WO2008114864A1 - 鉄錯体及び該鉄錯体を触媒とする重合体の製造方法 - Google Patents

鉄錯体及び該鉄錯体を触媒とする重合体の製造方法 Download PDF

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Publication number
WO2008114864A1
WO2008114864A1 PCT/JP2008/055257 JP2008055257W WO2008114864A1 WO 2008114864 A1 WO2008114864 A1 WO 2008114864A1 JP 2008055257 W JP2008055257 W JP 2008055257W WO 2008114864 A1 WO2008114864 A1 WO 2008114864A1
Authority
WO
WIPO (PCT)
Prior art keywords
iron complex
formula
catalyst
divalent
producing polymer
Prior art date
Application number
PCT/JP2008/055257
Other languages
English (en)
French (fr)
Inventor
Hideo Nagashima
Yusuke Sunada
Masataka Watanabe
Daisuke Noda
Mitsunobu Kawamura
Hidetomo Kai
Akane Hamada
Hitoshi Hayakawa
Nobuyuki Koike
Original Assignee
Kyushu University, National University Corporation
Dic Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kyushu University, National University Corporation, Dic Corporation filed Critical Kyushu University, National University Corporation
Priority to JP2008541524A priority Critical patent/JP4344779B2/ja
Publication of WO2008114864A1 publication Critical patent/WO2008114864A1/ja

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D255/00—Heterocyclic compounds containing rings having three nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D249/00 - C07D253/00
    • C07D255/02—Heterocyclic compounds containing rings having three nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D249/00 - C07D253/00 not condensed with other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Abstract

　下記一般式（１）で表される鉄化合物に対して下記一般式（２）で表される環状アミン化合物が配位してなる２価鉄錯体、及びこれを用い重合体の製造方法。ＦｅＸ１ ２ •••（１） （式（１）中、Ｆｅは２価であり、Ｘ１はアニオン性官能基を示す。） （式（２）中、Ｒ１、Ｒ２及びＲ３は、水素原子、炭素数１～２０の炭化水素基、又は芳香環上に炭素数１～４０の置換基を有していてもよいベンジル基を示す。ただし、Ｒ１、Ｒ２及びＲ３のすべてがメチル基である場合を除く。）
PCT/JP2008/055257 2007-03-20 2008-03-21 鉄錯体及び該鉄錯体を触媒とする重合体の製造方法 WO2008114864A1 (ja)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2008541524A JP4344779B2 (ja) 2007-03-20 2008-03-21 鉄錯体及び該鉄錯体を触媒とする重合体の製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007073657 2007-03-20
JP2007-073657 2007-03-20

Publications (1)

Publication Number Publication Date
WO2008114864A1 true WO2008114864A1 (ja) 2008-09-25

Family

ID=39765964

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/055257 WO2008114864A1 (ja) 2007-03-20 2008-03-21 鉄錯体及び該鉄錯体を触媒とする重合体の製造方法

Country Status (2)

Country Link
JP (1) JP4344779B2 (ja)
WO (1) WO2008114864A1 (ja)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013521087A (ja) * 2010-03-10 2013-06-10 ユニヴェルシテ・クロード・ベルナール・リヨン・プルミエ 放射線不透過性、非生分解性、水不溶性の、ポリ（ビニルアルコール）のヨウ素化ベンジルエーテル、その製造方法、それを含む注射可能な塞栓組成物、およびその使用方法
WO2020008204A1 (en) * 2018-07-05 2020-01-09 Catexel Limited Oxidatively curable coating composition

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002540234A (ja) * 1999-03-23 2002-11-26 カーネギー−メロン ユニバーシティ フリーラジカル的に（共）重合可能なモノマーの制御された重合のための触媒法、およびそれによって製造される官能性高分子系
WO2007032358A1 (ja) * 2005-09-14 2007-03-22 Kyushu University, National University Corporation 鉄錯体を触媒とする重合体の製造方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002540234A (ja) * 1999-03-23 2002-11-26 カーネギー−メロン ユニバーシティ フリーラジカル的に（共）重合可能なモノマーの制御された重合のための触媒法、およびそれによって製造される官能性高分子系
WO2007032358A1 (ja) * 2005-09-14 2007-03-22 Kyushu University, National University Corporation 鉄錯体を触媒とする重合体の製造方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DIEBOLD A. ET AL.: "Crystal Structures and Solution Behavior of Paramagnetic Divalent Transition Metal Complexes (Fe, Co) of the Sterically Encumbered Tridentate Macrocycles 1,4,7-R3-1,4,7-Triazacyclononane: Coordination Numbers 5 (R = i-Pr) and 6 (R = i-Bu)", INORGANIC CHEMISTRY, vol. 39, no. 17, 2000, pages 3915 - 3923, XP000940575 *
LIN G. ET AL.: "Extradiol Oxidative Cleavage of Catechols by Ferrous and Ferric Complexes of 1,4,7-Tetrazacyclononane: Insight into the Mechanism of the Extradiol Catechol Dioxygenases", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 123, no. 21, 2001, pages 5030 - 5039 *
NIIBAYASHI S. ET AL.: "Reusable and environmentally friendly ionic trinuclear iron complex catalysts for atom transfer radical polymerization", CHEMICAL COMMUNICATIONS, no. 18, 14 May 2007 (2007-05-14), pages 1855 - 1857 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013521087A (ja) * 2010-03-10 2013-06-10 ユニヴェルシテ・クロード・ベルナール・リヨン・プルミエ 放射線不透過性、非生分解性、水不溶性の、ポリ（ビニルアルコール）のヨウ素化ベンジルエーテル、その製造方法、それを含む注射可能な塞栓組成物、およびその使用方法
WO2020008204A1 (en) * 2018-07-05 2020-01-09 Catexel Limited Oxidatively curable coating composition

Also Published As

Publication number Publication date
JP4344779B2 (ja) 2009-10-14
JPWO2008114864A1 (ja) 2010-07-08

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