WO2008137583A3 - Catalyseur, sa préparation et son utilisation - Google Patents

Catalyseur, sa préparation et son utilisation Download PDF

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Publication number
WO2008137583A3
WO2008137583A3 PCT/US2008/062278 US2008062278W WO2008137583A3 WO 2008137583 A3 WO2008137583 A3 WO 2008137583A3 US 2008062278 W US2008062278 W US 2008062278W WO 2008137583 A3 WO2008137583 A3 WO 2008137583A3
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WO
WIPO (PCT)
Prior art keywords
compound
catalyst
preparation
silver
mixture
Prior art date
Application number
PCT/US2008/062278
Other languages
English (en)
Other versions
WO2008137583A2 (fr
Inventor
Ruth Mary Kowaleski
Original Assignee
Shell Oil Company
Shell Internationale Research Maatschappij B.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Oil Company, Shell Internationale Research Maatschappij B.V. filed Critical Shell Oil Company
Priority to EP08747393A priority Critical patent/EP2152412A2/fr
Priority to BRPI0810802-1A2A priority patent/BRPI0810802A2/pt
Priority to CA002685692A priority patent/CA2685692A1/fr
Priority to CN200880017659A priority patent/CN101678334A/zh
Priority to JP2010506648A priority patent/JP5313233B2/ja
Publication of WO2008137583A2 publication Critical patent/WO2008137583A2/fr
Publication of WO2008137583A3 publication Critical patent/WO2008137583A3/fr

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/745Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8946Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali or alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04Mixing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333Catalytic processes
    • C07C5/3332Catalytic processes with metal oxides or metal sulfides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/894Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04Alkali metals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/28Molybdenum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/48Silver or gold
    • C07C2523/50Silver
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74Iron group metals
    • C07C2523/745Iron
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with noble metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un catalyseur de déshydrogénation composé d'un oxyde de fer, d'un métal alcalin ou d'un de ses composés, et d'argent ou d'un de ses composés. Elle concerne également un procédé servant à préparer un catalyseur de déshydrogénation et consistant à préparer un mélange d'oxyde de fer, d'un métal alcalin ou d'un de ses composés, et d'argent ou d'un de ses composés, puis à effectuer la calcination de ce mélange. Elle concerne également un procédé servant à déshydrogéner un hydrocarbure pouvant être déshydrogéné et un procédé servant à polymériser cet hydrocarbure déshydrogéné.
PCT/US2008/062278 2007-05-03 2008-05-01 Catalyseur, sa préparation et son utilisation WO2008137583A2 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP08747393A EP2152412A2 (fr) 2007-05-03 2008-05-01 Catalyseur, sa préparation et son utilisation
BRPI0810802-1A2A BRPI0810802A2 (pt) 2007-05-03 2008-05-01 Catalisador de desidrogenação, e, processos para preparar o mesmo, e para desidrogenar um hidrocarboneto desidrogenável
CA002685692A CA2685692A1 (fr) 2007-05-03 2008-05-01 Catalyseur, sa preparation et son utilisation
CN200880017659A CN101678334A (zh) 2007-05-03 2008-05-01 催化剂及其制备和用途
JP2010506648A JP5313233B2 (ja) 2007-05-03 2008-05-01 触媒、それの調製および使用

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US91585307P 2007-05-03 2007-05-03
US60/915,853 2007-05-03

Publications (2)

Publication Number Publication Date
WO2008137583A2 WO2008137583A2 (fr) 2008-11-13
WO2008137583A3 true WO2008137583A3 (fr) 2009-11-05

Family

ID=39650470

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2008/062278 WO2008137583A2 (fr) 2007-05-03 2008-05-01 Catalyseur, sa préparation et son utilisation

Country Status (11)

Country Link
US (1) US8119559B2 (fr)
EP (1) EP2152412A2 (fr)
JP (3) JP5313233B2 (fr)
KR (1) KR20100017489A (fr)
CN (2) CN101678334A (fr)
AR (1) AR066417A1 (fr)
BR (1) BRPI0810802A2 (fr)
CA (1) CA2685692A1 (fr)
RU (1) RU2009144774A (fr)
TW (1) TW200911365A (fr)
WO (1) WO2008137583A2 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
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RU2009144770A (ru) * 2007-05-03 2011-06-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Катализатор, его получение и применение
KR20100017489A (ko) * 2007-05-03 2010-02-16 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 촉매, 이의 제조 및 용도
RU2458737C9 (ru) * 2011-07-13 2012-10-27 Открытое акционерное общество "Нижнекамскнефтехим" Катализатор дегидрирования изоамиленов
US9902667B2 (en) * 2012-12-19 2018-02-27 Technip Process Technology, Inc. Method for reducing energy consumption in a process to purify styrene monomer
CN105709738B (zh) * 2014-12-02 2018-06-19 中国石油化工股份有限公司 利用含铁废渣原料制备铁基加氢催化剂的方法
CN105709739B (zh) * 2014-12-02 2018-06-15 中国石油化工股份有限公司 一种铁基加氢催化剂的制备方法
WO2017099161A1 (fr) * 2015-12-11 2017-06-15 クラリアント触媒株式会社 Catalyseur de déshydrogénation pour composé alkylaromatique, son procédé de production, et procédé de déshydrogénation l'utilisant
CN106000413B (zh) * 2016-06-15 2018-07-27 河南大学 一种钼掺杂正方针铁矿纳米微粒的制备方法
FR3063917B1 (fr) * 2017-03-16 2022-04-01 Commissariat Energie Atomique Catalyseur pour reaction de gaz a l'eau inverse (rwgs), reaction rwgs associee et procede de regeneration in-situ du catalyseur
KR102436310B1 (ko) 2018-11-19 2022-08-25 주식회사 엘지화학 산화적 탈수소화 반응용 촉매 및 이의 제조방법
CN113880684B (zh) * 2020-07-01 2023-10-31 中国石油化工股份有限公司 混合二乙烯基苯及其生产方法

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KR20100017489A (ko) * 2007-05-03 2010-02-16 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 촉매, 이의 제조 및 용도

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Publication number Priority date Publication date Assignee Title
US2442131A (en) * 1943-03-13 1948-05-25 Standard Oil Dev Co Dehydrogenation catalysts
US3872027A (en) * 1970-02-13 1975-03-18 Petro Tex Chem Corp Oxidative dehydrogenation catalysts and their method of preparation
US3907916A (en) * 1974-01-14 1975-09-23 Dow Chemical Co Dehydrogenation of alkyl aromatic hydrocarbons
US5023225A (en) * 1989-07-21 1991-06-11 United Catalysts Inc. Dehydrogenation catalyst and process for its preparation
US5668075A (en) * 1994-12-14 1997-09-16 Shell Oil Company Restructured iron oxide for use in iron oxide catalysts
US5840648A (en) * 1997-09-02 1998-11-24 The Standard Oil Company Catalyst for the manufacture of acrylonitrile and hydrogen cyanide
EP1027928A1 (fr) * 1999-02-10 2000-08-16 Basf Aktiengesellschaft Catalyseur pour la déshydrogénation d'éthylbenzène en styrène
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EP2152412A2 (fr) 2010-02-17
KR20100017489A (ko) 2010-02-16
JP2013240789A (ja) 2013-12-05
TW200911365A (en) 2009-03-16
WO2008137583A2 (fr) 2008-11-13
US20090062588A1 (en) 2009-03-05
BRPI0810802A2 (pt) 2014-10-29
JP5313233B2 (ja) 2013-10-09
JP2010525941A (ja) 2010-07-29
AR066417A1 (es) 2009-08-19
CN105032448A (zh) 2015-11-11
CN101678334A (zh) 2010-03-24
JP2016117057A (ja) 2016-06-30

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