WO2009028446A1 - 液晶組成物および液晶表示素子 - Google Patents
液晶組成物および液晶表示素子 Download PDFInfo
- Publication number
- WO2009028446A1 WO2009028446A1 PCT/JP2008/065088 JP2008065088W WO2009028446A1 WO 2009028446 A1 WO2009028446 A1 WO 2009028446A1 JP 2008065088 W JP2008065088 W JP 2008065088W WO 2009028446 A1 WO2009028446 A1 WO 2009028446A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- liquid crystal
- nematic phase
- crystal composition
- display element
- composition
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K19/3066—Cyclohexane rings in which the rings are linked by a chain containing carbon and oxygen atoms, e.g. esters or ethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/42—Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
- C09K2019/0466—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the linking chain being a -CF2O- chain
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
- C09K2019/0474—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the linking chain being a -CHFO- chain
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
- C09K19/12—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings at least two benzene rings directly linked, e.g. biphenyls
- C09K2019/121—Compounds containing phenylene-1,4-diyl (-Ph-)
- C09K2019/123—Ph-Ph-Ph
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K19/3003—Compounds containing at least two rings in which the different rings are directly linked (covalent bond)
- C09K2019/3004—Cy-Cy
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K19/3003—Compounds containing at least two rings in which the different rings are directly linked (covalent bond)
- C09K2019/3009—Cy-Ph
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K19/3003—Compounds containing at least two rings in which the different rings are directly linked (covalent bond)
- C09K2019/301—Cy-Cy-Ph
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K19/3003—Compounds containing at least two rings in which the different rings are directly linked (covalent bond)
- C09K2019/3016—Cy-Ph-Ph
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
- C09K19/06—Non-steroidal liquid crystal compounds
- C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
- C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
- C09K19/3001—Cyclohexane rings
- C09K19/3003—Compounds containing at least two rings in which the different rings are directly linked (covalent bond)
- C09K2019/3019—Cy-Cy-Ph-Ph
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K19/00—Liquid crystal materials
- C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
- C09K19/54—Additives having no specific mesophase characterised by their chemical composition
- C09K19/542—Macromolecular compounds
- C09K2019/548—Macromolecular compounds stabilizing the alignment; Polymer stabilized alignment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/03—Viewing layer characterised by chemical composition
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Liquid Crystal Substances (AREA)
Abstract
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/672,411 US8454856B2 (en) | 2007-08-29 | 2008-08-25 | Liquid crystal composition and liquid crystal display device |
KR1020107003335A KR101503949B1 (ko) | 2007-08-29 | 2008-08-25 | 액정 조성물 및 액정 표시 소자 |
EP08792696.0A EP2182043B1 (en) | 2007-08-29 | 2008-08-25 | Liquid crystal composition and liquid crystal display device |
CN2008801012598A CN101790575B (zh) | 2007-08-29 | 2008-08-25 | 液晶组成物以及液晶显示元件 |
JP2009530101A JP5321462B2 (ja) | 2007-08-29 | 2008-08-25 | 液晶組成物および液晶表示素子 |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007222350 | 2007-08-29 | ||
JP2007-222350 | 2007-08-29 | ||
JP2008116653 | 2008-04-28 | ||
JP2008-116653 | 2008-04-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009028446A1 true WO2009028446A1 (ja) | 2009-03-05 |
Family
ID=40387166
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2008/065088 WO2009028446A1 (ja) | 2007-08-29 | 2008-08-25 | 液晶組成物および液晶表示素子 |
Country Status (7)
Country | Link |
---|---|
US (1) | US8454856B2 (ja) |
EP (1) | EP2182043B1 (ja) |
JP (1) | JP5321462B2 (ja) |
KR (1) | KR101503949B1 (ja) |
CN (1) | CN101790575B (ja) |
TW (1) | TWI488945B (ja) |
WO (1) | WO2009028446A1 (ja) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011065299A1 (ja) * | 2009-11-27 | 2011-06-03 | Jnc株式会社 | 液晶表示素子 |
JP5565530B1 (ja) * | 2013-03-04 | 2014-08-06 | Dic株式会社 | 液晶組成物及びこれを用いた液晶表示素子 |
WO2015072249A1 (ja) * | 2013-11-18 | 2015-05-21 | Jnc株式会社 | 液晶組成物および液晶表示素子 |
JP2018523736A (ja) * | 2015-08-05 | 2018-08-23 | メルク・パテント・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツングMerck Patent GmbH | 液晶媒体 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102226090B (zh) * | 2011-04-19 | 2013-06-19 | 西安瑞联近代电子材料有限责任公司 | 液晶组合物 |
JP5729149B2 (ja) * | 2011-06-08 | 2015-06-03 | Jnc株式会社 | 液晶組成物および液晶表示素子 |
CN102994098B (zh) * | 2012-05-03 | 2014-12-24 | 石家庄诚志永华显示材料有限公司 | Tft液晶组合物及其制备方法与应用 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3660505A (en) | 1969-08-27 | 1972-05-02 | Exxon Research Engineering Co | Hindered alkenyl phenols from quinone methide |
DE4006921A1 (de) | 1989-03-18 | 1990-09-20 | Merck Patent Gmbh | Difluormethylenverbindungen |
WO1996011897A1 (fr) | 1994-10-13 | 1996-04-25 | Chisso Corporation | Derive difluoroxymethane et composition a cristaux liquides |
JPH10251186A (ja) | 1997-03-10 | 1998-09-22 | Chisso Corp | ハロゲン置換ベンゼン誘導体、液晶組成物および液晶表示素子 |
JP2003176251A (ja) | 2001-09-29 | 2003-06-24 | Merck Patent Gmbh | 液晶化合物 |
WO2006061094A1 (en) * | 2004-12-11 | 2006-06-15 | Merck Patent Gmbh | Liquid crystal compounds, liquid crystal medium and liquid crystal display |
JP2007503487A (ja) * | 2003-08-25 | 2007-02-22 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | メソゲン性化合物、電気光学ディスプレイ用媒体および電気光学ディスプレイ |
JP2007503485A (ja) * | 2003-08-25 | 2007-02-22 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 液晶媒体 |
JP4030382B2 (ja) | 2002-08-19 | 2008-01-09 | 独立行政法人科学技術振興機構 | 高効率な有機発光性化合物 |
WO2008105286A1 (ja) * | 2007-02-28 | 2008-09-04 | Chisso Corporation | Cf2o結合基を有する5環液晶化合物、液晶組成物および液晶表示素子 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2696557B2 (ja) | 1989-03-07 | 1998-01-14 | チッソ株式会社 | トリフルオロベンゼン誘導体 |
JPH0430382A (ja) | 1990-05-24 | 1992-02-03 | Mazda Motor Corp | 車両用音響装置 |
JP2001003051A (ja) * | 1999-04-19 | 2001-01-09 | Chisso Corp | 液晶組成物および液晶表示素子 |
JP4534287B2 (ja) * | 1999-04-19 | 2010-09-01 | チッソ株式会社 | 液晶組成物および液晶表示素子 |
US8129002B2 (en) | 2003-08-25 | 2012-03-06 | Merck Patent Gmbh | Compounds for use in liquid crystal media |
JP2009292729A (ja) * | 2007-02-28 | 2009-12-17 | Chisso Corp | Cf2o結合基を有する5環液晶化合物、液晶組成物および液晶表示素子 |
US8153021B2 (en) * | 2007-08-31 | 2012-04-10 | Jnc Corporation | Liquid crystal composition and liquid crystal display device |
-
2008
- 2008-08-25 JP JP2009530101A patent/JP5321462B2/ja not_active Expired - Fee Related
- 2008-08-25 US US12/672,411 patent/US8454856B2/en not_active Expired - Fee Related
- 2008-08-25 CN CN2008801012598A patent/CN101790575B/zh not_active Expired - Fee Related
- 2008-08-25 EP EP08792696.0A patent/EP2182043B1/en not_active Not-in-force
- 2008-08-25 WO PCT/JP2008/065088 patent/WO2009028446A1/ja active Application Filing
- 2008-08-25 KR KR1020107003335A patent/KR101503949B1/ko not_active IP Right Cessation
- 2008-08-27 TW TW097132773A patent/TWI488945B/zh not_active IP Right Cessation
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3660505A (en) | 1969-08-27 | 1972-05-02 | Exxon Research Engineering Co | Hindered alkenyl phenols from quinone methide |
DE4006921A1 (de) | 1989-03-18 | 1990-09-20 | Merck Patent Gmbh | Difluormethylenverbindungen |
WO1996011897A1 (fr) | 1994-10-13 | 1996-04-25 | Chisso Corporation | Derive difluoroxymethane et composition a cristaux liquides |
JPH10251186A (ja) | 1997-03-10 | 1998-09-22 | Chisso Corp | ハロゲン置換ベンゼン誘導体、液晶組成物および液晶表示素子 |
JP2003176251A (ja) | 2001-09-29 | 2003-06-24 | Merck Patent Gmbh | 液晶化合物 |
JP4030382B2 (ja) | 2002-08-19 | 2008-01-09 | 独立行政法人科学技術振興機構 | 高効率な有機発光性化合物 |
JP2007503487A (ja) * | 2003-08-25 | 2007-02-22 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | メソゲン性化合物、電気光学ディスプレイ用媒体および電気光学ディスプレイ |
JP2007503485A (ja) * | 2003-08-25 | 2007-02-22 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 液晶媒体 |
WO2006061094A1 (en) * | 2004-12-11 | 2006-06-15 | Merck Patent Gmbh | Liquid crystal compounds, liquid crystal medium and liquid crystal display |
WO2008105286A1 (ja) * | 2007-02-28 | 2008-09-04 | Chisso Corporation | Cf2o結合基を有する5環液晶化合物、液晶組成物および液晶表示素子 |
Non-Patent Citations (2)
Title |
---|
M. IMAI ET AL., MOLECULAR CRYSTALS AND LIQUID CRYSTALS, vol. 259, 1995, pages 37 |
See also references of EP2182043A4 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011065299A1 (ja) * | 2009-11-27 | 2011-06-03 | Jnc株式会社 | 液晶表示素子 |
CN102712844A (zh) * | 2009-11-27 | 2012-10-03 | 捷恩智株式会社 | 液晶显示元件 |
US9005479B2 (en) | 2009-11-27 | 2015-04-14 | Jnc Corporation | Liquid crystal display device |
JP5765231B2 (ja) * | 2009-11-27 | 2015-08-19 | Jnc株式会社 | 液晶表示素子 |
CN105038811A (zh) * | 2009-11-27 | 2015-11-11 | 捷恩智株式会社 | 液晶组成物及液晶显示元件 |
KR101795820B1 (ko) * | 2009-11-27 | 2017-11-08 | 제이엔씨 주식회사 | 액정 표시 소자 |
JP5565530B1 (ja) * | 2013-03-04 | 2014-08-06 | Dic株式会社 | 液晶組成物及びこれを用いた液晶表示素子 |
WO2015072249A1 (ja) * | 2013-11-18 | 2015-05-21 | Jnc株式会社 | 液晶組成物および液晶表示素子 |
JPWO2015072249A1 (ja) * | 2013-11-18 | 2017-03-16 | Jnc株式会社 | 液晶組成物および液晶表示素子 |
US10294424B2 (en) | 2013-11-18 | 2019-05-21 | Jnc Corporation | Liquid crystal composition and liquid crystal display device |
JP2018523736A (ja) * | 2015-08-05 | 2018-08-23 | メルク・パテント・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツングMerck Patent GmbH | 液晶媒体 |
Also Published As
Publication number | Publication date |
---|---|
TW200918647A (en) | 2009-05-01 |
JPWO2009028446A1 (ja) | 2010-12-02 |
KR101503949B1 (ko) | 2015-03-18 |
CN101790575B (zh) | 2013-01-23 |
CN101790575A (zh) | 2010-07-28 |
EP2182043A4 (en) | 2013-05-08 |
JP5321462B2 (ja) | 2013-10-23 |
TWI488945B (zh) | 2015-06-21 |
EP2182043A1 (en) | 2010-05-05 |
EP2182043B1 (en) | 2016-05-11 |
US8454856B2 (en) | 2013-06-04 |
US20110116031A1 (en) | 2011-05-19 |
KR20100057808A (ko) | 2010-06-01 |
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