WO2008108358A1 - 活性エネルギー線硬化型樹脂組成物、活性エネルギー線硬化型塗料および保護層の形成方法 - Google Patents

活性エネルギー線硬化型樹脂組成物、活性エネルギー線硬化型塗料および保護層の形成方法 Download PDF

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Publication number
WO2008108358A1
WO2008108358A1 PCT/JP2008/053829 JP2008053829W WO2008108358A1 WO 2008108358 A1 WO2008108358 A1 WO 2008108358A1 JP 2008053829 W JP2008053829 W JP 2008053829W WO 2008108358 A1 WO2008108358 A1 WO 2008108358A1
Authority
WO
WIPO (PCT)
Prior art keywords
active energy
energy ray
coating material
protective layer
curable
Prior art date
Application number
PCT/JP2008/053829
Other languages
English (en)
French (fr)
Inventor
Yohzoh Yamashina
Hiroyuki Tokuda
Youichi Tanimoto
David
Nobuyuki Koike
Original Assignee
Dic Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dic Corporation filed Critical Dic Corporation
Priority to US12/530,070 priority Critical patent/US8414979B2/en
Priority to JP2009502585A priority patent/JP4304643B2/ja
Priority to CN200880007573XA priority patent/CN101657478B/zh
Priority to KR1020097013860A priority patent/KR101317795B1/ko
Priority to EP08721249A priority patent/EP2133374A4/en
Publication of WO2008108358A1 publication Critical patent/WO2008108358A1/ja

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
    • C08G18/3851—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing three nitrogen atoms in the ring
    • C08G18/3853—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing three nitrogen atoms in the ring containing cyanurate and/or isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8125—Unsaturated isocyanates or isothiocyanates having two or more isocyanate or isothiocyanate groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

　本発明は、硬度が高く、且つ、低硬化収縮の硬化塗膜が形成できる活性エネルギー線硬化型塗料、該塗料を得るための活性エネルギー線硬化型樹脂組成物及び、該塗料を用いた保護層の形成方法を提供することを目的とし、この目的を達成すべく、ビシクロ環を含有するポリイソシアネート化合物（ａ１）と水酸基を含有する３官能以上の（メタ）アクリレート（ａ２）とトリス２－ヒドロキシアルキルイソシアヌレートジ（メタ）アクリレート（ａ３）とを反応させて得られるウレタン（メタ）アクリレート（Ａ）を含有する活性エネルギー線硬化型樹脂組成物、該組成物を含有する活性エネルギー線硬化型塗料及び該塗料を支持体に塗布し支持体上に活性エネルギー線硬化型塗料の層を形成した後、該塗料の層に活性エネルギー線を照射することにより該塗料の層を硬化させて保護層を形成する保護層の形成方法を提供する。
PCT/JP2008/053829 2007-03-08 2008-03-04 活性エネルギー線硬化型樹脂組成物、活性エネルギー線硬化型塗料および保護層の形成方法 WO2008108358A1 (ja)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US12/530,070 US8414979B2 (en) 2007-03-08 2008-03-04 Radiation-curable resin composition, radiation-curable coating material, and method for forming protective layer
JP2009502585A JP4304643B2 (ja) 2007-03-08 2008-03-04 活性エネルギー線硬化型樹脂組成物、活性エネルギー線硬化型塗料および保護層の形成方法
CN200880007573XA CN101657478B (zh) 2007-03-08 2008-03-04 活性能量射线固化型树脂组合物、活性能量射线固化型涂料及保护层的形成方法
KR1020097013860A KR101317795B1 (ko) 2007-03-08 2008-03-04 활성 에너지선 경화형 수지 조성물, 활성 에너지선 경화형 도료 및 보호층의 형성 방법
EP08721249A EP2133374A4 (en) 2007-03-08 2008-03-04 RESIN COMPOSITION CURABLE BY ACTIVE RADIANT ENERGY, COATING MATERIAL CURABLE BY ACTIVE RADIANT ENERGY, AND METHOD OF FORMING PROTECTIVE LAYER

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-058522 2007-03-08
JP2007058522 2007-03-08

Publications (1)

Publication Number Publication Date
WO2008108358A1 true WO2008108358A1 (ja) 2008-09-12

Family

ID=39738236

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/053829 WO2008108358A1 (ja) 2007-03-08 2008-03-04 活性エネルギー線硬化型樹脂組成物、活性エネルギー線硬化型塗料および保護層の形成方法

Country Status (7)

Country Link
US (1) US8414979B2 (ja)
EP (1) EP2133374A4 (ja)
JP (1) JP4304643B2 (ja)
KR (1) KR101317795B1 (ja)
CN (1) CN101657478B (ja)
TW (1) TWI428410B (ja)
WO (1) WO2008108358A1 (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010083959A (ja) * 2008-09-30 2010-04-15 Dic Corp コーティング用活性エネルギー線硬化型樹脂組成物及びフィルム基材
EP2412773A1 (en) * 2009-03-23 2012-02-01 DIC Corporation Adhesive protective film, screen panel, and portable electronic terminal
US20120252998A1 (en) * 2009-09-18 2012-10-04 Dic Corporation Active-Energy-Ray-Curable Resin Composition, Cured Product Thereof, and Film
WO2017217522A1 (ja) * 2016-06-17 2017-12-21 日本合成化学工業株式会社 活性エネルギー線硬化性樹脂組成物及びこれを用いてなるコーティング剤

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102844346B (zh) * 2010-03-31 2014-10-15 Dic株式会社 活性能量射线固化型树脂组合物、其固化物及薄膜
TWI526506B (zh) * 2010-09-21 2016-03-21 Arakawa Chem Ind Non-aqueous primer with plastic film with reactive energy ray hardening film, plastic film with hardening film with active energy line
US20140004367A1 (en) * 2010-12-22 2014-01-02 Dic Corporation Method for producing dispersion, dispersion, coating material, coating film, and film
KR20150138281A (ko) * 2013-03-27 2015-12-09 디아이씨 가부시끼가이샤 활성 에너지선 경화성 조성물, 그 경화 도막, 및 당해 경화 도막을 갖는 물품
KR101751372B1 (ko) * 2013-09-25 2017-07-03 하리마 카세이 가부시키가이샤 광경화성 수지 조성물 및 그 경화막
CN103483900B (zh) * 2013-09-26 2015-01-07 江苏高博智融科技有限公司 一种金属漆填料
JP7218998B2 (ja) * 2015-02-06 2023-02-07 三菱瓦斯化学株式会社 硬化性樹脂組成物、硬化物及び積層体
JP6640624B2 (ja) * 2016-03-23 2020-02-05 第一工業製薬株式会社 活性エネルギー線硬化型組成物
CN109312047A (zh) * 2016-06-20 2019-02-05 Dic株式会社 氨基甲酸酯(甲基)丙烯酸酯树脂和层叠薄膜
KR101969326B1 (ko) * 2018-09-21 2019-04-17 민경기술 주식회사 2액형 중방식 도료 조성물 및 이를 사용한 친환경 보수보강 시공방법

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JP2006328364A (ja) * 2005-04-25 2006-12-07 Dainippon Ink & Chem Inc 活性エネルギー線硬化型樹脂組成物、それを用いた物品及び成形体
JP2007131837A (ja) * 2005-10-12 2007-05-31 Dainippon Ink & Chem Inc フィルム保護層用活性エネルギー線硬化型樹脂組成物、それを用いたフィルム及び光学シート

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010083959A (ja) * 2008-09-30 2010-04-15 Dic Corp コーティング用活性エネルギー線硬化型樹脂組成物及びフィルム基材
EP2412773A1 (en) * 2009-03-23 2012-02-01 DIC Corporation Adhesive protective film, screen panel, and portable electronic terminal
EP2412773A4 (en) * 2009-03-23 2014-08-13 Dainippon Ink & Chemicals ADHESIVE PROTECTIVE FILM, SCREEN PANEL AND PORTABLE ELECTRONIC TERMINAL
US20120252998A1 (en) * 2009-09-18 2012-10-04 Dic Corporation Active-Energy-Ray-Curable Resin Composition, Cured Product Thereof, and Film
US8754180B2 (en) * 2009-09-18 2014-06-17 Dic Corporation Active-energy-ray-curable resin composition, cured product thereof, and film
WO2017217522A1 (ja) * 2016-06-17 2017-12-21 日本合成化学工業株式会社 活性エネルギー線硬化性樹脂組成物及びこれを用いてなるコーティング剤

Also Published As

Publication number Publication date
TW200844195A (en) 2008-11-16
JPWO2008108358A1 (ja) 2010-06-17
TWI428410B (zh) 2014-03-01
EP2133374A4 (en) 2012-06-20
JP4304643B2 (ja) 2009-07-29
CN101657478B (zh) 2011-07-27
CN101657478A (zh) 2010-02-24
US20100104765A1 (en) 2010-04-29
KR20090128375A (ko) 2009-12-15
KR101317795B1 (ko) 2013-10-15
EP2133374A1 (en) 2009-12-16
US8414979B2 (en) 2013-04-09

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