WO2006125583A1 - Compositions d'apres-shampooing - Google Patents

Compositions d'apres-shampooing Download PDF

Info

Publication number
WO2006125583A1
WO2006125583A1 PCT/EP2006/004830 EP2006004830W WO2006125583A1 WO 2006125583 A1 WO2006125583 A1 WO 2006125583A1 EP 2006004830 W EP2006004830 W EP 2006004830W WO 2006125583 A1 WO2006125583 A1 WO 2006125583A1
Authority
WO
WIPO (PCT)
Prior art keywords
hair
aluminum oxide
conditioner
weight percent
conditioner composition
Prior art date
Application number
PCT/EP2006/004830
Other languages
English (en)
Inventor
Shimei Fan
Gabriel Lazaro Slavsky
Colleen Katherine Costello
Tracy Joella Sanborn
Jitendra Patel
Liang Bin Chen
Original Assignee
Unilever Plc
Unilever Nv
Hindustan Unilever Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever Plc, Unilever Nv, Hindustan Unilever Limited filed Critical Unilever Plc
Publication of WO2006125583A1 publication Critical patent/WO2006125583A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y5/00—Nanobiotechnology or nanomedicine, e.g. protein engineering or drug delivery
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/413—Nanosized, i.e. having sizes below 100 nm

Definitions

  • This invention relates to conditioner compositions for treating hair, which compositions comprise particulate aluminum oxide and a silicone additive.
  • the conditioner compositions are particularly suitable for imparting volumizing and conditioning properties to hair.
  • insoluble particulate materials in hair care compositions
  • Many of these materials function as frictionalizing agents.
  • frictionalizing agents may increase the perceived "volume" attributes of hair, e.g., fullness, body and bounce.
  • the use of frictionalizing agents may, however, increase the hair's tendency to tangle or snarl, and may otherwise negatively impact other sensory attributes related to the manageability of the hair or its ease of combing.
  • a conditioning agent for example, quaternary conditioning agents and organosilicones
  • quaternary conditioning agents and organosilicones may provide added manageability to hair care compositions that contain frictionalizing agent.
  • the benefits of such conditioning agents may come at the expense of volume properties, particularly when the hair treatment composition is a leave-on conditioner, that is, a conditioner that is applied and allowed to dry on the hair, rather than being rinsed from the hair within a short period of time (typically less than about 10 minutes) after its application.
  • leave-on conditioner that is, a conditioner that is applied and allowed to dry on the hair, rather than being rinsed from the hair within a short period of time (typically less than about 10 minutes) after its application.
  • These conditioning agents may, particularly when used at higher levels, i.e., levels above 1.0 wt.% on an active basis, result in leave-in formulations that impart a coated or "greasy" feel to the hair.
  • insoluble particulates e.g., silicas
  • silicas are anionic at the pH typical of many leave-on conditioners (i.e., pH of 4-7).
  • pH of 4-7 a pH typical of many leave-on conditioners
  • such particulates may give rise to stability issues when used in conditioners formulated to an acidic or neutral pH.
  • the difficulties in formulating conditioner compositions having a desirable balance of conditioning and volumizing properties, particularly, leave-on conditioner compositions tend to be exacerbated when the hair being treated is fine, thin hair.
  • Conditioner compositions that impart desirable volume and conditioning properties to hair, particularly fine, thin hair, are desired.
  • composition that is therein described as improving the appearance of volume in hair, which composition comprises: a) a liquid carrier, and
  • hair treated with said composition is said to demonstrate a "friction coefficient" of from about 1 to about 2 and a "hair feeling rating” of at least about 8.
  • the particles are disclosed as having a particle size of 0.1 micron or greater, preferably 0.5 or greater, and further that the particles preferably have a particle size of less than 300 microns, more preferably less than about 80 microns. Still more preferably, the particles are disclosed as ranging from about 1 to about 70 microns, even more preferably from about 2 microns to about 65 microns, and more preferably from about 2 microns to about 60 microns in diameter.
  • a surfactant selected from the group consisting of an anionic, cationic, nonionic, amphoteric, and zwitterionic surfactants and mixtures thereof;
  • phase separation initiator as therein more particularly described
  • U.S. 2003/0064047 to Barbuzzi et al. discloses aqueous hair care compositions comprising water-insoluble particles having a layered structure comprising oxygen atoms and silicon and/or phosphorous atoms, and further comprising organic functional groups which are covalently bonded to the silicon and/or phosphorus atoms in the layers.
  • U.S. 2003/0012757 to Barbuzzi et al. discloses aqueous hair treatment compositions comprising coated particles comprising a solid core having a D3,2 average particle size in the range from 10 to 700 nm, and a coating polymer covalently bonded to the solid core. Use of the coated particles in a hair treatment composition to impart body to the hair is described.
  • U.S. 2003/0095943 to Barbuzzi et al. discloses rinse-off hair conditioner compositions comprising (i) a cationic surfactant, (ii) a fatty alcohol material, and (iii) from 0.01 to 10 wt. % (preferably from 0.01 to 5 wt.%, more preferably form 0.05 to 3, wt . %, more preferably from 0.05 to 2.5 wt.
  • coated particles comprising (a) a solid core having a D3,2 average particle size in the range from 10 to 700nm (preferably from 10 to 500, more preferably from 20 to 300nm, yet more preferably from 20 to 200nm, and most preferably from 30 to 150nm) and (b) a coating of silicone polymer covalently bonded to the solid core.
  • sold cores polymers, which are preferably cross-linked (e.g., polystyrene, silicone elastomer powders, PTFE, rubber) , silicas, alumina, aluminum silicate, clays and colloidal metals.
  • U.S. 2004/0186030 to Hofrichter et al. discloses personal cleansing compositions containing a mixture of irregularly shaped particles and spherically shaped particles.
  • the application further discloses that the compositions "are intended to deliver the benefits of irregularly shaped particles, particularly hair volume and fullness, with benefits derived from the spherically shaped particles such as improved conditioning and combing.”
  • U.S. 6,524,563 to Wire et al. discloses a hair treatment composition which comprises 0.01-5 wt% of a particulate substance which is substantially unagglomerated or unaggregated prior to incorporation in the composition, which particulate substance has a modal primary particle size of 7-40nm, and a Youngs modulus of at least 4 Gpa, preferably at least 6 Gpa.
  • the particulate is unaggregated unagglomerated amorphous silica, with Ludox TM40, Ludox HS-40 , Ludox SM and Ludox LC, from DuPont, being identified as a preferred source of the silica .
  • conditioner molecules or molecular aggregates that have critical diameters larger than the largest average pore size of the microporous materials.
  • conditioner compositions more particularly, leave-on conditioner compositions, comprising: aluminum oxide particles, non-volatile organosilicone conditioning agent; cationic conditioning agent, fatty alcohol material, and an aqueous cosmetically acceptable carrier, can be formulated to impart desirable conditioning and volume/body properties to hair, particularly fine, thin hair.
  • a leave-on hair conditioner composition comprising:
  • a leave-on hair conditioner comprising:
  • compositions of this invention have particular application to the treatment and conditioning of fine, thin hair, but may also be used to add volume and body to all types of hair.
  • the present invention relates to methods of treating hair using the hair treatment compositions of this invention.
  • % or wt. % refers to the percent by weight of an ingredient as compared to the total weight of the composition or component that is being discussed. Except in the operating and comparative examples, or where otherwise explicitly indicated, all numbers in this description indicating amounts of materials or conditions of reaction, physical properties of materials and/or use are to be understood as modified by the word "about”. All amounts are by weight of the final composition, unless otherwise specified. It should be noted that in specifying any range of concentration, any particular upper concentration can be associated with any particular lower concentration.
  • the aluminum oxide used in the production of the subject compositions desirably has an average particle size, i.e., diameter, of from 0.01 to 1 micron, more particularly, from 0.05 to 0.5 micron and, in at least one embodiment of particular interest, from 0.1 to 0.3 micron.
  • the aluminum oxide has a particle size distribution such that at least 50 wt. %, preferably at least 90 wt. %, of the particles have a particle size within the particle size range of 0.01 to 1 micron, more particularly, 0.05 to 0.5 micron, that is to say, in at least one embodiment of this invention, it is desirable that the particles have a relatively uniform particle size.
  • the foregoing particle sizes refer to the sizes of the particles in the "as added" state, for example, as a raw material prior to its incorporation into the conditioner compositions of this invention.
  • such aggregation results in not more than 10%, preferably not more than 5% of the aluminum oxide having a diameter of less than 0.1 micron in the conditioner composition.
  • the compositions of this invention further comprise at least one ionizable salt.
  • the aluminum oxide particles generally have a regular, typically spherical, shape.
  • the aluminum oxide is a synthetic material. Fumed oxides and nanoparticles are representative, but not exhaustive of the aluminum oxides suitable for use herein.
  • the aluminum oxides may, but need not, be treated with one or more surface modifying agents. In at least one embodiment of interest, the aluminum oxide is untreated, i.e., uncoated.
  • the aluminum oxide is preferably incorporated into the subject compositions as dispersions, for example, as aqueous colloidal dispersions.
  • Aluminum oxides are commercially available from numerous suppliers, including, for example, Degussa and Cabot.
  • the aluminum oxide is present in the compositions of this invention in an amount of from 0.1 to 5 wt.%, preferably from 0.3 to 2 wt. %, and in an embodiment of particular interest from 0.1 to 1 wt . %.
  • the wt.% of the aluminum oxide refers to the amount of aluminum oxide present in the compositions of this invention exclusive of any carrier in which it is added (i.e., aluminum oxide on an active basis).
  • the charge density of the aluminum oxide component is at least 0.05 meq/g, preferably at least 0.08 meq/g.
  • Charge densities may be calculated by anionic potentiometric titration testing, a description of which is provided in the Examples that follow.
  • the charge density of the aluminum oxide refers to the charge density of the component as added, inclusive of any carrier in which the particles are supplied.
  • non-volatile organosilicone conditioning agents suitable for use herein are silicon-containing conditioners such as for example, polyorganosiloxanes, in particular polydimethylsiloxanes that have the CTFA designation dimethicone, as well as polydimethyl siloxanes having hydroxyl end groups, which have the CTFA designation dimethiconol .
  • silicon-containing conditioners such as for example, polyorganosiloxanes, in particular polydimethylsiloxanes that have the CTFA designation dimethicone, as well as polydimethyl siloxanes having hydroxyl end groups, which have the CTFA designation dimethiconol .
  • silicone gums having a slight degree of cross- linking as are described for example in WO 96/31188.
  • the polyorganosiloxane is commonly available as an emulsion in a cosmetically acceptable vehicle.
  • Emulsified silicones for use in the compositions of the invention will typically have an average silicone droplet size in the composition of less than 30 ⁇ m, preferably less than 20 ⁇ m, more preferably less than 10 ⁇ m, and in at least one embodiment of interest, from 0.01 to 1 ⁇ m. Silicone emulsions having an average silicone droplet size of ⁇ 0.15 ⁇ m are generally termed microemulsions .
  • emulsions DC2-1766, DC-1784, DC-1785, DC-1786, DC2-1310BB and microeraulsions DC2-1865 and DC2-1870 all available from Dow Corning. These are all emulsions/microemulsions of dimethiconol.
  • ultra-high molecular weight linear silicones such as Dow Corning HMW-2220 nonionic emulsion are suitable for use herein.
  • Cross-linked silicone gums are also available in a pre-emulsified form, which is advantageous for ease of formulation.
  • a preferred example is the material available from Dow Corning as DC-1787HS, which is an emulsion of cross-linked dimethiconol gum.
  • DC2-1391 is a microemulsion of cross- linked dimethiconol gum.
  • a further preferred class of organosilicones for inclusion in the conditioners of the invention are amino functional silicones.
  • amino functional silicone is meant a silicone containing at least one primary, secondary or tertiary amine group, or a quaternary ammonium group.
  • suitable amino functional silicones include: polysiloxanes having the CTFA designation
  • aminodimethicone aminodimethicone
  • Specific examples of amino functional silicones suitable for use in the invention are the aminosilicone oils DC2-8220, DC2-8166, and DC2-8466 (all ex Dow Corning) .
  • emulsions of amino functional silicone oils with non-ionic and/or cationic surfactant are also suitable for use herein.
  • Pre-formed emulsions of amino functional silicone are available from suppliers of silicone oils such as Dow Corning and General Electric. Specific examples include DC929 Cationic Emulsion, DC939 Cationic Emulsion, and the non-ionic emulsions DC2-7224, DC2-8177 and DC2-8154 (all ex Dow Corning) .
  • Emulsions of amino functional silicones with silicone gums are also suitable for use herein.
  • Organosilicone conditioning agents of particular interest in the practice of this invention are polydialkysiloxanes, preferably, dimethicone, dimethiconol and/or aminodimethicone .
  • the organosilicone conditioning agents are generally present in the subject compositions in an amount of from 0.1 to 5 wt. %, preferably from 0.5 to 3wt . % and, in an embodiment of particular interest, from 0.8 to 2 wt . %.
  • the wt.% of the organosilicone refers to the amount of organosilicone present in the compositions of this invention exclusive of any carrier in which it is added (i.e., organosilicone on an active basis) .
  • the relative amounts of aluminum oxide and nonvolatile organosilicone are selected to provide a good balance of conditioning and body/volume properties.
  • the ratio, by weight, of aluminum oxide particles to non-volatile organosilicone conditioning agent is from 1:5 to 1:1.5, more particularly, from 1:5 to 1:1.
  • the ratio, by weight, of aluminum oxide to non-volatile organosilicone conditioning agent is from 1:4 to 0.8 to 1, more particularly, from 1:3 to 0.8:1. Such ratios are on an actives basis.
  • the cationic conditioning agents suitable for use herein are cationic surfactants that contain amino or quaternary ammonium hydrophilic moieties, which are positively charged when dissolved in the aqueous composition of the present invention.
  • Suitable cationic surfactants are those corresponding to the general formula:
  • Ri, R 2 , R 3 , and R 4 are independently selected from (a) an aliphatic group of from 1 to 22 carbon atoms, or (b) an aromatic, alkoxy, polyoxyalkylene, alkylamido, hydroxyalkyl, aryl or alkaryl group having up to 22 carbon atoms; and X is a salt-forming anion such as those selected from halogen, (e.g. chloride, or bromide), acetate, citrate, lactate, glycolate, phosphate, nitrate, sulfate, and alkylsulfate radicals .
  • halogen e.g. chloride, or bromide
  • the aliphatic groups can contain, in addition to carbon and hydrogen atoms, ether linkages, and other groups such as amino groups.
  • the longer chain aliphatic groups e.g., those of about 12 carbons, or higher, can be saturated or unsaturated.
  • Monoalkyl quats are cationic surfactants having the general formula described above wherein Ri, R 2 and R 3 , which may be the same or different, are C1-C4 alkyl groups and R 4 is a C8 or greater, preferably C14 to C22, hydrocarbyl group, preferably alkyl.
  • R 4 is C16 to C22 alkyl.
  • the monoalkyl quats may but need not, be in the form of mixtures.
  • Dialkyl quats suitable for use herein include cationic conditioning surfactants having the general formula described above wherein Ri and R 2 , which may be the same or different, are C1-C4 alkyl group, and R 3 and R 4 , which may be the same or different, are C8 or greater, preferably C14 to C22, hydrocarbyl groups, preferably alkyl.
  • the dialkyl quats may, but need not, be in the form of mixtures.
  • Suitable cationic surfactants include quaternary ammonium compounds, particularly trimethyl quaternary compounds .
  • Preferred cationic conditioning agents include cetyltrimethylammonium chloride, pyridinium chloride, docosyl trimethyl ammonium chloride (behentrimonium chloride) , tetramethylammonium chloride, tetraethylammonium chloride, octyltrimethylammonium chloride, dodecyltrimethylammonium chloride, hexadecyltrimethylammonium chloride, octyldimethylbenzylammonium chloride, decyldimethylbenzylammonium chloride, stearyldimethylbenzylammonium chloride, didodecyldimethylammonium chloride, dioctadecyldimethylammonium chloride, tallowtrimethylammonium chloride, cocotrimethylaitimonium chloride, PEG-2 oleylammonium chloride and salts of these where the chloride is replaced by halogen (e.g.,
  • cationic conditioning agents include those materials having the CTFA designations Quaternium-5, Quaternium-31 and Quaternium-18. Mixtures of any of the foregoing materials may also be suitable.
  • a particularly useful cationic conditioning agent for use in hair conditioners of the invention is cetyltrimethylammonium chloride, available commercially, for example as GENAMIN CTAC, ex Hoechst Celanese.
  • the cationic conditioning agent is present in the compositions of this invention in an amount of from 0.1 to 10 wt. %, preferably from 0.5 to 5 wt. % and, in an embodiment of particular interest, from 0.5 to 3 wt % .
  • the total amount of conditioner present in the compositions of this invention is an amount of at least 1 wt. %, more particularly from 1 to 10 wt.%, preferably from 1 to 5 wt.%.
  • compositions of the invention additionally comprise at least one fatty alcohol material.
  • fatty alcohol material encompasses both alkoxylated and non-alkoxylated fatty alcohols, as well as their corresponding fatty acids.
  • the alkyl chain of the fatty alcohol is fully saturated.
  • Representative fatty alcohols comprise from 8 to 22 carbon atoms, more preferably 16 to 22 carbon atoms.
  • suitable fatty alcohols include cetyl alcohol, stearyl alcohol and mixtures thereof.
  • Alkoxylated, (e.g. ethoxylated or propoxylated) fatty alcohols having from about 12 to about 18 carbon atoms in the alkyl chain can be used in place of, or in addition to, the fatty alcohols themselves. Suitable examples include ethylene glycol cetyl ether, polyoxyethylene (2) stearyl ether, polyoxyethylene (4) cetyl ether, and mixtures thereof.
  • the amount of fatty alcohol material in the conditioners of this invention is suitably from 0.1 to 10 wt . %, preferably from 0.1 to 5 wt. %,and, in at least one embodiment of particular interest, from 1 to 3 wt%.
  • the weight ratio of the cationic conditioning agent to fatty alcohol is preferably from 10:1 to 1:10, more particularly from 3:1 to 1:6, and, in one embodiment of particular interest, from 1:1 to 1:6.
  • the use of these materials is also advantageous in that they contribute to the overall conditioning properties of compositions of the invention.
  • the carrier for the subject compositions comprises water and, optionally, one or more additional cosmetically acceptable solvents and/or diluents. Desirably, the carrier consists essentially of water.
  • the conditioner compositions of this invention preferably comprise carrier in an amount of from 80 to 98 wt. % and, in one embodiment of interest, from 85 to 96 wt . % .
  • compositions of the invention are formulated to a pH of 4 to 7, preferably 4.5 to 5.5.
  • compositions of the invention may be included in compositions of the invention.
  • additional ingredients include, for example, fragrances, perfumes, dyes, coloring agents, buffering or pH adjusting agents, suspending aids, additional conditioning agents, surfactants, viscosity modifiers, thickening agents, suspending agents, opacifiers, pearlizers, sunscreens, antioxidants, preservatives, antibacterial agents, proteins, amino acids, moisturizing agents, herb or other plant extracts and other natural ingredients .
  • the hair treatment of this invention may be prepared by conventional techniques.
  • the conditioner compositions may be formulated into any number of product forms, including, for example, creams, lotions, gels, mousses, mists, foams, and sprays.
  • the conditioners of this invention are applied to dry or, preferably wet or moistened hair.
  • the hair may be styled while the conditioner is wet or dry, with styling preferably taking place during blow-drying.
  • Leave-on conditioners were formulated by preparing compositions having the formulations described in Table 1 were prepared.
  • Charge density is calculated by means of the following formula :
  • N SLS the standardized concentration of the SLS solution used in the titration (eq/L)
  • V the volume of the SLS titrant (itiL)
  • the SLS solution is standardized by using it to titrate a solution of 0.075 ⁇ 0.005g of benethionium chloride in 75 ml of deionized water, using a surfactant sensitive electrode as described above.
  • the normality of the SLS solution (eq/L) is determined by means of the following equation:
  • N (W B c) (PurityBc)/ (V SLS ) (448. lg/eq) where:
  • V SLS the volume of the SLS titrant (L)
  • N SLS is the average normality of the SLS solution determined on triplicate analyses, where an accuracy of ⁇ 0.0005N is obtained between replicates.
  • the benethionium chloride used in the standardization of the SLS solution was Hyamine 1622 (99% purity) .
  • the hair was shampooed and rinsed thoroughly.
  • a first leave-on conditioner was applied to one side of the head and massaged evenly the hair on that side;
  • a second leave-on conditioner was applied to the other side of the head and massaged evenly into the hair on that side.
  • Leave-on conditioner was applied in an amount of about 1.6g per half-head of hair.
  • the panelists were instructed to blow- dry and style their hair, however, the only additional material that could be used by the panelists was hairspray, which could only be applied after the evaluation of the leave-on conditioner. After the styling was complete, the panelists evaluated wet and dry attributes for each side of their hair. Salon test results are reported in Table 2.
  • conditioner A a composition comprising aluminum oxide, organosilicone, cationic conditioning agent, fatty alcohol and water, was perceived as imparting a cleaner feel and less greasiness than both conditioner C (a composition free of hard particles), and conditioner B, an otherwise identical composition containing silica rather than aluminum oxide particles.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Inorganic Chemistry (AREA)
  • Biophysics (AREA)
  • Biotechnology (AREA)
  • General Engineering & Computer Science (AREA)
  • Medical Informatics (AREA)
  • Medicinal Chemistry (AREA)
  • Molecular Biology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une composition d'après-shampooing pour cheveux comprenant : des particules d'oxyde d'aluminium, au moins un agent après-shampooing à base d'organosilicone, au moins un agent après-shampooing cationique, au moins un matériau à base d'alcool gras et un véhicule aqueux acceptable du point de vue cosmétique. L'invention concerne également des procédés de traitement des cheveux utilisant de telles compositions.
PCT/EP2006/004830 2005-05-23 2006-05-17 Compositions d'apres-shampooing WO2006125583A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US68373305P 2005-05-23 2005-05-23
US60/683,733 2005-05-23

Publications (1)

Publication Number Publication Date
WO2006125583A1 true WO2006125583A1 (fr) 2006-11-30

Family

ID=36653277

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2006/004830 WO2006125583A1 (fr) 2005-05-23 2006-05-17 Compositions d'apres-shampooing

Country Status (1)

Country Link
WO (1) WO2006125583A1 (fr)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020054862A1 (en) * 2000-09-20 2002-05-09 Beatrice Perron Washing composition comprising particles of aluminium oxide, at least one conditioning agent and at least one detergent surfactant
US20030064047A1 (en) * 2001-04-30 2003-04-03 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Hair care compositions
US20030091521A1 (en) * 2001-10-03 2003-05-15 Sanjeev Midha Composition for improving hair volume
US20030134759A1 (en) * 2001-11-02 2003-07-17 The Procter & Gamble Co. Composition containing a cationic polymer and water insoluble solid material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020054862A1 (en) * 2000-09-20 2002-05-09 Beatrice Perron Washing composition comprising particles of aluminium oxide, at least one conditioning agent and at least one detergent surfactant
US20030064047A1 (en) * 2001-04-30 2003-04-03 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Hair care compositions
US20030091521A1 (en) * 2001-10-03 2003-05-15 Sanjeev Midha Composition for improving hair volume
US20030134759A1 (en) * 2001-11-02 2003-07-17 The Procter & Gamble Co. Composition containing a cationic polymer and water insoluble solid material

Similar Documents

Publication Publication Date Title
RU2319477C2 (ru) Композиция для ухода за волосами, содержащая композитные частицы из глины и заряженной органической молекулы
DE60025641T4 (de) Haarbehandlungsmittel enthaltend partikuläre substanzen
DE60016708T2 (de) Kosmetische Zusammensetzungen, die eine amphotere Stärke und ein kationisches Konditionierungsmittel enthalten, und deren Verwendungen
DE60031494T2 (de) Kosmetische Zusammensetzungen enhaltend ein Vinyldimethicon/Dimethicon Copolymer und ein Konditionierungsmittel, und ihre Anwendungen
DE60025121T2 (de) Kosmetische Zusammensetzungen enthaltend ein Vinyldimethicone/Dimethicon-Copolymer und ein Silicon und deren Verwendung
EP1383470B1 (fr) Compositions pour traitement capillaire
DE60311190T2 (de) Kosmetische Zusammensetzung, die ein quartäres Silikon, einen kationischen grenzflächenaktiven Stoff und zwei kationische Polymere enthält, und Verfahren zur kosmetischen Behandlung
DE60037992T2 (de) Kosmetische Emulsionzusammensetzungen enthaltend ein Vinyldimethicon/Dimethicon Copolymer und ein kationisches Tensid und ihre Anwendungen
US20060057096A1 (en) Cosmetic composition comprising at least one cationic surfactant, at least one aminated silicone, at least one fatty alcohol, and at least one diol
KR101150604B1 (ko) 모발 컨디셔닝 조성물
DE60209220T2 (de) Haarpflegemittel
MX2011000321A (es) Composicion acondicionadora de cabello comprendiendo tres clases de silicones.
EP2916803B1 (fr) Composition comprenant un composé dicarbonyle et procédé pour le lissage de cheveux utilisant cette composition
WO2006125583A1 (fr) Compositions d'apres-shampooing
DE102017215071A1 (de) Leistungsstarke Haarbehandlungsmittel mit gesteigerter Pflegewirkung
JP4166146B2 (ja) 無機粒子とポリエチレンイミンを含有する化粧品組成物
EP1383471B2 (fr) Composition pour le soin des cheveux
US20040152620A1 (en) Cosmetic composition containing mineral particles and a polyethyleneimine
DE102008004402A1 (de) Pulverförmige Zusammensetzung zur Form- und Glanzgebung keratinischer Fasern
WO2010046096A2 (fr) Préparations de soin capillaire contenant un nouveau type d'élastomères de siloxane
JP2023080777A (ja) 整髪剤組成物
DE102016225466A1 (de) Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern
DE102014222801A1 (de) Mittel und Verfahren zur temporären Verformung keratinhaltiger Fasern
MXPA00010163A (en) Cosmetic emulsion compositions containing a vinyldimethicone/dimethicone copolymer and a surfactant and their uses

Legal Events

Date Code Title Description
DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
NENP Non-entry into the national phase

Ref country code: DE

WWW Wipo information: withdrawn in national office

Country of ref document: DE

NENP Non-entry into the national phase

Ref country code: RU

WWW Wipo information: withdrawn in national office

Country of ref document: RU

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 06743015

Country of ref document: EP

Kind code of ref document: A1

122 Ep: pct application non-entry in european phase

Ref document number: 06743015

Country of ref document: EP

Kind code of ref document: A1