WO2006029934A2 - Lubrifiant pour la lubrification d'objets metalliques chauffes - Google Patents

Lubrifiant pour la lubrification d'objets metalliques chauffes Download PDF

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Publication number
WO2006029934A2
WO2006029934A2 PCT/EP2005/053631 EP2005053631W WO2006029934A2 WO 2006029934 A2 WO2006029934 A2 WO 2006029934A2 EP 2005053631 W EP2005053631 W EP 2005053631W WO 2006029934 A2 WO2006029934 A2 WO 2006029934A2
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WO
WIPO (PCT)
Prior art keywords
alkali
lubricant
lubricant according
weight
solids content
Prior art date
Application number
PCT/EP2005/053631
Other languages
German (de)
English (en)
Other versions
WO2006029934A3 (fr
Inventor
Norbert Aurin
Steffen Bugner
Bernd Schneider
Original Assignee
Chemische Fabrik Budenheim Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chemische Fabrik Budenheim Kg filed Critical Chemische Fabrik Budenheim Kg
Publication of WO2006029934A2 publication Critical patent/WO2006029934A2/fr
Publication of WO2006029934A3 publication Critical patent/WO2006029934A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
    • C10M103/02—Carbon; Graphite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
    • C10M103/06—Metal compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04—Elements
    • C10M2201/041—Carbon; Graphite; Carbon black
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085—Phosphorus oxides, acids or salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/10—Compounds containing silicon
    • C10M2201/102—Silicates
    • C10M2201/103—Clays; Mica; Zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/08—Solids

Definitions

  • the present invention relates to a lubricant for lubricating two surface-contacting heated metal objects, which perform a relative movement to each other, wherein the lubricant has a content of graphite and a content of at least one sheet silicate. Moreover, this invention relates to the use of such a lubricant in the hot deformation of metals and in particular in the manufacture of seamless pipes.
  • a solid steel block is heated to a specific forming temperature and rolled out into a short, thick-walled hollow body, the pipe core.
  • This tube blank is inserted via a tool, the mandrel, and extended or forged over the mandrel without additional heat supply.
  • lubricants for lubricating two heated metal objects in contact with each other in terms of area, such as, for example, a mandrel and a tube.
  • Various lubricant compositions are known from the state of the art, which are basically suitable for lubricating two hot metal objects contacting each other in a planar manner.
  • a large proportion of these lubricants contain graphite as an ingredient, which is also well-known as a lubricant for metal objects at ordinary ambient temperatures.
  • a disadvantage of graphite-containing lubricants is that, in particular at high processing temperatures, carburization frequently takes place, the graphite occupying outer grid positions of the B-scale crystal (iron carbide formation), which can lead to partial embrittlement.
  • the brittle material breaks at this point, and the part is unusable. The reject rate is increased, which is economically unsustainable.
  • EP 0 745 661 discloses a graphite-containing lubricant which has a proportion of one or more clay minerals from the class of smectites. In addition, these lubricants either have a content of silica sol or potassium aluminosilicate. According to EP 0 745 661, such lubricants can largely overcome the disadvantage of the Aufkoh ⁇ ment of graphite-containing lubricants at relatively high operating temperatures.
  • lubricants containing both graphite and alkali-containing phyllosilicate may have less carburization in metalworking, they often require improvement in the friction ratios between the metal surfaces in order to improve the durability of the tooling tools, e.g. the mandrel rods, extend.
  • the object underlying this invention is therefore to provide a graphite-containing lubricant which has no carburization when lubricating two heated metal objects which contact one another in a planar manner and which move relative to one another, and the restraining forces occurring between the surfaces of the metal objects reduced in comparison to corresponding lubricants from the prior art, so as to extend the durability of the very expensive tools (eg mandrel bars).
  • a lubricant of the type mentioned which is additionally da ⁇ characterized in that the lubricant, based on the solids content, at least 5 wt .-% alkali-free hydrous sheet silicate has.
  • the group of alkali-free hydrous sheet silicates has the common feature that these phyllosilicate minerals are substantially free of alkali.
  • the group of alkali-free wasserhal ⁇ term sheet silicates includes, inter alia, the minerals kaolinite, antigorite, halloysite, greenalite, pyrophyllite, talc, margarite, vermiculite, sudoite and chlorite.
  • the mica or micaceous sheet silicates are among the three-layer silicates.
  • the group of three-layer silicates includes e.g. the frequently used alkaline-containing smectites (inter alia montmorillonite), which are contained, inter alia, in the bentonites as main minerals.
  • the lubricant contains at least 30% by weight of graphite, based on solids content.
  • the graphite used can be of synthetic as well as natural origin.
  • the graphite content of a lubricant according to the invention is in a range of 30-90% by weight, and more preferably the graphite content is 50-80% by weight, based on the solids content. It is astonishing that even with lubricants according to this invention with relatively high graphite content no carburization could be detected on the surface of the machined metal objects.
  • the lubricant comprises at least 10% by weight of phyllosilicate based on solids content.
  • the lubricant preferably comprises 10-50% by weight of phyllosilicate, and phyllosilicate fractions, based on the solids content, of 20-40% by weight are particularly preferred. It should be noted that in some embodiments the proviso only applies that the proportion of alkali-free hydrous sheet silicate in the Bacllsili ⁇ catgehalt of the lubricant is at least so high that the proportion of alkali-free hydrous sheet silicate, based on the solids content of the total lubricant, at least 5 wt. -% is.
  • Vor ⁇ preferably comprises the lubricant, based on the solids content 10-90 wt .-% alkali-free hydrous sheet silicate, wherein the lubricant particularly preferably 20-60 wt .-% alkali-free hydrous sheet silicate comprises.
  • alkali-free hydrous sheet silicates which have single-component single layers, for example kaolinite, antigorite and halloysite.
  • Further preferred alkali-free hydrous sheet silicates selected from the group of non-hydrated alkali-free hydrous phyllosilicates.
  • Kaolinite is white, soft and flaky in its purest form.
  • the two-layered kaolinite layers are not hydrated and are unfolded.
  • Particularly characteristic of kaolinite is the great tendency for intercalation of chemical substances between the individual kaolinite layers.
  • the unfolded silicate layers are particularly stabilized.
  • the hydrated aluminum ions act in principle as very large ions.
  • Kaolinite is obtained either by slaking the clay kaolin or synthetically from polysilicic acid and aluminum hydroxide. Since kaolins consist predominantly of the mineral kaolinite (about 88%), kaolin is used instead of pure kaolinite in some embodiments, i. that the proportion of kaolinite, based on the solids content, is achieved by a correspondingly higher addition of kaolin. In other embodiments, both kaolinite and kaolin are used in appropriate amounts. The same applies to synthetically produced kaolinite, i. in that preferred lubricants according to the present invention are additionally characterized by comprising kaolin or synthetically produced kaolinite. The advantage of using the kaolin clay is the lower cost of the raw material.
  • the lubricant according to the invention comprises both kaolin and synthetically produced kaolinite.
  • Further embodiments of the invention are additionally characterized in that they comprise at least one thickener.
  • the at least one thickener is a bentonite, among which particularly smectites are preferred among the bentonites, and montmorillonite is particularly preferred among the smectites.
  • a particularly preferred specific embodiment of the present invention comprises, based on the solids content, at least 50-79% by weight of graphite, 20-40% by weight of kaolinite and 1-10% by weight of thickener.
  • preferred embodiments of the invention comprise at least one alkali metal thophosphate, particular preference being given to those alkali metal phosphates which are selected from trisodium, tripotassium or trilithium orthophosphate.
  • alkali orthophosphates is well known in the art, and for the purposes of this invention, preferably comprises 0.5-15% by weight, based on the solids content of the lubricant. Particularly preferred is the - -
  • Alkali orthophosphate content in the range of 1-10% by weight, based on the solids content of the lubricant, and more preferably in the range of 1-7.5% by weight.
  • the lubricants according to the invention can be used wherever, at high temperatures, two metal objects in contact with one another flatly make a relative movement relative to one another. These include e.g. also roller cages for plain bearings, where elevated temperatures can occur.
  • the lubricants according to the invention are preferably used in contact with one another on flat metal objects, one of which is a tool and another is a workpiece.
  • the lubricant according to the invention is in the form of an aqueous solution or dispersion or suspension.
  • the solids content of such a solution or dispersion / suspension is preferably 25-35% by weight.
  • aqueous preparation of a lubricant according to the invention can, for example, be applied to the tool (for example a mandrel bar), the lubricant forming a fine separating and lubricant film after evaporation of the water.
  • the inventive concept is suitable for the lubrication of any metal objects, but is preferably used in the hot deformation of metals, preferably at working temperatures of about 700-1300 9 C.
  • Under metal pipes are understood here, for example, tubes made of non-ferrous metals, aluminum or the like.
  • the graphite used in this example was a natural graphite having a purity of> 98% and an average particle size of 6 ⁇ m.
  • the kaolinite used was obtained by kaolin slurry (kaolin EGS 80, Erbslöh).
  • the thickener used was a modified bentonite (Optigel WM, Süd-Chemie).
  • the 30% aqueous suspension of the above composition was sprayed on the about 80 9 C hot mandrels of a MPM (Multiple Purpose MiII). After evaporation of the carrier liquid, the tubes were rolled. The case determined restraining forces were 85 to at a 1150 0 C block temperature. The durability of the spikes was 2000 pipes.
  • a 30% aqueous suspension was prepared.
  • the graphite used and the thickener used corresponded to the substances mentioned in Example 1.
  • the kaolin used was a white kaolin with a kaolin content of 88% by weight (kaolin EGS 80, Erbsloh).
  • K 3 PO 4 was from Chemische Fabrik Budenheim KG.
  • a 30% aqueous suspension of the above composition was sprayed onto the approximately 80 ° C mandrels of a Multiple Purpose MiII (MPM). After evaporation of the carrier liquid, the tubes were rolled. The retention forces were 80 to 1 150 9 C. The durability of the spikes was 2050 tubes.
  • a 30% aqueous suspension was prepared.
  • the graphite used and the thickener used corresponded to the substances mentioned in Example 1.
  • the inventive 30% aqueous suspension of the above composition was sprayed onto the about 80 9 C hot mandrels of a MPM (Multiple Purpose MiII). After evaporating the carrier liquid, the tubes were rolled. The retention forces determined in this case were 95 tons at a 1 150 ° C block temperature. The durability of the spikes was 1775 tubes.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

L'objet de la présente invention est d'obtenir un lubrifiant contenant du graphite et du phyllosilicate pour la lubrification de deux objets métalliques chauffés qui possèdent chacun une face plane en contact l'une avec l'autre et qui effectuent un mouvement relatif l'un par rapport à l'autre. A cet effet, ledit lubrifiant contient, par rapport à sa teneur en matière solides, au moins 5 % en poids de phyllosilicate contenant de l'eau et exempt d'alcalis.
PCT/EP2005/053631 2004-09-17 2005-07-26 Lubrifiant pour la lubrification d'objets metalliques chauffes WO2006029934A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102004045128.1 2004-09-17
DE102004045128A DE102004045128A1 (de) 2004-09-17 2004-09-17 Schmiermittel zum Schmieren von erhitzten Metallgegenständen

Publications (2)

Publication Number Publication Date
WO2006029934A2 true WO2006029934A2 (fr) 2006-03-23
WO2006029934A3 WO2006029934A3 (fr) 2006-12-07

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DE (1) DE102004045128A1 (fr)
WO (1) WO2006029934A2 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008043656A3 (fr) * 2006-10-09 2008-07-10 Chem Fab Budenheim Kg Lubrifiant haute température graphiteux pour aciers inoxydables et aciers au carbone
US11485929B2 (en) 2019-02-22 2022-11-01 Chemische Fabrik Budenheim Kg Lubricant for the hot forming of metals

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5528227B2 (ja) * 2009-10-16 2014-06-25 曙ブレーキ工業株式会社 固体潤滑材、その製造方法および用途
EP2519590B1 (fr) * 2009-12-30 2021-10-27 Dow Silicones Corporation Revêtements réduisant le frottement
DE102011001140A1 (de) * 2011-03-08 2012-09-13 Thyssenkrupp Steel Europe Ag Stahlflachprodukt, Verfahren zum Herstellen eines Stahlflachprodukts und Verfahren zum Herstellen eines Bauteils

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4898905A (en) * 1987-07-13 1990-02-06 Taiho Kogyo Co., Ltd. Sliding material
EP0745661A1 (fr) * 1995-05-30 1996-12-04 Timcal Ag Composition lubrifiante pour l'inhibition de la carburation pendant la production de tuyaux sans soudure
GB2322867A (en) * 1997-03-05 1998-09-09 T & N Technology Ltd Release agent
US6177386B1 (en) * 1996-07-02 2001-01-23 Chemische Fabrik Budenheim Rudolf A. Oetker Lubricant and use thereof
WO2002026919A2 (fr) * 2000-09-29 2002-04-04 Kelsan Technologies Corp. Compositions tribologiques

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3801504A (en) * 1971-03-22 1974-04-02 Texaco Inc Non-flammable water based hot forging lubricating compositions
JPS5755247A (en) * 1980-09-19 1982-04-02 Misao Kanaumi Automobile with slip preventive device to press tire against ground
EP0554822B1 (fr) * 1992-02-06 1999-12-29 Timcal Ag Lubrifiant de mandrin pour la fabrication de tubes sans soudures
JPH1060466A (ja) * 1996-08-22 1998-03-03 Fuji Dies Kk 自己潤滑複合材料
JP4189168B2 (ja) * 2002-04-19 2008-12-03 ユシロ化学工業株式会社 熱間塑性加工用潤滑剤

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4898905A (en) * 1987-07-13 1990-02-06 Taiho Kogyo Co., Ltd. Sliding material
EP0745661A1 (fr) * 1995-05-30 1996-12-04 Timcal Ag Composition lubrifiante pour l'inhibition de la carburation pendant la production de tuyaux sans soudure
US6177386B1 (en) * 1996-07-02 2001-01-23 Chemische Fabrik Budenheim Rudolf A. Oetker Lubricant and use thereof
GB2322867A (en) * 1997-03-05 1998-09-09 T & N Technology Ltd Release agent
WO2002026919A2 (fr) * 2000-09-29 2002-04-04 Kelsan Technologies Corp. Compositions tribologiques

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE INSPEC [Online] THE INSTITUTION OF ELECTRICAL ENGINEERS, STEVENAGE, GB; 10. März 2004 (2004-03-10), MOORE D E ET AL: "Crystallographic controls on the frictional behavior of dry and water-saturated sheet structure minerals" XP002363562 Database accession no. 8217340 & Journal of Geophysical Research American Geophys. Union USA, Bd. 109, Nr. B3, 3. März 2004 (2004-03-03), Seite 16 pp., ISSN: 0148-0227 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008043656A3 (fr) * 2006-10-09 2008-07-10 Chem Fab Budenheim Kg Lubrifiant haute température graphiteux pour aciers inoxydables et aciers au carbone
US20090305918A1 (en) * 2006-10-09 2009-12-10 Chemische Fabrik Budenheim Kg Graphite-containing high-temperature lubricant for high-grade steels and carbon steels
RU2454452C2 (ru) * 2006-10-09 2012-06-27 Хемише Фабрик Буденхайм Кг Графитсодержащая высокотемпературная смазка для применения при горячей обработке высококачественных и углеродистых сталей давлением
US8440597B2 (en) 2006-10-09 2013-05-14 Chemische Fabril Budenheim KG Graphite-containing high-temperature lubricant for high-grade steels and carbon steels
US11485929B2 (en) 2019-02-22 2022-11-01 Chemische Fabrik Budenheim Kg Lubricant for the hot forming of metals

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Publication number Publication date
DE102004045128A1 (de) 2006-03-23
WO2006029934A3 (fr) 2006-12-07

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