WO2008111140A1 - コア－シェル微粒子の製造方法及びその中間体としてのアルコキシアミン基含有単分散架橋微粒子の製造方法 - Google Patents

コア－シェル微粒子の製造方法及びその中間体としてのアルコキシアミン基含有単分散架橋微粒子の製造方法 Download PDF

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Publication number
WO2008111140A1
WO2008111140A1 PCT/JP2007/054689 JP2007054689W WO2008111140A1 WO 2008111140 A1 WO2008111140 A1 WO 2008111140A1 JP 2007054689 W JP2007054689 W JP 2007054689W WO 2008111140 A1 WO2008111140 A1 WO 2008111140A1
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WO
WIPO (PCT)
Prior art keywords
production
microparticle
core
shell
monomer
Prior art date
Application number
PCT/JP2007/054689
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English (en)
French (fr)
Inventor
Masaki Hayashi
Masumi Takamura
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Nof Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nof Corporation filed Critical Nof Corporation
Priority to EP07738174A priority Critical patent/EP2123686B1/en
Priority to US12/530,387 priority patent/US8404762B2/en
Priority to PCT/JP2007/054689 priority patent/WO2008111140A1/ja
Publication of WO2008111140A1 publication Critical patent/WO2008111140A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F271/00—Macromolecular compounds obtained by polymerising monomers on to polymers of nitrogen-containing monomers as defined in group C08F26/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F271/00—Macromolecular compounds obtained by polymerising monomers on to polymers of nitrogen-containing monomers as defined in group C08F26/00
    • C08F271/02—Macromolecular compounds obtained by polymerising monomers on to polymers of nitrogen-containing monomers as defined in group C08F26/00 on to polymers of monomers containing heterocyclic nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

コア－シェル微粒子（１０）は、アルコキシアミン基（１２）を含有する架橋微粒子（１１）と単量体との混合物を１００～１８０°Cに加熱してグラフト重合することにより製造される。架橋微粒子（１１）は、シード粒子に単量体混合物を吸収させ、架橋性単量体１５～９９質量％及びアルコキシアミン基含有単量体１～８５質量％を含有する単量体混合物を重合開始剤の添加により重合させて製造される。
PCT/JP2007/054689 2007-03-09 2007-03-09 コア－シェル微粒子の製造方法及びその中間体としてのアルコキシアミン基含有単分散架橋微粒子の製造方法 WO2008111140A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP07738174A EP2123686B1 (en) 2007-03-09 2007-03-09 Method for the production of monodisperse core-shell microparticles.
US12/530,387 US8404762B2 (en) 2007-03-09 2007-03-09 Method for production of core-shell microparticle, and method for production of monodisperse crosslinked microparticle having alkoxyamine group for use as intermediate for the production of the core-shell microparticle
PCT/JP2007/054689 WO2008111140A1 (ja) 2007-03-09 2007-03-09 コア－シェル微粒子の製造方法及びその中間体としてのアルコキシアミン基含有単分散架橋微粒子の製造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2007/054689 WO2008111140A1 (ja) 2007-03-09 2007-03-09 コア－シェル微粒子の製造方法及びその中間体としてのアルコキシアミン基含有単分散架橋微粒子の製造方法

Publications (1)

Publication Number Publication Date
WO2008111140A1 true WO2008111140A1 (ja) 2008-09-18

Family

ID=39759091

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/054689 WO2008111140A1 (ja) 2007-03-09 2007-03-09 コア－シェル微粒子の製造方法及びその中間体としてのアルコキシアミン基含有単分散架橋微粒子の製造方法

Country Status (3)

Country Link
US (1) US8404762B2 (ja)
EP (1) EP2123686B1 (ja)
WO (1) WO2008111140A1 (ja)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001064308A (ja) * 1999-08-27 2001-03-13 Nof Corp 高分子ラジカル重合開始剤、その製造方法およびそれを用いて得られるグラフトポリマー
JP2001261760A (ja) * 2000-03-21 2001-09-26 Nof Corp 熱硬化性樹脂用グラフト共重合体、熱硬化性樹脂用グラフト共重合体組成物、熱硬化性樹脂組成物及び熱硬化性樹脂組成物の硬化物
JP2001270859A (ja) * 2000-01-17 2001-10-02 Nof Corp ビニル基含有アルコキシアミン、その用途および製造方法
JP2003082014A (ja) * 2001-09-12 2003-03-19 Nof Corp グラフトコポリマーの製造方法
JP2004018557A (ja) * 2002-06-12 2004-01-22 Nisshinbo Ind Inc リビングラジカル重合開始基を有するポリマー微粒子及びその製造方法
JP2004331817A (ja) * 2003-05-07 2004-11-25 Nof Corp グラフトコポリマーの製造方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5455315A (en) * 1994-06-06 1995-10-03 Xerox Corporation Emulsion polymerization processes and toners thereof
US6919481B1 (en) * 1998-07-22 2005-07-19 Nof Corporation Alkoxyamines containing a vinyl group, their applications and methods of their production
FR2807439B1 (fr) * 2000-04-07 2003-06-13 Atofina Polymeres multimodaux par polymerisation radicalaire controlee en presence d'alcoxyamines
JP4215455B2 (ja) * 2002-06-12 2009-01-28 日清紡績株式会社 リビング開始種を有するポリマー粒子及びその製造方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001064308A (ja) * 1999-08-27 2001-03-13 Nof Corp 高分子ラジカル重合開始剤、その製造方法およびそれを用いて得られるグラフトポリマー
JP2001270859A (ja) * 2000-01-17 2001-10-02 Nof Corp ビニル基含有アルコキシアミン、その用途および製造方法
JP2001261760A (ja) * 2000-03-21 2001-09-26 Nof Corp 熱硬化性樹脂用グラフト共重合体、熱硬化性樹脂用グラフト共重合体組成物、熱硬化性樹脂組成物及び熱硬化性樹脂組成物の硬化物
JP2003082014A (ja) * 2001-09-12 2003-03-19 Nof Corp グラフトコポリマーの製造方法
JP2004018557A (ja) * 2002-06-12 2004-01-22 Nisshinbo Ind Inc リビングラジカル重合開始基を有するポリマー微粒子及びその製造方法
JP2004331817A (ja) * 2003-05-07 2004-11-25 Nof Corp グラフトコポリマーの製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2123686A4 *

Also Published As

Publication number Publication date
US20100113704A1 (en) 2010-05-06
EP2123686B1 (en) 2013-02-20
EP2123686A1 (en) 2009-11-25
EP2123686A4 (en) 2010-05-19
US8404762B2 (en) 2013-03-26

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