WO2008111639A1 - 触媒劣化判定装置 - Google Patents

触媒劣化判定装置 Download PDF

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Publication number
WO2008111639A1
WO2008111639A1 PCT/JP2008/054602 JP2008054602W WO2008111639A1 WO 2008111639 A1 WO2008111639 A1 WO 2008111639A1 JP 2008054602 W JP2008054602 W JP 2008054602W WO 2008111639 A1 WO2008111639 A1 WO 2008111639A1
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WO
WIPO (PCT)
Prior art keywords
catalyst
sensor output
oxygen
ammonia
vnh3
Prior art date
Application number
PCT/JP2008/054602
Other languages
English (en)
French (fr)
Inventor
Kenji Katoh
Kei Masuda
Original Assignee
Toyota Jidosha Kabushiki Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyota Jidosha Kabushiki Kaisha filed Critical Toyota Jidosha Kabushiki Kaisha
Priority to CN2008800013979A priority Critical patent/CN101578434B/zh
Priority to EP08722006.7A priority patent/EP2136046B1/en
Priority to US12/517,430 priority patent/US8033168B2/en
Publication of WO2008111639A1 publication Critical patent/WO2008111639A1/ja

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Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0814—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N11/00—Monitoring or diagnostic devices for exhaust-gas treatment apparatus, e.g. for catalytic activity
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
    • F01N3/0828—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
    • F01N3/0842—Nitrogen oxides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
    • F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
    • F01N3/2066—Selective catalytic reduction [SCR]
    • F01N3/208—Control of selective catalytic reduction [SCR], e.g. dosing of reducing agent
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2550/00—Monitoring or diagnosing the deterioration of exhaust systems
    • F01N2550/02—Catalytic activity of catalytic converters
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2550/00—Monitoring or diagnosing the deterioration of exhaust systems
    • F01N2550/03—Monitoring or diagnosing the deterioration of exhaust systems of sorbing activity of adsorbents or absorbents
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/02—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor
    • F01N2560/021—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor for measuring or detecting ammonia NH3
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/02—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor
    • F01N2560/025—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being an exhaust gas sensor for measuring or detecting O2, e.g. lambda sensors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2560/00—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics
    • F01N2560/06—Exhaust systems with means for detecting or measuring exhaust gas components or characteristics the means being a temperature sensor
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2570/00—Exhaust treating apparatus eliminating, absorbing or adsorbing specific elements or compounds
    • F01N2570/14—Nitrogen oxides
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2610/00—Adding substances to exhaust gases
    • F01N2610/02—Adding substances to exhaust gases the substance being ammonia or urea
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/40—Engine management systems

Abstract

　排気浄化触媒の下流の酸素濃度を考慮することで、触媒劣化判定を精度良く行うことが可能な触媒劣化判定装置を提供する。触媒活性状態である場合に、ＮＳＲ触媒下流の酸素センサ出力VO2とアンモニアセンサ出力VNH3を読み込む（ステップ１０４）。この読み込まれた酸素センサ出力VO2が基準値α以上であり、かつ、アンモニアセンサ出力VNH3が基準値β以上である場合には、ＮＳＲ触媒において酸素存在下でアンモニアの酸化反応が起こらないと推定される。この場合、ＮＳＲ触媒が劣化していると判定される（ステップ１０８，１１，１１４）。
PCT/JP2008/054602 2007-03-13 2008-03-13 触媒劣化判定装置 WO2008111639A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN2008800013979A CN101578434B (zh) 2007-03-13 2008-03-13 催化剂劣化判定装置
EP08722006.7A EP2136046B1 (en) 2007-03-13 2008-03-13 Device for judging deterioration of catalyst
US12/517,430 US8033168B2 (en) 2007-03-13 2008-03-13 Catalyst deterioration judgment device

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007063353A JP4665923B2 (ja) 2007-03-13 2007-03-13 触媒劣化判定装置
JP2007-063353 2007-03-13

Publications (1)

Publication Number Publication Date
WO2008111639A1 true WO2008111639A1 (ja) 2008-09-18

Family

ID=39759570

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/054602 WO2008111639A1 (ja) 2007-03-13 2008-03-13 触媒劣化判定装置

Country Status (5)

Country Link
US (1) US8033168B2 (ja)
EP (1) EP2136046B1 (ja)
JP (1) JP4665923B2 (ja)
CN (1) CN101578434B (ja)
WO (1) WO2008111639A1 (ja)

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WO2011114501A1 (ja) 2010-03-15 2011-09-22 トヨタ自動車株式会社 内燃機関の排気浄化装置
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CN102859136B (zh) 2010-04-01 2015-04-08 丰田自动车株式会社 内燃机的排气净化装置
CN102859160B (zh) * 2010-04-23 2015-09-09 丰田自动车株式会社 催化剂异常诊断装置
BRPI1013977B1 (pt) 2010-07-28 2020-08-18 Toyota Jidosha Kabushiki Kaisha sistema de purificação de escapamento de motor de combustão interna
JP5067511B2 (ja) 2010-08-30 2012-11-07 トヨタ自動車株式会社 内燃機関の排気浄化装置
CN103003539B (zh) 2010-08-30 2015-03-18 丰田自动车株式会社 内燃机的排气净化装置
JP5120498B2 (ja) 2010-10-04 2013-01-16 トヨタ自動車株式会社 内燃機関の排気浄化装置
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CN103221648B (zh) 2010-12-06 2016-08-24 丰田自动车株式会社 内燃机的排气净化装置
EP2495410B1 (en) 2010-12-20 2020-02-12 Toyota Jidosha Kabushiki Kaisha Exhaust gas purification method for an internal combustion engine
ES2629430T3 (es) 2010-12-24 2017-08-09 Toyota Jidosha Kabushiki Kaisha Sistema de purificación de gases de escape para motor de combustión interna
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US8707682B2 (en) * 2011-08-25 2014-04-29 Toyota Jidosha Kabushiki Kaisha Exhaust purification system of internal combustion engine
EP2754868B1 (en) * 2011-09-06 2016-12-28 Toyota Jidosha Kabushiki Kaisha Exhaust gas purification apparatus for internal combustion engine
DE102011083775B4 (de) * 2011-09-29 2013-12-05 Continental Automotive Gmbh Verfahren und Vorrichtung zum Betreiben einer Brennkraftmaschine
ES2633727T3 (es) 2011-11-07 2017-09-25 Toyota Jidosha Kabushiki Kaisha Dispositivo de limpieza de gases de escape para motor de combustión interna
US9097157B2 (en) 2011-11-09 2015-08-04 Toyota Jidosha Kabushiki Kaisha Exhaust purification system of internal combustion engine
JP5724839B2 (ja) * 2011-11-16 2015-05-27 トヨタ自動車株式会社 触媒劣化判定システム
US9175590B2 (en) 2011-11-30 2015-11-03 Toyota Jidosha Kabushiki Kaisha Exhaust purification system of internal combustion engine
JP5273304B1 (ja) 2011-11-30 2013-08-28 トヨタ自動車株式会社 内燃機関の排気浄化装置
US8402741B1 (en) * 2012-01-31 2013-03-26 United Technologies Corporation Gas turbine engine shaft bearing configuration
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US9604177B2 (en) * 2012-03-07 2017-03-28 Toyota Jidosha Kabushiki Kaisha Exhaust gas purification apparatus for an internal combustion engine
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Also Published As

Publication number Publication date
CN101578434B (zh) 2011-08-03
EP2136046B1 (en) 2014-08-13
US8033168B2 (en) 2011-10-11
EP2136046A4 (en) 2011-05-11
CN101578434A (zh) 2009-11-11
US20100005873A1 (en) 2010-01-14
EP2136046A1 (en) 2009-12-23
JP4665923B2 (ja) 2011-04-06
JP2008223611A (ja) 2008-09-25

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