WO2006054552A1 - 超音波処理装置及び超音波処理方法 - Google Patents
超音波処理装置及び超音波処理方法 Download PDFInfo
- Publication number
- WO2006054552A1 WO2006054552A1 PCT/JP2005/020947 JP2005020947W WO2006054552A1 WO 2006054552 A1 WO2006054552 A1 WO 2006054552A1 JP 2005020947 W JP2005020947 W JP 2005020947W WO 2006054552 A1 WO2006054552 A1 WO 2006054552A1
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- Prior art keywords
- ultrasonic
- medium
- processing
- ultrasonic waves
- present
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Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
- A61L2/025—Ultrasonics
Definitions
- the present invention relates to an ultrasonic processing apparatus and an ultrasonic processing method.
- an ultrasonic treatment apparatus that generates ultrasonic waves, irradiates an affected area as a treated area coated with a drug, and transmits the drug to treat the affected area, for example, treat athlete's foot
- An ultrasonic sterilization apparatus is provided as an example (see, for example, Patent Document 1) o
- Patent Document 1 Japanese Unexamined Patent Application Publication No. 2004-135954
- the present invention solves the problems of the conventional ultrasonic sterilization apparatus and provides an ultrasonic processing apparatus and an ultrasonic processing method capable of performing processing of a processing target without using a drug. For the purpose.
- the processing tank for immersing the processing target in the medium, the ultrasonic element that generates the ultrasonic wave, and the ultrasonic element are used.
- a diffusion device for diffusing ultrasonic waves is used.
- the diffusion device is further disposed in contact with an ultrasonic element, and resonates by receiving an ultrasonic wave generated by the ultrasonic element. Diffuse sound waves and irradiate the affected area.
- the diffusing device is a diffusing lens provided with a convex surface formed to protrude forward.
- the diffusion device is a rod-like body formed by projecting upward from the bottom wall of the processing tank.
- the diffusion device is a cylindrical body formed by projecting upward on the bottom wall of the processing tank.
- Still another ultrasonic processing apparatus of the present invention includes a processing tank for immersing the processing target in a medium and an ultrasonic element for generating ultrasonic waves.
- the ultrasonic elements facing each other are arranged so as to be shifted so that the radiation axes do not overlap.
- a processing tank that accommodates a medium, an ultrasonic element that is disposed at a predetermined location of the processing tank and generates ultrasonic waves, and the processing tank And a support member which is disposed so as to be movable in contact with the medium and for supporting the portion to be processed.
- the support member is formed with a hole for raising the medium by driving the ultrasonic wave and attaching the medium to the processing target.
- a fluid medium having water retention property is attached to a portion to be treated, ultrasonic waves are generated, and the fluid medium is irradiated with the ultrasonic waves.
- the processing tank for immersing the processing target in the medium, the ultrasonic element that generates the ultrasonic wave, and the ultrasonic wave generated by the ultrasonic element.
- a diffusing device for diffusing sound waves.
- the ultrasonic wave generated by the ultrasonic element is irradiated to the medium in the processing tank and decomposes the medium to generate hydroxyl radicals, the target part without using the drug is used. Processing can be performed.
- the diffusion device receives the ultrasonic wave generated by the ultrasonic element, diffuses the ultrasonic wave and irradiates the processing target part, the processing target part can be reliably processed.
- FIG. 1 is a diagram showing an arrangement state of ultrasonic elements of a processing tank in a first embodiment of the present invention.
- FIG. 2 is a diagram showing a control circuit of the ultrasonic sterilizer according to the first embodiment of the present invention.
- FIG. 3 is a diagram showing an oscillation circuit according to the first embodiment of the present invention.
- FIG. 4 is a diagram showing an arrangement state of ultrasonic elements of the treatment tank in the second embodiment of the present invention.
- FIG. 5 is a diagram illustrating a diffusion device according to a third embodiment of the present invention.
- FIG. 6 is a diagram showing an ultrasonic sterilizer according to a fourth embodiment of the present invention.
- FIG. 7 is a cross-sectional view of a jewel sheet according to a fifth embodiment of the present invention.
- ⁇ 8 It is a perspective view of a mounting plate member in the sixth embodiment of the present invention.
- FIG. 10 is a plan view of a treatment tank in a seventh embodiment of the present invention.
- FIG. 11 is a diagram illustrating a first example of a diffusion device according to a seventh embodiment of the present invention.
- FIG. 12 is a diagram showing a second example of the diffusion device according to the seventh embodiment of the present invention.
- FIG. 13 is a view showing a usage mode of an ultrasonic sterilizer according to a seventh embodiment of the present invention.
- FIG. 1 is a diagram showing an arrangement state of ultrasonic elements of a treatment tank according to the first embodiment of the present invention
- FIG. 2 is a control circuit of the ultrasonic sterilizer according to the first embodiment of the present invention
- FIG. 3 is a diagram showing an oscillation circuit according to the first embodiment of the present invention.
- reference numeral 11 denotes a processing tank having a predetermined shape, and in the present embodiment, a box-like shape having an open top surface.
- the processing tank 11 includes a bottom wall 12 and the bottom wall 12. Get up from
- water is contained as a medium for transmitting ultrasonic waves to the inside.
- a foot is placed in the treatment tank 11 so that at least a part to be treated of the foot, that is, an affected part can be immersed in water.
- a liquid other than water can be used as the medium.
- the treatment tank 11 includes a bath that has a size that can immerse the entire body, such as a bathtub, in addition to a bath that has a size sufficient to immerse the affected part in water. It is.
- At least one, in the present embodiment, four ultrasonic elements mi are attached to predetermined portions of the side wall 13.
- the ultrasonic frequency is set to a predetermined value from 950 [kHz] to 2 [MHz], and the output is set to 10 [mW] to 20 [W].
- Each of the ultrasonic elements mi is constituted by a ceramic vibrator, for example.
- a temperature sensor 15 as a temperature detection unit that detects the temperature of water is attached to a predetermined portion of the side wall 13.
- each of the ultrasonic elements mi and the temperature sensor 15 can be attached to the force bottom wall 12 adapted to be attached to the side wall 13.
- a heater 16 as a heating member for heating the water in the treatment tank 11 is disposed in the treatment tank 11.
- 20 is a control unit
- 21 is a drive circuit as drive processing means for driving each ultrasonic element mi
- the drive circuit 21 is shown in FIG. 3 for each ultrasonic element mi.
- a simple oscillation circuit is formed.
- Reference numeral 22 denotes an operation detection circuit as an operation detection processing means for detecting an operation for each ultrasonic element mi, that is, an output of an ultrasonic wave generated by each ultrasonic element mi, that is, an intensity (amplitude).
- 23 is a temperature control circuit as a temperature control processing means for controlling the temperature of water in the treatment tank 11
- 24 is a drive circuit 21, an operation detection circuit 22 and a temperature control circuit 23, 5-60 [V] This is a power supply circuit that applies a voltage of.
- the drive circuit 21 includes a transistor Trl as a switching element, a coil L1 as a detected element for detecting the intensity of ultrasonic waves, and a coil L2 as a detecting element for detecting the intensity of ultrasonic waves
- the terminal t2 is connected to the collector of the transistor Trl via the coil L1 and the terminals tl and t2 are connected to the power supply circuit 24.
- a first series circuit comprising an ultrasonic element mi and a capacitor C1 and constituting an LC circuit and a second series circuit comprising capacitors C2 and C3 are connected between the collector and the base
- the coil L1 is connected between the emitter of the transistor Trl and the midpoint of the capacitors C2 and C3.
- the coil L2 is disposed so as to face the coil L1, and the coil L2 and the motion detection circuit 22 are connected.
- the oscillation circuit utilizes the principle of the Colpitts oscillation circuit.
- the drive circuit 21 performs a drive process. And drive each ultrasonic element mi. That is, when noise enters the transistor Trl in each oscillation circuit, the noise is amplified by the ultrasonic element mi and the capacitor C1 and sent to each ultrasonic element mi as a drive signal. The drive signal is fed back to the transistor Trl and further amplified. In this way, the above operation is repeated, and the ultrasonic element mi resonates at the natural frequency and generates a stable ultrasonic wave.
- the intensity of the ultrasonic wave generated by the ultrasonic element mi can be changed by changing the voltage applied between the terminals tl and t2. That is, when the voltage applied between the terminals tl and t2 changes, it is generated by switching of the transistor Trl, and the amplitude of the current flowing through the coil L1 changes.
- the motion detection circuit 22 performs motion detection processing, and a current flows through the coil L1.
- the current generated in the coil L2 is read as the detection current and converted into a voltage, and the voltage is detected as the intensity of the ultrasonic wave.
- An output control processing unit (not shown) of the control unit 20 performs output control processing, compares the detected ultrasonic intensity with a set value, calculates a deviation, and performs feedback control based on the deviation. Then, the voltage applied to the drive circuit 21 is changed.
- the coils Ll and L2 constitute a current sensor as a current detection unit.
- each of the ultrasonic elements mi is attached to the side wall 13 as described above, the generated ultrasonic waves are applied to the water in the treatment tank 11. Along with this, water is decomposed by ultrasonic waves to generate hydroxyl radicals and hydrogen atoms. As a result, bacteria, for example, microorganisms such as the athlete's foot ringworm, etc. can be oxidized, decomposed and sterilized in the affected area immersed in water without using the drug, and the affected area can be treated. it can.
- the diffusing lens fi is disposed in contact with the ultrasonic element mi, resonates by receiving the ultrasonic wave generated by the ultrasonic element mi, diffuses the ultrasonic wave, and irradiates the affected area.
- the diffusing lens fi has a convex surface (a surface having a shape like a convex mirror) formed so as to protrude forward. In this way, since the ultrasonic waves are diffused and applied to the water, the ultrasonic waves are reliably applied to the affected part no matter what part of the treatment tank 11 the foot is inserted into. Therefore, sterilization can be performed reliably.
- athlete's foot ringworm etc. exist in the skin only on the surface of the skin, or enter the inside of the nail, but the ultrasonic waves generated by each of the ultrasonic elements mi are Water in the skin or nail inside the skin, not only on the surface of the skin, is also decomposed to generate hydroxyl radicals. Therefore, ringworm bacteria and the like existing in the skin or the inside of the nail can be sterilized.
- the diffusion lens fi is made of a material that receives ultrasonic waves and resonates at the frequency of the ultrasonic waves, for example, minerals such as metal, quartz, and sapphire. Further, as the diffusing lens fi, a material that does not resonate itself, but a material that transmits ultrasonic waves to water, for example, a molded product that includes silicon, metal, or the like as a transmission medium can be used. In that case, the diffusion lens fi receives ultrasonic waves and transmits them to water, and diffuses them to irradiate the affected area.
- the generation of the hydroxyl radicals depends on the temperature of water. The higher the temperature, the greater the amount of production and the higher the bactericidal ability. However, when the amount of production increases excessively, the cells in the affected area are destroyed. Damage the affected area. Therefore, in order to generate an appropriate amount of hydroxyl radicals, the temperature of water is controlled and maintained at a temperature within a predetermined range, that is, 40 [° C.] in the present embodiment. For this purpose, the temperature control circuit 23 performs a temperature control process,
- the temperature detected by the temperature sensor 15 is read as the detected temperature, the detected temperature is compared with the set value, a deviation is calculated, feedback control is performed based on the deviation, and the energization of the heater 16 is turned on / off.
- FIG. 4 is a diagram showing an arrangement state of the ultrasonic elements of the treatment tank in the second embodiment of the present invention.
- the ultrasonic elements are arranged so as to face each other and the respective radiation axes of the ultrasonic waves overlap with each other, the ultrasonic waves cancel each other, and the sterilization ability is lowered accordingly.
- the ultrasonic element mj ll, 12, 13, 14
- the ultrasonic wave of the ultrasonic elements ml3, 14 The ultrasonic elements ml 1 and ml2 and the ultrasonic elements ml3 and 14 are arranged so as not to overlap with each other.
- FIG. 5 is a diagram showing a diffusion device according to the third embodiment of the present invention.
- reference numeral 35 denotes a post as a support member formed to protrude inward from the side wall 13, and an attachment member 36 swings around the swing shaft shl at the tip of the post 35.
- the ultrasonic element mi is attached to the attachment member 36 so as to be freely movable.
- Reference numeral 31 denotes a motor 31 as a diffusion drive unit. By driving the motor 31, the ultrasonic elements mi are swung.
- a connecting body 38 is attached to the output shaft 32 of the motor 31.
- an arm 37 is connected to a predetermined portion of the mounting member 36, that is, a portion eccentric with respect to the post 35, and one end of the arm 37 is a swing shaft with respect to the mounting member 36.
- the sh2 is swingably mounted with the sh2 as a swing center, and is disposed so as to be movable back and forth (movable in the left-right direction in the figure) with respect to the side wall 13.
- the motor 31, the post 35, the mounting member 36, the arm 37, the coupling body 38, etc. constitute a diffusion device.
- the diffusion processing means (not shown) of the control unit 20 performs the diffusion processing, and when the motor 31 is driven, the coupling body 38 is rotated along with the rotation of the output shaft 32, and the coupling body As the arm 38 rotates, the arm 37 is moved back and forth. As a result, the attachment member 36 and the ultrasonic element mi are swung around the swing shaft shl, so that the ultrasonic wave generated by each ultrasonic element mi is diffused in water.
- the ultrasonic element mi is swung in the vertical direction, but can be swung in the left-right direction or in the circumferential direction.
- FIG. 6 is a diagram showing an ultrasonic sterilizer according to the fourth embodiment of the present invention.
- 51 is a predetermined shape, and in the present embodiment, a box shape having an open top surface.
- a treatment tank having a shape, 52 is an ultrasonic irradiation device, and the ultrasonic irradiation device 52 is disposed in contact with the ultrasonic element 53 that generates ultrasonic waves, and the ultrasonic element 53.
- An irradiating unit 54 is provided as a diffusing device that resonates in response to the ultrasonic wave generated by 53, diffuses the ultrasonic wave and irradiates the affected area.
- Reference numeral 55 denotes a control unit.
- the control unit 55 includes a drive circuit 21 as a drive processing unit (FIG. 2), an operation detection circuit 22 as an operation detection processing unit, a temperature control circuit 23 as a temperature control processing unit, Power supply circuit 24 etc. are provided.
- the drive circuit 21 is connected to the ultrasonic element 53 via the cable 56, and the drive circuit 21 and the ultrasonic element 53 form an oscillation circuit.
- 12 is a bottom wall and 13 is a side wall.
- the ultrasonic wave generated by the ultrasonic element 53 passes through the irradiation unit 54. Then, the water in the treatment tank 51 is irradiated. Along with this, water is decomposed by ultrasonic waves to generate hydroxyl radicals and hydrogen atoms.
- bacteria for example, microorganisms such as athlete's foot ringworms can be oxidized, decomposed and sterilized in the affected area immersed in water without using the drug, and the affected area can be treated.
- the irradiation unit 54 is made of a material that receives ultrasonic waves and resonates at the frequency of the ultrasonic waves, for example, minerals such as metal, crystal, and sapphire. Further, as the irradiation unit 54, a material that does not resonate itself, but a material that transmits ultrasonic waves to water, for example, a molded product that includes silicon, metal, or the like as a transmission medium may be used. In that case, the irradiation unit 54 receives the ultrasonic wave and transmits it to the water to irradiate the affected part.
- a fluid medium having water retention for example, a jelly sheet in which jelly is applied to the sheet is used as the medium.
- FIG. 7 is a cross-sectional view of a seal sheet according to the fifth embodiment of the present invention.
- 61 is a jelly sheet affixed to the affected area. It consists of a sheet 62 formed of oleoresin and the like and a jewel 63 applied to the sheet 62, and the jewel 63 is stuck so as to adhere to the affected area.
- the ultrasonic wave generated by the ultrasonic element 53 (FIG. 6) is applied to the jelly sheet 61 through the irradiating unit 54 and further applied to the jewel 63.
- the water in the diel 63 is decomposed by ultrasonic waves, generating hydroxyl radicals and hydrogen atoms.
- bacteria for example, microorganisms such as athlete's foot ringworms can be decomposed and sterilized in the affected area to which the jewel sheet 61 is attached, and the affected area can be treated.
- the ultrasonic element mi (Fig. 5) is arranged so as to be swingable with respect to the side wall 13. Fix it and move the affected area.
- FIG. 8 is a perspective view of a mounting plate member according to the sixth embodiment of the present invention
- FIG. 9 is a cross-sectional view of the ultrasonic sterilizer according to the sixth embodiment of the present invention.
- reference numeral 71 denotes a treatment tank that stores water as a medium
- 72 denotes a support that is supported by being in contact with the surface of the water in the treatment tank 71 and that is movably arranged in the front, rear, left and right directions
- It is a mounting plate member as a member, and the affected part can be supported by mounting, for example, a foot or the like on the mounting plate member 72.
- a plurality of, in the present embodiment, five holes 75 are formed in the mounting plate material 72 at a predetermined location in accordance with the shape of the affected part.
- the mounting plate material 72 is connected to a drive unit via a predetermined coupling mechanism (not shown), and when the drive unit is driven, the mounting plate material 72 is moved back and forth and left and right, and accordingly, the mounting plate material 72 is mounted. The affected part of the foot placed on the plate 72 is also moved back and forth and left and right.
- an ultrasonic element 73 is attached to the bottom wall 74 of the processing tank 71.
- the ultrasonic waves are generated in the processing tank 71. It is transmitted to the water and further upward.
- the mounting plate 72 moves, water rises at a position facing the ultrasonic element 73, and the water adheres to the affected area through the hole 75. It is done.
- each hole 75 is placed at a position facing the ultrasonic element 73, and water is attached to the affected part through the hole 75.
- FIG. 10 is a plan view of a treatment tank in the seventh embodiment of the present invention
- FIG. 11 is a diagram showing a first example of a diffusion device in the seventh embodiment of the present invention
- FIG. 13 is a diagram showing a second example of a diffusion device in the seventh embodiment of the invention
- FIG. 13 is a diagram showing a usage mode of the ultrasonic sterilization device in the seventh embodiment of the present invention.
- 11 is a treatment tank
- 12 is a bottom wall
- 13 is a side wall
- 81 is a bottom wall 12
- the rod-like body 81 is formed so as to protrude upward, and is attached to a hole hi formed at a predetermined position of the bottom wall 12.
- the rod-shaped body 81 is formed by a step in the rod-shaped main body 83, a mounting portion 84 formed to protrude outward in the radial direction of the lower end force of the main body 83, and the outer peripheral edge of the mounting portion 84.
- An O-ring 86 as a seal member is held between the holding portion 85 and the inner peripheral edge of the hole hi. Then, the ultrasonic element 87 is attached to the back surface of the mounting portion 84.
- the main body 83 has a predetermined diameter so that the body 83 can be sandwiched between the toes. It has a height that protrudes upward from the space.
- 82 is a cylindrical body serving as a spreading device provided on the bottom wall 12 by one or more, and in the present embodiment, one cylindrical body 82.
- the cylindrical body 82 faces upward. Formed with protruding bottom wall 1
- the cylindrical body 82 includes a cylindrical body 89 closed by a wall body 88 having a flat upper end, and a holding portion 91 formed by a flange with the lower end of the cylindrical body 89 facing radially outward.
- the O-ring 86 as a seal member is held between the holding portion 91 and the inner peripheral edge of the hole h2.
- An ultrasonic element 87 is attached to the back surface of the wall body 88.
- the cylindrical body 89 has a predetermined diameter and a predetermined height so that the back surface of the foot can be put thereon.
- the rod-shaped body 81 can be brought into contact between the toes of the affected area, and the cylindrical body 82 can be brought into contact with the sole of the affected area, so that the ultrasonic element 87 is driven. Therefore, it is possible to directly transmit the ultrasonic wave generated to the affected area.
- bacteria for example, microorganisms such as athlete's foot ringworms can be sufficiently oxidized, decomposed and sterilized in the affected part immersed in water, and the affected part can be treated.
- both the rod-like body 81 and the cylindrical body 82 can be made of force glass that is made of stainless steel.
- an ultrasonic sterilization apparatus is described.
- the present invention is applied to an ultrasonic treatment apparatus for treatment of foul odor, or ultrasonic cleaning for performing face washing or oral cleaning. It can be applied to a device or the like.
- an ultrasonic treatment apparatus is constituted by an ultrasonic treatment apparatus, an ultrasonic cleaning apparatus, or the like.
- the present invention can be applied to an ultrasonic sterilization apparatus, an ultrasonic treatment apparatus, an ultrasonic cleaning apparatus, or the like.
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- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Physical Water Treatments (AREA)
- Devices For Medical Bathing And Washing (AREA)
- Percussion Or Vibration Massage (AREA)
- Apparatus For Disinfection Or Sterilisation (AREA)
Abstract
Description
Claims
Priority Applications (1)
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JP2006544111A JP3999256B2 (ja) | 2004-11-17 | 2005-11-15 | 超音波処理装置及び超音波処理方法 |
Applications Claiming Priority (2)
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JP2004333573 | 2004-11-17 | ||
JP2004-333573 | 2004-11-17 |
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WO2006054552A1 true WO2006054552A1 (ja) | 2006-05-26 |
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PCT/JP2005/020947 WO2006054552A1 (ja) | 2004-11-17 | 2005-11-15 | 超音波処理装置及び超音波処理方法 |
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WO (1) | WO2006054552A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008075708A1 (ja) * | 2006-12-20 | 2008-06-26 | Haru Miyake | 超音波処理装置 |
CN103041414A (zh) * | 2013-01-22 | 2013-04-17 | 郭哲峰 | 用于杀灭脚气真菌的药袋及使用方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4142735B1 (ja) * | 2008-01-15 | 2008-09-03 | 治 三宅 | 超音波殺菌装置 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6379933U (ja) * | 1986-11-14 | 1988-05-26 | ||
JPH09108288A (ja) * | 1995-10-18 | 1997-04-28 | Katsuo Soga | 美容用超音波拡散発振装置 |
JP2000233006A (ja) * | 1999-02-16 | 2000-08-29 | Tdk Corp | 超音波健康・美容器用プローブ |
-
2005
- 2005-11-15 JP JP2006544111A patent/JP3999256B2/ja not_active Expired - Fee Related
- 2005-11-15 WO PCT/JP2005/020947 patent/WO2006054552A1/ja active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6379933U (ja) * | 1986-11-14 | 1988-05-26 | ||
JPH09108288A (ja) * | 1995-10-18 | 1997-04-28 | Katsuo Soga | 美容用超音波拡散発振装置 |
JP2000233006A (ja) * | 1999-02-16 | 2000-08-29 | Tdk Corp | 超音波健康・美容器用プローブ |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008075708A1 (ja) * | 2006-12-20 | 2008-06-26 | Haru Miyake | 超音波処理装置 |
JPWO2008075708A1 (ja) * | 2006-12-20 | 2010-04-15 | 治 三宅 | 超音波処理装置 |
KR101128044B1 (ko) * | 2006-12-20 | 2012-03-29 | 하루 미야케 | 초음파 처리 장치 |
US8226894B2 (en) | 2006-12-20 | 2012-07-24 | Haru Miyake | Ultrasonic treatment apparatus |
CN103041414A (zh) * | 2013-01-22 | 2013-04-17 | 郭哲峰 | 用于杀灭脚气真菌的药袋及使用方法 |
Also Published As
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JPWO2006054552A1 (ja) | 2008-05-29 |
JP3999256B2 (ja) | 2007-10-31 |
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