WO2008111501A1 - ポルフィセン-シリカハイブリッド化合物 - Google Patents
ポルフィセン-シリカハイブリッド化合物 Download PDFInfo
- Publication number
- WO2008111501A1 WO2008111501A1 PCT/JP2008/054125 JP2008054125W WO2008111501A1 WO 2008111501 A1 WO2008111501 A1 WO 2008111501A1 JP 2008054125 W JP2008054125 W JP 2008054125W WO 2008111501 A1 WO2008111501 A1 WO 2008111501A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- porphycene
- hybrid compound
- carbon atoms
- silica hybrid
- Prior art date
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title abstract 5
- 239000000377 silicon dioxide Substances 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 abstract 2
- HMSMOZAIMDNRBW-UHFFFAOYSA-N 100572-96-1 Chemical class C1=CC2=NC1=CC=C(N1)C=CC1=C(N1)C=CC1=CC=C1C=CC2=N1 HMSMOZAIMDNRBW-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 238000007539 photo-oxidation reaction Methods 0.000 abstract 1
- 229940124530 sulfonamide Drugs 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/29—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of hydroxy groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0254—Nitrogen containing compounds on mineral substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/1616—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
- B01J31/1625—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups
- B01J31/1633—Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts immobilised by covalent linkages, i.e. pendant complexes with optional linking groups covalent linkages via silicon containing groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/08—Silica
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
Abstract
例えば、式(1)で示されるような、1つ以上のポルフィセン化合物が、スルホニルアミド結合などの共有結合でシリカに固定化されてなるポルフィセン-シリカハイブリッド化合物は、高活性な光酸化触媒として用いることができ、かつ、再利用が可能である。 (式中、R1~R12は、それぞれ独立に、水素原子、ハロゲン原子、ニトロ基、シアノ基、スルホニル基、炭素数1~10のアルキル基、炭素数3~6のシクロアルキル基、炭素数1~6のアルコキシ基、フェニル基などを表す。ただし、R1~R12の少なくとも1つはスルホニル基である。)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009504019A JP5381702B2 (ja) | 2007-03-09 | 2008-03-07 | ポルフィセン−シリカハイブリッド化合物 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007059711 | 2007-03-09 | ||
JP2007-059711 | 2007-03-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008111501A1 true WO2008111501A1 (ja) | 2008-09-18 |
Family
ID=39759440
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2008/054125 WO2008111501A1 (ja) | 2007-03-09 | 2008-03-07 | ポルフィセン-シリカハイブリッド化合物 |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP5381702B2 (ja) |
WO (1) | WO2008111501A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010229127A (ja) * | 2009-03-06 | 2010-10-14 | Kyushu Univ | イオン液体類似構造を有するポルフィセン化合物および光酸化触媒 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000505439A (ja) * | 1996-02-19 | 2000-05-09 | シャファー、モシェ | 感光性組成物 |
JP2001039032A (ja) * | 1999-08-02 | 2001-02-13 | Ricoh Co Ltd | 光情報記録媒体 |
JP2001180117A (ja) * | 1999-12-27 | 2001-07-03 | Ricoh Co Ltd | 光情報記録媒体 |
JP2002114923A (ja) * | 2000-10-04 | 2002-04-16 | Hitachi Maxell Ltd | ポルフィセン化合物およびそれを用いた光情報記録媒体 |
JP2002137547A (ja) * | 2000-08-10 | 2002-05-14 | Mitsui Chemicals Inc | 光記録媒体およびポルフィセン化合物 |
JP2003055380A (ja) * | 2001-08-10 | 2003-02-26 | Japan Science & Technology Corp | ポルフィセン金属錯体 |
JP2007269790A (ja) * | 2006-03-09 | 2007-10-18 | Kyushu Univ | モリブデンポルフィセン錯体及び酸化触媒 |
-
2008
- 2008-03-07 JP JP2009504019A patent/JP5381702B2/ja not_active Expired - Fee Related
- 2008-03-07 WO PCT/JP2008/054125 patent/WO2008111501A1/ja active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000505439A (ja) * | 1996-02-19 | 2000-05-09 | シャファー、モシェ | 感光性組成物 |
JP2001039032A (ja) * | 1999-08-02 | 2001-02-13 | Ricoh Co Ltd | 光情報記録媒体 |
JP2001180117A (ja) * | 1999-12-27 | 2001-07-03 | Ricoh Co Ltd | 光情報記録媒体 |
JP2002137547A (ja) * | 2000-08-10 | 2002-05-14 | Mitsui Chemicals Inc | 光記録媒体およびポルフィセン化合物 |
JP2002114923A (ja) * | 2000-10-04 | 2002-04-16 | Hitachi Maxell Ltd | ポルフィセン化合物およびそれを用いた光情報記録媒体 |
JP2003055380A (ja) * | 2001-08-10 | 2003-02-26 | Japan Science & Technology Corp | ポルフィセン金属錯体 |
JP2007269790A (ja) * | 2006-03-09 | 2007-10-18 | Kyushu Univ | モリブデンポルフィセン錯体及び酸化触媒 |
Non-Patent Citations (4)
Title |
---|
BABA T. ET AL.: "Shinki Porphycene Hikari Zokanzai no Sosei Oyobi Koteika", THE CHEMICAL SOCIETY OF JAPAN DAI 87 SHUNKI NENKAI KOEN YOKOSHU, THE CHEMICAL SOCIETY OF JAPAN, vol. II, 12 March 2007 (2007-03-12), pages 1351 * |
BABA T. ET AL.: "Shinki Suiyosei Porphycene Haiishi no Gosei to Sakukeiseino", THE CHEMICAL SOCIETY OF JAPAN DAI 84 SHUNKI NENKAI KOEN YOKOSHU, THE CHEMICAL SOCIETY OF JAPAN, vol. I, 11 March 2004 (2004-03-11), pages 135 * |
ITO K. ET AL.: "Trifluoromethyl-ki o Yusuru Porphycene Tetsusakutai no Hanno", THE CHEMICAL SOCIETY OF JAPAN DAI 84 SHUNKI NENKAI KOEN YOKOSHU, THE CHEMICAL SOCIETY OF JAPAN, vol. I, 11 March 2004 (2004-03-11), pages 135 * |
MAEDA D. ET AL.: "Shinki Molybdenum Porphycene Sakutai no Gosei to Hikari Kagaku Tokusei", THE CHEMICAL SOCIETY OF JAPAN DAI 86 SHUNKI NENKAI KOEN YOKOSHU, THE CHEMICAL SOCIETY OF JAPAN, vol. I, 13 March 2006 (2006-03-13), pages 336 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010229127A (ja) * | 2009-03-06 | 2010-10-14 | Kyushu Univ | イオン液体類似構造を有するポルフィセン化合物および光酸化触媒 |
Also Published As
Publication number | Publication date |
---|---|
JPWO2008111501A1 (ja) | 2010-06-24 |
JP5381702B2 (ja) | 2014-01-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
IL204621A (en) | Amino Acid Derivatives - γ - In bicycles preparations containing them and their uses | |
WO2009147031A3 (en) | Oxime ester photoinitiators | |
MY158316A (en) | Cyclic carbodiimide compound | |
EP1798226A4 (en) | TRAIZOL DERIVATIVE | |
MY154772A (en) | Harmful arthropod control composition, and fused heterocyclic compound | |
WO2008113559A3 (en) | Indolizines and aza-analog derivatives thereof as cns active compounds | |
WO2008108448A1 (ja) | イソキサゾリン置換ベンズアミド化合物及び有害生物防除剤 | |
WO2007085895A3 (en) | Fap inhibitors | |
WO2008126890A1 (ja) | ヒドラジド化合物およびそれを含有する有害節足動物防除剤 | |
WO2008146871A1 (ja) | グルココルチコイド受容体結合活性を有する、スルホン酸エステル又はスルホン酸アミド構造を導入したフェニル基を置換基として有する新規1,2,3,4-テトラヒドロキノキサリン誘導体 | |
MY158466A (en) | Three and four atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture | |
DE602006019788D1 (de) | Oximester-Fotoinitiatoren | |
WO2011014529A3 (en) | Hydrolytically stable phosphite compositions | |
EP1968131A4 (en) | ORGANIC ELECTROLUMINESCENT DEVICE AND MATERIAL THEREFOR | |
CA2565660A1 (en) | Ortho substituted aryl or heteroaryl amide compounds | |
WO2007010453A3 (en) | Transition metal compounds having a cyclic phosphorus-containing ligand and a cyclic organic ligand for use in metathesis reactions | |
MX2007006690A (es) | Analogos 12-aril de prostaglandina. | |
WO2009001060A3 (en) | Use of compounds for preparing anti-tuberculosis agents | |
WO2008126889A1 (ja) | ヒドラジド化合物及びそれを含有する有害節足動物防除剤 | |
ATE550334T1 (de) | N-pyridylpiperidinverbindung, verfahren zu ihrer herstellung und schädlingsbekämpfungsmittel | |
WO2009019005A8 (en) | Tricyclic bridged cyclopentanedione derivatives as herbicides | |
WO2006136837A3 (en) | Pharmaceutical combinations comprising pyrazole derivatives as protein kinase modulators | |
DE602007009182D1 (de) | Clathrate einer quaternären Organosilan-Ammoniumverbindung und Urea und Verwendungsverfahren | |
WO2009083532A3 (en) | Novel method for the preparation of derivatives of dihydrotetraazapentacenes, products such as obtained, and uses thereof | |
WO2009007536A8 (fr) | Dérivés de 7 -alkynyl-1,8-naphthyridones, leur préparation et leur application en thérapeutique |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 08721543 Country of ref document: EP Kind code of ref document: A1 |
|
ENP | Entry into the national phase |
Ref document number: 2009504019 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 08721543 Country of ref document: EP Kind code of ref document: A1 |