Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
  • B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
  • B65H19/00—Changing the web roll
  • B65H19/10—Changing the web roll in unwinding mechanisms or in connection with unwinding operations
  • B65H19/102—Preparing the leading end of the replacement web before splicing operation; Adhesive arrangements on leading end of replacement web; Tabs and adhesive tapes for splicing
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J7/00—Adhesives in the form of films or foils
  • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
  • C09J7/29—Laminated material
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J7/00—Adhesives in the form of films or foils
  • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
  • C09J7/38—Pressure-sensitive adhesives [PSA]
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
  • C09J2203/342—Applications of adhesives in processes or use of adhesives in the form of films or foils for flying splice applications
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2301/00—Additional features of adhesives in the form of films or foils
  • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
  • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
  • C09J2301/124—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
  • C09J2301/1242—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape the opposite adhesive layers being different
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2301/00—Additional features of adhesives in the form of films or foils
  • C09J2301/20—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
  • C09J2301/204—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive coating being discontinuous
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2301/00—Additional features of adhesives in the form of films or foils
  • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
  • C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2421/00—Presence of unspecified rubber
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2433/00—Presence of (meth)acrylic polymer
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J2453/00—Presence of block copolymer
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/14—Layer or component removable to expose adhesive
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/14—Layer or component removable to expose adhesive
  • Y10T428/1462—Polymer derived from material having at least one acrylic or alkacrylic group or the nitrile or amide derivative thereof [e.g., acrylamide, acrylate ester, etc.]
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/14—Layer or component removable to expose adhesive
  • Y10T428/1481—Dissimilar adhesives
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
  • Y10T428/2852—Adhesive compositions
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
  • Y10T428/2852—Adhesive compositions
  • Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
  • Y10T428/2852—Adhesive compositions
  • Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
  • Y10T428/2883—Adhesive compositions including addition polymer from unsaturated monomer including addition polymer of diene monomer [e.g., SBR, SIS, etc.]
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
  • Y10T428/2852—Adhesive compositions
  • Y10T428/2878—Adhesive compositions including addition polymer from unsaturated monomer
  • Y10T428/2891—Adhesive compositions including addition polymer from unsaturated monomer including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof

Definitions

• the invention relates to an adhesive tape for the flying role change of unpolar flat web material wound on rolls according to the features of the preamble of the main claim and to a method for the flying reel change of unpolar flat web material wound on reels.
• the flying reel change is a common method to replace an old, almost unwound roll with a new role, without having to stop the fast-running machine for it.
• pressure-sensitive adhesive tapes are often used to connect the end of the old web to the beginning of the new web.
• flying reel change also called “dynamic reel change”
• dynamic reel change takes place in the film and nonwoven processing industry for materials with nonpolar surfaces according to two different methods.
• a single-sided self-adhesive tape is overlapped and glued in a straight line under the free end of the top sheet of the new role, so that the adhesive side faces outward and is only partially covered by the new web.
• the exposed part of the outwardly facing adhesive side is glued to the web of the old roll.
• the above method is also used in the paper processing industry.
• the splicing method (splicing method), in which the fixing serving for fixing is integrally formed in the self-adhesive tape connecting the paper webs.
• the splittable carrier serving as a fix splits, so that a part of the splittable carrier remains on the self-adhesive tape connecting the webs (ie on the upper winding), while the other part remains on the underlying winding.
• “Splittable” refers to those carriers which are cleavable parallel to their surface area, and in particular to those carriers which actually split in relation to the requirements in a splicing process. For the implementation of this method are in the paper processing industry quite a few
• DE 196 32 689 A2 discloses an adhesive tape which, in addition to the main carrier, is equipped with a splittable paper carrier. In the dynamic loads when connecting the webs of both roles splits the
• the object of the invention was therefore to provide an adhesive tape with at least one upper self-adhesive, a splittable carrier and a lower self-adhesive on the lower side of the splittable carrier, which is suitable for the flying role change at high web speeds of unpolar flat web material wound on rolls ,
• an adhesive tape which is suitable for the flying roll change of flat web material wound on rolls with non-polar surfaces, in particular polyolefinic substrates, and in which the upper self-adhesive is a silicone-free self-adhesive having an adhesion to a polyethylene primer of 1 , 5 N / cm or more (measuring method tesa Test A) and a tack corresponding to a taxiway length of 200 mm or less (measuring method tesa Test D), and in which the lower self-adhesive is a self-adhesive having an adhesion to a polyethylene primer of 1, 5 N / cm or more (measuring method tesa Test A) and a complex viscosity of 10,000 Pa-s or more at 1 rad / s and 40 ° C (measuring method tesa Test F) is used. It is particularly advantageous for the flying reel change when the tack of the top self-adhesive composition
• the upper self-adhesive is used in the splicing process to connect the top of the adhesive tape according to the invention with the web start of the new role and with the almost unwound web of the old role, whereby the webs of both roles are connected to each other via the tape.
• the lower self-adhesive serves to connect the underside of the adhesive tape according to the invention with the second uppermost winding, whereby the uppermost and the second uppermost winding of the new roll are first connected to one another via the adhesive tape.
• the compound of the upper two windings of the roll is separated again, in such a way that the adhesive regions of the upper self-adhesive and of the lower self-adhesive facing away from the upper side of the respective winding do not stick to the now split carrier stay covered.
• the concrete embodiment of the upper self-adhesive composition and of the lower self-adhesive composition is of crucial importance with regard to their adhesive strength, tack and viscosity.
• the choice according to the invention of the complex viscosity of the lower self-adhesive composition has the consequence that a cold flow of the lower self-adhesive composition is prevented.
• the self-adhesive on the lower side of the splittable carrier can not escape from the adhesive joint and stick to the upper side of the splittable carrier, whereby blocking of the carrier is avoided and the system continues to remain cleavable.
• the upper self-adhesive it is particularly advantageous to choose such a composition that meets the requirements for a film splicing process. It advantageously has sufficient tack to tackle non-polar materials, particularly polyolefinic substrates, in the splicing process, should not shear off from such substrates in the process, thus preferably has good shear strength thereon, and develops sufficiently good bond strengths on the polyolefinic material ,
• a polyethylene plate was used as a defined primer (adhesive plate), which was produced as a test plate by injection molding from HDPE granules Hostalen GC7260 from Basell. Before measurement, this plate was cleaned with ethanol.
• a standard polyester support having a thickness of 23 ⁇ m was coated on one side with the respective self-adhesive composition (self-adhesive composition: 50 g / m 2 ).
• a 20 mm wide strip of the coated standard polyester carrier was pressed under load (2 kg) onto the primer.
• the adhesive tape was peeled off from the substrate at a speed of 300 mm / min at an angle of 180 ° and the force required for this at room temperature was measured.
• the measured value (in N / cm) was the average of three individual measurements.
• tesa Test A a commercial test tape for testing non-adhesive coatings (type “tesa 7475" from tesa AG, bond strength to steel according to specification: 31, 25 N / 25 mm) was investigated in accordance with this measurement method; the adhesive strength determined on the polyethylene test plate was 4.5 N / cm. In some cases, comparative tests were carried out on steel instead of polyethylene with the otherwise identical experimental parameters (test A2).
• the determination of the initial tack was carried out as follows (tesa test D): The so-called rolling ball tack was measured as a measure of the initial tack with a very short contact time.
• a standard polyester support having a thickness of 23 ⁇ m of the respective self-adhesive composition was coated on one side (self-adhesive application: 50 g / m 2 ).
• An approximately 10 cm long strip of the adhesive tape was attached with the adhesive side up horizontally on the test plane.
• a sample ball of steel (diameter: 1 mm, mass: 5.6 g) was cleaned with acetone and kept in a room atmosphere for 2 h (temperature: 23 ° C +/- 1 ° C, relative humidity: 50% +/- 1 %).
• the steel ball was accelerated by descending from a 65 mm high ramp (inclination angle: 21 °) in the gravitational field of the earth. From the ramp, the steel ball was directed directly onto the adhesive surface of the sample. The distance traveled on the adhesive until the ball stopped was measured.
• the taxiway length determined in this way serves as an inverse measure of the tack of the self-adhesive (that is, the shorter the taxiway, the higher the tack and, vice versa).
• the respective measured value resulted (as length specification in mm) from the average value of five individual measurements.
• the determination of the complex viscosity was carried out as follows (tesa Test F): The particular PSA obtained was a cylindrical-round specimen with a diameter of 25 mm and a height of 0.8 mm in a deformation-controlled rheometer (type RDA IM, Rheometrics Scientific plate-plate geometry, measuring head: 2000 g Bendix) (preloaded with an axial force of 3 N). The dynamic measurement was carried out at 40 ° C in a room climate (normal conditions) and a 3% deformation of the specimen in the frequency range of 0.1 to 500 rad / s as a complex viscosity ⁇ * .
• the numerical value [in Pa-s] given as "complex viscosity" is the amount of the complex viscosity measured in the low-frequency range (1 rad / s) and at 40 ° C.
• a self-adhesive composition which has an adhesion to a polyethylene adhesion base of 3.0 N / cm or more (measurement method tesa Test A), where is particularly advantageous when the bond strength on a polyethylene adhesive base is 5.0 N / cm or more.
• This is a particularly efficient adhesion of the adhesive tape to be connected to the non-polar Flat web material achieved, which further improves the durability of the compound and thus the efficiency of the splicing process.
• a self-adhesive composition is used as the upper self-adhesive composition, which has an adhesive tack corresponding to a taxiway length of 40 mm or less (measurement method tesa Test D), and it is particularly advantageous if this rolling path length used as a measure of the tack tackiness is 20 mm or less. As a result, a particularly high efficiency in connecting the webs by merging both rotating rollers is achieved.
• an upper self-adhesive are all typical silicone-free self-adhesives for non-polar surfaces, particularly advantageously those which have a high bond strength, high tack and high cohesion, in particular acrylates, natural rubber compositions and particularly preferably adhesives based on styrene block copolymers.
• non-repulpable self-adhesive compositions are suitable here.
• Preferred upper self-adhesives are those based on block copolymers, in particular styrene block copolymers.
• copolymers are particularly suitable according to the invention, which consists of polymer blocks formed from a vinyl aromatic - particularly advantageously from styrene - (A blocks), and polymer blocks formed by polymerization of 1, 3-dienes (B blocks), such as butadiene or isoprene or a copolymer.
• Said copolymer may, for example, be one of the abovementioned compounds butadiene and isoprene.
• block copolymer blends are as a component block copolymers having a linear ABA structure.
• linear multiblock copolymers are advantageously usable.
• block copolymers of radial form and star-shaped multiblock copolymers are particularly advantageous.
• a self-adhesive composition based on a mixture of a plurality of styrene block copolymers is used as upper self-adhesive composition (1, 11), in which at least one of the copolymers is a two-block copolymer with one of the styrene-based blocks.
• Good for use according to the invention as an upper self-adhesive are, for example, diblock-containing (S ⁇ S) -styrene-isoprene-styrene copolymers with the styrene and / or diblock shares mentioned above, as for example under the trade name Europrene® SOL T-192 from the company EniChem (styrene content 25% by weight; double block coat 23% by weight) are commercially available.
• top pressure-sensitive adhesive are those adhesives which have at least one block copolymer mixture in which the styrene content is at least 25% by weight, preferably 30% by weight, and which has a diblock content of at least 40% by weight. preferably at least 60% by weight. This makes it possible in particular to realize good shear strength values.
• diblock-containing (SB) n- styrene-butadiene multiarm copolymers having the abovementioned styrene and diblock fractions, as described, for example, under the trade name Kraton® D1 118 (styrene fraction 33 ⁇ 2 Wt .-%; diblock fraction about 78% by weight It. Specification) are commercially available.
• the use concentrations for the block copolymer or the block copolymer mixture in a concentration in the range between 30 wt .-% and 70 wt .-%, in particular in the range between 35 wt .-% and 55 wt .-%, based on the PSA.
• Adhesive resins which are compatible with the elastomer block of the styrene block copolymers serve in particular as tackifiers.
• Suitable tackifier resins include, but are not limited to, non-hydrogenated or partially or fully hydrogenated rosin or rosin derivative resins, hydrogenated polymers of dicyclopentadiene, non-hydrogenated, partially, selectively or fully hydrogenated hydrocarbon resins based on C-5, C-5 / C-9 or C-9 monomer streams, or more preferably Polyterpene resins based on ⁇ -pinene and / or ⁇ -pinene and / or ⁇ -limonene.
• the aforementioned adhesive resins can be used both alone and in admixture.
• the adhesive composition particularly preferably has at least one adhesive resin that is liquid at room temperature.
• Primary antioxidants such as sterically hindered phenols
• Secondary antioxidants such as phosphites or thioethers
• process stabilizers such as C radical scavengers
• light stabilizers such as UV absorbers or sterically hindered amines
• the adhesive resins used contain a high proportion of liquid resins, in particular a proportion of at least 25 wt .-%, preferably at least 35% wt .-%, based on the total amount of resins used.
• Such a composition has a particularly favorable bond strength and tack. It is particularly advantageous if the upper self-adhesive composition has a complex viscosity of 15,000 Pa.s or more.
• the application of the upper self-adhesive composition in a range of 30 to 100 g / m 2 is selected, in particular in a range of 35 to 70 g / m 2 .
• Suitable cleavable carriers are all cleavable flat carrier materials, in particular readily cleavable papers, paper composite systems (for example duplex papers and sized paper systems), film composite systems (for example sized film systems), polymeric composite systems (for example coextruded polymeric composite systems) and polymeric nonwoven fabrics.
• a carrier is used, in which the total nip force is 5 to 70 cN / cm, in particular 12 to 60 cN / cm.
• the upper self-adhesive and the lower self-adhesive have a high bond strength.
• the bond strength of this must Self-adhesive on the respective surfaces (carrier and web material to be bonded) turn out to be greater than the force required for splitting the splittable carrier.
• a resin-modified acrylate composition is suitable.
• Such resin-modified or resin-blended compositions comprise an adhesive resin and an acrylate adhesive (partially crosslinked).
• the adhesive resins used may be the customary tackifier resins, for example terpene-phenolic resins and rosin resins.
• acrylate adhesive copolymers are used on an acrylate having a suitable glass transition temperature, in particular copolymers based on ingredients that make the total copolymer soft (for example, low molecular weight acrylates of the type C 4 to C 2, such as 2-ethylhexyl acrylate or n-butyl acrylate), and also components of which generally make the copolymer harder (for example, acrylic acid or functionalized components such as glycidyl methacrylate or hydroxyethyl methacrylate).
• both compositions are mixed.
• Crosslinking is then carried out by conventional crosslinking methods, for example as a crosslinking reaction at high temperatures or by using a suitable catalyst, for example Lewis acids such as zinc chloride.
• a self-adhesive composition having a complex viscosity of 12,000 Pa.s or more is used as the lower self-adhesive composition, in particular if 15,000 Pa.s or more.
• a resin-modified acrylate adhesive is used as the lower self-adhesive, and it is particularly advantageous if it comprises 70 to 80% by weight of acrylate adhesive and 20 to 30% by weight of adhesive resin.
• adhesive resin a terpene phenolic resin and / or acrylate as a copolymer of 48.5 wt .-% n-butyl acrylate, 48.5 wt .-% 2-ethylhexyl acrylate, 2 wt .-% glycidyl methacrylate and 1 Wt .-% acrylic acid to use.
• the upper self-adhesive composition and the lower self-adhesive composition can also be selected identically, for example as the above-resin-modified acrylate composition. In this exceptionally favorable case, the risk of blocking the splittable system is particularly low.
• the upper and lower self-adhesive compositions may, for example, also be used identically as silicone-free self-adhesive composition, in particular as described above, for example based on block copolymers.
• Adhesive composition 3 by the local upper adhesive (1, 11) and / or the local adhesive 4 are substituted by the local lower adhesive (3, 13), DE 198 41 609 A1 (prince), in particular constructions according to FIG. 1 and in Column 3, line 7 to line 37 explanatory facts, wherein the local adhesive 34 by the local upper adhesive (1, 11) and / or the local
• Adhesive composition 32 are substituted by the local lower adhesive (3, 13), US 2004/0075014 A1 (Jacobs et al.), In particular constructions according to FIG. 1 and the explanations in Sections [0049] to [0054] there adhesive 3 by the local upper adhesive (1, 11) and / or the local adhesive 2 are substituted by the local lower adhesive (3, 13), US 2005/0126688 A1 (Bean et al), in particular constructions according to FIGS.
• the adhesive tape comprises a non-splittable carrier whose upper side is coated with the upper self-adhesive and whose lower side is completely or at least partially connected to the upper side of the splittable carrier.
• a non-splittable carrier which bonds the web of the old roll to the web start of the new roll before and also after splitting of the splittable carrier, a particularly strong bond of both webs is achieved and the efficiency of the splicing process is further enhanced.
• the lower side of the non-cleavable carrier is (completely or partially) connected to the upper side of the cleavable carrier via a connecting self-adhesive (five-layer structure).
• this compound can be brought about as desired, for example with a self-adhesive composition, a thermosetting hotmelt adhesive and the like.
• the splicing process greatly increases the efficiency of bonding the web of the old roll to the web start of the new roll.
• main carrier all typical sheet-like carrier materials for adhesive tapes can be used, for example paper carriers made of one- or two-sided coated smooth base paper as well as film carriers, such as BOPP films, PET films, aluminised PET films and aluminum foils. It is desirable here that it is a tear-resistant main carrier.
• any typical self-adhesive may be used as a connective self-adhesive.
• the connecting self-adhesive composition and the lower self-adhesive composition are selected identically, for example as a resin-modified acrylate composition, since in this case the risk of blocking of the splittable system is particularly low.
• the adhesive tape therefore has a splittable carrier over the entire length of the bond and thus also over the entire length of the adhesive tape.
• the splittable carrier may extend across the entire width of the non-splittable carrier. It is favorable, however, if the width of the splittable carrier is smaller than the total width of the adhesive tape, so that only in a small part of its width a fixation with the underlying web is achieved. It is particularly advantageous in this case if the splittable carrier does not terminate flush with the non-splittable carrier, but is fastened in relation to the latter at its lower side. As a result, the risk of an occurrence of snappers is further reduced in the splicing process.
• the invention further comprises the use of the adhesive tape according to the invention for bonding flat web material wound on rolls with nonpolar surfaces in the course of a flying roll change, in particular of films and / or nonwovens.
• the adhesive tape By using the adhesive tape, the efficiency of the splicing process is significantly increased overall.
• the invention provides a splicing method for the flying roll change of unpolar flat web material wound on rolls, in particular films and / or nonwovens, wherein the adhesive tape according to the invention is pasted (at least partially) past the end of the uppermost web of a new roll of a nonpolar flat web material, while the lower side the adhesive tape is glued to the underlying web of the new role and this ensures this, whereupon the so-equipped new role next to a nearly completely unwound, replaced to be replaced role and accelerated to the same surface speed, the new role then against the top web old roll is pressed, wherein the exposed adhesive of the adhesive tape with the old web at substantially the same speeds Webs are glued, while at the same time splits the splittable system and the self-adhesive masses of the splittable system with the two cleaved remnants of the splittable carrier does not cover adhesive.
• Fig. 1 is a schematic side view of an embodiment of the adhesive tape according to the invention (three-layer structure, shown transversely to the longitudinal direction of the adhesive tape), and
• FIG 2 shows a schematic side view of a further embodiment of the adhesive tape according to the invention (five-layered structure, shown transversely to the longitudinal direction of the adhesive tape).
• Fig. 1 an inventive adhesive tape is shown, which is suitable for the flying role change of wound on rolls flat web material with non-polar surfaces.
• the adhesive tape is formed as a three-layer structure of the splittable carrier 2, which is coated on its upper side with the upper self-adhesive 1 and on its lower side with the lower self-adhesive layer 3.
• Such a structure can be used when the splittable carrier 2 along its surface extension has sufficient mechanical strength to withstand the stresses that occur when connecting the web of almost unwound roll with the web start of the new role.
• the adhesive tape additionally comprises a separating system 6 for non-adhesive covering of the upper self-adhesive 1, so that the adhesive upper side of the adhesive tape is protected during storage.
• a separation system all conventional release papers can be used, such as siliconized release papers or siliconized release films.
• the separation system can in this case be made in one or more parts (not shown in FIG. 1).
• Fig. 2 is another particularly advantageous embodiment of the invention
• Adhesive tape shown as a five-layered structure This embodiment of the adhesive tape system comprises a splittable carrier 12 and a non-splittable carrier 14 which connected to each other.
• the compound is here embodied as a separate, connecting, self-adhesive 15 which connects the upper side of the splittable carrier 12 to a part of the lower side of the non-splittable carrier 14.
• the non-splittable carrier 14 is coated on its upper side with the upper self-adhesive composition 1 1 and on a part of its lower side with the connecting self-adhesive 15, which anchors the splittable carrier 12 on the non-splittable carrier 14.
• the splittable carrier 12 is in this case indented or staggered with respect to the non-splittable carrier 14.
• the embodiment shown in FIG. 2 additionally has a separating system 16 for non-adhesive covering of the upper self-adhesive composition 1 1, for which purpose all conventional release papers can be used, for example siliconized release papers or siliconized release films.
• the two-part separation system 16a / 16b shown here which is divided longitudinally into a rear cover part 16a and a front cover part 16b, for example by means of a perforation or a slot.
• This has the advantage that the adhesive tape can first be glued to the web start of the new roll, for which only the adhesive area of the adhesive tape under the back cover portion 16a is exposed and the adhesive area for bonding to the web of the old roll through the front cover portion 16b remains covered and thus protected.
• An adhesive tape according to the invention with a width of 50 mm was produced from a machine-smooth base paper with a basis weight of 54 g / cm 2 and a thickness of 66 ⁇ m as a non-splittable carrier 14.
• the upper side of the non-splittable carrier 14 is coated with an upper self-adhesive composition 11.
• Block copolymer base used with the following composition: 48 wt .-% of a
• Styrene-butadiene-styrene block copolymer ("Kraton D1 118" from Kraton), 24% by weight of an alphapinen resin (type “Dercolyte A 1 15” from DRT, Softening point 1 15 ° C.), 27% by weight of a liquid hydrocarbon resin ("Wingtack 10" from Goodyear - liquid synthetic aliphatic C-5 polyterpene / hydrocarbon resin, softening point 10 ° C.), 0.5% by weight of a primary Antioxidant (type “Irganox 1010” from Ciba) and 0.5% by weight of a secondary antioxidant (type "Weston 339" from Interorgana).
• a primary Antioxidant type "Irganox 1010” from Ciba
• secondary antioxidant type "Weston 339" from Interorgana
• the adhesive tape also comprises the splittable carrier 12 and a lower self-adhesive composition 13 and a connecting self-adhesive composition 15.
• a splittable carrier 12 a paper having a weight per unit area of 51 g / cm 2 and a thickness of 90 ⁇ m was used.
• the width of the splittable carrier 12 was 12 mm.
• the adhesive tape has a two-part separation system 16 for non-adhesive covering of the upper self-adhesive composition 1 1, so that the adhesive upper side is protected during storage of the adhesive tape according to the invention.
• the present separation system 16 was made of siliconized release paper and includes a back cover portion 16a covering the portion of the adhesive tape which is bonded to the top layer of the web of the new roll and a front cover portion 16b covering the portion of the adhesive tape connected with the train of the old role. Both cover parts are separated by a slot which extends along the longitudinal direction of the adhesive tape.
• the terpene phenolic resin used was the product "DT1 10" from DRT.
• a copolymer of 48.5% by weight of n-butyl acrylate, 48.5% by weight of 2-ethylhexyl acrylate, 2% by weight of glycidyl methacrylate and 1% by weight of acrylic acid was used.
• the adhesive properties of the upper self-adhesive composition 11 and of the lower self-adhesive composition 13 or of the connecting self-adhesive composition 15 were investigated by determining the adhesive force of the self-adhesive compositions on a polyethylene primer (measurement method tesa Test A), their tack by means of the rolling ball tack (measurement method tesa test D) and the complex viscosities of the self-adhesive composition (measurement method tesa test F) were determined.
• the adhesive properties of the adhesive tape produced with the self-adhesive compositions 11, 13 and 15 were investigated.
• the shear strength of the adhesive tape on a polyethylene backing was determined as the shearing life (tesa Test B).
• a strip of the adhesive tape with a width of 13 mm and a length of 20 mm was applied to a previously cleaned with ethanol polyethylene test plate and pressed with constant contact pressure four times on the support.
• the adhesive tape was loaded at room temperature with 1 kg and the shearing life (in minutes) was determined as the average of three measurements.
• the relative splitting behavior of a cleavable support coated on both sides with the respective self-adhesive compositions was investigated (tesa Test C).
• the splitting behavior of a splittable carrier was used which was not coated with self-adhesive compositions.
• 12 cm long strips of the coated and uncoated support were first stored for 24 hours at 40 ° C under load (2 kg / cm 2 ).
• the carriers were pre-split to a length of 2 cm and the force required to split the carriers further at a splitting speed of 300 mm / min was measured. The test was passed if the difference in the force required for further splitting was less than 20% for the coated and uncoated substrates.
• Example 2 Several other adhesive tapes according to the invention were prepared and measured analogously to Example 1, in which the upper composition was based on the following compositions (total composition of the adhesive: 99% base adhesive, 0.5% by weight of primary antioxidant (type “Irganox 1010” from the company Ciba) and 0.5% by weight of secondary antioxidant ("Weston 339" from Interorgana) according to Example 1). Compare Table 2.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Adhesive Tapes (AREA)
• Adhesives Or Adhesive Processes (AREA)
• Materials For Medical Uses (AREA)
• Replacement Of Web Rolls (AREA)

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• 2006
  • 2006-11-10 DE DE102006053439A patent/DE102006053439A1/de not_active Withdrawn
  • 2006-11-15 PL PL06819521T patent/PL1989136T5/pl unknown
  • 2006-11-15 AT AT06819521T patent/ATE499317T1/de active
  • 2006-11-15 WO PCT/EP2006/068520 patent/WO2007096010A1/de not_active Ceased
  • 2006-11-15 JP JP2008555645A patent/JP5455376B2/ja active Active
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  • 2006-11-15 US US11/559,991 patent/US8268442B2/en active Active
  • 2006-11-15 EP EP06819521.3A patent/EP1989136B2/de active Active
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