WO2007111002A1 - High-formability aluminum material - Google Patents
High-formability aluminum material Download PDFInfo
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- WO2007111002A1 WO2007111002A1 PCT/JP2006/323861 JP2006323861W WO2007111002A1 WO 2007111002 A1 WO2007111002 A1 WO 2007111002A1 JP 2006323861 W JP2006323861 W JP 2006323861W WO 2007111002 A1 WO2007111002 A1 WO 2007111002A1
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- crystal grains
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- aluminum material
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Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/05—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys of the Al-Si-Mg type, i.e. containing silicon and magnesium in approximately equal proportions
Definitions
- the present invention relates to an aluminum material, and in particular, to high hem bendability required at the time of assembling automobile body sheets, automobile parts, machine parts, and plate formability such as press forming at the time of body formation or housing formation. It relates to an excellent aluminum material.
- Aluminium such as body seats, is advancing in automobiles, and the outer material is excellent in beta-hardness (property that precipitates and hardens when heated during paint baking), and has high strength after paint baking.
- —Mg— Si-based aluminum alloys are often used, and 5000 (A1-Mg) aluminum alloys with excellent drawability are used for the inner material.
- This outer material with 6000 series aluminum alloy strength is a force 6000 series (A1 Mg-S engagement metal plate) that is required to have excellent bending cacheability called hem bending, which is usually caulked with the inner material.
- the hem bendability is inferior, and in particular, in the case of a material solution-treated at a high temperature in order to increase the beta hardness, there is a problem that this hem bendability is remarkably inferior.
- the outer material of this 6000 series aluminum alloy is required to have a good press formability, which is a kind of plate forming, with few restrictions for determining the design of an automobile.
- the press formability is generally inferior to that of conventional steel plates and 5000 series aluminum alloy plates, and improvements are desired in order to integrate the materials used in consideration of the problem of recycling automobile parts.
- a method of controlling the surface hardness of the aluminum alloy plate for example, see Patent Document 1
- a method of controlling the crystal grain size and the precipitate size for example, see Patent Documents 2 and 3
- a method for controlling the crystal orientation of the aluminum alloy plate surface see, for example, Patent Documents 4 and 5
- a method for controlling the crystal orientation of the entire aluminum alloy plate see, for example, Patent Document 6)
- Aluminum alloy surface force a method of controlling the bending workability by controlling the crystal orientation up to a certain depth (for example, see Patent Document 7). It has been proposed.
- Patent Document 1 Japanese Unexamined Patent Publication No. 2003-129201
- Patent Document 2 Japanese Unexamined Patent Publication No. 2003-221637
- Patent Document 3 Japanese Unexamined Patent Publication No. 2003-268472
- Patent Document 4 Japanese Unexamined Patent Publication No. 2003-226926
- Patent Document 5 Japanese Unexamined Patent Publication No. 2003-226927
- Patent Document 6 Japanese Unexamined Patent Publication No. 2003-268475
- Patent Document 7 Japanese Unexamined Patent Application Publication No. 2004-27253
- Patent Document 9 JP 2004-10982 A Patent Document 10: Japanese Patent Laid-Open No. 2003-105473
- Non-Patent Document 1 Eiji Nakamachi, Yoshinori Hamada: Plasticity and Processing, 39-446 (1998), 252.
- Non-Patent Document 2 Hideo Morimoto, Eiji Nakamachi: Furukawa Electric Times, 103 (1999), 7.
- the present inventors have studied the influence of the crystal orientation distribution of crystal grains on hem bendability and plate formability. As a result, the present inventors can achieve both hem bendability and plate formability at a high level. Invented.
- An object of the present invention is to provide an aluminum material that can achieve both a high degree of hem bendability and sheet formability.
- the texture of a rolled sheet is expressed by the relationship between the rolling surface of the sheet and the rolling direction ((ABC) and DEF>) (A, B, C, D, E, and F represent integers).
- ABSC rolling surface of the sheet
- DEF rolling direction
- A, B, C, D, E, and F represent integers.
- the Cube orientation is the (100) ⁇ 001> orientation
- the Brass orientation is the (011) ⁇ 211> orientation
- the Copper orientation is the (112) ⁇ 111> orientation. Since the actual orientation of the plate material deviates from the ideal orientations of the Cube orientation, Brass orientation, and Copper orientation, each crystal is based on the ideal orientation of each crystal of the Cube orientation, Brass orientation, and Copper orientation. It is assumed that crystal orientations up to 5 ° from the ideal orientation are also included in Cube orientation, Brass orientation, and Copper orientation, respectively.
- An aluminum material composed of crystal grains having different crystal orientations wherein the crystal grain is composed of 1S Cube orientation crystal grains, Brass orientation crystal grains, Copper orientation crystal grains, and the balance is the other crystal grains.
- the crystal grain occupancy is 0.3 force, 0.7, and brass orientation.
- Grain occupancy is 0.1 force 0.5
- copper orientation occupancy is 0.2 or less
- total occupancy in these orientations is 0.4 to 1.0
- the balance Is an aluminum material characterized by being grains of other crystal orientations,
- the plate has a formability that does not cause cracks on the surface at an overhang height of 30 mm, and does not cause cracks on the bending surface in hem bendability. In the ratio
- the above-mentioned Noreminicum material strength Mg is 0.25 force, etc. 1.0 mass%, Si is 0.5 force, etc. 1.3 mass s%, and is an aluminum alloy composed of the balance A1 and inevitable impurities.
- Noreminicum material force Mg: 0.25 force, etc. 1.0 mass%, Si: 0.5 force, etc. 1.3 mass s%, Cu, Zn, Mn: less than lmass%, Fe: 0.40 mass % Or less, Ti, Cr 0.lmass%
- Noreminicum material strength Mg 0.40 force, etc. 1. Omass%, Si 0.5 force, etc. 1.3 mass s%, Cu, Mn lmass% or less, ZnO. 3 mass% or less, Fe Of (1) to (5) above, characterized in that it is an aluminum alloy that contains Ti and Cr in an amount of 0.220 mass% or less, Ti and Cr in an amount of less than 0.1 lmass%, and the balance Al and inevitable impurities.
- FIG. 1 Fig. 1 (a) to Fig. 1 (c) are diagrams schematically showing the hem bending workability test method performed in Example 1, and Fig. 1 (a) is a sample material.
- Fig. 1 (b) shows punch indentation, and
- Fig. 1 (c) shows tight bending (tightening) by vise.
- the present invention relates to the Cube orientation among the crystal orientations indicated by the crystal grains constituting the aluminum material.
- a material that satisfies both high-level bending such as hem bending and plate molding such as body press molding at a high level.
- the occupancy ratio of Cube orientation crystal grains is 0.3 to 0.7
- the occupancy ratio of Brass orientation crystal grains is 0.1 to 0.5
- the occupancy ratio of Copper orientation crystal grains is 0.2 or less.
- it exhibits good bendability and plate formability when compared with aluminum materials that satisfy a total occupancy ratio of Cube orientation, Brass orientation, and Copper orientation of 0.4 force 1.0.
- the relationship between the occupancy of each crystal orientation of the crystal grains constituting the aluminum material and both characteristics is described below.
- the crystal orientation density of Cube orientation crystal grains has a large effect on the heme bending, and as the crystal orientation density becomes higher than the crystal orientation density of random orientation grain, It is known that hem bending is good. Also in the present invention, it is preferable to increase the occupancy ratio of the crystal grains having the Cube orientation in order to improve the hem bending. However, an increase in the Cube-oriented crystal grain occupancy results in a significant loss of plate formability.
- the range of the occupation ratio is preferably 0.3 to 0.7, and more preferably 0.4 to 0.6.
- the lower limit of this range practically sufficient hem bendability can be provided, and in the upper limit, sufficient plate formability can be maintained to perform press molding of the body sheet to the car exterior.
- the plate formability is improved as opposed to the case where the occupancy ratio of the brass orientation crystal grains is high and the occupancy ratio of the Cube orientation crystal grains is high.
- the influence of brass-oriented grains on hem bendability was unknown, and the influence of the occupation rate was unknown.
- the occupancy ratio range is 0.1 to 0.5, preferably 0.2 to 0.4.
- the Cube-oriented crystal grain occupancy range by setting the brass-oriented crystal grain occupancy ratio to 0.1 to 0.5, both hem bending and plate forming can be obtained at a high level. . If the material is out of this range, either hem bending or plate forming will be superior, or both will be at a low level.
- the occupation ratio of copper-oriented crystal grains is 0.2 or less, preferably 0.05-0.15, and more preferably 0.05-0.1.
- the reason for this limitation is that the copper-oriented crystal grains are known to have the same function as the brass-oriented crystal grains for plate forming. Oriented grain force It has been found that the presence of the above-mentioned occupancy ratio has the effect of raising both the hem bendability and the plate forming level. It is expected that it will work as a cushioning material!
- an aluminum plate for measurement in this case an aluminum plate with a predetermined thickness (for example, lmm), degrease the surface with an oil cleaning material such as acetone, and then apply an oxide layer suitable for the material of the aluminum plate.
- An aluminum plate from which the surface of the acid oxide layer has been removed using a remover for example, aqua regia for an aluminum alloy
- a remover for example, aqua regia for an aluminum alloy
- the crystal orientation of the crystal grains is measured by an electron backscatter diffraction pattern (hereinafter abbreviated as EBSP).
- EBSP electron backscatter diffraction pattern
- the measurement is performed in a thermionic emission scanning electron microscope, each crystal orientation of the crystal grains in the unit area is measured, and when the number of all crystal grains in the unit area is 1, the Cu be orientation with respect to that
- the ratio of the number of crystal grains in the brass orientation and the copper orientation was determined, and the value was taken as the occupation ratio. For example: 1. If the total number of grains in the Omm square is 100, the total number of grains in the Cube, Brass, and Copper orientations is 100 (that is, there are no grains in other crystal orientations). ), The total occupancy (total occupancy) of each crystal grain in Cube orientation, Brass orientation and Copper orientation is 1.
- the aluminum material according to the present invention exhibits a good bendability and plate formability at the occupancy ratio of the crystal orientation because the crystal structure is a face-centered cubic structure.
- Materials with a face-centered cubic structure include A1 alloys, Cu alloys, Ni alloys, Ag alloys, and Au alloys, but the A1 alloys exhibit remarkable effects.
- the A1 alloy includes Mg of 0.25 force, 1. Omass%, Si of 0.5 force, 1.3 mass%, and the balance of A1 and inevitable impurities. Show a big effect Is preferable.
- Si and Mg contained as essential elements in this Al-Mg-Si alloy are Mg Si composites.
- the amount may be greatly reduced, causing a decrease in bending workability and beta-hardness.
- the lower limit value of Mg is preferably set to 0.40% or more.
- Cu, Zn, Mn, Cr, Ti, or the like may be added. Addition of Cu enhances strength, ductility, degreasing, chemical conversion, etc. Additive of Zn improves degreasing and chemical conversion, and additive of Mn, Ti, Cr refines crystal grains. It shows the action of improving the bending strength, but when these elements are added excessively, the corrosion resistance and ductility are lowered.
- the addition of Cu and Zn has no practical problem as long as any element is within the range of lmass% or less, but considering the balance between strength, ductility, degreasing, chemical conversion treatment, corrosion resistance and ductility.
- the upper limit can be appropriately determined to a level below lmass%.
- Zn to 0.3 mass% or less.
- the amount of added Mn, Cr, and Ti that promotes refinement of crystal grains and improves bending strength must be less than lmass% for Mn, and less than 0.1 lmass% for Ti and Cr. It is preferable to make it.
- Fe contained as an impurity forms a crystallized product that is harder than the Mg Si compound.
- the amount of Fe is preferably set to 0.40 mass% or less, and more preferably 0.20 mass% or less, because a large strain is formed in the periphery to promote the propagation of cracks.
- V, Zr, etc. can be included in the range of 0.20 mass% or less as necessary for the purpose of grain refinement. If the amount of V and Zr added is in the range of 0.20 mass% or less, there will be no effect on the plate formability such as hem bendability and press formability, but in consideration of corrosion resistance and ductility, it will be 0.1 lmass% or less. Preferably there is.
- An aluminum material excellent in formability can be provided.
- the Al alloy consisting of the remaining Al is melted and cast in a 500 mm thick ingot by a conventional method, and this ingot is subjected to homogenization treatment at 540 ° C for 6 hours, after which the start temperature is 500 ° C and the end temperature is 200 ° C A hot rolled sheet having a thickness of 10 mm was obtained by hot rolling below.
- this hot-rolled sheet was cold-rolled to a predetermined thickness such that a finished base sheet having a thickness of 1 mm was obtained at a finishing rate of 20%, 30%, 50%, 70%, and 90%.
- a finished blank having a thickness of 1 mm was obtained directly from a hot rolled sheet having a thickness of 10 mm.
- this cold-rolled sheet having a predetermined thickness was annealed at 325 ° C. for 2 hours and subjected to finish cold-rolling to produce a finished base sheet having a thickness of 1 mm.
- the finished base plate was subjected to a solution treatment at 500 ° C using a continuous annealing furnace and a stabilization treatment at 100 ° C for 24 hours to obtain a test material.
- Specimen No. 1 listed in Table 1 was finish-rolled at a finish cold work rate of 20%.
- No. 2 is 30%
- No. 3 is 50%
- No. 4 is 70. %
- No. 5 is 80%
- each crystal orientation includes crystal orientations 5 degrees apart from the ideal orientation of each crystal in the Cube orientation, Brass orientation, and Copper orientation.
- a 180 ° C bending test and a stretch forming test were performed using the prepared test materials, and the hem bending workability and the plate formability were evaluated.
- Fig. 1 (a) the pre-strain is applied in Fig. 1 (a), the punch is pushed in up to a bending angle of 170 degrees in Fig. 1 (b), and the vise tightening shown in Fig. 1 (c) is performed in order.
- ° C Bending Karoe test punch 1 tip curvature R was changed to 0.25, 0.5, 0.75, 1.0 mm. The test was repeated for each tip curvature with the number of tests of 5 sheets, and the minimum value of the tip curvature at which no rough skin and cracking occurred was recorded in the column of hem bending workability in Table 1. Therefore, in this test, rough skin and cracks do not occur! / If the tip curvature is small! /, The hem bending calorie is excellent.
- Table 1 shows all specimens with no cracks as “ ⁇ ”, specimens with only one crack as “ ⁇ ”, and specimens with two or more cracks as “X” in Table 1. .
- the strength and elongation of the specimens prepared were excluding the specimens with a finish cold working rate of 90%, and the strength was 230-240MPa, 0.2% strength 30-140MPa, and the elongation was More than 30%.
- the specimen with a finish cold work rate of 90% had the same strength and 0.2% resistance as the other specimens, but the elongation was as low as 17%.
- Example 1 the same materials as in Example 1 were used, except that only the Fe content was changed to 0.25 mass%, and the Fe content was changed to 0.25 mass% and the Cu content was changed to 0.15 mass%.
- the same materials were produced in the process, both obtained excellent results satisfying the item (7).
- V and Zr were added to the material of Example 1 with 0.1 and 15 mass% added, and V and Zr were both added with 0.08 mass% in the same process as Example 1.
- the aluminum material of the present invention is excellent in hem bendability and plate formability, it can be suitably used for automobile body sheets, automobile parts, machine parts, and the like.
Abstract
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JP2007535737A JP4158944B2 (en) | 2005-04-19 | 2006-11-29 | High formability aluminum material |
US12/294,833 US20100247369A1 (en) | 2005-04-19 | 2006-11-29 | Aluminum material with high formability |
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JP2006-90454 | 2006-03-29 | ||
JP2006090454A JP2006322064A (en) | 2005-04-19 | 2006-03-29 | High moldability aluminum material |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008144279A (en) * | 2008-02-01 | 2008-06-26 | Furukawa Electric Co Ltd:The | Aluminum material having high moldability |
WO2013093686A1 (en) | 2011-12-20 | 2013-06-27 | Koninklijke Philips Electronics N.V. | Apparatus and method for monitoring a sleeping person |
CN113927973A (en) * | 2021-09-30 | 2022-01-14 | 江西睿捷新材料科技有限公司 | External packing material for high-depth-of-penetration battery device |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002079533A1 (en) * | 2001-03-28 | 2002-10-10 | Sumitomo Light Metal Industries, Ltd. | Aluminum alloy sheet excellent in formability and hardenability during baking of coating and method for production thereof |
JP2003268475A (en) * | 2002-03-12 | 2003-09-25 | Sky Alum Co Ltd | Aluminum alloy sheet for forming, and manufacturing method therefor |
JP2005139530A (en) * | 2003-11-10 | 2005-06-02 | Furukawa Sky Kk | Method of producing aluminum alloy sheet for forming |
JP2005256053A (en) * | 2004-03-10 | 2005-09-22 | Kobe Steel Ltd | Aluminum alloy sheet having excellent bending workability and press formability |
JP2005273003A (en) * | 2004-03-22 | 2005-10-06 | Hyundai Motor Co Ltd | Production method of aluminum-magnesium-silicon alloy sheet suitable for flat hemming |
JP2006219763A (en) * | 1998-09-02 | 2006-08-24 | Kobe Steel Ltd | Al-Mg BASED ALLOY SHEET WITH GOOD PRESS FORMABILITY |
JP2006257506A (en) * | 2005-03-17 | 2006-09-28 | Kobe Steel Ltd | Aluminum alloy sheet having excellent extension flange formability and bending workability and method for producing the same |
JP2006322064A (en) * | 2005-04-19 | 2006-11-30 | Furukawa Electric Co Ltd:The | High moldability aluminum material |
-
2006
- 2006-11-29 WO PCT/JP2006/323861 patent/WO2007111002A1/en active Application Filing
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006219763A (en) * | 1998-09-02 | 2006-08-24 | Kobe Steel Ltd | Al-Mg BASED ALLOY SHEET WITH GOOD PRESS FORMABILITY |
WO2002079533A1 (en) * | 2001-03-28 | 2002-10-10 | Sumitomo Light Metal Industries, Ltd. | Aluminum alloy sheet excellent in formability and hardenability during baking of coating and method for production thereof |
JP2003268475A (en) * | 2002-03-12 | 2003-09-25 | Sky Alum Co Ltd | Aluminum alloy sheet for forming, and manufacturing method therefor |
JP2005139530A (en) * | 2003-11-10 | 2005-06-02 | Furukawa Sky Kk | Method of producing aluminum alloy sheet for forming |
JP2005256053A (en) * | 2004-03-10 | 2005-09-22 | Kobe Steel Ltd | Aluminum alloy sheet having excellent bending workability and press formability |
JP2005273003A (en) * | 2004-03-22 | 2005-10-06 | Hyundai Motor Co Ltd | Production method of aluminum-magnesium-silicon alloy sheet suitable for flat hemming |
JP2006257506A (en) * | 2005-03-17 | 2006-09-28 | Kobe Steel Ltd | Aluminum alloy sheet having excellent extension flange formability and bending workability and method for producing the same |
JP2006322064A (en) * | 2005-04-19 | 2006-11-30 | Furukawa Electric Co Ltd:The | High moldability aluminum material |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008144279A (en) * | 2008-02-01 | 2008-06-26 | Furukawa Electric Co Ltd:The | Aluminum material having high moldability |
WO2013093686A1 (en) | 2011-12-20 | 2013-06-27 | Koninklijke Philips Electronics N.V. | Apparatus and method for monitoring a sleeping person |
CN113927973A (en) * | 2021-09-30 | 2022-01-14 | 江西睿捷新材料科技有限公司 | External packing material for high-depth-of-penetration battery device |
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