WO2008028342A1 - A solid detergent paste and its preparation method - Google Patents

A solid detergent paste and its preparation method Download PDF

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Publication number
WO2008028342A1
WO2008028342A1 PCT/CN2006/002515 CN2006002515W WO2008028342A1 WO 2008028342 A1 WO2008028342 A1 WO 2008028342A1 CN 2006002515 W CN2006002515 W CN 2006002515W WO 2008028342 A1 WO2008028342 A1 WO 2008028342A1
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Prior art keywords
mixing tank
paste
decontamination
ethanol
triethanolamine
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PCT/CN2006/002515
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French (fr)
Chinese (zh)
Inventor
Jiameng Li
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Jiameng Li
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Publication of WO2008028342A1 publication Critical patent/WO2008028342A1/en

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/26—Organic compounds, e.g. vitamins containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/26—Organic compounds, e.g. vitamins containing oxygen
    • C11D9/265—Organic compounds, e.g. vitamins containing oxygen containing glycerol
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22—Organic compounds, e.g. vitamins
    • C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00—Compositions of detergents based essentially on soap
    • C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/44—Perfumes; Colouring materials; Brightening agents ; Bleaching agents

Definitions

  • the present invention relates to the field of household chemical washing, and more particularly to a solid decontamination paste and a method of preparing the same.
  • BACKGROUND OF THE INVENTION At present, most of the decontamination products used in China to remove stains, such as collars and cuffs, and stains on range hoods, are spray type, because most of the solvents used are small in molecular weight and extremely volatile, which leads to Decontamination is not effective, and it is not environmentally friendly.
  • stains such as collars and cuffs, and stains on range hoods
  • the spray cleaning described in CN1143 108A is composed of chloroform, trichloroethylene, carbon tetrachloride, acetone and ethanol.
  • decontamination and descaling also need to use the paste to both decontamination, but also It acts as a friction and polishing without damaging the decontamination and cleaning of the surface of the object.
  • a solid decontamination paste characterized in that the decontamination paste is composed of four parts A, B, C and D, part A consists of water and ethylene glycol, part B consists of TX-10 and soap particles, and part C consists of Glycerin and triethanolamine, part D consists of ethanol and flavor, wherein TX-10 is nonylphenol ethoxylate; based on the total weight of the decontamination paste, the weight percentage of each component is: Pure water 10% - 60%
  • the weight percentage of each component is preferably:
  • the decontamination paste is prepared by first mixing the components A, B, C and D according to the weight percentage of each component in the solid decontamination paste at normal temperature and pressure, and then adding the A portion in the mixing tank and heating. When the temperature of the material in the mixing tank reaches 50 °C, add part B to the mixing tank, continue to heat the material to 80 °C, until the material in the mixing tank is completely dissolved, then add part C in the mixing tank, stir evenly, The material in the mixing tank is cooled to 58 V, and finally the D part is added, and then evenly stirred, and poured into a mold at a temperature of not lower than 53 ° C.
  • the decontamination paste of the present invention is in a solid form and is environmentally friendly and hygienic.
  • the decontamination cream is not only suitable for garment factories, textile mills, socks factories and dry cleaners. Also suitable for home use, especially men's shirt collars, children's dirty clothes, ballpoint stains, as well as range hood grease, mechanics' dirty clothes and sportswear, as well as wood, metal, plastic surfaces and blood stains Clothes.
  • the method of using the decontamination cream to remove stains is as follows: It is best not to soak the water in the clothing category. First apply the decontamination cream to the stained clothing, and then wash it in the washing machine after 3-5 minutes. The hand washing effect will be better. . If the range hood is cleaned, first wet the cloth, then apply the decontamination paste on the wet cloth, and then wipe the range hood, generally to achieve clean light; if the range hood is not cleaned for a long time and the stain is too thick You can apply the decontamination cream directly on the stains. After a while, the stains on the range hood will become dry. Then use a knife to cut off the stains, then apply the decontamination paste on the wet cloth to scrub the range hood. The machine will be clean and bright. EXAMPLES OF THE INVENTION The invention is further described below by way of examples:
  • 21% TX-10 and 21% soap particles are mixed into Part B, 18% glycerin and 1 % triethanolamine is mixed into part C, 1% ethanol and 1% lemon flavor are mixed into part D; then the crucible portion is added to the mixing tank and heated, and when the temperature of the material in the mixing tank reaches 50 °C, B is added to the mixing tank. Part, continue to heat the material to 80 °C until the material in the mixing tank is completely dissolved, then add part C to the mixing tank, stir evenly, then cool the material in the mixing tank to 58 °C, and finally add part D, then stir evenly. , when it is not less than 53 °C, it is poured into the mold to form a solid decontamination paste.
  • the physical and chemical indicators of the solid decontamination paste prepared in Example 1 were determined: wherein the total active substance was determined according to GB/T 13173.2; the PH value was determined according to GB/T 6368, and the measurement was carried out with an aqueous solution of 1% sample as a standard solution; When determining the decontamination ratio, the solid decontamination paste is evenly rubbed on the standard contaminated cloth until the contaminated cloth is soaked. After 5 minutes, it is immersed in the standard washing powder solution and measured according to the procedures and methods specified in GB/T 13174-2003. And calculate The pollution ratio, wherein the concentration of the standard laundry detergent solution is 0.1%.
  • the physical and chemical indicators are shown in Table 1. It can be seen from Table 1 that the solid decontamination paste has good quality, does not hurt the hand and has strong detergency.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

A solid detergent paste which consists of four parts: A, B, C, and D. A is composed of 10-60% purified water and 1-30% ethylene glycol; B is composed of 1-40% nonylphenyl polyethyleneglycol ether, i.e. TX-10, and 15-35% neat soap; C is composed of 0.01-40% glycerin and 0.01-3% triethanolamine; and D is composed of 0.01-10% ethanol and 0.01-5% essence; wherein the weight percent is all based on the total weight of the dergent paste. And its preparation method.

Description

技术领域 本发明属于日用化工洗涤领域， 尤其涉及一种固体去污膏及其 制备方法。 背景技术 目前， 我国用于清除难除去污渍， 如衣领和袖口以及抽油烟机 上污渍的绝大多数去污用品为喷雾型， 由于所用溶剂大多分子量很 小， 极易挥发， 一方面会导致去污效力不好， 且不环保.。 如TECHNICAL FIELD The present invention relates to the field of household chemical washing, and more particularly to a solid decontamination paste and a method of preparing the same. BACKGROUND OF THE INVENTION At present, most of the decontamination products used in China to remove stains, such as collars and cuffs, and stains on range hoods, are spray type, because most of the solvents used are small in molecular weight and extremely volatile, which leads to Decontamination is not effective, and it is not environmentally friendly. Such as
CN1143 108A所述的喷洁净就是由三氯甲烷、 三氯乙烯、 四氯化碳、 丙酮、 乙醇构成的。 此外， 如一些硬质物体表面 （如不锈钢、 塑料、 铝制品、 玻璃等） 和一些软质包装表面 （如沙发等） 的去污除垢也 需要使用膏体类的既能去污， 又能起摩擦、 抛光作用， 而又不损伤 物品表面的去污、 清净品。 发明内容 本发明的目的在于克服现有技术的不足， 提供一种去污力强， 适用性广的固体去污膏及其制备方法。 The spray cleaning described in CN1143 108A is composed of chloroform, trichloroethylene, carbon tetrachloride, acetone and ethanol. In addition, such as the surface of some hard objects (such as stainless steel, plastics, aluminum products, glass, etc.) and some soft packaging surfaces (such as sofas), decontamination and descaling also need to use the paste to both decontamination, but also It acts as a friction and polishing without damaging the decontamination and cleaning of the surface of the object. SUMMARY OF THE INVENTION The object of the present invention is to overcome the deficiencies of the prior art and to provide a solid decontamination paste with strong detergency and wide applicability and a preparation method thereof.
本发明的目的是这样实现的：  The object of the invention is achieved in this way:
一种固体去污膏， 其特征在于该去污膏由 A， B， C和 D四部分 组成， A部分由水和乙二醇组成， B部分由 TX- 10和皂粒组成， C 部分由甘油和三乙醇胺组成， D部分由乙醇和香精组成，其中 TX-10 为壬基酚聚氧乙烯醚； 以去污膏总重量为基准， 各组分所占的重量 百分比为： 纯水 10%— 60% A solid decontamination paste, characterized in that the decontamination paste is composed of four parts A, B, C and D, part A consists of water and ethylene glycol, part B consists of TX-10 and soap particles, and part C consists of Glycerin and triethanolamine, part D consists of ethanol and flavor, wherein TX-10 is nonylphenol ethoxylate; based on the total weight of the decontamination paste, the weight percentage of each component is: Pure water 10% - 60%
乙二醇 1%— 30%  Ethylene glycol 1% - 30%
TX-10 1% -40%  TX-10 1% -40%
皂粒 15%— 35%  Soap particles 15% - 35%
甘油 0.01%— 40%  Glycerin 0.01% - 40%
三乙醇胺 0.01%—3%  Triethanolamine 0.01%-3%
乙醇 0.01%— 10%  Ethanol 0.01% - 10%
香精 0.01%— 5%。  Fragrance 0.01% - 5%.
其中， 各组分所占的重量百分比优选为:  Wherein, the weight percentage of each component is preferably:
纯水 21%  Pure water 21%
乙二醇 16%  Ethylene glycol 16%
TX-10 21%  TX-10 21%
皂粒 21%  Soap particles 21%
甘油 18%  Glycerin 18%
三乙醇胺 1%  Triethanolamine 1%
乙醇 1%  Ethanol 1%
1%。  1%.
该去污膏的制备方法为， 首先根据各组分在固体去污膏中的重 量百分比于常温常压下混合配制 A、 B、 C和 D部分， 然后在搅拌桶 里加入 A部分并加热， 当搅拌桶里物料温度到达 50°C时再在搅拌桶 里加入 B部分， 继续加热物料至 80°C， 直到搅拌桶里物料完全溶解， 再在搅拌桶里加入 C部分， 搅拌均匀后， 将搅拌桶里物料降温到 58 V， 最后加入 D部分， 再搅拌均匀， 在不低于 53°C时灌入模具中成 型即可。  The decontamination paste is prepared by first mixing the components A, B, C and D according to the weight percentage of each component in the solid decontamination paste at normal temperature and pressure, and then adding the A portion in the mixing tank and heating. When the temperature of the material in the mixing tank reaches 50 °C, add part B to the mixing tank, continue to heat the material to 80 °C, until the material in the mixing tank is completely dissolved, then add part C in the mixing tank, stir evenly, The material in the mixing tank is cooled to 58 V, and finally the D part is added, and then evenly stirred, and poured into a mold at a temperature of not lower than 53 ° C.
其中， 根据不同的要求， 可选用不同香味的香精。  Among them, according to different requirements, different flavors of fragrance can be selected.
本发明的去污膏为固体形态， 既环保又卫生。 在 25°C下配成 1 重％的溶液时？11值 10.5， 与同类产品相比， 产品质量好， 去污而 不褪色。 且甘油和乙二醇具有润肤的作用， 所以使用该去污膏时， 不会伤手。 该去污膏不仅适用于服装厂、 纺织厂、 袜厂和干洗店， 还适合家庭使用， 特别是男士的衬衣领、 小孩的脏衣服、 原子笔的 污渍， 以及抽油烟机的油渍、 机修人员的脏衣服和运动服， 还有木 家属、 金属、 塑料的表面以及血渍的衣服。 The decontamination paste of the present invention is in a solid form and is environmentally friendly and hygienic. When formulating a 1% by weight solution at 25 ° C? 11 value 10.5, compared with similar products, the product quality is good, decontamination without fading. And glycerin and ethylene glycol have an emollient effect, so when the decontamination paste is used, it does not hurt the hand. The decontamination cream is not only suitable for garment factories, textile mills, socks factories and dry cleaners. Also suitable for home use, especially men's shirt collars, children's dirty clothes, ballpoint stains, as well as range hood grease, mechanics' dirty clothes and sportswear, as well as wood, metal, plastic surfaces and blood stains Clothes.
使用该去污膏去除污渍的方法为： 属于衣物类的最好不浸水， 先把去污膏涂在有污渍的衣物上， 等 3-5 分钟后再用洗衣机洗， 手 洗的效果会更佳。 如清洗抽油烟机， 则先把布浸湿， 再把去污膏涂 在湿布上， 再去擦抽油烟机， 一般可达到清洁光亮； 如果抽油烟机 由于长时间没有清理而污渍太厚时， 可在污渍上面直接涂上去污膏， 一会儿抽油烟机上的污渍就会变得干巴巴的， 再用小刀刻掉污渍， 然后再用去污膏涂在湿布上擦洗抽油烟机， 抽油烟机就会干净光亮。 本发明的实施例 下面通过实施例进一步描述本发明：  The method of using the decontamination cream to remove stains is as follows: It is best not to soak the water in the clothing category. First apply the decontamination cream to the stained clothing, and then wash it in the washing machine after 3-5 minutes. The hand washing effect will be better. . If the range hood is cleaned, first wet the cloth, then apply the decontamination paste on the wet cloth, and then wipe the range hood, generally to achieve clean light; if the range hood is not cleaned for a long time and the stain is too thick You can apply the decontamination cream directly on the stains. After a while, the stains on the range hood will become dry. Then use a knife to cut off the stains, then apply the decontamination paste on the wet cloth to scrub the range hood. The machine will be clean and bright. EXAMPLES OF THE INVENTION The invention is further described below by way of examples:
实施例 1  Example 1
首先在常温常压下， 以去污膏总重量为基准将 21 %水和 16 %乙 二醇混合成 A部分， 21 % TX-10和 21 %皂粒混合成 B部分， 18 %甘 油和 1 %三乙醇胺混合成 C部分， 1 %乙醇和 1 %柠檬香精混合成 D 部分； 然后在搅拌桶里加入 Α部分并加热， 当搅拌桶里物料温度到 达 50°C时再在搅拌桶里加入 B部分， 继续加热物料至 80 °C， 直到搅 拌桶里物料完全溶解， 再在搅拌桶里加入 C部分， 搅拌均匀后， 将 搅拌桶里物料降温到 58 °C， 最后加入 D部分， 再搅拌均匀， 在不低 于 53 °C时灌入模具中成型即得到固体去污膏。  First, at room temperature and pressure, 21% water and 16% ethylene glycol are mixed into Part A based on the total weight of the decontamination paste. 21% TX-10 and 21% soap particles are mixed into Part B, 18% glycerin and 1 % triethanolamine is mixed into part C, 1% ethanol and 1% lemon flavor are mixed into part D; then the crucible portion is added to the mixing tank and heated, and when the temperature of the material in the mixing tank reaches 50 °C, B is added to the mixing tank. Part, continue to heat the material to 80 °C until the material in the mixing tank is completely dissolved, then add part C to the mixing tank, stir evenly, then cool the material in the mixing tank to 58 °C, and finally add part D, then stir evenly. , when it is not less than 53 °C, it is poured into the mold to form a solid decontamination paste.
实施例 2  Example 2
对实施例 1 制得的固体去污膏的理化指标进行测定： 其中总活 性物按 GB/T 13173.2测定； PH值按 GB/T 6368测定， 测定时以 1 %样品的水溶液为标准液进行； 测定去污比值时， 将固体去污膏均 匀擦在标准污染布上， 至污染布湿透， 5min后， 浸入标准洗衣粉溶 液中， 按 GB/T 13174-2003 规定的程序和方法进行测定， 并计算去 污比值， 其中标准洗衣粉溶液的浓度为 0.1%。测定理化指标见表 1 由表 1可知， 该固体去污膏质量好， 不伤手且去污力强。 The physical and chemical indicators of the solid decontamination paste prepared in Example 1 were determined: wherein the total active substance was determined according to GB/T 13173.2; the PH value was determined according to GB/T 6368, and the measurement was carried out with an aqueous solution of 1% sample as a standard solution; When determining the decontamination ratio, the solid decontamination paste is evenly rubbed on the standard contaminated cloth until the contaminated cloth is soaked. After 5 minutes, it is immersed in the standard washing powder solution and measured according to the procedures and methods specified in GB/T 13174-2003. And calculate The pollution ratio, wherein the concentration of the standard laundry detergent solution is 0.1%. The physical and chemical indicators are shown in Table 1. It can be seen from Table 1 that the solid decontamination paste has good quality, does not hurt the hand and has strong detergency.
表 1 理化指标  Table 1 Physical and chemical indicators
项目 指标  Project indicator
总活性物， ％ 30  Total active, % 30
pH值 （1%溶液， 25°C ) ^10.5  pH (1% solution, 25 ° C) ^10.5
去污比值 ^1.2  Decontamination ratio ^1.2

Claims

权 利 要 求 书 Claims
1、 一种固体去污膏， 其特征在于该去污膏由 A， B, C和 D 四 部分组成， A部分由水和乙二醇组成， B部分由 TX-10和皂粒组成， C 部分由甘油和三乙醇胺组成， D 部分由乙醇和香精组成， 其中 TX-10 为壬基酚聚氧乙烯醚； 以去污膏总重量为基准， 各组分所占 的重量百分比为： A solid decontamination paste, characterized in that the decontamination paste consists of four parts A, B, C and D, part A consists of water and ethylene glycol, and part B consists of TX-10 and soap particles, C Part of the composition consists of glycerol and triethanolamine, part D consists of ethanol and flavor, wherein TX-10 is nonylphenol ethoxylate; based on the total weight of the decontamination paste, the weight percentage of each component is:
纯水 10% -60%  Pure water 10% -60%
乙二醇 1% -30%  Ethylene glycol 1% -30%
TX-10 1% - 40%  TX-10 1% - 40%
皂粒 15%— 35%  Soap particles 15% - 35%
甘油 0.01% -40%  Glycerin 0.01% -40%
三乙醇胺 0.01% -3%  Triethanolamine 0.01% -3%
乙醇 其中以去污膏总重量为基  Ethanol, based on the total weight of the decontamination paste
21% twenty one%
乙二醇 16%  Ethylene glycol 16%
TX-10 21%  TX-10 21%
皂粒 21%  Soap particles 21%
甘油 18%  Glycerin 18%
三乙醇胺 1%  Triethanolamine 1%
乙醇 1%  Ethanol 1%
1%。  1%.
3、 权利要求 1或 2所述的固体去污膏的制备方法， 首先根据各 组分在固体去污膏中的重量百分比于常温常压下混合配制 A、 B、 C 和 D部分， 然后在搅拌桶里加入 A部分并加热， 当搅拌桶里物料温 度到达 50°C时再在搅拌桶里加入 B部分， 继续加热物料至 80°C， 直 到搅拌桶里物料完全溶解， 再在搅拌桶里加入 C部分， 搅拌均匀后， 将搅拌桶里物料降温到 58°C， 最后加入 D部分， 再搅拌均匀， 在不 低于 53°C时灌入模具中成型即可。 3. The method for preparing a solid detergent according to claim 1 or 2, wherein the components A, B, C and D are firstly mixed according to the weight percentage of each component in the solid detergent paste at normal temperature and pressure, and then Add part A to the mixing tank and heat it. When the temperature of the material in the mixing tank reaches 50 °C, add part B to the mixing tank and continue heating the material to 80 °C. Into the mixing tank, the material is completely dissolved, then add the C part in the mixing tank. After stirring evenly, the material in the mixing tank is cooled to 58 °C, and finally the D part is added, and then evenly stirred, and poured at not lower than 53 °C. It can be molded into the mold.
PCT/CN2006/002515 2006-08-28 2006-09-25 A solid detergent paste and its preparation method WO2008028342A1 (en)

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CN102586044B (en) * 2011-12-30 2013-08-07 黎宗和 Natural plant environment-friendly and rapid decontamination paste and preparation method of paste body thereof
CN110055145A (en) * 2019-05-17 2019-07-26 余凤军 A kind of crystallite laundry soap

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