EP0334977B1 - Lubrifiant pour la déformation des métaux - Google Patents

Lubrifiant pour la déformation des métaux Download PDF

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Publication number
EP0334977B1
EP0334977B1 EP88104991A EP88104991A EP0334977B1 EP 0334977 B1 EP0334977 B1 EP 0334977B1 EP 88104991 A EP88104991 A EP 88104991A EP 88104991 A EP88104991 A EP 88104991A EP 0334977 B1 EP0334977 B1 EP 0334977B1
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EP
European Patent Office
Prior art keywords
weight
alkali
mass
alkaline earth
lubricants
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP88104991A
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German (de)
English (en)
Other versions
EP0334977A1 (fr
Inventor
Heinz-Rüdiger Dr.rer.nat. Vogel
Hans Dr.Sc.Techn. Fiedler
Harri Dr.-Ing. Weinhold
Dieter Rauschenbach
Jürgen Dipl.-Chem. Reichert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecoform Umformtechnik GmbH
Original Assignee
Ecoform Umformtechnik GmbH
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Publication date
Application filed by Ecoform Umformtechnik GmbH filed Critical Ecoform Umformtechnik GmbH
Priority to EP88104991A priority Critical patent/EP0334977B1/fr
Priority to AT88104991T priority patent/ATE86653T1/de
Priority to DE8888104991T priority patent/DE3879181D1/de
Publication of EP0334977A1 publication Critical patent/EP0334977A1/fr
Application granted granted Critical
Publication of EP0334977B1 publication Critical patent/EP0334977B1/fr
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
    • C10M103/06—Metal compounds
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
    • C10M105/22—Carboxylic acids or their salts
    • C10M105/24—Carboxylic acids or their salts having only one carboxyl group bound to an acyclic carbon atom, cycloaliphatic carbon atom or hydrogen
    • C—CHEMISTRY; METALLURGY
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    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/22—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/24—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol, aldehyde, ketonic, ether, ketal or acetal radical
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    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/36—Polysaccharides, e.g. cellulose
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    • C10M111/00—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C10M111/04—Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a macromolecular organic compound
    • C—CHEMISTRY; METALLURGY
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    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/24—Compounds containing phosphorus, arsenic or antimony
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    • C10M125/26—Compounds containing silicon or boron, e.g. silica, sand
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    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
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    • C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
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    • C10M145/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol, aldehyde, ketonic, ether, ketal or acetal radical
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    • C10M2201/02—Water
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    • C10M2201/061—Carbides; Hydrides; Nitrides
    • C10M2201/0613—Carbides; Hydrides; Nitrides used as base material
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    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C10M2201/0623—Oxides; Hydroxides; Carbonates or bicarbonates used as base material
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/16—Naphthenic acids
    • C10M2207/163—Naphthenic acids used as base material
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/18—Tall oil acids
    • C10M2207/183—Tall oil acids used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/20—Rosin acids
    • C10M2207/203—Rosin acids used as base material
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/24—Epoxidised acids; Ester derivatives thereof
    • C10M2207/243—Epoxidised acids; Ester derivatives thereof used as base material
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
    • C10M2209/043—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
    • C—CHEMISTRY; METALLURGY
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    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
    • C10M2209/062—Vinyl esters of saturated carboxylic or carbonic acids, e.g. vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/12—Polysaccharides, e.g. cellulose, biopolymers
    • C10M2209/123—Polysaccharides, e.g. cellulose, biopolymers used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/04—Groups 2 or 12
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • C—CHEMISTRY; METALLURGY
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/015—Dispersions of solid lubricants
    • C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating

Definitions

  • these lubricants 2 to 8 mass% of alkaline earth soap A, 1.2 to 8 mass% of alkali or ammonium borate B, 0 to 0.5 mass% of alkali or ammonium phosphate C and 0 to 2.5 % By mass of polymeric organic compounds D.
  • Lime soaps with an increased stearate content of up to 65% by mass can be used as alkaline earth soaps A and sodium tetra- or sodium metaborate as alkali borate B.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Lubricants (AREA)

Claims (9)

  1. Lubrifiants pour le formage des matériaux métalliques, qui se composent d'eau et des composants suivants, dissous ou dispersés dans celle-ci:
    0,01 à 15 %   en masse de savons de métaux alcalino-terreux A
    0,05 à 15 %   en masse de borate de métal alcalin ou d'ammonium B,
    0 à 14 %   en masse de phosphate de métal alcalin ou d'ammonium C,
    et
    0 à 10 %   en masse de composés organiques polymères D,
    ainsi que
    0,005 à 10 %   en masse de produits de réaction E des composants A à D, formés en solution aqueuse, à un pH supérieur à 6,9 et à des températures inférieures à 95 °C,
    la somme des proportions des composants A à E étant inférieure à 35 % en masse.
  2. Lubrifiants selon la revendication 1 pour le formage à chaud des matériaux métalliques, caractérisés en ce qu'ils renferment
    0,25 à 10 %   en masse de savons de métaux alcalino-terreux A
    0,05 à 3 %   en masse de borate de métal alcalin ou d'ammonium B,
    0,05 à 8 %   en masse de phosphate de métal alcalin ou d'ammonium C,
    0,01 à 2 %   en masse de composés organiques polymères D
    et
    0,005 à 8 %   en masse de produits de réaction E des composants A à D, formés en solution aqueuse, à un pH supérieur à 6,9 et à des températures inférieures à 80 °C,
    la somme des proportions des composants A à E étant inférieure à 20 % en masse.
  3. Lubrifiants selon la revendication 2, caractérisés en ce qu'ils renferment 0,5 à 6 % en masse de savons de métaux alcalino-terreux A, 0,5 à 3 % en masse de borate de métal alcalin ou d'ammonium B, 1 à 7 % en masse de phosphate de métal alcalin ou d'ammonium C et 0,15 à 0,5 % en masse de composés organiques polymères D.
  4. Lubrifiants selon la revendication 1, caractérisés en ce qu'ils renferment 2 à 8 % en masse de savons de métaux alcalino-terreux A, 0,2 à 1,5 % en masse de borate de métal alcalin ou d'ammonium B, 3 à 6 % en masse de phosphate de métal alcalin ou d'ammonium C et 0,1 à 0,8 % en masse de composés organiques polymères D.
  5. Lubrifiants selon la revendication 1, caractérisés en ce qu'ils renferment 2 à 8 % en masse de savons de métaux alcalino-terreux A, 1,2 à 8 % en masse de borate de métal alcalin ou d'ammonium B, 0 à 0,5 % en masse de phosphate de métal alcalin ou d'ammonium C et 0 à 2,5 % en masse de composés organiques polymères D.
  6. Lubrifiants selon l'une des revendications 1 à 5, caractérisés en ce qu'ils renferment comme savons de métaux alcalino-terreux A, des savons de chaux, avec une teneur élevée en stéarate allant jusqu'à 65 % en masse.
  7. Lubrifiants selon l'une des revendications 1 à 6, caractérisés en ce qu'ils renferment comme borate de métal alcalin B, du tétra- ou du métaborate de sodium.
  8. Lubrifiants selon l'une des revendications 1 à 7, caractérisés en ce qu'ils renferment comme phosphate de métal alcalin C, du polyphosphate de sodium, de préférence du sel de Graham.
  9. Lubrifiants selon l'une des revendications 1 à 8, caractérisés en ce qu'ils renferment comme composés organiques polymères D, de l'alcool polyvinylique, de l'alcool polyvinylique modifié par oxydation, de l'amidon agglutiné et/ou des adduits d'oxyde de polyéthylène à du nonylphénol.
EP88104991A 1988-03-28 1988-03-28 Lubrifiant pour la déformation des métaux Expired - Lifetime EP0334977B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP88104991A EP0334977B1 (fr) 1988-03-28 1988-03-28 Lubrifiant pour la déformation des métaux
AT88104991T ATE86653T1 (de) 1988-03-28 1988-03-28 Schmiermittel fuer die umformung metallischer werkstoffe.
DE8888104991T DE3879181D1 (de) 1988-03-28 1988-03-28 Schmiermittel fuer die umformung metallischer werkstoffe.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP88104991A EP0334977B1 (fr) 1988-03-28 1988-03-28 Lubrifiant pour la déformation des métaux

Publications (2)

Publication Number Publication Date
EP0334977A1 EP0334977A1 (fr) 1989-10-04
EP0334977B1 true EP0334977B1 (fr) 1993-03-10

Family

ID=8198847

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88104991A Expired - Lifetime EP0334977B1 (fr) 1988-03-28 1988-03-28 Lubrifiant pour la déformation des métaux

Country Status (3)

Country Link
EP (1) EP0334977B1 (fr)
AT (1) ATE86653T1 (fr)
DE (1) DE3879181D1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006030113A1 (de) * 2006-06-28 2008-01-03 Chemische Fabrik Budenheim Kg Graphitfreier Hochtemperatur-Schmierstoff

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2586871B2 (ja) * 1993-03-02 1997-03-05 協同油脂株式会社 油中分散型非黒鉛系潤滑油
CN101932686B (zh) 2007-11-16 2015-03-25 汉高股份及两合公司 干膜抗腐蚀性冷成形润滑剂
EP2937411A1 (fr) * 2014-04-25 2015-10-28 Voestalpine Stahl GmbH Tôle et procédé destiné à l'amélioration de la déformabilité d'une tôle

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1444345A (fr) * 1964-08-06 1966-07-01 Parker Ste Continentale Composition lubrifiante et son application au formage des métaux
DE1594512A1 (de) * 1966-02-26 1970-05-06 Metallgesellschaft Ag Schmiermittel
US3313729A (en) * 1966-05-02 1967-04-11 Hooker Chemical Corp Lubricating composition and method
US3725274A (en) * 1970-11-12 1973-04-03 G Orozco Composition and method for preparing metal for cold-working
US3974674A (en) * 1973-01-12 1976-08-17 Man-Gill Chemical Company Composition for and method for preparation of metal for subsequent cold working
US3998984A (en) * 1974-01-03 1976-12-21 Pennwalt Corporation Sodium tetraborate carrier coating for rod
CA1108115A (fr) * 1978-06-06 1981-09-01 Alan D. Eckard Lubrifiants pour etirage en fils a sec, a base de polymeres de 1,2,4- et de 1,3,4- thiadiazoledithiols

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006030113A1 (de) * 2006-06-28 2008-01-03 Chemische Fabrik Budenheim Kg Graphitfreier Hochtemperatur-Schmierstoff
DE102006030113B4 (de) * 2006-06-28 2009-02-12 Chemische Fabrik Budenheim Kg Graphitfreier Hochtemperatur-Schmierstoff

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Publication number Publication date
ATE86653T1 (de) 1993-03-15
EP0334977A1 (fr) 1989-10-04
DE3879181D1 (de) 1993-04-15

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