-ring aromatics at 272nm can be made by the perpendicular drop method. Wavelength dependent response factors for each general aromatic class can be first determined by constructing Beer's Law plots from pure model compound mixtures based on the nearest spectral peak absorbances to the substituted aromatic analogs.
• Weight percent concentrations of aromatics can be calculated by assuming that the average molecular weight for each aromatic class was approximately equal to the average molecular weight for the whole base oil sample. [038] NMR analysis. In one embodiment, the weight percent of all molecules with at least one aromatic function in the purified mono-aromatic standard can be confirmed via long-duration carbon 13 NMR analysis. The NMR results can be translated from % aromatic carbon to % aromatic molecules (to be consistent with HPLC-UV and D 2007) knowing that 95-99% of the aromatics in highly saturated base oils are single-ring aromatics.
• Branching and branching position can be determined using carbon- 13 ( 13 C) NMR according to the following nine-step process: 1) Identify the CH branch centers and the CH 3 branch termination points using the DEPT Pulse sequence (Doddrell, D.T.; D. T. Pegg; M.R. Bendall, Journal of Magnetic Resonance 1982, 48, 323ff.). 2) Verify the absence of carbons initiating multiple branches (quaternary carbons) using the APT pulse sequence (Patt, S.L.; J. N. Shoolery, Journal of Magnetic Resonance 1982, 46, 535ff.). 3) Assign the various branch carbon resonances to specific branch positions and lengths using tabulated and calculated values known in the art (Lindeman, L.
• the average carbon number is determined by dividing the molecular weight of the sample by 14 (the formula weight of CH 2 ). 6) The number of branches per molecule is the sum of the branches found in step 4. 7) The number of alkyl branches per 100 carbon atoms is calculated from the number of branches per molecule (step 6) times 100 / average carbon number. 8) Estimate Branching Index (BI) by 1 H NMR Analysis, which is presented as percentage of methyl hydrogen (chemical shift range 0.6-1.05 ppm) among total hydrogen as estimated by NMR in the liquid hydrocarbon composition.
• % in chloroform-dl are excited by 30 degrees pulses followed by a 1.3 seconds (sec.) acquisition time.
• the broadband proton inverse-gated decoupling is used during a 6 sec. delay prior to the excitation pulse and on during acquisition.
• Samples are doped with 0.03 to 0.05 M Cr (acac) 3 (tris (acetyl acetonato)-chromium (III)) as a relaxation agent to ensure full intensities are observed.
• the DEPT and APT sequences can be carried out according to literature descriptions with minor deviations described in the Varian or Bruker operating manuals.
• DEPT is Distortionless Enhancement by Polarization Transfer.
• the DEPT 45 sequence gives a signal all carbons bonded to protons.
• DEPT 90 shows CH carbons only.
• DEPT 135 shows CH and CH 3 up and CH 2 180 degrees out of phase (down).
• APT is attached proton test, known in the art. It allows all carbons to be seen, but if CH and CH 3 are up, then quaternaries and CH 2 are down.
• the branching properties of the sample can be determined by 13 C NMR using the assumption in the calculations that the entire sample was iso-paraffinic. The unsaturates content may be measured using Field Ionization Mass Spectroscopy (FIMS).
• the hydraulic fluid composition comprises 0.001 - 20 wt. % optional additives in a matrix of base oil or base oil blends in an amount of 80 to 99.999 wt. % based on the total weight of the composition.
• the matrix of base oil or blends thereof comprises at least an isomerized base oil which the product itself, its fraction, or feed originates from or is produced at some stage by isomerization of a waxy feed from a Fischer-Tropsch process ("Fischer-Tropsch derived base oils").
• the base oil comprises at least an isomerized base oil made from a substantially paraffinic wax feed ("waxy feed”).
• Fischer-Tropsch derived base oils are disclosed in a number of patent publications, including for example U.S. Pat. Nos. 6080301, 6090989, and 6165949, and US Patent Publication No.
• Fischer-Tropsch process is a catalyzed chemical reaction in which carbon monoxide and hydrogen are converted into liquid hydrocarbons of various forms including a light reaction product and a waxy reaction product, with both being substantially paraffinic.
• the isomerized base oil has consecutive numbers of carbon atoms and has less than 10 wt% naphthenic carbon by n-d-M.
• the isomerized base oil made from a waxy feed has a kinematic viscosity at 100 0 C between 1.5 and 3.5 mm 2 /s.
• the isomerized base oil is made by a process in which the hydroisomerization dewaxing is performed at conditions sufficient for the base oil to have: a) a weight percent of all molecules with at least one aromatic functionality less than 0.30; b) a weight percent of all molecules with at least one cycloparaffinic functionality greater than 10; c) a a ratio of weight percent molecules with monocycloparaff ⁇ nic functionality to weight percent molecules with multicycloparaffinic functionality greater than 20 and d) a viscosity index greater than 28 x Ln (Kinematic viscosity at 100 0 C.) + 80.
• the isomerized base oil is made from a process in which the highly paraffinic wax is hydroisomerized using a shape selective intermediate pore size molecular sieve comprising a noble metal hydrogenation component, and under conditions of 600 - 75O 0 F. (315 - 399 0 C.) In the process, the conditions for hydroisomerization are controlled such that the conversion of the compounds boiling above 700 0 F (371 0 C.) in the wax feed to compounds boiling below 700 0 F (371 0 C.) is maintained between 10 wt % and 50 wt%.
• a resulting isomerized base oil has a kinematic viscosity of between 1.0 and 3.5 mm 2 /s at 100 0 C. and aNoack volatility of less than 50 weight %.
• the base oil comprises greater than 3 weight % molecules with cycloparaffinic functionality and less than 0.30 weight percent aromatics.
• the isomerized base oil has a Noack volatility less than an amount calculated by the following equation: 1000 x (Kinematic Viscosity at 100 0 C) " 2 7 .
• the isomerized base oil has a Noack volatility less than an amount calculated by the following equation: 900 x (Kinematic Viscosity at 100 0 C.) '2 8 .
• the isomerized base oil has a Kinematic Viscosity at 100 0 C.
• the isomerized base oil has a kinematic viscosity at 100°C. of less than 4.0 mm 2 /s, and a wt% Noack volatility between 0 and 100.
• the isomerized base oil has a kinematic viscosity between 1.5 and 4.0 mm 2 /s and a Noack volatility less than the Noack volatility calculated by the following equation: 160 - 40 (Kinematic Viscosity at 100 0 C).
• the isomerized base oil has a kinematic viscosity at 100 0 C. in the range of 2.4 and 3.8 mm 2 /s and a Noack volatility less than an amount defined by the equation: 900 x (Kinematic Viscosity at 100°C.) "2 8 -15).
• 900 x Kinematic Viscosity at 100 0 C
• 2 8 -15 provides a lower Noack volatility than the equation: 160- 40 (Kinematic Viscosity at 100 0 C.)
• the isomerized base oil is made from a process in which the highly paraffinic wax is hydroisomerized under conditions for the base oil to have a kinematic viscosity at 100°C. of 3.6 to 4.2 mm 2 /s, a viscosity index of greater than 130, a wt% Noack volatility less than 12, a pour point of less than -9 0 C.
• the isomerized base oil has an aniline point, in degrees F, greater than 200 and less than or equal to an amount defined by the equation: 36 x Ln(Kinematic Viscosity at 100 0 C, in mm 2 /s) + 200.
• AIT in 0 C. 1.6 x (Kinematic Viscosity at 40 0 C, in mm2/s) + 300.
• the base oil as an AIT of greater than 329 0 C. and a viscosity index greater than 28 x Ln (Kinematic Viscosity at 100 0 C, in mm 2 /s) + 100.
• the isomerized base oil has a traction coefficient of less than 0.023 (or less than 0.021) when measured at a kinematic viscosity of 15 mm 2 /s and at a slide to roll ratio of 40%.
• the isomerized base oil has a traction coefficient of less than 0.017 when measured at a kinematic viscosity of 15 mm 2 /s and at a slide to roll ratio of 40%. In another embodiment the isomerized base oil has a viscosity index greater than 150 and a traction coefficient less than 0.015 when measured at a kinematic viscosity of 15 mni 2 /s and at a slide to roll ratio of 40 percent.
• the isomerized base oil having low traction coefficients also displays a higher kinematic viscosity and higher boiling points.
• the base oil has a traction coefficient less than 0.015, and a 50 wt% boiling point greater than 565°C (1050 0 F).
• the base oil has a traction coefficient less than 0.011 and a 50 wt% boiling point by ASTM D 6352-04 greater than 582°C. (1080 0 F).
• the isomerized base oil having low traction coefficients also displays unique branching properties by NMR, including a branching index less than or equal to 23.4, a branching proximity greater than or equal to 22.0, and a Free Carbon Index between 9 and 30.
• the base oil has at least 4 wt% naphthenic carbon, in another embodiment, at least 5 wt% naphthenic carbon by n- d-M analysis by ASTM D 3238-95 (Reapproved 2005).
• the isomerized base oil is produced in a process wherein the intermediate oil isomerate comprises paraffinic hydrocarbon components, and in which the extent of branching is less than 7 alkyl branches per 100 carbons, and wherein the base oil comprises paraffinic hydrocarbon components in which the extent of branching is less than 8 alkyl branches per 100 carbons and less than 20 wt % of the alkyl branches are at the 2 position.
• the base oil comprises greater than 10 wt. % and less than 70 wt. % total molecules with cycloparaffinic functionality, and a ratio of weight percent molecules with monocycloparaffinic functionality to weight percent molecules with multicycloparaffinic functionality greater than 15.
• the isomerized base oil has an average molecular weight between 600 and 1100, and an average degree of branching in the molecules between 6.5 and 10 alkyl branches per 100 carbon atoms.
• the isomerized base oil has a kinematic viscosity between about 8 and about 25 mm 2 /s and an average degree of branching in the molecules between 6.5 and 10 alkyl branches per 100 carbon atoms.
• the isomerized base oil is obtained from a process in which the highly paraffinic wax is hydroisomerized at a hydrogen to feed ratio from 712.4 to 3562 liter H 2 /liter oil, for the base oil to have a total weight percent of molecules with cycloparaffinic functionality of greater than 10, and a ratio of weight percent molecules with monocycloparaffinic functionality to weight percent molecules with multicycloparaffinic functionality of greater than 15.
• the base oil has a viscosity index greater than an amount defined by the equation: 28 x Ln (Kinematic viscosity at 100 0 C.) + 95.
• the base oil comprises a weight percent aromatics less than 0.30; a weight percent of molecules with cycloparaffinic functionality greater than 10; a ratio of weight percent of molecules with monocycloparaffinic functionality to weight percent of molecules with multicycloparaffinic functionality greater than 20; and a viscosity index greater than 28 x Ln (Kinematic Viscosity at 100°C.) + 110.
• the base oil further has a kinematic viscosity at 100°C. greater than 6 mm 2 /s.
• the base oil has a weight percent aromatics less than 0.05 and a viscosity index greater than 28 x Ln (Kinematic Viscosity at 100 0 C.) + 95.
• the base oil has a weight percent aromatics less than 0.30, a weight percent molecules with cycloparaffinic functionality greater than the kinematic viscosity at 100 0 C, in mm 2 /s, multiplied by three, and a ratio of molecules with monocycloparaffinic functionality to molecules with multicycloparaffinic functionality greater than 15.
• the isomerized base oil contains between 2 and 10 % naphthenic carbon as measured by n-d-M.
• the base oil has a kinematic viscosity of 1.5 - 3.0 mm 2 /s at 100 0 C. and 2-3 % naphthenic carbon.
• the isomerized base oil has an average molecular weight greater than 475; a viscosity index greater than 140, and a weight percent olefins less than 10.
• the base oil improves the air release and low foaming characteristics of the mixture when incorporated into the hydraulic fluid composition.
• the isomerized base oil is a white oil as disclosed in U.S. Patent No. 7,214,307 and US Patent Publication US20060016724.
• the hydraulic composition employs a base oil that consists of at least one of the isomerized base oils described above. In another embodiment, the composition consists essentially of at least a Fischer-Tropsch base oil.
• the hydraulic fluid comprises an isomerized base oil having lbetween 0.001 to 0.05 wt. % aromatics and a molecular weight of greater than 600 by ASTM D 2503-92 (Reapproved 2002), and 0 to 0.10 wt. % olefins.
• the isomerized base oil has a molecular weight of greater than 650.
• the isomerized base oil has a wt% total molecules with cycloparaffinic functionality greater than 25 and a ratio of molecules with monocycloparaffinic functionality to molecules with multicyloparaffinic functionality greater than 10.
• the hydraulic fluid comprises an isomerized base oil having a kinematic viscosity at 100 0 C. between 6 mm 2 /s and 20 mm 2 /s; a kinematic viscosity at 40 0 C.
• the hydraulic fluid composition employs at least a isomerized base oil (or mixtures of isomerized base oils) and optionally 5 to 50 wt. % (based on the weight of the base oil matrix) of at least another type of oil, e.g., lubricant base oils selected from vegetable oils (e.g., soybean, sunflower, rape seed, etc.), Group I, II, III, IV, and V lubricant base oils as defined in the API Interchange Guidelines, and mixtures thereof. Examples include conventionally used mineral oils, synthetic hydrocarbon oils or synthetic ester oils, or mixtures thereof depending on the application. Mineral lubricating oil base stocks can be any conventionally refined base stocks derived from paraffinic, naphthenic and mixed base crudes.
• Synthetic lubricating oils that can be used include esters of glycols and complex esters.
• Other synthetic oils that can be used include synthetic hydrocarbons such as polyalphaolefins; alkyl benzenes, e.g., alkylate bottoms from the alkylation of benzene with tetrapropylene, or the copolymers of ethylene and propylene; silicone oils, e.g., ethyl phenyl polysiloxanes, methyl polysiloxanes, etc., polyglycol oils, e.g., those obtained by condensing butyl alcohol with propylene oxide; etc.
• suitable synthetic oils include the polyphenyl ethers, e.g., those having from 3 to 7 ether linkages and 4 to 8 phenyl groups.
• Other suitable synthetic oils include polyisobutenes, and alkylated aromatics such as alkylated naphthalenes.
• the hydraulic fluid composition is characterized as having excellent oxidation stability with minimal amount of oxidation additives added.
• antioxidants oxidation additives
• examples of antioxidants include but are not limited to the group of phenolic antioxidants, aromatic amine antioxidants, sulfurized phenolic antioxidants, and organic phosphites, among others.
• phenolic antioxidants examples include 2,6-di-tert-butylphenol, liquid mixtures of tertiary butylated phenols, 2,6-di-tert-butyl-4-methylphenol, 4,4'-methylenebis(2,6-di-tert-butylphenol), 2,2'- methylenebis(4-methyl6-tert-butylphenol), mixed methylene-bridged polyalkyl phenols, 4,4'-thiobis(2-methyl-6-tert-butylphenol),
• the antioxidant is an organic phosphonate having at least one direct carbon-to-phosphorus linkage.
• Diphenylamine-type oxidation inhibitors include, but are not limited to, alkylated diphenylamine, phenyl-alpha-naphthylamine, and alkylated-alpha-naphthylamine.
• Other types of oxidation inhibitors include metal dithiocarbamate (e.g., zinc dithiocarbamate), and 15-methylenebis(dibutyldithiocarbamate).
• the composition optionally comprises 0.01 to 1 wt. % of a seal swell agent.
• the level of seal swell additives is less than 0.5 wt. %.
• optional seal swell agents known include but are not limited to dioctylphthalate, tertiary diamide, dioctyl sebacate, polyol esters, branched chain carboxylic esters and mixtures thereof.
• the hydraulic fluid composition further comprises 0.001 to 6 wt. %. of at least a viscosity index modifier.
• the viscosity index modifiers used is a mixture of modifiers selected from polyacrylate or polymethacrylate and polymers, comprising vinyl aromatic units and esterified carboxyl- containing units.
• the first viscosity modifier is a polyacrylate or polymethacrylate having an average molecular weight of 10,000 to 60,000.
• the second viscosity modifier comprises vinyl aromatic units and esterified carboxyl-containing units, having an average molecular weight of 100,000 to 200,000.
• the viscosity modifier is a blend of a polymethacryalte viscosity index improver having a weight average molecular weight of 25,000 to 150,000 and a shear stability index less than 5 and a polymethacryate viscosity index improver having a weight average molecular weight of 500,000 to 1,000,000 and a shear stability index of 25 to 60.
• the viscosity modifier is selected from the group of polymethacrylate type polymers, ethylene-propylene copolymers, styrene-isoprene copolymers, hydrated styrene-isoprene copolymers, polyisobutylene, and mixtures thereof.
• the hydraulic fluid further comprises at least a surfactant, or also known as a dispersant, which can be generally classified as anionic, cationic, zwitterionic, or non-ionic.
• a dispersant may be used alone or in combination of one or more species or types of dispersants. Examples include an oil-soluble dispersant selected from the group consisting of succinimide dispersants, succinic ester dispersants, succinic ester-amide dispersant, Mannich base dispersant, phosphorylated forms thereof, and boronated forms thereof.
• the dispersants may be capped with acidic molecules capable of reacting with secondary amino groups.
• the molecular weight of the hydrocarbyl groups may range from 600 to 3000, for example from 750 to 2500, and as a further example from 900 to 1500.
• the dispersant is selected from the group of alkenyl succinimides, alkenyl succinimides modified with other organic compounds, alkenyl succinimides modified by post-treatment with ethylene carbonate or boric acid, pentaerythritols, phenate-salicylates and their post-treated analogs, alkali metal or mixed alkali metal, alkaline earth metal borates, dispersions of hydrated alkali metal borates, dispersions of alkaline-earth metal borates, polyamide ashless dispersants and the like or mixtures of such dispersants.
• the ashless dispersant may include the products of the reaction of a polyethylene polyamine, e.g., triethylene tetramine or tetraethylene pentamine, with a hydrocarbon substituted carboxylic acid or anhydride made by reaction of a polyolefin, such as polyisobutene, of suitable molecular weight, with an unsaturated polycarboxylic acid or anhydride, e.g., maleic anhydride, maleic acid, fumaric acid, or the like, including mixtures of two or more such substances.
• the ashless dispersant is a borated dispersant.
• Borated dispersants may be formed by boronating (borating) an ashless dispersant having basic nitrogen and/or at least one hydroxyl group in the molecule, such as succinimide dispersant, succinamide dispersant, succinic ester dispersant, succinic ester-amide dispersant, Mannich base dispersant, or hydrocarbyl amine or polyamine dispersant.
• the hydraulic fluid further comprises one or more metallic detergents.
• metallic detergent include an oil-soluble neutral or overbased salt of alkali or alkaline earth metal with one or more of the following acidic substances (or mixtures thereof): (1) a sulfonic acid, (2) a carboxylic acid, (3) a salicylic acid, (4) an alkyl phenol, (5) a sulfurized alkyl phenol, and (6) an organic phosphorus acid characterized by at least one direct carbon-to-phosphorus linkage, such as phosphonate.
• Such an organic phosphorus acid may include those prepared by the treatment of an olefin polymer (e.g., polyisobutylene having a molecular weight of 1,000) with a phosphorizing agent such as phosphorus trichloride, phosphorus heptasulfide, phosphorus pentasulfide, phosphorus trichloride and sulfur, white phosphorus and a sulfur halide, or phosphorothioic chloride.
• an olefin polymer e.g., polyisobutylene having a molecular weight of 1,000
• a phosphorizing agent such as phosphorus trichloride, phosphorus heptasulfide, phosphorus pentasulfide, phosphorus trichloride and sulfur, white phosphorus and a sulfur halide, or phosphorothioic chloride.
• the metallic detergent is selected from the group of sulfurized or unsulfurized alkyl or alkenyl phenates, alkyl or alkenyl aromatic sulfonates, borated sulfonates, sulfurized or unsulfurized metal salts of multi-hydroxy alkyl or alkenyl aromatic compounds, alkyl or alkenyl hydroxy aromatic sulfonates, sulfurized or unsulfurized alkyl or alkenyl naphthenates, metal salts of alkanoic acids, metal salts of an alkyl or alkenyl multiacid, and chemical and physical mixtures thereof.
• the hydraulic fluid further comprises at least a corrosion inhibitor selected from thiazoles, triazoles, and thiadiazoles.
• a corrosion inhibitor selected from thiazoles, triazoles, and thiadiazoles.
• examples of such compounds include benzotriazole, tolyltriazole, octyltriazole, decyltriazole, dodecyltriazole, 2-mercapto benzothiazole, 2,5-dimercapto-l,3,4-thiadiazole, 2- mercapto-5-hydrocarbylthio-l ,3,4-thiadiazoles, 2-mercapto-5-hydrocarbyldithio-l ,3,4- thiadiazoles, 2,5-bis(hydrocarbylthio)-l,3,4-thiadiazoles, and 2,5-bis(hydrocarbyldithio)- 1,3,4-thiadiazoles.
• Suitable compounds include the 1,3,4-thiadiazoles, a number of which are available as articles of commerce, and also combinations of triazoles such as tolyltriazole with a 1,3,5-thiadiazoIe such as 2,5-bis(alkyldithio)-l,3,4-thiadiazole.
• the 1,3,4-thiadiazoles are generally synthesized from hydrazine and carbon disulfide by known procedures. See, for example, U.S. Pat. Nos. 2,765,289; 2,749,311 ; 2,760,933; 2,850,453; 2,910,439; 3,663,561; 3,862,798; and 3,840,549.
• the hydraulic fluid composition further includes rust or corrosion inhibitors selected from the group of monocarboxylic acids and polycarboxylic acids.
• suitable monocarboxylic acids are octanoic acid, decanoic acid and dodecanoic acid.
• Suitable polycarboxylic acids include dimer and trimer acids produced from acids such as tall oil fatty acids, oleic acid, linoleic acid, or the like.
• rust inhibitor may comprise alkenyl succinic acid and alkenyl succinic anhydride corrosion inhibitors, for example, tetrapropenylsuccinic acid, tetrapropenylsuccinic anhydride, tetradecenylsuccinic acid, tetradecenylsuccinic anhydride, hexadecenylsuccinic acid, hexadecenylsuccinic anhydride, and the like.
• half esters of alkenyl succinic acids having 8 to 24 carbon atoms in the alkenyl group with alcohols such as the polyglycols.
• Suitable rust or corrosion inhibitors include ether amines; acid phosphates; amines; polyethoxylated compounds such as ethoxylated amines, ethoxylated phenols, and ethoxylated alcohols; imidazolines; aminosuccinic acids or derivatives thereof, and the like. Mixtures of such rust or corrosion inhibitors can be used.
• Other examples of rust inhibitors include a polyethoxylated phenol, neutral calcium sulfonate and basic calcium sulfonate.
• the hydraulic fluid further comprise at least a friction modifier selected from the group of succinimide, a bis-succinimide, an alkylated fatty amine, an ethoxylated fatty amine, an amide, a glycerol ester, an imidazoline, fatty alcohol, fatty acid, amine, borated ester, other esters, phosphates, phosphites, phosphonates, and mixtures thereof.
• a friction modifier selected from the group of succinimide, a bis-succinimide, an alkylated fatty amine, an ethoxylated fatty amine, an amide, a glycerol ester, an imidazoline, fatty alcohol, fatty acid, amine, borated ester, other esters, phosphates, phosphites, phosphonates, and mixtures thereof.
• the hydraulic fluid composition further comprises at least an antiwear additive.
• antiwear additive examples include, but are not limited to, phosphates, carbamates, esters, and molybdenum complexes.
• the antiwear additive is selected from the group of a zinc dialkyl dithio phosphate (ZDDP), an alkyl phosphite, a trialkyl phosphite, and amine salts of dialkyl and mono-alkyl phosphoric acid.
• the hydraulic fluid optionally comprises a sufficient amount of pour point depressant to cause the pour point of the hydraulic fluid to be at least 3 0 C below the pour point of a blend that does not have the pour point depressant.
• Pour point depressants are known in the art and include, but are not limited to esters of maleic anhydride-styrene copolymers, polymethacrylates, polyacrylates, polyacrylamides, condensation products of haloparaffin waxes and aromatic compounds, vinyl carboxylate polymers, and terpolymers of dialkylfumarates, vinyl esters of fatty acids, ethylene-vinyl acetate copolymers, alkyl phenol formaldehyde condensation resins, alkyl vinyl ethers, olefin copolymers, and mixtures thereof.
• the pour point depressant is a Pour Point Reducing Blend Component.
• the Pour Point Reducing Blend Component is an isomerized Fischer-Tropsch derived vacuum distillation bottoms product, which is a high boiling syncrude fraction which has been isomerized under controlled conditions to give a specified degree of alkyl branching in the molecule.
• Syncrude prepared from the Fischer-Tropsch process comprises a mixture of various solid, liquid, and gaseous hydrocarbons.
• the pour Point Reducing Blend Component is an isomerized Fischer-Tropsch derived vacuum distillation bottoms product having an average molecular weight between 600 and 1100 and an average degree of branching in the molecules between 6.5 and 10 alkyl branches per 100 carbon atoms.
• the higher molecular weight hydrocarbons are more effective as Pour Point Reducing Blend Components than the lower molecular weight hydrocarbons.
• a higher cut point in a vacuum distillation unit which results in a higher boiling bottoms material is used to prepare the Pour Point Reducing Blend Component.
• the higher cut point also has the advantage of resulting in a higher yield of the distillate base oil fractions.
• the Pour Point Reducing Blend Component is an isomerized Fischer- Tropsch derived vacuum distillation bottoms product having a pour point that is at least 3 0 C. higher than the pour point of the distillate base oil it is blended with.
• the 10 percent point of the boiling range of the Pour Point Reducing Blend Component that is a vacuum distillation bottoms product is between about 85O 0 F - 1050 0 F (454 - 565 0 C).
• the Pour Point Reducing Blend Component is derived from either Fischer-Tropsch or petroleum products, having a boiling range above 95O 0 F. (510 0 C), and contains at least 50 percent by weight of paraffins. In yet another embodiment the Pour Point Reducing Blend Component has a boiling range above 1050 0 F. (565 0 C.)
• the pour Point Reducing Blend Component is an isomerized petroleum derived base oil containing material having a boiling range above about 1050 0 F.
• the isomerized bottoms material is solvent dewaxed prior to being used as a Pour Point Reducing Blend Component.
• the waxy product further separated during solvent dewaxing from the Pour Point Reducing Blend Component were found to display excellent improved pour point depressing properties compared to the oily product recovered after the solvent dewaxing.
• the Pour Point Reducing Blend Component has an average degree of branching in the molecules within the range of from 6.5 to 10 alkyl branches per 100 carbon atoms.
• the pour Point Reducing Blend Component has an average molecular weight between 600 - 1100. In a third embodiment, between 700 - 1000. In one embodiment, the Pour Point Reducing Blend Component has a kinematic viscosity at 100 0 C. of 8 - 30 mm 2 /s, with the 10% point of the boiling range of the bottoms falling between about 850- 1050 0 F. In yet another embodiment, the Pour Point Reducing Blend Component has a kinematic viscosity at 100°C of 15- 20 mm 2 /s and a pour point of -8 to -12 0 C.
• the pour Point Reducing Blend Component is an isomerized oil having a kinematic viscosity at 100°C of at least about 8 mm 2 /s made from polyethylene plastic.
• the Pour Point Reducing Blend Component is made from waste plastic.
• the Pour Point Reducing Blend Component is made from a process comprising: pyrolysis of polyethylene plastic, separating out a heavy fraction, hydrotreating the heavy fraction, catalytic isomerizing the hydrotreated heavy fraction, and collecting the Pour Point Reducing Blend
• the Pour Point Reducing Blend Component derived from polyethylene plastic has a boiling range above 1050 0 F. (565 0 C), or even a boiling range above 1200 0 F (649°C).
• the hydraulic fluid futher comprises at least an extreme pressure anti-wear agent (EP/AW Agent).
• EP/AW Agent extreme pressure anti-wear agent
• examples include zinc dialky-1-dithiophosphate (primary alkyl, secondary alkyl, and aryl type), diphenyl sulfide, methyl trichlorostearate, chlorinated naphthalene, fluoroalkylpolysiloxane, lead naphthenate, neutralized phosphates, dithiophosphates, and sulfur-free phosphates.
• the hydraulic fluid may also include conventional additives in addition to those described above.
• additives include but are not limited to colorants, metal deactivators such as disalicylidene propylenediamine, triazole derivatives, thiadiazole derivatives, and mercaptobenzimidazoles, antifoam and defoamer additives such as alkyl methacrylate polymers and dimethyl silicone polymers, and/or air expulsion additives.
• additives may be added to provide, for example, viscometric multigrade functionality.
• the additional components are added as a fully formulated additive package fully formulated to meet an original equipment manufacturer's requirements for a hydraulic fluid, e.g., giving the fluid the capacity to meet bench and dynamometer tests.
• the package to be used depends in part by the requirements of the specific equipment to receive the lubricant composition. Examples of additives and additive packages that have been used in hydraulic fluids are disclosed in U.S. Pat. Nos. 5,635,459 and 5,843,873.
• the additive package comprises among other materials, metal-containing detergents, in an amount of 1 - 2% (e.g.
• a calcium-overbased sulfonate detergent 1.41%
• antioxidants or anti-wear agents in an amount of 1 - 2 % (e.g., 1.69%) of a zinc dialkyldithiophosphate; 0.5 to 2% (e.g. 1.03%) of friction modifiers; and 0.1 to 2 % (e.g., 0.25%) of a nitrogen-containing dispersant such as succinimide dispersants.
• Other conventional components may also be present, if desired.
• additives can provide a multiplicity of effects; thus for example, a single additive may act as a dispersant as well as an oxidation inhibitor.
• each additive when the hydraulic fluid contains one or more of the above-mentioned additives, each additive is typically blended into the base oil in an amount that enables the additive to provide its desired function. It may be desirable, although not essential, to prepare one or more additive concentrates comprising additives (concentrates containing at least one of above-mentioned additives sometimes being referred to as "additive packages") to add to the hydraulic fluid composition.
• the final composition may employ from about 0.001 to 20 wt.% of the concentrate, the remainder being the oil of lubricating viscosity.
• the components can be blended in any order and can be blended as combinations of components.
• Additives used in formulating the hydraulic fluid composition can be blended into the base oil matrix individually or in various sub- combinations to subsequently form the hydraulic fluid.
• all of the components are blended concurrently using an additive concentrate (i.e., additives plus a diluent, such as a hydrocarbon solvent).
• an additive concentrate i.e., additives plus a diluent, such as a hydrocarbon solvent.
• the use of an additive concentrate takes advantage of the mutual compatibility afforded by the combination of ingredients when in the form of an additive concentrate.
• the hydraulic fluid composition is prepared by mixing the base oil matrix with the separate additives or additive package(s) at an appropriate temperature, such as approximately 6O 0 C, until homogeneous.
• the hydraulic fluid is characterized as having excellent oxidation stability, i.e., meeting all of the performance specifications of JACMAS HK.
• oxidation stability of a hydraulic fluid is evaluated based on: a) change in the fluid viscosity; b) increase in the acid number; c) the amount of sludge generated; and d) change in the copper content in a fluid.
• the hydraulic fluid is characterized as having excellent oxidation stability with a change (variation) in kinematic viscosity of less than 5% (from the starting viscosity) over a period of 1000 hours in operation in a JCMAS HK test. In a second embodiment, the viscosity variation is less than 2.5 % over a period of 1000 hrs.
• the hydraulic fluid composition is characterized as being very stable for use with a wide range of temperatures with a viscosity index (VI) of at least 140.
• the hydraulic fluid has a VI of at least 150.
• a VI of at least 160 is another embodiment.
• the hydraulic fluid composition is characterized as being particularly suitable for use in applications demanding the use of fire resistant fluids, e.g., electrohydraulic control for driving electric generators in a power plant with a flash point of at least 27O 0 C.
• the hydraulic fluid has a flash point of at least 28O 0 C.
• the hydraulic fluid composition has an auto-ignition temperature of at least 36O 0 C.
• the hydraulic fluid has is characterized as having excellent air release properties and low foaming tendency with air release of less than 0.8 minutes at 50 degrees C. as measured by ASTM D 3427-06, and a sequence II foam tendency by ASTM D 892-03 of less than 50 ml.
• the hydraulic fluid composition consisting essentially of at least an isomerized base oil such as a Fischer-Tropsch derived base oil shows OECD 30 ID levels ranging from inherently biodegradable of > 30% to readily biodegradable of > 90%.
• JCMAS HKB is the specification for biodegradable hydraulic fluids for construction machinery, with a current biodegradability standard of at least 60% or more within 28 days as measured by test methods such as OECD 301 D.
• a hydraulic fluid composition containing an isomerized base oil having a kinematic viscosity at 4O 0 C. of ⁇ 100 mm 2 /s exhibits an OECD 301D biodegrability of about 30%.
• the hydraulic fluid composition containing an isomerized base oil having having a kinematic viscosity at 4O 0 C. of ⁇ 40 mm 2 /s shows an OECD 301D biodegrability of about 40%.
• a hydraulic fluid composition with a base oil matrix having a kinematic viscosity at 4O 0 C. of ⁇ 11 mm 2 /s shows an OECD 30 ID biodegrability of about 80%.
• a hydraulic fluid composition with a base oil matrix having a kinematic viscosity at 4O 0 C. of ⁇ 6 mm 2 /s shows an OECD 301D biodegrability of > 93%.
• the hydraulic fluid composition has a RPVOT as measured according to ASTM D2272-02 of greater than 600 minutes. In another embodiment, the RPVOT is greater than 1000 minutes. In a third embodiment, the hydraulic fluid composition has a cold crank viscosity of 4,000 to 50,000 cP at -30 0 C and 1 ,000 to 25,000 cp at -25 0 C. In yet another embodiment, the hydraulic fluid composition has a kinematic viscosity at 4O 0 C. from 10 to 800 mm 2 /s.
• the composition is used in hydraulic pumps.
• the performance of pumps and motors is a critical factor in overall hydraulic system reliability.
• An important role of a hydraulic pump is to transmit energy from electrical or mechanical energy into hydraulic energy, e.g. volumetric flow and pressure.
• the hydraulic fluid composition is supplied to the fluid reservoir of the equipment to be lubricated, and thence to the moving parts of the equipment itself including but not limited to mobile as well as non-mobile equipment including but not limited to turbines, tractors, vehicles and off-highway mobile equipment.
• Moving parts include a transmission, a hydrostatic transmission, a gear box, a drive, a hydraulic system, etc.
• EXAMPLES were prepared by mixing the components in the amounts indicated Table 1. The formulae were subject to the piston pump test according to JCMAS HK standard specifications developed by the Fuels and Lubricants Technical Committee of Japan Construction Mechanization Association (JCMA).
• JCMA Fuels and Lubricants Technical Committee of Japan Construction Mechanization Association
• FTBO base oils are from Chevron Corporation of San Ramon, CA. The properties of the FTBO base oils used in the examples are shown in Table 4. [099] NexbaseTM 3060 is a colorless, catalytically hydroisomerized and dewaxed
• Group III base oil from Neste Oil Corporation.
• PennzoilTM HC 575 is a Group II mineral oil from Pennzoil-Quaker State Company.
• Additive 1 is a commercially available rust and oxidation package.
• Additive 2 is a triaryl phosphate ashless antiwear and extreme pressure additive.
• Additive 3 is an amine phosphate an ashless multifunctional additive with extreme pressure / antiwear and antirust activity, typically containing 4.9% phosphorus and 2.7% nitrogen.
• Additive 4 is a tolutriazole derivative metal deactivator.
• Additive 5 is a commercially available sorbitan monooleate.
• Additive 6 is a polyalkyl methacrylate (Cl 1-C20).
• Additive 7 is a low molecular weight organic acrylic polymer.
• Figure 1 compares the change in the fluid kinematic viscosity at 4O 0 C. over time (test periods of 0 - 1000 hours), between Formula A which contains the base oils Group II / III of the prior art, and Formula B which is an embodiment of the hydraulic fluid of the invention.
• Figure 2 compares the change in the total acid number over time between Formulae A and B.
• Formula B shows excellent stability with minor changes / variations in the fluid viscosity at 4O 0 C. and in the total acid number as a function of time as compared in the more dramatic variations in the formulation of the prior art.
• Table 1 compares the change in the fluid kinematic viscosity at 4O 0 C. over time (test periods of 0 - 1000 hours), between Formula A which contains the base oils Group II / III of the prior art, and Formula B which is an embodiment of the hydraulic fluid of the invention.
• Figure 2 compares the change in the total acid number over time between Formulae A and B.
• Formula B shows excellent stability with minor changes / variations

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