WO2006128737A1 - Procede de maquillage - Google Patents

Procede de maquillage Download PDF

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Publication number
WO2006128737A1
WO2006128737A1 PCT/EP2006/006149 EP2006006149W WO2006128737A1 WO 2006128737 A1 WO2006128737 A1 WO 2006128737A1 EP 2006006149 W EP2006006149 W EP 2006006149W WO 2006128737 A1 WO2006128737 A1 WO 2006128737A1
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WO
WIPO (PCT)
Prior art keywords
layer
make
film
decorated
carrier layer
Prior art date
Application number
PCT/EP2006/006149
Other languages
English (en)
Inventor
Aline Abergel
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR0551435A external-priority patent/FR2886146B1/fr
Application filed by L'oreal filed Critical L'oreal
Publication of WO2006128737A1 publication Critical patent/WO2006128737A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/645—Proteins of vegetable origin; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/732—Starch; Amylose; Amylopectin; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/736—Chitin; Chitosan; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8135—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers, e.g. vinyl esters (polyvinylacetate)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q3/00—Manicure or pedicure preparations
    • A61Q3/02—Nail coatings

Definitions

  • the invention concerns a method for making up/decorating keratinous materials by transferring a layer of make-up to facilitate the creation of semipermanent decorative patterns.
  • the invention concerns a method for making up/decorating the skin, lips, nails, hair, eyelashes or eyebrows.
  • non-permanent or semipermanent decorative patterns there are numerous methods that enable non-permanent or semipermanent decorative patterns to be made on the skin.
  • the expression non- permanent or semi-permanent is understood to mean a colouring that is retained on the skin for a period of between several hours and several weeks.
  • a common method of creating decorative patterns on the skin is by means of transfers.
  • transfer methods one involves transferring a printed image onto the skin after wetting a carrier layer covered with a water-soluble layer carrying the images.
  • the carrier layer is not very flexible, it is relatively difficult to cover certain surfaces, in particular uneven surfaces such as the back of the hands to which they are unable to conform perfectly without creasing.
  • henna which colours the horny layer of the skin and is thus able to remain on the surface of the skin for between 1 and 4 weeks.
  • the application of henna to the skin in a conventional manner calls for a degree of technical drawing skill and should preferably be carried out by an artist.
  • henna is generally applied in the form of a paste or a cream which stains the skin.
  • this paste can smear or can be improperly applied to the wrong area of the body surface by an unskilled hand.
  • this paste can also stain clothing.
  • French patent application FR-A-2 792 192 describes an adhesive patch device for make-up designed to be applied to the skin and then to be removed when the make-up is no longer wanted.
  • a device includes a detachable protective sheet or film, a reversible pressure adhesion layer, able to contain a make-up material, at least one layer selected from a layer bonded to the adhesive layer and able to contain a make-up material, and an outer protective layer.
  • the make-up device that is the vehicle for the decorative pattern (coloured or otherwise), said pattern being visible in relief, and being more or less blurred depending on its location and the nature and thickness of the layer in which the make-up material is incorporated.
  • some individuals may find that such a device is uncomfortable to wear by reason of the unpleasant sensation which can result therefrom, and the images are dependent on the carrier to which they are attached, imparting an artificial character to the make-up.
  • document FR-A-2 281 833 describes a method of decorating synthetic resin moulded articles which involves printing a pattern onto a transfer film such as a polyvinyl alcohol film which is placed in a bath, the articles to be decorated being immersed so as to apply the film against the surface of the article and thereby transfer the pattern to the surface of the article.
  • a transfer film such as a polyvinyl alcohol film which is placed in a bath
  • the invention discloses a method for making up/decorating keratinous materials, in particular skin, lips, nails or keratinous fibres, by means of a film forming a multi-layered structure incorporating a carrier layer including a material soluble in a solvent, the carrier layer being at least partially covered with at least one layer of make-up designed to make up/decorate the keratinous materials, the make-up layer including a material that is not soluble in the solvent, the method including the step of.
  • the carrier layer forming, upon the transfer of the make-up layer onto the surface to be made up/decorated, an outer layer of the film.
  • a soluble carrier layer makes it possible to obtain a flexible film, in particular when it starts to dissolve so that it is able to conform perfectly to relatively complex surfaces, that is to say surfaces including projections for example. Such surfaces, particularly the hands or the feet, can thus be readily decorated.
  • the carrier layer can be entirely covered by the make-up layer. It is then possible for example to choose a carrier layer of a particular shape so that the make-up layer to be transferred also has the same shape.
  • the carrier layer can be partially covered by the make-up layer so as to form at least one pattern.
  • the make-up layer designed to be transferred onto the surface to be decorated is drawn in a highly precise manner, which makes it possible to readily produce complicated and very accurate decorative patterns. Using several identical films, the make-up can additionally be reproducible.
  • the invention also discloses a method for making up/decorating keratinous materials, in particular the skin, lips, nails or keratinous fibres, by means of a film including a carrier layer incorporating a solvent-soluble material in which is included at least one make-up element designed to make up/decorate keratinous materials, the make-up element including a material that is not soluble in the solvent, the shape and/or dimensions of the carrier layer being different from the shape and/or dimensions of the make-up element, the method including the step of:
  • the decorative element can be made from a make-up composition or from a solid element such as a patch.
  • the decorative element can be smooth or can include projections.
  • the film can be placed on a surface of liquid solvent before being placed on the surface to be made up/decorated.
  • the surface to be made up/decorated can then be placed in the liquid solvent so as to position it against the make-up layer of the film previously placed on the surface of liquid solvent.
  • the film can be placed on the surface of liquid solvent with the make-up layer turned towards the surface of liquid solvent and the surface to be made up/decorated can be placed in the liquid solvent under the film.
  • the film can be placed on the surface of liquid solvent with the make-up layer facing away from the liquid solvent surface and the surface to be made up/decorated can be placed in the liquid solvent over the film.
  • the surface to be made up/decorated can then be removed from the solvent while the make-up layer is retained on the surface to be made up/decorated.
  • Solvent can also be applied on the surface which has just been made up/decorated while rubbing gently to remove any residues of the soluble carrier.
  • the film in a second embodiment, can be placed on the surface to be made up/decorated with the make-up layer against the surface to be made up/decorated before placing it in contact with the solvent.
  • the surface to be made up/decorated covered by the film can then be coated with liquid solvent to dissolve the carrier layer.
  • the film carrier layer used can include a water-soluble material. It can include at least one water-soluble polymer selected in particular from polyvinylpyrolidone, polyvinyl alcohol, caprolactam, acrylamide, water soluble or dispersible polysaccharides capable of forming a film in the dry state such as cellulose derivatives, starches and derivatives, pullulan, gum, pectin, alginate, carrageenan, galactomannan, agars, chitosan, hyaluronic acid, xanthan gum, water soluble or dispersible proteins capable of forming a film in the dry state such as gelatine, gluten, casein, zein and their natural or synthetic derivatives, acrylic copolymers of phosphorylcholine (lipidure), anion-cation complexes of the type gum arabic/gelatine or gum arabic/chitosan, or the association collagen/ glycosaminoglycan.
  • water-soluble polymer selected in particular from polyvinylpyr
  • the film can be placed in contact with an aqueous composition at a temperature ranging from 5°C to 60 0 C, and preferably from 2O 0 C to 30°C, and for a period ranging from 10 seconds to 10 minutes, preferably from 10 seconds to 2 minutes.
  • the carrier layer can include a film structure composed of, or including, a woven or non-woven fibrous material.
  • a bonding layer can be applied to the surface to be made up/decorated before placing it in the liquid solvent or before placing the film on the surface to be made up/decorated.
  • the bonding layer is designed to strengthen the attachment of the make-up layer to the surface to be made up/decorated.
  • the bonding layer can be a nail varnish when the surface to be made up/decorated is a nail.
  • the multi-layered structure of the film can include an adhesive layer.
  • the adhesive layer can include an adhesive polymer selected from acrylic adhesive polymers, silicone adhesive polymers, polyisobutylenes and/or mixtures thereof.
  • the adhesive layer can cover the make-up layer.
  • the adhesive layer can include a reactivatable adhesive, that is to say an adhesive which does not bond without having been activated by a reactivation substance, such as water.
  • the multi-layered structure of the film can include a peelable protective layer covering the make-up layer or the adhesive layer, which is removed before using the film thereby protecting the make-up layer before use.
  • the multi-layered structure of the film can include a layer of transparent varnish between the soluble carrier layer and the make-up layer which serves to protect the make-up layer once it is transferred onto the surface to be made up/decorated.
  • the surface to be made up/decorated covered by the make-up layer can be dried in the ambient air or by means of a heat source, in particular a hair dryer or a UV lamp.
  • a protective transparent layer can be applied on the made up/decorated surface after it has been dried so as to protect the make-up.
  • the protective layer can be a nail varnish when the surface to be made up/decorated is a nail, or a transparent gloss in the case of lip decoration.
  • the carrier layer can have a thickness between 10 ⁇ m and 300 ⁇ m, and preferably between 30 and 40 ⁇ m.
  • the carrier layer is readily able to deform, particularly after it has been placed in contact with solvent, so as to conform to the surface to be decorated. It is thus possible to decorate highly complex surfaces such as the back of the hands or feet.
  • the make-up layer can include a colouring composition which includes a coloured or colouring material selected from colourants of vegetable or synthetic origin, fat-dispersible or fat-soluble colourants, lakes, direct colourants, fluorescent, photochromic or thermochromic colourants and/or mixtures thereof, pigments or mother-of-pearl.
  • a colouring composition which includes a coloured or colouring material selected from colourants of vegetable or synthetic origin, fat-dispersible or fat-soluble colourants, lakes, direct colourants, fluorescent, photochromic or thermochromic colourants and/or mixtures thereof, pigments or mother-of-pearl.
  • the make-up layer can also include at least one or more sunscreens active in the UVA and/or the UVB spectrum, as well as cosmetic additives in particular selected from organic solvents such as alcohols, glycols, lower polyols, ionic or non-ionic thickeners, softeners, anti-free-radical agents, opacifiers, stabilisers, emollients, silicones, ⁇ -hydroxyacids, anti-foaming agents, hydrating agents, vitamins, perfumes, preservatives, surfactants, fillers, polymers, propellants, alkalising or acidifying agents, repellents, or any other ingredient normally used in the field of cosmetics, and mixtures thereof.
  • organic solvents such as alcohols, glycols, lower polyols, ionic or non-ionic thickeners, softeners, anti-free-radical agents, opacifiers, stabilisers, emollients, silicones, ⁇ -hydroxyacids, anti-foaming agents
  • FIG. 1 illustrates a perspective view of a film designed to be used in the make-up method according to the invention
  • Figure 2 illustrates a sectional view of the film in Figure 1 ;
  • FIG. 6 illustrates a perspective view of a second example of a film designed to be used in the make-up method according to the invention
  • FIG. 11 to 14 illustrate sectional views of different alternative embodiments of a film suitable for use in the make-up method according to the invention.
  • the make-up method according to the invention is designed to decorate keratinous materials such as the skin, lips, nails or keratinous fibres, by transferring a make-up layer initially present in a film forming a multi- layered structure.
  • the film includes a carrier layer including a solvent-soluble material, that is to say a carrier layer designed to solubilise when the film is placed in contact with a solvent for a certain period of time.
  • the carrier layer is covered by a make-up layer to be transferred which includes a material that is not soluble in the solvent designed to solubilise the carrier layer, but which can of course be soluble in another solvent.
  • the make-up layer includes a colouring composition which includes a coloured or colouring material, and which is designed to be visible on the surface to be decorated onto which it is to be transferred.
  • the film is placed in contact with the solvent and the surface to be decorated while the carrier layer constitutes an external face of the multi-layered structure.
  • the carrier layer then dissolves so that only the make-up layer, which does not itself dissolve in the solvent used, is left on the surface to be decorated.
  • composition of the carrier layer and the make-up layer is selected appropriately so that they are never soluble in the same solvent.
  • the carrier layer can include a water-soluble material or a material soluble in any other solvent, for example in an alcohol or an alcohol-based solution.
  • the carrier layer includes a water-soluble material
  • it can include for example at least one water-soluble polymer selected in particular from polyvinylpyrolidone, polyvinyl alcohol, caprolactam, acrylamide, water-soluble or dispersible polysaccharides capable of forming a film in the dry state such as cellulose derivatives, starches and derivatives, pullulan, gum, pectin, alginate, carrageenan, galactomannan, agars, chitosan, hyaluronic acid, xanthan gum, water-soluble or dispersible proteins capable of forming a film in the dry state such as gelatine, gluten, casein, zein and natural or synthetic derivatives thereof, acrylic copolymers of phosphorylcholine (lipidure), anion- cation complexes of the type gum arabic/gelatine or gum arabic/chitosan, or the association collagen/glycosaminoglycan.
  • water-soluble polymer selected in particular from polyvin
  • the colouring composition can include a skin colouring agent, i.e. a compound having a particular affinity for the skin enabling it to impart thereto a long-lasting artificial colour, possibly by reacting with amino acids in the skin or by accumulating and/or diffusing colouring agents in the horny layer.
  • a skin colouring agent i.e. a compound having a particular affinity for the skin enabling it to impart thereto a long-lasting artificial colour, possibly by reacting with amino acids in the skin or by accumulating and/or diffusing colouring agents in the horny layer.
  • the expression long-lasting colour is understood to mean colour that is resistant both to friction and to multiple washing with a solution containing surfactants.
  • the long-lasting colouring agent can be selected from compounds chosen from colourants of vegetable or synthetic origin, fat-dispersible or fat- soluble colourants, lakes obtained by fixing a vegetable or synthetic colourant on an inorganic substrate or on a polymer, direct colourants, fluorescent, photochrome or thermochromic colourants, and
  • extracts of dye plants such as for example Aleurites Moluccana WiIId, Alkanna Tinctoria Tausch, Areca Catechu L., Arrabidaea Chica E. and B., Bixa Orellana L.
  • henna also called henna, or from lmpatiens Balsamina, red wood extracts such as described in document WO98/44902, beetroot juice, anthocyans such as red fruit extracts, dihydroxyacetone, mono or polycarbonyl derivatives such as isatin, alloxan, ninhydrin, glyceraldehyde, mesotartric aldehyde, derivatives of pyrazoline-4,5-dione, and mixtures thereof, and these skin colouring agents may or may not be associated with directs colourants or indoline derivatives, and/or mixtures thereof.
  • colourant complexes such as for example those made by complexing conventional synthetic colourants with lysine palmitate-myristate and dipropylene glycol: mention may thus be made of the eosin (10%)/lysine palmitate- myristate/dipropylene glycol complex sold under the brand name "MMB Red 21/1 OR" by the company Phytocos.
  • lake mention may be made by way of examples of aluminium lakes, curcumin lakes, in particular the product marketed under the brand name "Eurovit curcumin lake” by the company Warner Jenkinson, phloxine B lake coated with perfluoropolymethylisopropyl ether ethoxy phosphate sold under the brand name "D&C Red #27 Al lake” by the company Cardre, tartrazine lake coated with polydimethylsiloxane sold under the brand name "Chroma wrap yellow 5 aluminium lake” by the company Enhance Technologies; calcium lakes, such as the Bordeaux Red B in a mixture of acrylate copolymers/water sold under the brand name "Rubis Covacryl WNL 4723", or Lithol B red coated with polydimethylsiloxane sold under the brand name "Chroma wrap red 7 calcium lake” by Enhance Technologies, zirconium, barium, barium-strontium lakes and/or mixtures thereof.
  • direct colourants such as benzene nitrate colourants, nitrophenylenediamines, nitrodiphenylamines, nitroanilines, esters of phenol nitrate or nitrophenols, nitropyridines, anthraquinone colourants, mono- or di-nitrogen colourants, triarylmethane colourants, azine colourants, acridine and xanthenic colourants, or metalliferous colourants and/or mixtures
  • the colouring composition may include a decorative makeup product which in this instance is a superficial and temporary colourant rather than a long-lasting one.
  • the colouring composition may include at least one colouring material, in particular selected from pigments, mother-of-pearl, fat-soluble colourants, and mixtures thereof.
  • pigments is understood to mean particles of any shape, white or coloured, mineral or organic, insoluble in the physiological medium, designed to colour the composition.
  • mother-of-pearl is understood to mean particles of any shape of iridescent colour, in particular as produced by certain molluscs in their shell or produced synthetically.
  • colourants is understood to mean generally organic compounds that are soluble in fatty media such as oils.
  • Pigments can be white or coloured, mineral and/or organic.
  • mineral pigments mention may be made of titanium dioxide, optionally surface treated, oxides of zirconium or cerium, as well as oxides of zinc, iron (black, yellow or red) or chromium, manganese violet, ultramarine blue, chromium hydrate and ferric blue, metallic powders such as aluminium powder, copper powder.
  • organic pigments mention may be made of carbon black, D&C type pigments, lakes based on cochineal carmine, barium, strontium, calcium, aluminium.
  • Pearlescent pigments can be selected from white pearlescent pigments such as mica coated with titanium, or bismuth oxychloride, coloured pearlescent pigments such as the mica-titanium coated with iron oxides, mica- titanium coated in particular with ferric blue or chromium oxide, mica-titanium coated with an organic pigment of the type described hereinbefore, and pearlescent pigments based on bismuth oxychloride.
  • Pigments can also be interferential, goniochromatic, fluorescent, reflecting, or in flake form.
  • Fat-soluble colourants include for example Sudan Red, D&C Red no. 17, D&C Green no. 6, ⁇ -carotene, soya oil, Sudan Brown, D&C Yellow no. 11 , D&C Violet no. 2, D&C Orange no. 5, quinoleine yellow, annatto, bromoacids.
  • the make-up layer can also include at least one or more sunscreens active in the UVA and/or UVB spectrum. It can also include cosmetic additives in particular selected from organic solvents such as alcohols, glycols, lower polyols, ionic or non-ionic thickeners, softeners, anti-free-radical agents, opacifiers, stabilisers, emollients, silicones, ⁇ -hydroxyacids, anti-foaming agents, hydrating agents, vitamins, perfumes, preservatives, surfactants, fillers, polymers, propellants, alkalising or acidifying agents, repellents, or any other ingredient normally used in the field of cosmetics, and mixtures thereof.
  • organic solvents such as alcohols, glycols, lower polyols, ionic or non-ionic thickeners, softeners, anti-free-radical agents, opacifiers, stabilisers, emollients, silicones, ⁇ -hydroxyacids, anti-foaming agents
  • Figures 1 and 2 illustrate a first example of a film 10 designed to be used to transfer a pattern onto a surface to be decorated.
  • the film illustrated is designed in particular for the application of patterns onto the skin, particularly on the back of the hand or foot, so as to form decorative patterns thereon in imitation of henna make-up for example.
  • the film 10 is advantageously solid and graspable. It has a flexible consistency so that it conforms to the shape of the area to be decorated when it is applied.
  • the film 10 is square shaped, but the scope of the invention is not exceeded by using a rectangular or disc-shaped film or any other shape. In the example described, it measures approximately ten centimetres on the side so that patterns can be applied to the whole of the back of the hand.
  • the film 10 forms a multi-layered structure which includes a carrier layer 11 in the form of a film, a non-woven or woven material.
  • the carrier layer 11 has for example a thickness between 10 and 300 ⁇ m, preferably between 30 and 40 ⁇ m.
  • the carrier layer 11 is for example made of a water-soluble material and can therefore solubilise in contact with an aqueous composition.
  • a carrier layer 11 made of polyvinyl alcohol polymer is used.
  • the carrier layer 11 dissolves in the water in a temperature range between 5 and 60 0 C and preferably between 20 0 C and 30°C, for a period between 10 seconds and 10 minutes, and preferably between 10 seconds and 2 minutes.
  • the dissolution time depends in particular on the thickness of the carrier layer 11 but also on the temperature of the water and the chemical composition of the carrier layer, in particular the rate of hydrolysis in relation to the alcohol content.
  • the carrier layer 11 is partially covered with a make-up layer 12 in the form of patterns.
  • the make-up layer is obtained from a colouring composition which has been pre-deposited on the carrier layer by coating or by various printing techniques such as heliogravure, screen printing, pad printing, offset, digital printing, flexography, and the like. It is thus possible to obtain very sharp and very precise patterns formed in one or more colours.
  • the colouring composition can include a skin colouring agent selected from fat-soluble colourants. It is possible for example to choose Sudan Red II, beta-carotene or bixine.
  • Figures 3 to 5 depict the different steps of a first example of a make-up method that uses the film just described according to Figures 1 and 2.
  • the film 10 is first placed on a surface 21 of water 20, for example in a container holding a certain volume of water so that the film 10 floats on the surface 21 , as illustrated in Figure 3.
  • the container can be a bowl, a washbasin or a bath.
  • the film 10 is placed so that the make-up layer 12 is turned to face the volume of water, the carrier layer 11 being uppermost.
  • the film 10 is left for a certain length of time in the volume of water to allow it to gelify.
  • the carrier layer will thus expand more or less in all directions, depending on the nature of the carrier layer, which gives it the ability to be stretched.
  • the carrier layer can then dissolve.
  • the hand 30 is immersed in the volume of water 20 by sliding it under the film 10. The hand is positioned so that the area to be decorated is placed against the make-up layer 12 of the film 10.
  • the film 10 can be placed on the water surface 21 with the make-up layer uppermost, that is to say turned away from the water volume. Instead of placing the hand under the film, it is placed over the film.
  • the film 10 conforms perfectly to the surface to be decorated by virtue of its flexibility which is further increased by the fact that the carrier has gelified and by the fact that it is able to be stretched.
  • the hand is then removed from the water with the pattern which remains on the hand because it has not dissolved. If necessary the hand may be re-immersed in the volume of water or held under a tap if residues of the water-soluble carrier remain, rubbing gently if required. It can also be envisaged to leave residues of the carrier layer on the make-up so as to protect it.
  • the decoration obtained is then dried in the ambient air or with hot air for example by means of a hair dryer or any other activation means if it is desired to accelerate the drying process.
  • a transparent protection layer can then be applied over the make-up by means of a brush or a spray. It is possible for example to apply a moisturising cream to increase the retention time of the make-up on the surface to be decorated.
  • the make-up illustrated in figure 5 is thus obtained.
  • the method just described is particularly suitable for making up complex surfaces, particularly surfaces that include depressions and projections, to which the film can perfectly conform.
  • Figures 6 to 10 depict the different steps of a second example of a make-up method which uses a film 10 similar to that previously described.
  • the film 10 illustrated in Figure 6 is in this instance designed to transfer a make-up layer onto a finger nail, for example a star-shaped pattern.
  • the film 10 is preferably smaller than that used to decorate a hand, the dimensions of the films being adapted to suit the surface to be decorated.
  • the film is square with 3 cm sides for example.
  • the carrier layer 11 is made from a polyvinyl alcohol polymer for example.
  • the colouring agent used to form the make-up layer 12 is a nail varnish containing pigments for example.
  • a bonding layer 40 is first applied to the nail to be decorated which strengthens the attachment of the make-up layer 12.
  • a layer of transparent nail varnish is applied for example by means of a brush as illustrated in Figure 7.
  • the film 10 is then placed on the nail with the make-up layer 12 facing towards the nail, the water-soluble carrier layer 11 being uppermost. If necessary light pressure can be exerted on the film to facilitate its adherence to the nail.
  • Water is then passed over the nail for example by holding the hand under a tap ( Figure 9).
  • a tap Figure 9
  • the decorative make-up illustrated in Figure 10 is obtained.
  • a transparent protective layer for example a transparent nail varnish, can be applied to the nail if necessary to protect the finished decoration.
  • the decorated surface is then dried in the ambient air or in hot air using a hair dryer or other activation means for example.
  • the method just described allows very precise placement of the decoration, which is particularly well suited to decoration of the finger nails.
  • the surface decorated using one or other of the methods just described can subsequently be cleaned using a make-up remover solvent.
  • the multi-layered structure of the film 10 can also include an adhesive layer 13 which serves to improve the attachment of the make-up layer on the surface to be decorated. This dispenses with the need to coat the surface to be decorated with a bonding layer.
  • the adhesive layer can also be deposited on the carrier layer 11 by printing or by coating.
  • the adhesive layer 13 includes for example a polymer composition formed on the basis of pressure sensitive adhesive polymers, that is to say materials that adhere instantly to the skin by the application of light pressure.
  • adhesive polymers mention may be made of acrylic adhesive polymers, silicone adhesive polymers, polyisobutylenes, and/or mixtures thereof. Mention may be made in particular of acrylic polymers sold under the brand name "GELVA” by the company Monsanto or under the brand name "DURO-TAK” by the company National Starch, and silicone polymers sold under the brand name "BIO-PSA X7-4302 Silicone” by the company Dow Corning.
  • the film 10 illustrated in Figure 11 includes for example an adhesive layer 13 placed over the make-up layer 12.
  • This adhesive layer 13 is designed to be placed in contact with the surface to be decorated 30.
  • a peelable protective film 14 is advantageously provided which can be removed before using the film 10.
  • the protective film 14 is a silicone paper for example.
  • a transparent protective layer 15 can be provided between the soluble carrier layer 11 and the make-up layer 12. This protective layer serves to increase the retention time of the make-up on the surface to be decorated 30.
  • This transparent protective layer 15 can for example be a transparent varnish applied on the carrier 11 either by printing or by coating.
  • a film 110 forming a multi-layered structure that includes a solvent-soluble carrier layer 111 incorporating at least one make-up element 112 designed to be transferred onto the surface to be decorated.
  • the make-up element 112 can be a pattern formed from a layer of a make-up composition, or as a variant can be a pattern formed by a solid structure that can be transferred onto the surface to be decorated.
  • the make-up element is not soluble in the solvent in which the carrier layer is soluble.
  • the carrier layer is square shaped for example, and the make-up element is a smooth star-shaped patch for example.
  • the patch can include projections.
  • the films 10 or 110 just described can be presented in the form of sheets with one or more decorations per sheet which can be cut out before a first use.
  • the films 10 will be packaged so as to be protected against moisture before being used.
  • they can be packaged in sachets or multi-layer flowpacks incorporating layers of aluminium and polymers, or in a box or a sealed pot.
  • the films 10 or 110 can also be presented in roll form including a continuous soluble carrier layer 11 or 111 covered by the make-up layer 12 or in which the make-up element 112 is incorporated, with the ability to cut the carrier layer to suit the size of the area to be decorated.
  • the soluble carrier layer 11 or 111 can include lines of weakening delineating the shape to be decorated.
  • the protective film 14 can be the portion in continuous roll form, the rest of the film then being presented in the form of labels for example.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne un procédé permettant de maquiller/décorer des matières kératineuses, au moyen d'un film (10) formant une structure multicouche intégrant une couche support (11) comprenant un matériau soluble dans un solvant (20), la couche support (11) étant recouverte, au moins en partie, par au moins une couche (12) de maquillage conçue pour maquiller/décorer les matières kératineuses. La couche de maquillage (12) comprend une matière non soluble dans le solvant: le procédé comprend les étapes suivantes: placer le film (10) en contact avec le solvant (20) et avec une surface à maquiller/décorer (30), pour favoriser une solubilisation au moins partielle de la couche support et transférer la couche de maquillage (12) sur la surface à maquiller/décorer (30). Dès le transfert de la couche de maquillage sur la surface à maquiller/décorer, la couche support (11) forme une couche extérieure du film.
PCT/EP2006/006149 2005-05-31 2006-05-19 Procede de maquillage WO2006128737A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR0551435A FR2886146B1 (fr) 2005-05-31 2005-05-31 Procede de maquillage
FR0551435 2005-05-31
US68835005P 2005-06-08 2005-06-08
US60/688,350 2005-06-08

Publications (1)

Publication Number Publication Date
WO2006128737A1 true WO2006128737A1 (fr) 2006-12-07

Family

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Application Number Title Priority Date Filing Date
PCT/EP2006/006149 WO2006128737A1 (fr) 2005-05-31 2006-05-19 Procede de maquillage

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Country Link
WO (1) WO2006128737A1 (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015097617A1 (fr) * 2013-12-27 2015-07-02 L'oreal Dispositif de transfert pour maquillage de matières kératiniques
WO2015097612A1 (fr) * 2013-12-27 2015-07-02 L'oreal Dispositif de transfert pour maquiller des matières kératiniques
WO2015097615A1 (fr) * 2013-12-27 2015-07-02 L'oreal Dispositif de transfert et traitement de maquillage de matières kératiniques
WO2015097616A1 (fr) * 2013-12-27 2015-07-02 L'oreal Dispositif de transfert pour maquiller des matières kératiniques
FR3015891A1 (fr) * 2013-12-27 2015-07-03 Oreal Ensemble et procede pour le maquillage par transfert des matieres keratiniques
KR20160102566A (ko) * 2013-12-27 2016-08-30 로레알 케라틴 물질의 메이크업을 위한 전사 장치
US9713580B2 (en) 2014-04-16 2017-07-25 The Procter & Gamble Company Device for applying a cosmetic composition
US10265260B2 (en) 2013-12-27 2019-04-23 L'oreal Transfer makeup process and related device
US10477938B2 (en) 2013-12-27 2019-11-19 L'oreal Makeup device comprising a plurality of cosmetic dyes
US11272777B2 (en) 2013-12-27 2022-03-15 L'oreal Transfer device for making up keratin materials

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5724999A (en) * 1996-12-05 1998-03-10 Kim; Ho Choong Method of decorating a finger nail
DE29810625U1 (de) * 1997-06-12 1998-11-05 Hufnagl Karl UV-Abdeckaufkleber
US5836998A (en) * 1997-10-08 1998-11-17 Mueller; Linda Adhesive stencil for body art
FR2792192A1 (fr) * 1999-04-19 2000-10-20 Lcw Les Colorants Wackherr Dispositif de maquillage pour la peau et son procede d'obtention

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5724999A (en) * 1996-12-05 1998-03-10 Kim; Ho Choong Method of decorating a finger nail
DE29810625U1 (de) * 1997-06-12 1998-11-05 Hufnagl Karl UV-Abdeckaufkleber
US5836998A (en) * 1997-10-08 1998-11-17 Mueller; Linda Adhesive stencil for body art
FR2792192A1 (fr) * 1999-04-19 2000-10-20 Lcw Les Colorants Wackherr Dispositif de maquillage pour la peau et son procede d'obtention

Cited By (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017502754A (ja) * 2013-12-27 2017-01-26 ロレアル ケラチン材料をメイクアップするための転写デバイス
KR102512107B1 (ko) * 2013-12-27 2023-03-20 로레알 케라틴 재료들을 메이크업하기 위한 전사 디바이스
WO2015097615A1 (fr) * 2013-12-27 2015-07-02 L'oreal Dispositif de transfert et traitement de maquillage de matières kératiniques
WO2015097616A1 (fr) * 2013-12-27 2015-07-02 L'oreal Dispositif de transfert pour maquiller des matières kératiniques
FR3015889A1 (fr) * 2013-12-27 2015-07-03 Oreal Dispositif pour le maquillage par transfert des matieres keratiniques
FR3015890A1 (fr) * 2013-12-27 2015-07-03 Oreal Dispositif pour le maquillage par transfert des matieres keratiniques
FR3015887A1 (fr) * 2013-12-27 2015-07-03 Oreal Dispositif et procede pour le maquillage par transfert des matieres keratiniques
FR3015871A1 (fr) * 2013-12-27 2015-07-03 Oreal Dispositif pour le maquillage par transfert des matieres keratiniques.
WO2015097617A1 (fr) * 2013-12-27 2015-07-02 L'oreal Dispositif de transfert pour maquillage de matières kératiniques
CN105873640A (zh) * 2013-12-27 2016-08-17 欧莱雅 用于化妆角蛋白材料的转移装置
CN105899184A (zh) * 2013-12-27 2016-08-24 欧莱雅 用于对角蛋白材料进行化妆的转移装置
KR20160102284A (ko) * 2013-12-27 2016-08-29 로레알 케라틴 재료들을 메이크업하기 위한 전사 디바이스
KR20160102566A (ko) * 2013-12-27 2016-08-30 로레알 케라틴 물질의 메이크업을 위한 전사 장치
KR20160103090A (ko) * 2013-12-27 2016-08-31 로레알 케라틴 물질의 메이크업을 위한 전사 장치 및 방법
CN106029173A (zh) * 2013-12-27 2016-10-12 欧莱雅 对角蛋白材料进行化妆的转移装置和方法
US20160324298A1 (en) * 2013-12-27 2016-11-10 L'oreal Transfer device for making up keratin materials
JP2017501812A (ja) * 2013-12-27 2017-01-19 ロレアル ケラチン材料をメイクアップするための転写デバイス
JP2017501814A (ja) * 2013-12-27 2017-01-19 ロレアル 転写デバイス及びケラチン物質のメーキャップ方法
FR3015891A1 (fr) * 2013-12-27 2015-07-03 Oreal Ensemble et procede pour le maquillage par transfert des matieres keratiniques
WO2015097612A1 (fr) * 2013-12-27 2015-07-02 L'oreal Dispositif de transfert pour maquiller des matières kératiniques
JP2020075145A (ja) * 2013-12-27 2020-05-21 ロレアル ケラチン材料をメイクアップするための転写デバイス
US10265260B2 (en) 2013-12-27 2019-04-23 L'oreal Transfer makeup process and related device
CN106029173B (zh) * 2013-12-27 2019-10-11 欧莱雅 对角蛋白材料进行化妆的转移装置和方法
US10477938B2 (en) 2013-12-27 2019-11-19 L'oreal Makeup device comprising a plurality of cosmetic dyes
US10532011B2 (en) 2013-12-27 2020-01-14 L'oreal Transfer device for making up keratin materials
EP4218940A3 (fr) * 2013-12-27 2023-08-09 L'oreal Dispositif de transfert pour le maquillage de matières kératiniques
JP2020203101A (ja) * 2013-12-27 2020-12-24 ロレアル 転写デバイス及びケラチン物質のメーキャップ方法
KR102294247B1 (ko) 2013-12-27 2021-08-25 로레알 케라틴 물질의 메이크업을 위한 전사 장치 및 방법
KR20210107919A (ko) * 2013-12-27 2021-09-01 로레알 케라틴 재료들을 메이크업하기 위한 전사 디바이스
US11178955B2 (en) 2013-12-27 2021-11-23 L'oreal Transfer device and process for making up keratin materials
US11191340B2 (en) 2013-12-27 2021-12-07 L'oreal Transfer device for making up keratin materials
KR102343157B1 (ko) * 2013-12-27 2021-12-23 로레알 케라틴 재료들을 메이크업하기 위한 전사 디바이스
US11272777B2 (en) 2013-12-27 2022-03-15 L'oreal Transfer device for making up keratin materials
KR102376795B1 (ko) * 2013-12-27 2022-03-18 로레알 케라틴 물질의 메이크업을 위한 전사 장치
JP7083804B2 (ja) 2013-12-27 2022-06-13 ロレアル ケラチン材料をメイクアップするための転写デバイス
US11445801B2 (en) 2013-12-27 2022-09-20 L'oreal Transfer device for making up keratin materials
US9713580B2 (en) 2014-04-16 2017-07-25 The Procter & Gamble Company Device for applying a cosmetic composition
US9839586B2 (en) 2014-04-16 2017-12-12 The Procter & Gamble Company Device for applying a cosmetic composition

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