WO2006052253A1 - Compositions resineuse durcissable et revetements de comptoirs resistants aux egratignures derives de ces compositions - Google Patents
Compositions resineuse durcissable et revetements de comptoirs resistants aux egratignures derives de ces compositions Download PDFInfo
- Publication number
- WO2006052253A1 WO2006052253A1 PCT/US2004/037419 US2004037419W WO2006052253A1 WO 2006052253 A1 WO2006052253 A1 WO 2006052253A1 US 2004037419 W US2004037419 W US 2004037419W WO 2006052253 A1 WO2006052253 A1 WO 2006052253A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- anhydride
- resinous composition
- curable resinous
- acid
- sand
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/14—Polyepoxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Definitions
- the invention relates to a curable resinous composition containing an epoxy resin and hardened scratch resistant countertops derived from such curable compositions.
- the surfaces from these materials are generally designed for residential and light commercial use. They are not as durable physically or chemically as some applications require for long-term use. Further, some more expensive materials at about two to three times the price of the above materials can offer durability but again are priced at a range that limits many persons from enjoying such surfaces.
- Some additional examples include an epoxy thermosetting material as part of a resin matrix and fill materials of metal or stone particles.
- U.S. Patent No. 6,365,662 to Sakai discloses an artificial stone comprising an inorganic particle component of 82-93% by weight of a mixture of small and large particles of specific size ranges and a resin component of 7-18%.
- the resin component can include thermosetting resins such as acrylics, methacrylics, unsaturated polyesters, and epoxies.
- WO 99/00235 discloses a resin matrix bound to a substrate where the resin matrix contains a curable liquid resin, metal or stone particles, and a catalyst.
- the curable resin can be acrylates, methacrylates, styrenes, methylstyrenes, allys, diallylphthalates, unsaturated polyesters, vinyl esters, urethanes and epoxies.
- the catalyst can include aliphatic amines, aromatic amines, catalytic curing agents and acid anhydrides.
- Other known efforts include using an epoxy resin in conjunction with an anhydride and silica as the fill material to form a mixture and then catalyzing the mixture with an amine.
- the industry is still lacking in a particular process and corresponding product that combines the benefits of an epoxy resin with mineral fill materials in a particular manner to produce a commercially viable and relatively inexpensive manufactured structural synthetic surface.
- the synthetic surface needs the combination of scratch resistance and hardness while being durable and impact resistant at a moderate costs. Therefore, there remains a need in the industry for such a material.
- the invention relates to a resinous curable composition and hardened surfaces derived therefrom.
- the resinous curable composition contains an epoxy resin and at least one carboxylic acid anhydride, along with multiple sized inorganic filler materials which serve to increase the loading capacity of the composition.
- the composition is hardened in the presence of a heat-activated catalyst.
- the resulting product is harder and more scratch resistant than other known commercially available materials and, further, is cheaper to produce.
- the hardened surface may be a countertop such as a kitchen countertop, laboratory bench countertop and other type of working surface.
- the curable resinous composition of the invention comprises:
- the resinous composition of the invention employs dramatically less epoxy resin and more fillers than the formulations of the prior art. As such, the resinous compositions of the invention can be more economically produced than the compositions of the prior art. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
- the curable resinous composition of the invention contains an epoxy resin.
- the amount of epoxy resin in the resinous curable composition is less than 15 weight percent, typically less than 13 weight percent. In some cases, the amount of epoxy resin in the resinous curable composition may be as low as 6 weight percent. For instance, where granite chips and/or sand are used as the inorganic filler (D) of the curable resinous composition, the amount of requisite epoxy resin is generally half of that required in the more traditional epoxy resin formulations.
- the epoxide resin may be a cycloaliphatic epoxide resin, i.e. a resin that has a least one epoxide group in which the oxygen atom is attached to carbon atoms in a cycloaliphatic ring, a N-glycidylamine, a polyglycidyl ester of a polycarboxylic acid or a polyglycidyl ether of a polyhydric alcohol or phenol.
- epoxy resins contain aliphatic, cycloaliphatic or aromatic backbones.
- One type of epoxy resin preferred for use in accordance with the invention is a polyfunctional epoxy composition containing at least three epoxide groups.
- Preferred resin compositions include those comprising at least one glycidyl ether of a polyhydric phenol such as 2,2-bis(4-hydroxyphenyl)propane (bisphenol A), bis(4- hydroxyphenyl)methane (bisphenol F), a phenol formaldehyde novolak or a cresol- formaldehyde novolak.
- a polyhydric phenol such as 2,2-bis(4-hydroxyphenyl)propane (bisphenol A), bis(4- hydroxyphenyl)methane (bisphenol F), a phenol formaldehyde novolak or a cresol- formaldehyde novolak.
- epoxy resins preferred for this invention include 2,2- bis[4-(2,3-epoxypropoxy)phenyl]propane (diglycidyl ether of bisphenol A) and materials under the trade designation "Epon 828", “Epon 1004" and “Epon 1001F”, commercially available from Resolution Performance Polymers, "DER-331 ", “DER-332” and “DER-334”, commercially available from Dow Chemical Co.
- Other suitable epoxy resins include glycidyl ethers of phenol formaldehyde novolac (e.g., "DEN-43 " and "DEN-428”, commercially available from Dow Chemical Co.). Such resins preferably have a weight average molecular weight less than about 20,000, most preferably less than 14,000.
- Epoxy resins may further include monomeric epoxy resins as well as polymeric epoxy resins. These resins can vary greatly in the nature of their backbones and substituent groups.
- the backbone may be of any type normally associated with epoxy resins and substituent groups thereon can be any group free of an active hydrogen atom that is reactive with an oxirane ring at room temperature.
- substituent groups for epoxy resins include halogens, ester groups, ether groups, sulfonate groups, siloxane groups, nitro groups, and phosphate groups.
- the polyfunctional epoxy compounds of the invention may be derived from any number of sources, including the reaction product of chlorohydrin compounds such as epichlorohydrin, glycerol dichlorohydrin, and beta-methylepichlorohydrin with polycarboxylic acid compounds including aromatic and aliphatic polycarboxylic acids such as tri and tetra carboxylic acids; with polyhydroxyl compounds such as alcoholic and phenolic polyhydroxyl compounds; with amine compounds comprising three or more amino hydrogen atoms including aliphatic, cycloaliphatic, and aromatic amines; with polythiol compounds; and with polyene type unsaturated cycloaliphatic compounds.
- chlorohydrin compounds such as epichlorohydrin, glycerol dichlorohydrin, and beta-methylepichlorohydrin
- polycarboxylic acid compounds including aromatic and aliphatic polycarboxylic acids such as tri and tetra carboxylic acids
- polyhydroxyl compounds such as alcoholic and phenolic
- desirable epoxy resins include those derived from saturated and unsaturated polyfunctional alcohols such as tetritols, pentitols, and hexitols such as sorbitol, and maltitol.
- polyfunctional epoxies are aliphatic epoxy resins of hexitol polyglycidyl ethers such as sorbitols and maltitols.
- Polyfunctional epoxy resins are available from suppliers such as Dow Chemical, Ciba Geigy, Rhone-Poulenc, Resolution Performance Polymers as well as from Dixie Chemical Company of Houston, Tex. which offers the sorbitol polyglycidyl ether as Dixie DCE 358.
- the carboxylic acid anhydride for use in the invention typically comprises from about 4 to about 15, preferably from about 6 to about 10, weight percent of the curable composition.
- Preferred as the carboxylic acid anhydride are aromatic acid anhydrides such as phthalic acid anhydride, isophthalic acid anhydride, terephthalic acid anhydride, pyromellitic acid and benzophenone-3,3',4,4'-tetracarboxylic acid as well as alicyclic aromatic acid anhydrides such as tetrahydrophthalic acid anhydride, methyltetrahydrophthalic acid anhydride, hexahydrophthalic acid anhydride, methylhexahydrophthalic acid anhydride, methylendomethylenetetrahydrophthalic acid anhydride, hexahydroterephthalic acid anhydride, 4-methyltetrahydrophthalic acid anhydride, tetrahydroisophthalic acid anhydride, endomethylenetetrahydrophthalic
- More preferred blends include methyltetrahydrophthalic anhydride, hexahydrophthalic anhydride and methylhexahydrophtahlic anhydride and especially preferred is a 45:55 to 55:45 weight ratio blend of hexahydrophthalic acid anhydride: methylhexahydrophthalic acid anhydride.
- two or more carboxylic acid anhydrides are used; most preferably at least one carboxylic acid anhydride is an aromatic acid anhydride and the second is an alicyclic aromatic acid anhydride.
- the aromatic acid anhydride is a flake material.
- the molar ratio of aromatic acid anhydride:alicyclic aromatic acid anhydride is generally from about 1.2:0.8 to 0.8: 1.2.
- the composition of the invention further contains as high as 75, and may be as high as 89, weight percent of inorganic filler.
- inorganic filler loadings are higher than the permissible inorganic filler loadings of the compositions of the prior art formulations.
- the amount of epoxy resin employed in the composition is reduced.
- One of the inorganic fillers defined as “inorganic filler (D)" are particulates having high particle diameter sizes. For instance, 80% of the particulates of such inorganic fillers are typically characterized by a particle size greater than about 90 microns.
- Such particulates are typically sand or chips of natural stone, such as granite, tuff, marble, sandstone and the like or a combination thereof.
- the sand in addition to containing silica, may contain trace amounts of iron oxide, aluminum oxide, titanium dioxide, calcium oxide, and magnesium oxide as well as other oxides.
- the use of natural stone chips is most preferred because the amount of epoxy resin required to be employed, when such chips are used as the inorganic filler, is almost half of that required in the epoxy resin formulations of the prior art. In a most preferred mode, at least 80% of the chips of natural stone have a particle size diameter greater than 1/8 inch.
- the curable composition of the invention further contains a second inorganic filler, defined as "inorganic filler (C)".
- inorganic fillers have much smaller average particle size diameter than inorganic fillers (D); typically, at least about 80% of the particles of inorganic filler (C) have a particle diameter size of from between about 10 to about 40 microns.
- Exemplary of such inorganic fillers are naturally occurring inorganic materials such as silica stone, silica sand, diatomaceous earth, kaolin, halloysite, montmorillonite, bentonite, zeolite, phosphorite, diaspore, gibbsite, bauxite, Japanese acid clay, porcelain stone, pyrophyllite rock, feldspars, limestone, wollastonite, gypsum, dolomite, magnesite and talc.
- the (second) inorganic filler is sand.
- inorganic filler (C) is sand and inorganic filler (D) is sand and/or granite chips.
- the weight ratio of the sand of inorganic filler C:inorganic filler D is typically 7:1 to about 1 :1.5. Particularly desirous results have been obtained where the inorganic filler D is a combination of sand and granite chips. In such instances, the weight ratio of the sand of inorganic filler C to the sand of inorganic filler D is approximately 1 :1 and the weight ratio of total sand (of inorganic filler (C) and inorganic filler (D)) to the granite chips is about 1 : 1.
- the resinous composition of the further invention may be cured by heating, preferably in the presence of a heat activated catalyst.
- Typical heat activated catalysts include cycloaliphatic and aromatic polyamiiies, polyhydric phenols or an imidazole.
- 200 Sand refers to Unimin No. 200 sieve silica sand (80% of the particulates having a particle diameter size range of 10 to 40 microns);
- 325 Sand refers to Unimin No. 325 sieve silica sand (80% of the particulates having a particle diameter size range of about 10 to 25 microns); 7010 Sand refers to Unimin No. 7010 sieve silica sand (80% of the particulates having a particle diameter size range of about 90 to 150 microns);
- Epon 828 is a commercially available epoxy resin from Resolution Performance Polymers.
- Liquid Anhydride Mix refers to ECA 10OH, available from Dixie Chemical Company of Houston, Tex., is a mixture of from about 0-5% by weight methyltetrahydrophthalic anhydride, 45-50% by weight hexahydrophthalic anhydride and 45 -50% by weight methylhexahydrophthalic anhydride; flake phthalic anhydride refers to melted flake phthalic anhydride, available from Koppers; and LINDAX 1 is l-(2 hydroxypropyl) imidazole heat activated catalyst, available from
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002584418A CA2584418A1 (fr) | 2004-11-10 | 2004-11-10 | Compositions resineuse durcissable et revetements de comptoirs resistants aux egratignures derives de ces compositions |
PCT/US2004/037419 WO2006052253A1 (fr) | 2004-11-10 | 2004-11-10 | Compositions resineuse durcissable et revetements de comptoirs resistants aux egratignures derives de ces compositions |
EP04800941A EP1824916A1 (fr) | 2004-11-10 | 2004-11-10 | Compositions resineuse durcissable et revetements de comptoirs resistants aux egratignures derives de ces compositions |
MX2007005334A MX2007005334A (es) | 2004-11-10 | 2004-11-10 | Composiciones resinosas curables y cubiertas resistentes al rayado y derivados de estas. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2004/037419 WO2006052253A1 (fr) | 2004-11-10 | 2004-11-10 | Compositions resineuse durcissable et revetements de comptoirs resistants aux egratignures derives de ces compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006052253A1 true WO2006052253A1 (fr) | 2006-05-18 |
Family
ID=34959513
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2004/037419 WO2006052253A1 (fr) | 2004-11-10 | 2004-11-10 | Compositions resineuse durcissable et revetements de comptoirs resistants aux egratignures derives de ces compositions |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1824916A1 (fr) |
CA (1) | CA2584418A1 (fr) |
MX (1) | MX2007005334A (fr) |
WO (1) | WO2006052253A1 (fr) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2098561A2 (fr) | 2008-03-05 | 2009-09-09 | Weatherford/Lamb, Inc. | Formulation de matériau composite |
US8383243B2 (en) | 2008-12-10 | 2013-02-26 | Xerox Corporation | Composite containing polymer, filler and metal plating catalyst, method of making same, and article manufactured therefrom |
EP2662348A2 (fr) | 2012-05-06 | 2013-11-13 | R&D Project Sp. z o.o. | Procédé de fabrication de dalles en pierre recouvertes de résine |
WO2014008235A1 (fr) * | 2012-07-02 | 2014-01-09 | E. I. Du Pont De Nemours And Company | Procédé de fabrication de matériaux polymères chargés avec des particules de charge modifiées |
WO2015078901A1 (fr) * | 2013-11-26 | 2015-06-04 | Shaun Friel | Revêtement de surface à coefficient de frottement élevé et son procédé de fabrication |
IT201700102110A1 (it) * | 2017-09-12 | 2019-03-12 | Rosa Riccardo Salvatore La | Composto, lapideorinforzato a basso peso, ottenuto da scarti di fanghi e polveri delle lavorazioni lapidee, processo di recupero dalle lavorazioni e metodo per l'utilizzo di detti materiali di risulta all'interno dello stabilimento di produzione o presso strutture esterne |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3594460A (en) * | 1968-08-05 | 1971-07-20 | Sheldon & Co E H | Method for preparing a laboratory counter top |
JPH10330647A (ja) * | 1997-06-02 | 1998-12-15 | Nippon Shokubai Co Ltd | 透明性塗料組成物およびその硬化方法 |
JP2000063679A (ja) * | 1998-08-17 | 2000-02-29 | Yamaha Ribingutetsuku Kk | 熱硬化性樹脂組成物 |
US6365662B1 (en) * | 1998-01-16 | 2002-04-02 | Doppel Co., Ltd. | Non-slip artificial stone |
-
2004
- 2004-11-10 WO PCT/US2004/037419 patent/WO2006052253A1/fr active Application Filing
- 2004-11-10 CA CA002584418A patent/CA2584418A1/fr not_active Abandoned
- 2004-11-10 EP EP04800941A patent/EP1824916A1/fr not_active Withdrawn
- 2004-11-10 MX MX2007005334A patent/MX2007005334A/es unknown
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3594460A (en) * | 1968-08-05 | 1971-07-20 | Sheldon & Co E H | Method for preparing a laboratory counter top |
JPH10330647A (ja) * | 1997-06-02 | 1998-12-15 | Nippon Shokubai Co Ltd | 透明性塗料組成物およびその硬化方法 |
US6365662B1 (en) * | 1998-01-16 | 2002-04-02 | Doppel Co., Ltd. | Non-slip artificial stone |
JP2000063679A (ja) * | 1998-08-17 | 2000-02-29 | Yamaha Ribingutetsuku Kk | 熱硬化性樹脂組成物 |
Non-Patent Citations (2)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 1999, no. 03 31 March 1999 (1999-03-31) * |
PATENT ABSTRACTS OF JAPAN vol. 2000, no. 05 14 September 2000 (2000-09-14) * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2098561A2 (fr) | 2008-03-05 | 2009-09-09 | Weatherford/Lamb, Inc. | Formulation de matériau composite |
US8383243B2 (en) | 2008-12-10 | 2013-02-26 | Xerox Corporation | Composite containing polymer, filler and metal plating catalyst, method of making same, and article manufactured therefrom |
US8592043B2 (en) | 2008-12-10 | 2013-11-26 | Xerox Corporation | Composite containing polymer, filler and metal plating catalyst, method of making same, and article manufactured therefrom |
EP2662348A2 (fr) | 2012-05-06 | 2013-11-13 | R&D Project Sp. z o.o. | Procédé de fabrication de dalles en pierre recouvertes de résine |
WO2014008235A1 (fr) * | 2012-07-02 | 2014-01-09 | E. I. Du Pont De Nemours And Company | Procédé de fabrication de matériaux polymères chargés avec des particules de charge modifiées |
WO2015078901A1 (fr) * | 2013-11-26 | 2015-06-04 | Shaun Friel | Revêtement de surface à coefficient de frottement élevé et son procédé de fabrication |
GB2522518B (en) * | 2013-11-26 | 2017-04-26 | Friel Shaun | High friction surface coating |
US9739017B2 (en) | 2013-11-26 | 2017-08-22 | Shaun Friel | High friction surface coating and method of making thereof |
IT201700102110A1 (it) * | 2017-09-12 | 2019-03-12 | Rosa Riccardo Salvatore La | Composto, lapideorinforzato a basso peso, ottenuto da scarti di fanghi e polveri delle lavorazioni lapidee, processo di recupero dalle lavorazioni e metodo per l'utilizzo di detti materiali di risulta all'interno dello stabilimento di produzione o presso strutture esterne |
Also Published As
Publication number | Publication date |
---|---|
EP1824916A1 (fr) | 2007-08-29 |
MX2007005334A (es) | 2007-09-11 |
CA2584418A1 (fr) | 2006-05-18 |
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