WO2008092984A1 - Matière cristalline microporeuse de nature zéolitique, zéolite itq-39, son procédé de préparation et utilisation - Google Patents

Matière cristalline microporeuse de nature zéolitique, zéolite itq-39, son procédé de préparation et utilisation Download PDF

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Publication number
WO2008092984A1
WO2008092984A1 PCT/ES2008/070014 ES2008070014W WO2008092984A1 WO 2008092984 A1 WO2008092984 A1 WO 2008092984A1 ES 2008070014 W ES2008070014 W ES 2008070014W WO 2008092984 A1 WO2008092984 A1 WO 2008092984A1
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sio
ade
reaction mixture
source
crystalline material
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PCT/ES2008/070014
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English (en)
Spanish (es)
Inventor
Avelino CORMA CANÓS
Manuel MOLINER MARÍN
Fernando REY GARCÍA
Jorge GONZÁLEZ GONZÁLEZ
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Consejo Superior De Investigaciones Científicas
Universidad Politécnica De Valencia
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Application filed by Consejo Superior De Investigaciones Científicas, Universidad Politécnica De Valencia filed Critical Consejo Superior De Investigaciones Científicas
Priority to US12/525,506 priority Critical patent/US8226925B2/en
Priority to EP08718461.0A priority patent/EP2119669B1/fr
Priority to ES08718461T priority patent/ES2728311T3/es
Publication of WO2008092984A1 publication Critical patent/WO2008092984A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent

Definitions

  • the present invention belongs to the technical field of microporous crystalline materials of a zeolitic nature, useful as adsorbents, catalysts or catalyst components, for processes of transformation, adsorption and separation of organic compounds.
  • Zeolites are microporous crystalline materials formed by a network of TO 4 tetrahedra that share all their vertices giving rise to a three-dimensional structure that contains channels and / or cavities of molecular dimensions. They are of variable composition, and T generally represents atoms with a formal oxidation state +3 or +4, such as Si, Ge, Ti, Al, B, Ga, ... When any of the T atoms has an oxidation state less than +4, the crystalline network formed has negative charges that are compensated by the presence in the channels or cavities of organic or inorganic cations.
  • organic molecules and H 2 O can also be accommodated, so that, in general, the chemical composition of the zeolites can be represented by the following empirical formula: x (MiZ n XO 2 ): and YO 2 : z R: w H 2 O where M is one or more organic or inorganic charge cations + n; X is one or more trivalent elements; And it is one or several tetravalent elements, generally Si; and R is one or several organic cations.
  • the chemical composition of a zeolite (as synthesized or after calcination) has a range characteristic of each zeolite and its method of obtaining.
  • each zeolite with a specific system of channels and cavities, gives rise to a characteristic X-ray diffraction pattern, which allows them to be differentiated from each other.
  • zeolites have been synthesized in the presence of an organic molecule that acts as a structure directing agent.
  • Organic molecules that act as structure directing agents (ADE) generally contain nitrogen in their composition, and can lead to stable organic cations in the reaction medium.
  • the mobilization of the precursor species during the synthesis of zeolites can be carried out in the presence of hydroxyl groups and basic medium, which can be introduced as hydroxide of the same ADE, such as tetrapropylammonium hydroxide in the case of zeolite ZSM-5.
  • fluoride ions can act as mobilizing agents in zeolite synthesis, for example in the patent EP-A-337479 the use of HF in H 2 O at low pH is described as the mobilizing agent of silica for the synthesis of zeolite ZSM- 5.
  • the present invention relates to a new microporous crystalline material of a zeolitic nature, identified as "ITQ-39 zeolite", and to its preparation process.
  • This material both in its calcined and synthesized form without calcining, has an X-ray diffraction pattern that is different from other known zeolitic materials and, therefore, is characteristic of this material.
  • the present invention relates firstly to a microporous crystalline material of a zeolitic nature that has, in the calcined state and in the absence of defects in its crystalline network manifested by the presence of silanoles, the empirical formula x (M 17n XO 2 ): y YO 2 : SiO 2 in which
  • M is selected from H + , an inorganic cation of charge + n, and a mixture of both,
  • X is at least one chemical element of oxidation state +3,
  • x takes a value between 0 and 0.3, both included, and takes a value between 0 and 0.1, both included, and because the material, as synthesized, has an X-ray diffraction pattern with at least 2, angle values (degrees) and relative intensities (1 / I 0 ) shown in Table I, where I 0 is the intensity of the most intense peak to which a value of 100 is assigned: Table I
  • d is a weak relative intensity between 0 and 20%
  • m is an average relative intensity between 20 and 40%
  • f is a strong relative intensity between 40 and 60%
  • mf is a very strong relative intensity between 60 and 100%
  • h means that this diffraction peak appears as a shoulder.
  • microporous crystalline material of zeolitic nature after being calcined to remove the organic compounds occluded therein, has an X-ray diffraction pattern with at least 2, angle values (degrees) and relative intensities (VLo ) indicated in table II:
  • Element X is preferably selected from Al, Ga, B, Fe, Cr and mixtures thereof.
  • the element Y is preferably selected from Ge, Ti, Sn, V and mixtures thereof.
  • the microporous crystalline material of zeolitic nature ITQ-39 has, in the calcined state and in the absence of defects in its crystalline network manifested by the presence of silanoles, the empirical formula in which
  • M is selected from H + , at least one inorganic cation of charge + n, preferably alkaline or alkaline earth, and a mixture of both,
  • X is at least one chemical element of oxidation state +3, selected from Al, Ga, B, Fe, Cr and mixtures thereof
  • Y is at least one chemical element with oxidation state +4 other than Si, selected from Ge, Ti, Sn, V and mixtures thereof
  • x takes a value between 0 and 0.3, both included, and takes a value between 0 and 0.05, both included
  • the material, as synthesized has an x-ray diffraction pattern with, at less, the values of angle 2 ⁇ (degrees) and relative intensities mentioned above (table I) and said material has in a calcined state an X-ray diffraction pattern with at least the values of angle 2 ⁇ (degrees) and relative intensities ( 1 / I 0 ) mentioned above (table II).
  • the X-ray diffraction patterns of the ITQ-39 material have been obtained by the powder method using a fixed divergence slit of 1/4 ° and using the Cu radiation Ka. It should be noted that the diffraction data listed for this ITQ-39 zeolite sample as single or single lines, may be formed by multiple overlaps or overlapping reflections that, under certain conditions, such as differences in crystallographic changes, may appear as lines resolved or partially resolved. Generally, crystallographic changes may include small variations in the parameters of the unit cell and / or changes in the symmetry of the crystal, without a change in structure. Thus, the positions, widths and relative intensities of the peaks depend to some extent on the chemical composition of the material, as well as on the degree of hydration and crystal size.
  • the ITQ-39 zeolite as synthesized presents an X-ray diffraction pattern as shown in Figure 2.
  • This diagram is characterized by the values of angle 2 ⁇ (degrees) and relative intensities (1 / I 0 ) presented in the table
  • the reaction mixture comprises exclusively: one or more sources of SiO 2 , one or more sources of ADE-I organic cation, one or more sources of fluoride ions, and water, and has a composition, in terms of molar relationships, between intervals
  • the reaction mixture further comprises: a source of one or more trivalent elements X, and has a composition, in terms of molar ratios, between the intervals
  • the reaction mixture further comprises: a source of another or other tetravalent elements Y, other than Si, and has a composition, in terms of molar relationships, between the intervals
  • the reaction mixture comprises: a source of SiO 2 , a source of another or other tetravalent elements Y, other than Si, selected from Ge, Ti, V, Sn, and mixtures thereof, a source of one or several trivalent elements X selected from Al, B, Ga, Fe, Cr and mixtures thereof, a source of inorganic M-loading cations -Mi, selected from alkaline, alkaline earth, and mixtures thereof, a cation source Organic ADE-I 2+ , shown in Figure 1, a source of fluoride ions, and water, is subjected to heating with or without stirring at a temperature between 80 and 200 0 C, until its crystallization is achieved, and it has a composition, in terms of molar ratios, between the intervals
  • composition of the reaction mixture that results in obtaining the ITQ-39 material can be represented in general by the following formula with the values of the parameters indicated in terms of molar ratios: r ADE-I (OH) 2 : s Mi 7n OH: t X 2 O 3 : u YO 2 : v F: SiO 2 : w H 2 O
  • M is one or several inorganic charge cations -in; preferably alkaline or alkaline earth, X is one or more trivalent elements, preferably Al, B, Ga, Fe, Cr or mixtures thereof; Y is one or several tetravalent elements other than Si, preferably Ge, Ti, Sn, V or mixtures thereof; ADE-I is the cation depicted in Figure 1; F is one or more sources of fluoride ions, preferably HF, NH 4 F, or a mixture of both, and the values of r, s, t, u, v and w vary in the ranges:
  • the components of the synthesis mixture can come from different sources, and depending on these the crystallization times and conditions may vary.
  • the heat treatment of the mixture takes place at temperatures between 130 and 200 0 C.
  • the heat treatment of the reaction mixture can be carried out in static or with stirring of the mixture.
  • the solid product is separated by filtration or centrifugation and dried.
  • the source of SiO 2 may be, for example, tetraethylorthosilicate, colloidal silica, amorphous silica and a mixture thereof.
  • the fluoride anion is used as a mobilizing agent for precursor species.
  • the source of fluoride ions is preferably HF, NH 4 F or a mixture of both.
  • the organic cation, represented by ADE-I is preferably added to the reaction mixture in the form of salt, for example, a halide, or in the form of hydroxide and, additionally, a source of alkali, alkaline earth or ionic ions can be added of both (M), in the form of hydroxide or in the form of salt.
  • an amount of ITQ-39 crystalline material of the present invention is added to the reaction mixture as a crystallization promoter in an amount between 0.01 and 20% by weight, preferably between 0, 05 and 10% by weight with respect to the total inorganic oxides added.
  • the material produced by this invention can be pelletized according to known techniques, and can be used as a catalyst or catalyst component in processes of transformation of organic compounds, or as an adsorbent in processes of adsorption and separation of organic compounds.
  • the ITQ-39 material used in these applications may be in its acid form and / or exchanged with suitable cations.
  • the resulting solution is concentrated by rotary evaporator and a solution of KOH (25% by weight) is added until a pH of more than 12 is reached. In this step, a bank precipitate appears. The resulting mixture is saturated with NaCl, and poured into water. Finally, the diamine l-propyl-4-pyrrolidin-l-yl-piperidine is extracted with diethyl ether and dried with anhydrous MgSO 4 .
  • the quaternization of the diamine is carried out as follows: 100 g of propyl iodide are added to a solution of 43.5 g of diamine in 70 ml of MeOH. The mixture is maintained with continuous stirring at room temperature for
  • the cation iodide is exchanged for hydroxide using an ion exchange resin according to the following procedure: 44 mmol of cation iodide ([ADE-I] I 2 ) is dissolved in water. To the solution obtained is added 89 g of Dowex SBR resin and kept under stirring until the next day. Subsequently, it is filtered, washed with distilled water and a dihydroxide solution of the cation shown in Figure 1 is obtained, ([ADE-I] (OH) 2 ), which is titrated with HCl (aq.), Using phenolphthalein as indicator, obtaining an efficiency in the exchange superior to 90%. The final solution contains 0.62 equivalents of hydroxide per 1000 g of solution.
  • the gel is heated for 7 days in steel autoclaves with an internal Teflon sheath at 15O 0 C in static.
  • the solid obtained after filtering, washing with distilled water and dried at 100 0 C is ITQ-39.
  • the gel is heated for 12 days in steel autoclaves with an internal Teflon cover at 135 0 C in static.
  • the solid obtained after filtering, washing with distilled water and dried at 100 0 C is ITQ-39.
  • the gel is heated for 14 days in steel autoclaves with an internal Teflon sheath at 15O 0 C in static.
  • the solid obtained after filtering, washing with distilled water and dried at 100 0 C is ITQ-39.
  • the gel is heated for 11 days in steel autoclaves with an internal Teflon sheath at 15O 0 C in static.
  • the solid obtained after filtering, washing with distilled water and drying at 100 0 C is ITQ-39 and its X-ray diffractogram is shown in Figure 2.
  • Figure 1 represents the organic cation in the presence of which the ITQ-39 zeolite is synthesized
  • Figure 2 represents the most characteristic peaks of the X-ray diffraction pattern of the ITQ-39 material, as synthesized, obtained according to example 5.
  • Figure 3 represents the most characteristic peaks of the X-ray diffraction pattern of the material of Example 5 in a calcined state.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

L'invention concerne une matière cristalline microporeuse de nature zéolitique, ITQ-39, caractérisée en ce qu'elle comprend, à l'état calciné et en l'absence de défaut sur son réseau cristallin manifestés par la présence de silanoles, la formule empirique : 5 x (M 1/n XO 2 ) : y YO 2 : SiO 2, M étant sélectionné entre H +, un cation inorganique de charge +n est un mélange des deux, X étant au moins un élément chimique d'état d'oxydation +3, Y étant au moins un élément chimique d'état d'oxydation +4 différent de Si, 10 x prenant une valeur comprise entre 0 et 0,3, les deux étant incluses, y prenant une valeur comprise entre 0 et 0,1, les deux étant incluses, et en ce que la matière, selon la manière de synthétiser, présente un patron de diffraction de rayons X, avec au moins les valeurs d'angle 2ϑ (degrés) et intensités relatives (I/I 0 ) affichées dans le tableau I. L'invention concerne aussi son procédé de préparation et son utilisation dans des processus de transformation, d'absorption et de séparation de composés organiques.
PCT/ES2008/070014 2007-02-01 2008-01-31 Matière cristalline microporeuse de nature zéolitique, zéolite itq-39, son procédé de préparation et utilisation WO2008092984A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US12/525,506 US8226925B2 (en) 2007-02-01 2008-01-31 Microporous crystalline material of zeolitic nature, zeolite ITQ-39, method of preparation and uses
EP08718461.0A EP2119669B1 (fr) 2007-02-01 2008-01-31 Matière cristalline microporeuse de nature zéolitique, zéolite itq-39, son procédé de préparation et utilisation
ES08718461T ES2728311T3 (es) 2007-02-01 2008-01-31 Material cristalino microporoso de naturaleza zeolítica, zeolita ITQ-39, método de preparación y usos

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ES200700334A ES2303787B2 (es) 2007-02-01 2007-02-01 "material cristalino microporoso de naturaleza zeolitica, zeolita itq-39, procedimiento de preparacion y usos".
ESP200700334 2007-02-01

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014013102A1 (fr) 2012-07-19 2014-01-23 Consejo Superior De Investigaciones Científicas (Csic) Procédé d'oligomérisation d'alcènes faisant appel à la zéolithe itq-39

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI1102638B1 (pt) * 2011-06-16 2020-10-20 Universidade Federal Do Rio Grande Do Sul zeólita e materiais mesoporosos organizados como carga para a formulação de compostos de borracha, borracha termoplástica, plástico e fabricação de produtos
ES2421063B1 (es) * 2012-01-25 2014-06-26 Consejo Superior De Investigaciones Cientificas (Csic) Material ITQ-38, su procedimiento de obtención y su uso
GB201209162D0 (en) * 2012-05-24 2012-07-04 Air Fuel Synthesis Ltd Methanol conversion process
WO2016058541A1 (fr) * 2014-10-15 2016-04-21 Basf Se Synthèse solidothermique de matériaux zéolitiques et zéolites ainsi obtenues

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0337479A2 (fr) 1988-04-15 1989-10-18 Deggendorfer Werft Und Eisenbau Gmbh Procédé de préparation de zéolites
EP1010667A1 (fr) * 1998-12-18 2000-06-21 Uop Llc Tamis moléculaires de type stannosilicate et de structure beta
WO2005030646A1 (fr) * 2003-09-29 2005-04-07 Consejo Superior De Investigaciones Científicas Materiau cristallin microporeux de type zeolithique, zeolithe itq-28, procede de preparation et applications
WO2005113438A1 (fr) * 2004-04-20 2005-12-01 Uop Llc Uzm-16: un matériau zéolitique d'aluminosilicate cristallin

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5007997A (en) * 1988-03-23 1991-04-16 Chevron Research Company Zeolite SSZ-26
FR2752567B1 (fr) * 1996-08-23 1998-10-16 Inst Francais Du Petrole Zeolithe nu-88, son procede de preparation et ses applications catalytiques
US6616911B2 (en) * 2000-03-07 2003-09-09 Chevron U.S.A. Inc. Process for preparing zeolites using pyrrolidinium cations
US6787124B2 (en) * 2002-03-15 2004-09-07 Exxonmobil Research And Engineering Company Synthetic porous crystalline material, EMM-1, its synthesis and use
US7022308B1 (en) * 2004-09-22 2006-04-04 Chevron U.S.A. Inc. Preparation of molecular sieve SSZ-33
ES2263369B1 (es) * 2005-02-02 2007-12-16 Universidad Politecnica De Valencia Material cristalino microporoso de naturaleza zeolitica, zeolita itq-32, procedimiento de preparacion y uso.
US7998457B2 (en) * 2008-11-25 2011-08-16 Chevron U.S.A. Inc. Molecular sieve SSZ-83
US8865121B2 (en) * 2009-06-18 2014-10-21 Basf Se Organotemplate-free synthetic process for the production of a zeolitic material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0337479A2 (fr) 1988-04-15 1989-10-18 Deggendorfer Werft Und Eisenbau Gmbh Procédé de préparation de zéolites
EP1010667A1 (fr) * 1998-12-18 2000-06-21 Uop Llc Tamis moléculaires de type stannosilicate et de structure beta
WO2005030646A1 (fr) * 2003-09-29 2005-04-07 Consejo Superior De Investigaciones Científicas Materiau cristallin microporeux de type zeolithique, zeolithe itq-28, procede de preparation et applications
WO2005113438A1 (fr) * 2004-04-20 2005-12-01 Uop Llc Uzm-16: un matériau zéolitique d'aluminosilicate cristallin

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2119669A4

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014013102A1 (fr) 2012-07-19 2014-01-23 Consejo Superior De Investigaciones Científicas (Csic) Procédé d'oligomérisation d'alcènes faisant appel à la zéolithe itq-39
ES2443539A1 (es) * 2012-07-19 2014-02-19 Consejo Superior De Investigaciones Científicas (Csic) Proceso de oligomerización de alquenos utilizando la zeolita ITQ-39
US9550706B2 (en) 2012-07-19 2017-01-24 Exxonmobil Chemical Patents Inc. Method for oligomerising alkenes using the ITQ-39 zeolite

Also Published As

Publication number Publication date
ES2728311T3 (es) 2019-10-23
EP2119669A4 (fr) 2016-02-24
EP2119669B1 (fr) 2019-03-20
EP2119669A1 (fr) 2009-11-18
US8226925B2 (en) 2012-07-24
ES2303787A1 (es) 2008-08-16
ES2303787B2 (es) 2009-06-12
US20090312177A1 (en) 2009-12-17

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