WO2007060001A3 - Verfahren zur reformierung von dieselkraftstoff und reaktor hierzu - Google Patents

Verfahren zur reformierung von dieselkraftstoff und reaktor hierzu Download PDF

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Publication number
WO2007060001A3
WO2007060001A3 PCT/EP2006/011307 EP2006011307W WO2007060001A3 WO 2007060001 A3 WO2007060001 A3 WO 2007060001A3 EP 2006011307 W EP2006011307 W EP 2006011307W WO 2007060001 A3 WO2007060001 A3 WO 2007060001A3
Authority
WO
WIPO (PCT)
Prior art keywords
diesel fuel
reactor
mixture
fuel reforming
reforming method
Prior art date
Application number
PCT/EP2006/011307
Other languages
English (en)
French (fr)
Other versions
WO2007060001A2 (de
Inventor
Axel Maurer
Klaus Wanninger
Herbert Wancura
Original Assignee
Fraunhofer Ges Forschung
Sued Chemie Ag
Alpps Fuel Cell Systems Gmbh
Axel Maurer
Klaus Wanninger
Herbert Wancura
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to US12/094,913 priority Critical patent/US20090053562A1/en
Application filed by Fraunhofer Ges Forschung, Sued Chemie Ag, Alpps Fuel Cell Systems Gmbh, Axel Maurer, Klaus Wanninger, Herbert Wancura filed Critical Fraunhofer Ges Forschung
Priority to EP06818821A priority patent/EP1957399A2/de
Publication of WO2007060001A2 publication Critical patent/WO2007060001A2/de
Publication of WO2007060001A3 publication Critical patent/WO2007060001A3/de

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0625—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material in a modular combined reactor/fuel cell structure
    • H01M8/0631—Reactor construction specially adapted for combination reactor/fuel cell
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1247—Higher hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1276—Mixing of different feed components
    • C01B2203/1282—Mixing of different feed components using static mixers
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Exhaust Gas After Treatment (AREA)

Abstract

Die Erfindung betrifft ein Verfahren und eine Vorrichtung zur Reformierung von Dieselkraftstoff in ein H2 und CO enthaltendes Produktgas, wobei der Dieselkraftstoff in einer ersten Vormischstufe mit einem O2 enthaltenden Gasgemisch vermischt und anschließend die so erhaltene Mischung in einer zweiten Vormischstufe mit einem O2 enthaltenden Gasgemisch sowie mit einer Abgasmischung vermischt und nachfolgend diese Mischung einer Kohlenwasserstoffoxidation in einem Reaktor mit einem Katalysator unterzogen wird.
PCT/EP2006/011307 2005-11-25 2006-11-24 Verfahren zur reformierung von dieselkraftstoff und reaktor hierzu WO2007060001A2 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US12/094,913 US20090053562A1 (en) 2005-11-25 2006-11-11 Method for reforming diesel fuel and reactor for this purpose
EP06818821A EP1957399A2 (de) 2005-11-25 2006-11-24 Verfahren zur reformierung von dieselkraftstoff und reaktor hierzu

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005056363.5 2005-11-25
DE102005056363A DE102005056363A1 (de) 2005-11-25 2005-11-25 Reformierung höherer Kohlenwasserstoffe mit Wasserzugabe aus Verbrennungsabgas

Publications (2)

Publication Number Publication Date
WO2007060001A2 WO2007060001A2 (de) 2007-05-31
WO2007060001A3 true WO2007060001A3 (de) 2007-08-23

Family

ID=38037669

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2006/011307 WO2007060001A2 (de) 2005-11-25 2006-11-24 Verfahren zur reformierung von dieselkraftstoff und reaktor hierzu

Country Status (4)

Country Link
US (1) US20090053562A1 (de)
EP (1) EP1957399A2 (de)
DE (1) DE102005056363A1 (de)
WO (1) WO2007060001A2 (de)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9843062B2 (en) * 2016-03-23 2017-12-12 Energyield Llc Vortex tube reformer for hydrogen production, separation, and integrated use

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5987878A (en) * 1995-01-09 1999-11-23 Hitachi, Ltd. Fuel reforming apparatus and electric power generating system having the same
EP1095904A2 (de) * 1999-10-27 2001-05-02 DaimlerChrysler AG Reaktoranlage zur katalytischen Brennstoffumsetzung mit Wasser und Sauerstoff
EP1284235A1 (de) * 2001-08-15 2003-02-19 Sulzer Hexis AG Verfahren zum Reformieren von Brennstoffen, insbesondere Heizöl
DE10318865A1 (de) * 2003-04-25 2004-11-11 Daimlerchrysler Ag Vorrichtung zur Erzeugung eines wasserstoffhaltigen Gases
EP1538688A2 (de) * 2003-11-27 2005-06-08 Webasto AG System und Verfahren zum Umsetzen von Brennstoff und Oxidationsmittel zu Reformat

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3047734A1 (de) * 1979-12-26 1981-10-08 Texaco Development Corp., 10650 White Plains, N.Y. Brenner zum vermischen einzelner einsatzstroeme zur bildung eines mehrphasengemisches zur umsetzung in einem partialoxidations-gaserzeuger
DE19934649A1 (de) * 1999-07-23 2001-01-25 Daimler Chrysler Ag Verfahren zur Erzeugung von Wasserstoff, insbesondere zum Einsatz in Brennstoffzellen, mittels Reformierung von Kohlenwasserstoffen
US6521204B1 (en) * 2000-07-27 2003-02-18 General Motors Corporation Method for operating a combination partial oxidation and steam reforming fuel processor
US6596424B2 (en) * 2001-03-30 2003-07-22 General Motors Corporation Apparatus for mixing fuel and an oxidant
US6872379B2 (en) * 2001-08-15 2005-03-29 Sulzer Hexis Ag Method for the reformation of fuels, in particular heating oil
US6936238B2 (en) * 2002-09-06 2005-08-30 General Motors Corporation Compact partial oxidation/steam reactor with integrated air preheater, fuel and water vaporizer
DE102004001310A1 (de) * 2004-01-07 2005-08-11 Viessmann Werke Gmbh & Co Kg Verfahren zum Betrieb einer Anlage zur Wasserdampfreformierung eines Kohlenwasserstoffgases
DE102004041676A1 (de) * 2004-08-23 2006-03-02 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verfahren und Reaktor zur Reformierung

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5987878A (en) * 1995-01-09 1999-11-23 Hitachi, Ltd. Fuel reforming apparatus and electric power generating system having the same
EP1095904A2 (de) * 1999-10-27 2001-05-02 DaimlerChrysler AG Reaktoranlage zur katalytischen Brennstoffumsetzung mit Wasser und Sauerstoff
EP1284235A1 (de) * 2001-08-15 2003-02-19 Sulzer Hexis AG Verfahren zum Reformieren von Brennstoffen, insbesondere Heizöl
DE10318865A1 (de) * 2003-04-25 2004-11-11 Daimlerchrysler Ag Vorrichtung zur Erzeugung eines wasserstoffhaltigen Gases
EP1538688A2 (de) * 2003-11-27 2005-06-08 Webasto AG System und Verfahren zum Umsetzen von Brennstoff und Oxidationsmittel zu Reformat

Also Published As

Publication number Publication date
US20090053562A1 (en) 2009-02-26
WO2007060001A2 (de) 2007-05-31
EP1957399A2 (de) 2008-08-20
DE102005056363A1 (de) 2007-05-31

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