WO2007116426A1 - Piston for cold chamber die-casting machine - Google Patents
Piston for cold chamber die-casting machine Download PDFInfo
- Publication number
- WO2007116426A1 WO2007116426A1 PCT/IT2007/000255 IT2007000255W WO2007116426A1 WO 2007116426 A1 WO2007116426 A1 WO 2007116426A1 IT 2007000255 W IT2007000255 W IT 2007000255W WO 2007116426 A1 WO2007116426 A1 WO 2007116426A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- piston
- band
- piston according
- head
- sealing band
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D17/00—Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
- B22D17/20—Accessories: Details
- B22D17/2015—Means for forcing the molten metal into the die
- B22D17/203—Injection pistons
Definitions
- the present invention relates to die-casting machines and in particular it refers to a piston of a press for cold chamber die-casting.
- EP1197279 by the same applicant, describes a piston for cold chamber die-casting machines which comprises a steel body having a head with or without peripheral chamfer and at least one copper alloy sealing band arranged about the body in a respective seat obtained in retracted position relative to the head, and wherein on the outer piston surface comprised between the head and the band there are obtained at least two channels intended for placing the piston head in communication with the annular seat of the band for metal inflow underneath the band itself.
- the metal that flows into the seat creates a continuous thickening that radially pushes the band outwards, progressively recovering the wear thereof, adapting it to any deformations of the piston container and therefore protecting the latter.
- sealing band tends to rotate on the piston making the operation thereof less effective.
- all sealing bands have a split or interruption shaped as a step along the circumference that allows assembling the band on the piston and ensures certain radial expansion thereof. Especially in the assembly step, when the band is released, the elasticity thereof could cause settling in an unsuitable position that impairs the sealing thereof.
- the band split should not be: [0007] - facing the top side of the container, where fused aluminium exhibits greater fluidity (in fact, aluminium lays by gravity on the bottom portion, remaining in contact with the surface of the container and of the piston head for longer, losing a few temperature degrees) ; [0008] - at the starting points of the casting branches, where metal at the liquid state has greater fluidity, [0009] - at the mechanical interference points that could occur at the container openings (liquid metal loading inlet and casting channel starting points) . [0010] In an attempt to obviating such disadvantage, a piston having a radial pin and a sealing band has been proposed, which at the step-wise split or interruption exhibits a seat suitable for receiving said pin.
- the object of the present invention therefore is to propose a piston for cold chamber die-casting machines, which should allow obviating the disadvantage mentioned above in a safe and effective manner.
- Another object of the invention is to provide a piston provided with means suitable for locking the sealing band in axial and angular direction at the same time.
- Figure 1 shows an exploded view of the piston according to the invention
- figure 2 shows the assembled piston
- figure 3 shows a partial axial section view of the piston,-
- figure 4 shows an embodiment variation of the piston
- figure 5 shows a perspective view of the piston of figure 4 in a retracted position relative to the container of a press
- figure 6 shows the piston of figure 4 in a forward position in the container;
- figure 7 shows an axial section view of the piston in another embodiment;
- figure 7a shows an enlarged view of the circled detail in figure 7;
- figure 7b shows an exploded perspective view of the piston of figure 7;
- figures 8 and 8a show an axial section and an exploded perspective view of a piston in another embodiment ;
- figures 9 and 9a show an axial section and an exploded perspective view of a piston in another embodiment ;
- figures 10, 10a and 10b show an axial section, a front view and an exploded perspective view of a piston in another embodiment
- figures 11 and 11a show an axial section and an exploded perspective view of a piston in another embodiment
- figures 12 and 12a show an axial section and an exploded perspective view of a piston in a further embodiment
- figures 13 and 13a show an axial section and an exploded perspective view of a piston in another embodiment
- figures 14 and 14a show an axial section and an exploded perspective view of a piston in a further embodiment
- figures 15 and 15b show an axial section and an exploded perspective view of a piston in another embodiment ;
- figure 15a shows an enlarged view of the circled detail in figure 15;
- figures 16 and 16b show an axial section and an exploded perspective view of a piston in another embodiment ; and [0035] figure 16a shows an enlarged view of the circled detail in figure 16.
- Piston 10, 110 denote a piston having a cylindrical body 11, 111, preferably of steel. The body ends at the front, or on the side pushing the fused metal, with a head 11', 111' .
- Piston 10, 110 slides inside a container 60 of a press of a die-casting machine. Considering piston and container arranged horizontally, container 60 has, obtained in a top portion 2 and at an end thereof, an inlet 1 for loading the metal at the liquid state, for example aluminium. At the opposite end relative to inlet 1, container 60 has splits 3 corresponding to starting points of the casting branches.
- said body 11 is mounted on a support plug 12.
- Plug 12 exhibits a front portion 13 of smaller diameter so that between it and body 11 there is defined a cooling chamber 14.
- Plug 12 is axially crossed by a duct 15 for a cooling fluid. Said duct 15 leads into chamber 14 through radial channels 15' .
- a copper pad 50 that contributes to increasing the cooling of said head 11' , which is the piston portion that overheats more during use.
- On the front portion of the piston body 11, in the proximity of head 11' there is mounted at least one sealing band 16, preferably of copper alloy.
- each sealing band 16 and the piston comprise connecting means suitable for concurrently making an axial and angular locking of each band to the piston body 11.
- At least two openings 17 are obtained in band 16 wherein respective radial projections 18 that extend from the piston body 11 engage.
- said openings 17 are shaped as slots and each radial projection 18 is configured as a circular sector.
- openings 17, and as a consequence the piston projections 18, are arranged symmetrically relative to the main axis X of the band and of the piston.
- N is the number (greater than or equal to, two) of the openings and of the relevant projections
- openings 17 are through openings .
- projections 18 have a height not more than the band thickness, so as to not protrude from said openings and thus damage the container wherein piston 10 slides.
- each opening 17 has a greater passage section than the cross section of projections 18. On the one side this facilitates the assembly and the expansion of the band following the penetration of metal thereunder; on the other side, it allows the excess liquid metal to escape through the openings of the band preventing the latter from being removed.
- slots 17 have curved end portions 17' not occupied by the respective projections 18, which on the other hand have a substantially rectangular section.
- piston 10 is provided with a single sealing band 16 that extends starting from an annular stop shoulder 20 up to head 11' of body 11. Said stop shoulder 20 axially constrains band 16 during the forward movement of the piston. The axial locking of the band during the piston roll-back on the other hand, is guaranteed by the interaction between projections 18 and openings 17.
- piston 110 is provided with two sealing bands 116, 116' located in respective seats 120, 120' obtained around body 111.
- bands 116, 116' are axially and angularly locked to body 111 by the coupling between radial projections 18 and openings 17.
- Head 111' of body 111 has a peripheral chamfer.
- the piston body 111 comprised between head 111' and the band 116 that is closer thereto there are obtained at least two channels 160 that connect the bottom of seat 120 of the band to head 111' of the piston body.
- the fused metal can flow into seat 120 under band 116, so as to create a continuous thickening that compensates the thinning of the band due to the wear thereof as a consequence of the piston use and of the thermal deformations of the container thereof.
- the piston therefore, keeps the seal and the efficiency longer irrespective of the level of wear of the copper alloy band.
- Bands 16, 116, 116' have respective splits or interruptions 19, for example step-wise, suitable for allowing the band assembly on the piston body and, especially in the case of the embodiment described in figure 4, the expansion thereof subsequent to the inflow of the liquid metal into the seat under the band.
- the piston body 11 has, in the proximity of head 11', an annular channel 30. Such annular channel 30 is covered by the sealing band 16 when this is not fitted on body 11.
- channel 30 is to hold any metal that could introduce between band 16 and body 11, creating a thickening under band 16 when the metal solidifies that contributes to keeping the band seal on the walls of container 60 unchanged.
- the sealing band 16 does not end at the level of head 11' of the piston body 11, but remains in retracted position.
- band 16 links to head 11' by a conical surface 33.
- conical surface 33 is inclined by 45° relative to the piston axis.
- Such embodiment solution allows lightening the feedhead thanks to the presence of a head 11' -33 of the piston that protrudes from the sealing band 16; moreover, the presence of such protruding head favours the detachment of the feedhead itself from the piston and protects the band from the heat produced by the metal at the liquid state.
- band 16 has a symmetry relative to a cross axis, besides the main axis.
- openings 17 are obtained in intermediate position relative to the longitudinal extension of the band. This allows mounting the band on body 11 without distinction on both ends and, advantageously, reversing the band orientation when the portion thereof facing the piston head is worn.
- the piston body 11 has a concave head 11' .
- Such configuration of the head in the first place allows relieving the pressures exerted by the metal in the container towards the piston axis, thereby relieving the pressure on the peripheral zone where the sealing band is; in the second place, it has been proved that the feedhead separation is facilitated.
- the piston illustrated in figures 10, 10a and 10b is similar to that of figure 4, since it comprises a band 16 retracted relative to a truncated-cone head 111' of the piston body 111, and a plurality of radial channels 160 obtained on the side surface of said head 111' .
- band 16 is not seated in a special seat communicating with channels 160, but is held into position only by the coupling between projections 18 and slots 17.
- the metal that solidifies under the band tends to compensate the wear thereof radially pushing it and keeping it always adhering to the container wall .
- the sealing band 216 and the piston body 211 have, along the axial direction, two orders of slots 17 and projections 18 for further increasing the axial and angular locking of the band.
- the piston of figures 12 and 12a comprises, liked that shown in figure 4, two parallel sealing bands 16, 316, front and back respectively.
- the back band 316 is mounted in a relevant seat 316' obtained in the support plug 12, rather than on body 11. This allows further spacing the two bands and thereby increasing the piston coaxiality relative to the container chamber and the guide effect of the bands .
- Such configuration is especially suitable for vacuum die-casting.
- the sealing band 16 is seated in a seat 420 obtained in retracted position relative to head 411' of the piston body 411.
- body 411 has a cylindrical end portion 411" that along with the most retracted band 16, contributes to sealing on the wall of the chamber of container 60. This can be obtained by making such cylindrical end portion 411" with a tolerance lower than the fluidity of metal at the liquid state (that in the case of aluminium is about one tenth) .
- the piston body 11 is mounted on a plug 112 with simplified structure, without the reduced diameter portion 13.
- the plug portion 112 is crossed by the cooling duct 15 that extends up in the proximity of the piston head.
- Such plug structure 112 can be used in particular for reduced diameters, where there are no particular cooling problems.
- projections 518, 618 of the piston body 511, 611 are shaped as fitted blocks fixed to the body, not integral therewith.
- blocks 518 are removably connected to body 511 by screws 518' .
- Each block 518 has a seating recess for the screw head 518' , so that this does not protrude at the level of the sealing band 16.
- each block 518 is seated in a respective seat 518" obtained in the piston body 511. At least at the level of the holes for screws 518', the latter may have an increased thickness zone .
- the sealing band 616 is shaped as a cap that covers not only the side cylindrical surface of body 611, but also head 611' .
- the cap simulates the effect of a copper piston that for certain applications and in certain conditions, is preferable to a steel piston with copper sealing band.
- cap 616 is obtained by spinning so as to be more resistant than a cap made by extrusion.
- the embodiment with fitted blocks 518, 618 is particularly suitable for the use of the closed cap band 616 since it is possible to first axially fit band 616 on the piston body, and then the locking blocks are applied.
- the cap band 616 may be applied to the piston also in a different way, for example by screwing, mechanical deformation, etc.
- the system for locking the sealing bands on the piston proposed herein allows choosing and maintaining the optimum position of the band based on the features of the machine and of the die.
- the points wherein the liquid metal exhibits the greater fluidity- are known, for example zones 1, 2 and 3 of container 60 at the inlet, at the top side and at the starting points of the casting branches, respectively, it is possible to arrange the band so that the step-wise split thereof 19 is far from said points, for example in zones 4 and 5 indicated in figures 5 and 6.
- the sealing band width is at least equal to the width, measured in axial direction, of splits 3 of the casting branches. In this way, in fact, the metal into the feedhead does not reach the piston portion upstream of the band and this is therefore prevented from getting damaged or even removed from the piston.
- the axial and angular locking of the band is not localised in a single point but is distributed along the piston and the band circumference, and is therefore solid and safe, and is obtained by the same coupling means between the piston body and the band.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Pistons, Piston Rings, And Cylinders (AREA)
- Clamps And Clips (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07736759A EP2007536B1 (en) | 2006-04-12 | 2007-04-04 | Piston for cold chamber die-casting machine |
| JP2009504898A JP5370146B2 (ja) | 2006-04-12 | 2007-04-04 | コールドチャンバーのダイカストマシーン用ピストン |
| AT07736759T ATE453473T1 (de) | 2006-04-12 | 2007-04-04 | Kolben für eine kaltkammer-druckgiessmaschine |
| DE602007004095T DE602007004095D1 (https=) | 2006-04-12 | 2007-04-04 | |
| CA2648762A CA2648762C (en) | 2006-04-12 | 2007-04-04 | Piston for cold chamber die-casting machine |
| US12/245,987 US7900552B2 (en) | 2006-04-12 | 2008-10-06 | Piston for cold chamber die-casting machine |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000087A ITBS20060087A1 (it) | 2006-04-12 | 2006-04-12 | Pistone per macchine per la pressofusione a camera fredda |
| ITBS2006A000087 | 2006-04-12 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US12/245,987 Continuation US7900552B2 (en) | 2006-04-12 | 2008-10-06 | Piston for cold chamber die-casting machine |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2007116426A1 true WO2007116426A1 (en) | 2007-10-18 |
Family
ID=38377292
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/IT2007/000255 Ceased WO2007116426A1 (en) | 2006-04-12 | 2007-04-04 | Piston for cold chamber die-casting machine |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7900552B2 (https=) |
| EP (1) | EP2007536B1 (https=) |
| JP (1) | JP5370146B2 (https=) |
| CN (1) | CN101421062A (https=) |
| AT (1) | ATE453473T1 (https=) |
| CA (1) | CA2648762C (https=) |
| DE (1) | DE602007004095D1 (https=) |
| IT (1) | ITBS20060087A1 (https=) |
| RU (1) | RU2431543C2 (https=) |
| WO (1) | WO2007116426A1 (https=) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009125437A1 (en) * | 2008-04-08 | 2009-10-15 | Copromec S.R.L. | Piston for cold chamber die-casting machines |
| WO2009146568A1 (de) * | 2008-06-05 | 2009-12-10 | Mueller Andre | Giesskolben zum einsetzen in einer giesskammer |
| ITMI20090058A1 (it) * | 2009-01-21 | 2010-07-22 | Brondolin S P A | Pistone e anello di tenuta per pressofusione |
| JP2012515656A (ja) * | 2009-01-21 | 2012-07-12 | ブロンドリン エス ピー エー | ダイカスト用の冷却式ピストン |
| ITBS20110095A1 (it) * | 2011-06-28 | 2012-12-29 | Copromec S R L | Pistone per una macchina per la pressofusione |
| WO2014161101A1 (en) * | 2013-04-04 | 2014-10-09 | Murselaj Gani | Piston for metal die casting |
| WO2018042309A1 (en) * | 2016-08-29 | 2018-03-08 | COPROMEC DIE CASTING S.r.l. A SOCIO UNICO | Piston for die-casting machine |
| IT202000031472A1 (it) | 2020-12-18 | 2022-06-18 | Copromec Die Casting S R L A Socio Unico | Testa e pistone lubrificato |
| IT202300010818A1 (it) * | 2023-05-29 | 2024-11-29 | Copromec Die Casting S R L A Socio Unico | Testa e pistone lubrificato |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX350918B (es) * | 2012-04-20 | 2017-09-25 | Cpr Suisse S A | Pistón para máquinas de fundición a presión de cámara fría. |
| US20130284018A1 (en) * | 2012-04-30 | 2013-10-31 | Brett Tennar | Screw-on annular rings for die cast beryllium copper plunger tips |
| SI24339A (sl) | 2013-04-24 | 2014-10-30 | Hts Ic D.O.O. | Bat z optimalno hladilno efektivnostjo za hladno-komorne tlačno-livne sisteme |
| JP2016533271A (ja) | 2013-10-18 | 2016-10-27 | エクスコ テクノロジーズ リミテッドExco Technologies Limited | ダイカストピストンのための摩耗リング、摩耗リングを組み込んだダイカストピストン、及び、摩耗リングを形成する方法 |
| US20150136560A1 (en) * | 2015-01-27 | 2015-05-21 | Caterpillar Inc. | Hydraulic piston system |
| IT201600087839A1 (it) * | 2016-08-29 | 2018-03-01 | Cpr Suisse S A | Pistone per una macchina per la pressofusione |
| WO2018119517A1 (en) | 2016-12-30 | 2018-07-05 | Exco Technologies Limited | Die-casting piston, and die-casting apparatus incorporating same |
| CN107138705B (zh) * | 2017-06-27 | 2023-06-06 | 重庆市铸佑机械有限公司 | 可变径高密封压射装置 |
| RU2757575C1 (ru) * | 2020-12-14 | 2021-10-18 | Кожокин Тимофей Иванович | Поршневой узел машины литья под давлением |
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| US4886107A (en) * | 1986-02-28 | 1989-12-12 | Zecman Kenneth P | Piston for cold chamber |
| US5048592A (en) * | 1989-10-18 | 1991-09-17 | Allper Ag | Plunger for a diecasting machine |
| EP1197279A2 (en) * | 2000-10-13 | 2002-04-17 | Copromec S.r.l. | Cold chamber die-casting piston |
| WO2003074214A1 (de) * | 2002-03-04 | 2003-09-12 | Allper Ag | Dichtring und kolben für einen druckgiesszylinder |
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| JP2002181010A (ja) * | 2000-12-13 | 2002-06-26 | Mitsubishi Heavy Ind Ltd | 油圧機器のシールリング |
| DE10356396B4 (de) * | 2003-12-03 | 2005-09-01 | Danfoss Compressors Gmbh | Kolbenanordnung |
-
2006
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-
2007
- 2007-04-04 AT AT07736759T patent/ATE453473T1/de not_active IP Right Cessation
- 2007-04-04 WO PCT/IT2007/000255 patent/WO2007116426A1/en not_active Ceased
- 2007-04-04 CN CNA2007800128997A patent/CN101421062A/zh active Pending
- 2007-04-04 JP JP2009504898A patent/JP5370146B2/ja not_active Expired - Fee Related
- 2007-04-04 RU RU2008144577/02A patent/RU2431543C2/ru not_active IP Right Cessation
- 2007-04-04 DE DE602007004095T patent/DE602007004095D1/de active Active
- 2007-04-04 EP EP07736759A patent/EP2007536B1/en active Active
- 2007-04-04 CA CA2648762A patent/CA2648762C/en not_active Expired - Fee Related
-
2008
- 2008-10-06 US US12/245,987 patent/US7900552B2/en active Active - Reinstated
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5768257A (en) * | 1980-10-17 | 1982-04-26 | Toyota Motor Corp | Injector for die casting |
| US4886107A (en) * | 1986-02-28 | 1989-12-12 | Zecman Kenneth P | Piston for cold chamber |
| US5048592A (en) * | 1989-10-18 | 1991-09-17 | Allper Ag | Plunger for a diecasting machine |
| EP1197279A2 (en) * | 2000-10-13 | 2002-04-17 | Copromec S.r.l. | Cold chamber die-casting piston |
| WO2003074214A1 (de) * | 2002-03-04 | 2003-09-12 | Allper Ag | Dichtring und kolben für einen druckgiesszylinder |
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009125437A1 (en) * | 2008-04-08 | 2009-10-15 | Copromec S.R.L. | Piston for cold chamber die-casting machines |
| WO2009146568A1 (de) * | 2008-06-05 | 2009-12-10 | Mueller Andre | Giesskolben zum einsetzen in einer giesskammer |
| US9550233B2 (en) | 2009-01-21 | 2017-01-24 | Brondolin S.P.A. | Die casting cooled pistons |
| ITMI20090058A1 (it) * | 2009-01-21 | 2010-07-22 | Brondolin S P A | Pistone e anello di tenuta per pressofusione |
| KR20110132333A (ko) * | 2009-01-21 | 2011-12-07 | 브론돌린 에스.피.에이. | 다이 캐스팅 피스톤 및 링 조립체 |
| CN102325613A (zh) * | 2009-01-21 | 2012-01-18 | 布龙多林股份有限公司 | 模铸活塞与环的组件 |
| JP2012515655A (ja) * | 2009-01-21 | 2012-07-12 | ブロンドリン エス ピー エー | ダイカスト用のピストンおよびリングの組立体 |
| JP2012515656A (ja) * | 2009-01-21 | 2012-07-12 | ブロンドリン エス ピー エー | ダイカスト用の冷却式ピストン |
| WO2010084449A1 (en) * | 2009-01-21 | 2010-07-29 | Brondolin S.P.A. | Die casting piston and ring assembly |
| US9829108B2 (en) | 2009-01-21 | 2017-11-28 | Brondolin S.P.A. | Die casting piston and ring assembly |
| KR101757483B1 (ko) * | 2009-01-21 | 2017-07-12 | 브론돌린 에스.피.에이. | 다이 캐스팅 냉각 피스톤 |
| US8931395B2 (en) | 2009-01-21 | 2015-01-13 | Brondolin S.P.A. | Die casting piston and ring assembly |
| KR101719829B1 (ko) * | 2009-01-21 | 2017-03-24 | 브론돌린 에스.피.에이. | 다이 캐스팅 피스톤 및 링 조립체 |
| ITBS20110095A1 (it) * | 2011-06-28 | 2012-12-29 | Copromec S R L | Pistone per una macchina per la pressofusione |
| US9523430B2 (en) | 2011-06-28 | 2016-12-20 | COPROMEC DIE CASTING S.r.l. A SOCIO UNICO | Piston for a die-casting machine |
| RU2589647C2 (ru) * | 2011-06-28 | 2016-07-10 | Копромек Ди Кастинг С.Р.Л. А Сочо Унико | Плунжер машины для литья под давлением |
| WO2013001469A1 (en) | 2011-06-28 | 2013-01-03 | COPROMEC DIE CASTING S.r.l. A SOCIO UNICO | Piston for a die-casting machine |
| US9463505B2 (en) | 2013-04-04 | 2016-10-11 | Gani MURSELAJ | Piston for metal die casting |
| WO2014161101A1 (en) * | 2013-04-04 | 2014-10-09 | Murselaj Gani | Piston for metal die casting |
| WO2018042309A1 (en) * | 2016-08-29 | 2018-03-08 | COPROMEC DIE CASTING S.r.l. A SOCIO UNICO | Piston for die-casting machine |
| IT202000031472A1 (it) | 2020-12-18 | 2022-06-18 | Copromec Die Casting S R L A Socio Unico | Testa e pistone lubrificato |
| IT202300010818A1 (it) * | 2023-05-29 | 2024-11-29 | Copromec Die Casting S R L A Socio Unico | Testa e pistone lubrificato |
| WO2024246678A1 (en) * | 2023-05-29 | 2024-12-05 | COPROMEC DIE CASTING S.r.l. A SOCIO UNICO | Lubricated head and piston |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101421062A (zh) | 2009-04-29 |
| EP2007536A1 (en) | 2008-12-31 |
| JP5370146B2 (ja) | 2013-12-18 |
| JP2009533226A (ja) | 2009-09-17 |
| CA2648762A1 (en) | 2007-10-18 |
| DE602007004095D1 (https=) | 2010-02-11 |
| ATE453473T1 (de) | 2010-01-15 |
| US20090071326A1 (en) | 2009-03-19 |
| CA2648762C (en) | 2014-02-18 |
| US7900552B2 (en) | 2011-03-08 |
| RU2008144577A (ru) | 2010-05-20 |
| RU2431543C2 (ru) | 2011-10-20 |
| EP2007536B1 (en) | 2009-12-30 |
| ITBS20060087A1 (it) | 2007-10-13 |
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