Classifications

• • H—ELECTRICITY
  • H03—ELECTRONIC CIRCUITRY
  • H03K—PULSE TECHNIQUE
  • H03K17/00—Electronic switching or gating, i.e. not by contact-making and –breaking
  • H03K17/94—Electronic switching or gating, i.e. not by contact-making and –breaking characterised by the way in which the control signals are generated
  • H03K17/945—Proximity switches
  • H03K17/955—Proximity switches using a capacitive detector
• • H—ELECTRICITY
  • H03—ELECTRONIC CIRCUITRY
  • H03K—PULSE TECHNIQUE
  • H03K17/00—Electronic switching or gating, i.e. not by contact-making and –breaking
  • H03K17/94—Electronic switching or gating, i.e. not by contact-making and –breaking characterised by the way in which the control signals are generated
  • H03K17/96—Touch switches
  • H03K2017/9602—Touch switches characterised by the type or shape of the sensing electrodes
• • H—ELECTRICITY
  • H03—ELECTRONIC CIRCUITRY
  • H03K—PULSE TECHNIQUE
  • H03K2217/00—Indexing scheme related to electronic switching or gating, i.e. not by contact-making or -breaking covered by H03K17/00
  • H03K2217/94—Indexing scheme related to electronic switching or gating, i.e. not by contact-making or -breaking covered by H03K17/00 characterised by the way in which the control signal is generated
  • H03K2217/96—Touch switches
  • H03K2217/96015—Constructional details for touch switches

Definitions

• the present disclosure relates to a capacitive sensor film for mounting to a body, for example to detect the presence of an external object.
• the present disclosure also relates to an improved method for manufacturing such capacitive sensor films.
• Capacitive proximity sensors have been used in various industrial applications for locating the presence of objects or materials.
• Various forms of capacitive proximity sensors are known and are suitable for use in different environments and applications including, for example, touch-operated systems, collision-prevention systems, occupancy-detection systems, and security/warning systems.
• capacitive proximity sensors have been fitted, for example, with the rear side and/or bumpers of cars. When the vehicle is reversed a warning signal is provided when the car approaches an object so that a collision can be safely avoided while still allowing the driver to conveniently position the car close to such object.
• GB 2,400,666 discloses a capacitive proximity sensor comprising a substrate bearing two metal plates on its opposite major surfaces.
• the capacitive proximity sensor can be provided inside the bumper of a vehicle.
• the metal plate facing outwardly is referred to as the sensor conductor whereas the metal plate facing the car body is called the guard conductor.
• the sensor conductor is screen-printed with conductive ink onto the substrate whereas the guard conductor may be a metal strip.
• the guard conductor is typically larger than the sensor conductor and provides a shield between the sensor conductor and the car body. The change of the capacitance between the sensor conductor and ground is monitored and provides an indication of the distance between the car and an object outside of the car.
• GB 2,374,422 addresses the problem of reducing the sensitivity of a capacitive proximity sensor to very close objects that the sensor is not required to detect. Specifically, in the case of a sensor on a vehicle bumper, GB 2,374,422 addresses the problem of reducing the effect of the presence of water as caused, for example, by steady rain on the sensitivity of the capacitive proximity sensor. In one embodiment it is suggested to arrange an extra conductive plate on the major side of the substrate bearing the sensor conductor. The extra conductive plate, which can be arranged on the sensor conductor side above or below said sensor conductor or both (with respect to the level of the street), is often referred to as superguard conductor.
• an amplified guard signal is applied to the superguard conductor which has the effect of making the guard appear bigger.
• the superguard conductor is effective in attenuating or minimizing capacitance changes resulting from drips of water running across the front of the sensor.
• a capacitive proximity sensor comprising a superguard conductor is also disclosed in GB 2,404,443.
• the guard conductor acts as a shield to reduce the sensitivity of the sensor conductor and, if present, the superguard conductor to anything behind it in the direction of the body. Therefore the dimensions of the guard conductor are typically chosen to exceed those of the sensor conductor and, if present, of the superguard conductor.
• GB 2,400,666 discloses, for example, a capacitive sensor film wherein the guard conductor is formed by an aluminium strip which preferably fully covers the rear major surface of the substrate.
• the dimensional extension may be an important design criterion their geometrical shape usually is less critical. Contrary to this, the zones of the sensor conductor and, if present, of the superguard conductor, are typically smaller than that of the substrate whereas their respective sensitivity may depend on their geometrical shape.
• GB 2,348,505 discloses, for example, a sensor conductor geometry where the end regions of such conductor may be wider than its central region. This tends to improve the sensitivity of the capacitive proximity sensor at the corners of the vehicle.
• the co-pending European patent application No. 06001149.1 with the title "Proximity sensor and method for manufacturing the same" which was filed by the present applicant on January 19, 2006 discloses a sensor conductor comprising a sequence of strips essentially extending in the longitudinal direction of the substrate.
• the strips may be formed by optionally flattened metal wires or strips of a metal foil.
• the strips may be arranged essentially parallel to each other whereby another strip is preferably provided in a transverse direction to electrically connect the strips or wires in the longitudinal direction.
• This sensor design has an especially advantageous sensitivity.
• the present disclosure provides a capacitive sensor film which does not exhibit the shortcomings of the state-of-the-art devices or exhibits them to a low degree only, respectively.
• the present disclosure provides capacitive sensor films comprising alternative and/or improved designs of the sensor conductor and/or the superguard conductor.
• the present disclosure provides a method of manufacturing capacitive sensor films which allows for providing a broad variability of designs and geometries of the sensor conductor and the superguard conductor.
• the present disclosure relates to a capacitive sensor film for mounting to a body, said film comprising a dielectric backing layer having, on one side, a rear major surface facing, in use, the body and, on the other side, a front major surface, a sensor conductor on the front major surface, and a guard conductor on at least one of the major surfaces to provide an electrical shield for the sensor conductor; said front major surface bearing a front conductor at least partly surrounding the sensor conductor, against which the sensor conductor is electrically isolated by zones where the front conductor is removed and the front major surface of the backing layer or another layer beneath the front conductor is exposed.
• the present disclosure furthermore relates to a method of manufacturing a capacitive sensor film comprising
• the present disclosure furthermore relates to another method of manufacturing a capacitive sensor film comprising
• the present disclosure furthermore relates more particularly, although not exclusively, to the use of the capacitive sensor film of the present invention for automotive applications.
• Figs. 1 and Ia show top views of two embodiments of a capacitive sensor film 50 according to some embodiments of the present disclosure.
• Figs. 2 and 2a are cross-sectional views of two different embodiments of the capacitive sensor film 50 of Fig. Ia along the line A — A indicated in Fig. Ia.
• Figs. 3a — 3c show the top view of the left part of the capacitive sensor film 50 of Fig. Ia additionally comprising two through-going holes 10 applied in the connector zones 8 of the superguard conductor 5 and the top-most strip of the sensor conductor 7, respectively.
• Figs. 4 is a cross-sectional view of the capacitive sensor film 50 of Fig. 3c along the line
• Fig. 5 is the cross-sectional view of the capacitive sensor film 50 of Fig. 4 additionally comprising two protective layers 16, 17.
• Fig. 6 is the top view of a capacitive sensor film 50 similar to the embodiment of Fig. 3c which comprises a further through-going hole 10.
• Fig. 6 ⁇ is a cross-sectional view, of the capacitive sensor film 50 of Fig. 6 along the line
• Fig. 7 is a cross-sectional view of another capacitive sensor film.
• film refers to an article having an extension in two directions which exceeds the extension in a third direction, which is essentially normal to said two directions, by a factor of at least 5 and more preferably by at least 10. More generally, the term “film” is used herein to refer to a flexible sheet-like material, and includes sheetings, foils, strips, laminates, ribbons and the like.
• electrically isolating refers to materials having a specific bulk resistivity as measured according to ASTM D 257 of at least 1 x 10 12 Ohm # centimeter ( ⁇ cm) and more preferably of at least 1 x 10 13 ⁇ cm.
• electrically conductive refers to materials having a surface resistivity as measured according to ASTM B 193-01 of less than 1 Ohm per square centimeter ( ⁇ /cm 2 ).
• the capacitive sensor film 50 comprises an electrically isolating backing layer 2 bearing on one of its major surfaces 2a a guard conductor 1 and on its opposite major surface 2b a front conductor 4 in which is defined a sensor conductor 7 (and, optionally, a superguard conductor 5). As described below, the sensor conductor 7 is electrically-isolated from the surrounding front conductor 4 (as is the superguard conductor 5, when present).
• the backing layer 2 is preferably continuous and, in some embodiments, has a thickness of between 20 — 200 ⁇ m and, in some embodiments, of between 25 — 150 ⁇ m.
• Suitable backing materials include, e. g., polymeric films and layers, paper films and layers, layers of non-wovens, laminates (such as, for example, polyacrylate foams laminated on both sides with polyolefin films, and papers laminated or jig-welded with polyethylene terephthalate) and combinations thereof.
• Useful polymeric films and layers include, for example, polyolefin polymers, monoaxially oriented polypropylene (MOPP), biaxially oriented polypropylene (BOPP), simultaneously biaxially oriented polypropylene (SBOPP), polyethylene, copolymers of polypropylene and polyethylene, polyvinylchloride, copolymers having a predominant olefin monomer which may be optionally chlorinated or fluorinated, polyester polymers, polycarbonate polymers, polymethacrylate polymers, cellulose acetate, polyester (e. g. biaxially oriented polyethylene terephthalate), vinyl acetates, and combinations thereof.
• Useful backings also include surface modified backings modified by, e. g., plasma discharge techniques including corona discharge treatment and flame treatment, mechanical roughening and chemical primers.
• the guard conductor 1 comprises an electrically conductive material that, in some embodiments, includes one or more metals which are applied as a layer or a film to one of the major surfaces of the backing layer 2.
• the guard conductor 1 comprises an aluminium layer.
• the guard conductor may be formed, for example, by a metal film which is bonded to such major surface of the backing layer 2 with an adhesive layer 3 such as, for example, a pressure-sensitive adhesive layer.
• the guard conductor 1 may also be directly applied to such major surface of the backing layer 2, for example, by vacuum metal vapour deposition.
• the thickness of the guard conductor 1 may vary widely depending on the method of manufacturing it.
• a guard conductor layer 1 obtained by vacuum metal vapour deposition may be as thin as 200 — 800 Angstroms (A) and, in some embodiments, 300 — 500 A.
• an aluminium film or foil it may have a thickness of from 1 - 50 micrometers ( ⁇ m), in some embodiments, 2 - 30 ⁇ m and, in some embodiments, 3 - 15 ⁇ m.
• the front conductor 4 can optionally be electrically connected with the guard conductor 1.
• Fig. 6a shows a cross-sectional view of the capacitive sensor film of Fig. 6 along line C — C indicated in Fig. 6. It can be taken from the cross-sectional view of Fig. 6a that a through-going hole 10 has been applied extending from the front major surface of the front conductor 4 through the capacitive sensor film 50 to the rear major surface of the guard conductor 1.
• a strip of an auxiliary connector adhesive tape 12 comprising, for example, a metal film backing 15 and an electrically conductive pressure- sensitive adhesive 14 is attached to the front conductor 4 so that it covers the through- going hole 10.
• the through-going hole 10 is then filled with a conductive ink electrically connecting the front conductor 4 and the guard conductor 1 so that these can be contacted from the rear major surface of the capacitive sensor film 50.
• the guard conductor 1 can be connected to the front conductor 4 via the electrically conductive adhesive strip 12, rather than directly.
• the guard conductor 1 which is optionally connected to the front conductor 4 acts as a shield to reduce the sensitivity of the sensor conductor 7 to anything behind it in the direction of the body.
• the sensor conductor 7 detects objects that are generally outward of the vehicle but is substantially less sensitive and, preferably, substantially blind towards the inside of the vehicle. Therefore the dimensions of the guard conductor 1 or, optionally, the joint dimensions of the guard conductor 1 and the front conductor 4 if these are electrically connected, may be chosen to match at least those of the sensor conductor 7 but, in some embodiments, the dimensions of the guard conductor 1 or, optionally, the joint dimensions of the guard conductor 1 and the front conductor 4 exceed at least partly those of the sensor conductor 7.
• the guard conductor 1 essentially fully covers the major side of the backing layer 2 it is attached to as is shown, for example, in Fig. 2.
• the guard conductor 1 is electrically connected to the front conductor 4 so that the combination of the guard conductor 1 and the front conductor 4 essentially fully matches the dimensional extension of the backing layer 2 as is shown, for example, in Fig. 2a.
• the front conductor 4 comprises an electrically conductive material and, in some embodiments, one or more metals.
• the front conductor 4 comprises a relatively cheap material such as an aluminium layer which may be applied by vacuum metal vapour deposition or as an aluminium film or foil which can be bonded to the backing 2, for example, by an adhesive layer such as, for example, a pressure-sensitive adhesive layer.
• the front conductor 4 comprises a copper layer which can be applied, for example, by vacuum metal vapour deposition or as an adhesively bonded copper film or foil.
• the thickness of the front conductor 4 may vary widely depending on the method of manufacturing it.
• Front conductors comprising metal films such as, for example, an aluminium foil may have a thickness of from 1 — 50 ⁇ m, in some embodiments, 2 — 30 ⁇ m and, in some embodiments, 3 — 15 ⁇ m.
• Front conductors 4 obtained by vacuum metal vapour deposition may be as thin as 200 - 800 A and, in some embodiments, 300 — 500 A.
• the sensor conductor 7 is formed by removing the front conductor 4 in zones at least partly surrounding the sensor conductor to an extent sufficient to electrically isolating the sensor conductor 7 from the front conductor 4. In some cases the front conductor 4 may completely surround the sensor conductor 7 as is shown, for example, in the embodiment of Fig.
• the black lines represent the removed portions of the front conductor 4 i. e. the front conductor 4 fully covers the front major surface 2b of the backing layer 2 prior to the formation of the sensor conductor.
• the front conductor 4 may only partly surround the sensor conductor 7.
• the front conductor 4 comprises a metal layer which is directly applied, for example, by means of vacuum metal vapour deposition onto the front major surface 2b of the backing layer 2, removal of the front conductor 4 will preferably result in exposing the front major surface 2b in said zones as is schematically illustrated, for example, in Figs. 1 and 2.
• the front conductor 4 comprises a metal film or foil which is applied to the front major surface 2b of the backing layer 2 (for example, by means of an adhesive layer), removal of the front conductor 4 will preferably result in exposing the adhesive layer 3 and/or the front major surface 2b in said zones.
• other layers arranged beneath the front conductor 4 may be exposed.
• the capacitive sensor film 50 may, as already mentioned, additionally comprise a superguard conductor 5 which may be arranged on the surface of the backing 2 bearing the sensor conductor 7 with a view to reducing the sensitivity of the sensor to very close objects that the sensor is not required to detect.
• a superguard conductor 5 which may be arranged on the surface of the backing 2 bearing the sensor conductor 7 with a view to reducing the sensitivity of the sensor to very close objects that the sensor is not required to detect.
• an amplified guard signal may be applied to the superguard conductor 5 which has the effect of making the guard appear bigger.
• this may be effective in automotive applications when the proximity sensor 50 is assembled, for example in the rear-side bumper of a car, to minimize the effect of water drips running down in rainy weather conditions across the bumper, on the signal of the sensor conductor 7.
• the superguard conductor 5 may be arranged — relative to the road level — above or below the sensor conductor.
• the superguard conductor 5 may be formed by removing the front conductor 4 in zones at least partly surrounding the superguard conductor 5 to an extent sufficient to reliably electrically isolate the superguard conductor 5 from the front conductor 4.
• the superguard conductor 5 may be arranged outside the zone of the sensor conductor 7 but may in some cases also be arranged within the zone of the sensor conductor 7. In such case, the superguard conductor 5 may be formed by removing the sensor conductor 7 in zones at least partly surrounding the superguard conductor 5 to an extent to electrically isolate the superguard conductor 5 from both the sensor conductor and the front conductor 4.
• the front conductor 4 may completely surround the superguard conductor 5 as is shown, for example, in the embodiment of Fig. 1 where the black lines represent the removed portions of the front conductor 4 i. e. the front conductor 4 fully covers the front major surface 2b of the backing layer 2 prior to the formation of the superguard, and sensor, conductors.
• the front conductor 4 for example, covers only part of the front major surface 2b of the backing layer 2 or where the superguard conductor 5 is arranged at an edge of the front conductor 4, the front conductor 4 may only partly surround the superguard conductor 5.
• the superguard conductor 5 is formed within the sensor conductor 7, the sensor conductor 7 may completely or partly surround the superguard conductor 5.
• front conductor 4 and/or the sensor conductor 7 comprise a metal layer which is directly applied, for example, by means of vacuum metal vapour deposition onto the front major surface 2b of the backing layer 2, removal of the front conductor 4 and/or the sensor conductor 7 will result in exposing the front major surface 2b in said zones as is schematically illustrated, for example, in Fig. 1 and 2.
• the front conductor 4 and/or the sensor conductor 7 comprise a metal film or foil which is applied to the front major surface 2b of the backing layer 2, for example by means of an adhesive layer, removal of the front conductor 4 may result in exposing the adhesive layer and/or the front major surface 2b in said zones.
• other layers arranged beneath the front conductor 4 may be exposed.
• the sensor conductor 7 and, if present, the superguard conductor 5 both comprise an electrically conductive material. Since the sensor conductor 7 and the superguard conductor 5 are preferably formed within the front conductor 4 by removing zones of the front conductor 4 at least partly surrounding said sensor conductor 7 and superguard conductor 5, the material comprised by the sensor conductor 7 and the superguard conductor 5 preferably corresponds to the material comprised by the front conductor 4.
• the sensor conductor 7 and the superguard conductor 5 may be formed by separate part zones of the front conductor 4 so that the material and the thickness of the sensor conductor 7 and the superguard conductor 5 correspond to that of the front conductor 4.
• zones which are removed from the front conductor 4 and, if the superguard conductor 5 is formed within the sensor conductor 7, from the sensor conductor 7, and which are surrounding the sensor conductor 7 and, if present, the superguard conductor 5 may exhibit various dimensions and shapes.
• such zones are elongate channels having a width of at least 5 ⁇ m, in some embodiments, between 5-50 ⁇ m and, in some embodiments, between 10-40 ⁇ m.
• the depth of the channels corresponds at least to the thickness of the front conductor 4 but typically exceeds such thickness, for example, by at least 1 % in order to reliably isolate the sensor conductor 7 and the superguard conductor 5 against each other and against the front conductor 4.
• Such channels which are also referred to above and below as void lines, at least partly surround the sensor conductor 7 and, if present, the superguard conductor 5 thereby defining the geometry of such conductors.
• the zones may be essentially linear but curved and/or polygonic shapes, combinations of these or more complicated shapes are also possible. Any such shapes are easily accessible within the present type of construction, which therefore allows to improve and/or tailor-make the sensitivity to the capacitive sensor film to an extent not available so far.
• the guard conductor 1 on the rear surface of the 2b of the backing layer 2 is omitted and the function of the guard conductor is provided by the front conductor 4 in combination with a conductive layer applied over the sensor and superguard conductors.
• a film 50' of that type is shown in Fig. 7.
• the sensor and superguard conductors have the same configuration as in Figs. 1 and 2, and are indicated by the same reference numerals (7, 5).
• the front conductor, now functioning as part of the guard conductor, is indicated by the reference numeral 1'.
• the remainder of the guard conductor comprises a conductive layer 53 applied over the sensor and superguard conductors 1, 5 and electrically-isolated therefrom by a dielectric layer 52.
• the conductive layer 53 contacts, and is electrically-connected to, the front conductor 1' in the region surrounding the sensor and superguard conductors 7, 5.
• the adhesive layer 3 on the rear major surface 2b of the backing layer 2 is used to attach the sensor film to a surface in a desired location and, prior to use, is protected by a release liner 51.
• a protective film (not shown) may be applied over the other face of the sensor film, if required.
• the removal of the front conductor 4 in the zones at least partly surrounding the sensor conductor 7 can be accomplished by several methods.
• the front conductor 4 is removed in said zones by laser ablation.
• this method utilizes diode-pumped or lamp-pumped solid-state lasers such as, for exam ⁇ le s Nd: YAG, Nd:YVO 4 , Nd:GdVO 4 or Nd:YLF lasers. It is also possible to use gas lasers such as, for example, CO 2 lasers. The output of such lasers is typically pulsed so that a specific laser emits energy pulses at a predetermined frequency.
• the laser beam may be moved along a desired path by a reflecting galvanometer mirror in order to create, for example, the zones and, preferably, void lines surrounding the sensor conductor 7 or the superguard conductor 5 when the front conductor 4 is removed.
• the laser is focused at a first point in time at a first desired spot, and a first energy pulse is released.
• the front conductor e. g. a metal layer of a certain thickness comprising aluminium or copper
• the front conductor is evaporated in such first spot thereby exposing the underlying layer such as, for example, the front major surface 2b of the backing layer 2 or an underlying adhesive layer 3.
• the laser power required depends on several parameters including, in particular, the thickness of the front conductor layer 4 and the material of the front conductor layer 4.
• the laser power can easily selected by the person skilled in the art in view of such parameters and is frequently chosen to be between 5 and 250 W/cm 2 .
• the width of the spots created by the laser pulses can be varied by varying the aperture of the laser and thus the pulse width.
• the pulse width is preferably chosen to be at least 5 ⁇ m, more preferably at least 40 ⁇ m and especially preferably at least 50 ⁇ m.
• the first laser pulse thus creates a void in the front conductor at a first desired spot.
• the galvanometer mirror system deflects the laser beam to a second desired spot where a second pulse is emitted and so on.
• the laser ablating system is tuned so that the speed of the laser beam along the desired path and the pulse frequency of the laser are aligned to provide the desired overlap between adjacent spots and consequently a continuous zone between the front conductor 4 and the sensor conductor 7 or the superguard conductor 5, if present, respectively, where the front conductor 4 is removed.
• the laser pulse frequency is slower than the speed of the laser beam along the desired path discrete unconnected spots are obtained so that the sensor conductor 7 and, if present, the superguard conductor 5 are not reliably electrically isolated against each other in said zones. If the laser pulse frequency is higher than the speed of the laser beam along the desired path multiple burns over the same spot will occur which may result in damaging the underlying layer or layers.
• the linear speed of the laser beam is at least 300 mm/s and, in some embodiments, at least 400 mm/s. In some embodiments, the linear speed of the laser beam is between 400 and 5,000 mm/s and, in some embodiments, between 500 and 4,000 mm/s.
• the material of the front conductor 4 can be removed in the zones at least partly surrounding the sensor conductor 7 and, if present, the superguard conductor 5 by various other techniques comprising, for example, mechanical abrasion, plasma ablation, ion sputtering or chemical etching.
• a thin rotating pin comprising a tip with abrasive properties may be moved along a desired path through the front conductor 4 in order to abrade the material of the front conductor 4 in the zone along said path.
• the abrasive tip may have various shapes such as, for example, a spherical, cylindrical or conical shape, and its dimensions are preferably selected so that the width of said zones or void line formed in the front conductor 4 is at least 25 ⁇ m and more preferably at least 50 ⁇ m.
• the abrasive tip is introduced into the front conductor 4 and, if necessary, into the underlying layer at a depth sufficient to reliably remove the material of the front conductor in said zone and exposing the front major surface 2b of the backing layer 2 and/or the adhesive layer 3.
• the exposed major surface of the front conductor 4 may be impinged by an optionally pulsed water jet.
• the front conductor 4 may also be removed in said zones by other techniques including chemical etching or plasma ablation.
• the guard conductor 1 , the front conductor 4, the sensor conductor 7 and, if present, the superguard conductor 5 of the capacitive sensor film 50 may be electrically contacted from one of the major surfaces of the film or at the edge of the film.
• the term edge of the film denotes its circumferential extension in the direction of its thickness.
• the rear major surface of the film 50 may be formed by the exposed surface of the guard conductor, the rear major surface 2a of the backing layer or, if present, by the exposed surface of a rear protective layer 17 (Fig. 5).
• the front major surface of the film 50 may be formed by the front major surface 2b of the backing layer 2 or the exposed surfaces of the front conductor 4, the sensor conductor 7 or the superguard conductor 5, respectively, or, if present, by the exposed surface of a front protective layer 16 (Fig. 5).
• the capacitive sensor film 50 may comprise at least one through-going hole 10 extending through the backing layer 2 to one of the major surfaces of the film 50. In case electrical connections are made to the capacitive sensor film 50 from its rear major surface, the sensor conductor 7 and, if present, the superguard conductor 5 may be contacted through such one or more through- going holes 10. Likewise, in case the film 50 is electrically contacted from its front major surface, the guard conductor 1 may be contacted through such one or more through-going holes 10.
• the one or more through-going holes 10 may be applied by any punching or die-cutting device such as, for example, by a pneumatic or mechanical hole punch, machined die or rotating block.
• the cross-section of the through-going holes 10 may have any shape including, for example, a circular, ellipsoidal, rectangular or irregular shape.
• the cross- sectional dimension of the through-going holes 10 is not critical and is selected to allow for a reliable electrical connection while not adversely affecting the integrity of the capacitive sensor film. In some embodiments, the cross-sectional dimension of the through-going holes varies between 0.2 and 5 cm 2 and, in some embodiments, between 0.5 and 2.5 cm 2 .
• the one or more through-going holes 10 may or may not extend through the guard conductor 1, sensor conductor 7, the front conductor 4 and, if present, the superguard conductor 5.
• the one or more through-going holes 10 may extend to the rear surface of the corresponding conductor but do not extend through such conductor.
• the rear surface of the sensor conductor 7, the front conductor 4 and, if present, the superguard conductor 5 can be easily contacted through the one or more through-going holes 10 from the rear surface of the film.
• the one or more through-going holes 10 extend through the corresponding conductor so that the front surface of the sensor conductor 7, the front conductor 4 and/or the superguard conductor 5 can be contacted through the one or more through-going holes 10 from the rear side of the film.
• one or more auxiliary conductors 12 may be provided which are electrically connected to the sensor conductor 7, the front conductor 4 and/or, if present, to the superguard conductor 5.
• the auxiliary conductors 12 may be formed, for example, by electrically conductive adhesive tapes comprising a backing 15 bearing an electrically conductive adhesive 14.
• a strip of such tape is attached via its electrically conductive adhesive layer to the corresponding conductor, and the length of such adhesive strip is selected so that it extends into the area of the through-going hole 10.
• the corresponding conductor can be electrically connected from the rear side of the capacitive sensor film 50 via such auxiliary conductive adhesive strip.
• the auxiliary conductors 12 may also be formed by metal foils or carrier films bearing a metal coating layer obtained, e. g., by vacuum metal vapour deposition. Such conductors 12 are applied so that the metal foil or the metal coating layer contacts the sensor conductor 7, the front conductor 4 and/or, if present, the superguard conductor 5, and they may be held in place, for example, by conventional one-sided adhesive tapes.
• the backing 15 of an electrically conductive adhesive tape which can be used as auxiliary conductor 12 may include electrically conductive and non-conductive materials such as metal films or polymeric films.
• Conductive film tapes comprising an aluminium or copper foil backing, respectively, bearing in each case an electrically conductive pressure-sensitive adhesive, are commercially available from 3M Company, St. Paul/MN, USA, under the trade designations "3M 1170 EMI Aluminium Foil Shielding Tape" and "3M 1181 EMI Copper Foil Shielding Tape", respectively.
• An aluminium foil having a thickness of 20 ⁇ m which can be used as the backing 15 of an auxiliary conductor 12, is available, for example, from Tesco Comp. under the designation "cooking foil".
• the auxiliary conductor 12 may generally be formed by any material which can be attached to the sensor conductor 7, to the front conductor 4 and/or, if present, to the superguard conductor 5 in an electrically connecting way and which is sufficiently self- supporting so that it provides a reliable electrical contact zone within the area of the through-going hole 10.
• the auxiliary conductor 12 may also be formed, for example, by an optionally flattened metal wire which is attached to the corresponding conductor by means of an electrically conductive adhesive.
• an electrically insulating film 11 may be applied to fully cover the one or more through-going holes 10 on the front and/or rear side of the backing layer 2, respectively, before applying the auxiliary conductors 12.
• Such electrically insulating film 11 comprises a backing (not designated by a reference number in the below figures) which may be formed, for example, by any non-conductive polymeric or paper film.
• Useful non- conductive polymeric materials include, for example, polyolefin polymers, monoaxially oriented polypropylene (MOPP), biaxially oriented polypropylene (BOPP), simultaneously biaxially oriented polypropylene (SBOPP), polyethylene, copolymers of polypropylene and polyethylene, polyvinylchloride, copolymers having a predominant olefin monomer which may optionally be chlorinated or fluorinated, polyester polymers, polycarbonate polymers, polymethacrylate polymers, cellulose acetate, polyester (e. g. biaxially oriented polyethylene terephthalate), vinyl acetates, and combinations thereof.
• polyolefin polymers monoaxially oriented polypropylene (MOPP), biaxially oriented polypropylene (BOPP), simultaneously biaxially oriented polypropylene (SBOPP), polyethylene, copolymers of polypropylene and polyethylene, polyvinylchloride, copolymers having a predominant o
• the backing of the electrically insulating film 11 preferably bears an adhesive layer 6 and, in particular, a pressure-sensitive adhesive layer on one of its major surfaces through which it is attached to the front and/or rear side of the capacitive sensor film 50 thereby covering the through- going holes 10. Then, holes are punched through the one or more electrically insulating films so that the through-going hole 10 is restored which now additionally extends through the insulating films.
• the cross-sectional extension and/or shape of the holes punched into the electrically insulating films are selected so that the hole punched through the insulating film is smaller than the through-going hole punched originally.
• the length of the edges of the electrically insulating films 11 extending into the zone of the through-going hole 10, is selected so that the inner wall of the through-going hole is essentially fully covered by the electrically insulating films 11. This specific design reliably insulates the guard conductor 1 from the sensor conductor 7, the front conductor 4 and, optionally, the superguard conductor 5 and additionally reinforces the area of the through-going hole 10.
• Electrically insulating films 11 are preferably applied both to the front major surface of the film 50 (i.e. onto the front conductor 4, the sensor conductor 7, the superguard conductor 5 and/or the exposed front major surface 2b of the backing layer) and to the exposed rear major surface of the film 50 including the guard conductor.
• the capacitive sensor film 50 is contacted from its front major surface.
• the one or more through-going holes 10 will extend from the front major surface to the front surface of the guard conductor 1 or through the guard conductor to its rear surface, respectively. If the guard conductor does not fully cover the rear major surface 2a of the backing 2 and the one or more through-going holes are arranged outside the area of the guard conductor 1, one or more auxiliary conductors 12 and, if desirable, one or more insulating films 11 may optionally be used as was described above to allow for an easy and reliable connection.
• the film 50 is electrically connected at its edge.
• the sensor conductor 7 and the guard conductor 1 each comprise at least one edge area or portion which are adjacent to each other and to the edge of the film
• the capacitive sensor film 50 comprises a superguard conductor 5, or if the front conductor 4 and the guard conductor are to be electrically connected these conductors 4, 5 may also exhibit edge areas or portions adjacent to those of the sensor conductor and the guard so that the electrical connections to such conductors 1,7,5 and/or 4 can be easily integrated, for example, into a socket. Further details on electrically connecting the capacitive sensor films 50 can be taken from the co-pending European patent application No. 06001 149.1 with the title "Proximity sensor and method for manufacturing the same" which was filed by the present applicant on January 19, 2006.
• protective films 16, 17 In some applications it is desirable to seal the capacitive sensor film 50 between protective films 16, 17 (already mentioned) to protect the capacitive sensor film 50 against environmental impacts such as water or moisture, to electrically insulate the film 50 and/or to render it more easily handleable.
• protective films may be selected from the group of polymeric films, layers and laminates.
• Useful polymers include, for example, poly olefin polymers, monoaxially oriented polypropylene (MOPP), biaxially oriented polypropylene (BOPP), simultaneously biaxially oriented polypropylene (SBOPP), polyethylene, copolymers of polypropylene and polyethylene, polyester polymers, polycarbonate polymers, polymethacrylate polymers, cellulose acetate, polyester (e. g. biaxially oriented polyethylene terephthalate), vinyl acetates, and combinations thereof.
• MOPP monoaxially oriented polypropylene
• BOPP biaxially oriented polypropylene
• SBOPP simultaneously biaxially
• the protective polymer films may be applied to the front major surface 2b of the backing layer bearing the sensor conductor 7, the front conductor 4 and, optionally, the superguard conductor 5 and to the guard conductor 1 on the back major surface 2a of the backing 2 by adhesive means including, for example, hot-melt adhesives and pressure-sensitive adhesives.
• the length and width of the protective films 16, 17 generally exceeds the length and width of the backing film 2 and/or the guard conductor 1 to provide an edge sealing to the capacitive sensor film 50 to protect, in particular, the edges of the guard conductor against corrosion.
• the length and width of the protective films 16, 17 may be selected to provide an edge sealing border with a width of 1 — 50 mm, in some embodiments, of 1 - 40 mm and, in some embodiments of 2 — 20 mm.
• the protective films 16, 17 may be removed in the edge areas or portions of the conductors 1, 4, 5 and/or 7 adjacent to the edge subsequent to applying such films 16, 17.
• the protective films 16, 17 may be approximately shaped prior to lamination so that such edge zones or portions are not covered by the protective film upon lamination.
• the capacitive sensor film 50 is contacted via one or more through-going holes 10 these may be punched into the protective film 16, 17 on the major surface of the capacitive sensor film 50 from which the capacitive sensor film 50 is contacted thereby extending the through-going holes to such surface.
• a further hole may be punched into the protective film 17 to allow for contacting the guard conductor 1.
• one or more additional holes may be punched into the protective layer 16 to allow for contacting the sensor conductor 7, the front conductor 4 and, optionally, the superguard conductor 5 whereas the guard conductor 1 is contacted via one or more through-going holes 10.
• one or more holes can be punched at appropriate locations into the protective film 16, 17 prior to lamination so that such pre-punched holes extend the through-going hole or holes 10 to the respective major surface of the capacitive sensor film 50 and/or provide access to the desired conductors 1, 7, 4 and/or 5.
• the capacitive sensor film 50 is contacted at one of its edges connecting cables or strips are supplied into such edge region and pressed against the guard conductor 1, the sensor conductor 7 and, optionally, the superguard conductor 5 and/or the front conductor 4 to establish electrical contact.
• Pressure can be applied, for example, via spring loaded pads which continuously press on the connection zones between the conductors 1, 7, 4 and/or 5 and the connections strips.
• connecting cables or strips are supplied through the one or more through-going holes 10 or through the additional holes which may be present to contact the guard conductor 1, the sensor conductor 7 and, optionally, the superguard conductor 5, the front conductor 4 and/or any auxiliary conductors 12 which may be attached to conductors 1, 7, 4 and/or 5.
• connection strips are supplied from the rear side of the capacitive sensor film 50 through the one or more through-going holes 10 and pressed against the sensor conductor 7, the superguard conductor 5, the front conductor 4 and/or the auxiliary conductors 12, respectively to establish electrical contact.
• Pressure can be applied, for example, via spring loaded pads which continuously press on the connection areas between the connectors and the sensor conductor 7, the superguard conductor 5, the front conductor and/or the auxiliary conductors 12, respectively.
• the one or more through-going holes 10 may be filled with a conductive ink such as a silver ink which is subsequently solidified by evaporative drying or curing.
• the through-going hole 10 may also be filled, for example, with a precursor of a silver epoxy adhesive which is thermally cured upon insertion into the one or more through-going holes 10.
• the connecting strips do not need to be supplied through the through-going holes 10 but can be applied, for example, at the respective major surface of the capacitive sensor film 50. Establishing of electrical contact between the connectors and the sensor conductor 7, the superguard conductor 5, the front conductor 4 and/or the auxiliary conductors 12 is thus facilitated, and the resulting connection is more reliable and mechanically stable.
• the capacitive sensor film 50 can thus easily and reliably be electrically contacted from one of its major surfaces or from its edge respectively. Contacting the capacitive sensor film 50 from one of its major surfaces and, in particular, from its rear major surface may be desirable in automotive applications.
• the socket body which may be applied to the capacitive sensor film 50 to allow for a standardized connection.
• a complete hermetic seal is preferably formed between the periphery of the socket body and the capacitive sensor film 50 or thus preventing water, air or dust ingress into the inner layers or the connection area.
• the socket body comprises sealing means such as sealing O rings or adhesive gaskets around its periphery contacting the capacitive sensor film 50. The socket body is applied to the capacitive sensor film 50 so that the sealing O rings or the adhesive gaskets are pressurized and form the required hermetic seal.
• the capacitive sensor film 50 may be advantageously used in automotive applications for sensing the proximity of a car to other objects where it can be introduced, for example, in the rear and front bumper.
• the shape and geometry, in particular, of the sensor conductor 7 and the superguard conductor 5 can vary widely, thus allowing to improve the sensitivity of the capacitive sensor film 50 or to adapt and tailor-make it for specific applications.
• the effective area of the guard conductor 1 can be increased by electrically combining the guard conductor 1 on the rear major surface 2a of the backing layer with the front conductor 4 on the front major surface 2b of the backing layer.
• the capacitive sensor film 50 can be cut into the required shape by any die-cutting, punching or laser cutting means, for example.
• the capacitive sensor film 50 can be easily electronically connected from its rear side which does not only facilitate assembling at the OEM (original equipment manufacturer) site but also allows, for example, for an easy replacement of such capacitive sensor film 50 if the bumper incorporating it is damaged in an accident.
• the capacitive sensor film 50 can be easily installed and is flexible so that it can be applied to shaped substrates having, for example, curved surfaces. It is particularly advantageous that the capacitive sensor film 50 can be electrically contacted in an easy and reliable way. In view of these advantages, the capacitive sensor film 50 is especially suited for use in the automotive industry.
• a capacitive sensor film 50 which may be contacted from one of its major surfaces, an aluminium film laminate comprising the backing layer 2 bearing an aluminium layer which forms the guard conductor 1, is provided first. Then a front conductor 4 is applied to the opposite major surface of the backing.
• the front conductor 4 may be a metal film or foil bonded, for example, by adhesive means. Alternatively, the front conductor 4 may also be applied by vacuum metal vapour coating.
• the sensor conductor 7 and, optionally, the superguard conductor 5 are formed within the front conductor by removing the front conductor 4 in zones at least partly surrounding the sensor conductor 7 and the guard conductor 5 as was described above.
• Fig. 1 shows a top view of a first embodiment of a capacitive sensor film 50 comprising a front conductor 4 surrounding a sensor conductor 7 and a superguard conductor 5.
• the front conductor 4 is separated from the superguard conductor 5 and the sensor conductor 7, respectively, by zones or void lines (i.e. the black lines in the drawing) in which the front conductor 4 is removed so that the front major surface 2b of the backing layer 2 is exposed. This ensures that the superguard conductor 5 and the sensor conductor 7, respectively, are electrically isolated against each other and against the front conductor 4.
• the superguard conductor 5 comprises one strip extending essentially along the length of the film 50.
• the sensor conductor 7 exhibits a more complicated design and comprises four strips essentially extending along the length of the film 50.
• the sensor conductor comprises three shorter additional strips each to provide lobe type end regions in order to increase the sensitivity " of the sensor conductor at its lateral end regions.
• the upper longitudinal edge of the film 50, the superguard conductor strip 5 and the strips of the sensor conductor 7 are essentially parallel to each other.
• the different strips of the sensor conductor 7 are electrically connected at both end regions by a further strip each extending transversely inclined to the longitudinal direction of the film 50.
• Fig Ia shows an enlarged top view of the left part of a second embodiment of a capacitive sensor film 50 which is slightly modified in comparison to the sensor film of Fig. 1 in that the superguard conductor 5 and the top-most strip of the sensor conductor 7 each additionally comprise a connection area 8 which may be used for electrically connecting such conductors.
• the connecting area S of the superguard conductor 5 is essentially square whereas the connecting area 8 of the sensor conductor 7 has an essentially rectangular shape in order to facilitate, for example, the application of the through-going holes 10, the insulating tapes 11 and the auxiliary connector strips 12 in the embodiment shown in Fig. 3a-c below.
• the connecting areas 8 can be arranged anywhere on the front major surface of the film 50 and do not need to be positioned at its left part.
• Figs. 2 and 2a are cross-sectional views of two different embodiments of the capacitive sensor film 50 of Fig. Ia along the line A — A indicated in Fig. Ia: the embodiments differ in the extension of the guard conductor 1 along the line A — A.
• the guard conductor 1 extends over the full width of the capacitive sensor film 50 whereas in the embodiment of Fig.2a the extension of the guard conductor 1 is selected to essentially match that of the superguard conductor 5 and the sensor conductor 7.
• FIG. 2 and 2a show that the front conductor 4 has been removed in the void lines between such front conductor 4 on the one hand and the superguard conductor 5 and the different strips of the sensor conductor 7, respectively, on the other hand; the Figures are highly schematic and only show the cross-section of three conductive strips of the sensor conductor 7 (rather than the full number shown in Fig. Ia) in order to avoid unnecessary complexity.
• the front conductor 4, the superguard conductor 5 and the sensor conductor 7 are borne by the front major surface 2b of the backing layer 2.
• the guard conductor 1 is attached to the rear major surface 2a of the backing layer 2 via the adhesive layer 3.
• Figs. 3a — 3c show a process of applying through-going holes 10 to the film 50 so that such film can be electrically connected from its rear major surface.
• Fig. 3a shows the top view of the left part of the capacitive sensor film 50 of Fig. Ia additionally where two through- going holes 10 have been applied in the connecting areas 8 of the superguard conductor 5 and the top-most strip of the sensor conductor 7, respectively.
• an electrically insulating film 11 has been applied covering the through-going holes 10. Subsequently holes have been punched into the electrically insulating film to re-expose the through- going holes.
• auxiliary conductors 12 are attached so that they cover the through- going holes 10 and the electrically insulating film 11.
• Figs. 4 and 5 are cross-sectional views of the capacitive sensor film 50 of Fig. 3c along the line B — B indicated in Fig. 3c.
• the same remarks relative to the number of the strips of the sensor conductor 7 as given above in connection with Fig. 2 and 2a apply here, as well.
• the through-going hole 10 shown in the cross-sectional view of Fig. 4 extends from the front major surface of the superguard conductor 5 to the rear major surface of the guard conductor 1.
• Insulating tapes 11 have been applied at both ends of the through-going hole 10 whereby the diameter of the holes punched into the insulating tapes 11 is in each case smaller than the diameter of the through-going hole 10.
• Fig. 5 is the cross-sectional view of the capacitive sensor film 50 of Fig.4 additionally comprising two protective layers 16, 17.
• Fig. 6 is the top view of a capacitive sensor film 50 similar to the embodiment of Fig. 3c which comprises a further through-hole 10 covered with an auxiliary conductor 12 which is arranged in the area of the front conductor 4 between the connecting areas 8 of the sensor conductor 7 and the superguard conductor 5, respectively.
• Fig. 6a is a cross-sectional view of the capacitive sensor film 50 of Fig. 6 along the line C — C indicated in Fig. 6.
• the through-going hole 10 extends from the front major surface of the front conductor 4 to the rear major surface of the guard conductor 1.
• a strip of a conductive tape 12 is applied on top of the front conductor 4 so that the front conductor 4 and the guard conductor 1 can be jointly contacted from the rear side of the film 50.
• the same remarks relative to the number of the strips of the sensor conductor 7 as given above in connection with Fig. 2 and 2a apply here, as well.
• Fig. 7 is a cross-sectional view of another capacitive sensor film.
• the sensor and superguard conductors have the same configuration as in Figs. 1 and 2, and are indicated by the same reference numerals (J, 5).
• the front conductor, now functioning as part of the guard conductor, is indicated by the reference numeral 1'.
• the remainder of the guard conductor comprises a conductive layer 53 applied over the sensor and superguard conductors 7, 5 and electrically-isolated therefrom by a dielectric layer 52.
• the conductive layer 53 contacts, and is electrically-connected to, the front conductor I 1 in the region surrounding the sensor and superguard conductors 7, 5.
• the adhesive layer 3 on the rear major surface 2b of the backing layer 2 is used to attach the sensor film to a surface in a desired location and, prior to use, is protected by a release liner 51.
• a protective film (not shown) may be applied over the other face of the sensor film, if required.
• PET film (length 1.5 m, width 325 mm) bearing on one of its major surfaces an electrically conductive aluminium vapour coating layer with a thickness of 0.3 ⁇ m (obtainable from Amcor, UK) was laminated onto a 100 ⁇ m PET film bearing a 25 ⁇ m ethylenevinylacetate (EVA) adhesive layer so that the aluminium vapour coat layer forming the front conductor 4 was exposed and the EVA adhesive layer bonded the two PET layers.
• EVA ethylenevinylacetate
• the PET film bearing the adhesive layer was available from GBC, UK.
• the lamination was performed using a CATENA 35 laminator, available from GBC, at about lm/min speed with a roller temperature of about 110 0 C.
• the resulting film was placed into a flat bed on an XY table below a YAG laser head.
• the laser system used had a power of 90 Watt.
• the source was a continuous wave, lamp- pumped Nd: Y AG laser (1064 m).
• the output of the laser was Q-switched to produce pulsed emission.
• the laser was coupled with a Galvo-head with X and Y mirrors and a 300 mm flat-field lens to keep the spot in focus at the edge as well as at the centre of the path along which the void line was formed. Distortion of the image through the lens was compensated for in the controlling software.
• the settings used were: - aperture: 1375 mm
• a conductor circuit as shown in Fig. 6 was obtained on the aluminium side of the film.
• the black lines in Fig 6 represent the void lines, i.e. the zones where the aluminium has been removed.
• the white zones represent the remaining aluminium which forms the superguard conductor 5, the sensor conductor 7 and the front conductor 4.
• the wider strip which is arranged above the series of smaller strips and has a width of 12 mm is the superguard conductor 5. It comprises a contact zone for applying a through- going hole 10 and extends along the length of the film.
• the seven smaller strips below which are connected to each other form the sensor conductor 7.
• the distance between the superguard conductor 5 and the sensor conductor was -outside the contact zone- 20 mm.
• the overall length of the upper four strips of the sensor conductor 7 was 1,44 m each whereas the three lower strips each had a length of 0.2 m on each side; the overall geometry of the film of Fig. 6 was symmetrical and exhibits three lower strips on both sides of the film similar to the geometry shown in Fig. 1.
• the strips of the sensor conductor 7 each had a width of 0.5 mm and the distance between the strips was 5 mm.
• connection zone of the superguard conductor 5 was essentially square with a width of 12mm.
• the connection zone of the guard conductor 7 was rectangular and had a width of about 12 mm and a length of about 25 mm.
• the connection zone of the superguard conductor was arranged at a distance of about 140 mm from the left edge of the superguard conductor 5.
• the distance between the connection zones of the superguard conductor 5 and the sensor conductor 7, respectively, was about 15. mm.
• the capacitance between the sensor conductor 7 and the superguard conductor 5 was measured using a conventional capacitance meter. A value of 0.77 nF was recorded
• a 70 mm wide strip of aluminium foil tape (available from 3M as tape 425 or similar) was applied as a guard conductor 1 as is shown in Fig. 6a so that it extended in the width direction from the upper edge of the film; the width of the aluminium foil tape was chosen so that it matched the extension of both the superguard conductor 5 and the sensor conductor on the other major side of the film.
• the aluminium foil tape extended in length direction along the length of the film.
• the aluminium foil guard conductor 1 tape holes exhibited holes matching the position of the through-going holes 10 so that such holes were exposed on the rear side of the film.
• the through-going holes 10 were filled with a conductive ink so that the film could be contacted from the rear side.
• the whole capacitive sensor film 50 was then cut to the required shape using a clear acrylic plastic template.
• the capacitive sensor film thus obtained was then laminated between two layers of DK 951 PP polypropylene laminating tape acting as protective layers 16,17.
• two layers of heat seal protective polyester film 50 ⁇ PET film with 25 ⁇ EVA heat seal adhesive, available from GBC, UK) were used.
• An aluminized film is laminated, with the aluminium side uppermost, onto an adhesive transfer web comprising an adhesive layer on a release liner.
• the vapour-coated aluminium layer on the film is then laser ablated to create a conductor configuration as shown in Fig. 1 and also a 5mm wide border around the whole of the intended final periphery of the sensor.
• a filmic double sided tape is then laminated over the area occupied by the sensor and superguard conductors, followed by a layer of aluminium foil, about 10mm wider than the double sided tape, such that it is stuck down by the tape and overlaps it on each side.
• the aluminium foil thus contacts the vapour-coated aluminium layer surrounding the area occupied by the sensor and superguard conductors and, together, they form the guard conductor of the sensor.
• a protective film is then heat laminated over the whole upper surface.
• the completed sensor is cut out from the web around the outer edge of the ablated border.
• the ablated border ensures that no aluminium is exposed at the edges of the sensor, thus eliminating the chances of electrical shorting or degradation.
• the method of this example enables manufacturing to be simplified, in that the materials are handled as a continuous web until the completed sensor is cut out.

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• Measurement Of Length, Angles, Or The Like Using Electric Or Magnetic Means (AREA)
• Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
• Electronic Switches (AREA)
• Measuring Fluid Pressure (AREA)
• Transmission And Conversion Of Sensor Element Output (AREA)

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• 2006
  • 2006-01-19 EP EP06001155A patent/EP1814226A1/en not_active Withdrawn
• 2007
  • 2007-01-19 US US12/160,631 patent/US20080297176A1/en not_active Abandoned
  • 2007-01-19 WO PCT/US2007/001288 patent/WO2007084590A2/en not_active Ceased
  • 2007-01-19 JP JP2008551368A patent/JP2009524056A/ja not_active Withdrawn
  • 2007-01-19 EP EP07716745A patent/EP1977515A2/en not_active Withdrawn
  • 2007-01-19 CN CNA2007800031614A patent/CN101375502A/zh active Pending
  • 2007-01-19 TW TW096102143A patent/TW200740641A/zh unknown

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