Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
  • C08J5/18—Manufacture of films or sheets
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L101/00—Compositions of unspecified macromolecular compounds
  • C08L101/12—Compositions of unspecified macromolecular compounds characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/02—Diffusing elements; Afocal elements
  • G02B5/0205—Diffusing elements; Afocal elements characterised by the diffusing properties
  • G02B5/0236—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place within the volume of the element
  • G02B5/0242—Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place within the volume of the element by means of dispersed particles
• • G—PHYSICS
  • G02—OPTICS
  • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
  • G02B5/00—Optical elements other than lenses
  • G02B5/02—Diffusing elements; Afocal elements
  • G02B5/0273—Diffusing elements; Afocal elements characterized by the use
  • G02B5/0278—Diffusing elements; Afocal elements characterized by the use used in transmission
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L2205/00—Polymer mixtures characterised by other features
  • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
  • C08L2205/18—Spheres
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
  • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
  • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers

Definitions

• the present invention relates to a plastic composition of a transparent plastic, especially polycarbonate, and transparent polymeric particles having a different optical density from the matrix material and the use of this plastic composition for films, in particular for diffuser films in flat screens.
• Light-scattering translucent products of transparent plastics with various light-scattering additives and moldings produced therefrom are already known from the prior art.
• US 2004/0066645 A1 generally claims light-scattering materials which contain 0.2 to 5% light-scattering particles, and the light transmission is greater than 70% and the haze at least 10%.
• the litter additive has a mean diameter of 3 to 10 ⁇ m.
• JP 07-090167 a light scattering plastic is claimed, which consists of 1 to 10% of particles having a refractive index of less than 1.5 and a particle size of 1 to 50 microns, and 90 to 99% of an aromatic polycarbonate, wherein the particles do not substantially dissolve in the aromatic polycarbonate.
• scattering additives acrylate, polystyrene, glass, titanium dioxide or calcium carbonate particles are used.
• the morphology of the core / shell acrylates and the light-scattering compounds containing them is not further described and characterized.
• EXL 5137 is used as a scattering additive in combination with inorganic particles, inter alia in polycarbonate, wherein 0.001 to 0.3% of these particles, for example titanium dioxide, contribute to improved aging resistance and thus color stability. This advantage is particularly important when compounds with high levels of litter (> 2%) are exposed to elevated service temperatures (eg 14O 0 C) for a long time (> 500 hours).
• JP 2004-053998 describes light-scattering polycarbonate films having a thickness of 30 to 200 ⁇ m, which consist of more than 90% polycarbonate, have a light transmission of more than 90%, at least one side of the film surface has a concavo-convex structure , have a haze of at least 50% and have a retardation of less than 30nm.
• diffuser films are claimed in back light units.
• diffuser films with low birefringence (retardation ⁇ 30 nm, better even ⁇ 20 nm) are described and claimed because they cause higher brightnesses in the BLU.
• inorganic particles e.g. Silicates, calcium carbonate or talc, or organic particles such as crosslinked acrylates or polystyrenes having an average diameter of 1 to 25 .mu.m, preferably used from 2 to 20 microns.
• JP 08-146207 describes optical diffuser films in which the surface has been patterned on at least one side by a molding process. Furthermore, a film is claimed in which, when using only a transparent scattering additive, this unevenly distributed over the thickness of the film. If two or more scattering additives are used, they can be distributed uniformly over the thickness of the film.
• the littering additives used may be acrylate, polyethylene, polypropylene, polystyrene, glass, alumina or silica particles having a mean particle diameter of 1 to 25 microns.
• the films can have a thickness of 100 to 500 ⁇ m.
• JP 2004-272189 optical diffuser plates are described with a thickness of 0.3 to 3 mm, wherein litter additives having a particle diameter of 1 to 50 microns are used. Furthermore, it is claimed that in a brightness range of 5000 to 6000 Cd / m 2, the differences in brightness are less than 3%.
• diffuser films are described with a thickness of 20 to 200 microns for use in LCD, containing 0.2 to 10% scattering additive and at least on one side have a gloss of 20 to 70%.
• Crosslinked silicones, acrylates or talcum are compounded as littering additives having a particle diameter of 5 to 30 ⁇ m.
• JP 06-123802 describes diffuser films having a thickness of 100 to 500 ⁇ m for LCD, wherein the refractive index difference between the transparent base material and the transparent light-scattering particles is at least 0.05.
• one side of the film is smooth, while on the other side the litter additives stick out of the surface and form the structured surface.
• the litter additives have a particle diameter of 10 to 120 microns.
• a backlight unit (Direct Light System) has the structure described below. It usually consists of a housing in which, depending on the size of the backlight unit, a different number of fluorescent tubes, so-called. CCFL (CoId Cathode Fluorescent Lamp) are arranged. The inside of the housing is equipped with a light reflecting surface. On this illumination system, the diffuser plate has a thickness of 1 to 3 mm, preferably a thickness of 2 mm. On the diffuser plate there is a set of foils, which can have the following functions: light scattering (diffuser foils), circular palmarisators, focusing of the light in the forward direction by sogn. BEF (Brighness Enhancing Film) and Linear Polarizers. The linearly polarizing film lies directly under the LCD display above.
• CCFL CoId Cathode Fluorescent Lamp
• Light-diffusing plastic compositions in optical applications conventionally contain inorganic or organic particles having a diameter of 1 to 50 microns, in some cases even up to 120 microns, i. they contain scattering centers that are responsible for both the diffusive and the focusing properties.
• all acrylates which have a sufficiently high thermal stability of up to at least 300 ° C. can be used as transparent scattering pigments in order not to be decomposed at the processing temperatures of the transparent plastic, preferably polycarbonate.
• pigments must not have any functionalities that lead to degradation of the polymer chain of the polycarbonate.
• Paraloid® from Rohm & Haas or Techpolymer® from Sekisui can be used very well for the pigmentation of transparent plastics. From this product line a variety of different types are available. Core shell acrylates from the paraloid series are preferably used.
• plastic compositions which contain conventional micrometer-sized particles, in particular so-called core-shell acrylates and as few nanoscale particles as possible, are suitable for backlight units due to the brightness properties and at the same time high light scattering. This effect is even more pronounced in connection with the foil set typically used in a backlight unit (BLU).
• BLU backlight unit
• plastic compositions with light-scattering additives having average particle sizes below 500 nm have no significant influence on the optical properties of films.
• the proportion of particles having an average particle diameter of 80 to 200 nm is below 20 particles per 100 ⁇ m 2 surface of the plastic composition, preferably below 10 particles per 100 ⁇ m 2 , more preferably below 5 particles per 100 ⁇ m 2 .
• the number of particles per surface is determined by examining the surface using Atomic Force Microscopy (AFM). This method is familiar to the person skilled in the art and will be explained in more detail in the exemplary embodiments.
• AFM Atomic Force Microscopy
• the plastic composition has at most 500 ppm, preferably less than 300 ppm, particularly preferably less than 100 ppm of these nanoscale particles.
• ppm is based on the composition.
• the invention therefore relates to plastics compositions which contain transparent polymeric particles having a different index of refraction from the matrix material and are characterized by a proportion of nanoscale particles having an average particle diameter of from 80 to 200 nm, the proportion of nanoscale particles being below 20 particles per 100 ⁇ m 2 Surface of the plastic composition, preferably below 10 particles per 100 microns 2 , more preferably below 5 particles per 100 microns 2 .
• a preferred embodiment of the invention is a plastic composition
• a plastic composition comprising a composition comprising about 90 to 99.95% by weight of a transparent plastic, preferably polycarbonate, and about 0.01 to 10% by weight of polymeric, transparent particles, said polymeric particles having a particle size substantially between 1 and 50 ⁇ m, and up to a maximum of 500 ppm of polymeric, transparent particles having a particle size of 80 to 200 ⁇ m.
• Another object of this invention is a process for the preparation of the inventive plastic composition.
• the plastic compositions according to the invention are preferably produced and further processed by thermoplastic processing.
• the shearing in the thermoplastic processing forms the nanoscale polymeric particles. This formation mechanism is shown by AFM studies on the extruded films. To secure the results, three samples per material were prepared and three sites were examined for their morphology.
• core / shell acrylates are used because they provide the plastic compositions of the present invention.
• Another object of this invention is the use of the plastic composition according to the invention for diffuser films of flat panel displays, in particular in the backlighting of LCD displays.
• the diffuser films produced from the inventive plastic compositions have a high light transmission with simultaneously high light scattering and can be used, for example, in the illumination systems of flat screens (LCD screens).
• LCD screens flat screens
• a high light scattering with simultaneous high light transmission and focusing of the light in the direction of the viewer is of crucial importance.
• the illumination system of such flat screens can be done either with lateral light coupling (edge light system) or larger screen sizes where the lateral light coupling is no longer sufficient, via a backlight unit (BLU), in which the direct illumination behind the diffuser film through This must be distributed as evenly as possible (Direct Light System).
• BLU backlight unit
• Suitable plastics for the plastic composition are all transparent thermoplastics: polyacrylates, polymethacrylates (PMMA, Plexiglas® from Röhm), cycloolefin Copolymers (COC; Topas® from Ticona, Zenoex® from Nippon Zeon or Apel® from Japan Synthetic Rubber), polysulfones (Ultrason @ from BASF or Udel® from Solvay), polyester such as PET or PEN, polycarbonate, polycarbonate / polyester blends, eg PC / PET, polycarbonate / polycyclohexylmethanol cyclohexanedicarboxylate (PCCD, Sollx® from GE), polycarbonate / PBT (Xylex®).
• Suitable polycarbonates for the production of the plastic composition according to the invention are all known polycarbonates. These are homopolycarbonates, copolycarbonates and thermoplastic polyestercarbonates.
• the suitable polycarbonates preferably have average molecular weights M w of from 18,000 to 40,000, preferably from 26,000 to 36,000 and in particular from 28,000 to 35,000, determined by measuring the relative solution viscosity in dichloromethane or mixtures of equal amounts by weight phenol / o-dichlorobenzene calibrated by light scattering.
• the polycarbonates are preferably prepared by the phase boundary process or the melt transesterification process and will be described below by way of example by the phase boundary process.
• Suitable diphenols are e.g. in US Pat. Nos. 2,999,835, 3,148,172, 2,991,273, 3,271,367, 4,982,014 and 2,999,846, in German Offenlegungsschriften 1,570,703, 2,063,050, 2,036,052, 2,111,956 and 3,832,396, French Patent 1,561,518, in the monograph "H. Schnell, Chemistry and Physics of Polycarbonates, Interscience Publishers, New York 1964, p28ff; p.102ff, and in” DG Legrand, J.T. Bendler, Handbook of Polycarbonates Science and Technology, Marcel Dekker New York 2000, pp. 72ff. "
• transesterification for example, in US-A 34 94 885, 43 86 186, 46 61 580, 46 80 371 and 46 80 372, in EP-A 26 120, 26 121, 26 684, 28 030 , 39 845, 39 845, 91 602, 97 970, 79 075, 14 68 87, 15 61 03, 23 49 13 and 24 03 Ol and described in DE-A 14 95 626 and 22 32 977.
• copolycarbonates Both homopolycarbonates and copolycarbonates are suitable.
• copolycarbonates according to the invention it is also possible to use from 1 to 25% by weight, preferably from 2.5 to 25% by weight (based on the total amount of diphenols to be used) of hydroxyl-aryloxy endblocked polydiorganosiloxanes. These are known (see, for example, US Patent 3,419,634) or produced by literature methods.
• the preparation of poly-diorganosiloxan braver copolycarbonates is z. B. in DE-OS 33 34 782 described.
• Aromatic dicarboxylic acid dihalides for the preparation of aromatic polyester carbonates are preferably the diacid dichlorides of isophthalic acid, terephthalic acid, diphenyl ether-4,4'-dicarboxylic acid and naphthalene-2,6-dicarboxylic acid.
• Polydiorganosiloxane-polycarbonate block copolymers are characterized in that they contain in the polymer chain, on the one hand, aromatic carbonate structural units (1) and, on the other hand, aryloxy end group-containing polydiorganosiloxanes (2).
• Such polydiorganosiloxane polycarbonate block copolymers are e.g. From US-PS 3,189,662, US-PS 3,821,325 and US-PS 3,832,419.
• Preferred polydiorganosiloxane-polycarbonate block copolymers are prepared by reacting alpha, omega Bishydroxyaryloxyend phenomenon-containing polydiorganosiloxanes together with other diphenols, optionally with the use of branching agents in the usual amounts, for. B. by the two-phase interface method (see H. Schnell, Chemistry and Physics of Polycarbonate Polymer Rev. Vol., DC, page 27 et seq., Interscience Publishers New York 1964), wherein in each case the ratio of the bifunctional phenolic reactants is selected such that from which the inventive content of aromatic carbonate structural units and diorganosiloxy units results.
• Such alpha, omega Bishydroxyaryloxyend phenomenon-containing polydiorganosiloxanes are z. B. from US 3 419 634 known.
• the preferred acrylate-based polymeric particles to be used in accordance with the invention having a core-shell morphology are, for example and preferably, those disclosed in EP-A 634445.
• the polymeric particles preferably have a core of a rubbery vinyl polymer.
• the rubbery vinyl polymer may be a homo- or copolymer of any of the monomers having at least one ethylenically unsaturated group which are known to those skilled in the art for addition polymerization under the conditions of emulsion polymerization in an aqueous medium. Such monomers are listed in US 4,226,752, column 3, lines 40-62.
• the polymeric particles contain a core of rubbery alkyl acrylate polymer wherein the alkyl group has from 2 to 8 carbon atoms, optionally copolymerized with from 0 to 5% crosslinker and from 0 to 5% graft crosslinker, based on the total weight of the core.
• the rubbery alkyl acrylate is preferably copolymerized with up to 50% of one or more copolymerizable vinyl monomers, for example those mentioned above.
• Suitable crosslinking and graftlinking monomers are well known to those skilled in the art and are preferably those described in EP-A-0269324.
• the polymeric particles are useful to impart light scattering properties to the transparent plastics, preferably polycarbonate.
• the refractive index n of the core and the cladding / cladding of the polymeric particles is preferably within +/- 0.25 units, more preferably within +/- 0.18 units, most preferably within +/- 0.12 units of the refractive index of the polycarbonate.
• the refractive index n of the core and the sheath (s) is preferably not closer than +/- 0.003 units, more preferably not closer than +/- 0.01 units, most preferably not closer than +/- 0.05 units in the Refractive index of the polycarbonate.
• the refractive index is measured in accordance with ASTM D 542-50 and / or DIN 53 400.
• the polymeric particles generally have an average particle diameter of at least 0.5 microns, preferably from at least 1 microns to at most 100 microns, more preferably from 2 to 50 microns, most preferably from 2 to 15 microns. Preferably, at least 90%, most preferably at least 95% of the polymeric particles have a diameter greater than 2 microns
• the polymeric particles are a free-flowing powder, preferably in compacted form, ie pressed into pellets , also for dust reduction.
• the polymeric particles can be prepared in a known manner. Generally, at least one monomer component of the core polymer is subjected to emulsion polymerization to form emulsion polymer particles.
• the emulsion polymer particles are swollen with the same or one or more other monomer components of the core polymer, and the monomer (s) are polymerized within the emulsion polymer particles. The steps of swelling and polymerisation can be repeated until the particles have grown to the desired core size.
• the core polymer particles are suspended in a second aqueous monomer emulsion and a polymer shell of the monomer (s) is polymerized onto the polymer particles in the second emulsion.
• One or more coats may be polymerized on the core polymer.
• the preparation of core / shell polymer particles is described in EP-A 0 269 324 and in U.S. Patents 3,793,402 and 3,808,180.
• the brightness values can be further increased by using a small amount of optical brightener.
• An embodiment of the invention therefore represents a plastic composition according to the invention which may additionally contain from 0.001 to 0.2% by weight, preferably about 1000 ppm, of an optical brightener of the class bis-benzoxazoles, phenylcoumarins or bis-styrylbiphenyls.
• a particularly preferred optical brightener is Uvitex OB, from Ciba Specialty Chemicals.
• plastic compositions according to the invention can be prepared by extrusion.
• a polycarbonate granulate is fed to the extruder and melted in the plasticizing system of the extruder.
• the plastic melt is forced through a slot die and thereby deformed, brought to the desired final shape in the nip of a smoothing calender and shaped by means of reciprocal cooling on smoothing rolls and the ambient air.
• the polycarbonates of high melt viscosity used for extrusion are usually processed at melt temperatures of 260 to 32O 0 C, according to the cylinder temperatures of the plasticizing and die temperatures are set.
• Both the base layer and the optionally present coextrusion layer (s) of the moldings according to the invention may additionally contain additives such as, for example, UV absorbers and other customary processing aids, in particular mold release agents and flow agents, and the stabilizers customary for polycarbonates, in particular heat stabilizers and also antistatic agents, optical brighteners.
• additives such as, for example, UV absorbers and other customary processing aids, in particular mold release agents and flow agents, and the stabilizers customary for polycarbonates, in particular heat stabilizers and also antistatic agents, optical brighteners.
• additives such as, for example, UV absorbers and other customary processing aids, in particular mold release agents and flow agents, and the stabilizers customary for polycarbonates, in particular heat stabilizers and also antistatic agents, optical brighteners.
• additives such as, for example, UV absorbers and other customary processing aids, in particular mold release agents and flow agents, and the stabilizers customary for polycarbonates, in particular heat stabilizers and also anti
• the composition of the film additionally contains 0.01 to 0.5% by weight of a UV absorber of the classes benzotriazole derivatives, dimer benzotriazole derivatives, triazine derivatives, dimer triazine derivatives, diaryl cyanoacrylates.
• a UV absorber of the classes benzotriazole derivatives, dimer benzotriazole derivatives, triazine derivatives, dimer triazine derivatives, diaryl cyanoacrylates.
• the coextrusion layer may contain antistatics, UV absorbers and mold release agents.
• Suitable stabilizers are, for example, phosphines, phosphites or Si-containing stabilizers and further compounds described in EP-A 0 500 496.
• Examples are triphenylphosphites, diphenylalkylphosphites, phenyldialkylphosphites, tris (nonylphenyl) phosphite, tetrakis- (2,4-di-tert-butylphenyl) -4,4'-biphenylene-diphosphonite, bis (2,4-dicumylphenyl ) called petaerythritol diphosphite and triaryl phosphite.
• Particularly preferred are triphenylphosphine and tris (2,4-di-tert-butylphenyl) phosphite.
• Suitable mold release agents are, for example, the esters or partial esters of monohydric to hexahydric alcohols, in particular of glycerol, pentaerythritol or guerbet alcohols.
• Monohydric alcohols are, for example, stearyl alcohol, palmityl alcohol and Guerbet alcohols
• a dihydric alcohol is, for example, glycol
• a tetrahydric alcohol is, for example, glycerol
• tetrahydric alcohols are, for example, pentaerythritol and mesoerythritol
• fivefold alcohols are, for example, arabitol, ribitol and xylitol
• hexahydric alcohols are, for example, mannitol, Glucitol (sorbitol) and Dulcite.
• the esters are preferably the monoesters, diesters, triesters, tetraesters, pentaesters and hexaesters or mixtures thereof, in particular random mixtures, of saturated, aliphatic Qo to C 36 -monocarboxylic acids and optionally hydroxy-monocarboxylic acids, preferably with saturated, aliphatic C H to C 32 Monocarboxylic acids and optionally hydroxy-monocarboxylic acids.
• the commercially available fatty acid esters in particular of pentaerythritol and of glycerol, may contain ⁇ 60% of different partial esters as a result of the preparation.
• Saturated, aliphatic monocarboxylic acids having 10 to 36 carbon atoms are, for example, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, hydroxystearic acid, arachidic acid, behenic acid, lignoceric acid, cerotic acid and montanic acids.
• antistatic agents examples include cationic compounds, for example quaternary ammonium, phosphonium or sulfonium salts, anionic compounds, for example alkyl sulfonates, alkyl sulfates, alkyl phosphates, carboxylates in the form of alkali metal or alkaline earth metal salts, nonionic compounds, for example polyethylene glycol esters, polyethylene glycol ethers, fatty acid esters, ethoxylated fatty amines.
• Preferred antistatic agents are nonionic compounds.
• the plastic compositions according to the invention can be processed into polycarbonate films with a thickness of 35 ⁇ m to 1000 ⁇ m. Depending on the application, they can also be thicker.
• the films may also be multilayer composites of at least two solid shaped articles, for example films, which have been produced by extrusion. In this case, the films of the invention are composed of at least two polymer layers.
• the polycarbonate granules are fed to the hopper of an extruder and passes through this into the plasticizing system, consisting of screw and cylinder.
• the plasticizing system conveys and melts the material.
• the plastic melt is forced through a slot die.
• a filter device Between plasticizing and slot die a filter device, a melt pump, stationary mixing elements and other components can be arranged.
• the melt leaving the nozzle reaches a smoothing calender.
• a rubber roller For unilateral structuring of the film surface, a rubber roller was used.
• the final shaping takes place in the nip of the smoothing calender.
• the rubber rolls used for structuring the film surface are disclosed in DE 32 28 002 (or US equivalent 4,368,240) by Nauta Roll Corporation.
• the shape fixation is done by cooling and that alternately on the smooth rollers and in the ambient air.
• the other facilities are used for transport, the application of protective film, the winding of the extruded films.
• a masterbatch with the following composition was prepared:
• Shell Paraloid EXL 5137 from Rohm & Haas with a particle size of 2 to 15 ⁇ m and an average particle size of 8 ⁇ m with a proportion of 20% by weight.
• the system used consists of
• the screw has a degassing zone
• Roller is pivotable by +/- 45 ° relative to the horizontal;
• the third roller is a rubber roller to structure the film surface.
• a rubber roller was used for unilateral structuring of the film surface.
• the rubber rolls used for structuring the film surface are disclosed in DE 32 28 002 (or US equivalent 4,368,240) by Nauta Roll Corporation.
• the smoothing calender the final shaping and cooling of the material takes place. Subsequently, the film is transported through a trigger, it is applied on both sides of the protective film, then the winding of the film takes place.
• a masterbatch with the following composition was prepared:
• Acrylic scattering particles Techpolymer MBX-5 of the company Sekisui a particle size of 2 to 15 microns and a mean particle size of 5 microns with a share of 20 wt .-%.
• the compound is used to extrude 300 ⁇ m thick polycarbonate films 1340 mm wide.
• the system used consists of
• the screw has a degassing zone
• the melt reaches the smoothing calender whose rolls have the temperature given in Table 1.
• the smoothing calender takes the final shape and Cooling of the material.
• a rubber roller was used for unilateral structuring of the film surface. The rubber rolls used for structuring the film surface are disclosed in DE 32 28 002 (or US equivalent 4,368,240) by Nauta Roll Corporation. Subsequently, the film is transported through a trigger, it is applied on both sides of the protective film, then the winding of the film takes place.
• the luminance measurements were carried out on a backlight unit (BLU) from DS LCD, (LTA320W2-L02, 32 "LCD TV panel, with the aid of a Luminance Meter LS100 from Minolta, where the standard diffuser film was produced removed and replaced in each case by the films produced in Examples 3 and 5 respectively.
• BLU backlight unit
• the content of the scattering pigments and the light-scattering layer are the same and the layer thickness is 300 ⁇ m. Also, the base material used is the same. Above all, it is surprising that the diffuser films from Example 5 have the highest luminance in the BLLJ.
• Brightness was then examined with and without the slide set used in this backlight unit.
• the brightness was measured at a total of 9 different points of the backlight unit (with the help of a Minolta Luminance Meter LS100) and the mean value calculated from it.
• the examples show that the brightness is associated with the number of nanoscale particles. The fewer of these particles are present, the better the brightness.

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• Chemical & Material Sciences (AREA)
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• Polymers & Plastics (AREA)
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• Dispersion Chemistry (AREA)
• Manufacture Of Macromolecular Shaped Articles (AREA)
• Compositions Of Macromolecular Compounds (AREA)
• Optical Elements Other Than Lenses (AREA)
• Laminated Bodies (AREA)
• Extrusion Moulding Of Plastics Or The Like (AREA)

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  • 2005-10-05 DE DE102005047614A patent/DE102005047614A1/de not_active Withdrawn
• 2006
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