WO2009008514A1 - 撥水撥油剤組成物の製造方法および物品 - Google Patents

撥水撥油剤組成物の製造方法および物品 Download PDF

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Publication number
WO2009008514A1
WO2009008514A1 PCT/JP2008/062624 JP2008062624W WO2009008514A1 WO 2009008514 A1 WO2009008514 A1 WO 2009008514A1 JP 2008062624 W JP2008062624 W JP 2008062624W WO 2009008514 A1 WO2009008514 A1 WO 2009008514A1
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WO
WIPO (PCT)
Prior art keywords
oil
water
repellency
article
repellent
Prior art date
Application number
PCT/JP2008/062624
Other languages
English (en)
French (fr)
Inventor
Takao Hirono
Kazunori Sugiyama
Yuichi Ohmori
Minako Shimada
Original Assignee
Asahi Glass Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Glass Company, Limited filed Critical Asahi Glass Company, Limited
Priority to CN200880024291A priority Critical patent/CN101688106A/zh
Priority to JP2009522690A priority patent/JPWO2009008514A1/ja
Priority to EP08791105A priority patent/EP2172530B1/en
Publication of WO2009008514A1 publication Critical patent/WO2009008514A1/ja
Priority to US12/652,785 priority patent/US20100113665A1/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C08F220/24—Esters containing halogen containing perhaloalkyl radicals
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3566—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02—Monomers containing chlorine
    • C08F214/04—Monomers containing two carbon atoms
    • C08F214/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1818—C13or longer chain (meth)acrylate, e.g. stearyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/34—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate
    • C08F220/36—Esters containing nitrogen, e.g. N,N-dimethylaminoethyl (meth)acrylate containing oxygen in addition to the carboxy oxygen, e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

Abstract

　物品の表面に撥水撥油性を付与でき、かつ耐久性（洗濯耐久性および豪雨耐久性）に優れる撥水撥油剤組成物の製造方法および撥水撥油性を有し、かつ洗濯および豪雨による撥水撥油性の低下が少ない物品を提供する。 　界面活性剤および重合開始剤の存在下、媒体中にて単量体（ａ）を含む単量体成分を化合物（ｘ）の共存下に重合する撥水撥油剤組成物の製造方法。単量体（ａ）：（Ｚ－Ｙ）ｎＸで表される化合物。ただし、Ｚは炭素数が１～２０のポリフルオロアルキル基等、Ｙは２価有機基または単結合、ｎは１または２、Ｘは重合性不飽和基である。化合物（ｘ）：Ｒｆ１－（ＣＨ２）ｂ－Ｑ－（ＣＨ２）ａ－ＳＨで表される化合物。ただし、Ｒｆ１は炭素数が１～３０のポリフルオロアルキル基、Ｑは２価有機基または単結合、ａは１～２０の整数、ｂは０～２０の整数である。
PCT/JP2008/062624 2007-07-11 2008-07-11 撥水撥油剤組成物の製造方法および物品 WO2009008514A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN200880024291A CN101688106A (zh) 2007-07-11 2008-07-11 斥水斥油剂组合物的制造方法及物品
JP2009522690A JPWO2009008514A1 (ja) 2007-07-11 2008-07-11 撥水撥油剤組成物の製造方法および物品
EP08791105A EP2172530B1 (en) 2007-07-11 2008-07-11 Method for production of water-repellent and oil-repellant composition, and article
US12/652,785 US20100113665A1 (en) 2007-07-11 2010-01-06 Method for production of water/oil repellent composition and article

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007182398 2007-07-11
JP2007-182398 2007-07-11

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/652,785 Continuation US20100113665A1 (en) 2007-07-11 2010-01-06 Method for production of water/oil repellent composition and article

Publications (1)

Publication Number Publication Date
WO2009008514A1 true WO2009008514A1 (ja) 2009-01-15

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PCT/JP2008/062624 WO2009008514A1 (ja) 2007-07-11 2008-07-11 撥水撥油剤組成物の製造方法および物品

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Country Link
US (1) US20100113665A1 (ja)
EP (1) EP2172530B1 (ja)
JP (1) JPWO2009008514A1 (ja)
KR (1) KR20100031524A (ja)
CN (1) CN101688106A (ja)
TW (1) TW200920751A (ja)
WO (1) WO2009008514A1 (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012014850A1 (ja) * 2010-07-30 2012-02-02 日華化学株式会社 撥水撥油剤組成物、機能性繊維製品及び機能性繊維製品の製造方法
CN102666773A (zh) * 2009-12-25 2012-09-12 旭硝子株式会社 拒水拒油剂组合物、其制造方法及物品的处理方法
WO2013099611A1 (ja) * 2011-12-28 2013-07-04 ダイキン工業株式会社 含フッ素組成物および含フッ素重合体
JP7464882B2 (ja) 2020-07-30 2024-04-10 ダイキン工業株式会社 含フッ素エラストマー水性分散液の製造方法、含フッ素エラストマーおよび水性分散液

Families Citing this family (5)

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JP5678660B2 (ja) * 2008-06-04 2015-03-04 旭硝子株式会社 共重合体、その製造方法および撥水撥油剤組成物
CN103080267A (zh) * 2010-08-11 2013-05-01 旭硝子株式会社 拒水拒油剂组合物和物品
WO2014021277A1 (ja) 2012-08-01 2014-02-06 旭硝子株式会社 撥水撥油剤組成物および物品
EP3444314B1 (en) * 2016-04-15 2021-03-31 Agc Inc. Water-repellent composition and process for producing moisture permeable waterproof film coated article
CN110042661B (zh) * 2019-03-22 2021-11-12 东莞东阳光科研发有限公司 整理剂组合物、整理剂及其制备方法和应用

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JPH10212305A (ja) * 1997-01-31 1998-08-11 Asahi Glass Co Ltd 重合体の製造方法、合成樹脂添加剤、および樹脂組成物
JP2002088105A (ja) * 2000-09-14 2002-03-27 Nippon Mektron Ltd 含フッ素共重合体の製造方法
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JPH10212305A (ja) * 1997-01-31 1998-08-11 Asahi Glass Co Ltd 重合体の製造方法、合成樹脂添加剤、および樹脂組成物
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102666773A (zh) * 2009-12-25 2012-09-12 旭硝子株式会社 拒水拒油剂组合物、其制造方法及物品的处理方法
WO2012014850A1 (ja) * 2010-07-30 2012-02-02 日華化学株式会社 撥水撥油剤組成物、機能性繊維製品及び機能性繊維製品の製造方法
CN103038306A (zh) * 2010-07-30 2013-04-10 日华化学株式会社 抗水抗油剂组合物、功能性纤维制品及功能性纤维制品的制造方法
WO2013099611A1 (ja) * 2011-12-28 2013-07-04 ダイキン工業株式会社 含フッ素組成物および含フッ素重合体
JP2013151651A (ja) * 2011-12-28 2013-08-08 Daikin Industries Ltd 含フッ素組成物および含フッ素重合体
KR101507698B1 (ko) 2011-12-28 2015-03-31 다이킨 고교 가부시키가이샤 불소 함유 조성물 및 불소 함유 중합체
US10640594B2 (en) 2011-12-28 2020-05-05 Daikin Industries, Ltd. Fluorine-containing composition and fluorine-containing polymer
JP7464882B2 (ja) 2020-07-30 2024-04-10 ダイキン工業株式会社 含フッ素エラストマー水性分散液の製造方法、含フッ素エラストマーおよび水性分散液

Also Published As

Publication number Publication date
CN101688106A (zh) 2010-03-31
EP2172530A4 (en) 2010-08-04
EP2172530A1 (en) 2010-04-07
US20100113665A1 (en) 2010-05-06
JPWO2009008514A1 (ja) 2010-09-09
TW200920751A (en) 2009-05-16
KR20100031524A (ko) 2010-03-22
EP2172530B1 (en) 2013-03-27

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