WO2006016549A1 - Cosmetic hair preparations - Google Patents

Abstract

A cosmetic hair preparation which comprises a polyphenol (A) and a vegetable sterol (B); or a cosmetic hair preparation which comprises the ingredient (A), a cationic surfactant (C), and a specific partial-esterification product (D). The cosmetic hair preparations enable the hair to be reinforced or strengthened. Also provided is a cosmetic hair preparation which comprises the ingredient (A), a specific amide-amine compound, and a C2-4 alcohol (F). This composition, which contains a polyphenol, can be inhibited from suffering coloration with time.

Description

 Specification

 Hair cosmetics

 Technical field

 [0001] In the first invention, when hair is damaged and weakened due to repeated coloring, etc., and the hair ends are crumpled, strengthened and split ends, cuts, tears and hair are pulled. The second invention relates to a hair-dressing cosmetic composition that has an excellent anti-elongation effect and can impart a natural natural texture to the hair. The second invention is excellent in reinforcing and strengthening damaged hair and has an excellent moisture feeling. The present invention relates to a hair cosmetic composition that imparts suppleness and coherence.

 According to a third aspect of the present invention, in a hair cosmetic composition containing a polyphenol having a binding action or the like, the coloring of the composition over time is suppressed, and a good feeling of use is imparted to the skin and hair. It relates to cosmetics.

 Background art

 [0002] As a method of repairing hair damaged by coloring or the like and preventing split hair, cut hair, tear hair, etc., a method using a polymer compound or silicone is widely used (Japanese Patent Laid-Open No. 00-44434). This method coats the hair to cover the split ends or improve the brush path to make split ends. In addition, a cosmetic material effective for split ends using a specific moisturizing plant extract has been proposed (Japanese Patent Laid-Open No. 2000-53557).

 [0003] However, since these techniques are applied to the surface of the hair and the vicinity thereof, the effect is lost by washing with, for example, shampoo or the like, and stickiness and adhesion are inherent in the hair. Unlike natural texture, there may be inconveniences such as unnatural feel. Furthermore, in the case of hair that has been used repeatedly in recent years, and the hair ends have a chilli-chilli shape, the effect of preventing the split ends from breaking is strong.

[0004] As described above, hair cosmetics and hair reinforcement that are excellent in hair strengthening / strengthening effects such as prevention of split ends, cuts and tears even after hair washing, and that can impart the natural natural texture of hair. · A toughening agent was desired. [0005] In order to improve the cohesiveness, a technique has been proposed in which the spread is suppressed by bonding the hairs together with polymers or oils. However, there were problems such as force that the finger could pass and stickiness. In addition, cationic surfactants, silicones, and protein hydrolysates have been proposed as feeling improvers for moisture reduction and the like. However, it was powerful even though it had a sufficient effect on hair that had been damaged to the CMC (cell membrane complex) and matrix inside the hair due to intense damage such as bleaching. For this reason, a hair cosmetic that is further excellent in the repair effect of CMC (cell membrane complex) and matrix has been desired.

 [0006] In addition, polyphenols and plant extracts containing them are commonly used in hair cosmetics used for skin and hair for the purpose of obtaining an astringent action, protein binding action, and antioxidant action. Has been. However, polyphenols and plant extracts containing the same cause discoloration and precipitation in the composition, and there have been major issues regarding ensuring the quality of the composition.

 [0007] To date, as a method for solving the problem, a method using a porphyrin metal complex and an organic reducing agent, a method using cysteine or sulfite, or a compound having two or more alcoholic hydroxyl groups has been used. There have been proposed a method, a method using a sugar alcohol, and a method using a guanidine derivative.

[0008] However, the method using a porphyrin metal complex is not preferable because coloration or coloring peculiar to the compound occurs. In the method using cysteine or sulfite, a odor peculiar to the compound is generated over time, which is not preferable as a hair cosmetic. In the method using a compound having two or more alcoholic hydroxyl groups or the method using a sugar alcohol, in order to obtain a sufficient discoloration preventing effect, the substance must be added in a large amount, and sticky. There is a problem with the feeling of use during external application. Further, since the method using a guanidine derivative is not sufficient for obtaining a suitable feeling during external use, an improvement has been desired. In addition, a method of using a gallic acid derivative to stabilize gallic acid (Japanese Patent Laid-Open No. 2000-319116) has been proposed, but if the degree of purification is high, the desired effect is obtained, but the degree of purification is high. Since it is costly to obtain, industrially available products that are not commercially available contain a small amount of gallic acid, intermediates, etc., and further improvement of the stability effect is desired. It was. Patent Document 1: Japanese Patent Application Laid-Open No. 2000-44434

 Patent Document 2: JP 2000-53557 A

 Patent Document 3: Japanese Patent Laid-Open No. 2-6403

 Patent Document 4: Japanese Patent Laid-Open No. 2001-172135

 Patent Document 5: Japanese Patent Laid-Open No. 52-79031

 Patent Document 6: Japanese Unexamined Patent Publication No. 2001-163764

 Patent Document 7: Japanese Unexamined Patent Application Publication No. 2002-161026

 Disclosure of the invention

 Problems to be solved by the invention

[0010] The present invention has a hair-reinforcing / strengthening-reinforcing effect such as prevention of split ends, cuts and tears, even if the hair is permeated repeatedly and the tip of the hair is chilli-chilli-like hair. The first object is to provide a hair cosmetic that can impart an original natural texture.

 The present invention provides a hair cosmetic composition that provides moisture, suppleness, strength and touch, and excellent cohesiveness by repairing CMC (cell membrane complex) and matrix in damaged hair. The second purpose is to do.

 It is a third object of the present invention to provide a hair cosmetic composition that suppresses coloring over time in a composition containing polyphenols and provides a good feeling of use to hair and an excellent conditioning effect. And

 Means for solving the problem

[0011] By combining polyphenols and plant sterols, the inventor can prevent split ends and cut hairs, and by combining a cationic surfactant, the hair ends and perms are repeated, and the hair ends. We found that even if the hair is chilli-chili-like hair, it can restore the natural hair texture before dyeing and perming without causing stickiness and adhesion.

[0012] Hair is roughly divided into a hair epidermis (cuticle), fur (cortex), and medulla (medulla) from the outside. Hair epidermis (cuticle) and fur (cortex) contain CMC (cell membrane complex), and fur (cortex) contains matrix protein. If the CMC (cell membrane complex) in the hair is damaged due to damage such as dyeing or permanent, oil and moisture are easily removed, and moisture is lost. Matrix If it is partially damaged, the hair will swell and become untidy. As the damage progresses, the hair and hair are lost and the suppleness is lost, and the cross-section becomes a broom as shown in Fig. 1 and the aesthetic appearance is significantly impaired.

[0013] The inventor of the present invention relates to polysphenols and polyhydric alcohols having r hydroxyl groups (r is 4 or more), fatty acid strength S _s (2≤s≤r—2) partial ester alcohols having 8 or more carbon atoms. It has been found that by using a hair cosmetic composition containing a glazed esterified product and a cationic surfactant, it has good cohesiveness and can reproduce a moist feeling, suppleness and a favorable tactile feeling before damage.

 [0014] Further, the present inventor suppresses discoloration of the composition by using polyphenols, a specific amidoamine compound, and a lower alcohol having 2 to 4 carbon atoms, and is good for hair. It has been found that a hair and cosmetic composition that gives a feeling of use can be obtained.

 [0015] That is, the present invention provides the following inventions [1] to [3].

 [1] A hair cosmetic composition containing (A) polyphenols and (B) plant sterols.

 [2]. (A) Polyphenols, (C) a cationic surfactant, (D) a polyhydric alcohol having a hydroxyl group: (r is 4 or more) and a fatty acid having 8 or more carbon atoms Hair cosmetics containing individual (2 ≤ s ≤ r-2) partial esterified products.

 [3] A hair cosmetic composition comprising (A) a polyphenol, (E) an amidoamine compound represented by the following general formula (1), and (F) a lower alcohol having 2 to 4 carbon atoms. Fee.

 [Chemical 1]

R— C-N-R--N (1)

 O II H I

(In the formula, R ¹ represents a linear or branched alkyl group having 11 to 25 carbon atoms, an alkyl group, or a hydroxyalkyl group, R ² is an alkylene group having 1 to ³ carbon atoms, and R ³ is carbon. Represents an alkyl group of the number 1 to 3.)

 The invention's effect

[0016] According to the first invention, even if the hair ends are repeatedly chili-chili-like hair, the hair has a hair-reinforcing / strengthening / strengthening effect of preventing split ends, breaks and tears, and Original hair It is possible to provide a hair cosmetic composition and a hair reinforcing / strengthening agent capable of imparting a natural texture.

 According to the second invention, by repairing CMC (cell membrane complex) and matrix in damaged hair, it is possible to provide a hair cosmetic that imparts excellent moisture feeling, suppleness and cohesiveness. it can.

 According to the third aspect of the present invention, there is provided a hair cosmetic composition that suppresses coloring over time in a composition containing polyphenols, imparts a good feeling to the skin and hair, and has an excellent conditioning effect. Can be provided.

 Brief Description of Drawings

 FIG. 1 is a scanning electron microscope (SEM) photograph showing unrepaired hair in an example of the present invention.

 FIG. 2 is a scanning electron microscope (SEM) photograph showing repaired hair in an example of the present invention.

 BEST MODE FOR CARRYING OUT THE INVENTION

[0018] A first invention is a hair cosmetic containing (A) polyphenols and (B) plant sterols.

 (A) Polyphenols include tannic acid, gallotannic acid, kebulinic acid, hammameltannin, azeltannin, gallic acid, gallic acid hydrate, m-di gallic acid, dehydrodi gallic acid, baronic acid, kebulic acid, hexane. List polyphenols and their salts such as hydroxydiphenic acid, caffeic acid, p-coumaric acid, ferulic acid, sinapinic acid, chlorogenic acid, rosmarinic acid, and their derivatives and salts of these derivatives. Can do. These can be used singly or in appropriate combination of two or more.

[0019] (A) As the polyphenols, acidic polyphenols or derivatives thereof are preferred. An acidic polyphenol is one having an acid dissociable group in the molecule. Specific examples include gallic acid, tannic acid, kebric acid, baronic acid, kebulic acid, hexahydroxydiphenic acid, force feic acid, ρ-tamaric acid, ferulic acid, sinapinic acid, chlorogenic acid, rosmarinic acid, etc. Can be mentioned.

[0020] Among them, (B) polyphenols include gallic acid represented by the following general formula (2) or its Derivatives are preferred.

 [Chemical 2]

(In the formula, R ⁴ represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, an amino group, or an alkyl group or a alkenyl group having 1 to 18 carbon atoms; R ⁵ ,

And R ⁷ are each independently a hydrogen atom, a hydroxyl group, an alkoxy group having 1 to 18 carbon atoms, a polyoxyethylene group, a polyoxypropylene group, a monosaccharide residue, a disaccharide residue, or an oligosaccharide residue. , R ⁵ ,

And at least one of R ⁷ is a hydroxyl group. )

 [0021] The gallic acid represented by the following general formula (2) or a derivative thereof includes gallic acid glycosides such as gallic acid, propyl gallate, and galcoside gallate, maltoside gallate, and mannoside gallate. Of these, gallic acid glycosides are preferred. More specifically, gallic acid glycosides include gallic acid methyl ester-3-dalcoside, gallic acid methyl ester-4-dalcoside, gallic acid propyl ester-3-dalcoside, gallic acid methyl ester 3-maltoside. , Gallic acid 3-dalcoside, gallic acid monoglycoside such as gallic acid 3-maltside, gallic acid methyl ester 3,5-didarcoside, gallic acid 3,4-didarcoside, gallic acid 3,5-didarcoside, etc. Gallic acid diglycoside. Among these, gallic acid diglycoside having two sugars is particularly preferred, and gallic acid didarcoside is particularly preferred.

[0022] The blending amount of the polyphenols is not particularly limited, but is usually 0.001 to 10% by mass, more preferably 0.01 to 5% by mass, and more preferably 0.1% to 10% by mass with respect to the total amount of the hair and cosmetics. preferably 0.05 to 3 mass ^_0/0.

[0023] (B) Plant sterols are those starting from plants, and can be used singly or in appropriate combination of two or more. Specifically, j8-sitosterol, stigmasterol, campesterol, ergosterol, phytosterol, which is a mixture thereof, and esters, ethers, glycosides and alkylene oxysais thereof. And phytosterol derivatives such as adducts.

 [0024] Among these, a phytosterol alkylene oxide-attached case, particularly, an α-hydroxyl group attached with an alkylene oxide is preferably used. Among these, ethylene oxide, propylene oxide, and butylene oxide are preferred as the alkylene oxide, and ethylene oxide is more preferred. Specific examples of phytosterol ethylene oxide adducts (polyoxyethylene phytosterols) include BPS-5, BPS-10, BPS-20, BPS-30, BPSH-25 (trade names, Nikko Chemicals Co., Ltd.) Manufactured, and the number at the end indicates the number of moles with EO.), GENEROL 100, GENEROL 12 2N (trade name, manufactured by COGNIS).

 [0025] The average added mole number of ethylene oxide is not particularly limited, but 2 to 80 is more preferable, 3 to 70 is more preferable, and 4 to 60 is more preferable. If the added mole number is too small, uniform mixing may not be possible in the case of an aqueous preparation, and if it is too large, the desired effect may not be fully expressed.

 [0026] The amount of the plant sterols is not particularly limited, but usually 0.01 to 20% by mass is preferable to 0.05 to 15% by mass, more preferably 0.05 to 15% by mass, and more preferably to the total amount of hair cosmetics. Preferably, 0.1 to: L0 mass%. If the blending amount is less than 0.01% by mass, it may be difficult to obtain the intended effect. If the blending amount exceeds 20% by mass, stickiness will appear and the hair will become unfavorable as a hair cosmetic. There is a case.

 [0027] In addition to the above components, (C) a cationic surfactant may be blended in the hair cosmetic composition of the present invention. Cationic surfactants are not particularly limited, but amine salts, ammonium salts, guanidine salts, benzethonium salts, pyridinium salts, imidazolinium salts, pyrrolidone carboxylates, mono-N-long chain acyl acyl basic amino acids Examples thereof include alkyl ester salts. These can be used singly or in appropriate combination of two or more.

 [0028] Examples of the cationic surfactant include the following.

 (1) Amine salt and ammonium salt represented by the following general formula (3)

[Chemical 3]

(In the formula, R ⁸ , R ⁹ , R ^1U and R ¹¹ each represent a hydrogen atom, an alkyl group, an alkenyl group, a hydroxyalkyl group, a polyalkylene oxide group or a benzyl group, one or two of which. Is a linear or branched alkyl group, alkenyl group or hydroxyalkyl group having 8 to 24 carbon atoms, and the remainder represents a hydrogen atom, a methyl group, an ethyl group, a benzyl group or a polyalkylene oxide group. Is one (CHO) H, one (C

 2 4 p

H 2 O) H (wherein p and q are each an integer of 1 to 5)

3 6 q

 A dodo group is preferred. X— is a halogen ion such as chlorine ion, bromine ion, iodine ion, sulfuric acid, methyl sulfuric acid, ethyl sulfuric acid, acetic acid, pyrrolidone carboxylic acid, glycolic acid, citrate, tartaric acid, p-toluenesulfonic acid, pyroglutamic acid, higher fatty acid In addition, it represents a cation derived from an inorganic or organic acid such as an acidic amino acid. )

[0029] (2) Guanidine salt represented by the following general formula (4)

 [Chemical 4]

X "(4)

(Wherein R ¹² is a linear or branched alkyl group or alkenyl group having 1 to 21 carbon atoms, and A is a linear or branched alkylene group or alkene group having 1 to 10 carbon atoms. , T is an integer of 1 to 5, and when t is 2 or more, A in each block may be different from each other. X "is the same as above.)

[0030] (3) A benzethonium salt represented by the following general formula (5)

 [Chemical 5]

(Where R ″ is the same as above, R ″ and R ¹⁴ are a hydrogen atom, a methyl group, an ethyl group, a benzyl group, or — (CHO) H or — (CHO) H (where p and q 1-5 each

 2 4 p 3 6 q

 Polyalkylene oxide group represented by the formula: B is a divalent hydrocarbon group of 1 to: LO, or — (CHO) —or — (CHO) — (wherein p and q are each 1 to 5) Integer

 2 4 p 3 6 q

 ). Same as above. )

[0031] (4) Pyridinium salt represented by the following general formula (6)

[Chemical 6]

 (In the formula, R 1 and X— are the same as above.)

 [0032] (5) Imidazolinium salt represented by the following general formula (7)

 [Chemical 7]

(Wherein R ¹² , R ¹³ , R ¹⁴ and X— are the same as above.)

In addition, examples of the amino acid-based cationic surfactant include mono-N-long chain acyl acyl basic amino acid lower (1 to 7 carbon atoms) alkyl ester salts. Examples of basic amino acids constituting this compound include natural amino acids such as ortin, lysine and arginine. It is also possible to use synthetic amino acids such as α, γ-diaminobutyric acid. These may be optically active or racemic. The acyl group is a saturated or unsaturated fatty acid residue having 8 to 22 carbon atoms. These may be natural or synthesized. For example, it is possible to use single higher fatty acid residues such as lauroyl group, myristoyl group, palmitoyl group and stear yl group, and natural mixed higher fatty acid residues such as coconut oil fatty acid residue and beef tallow higher fatty acid residue. it can. Lower alkyl ester components include methyl ester, ethyl ester, propyl ester, butyl ester , Pentyl ester, hexyl ester, heptyl ester and otatil ester are preferred. Examples of the counter ion are the same as those described above for X-.

[0034] More specifically, stearyl chloride trimethylammonium chloride, cetyltrimethylammonium chloride, beryltrimethylammonium chloride, distearyldimethylammonium chloride, dichloride chloride Oleyl dimethyl ammonium, didecyl dimethyl ammonium chloride, lauric acid amide butyl dardin, acetic acid myristate amide butyl dardin, acetic acid palmitate amide butyl aldehyde, distearyl dimethyl ammonium Umsulfate, stearylethyl dihydroxyethyl ammoyl sulfate, N coconut oil fatty acid acyl arginine cetyl DL pyrrolidone carboxylate, dipolyoxyethylene oleylmethyl ammonium molybdate, ethyl sulfate lanolin fatty acid fatty acid And minopropyl ethyl dimethyl ammonium. Among them, stearyl trimethylammonium chloride, distearyldimethylammonium chloride, beryltrimethylammonium chloride, dioxypolyoxyethyleneoleylmethylammonium chloride, lanyl fatty acid lanthanum fatty acid amino Propylethyldimethyl ammonium and lauric acid amide butyldardine are preferred.

[0035] The amount of cationic surfactant is particularly limited, suchヽusually against hair total amount of the cosmetic, 0.01 to 20 weight _^0/0, preferably from 0.1 to 15 weight _^0/0 More preferably, the content is 0.1 to 10% by mass. If the blending amount is less than 0.01% by mass, the desired effect may be difficult to obtain, and if it exceeds 20% by mass, an increase in the effect cannot be expected and it may be uneconomical.

 [0036] The hair cosmetic composition of the present invention includes (D) a polyhydric alcohol having r hydroxyl groups (r is 4 or more) and 8 or more carbon atoms from the viewpoint of repair of CMC (cell membrane complex) and matrix. It is advisable to add s (2≤s≤r—2) esterified products that are partially fatty acids. (D) エ ス テ ル τ (2 ≤ s ≤ r-2) of ester alcohols with ¾τ hydroxyl groups (r is 4 or more) and fatty acids with 8 or more carbon atoms. explain.

[0037] The blending amount of the component (D) is not particularly limited, but is preferably 0.01 to 10% by mass, more preferably 0.1 to 5% by mass, and still more preferably based on the total amount of the hair and cosmetics. Is 0.1 to 3% by mass. If the blending amount is too small, the effect of good unity and feel may not be demonstrated. Yes, too much may result in stickiness or heavy finish.

 [0038] The hair cosmetic composition of the present invention includes (A) an amidoamine compound represented by the following general formula (1) from the viewpoint of suppression of coloration with time in a composition containing polyphenols. And (F) a lower alcohol having 2 to 4 carbon atoms may be added. (E) The amide amine compound represented by the following general formula (1) and (F) the lower alcohol having 2 to 4 carbon atoms will be described in detail later.

 [Chemical 8]

R ¹ — CNR-— N (1)

II I \ R ³

 O H

(In the formula, R ¹ represents a linear or branched alkyl group having 11 to 25 carbon atoms, an alkyl group, or a hydroxyalkyl group, R ² is an alkylene group having 1 to ³ carbon atoms, and R ³ is carbon. Represents an alkyl group of the number 1 to 3.)

 [0039] The blending amount of the amidoamine compound is preferably 0.01 to 20% by mass, more preferably 0.1 to 5% by mass with respect to the total amount of the hair cosmetic. If the amount is less than 01% by mass, a sufficient anti-coloring effect may not be obtained, and if it exceeds 20% by mass, the feeling of use may be deteriorated. The blending amount of the lower alcohol having 2 to 4 carbon atoms is preferably 0.1 to 95% by mass, more preferably 0.5 to 80% by mass, and further preferably 1 to 50% by mass with respect to the total amount of the hair and cosmetics. % Range. When the amount is less than 1% by mass, a sufficient anti-coloring effect may not be obtained. When the amount exceeds 95% by mass, the solubility of polyphenols may be deteriorated.

[0040] The hair cosmetic composition of the present invention may contain components other than the above, which are generally blended into hair cosmetics as desired, for example, nonionic surfactants, amphoteric surfactants, anionic surfactants, silicones, high molecular compounds, amino acids, protein hydrolysates, sequestering agents, said other than alcohols, polyols, oils, UV absorbers, _P H modifiers, antioxidants, oxidants, reducing agents, Alkaline agents, pigments, antibacterial agents, bactericides, and propellants can be added.

[0041] When a fragrance is blended in the hair cosmetic composition of the present invention, the fragrance and fragrance composition described in JP-A-2003-95895 are used. In addition, when the fragrance and the fragrance composition are blended with the hair cosmetic composition of the present invention, the fragrance and the fragrance composition are added to the total amount of the hair cosmetic composition of the present invention. It is suitable to be blended so as to be ˜50 mass%, more preferably 0.0001 to 30 mass%.

 [0042] The hair cosmetic composition of the present invention can be prepared and used in various shapes such as liquid, cream, mist, foam, jewel, and wax. The method for preparing the hair cosmetic composition of the present invention is not particularly limited, and can be prepared according to the conventional method for each shape, and can be used based on the conventional method for each preparation.

 [0043] The hair cosmetic of the present invention can be applied as a shampoo, rinse, treatment, hair styling and the like. In particular, it is preferable to use it as a treatment because it is excellent in reinforcing and strengthening hair, such as split hair, cut hair, split hair, and prevention of elongation when the hair is pulled, and gives the hair a natural natural texture. Hair cosmetics containing (A) polyphenols and (B) plant sterols are useful as hair reinforcement and reinforcing agents.

 [0044] The second invention provides (A) a polyphenol, (C) a cationic surfactant, (D) a polyhydric alcohol having r hydroxyl groups (r is 4 or more) and a carbon number of 8 or more. This is a hair cosmetic composition containing s (2≤s≤r 2) fatty acids and esterified products.

 [0045] As (A) polyphenols, those similar to the above can be used.

 The blending amount of the component (A) in the second invention is not particularly limited, but 0.001 to 10% by mass is preferable with respect to the total amount of the hair cosmetic, more preferably 0.1 to 3% by mass. When two or more types are blended, the above blending amount is the total amount of polyphenols used. If the blending amount is less than 0.001% by mass, the hair may be bundled and the touch effect may not be exhibited, and if it exceeds 10% by mass, it may be stiff.

 [0046] In the second invention, (C) a cationic surfactant is essential, and (C) a cationic surfactant similar to the above can be used.

 The blending amount of component (C) in the case of the second invention is not particularly limited, but is preferably 0.01 to 10% by mass, more preferably 0.1 to 5% by mass, particularly preferably based on the total amount of hair cosmetics. Is 0.1 to 3% by mass. If the blending amount is less than 0.01% by mass, the effect of good unity and feel may not be exhibited, and if it exceeds 10% by mass, stickiness or a heavy finish may occur.

[0047] The component (D) includes a polyhydric alcohol having r hydroxyl groups (r is 4 or more) and a fat having 8 or more carbon atoms. Fatty acid is an ester product containing s (2≤s≤r-2) partial esters. There is no particular limitation as long as it is such an esterified product, and one kind can be used alone, or two or more kinds can be used in appropriate combination. In the present invention, the number of fatty acids (s) is important because the feeling varies greatly depending on the number of fatty acids in the esterified form. If the number of fatty acids (s) is less than 2, the stickiness peculiar to polyhydric alcohol increases and the feel becomes worse. On the other hand, if the number of fatty acids (s) is greater than r-2, an oily feeling will appear and nulling will increase. Thus, the balance between the number of hydroxyl groups (r) and the number of esterified fatty acids (s) is necessary to develop a good feel, and in order to obtain such a suitable balance, the hydroxyl group power is required. It is necessary to use the above polyhydric alcohol.

[0048] Examples of such ester compounds include polyglycerin fatty acid ester represented by the following general formula (8), polyoxyethylene sorbite fatty acid ester represented by the following general formula ( ₉ ), Examples thereof include polyoxyethylene pentaerythritol fatty acid ester represented by formula (10) and polyoxyethylene sorbitan fatty acid ester represented by the following general formula (11). In the following general formulas (2) to (5), R is a hydrogen atom or a fatty acid residue (COR ′: R ′ is a fatty acid residue represented by a saturated or unsaturated hydrocarbon group), and the hydroxyl group is r It is appropriately selected so that s (2 ≤ s ≤ r-2) partial esters of polyhydric alcohols (r is 4 or more) and fatty acids of 8 or more carbon atoms. m is preferably 0 to 30. a to d are the number of additions of ethylene oxide groups. )

[0049] [Chemical 9]

C¾-CHC¾-OH-CH H-C¾-0 (8)

OR OR OR OR OR

Hi. )

Polyglycerin fatty acid esters include hexaglyceryl tetrabehenate, decaglyceryl distearate, triglyceryl distearate, pentaglyceryl distearate, hexaglyceryl tristearate, hexaglyceryl tetrabehenate, and hexaoleic pentaoleate. Glyceryl, hexaglyceryl diricinoleate, hexaglyceryl triricinoleate, hexaglyceryl tetraricinoleate, hexaglyceryl pentaricinoleate, hexaglyceryl hexalysinoleate, hexaglyceryl pentaoleate, decaglyceryl tristearate, Decaglyceryl trioleate, decaglyceryl pentastearate, decaglyceryl pentahydroxystearate, decaglyceryl pentaoleate, heptaster Decaglyceryl allate, decaglyceryl decastearate, decaglyceryl decaoleate, decamacademia nut oil fatty acid decaglyceryl, decaglyceryl diricinoleate, Examples include decaglyceryl liricinoleate, decaglyceryl tetraricinoleate, decaglyceryl pentaricinoleate, decaglyceryl hexalisinoleate, and diglyceryl dioleate.

 [0051] Polyoxyethylene sorbite fatty acid esters include tetraoleic acid POE (4) ~

 (60) Sonolebit, dioleic acid POE (6) to (60) Sonorebit, trioleic acid POE (6) to (60) Sorbite, distearic acid POE (6) to (60) Sorbite, tristearic acid POE (6) to (60) Sorbit, tetrastearic acid POE (6)-(60) Sorbit, dicaprylic acid POE (6)-(60) Sorbit, tri strength prillic acid POE (6)-(60) Sorbit, tetra force prillic acid PO E (6) to (60) Sorbite, dilauric acid POE (6) to (60) Sorbite, trilauric acid POE (6) to (60) Sorbite, tetralauric acid POE (6) to (60) Sorbite, dimyristic acid PO E (6) to (60) Sonorbit, Trimyristate POE (6) to (60) Sonorebit, Tetramyristate POE (6) to (60) Sorbite, Dipalmitate POE (6) to (60) Sorbite, Tripalmi Chinoic acid POE (6) to (60) Sorbit, Tetrapalmitic acid POE (6) to (60) Examples include sorbit, didecanoic acid POE (6) to (60) sonorebit, triundecanoic acid POE (6) to (60) sonorebit, tetraundecanoic acid POE (6) to (60) sorbit, and the like.

 [0052] Examples of polyoxyethylene pentaerythritol fatty acid esters include distearic acid POE (6) to (60) pentaerythritol, dilauric acid POE (6) to (60) pentaerythritol, dicaprylic acid polyoxyethylene pentaerythritol. Tritite (6) to (60), Didecanoic acid polyoxyethylene pentaerythritol (6) to (60), Dimyristic acid polyoxyethylene pentaerythritol (6) to (60), Dipalmitic acid polyoxyethylene pentane Examples include erythritol (6) to (60) and dioleic acid polyoxyethylene pentaerythritol (6) to (60).

[0053] Polyoxyethylene sorbitan fatty acid esters include dioleic acid POE (6) to (60) sorbitan, distearic acid POE (6) to (60) sorbitan, dicaprylic acid POE (6) to (60) sorbitan, diundecan Acid POE (6)-(60) Sorbitan, Dilauric acid POE (6)-(60) Sorbitan, Dimyristic acid POE (6)-(60) Sorbitan, Dipalmitic acid POE (6)-(60) Sorbitan, Distearin Acid POE (6)-(60) Sorbitan, dibehenic acid POE (6)-(60) Sonorebitan, sesquistearic acid POE (6)-(60) Sonorebitan, Sesquioleic acid POE (6)-(60) Sorbitan, etc. Is mentioned. Of these, polyoxyethylene sorbit fatty acid ester, polyoxyethylene pentaerythritol fatty acid ester, and polyoxyethylene sorbitan fatty acid ester are preferable from the viewpoint of solubility. Furthermore, polyoxyethylene sorbite fatty acid esters are preferred, especially polyoxyethylene tetraoleate (4) sorbite, polyoxyethylene tetraoleate (6), sorbite tetraoleate, polyoxyethylene (30) sorbitol, polytetraoleate Oxyethylene (40) sorbit and tetraoleic acid polyoxyethylene (60) sorbit are particularly preferred!

 [0055] The blending amount of the component (D) is not particularly limited, but is preferably 0.01 to 10% by mass, more preferably 0.1 to 5% by mass, particularly preferably based on the total amount of the hair and cosmetics. Is 0.1 to 3% by mass. If the blending amount is less than 0.01% by mass, the effect of good unity and feel may not be exhibited, and if it exceeds 10% by mass, stickiness or a heavy finish may occur.

 [0056] Further, (A) from the viewpoint of suppression of coloring over time in the composition containing polyphenols,

E) An amidoamine compound represented by the following general formula (1) and (F) a lower alcohol having 2 to 4 carbon atoms may be blended. (E) an amidoamine compound represented by the following general formula (1) and (

F) The lower alcohol having 2 to 4 carbon atoms will be described in detail later.

 [0057] The blending amount of the amidoamine compound is preferably 0.01 to 20% by mass, more preferably 0.1 to 5% by mass with respect to the total amount of the hair cosmetic. If the amount is less than 01% by mass, a sufficient anti-coloring effect may not be obtained, and if it exceeds 20% by mass, the feeling in use may be deteriorated. The blending amount of the lower alcohol having 2 to 4 carbon atoms is preferably 0.1 to 95% by mass, more preferably 0.5 to 80% by mass, and further preferably 1 to 50% by mass with respect to the total amount of the hair and cosmetics. % Range. When the amount is less than 1% by mass, a sufficient anti-coloring effect may not be obtained. When the amount exceeds 95% by mass, the solubility of polyphenols may be deteriorated.

 [0058] Further, in the hair cosmetic composition of the second invention, as in the first invention, an appropriate amount of components generally blended into the hair cosmetic composition can be blended as desired.

[0059] When blending a fragrance with the hair cosmetic composition of the present invention, the fragrance used is blended with a fragrance composition according to the fragrance and fragrance composition described in JP-A-2003-267841. It is preferable that the fragrance composition is blended in an amount of 0.0001 to 50% by mass, more preferably 0.0001 to 30% by mass based on the total amount of the hair cosmetic. [0060] The hair cosmetic composition of the present invention can be prepared based on a conventional method of hair cosmetic composition. As hair cosmetics, it can be applied as shampoo, rinse, treatment, hair conditioner, hair restorer, keratin fiber treatment agent. In particular, since the hair cosmetic composition of the present invention has an excellent CMC (cell membrane complex) and matrix repair (repair) effect, it is optimal as a CMC (cell membrane complex) repair and repair agent and an excellent matrix repair agent. It can provide a moist feeling, suppleness, a favorable tactile sensation before damage, and an excellent cohesiveness.

 [0061] A third invention relates to hair comprising (A) polyphenols, (E) an amide amine compound represented by the following general formula (1), and (F) a lower alcohol having 2 to 4 carbon atoms.匕 Cosmetics, (A) Hair cosmetics containing polyphenols, (E) Amidoamine compound represented by the following general formula (1) and (F) C2-C4 lower alcohol (A) A method for suppressing coloring of hair cosmetics containing polyphenols.

 [Chemical 10]

R— C-N-R--N (1)

 II I

O H

(In the formula, R ¹ represents a linear or branched alkyl group having 11 to 25 carbon atoms, an alkyl group, or a hydroxyalkyl group, R ² is an alkylene group having 1 to ³ carbon atoms, and R ³ is carbon. Represents an alkyl group of the number 1 to 3.)

 [0062] (A) As the polyphenols, those similar to the above can be used.

 The blending amount of the polyphenols in the case of the third invention is preferably 0.001 to 5% by mass, more preferably 0.001 to 2% by mass with respect to the total amount of the hair and cosmetics. If the amount is less than 0.001% by mass, sufficient effects such as astringent action, antioxidant effect and protein binding may not be obtained. If it exceeds 5% by mass, stickiness or wrinkle may occur.

 [0063] The amidoamine compound used in the present invention is represented by the following general formula (1), and can be used singly or in appropriate combination of two or more.

 [0064] [Chemical 11]

R ¹ — C good N (1)

II I \ R ³

OH ^Κ (In the formula, R ¹ represents a linear or branched alkyl group having 11 to 25 carbon atoms, preferably 15 to 21 alkyl group, a alkenyl group or a hydroxyalkyl group, and R ² represents an alkylene group having 1 to 3 carbon atoms. R ³ represents an alkyl group having 1 to ³ carbon atoms.)

 Examples of the amidoamine compound represented by the general formula (1) include lauric acid dimethylaminopropylamide, myristic acid dimethylaminopropylamide, palmitic acid dimethylaminopropylamide, stearic acid dimethylaminopropylamide, Dimethylamino acid pyramide, oleic acid dimethylaminopropylamide, isostearic acid dimethylaminopropylamide, palm fatty acid dimethylaminopropylamide, palm fatty acid dimethylaminopropylamide, beef tallow fatty acid dimethylaminopropylamide, lauric acid jetylaminoethylamide, myristic Acid jetylaminoethylamide, palmitic acid ethylaminoamide, stearic acid jetylaminoethylamide, behenic acid jetylaminoethylamide Oleic acid jetylaminoethylamide, isostearic acid jetylaminoethylamide, coconut fatty acid jetylaminoethylamide, palm fatty acid jetylaminoethylamide, beef tallow fatty acid jetylaminoethylamide, lauric acid jetylaminopropyl Amides, Myristate Jetylaminopropylamide, Palmitic acid Jetylaminopropylamide, Stearic acid Jetylaminopropylamide, Behenic acid Jetylaminopropylamide, Oleic acid Jetylaminopropylamide, Isostearic acid Examples thereof include amidoamine compounds such as acid jetylaminopropylamide, coconut fatty acid jetylaminopropylamide, palm fatty acid jetylaminopropylamide, and beef tallow fatty acid jetylaminopropylamide. Among these, stearic acid dimethylaminopropylamide, stearic acid jetylaminoethylamide, behenic acid dimethylaminopropylamide, and isostearic acid dimethylaminopropylamide are preferably used.

[0066] The amidoamine compound of the present invention is preferably used after neutralizing with an acid and adjusting the pH. Examples of the acid include inorganic acids such as hydrochloric acid, sulfuric acid, nitric acid, and phosphoric acid, and organic acids such as acetic acid, lactic acid, citrate, phosphonic acid, tartaric acid, glycolic acid, glutamic acid, succinic acid, and alkyl sulfuric acid. Among these, hydrochloric acid, phosphoric acid, lactic acid, citrate, and dallic acid are more preferable from the viewpoint of odor and effect. Further, the pH (25 ° C.) of the hair cosmetic obtained by neutralization is preferably 2 to 6 and more preferably 3 to 5 from the point of use feeling. [0067] The blending amount of the amidoamine compound is preferably 0.01 to 20% by mass, more preferably 0.1 to 5% by mass with respect to the total amount of the hair cosmetic. If the amount is less than 01% by mass, a sufficient anti-coloring effect may not be obtained, and if it exceeds 20% by mass, the feeling of use may be deteriorated.

 [0068] Examples of the lower alcohol having 2 to 4 carbon atoms used in the present invention include ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-1-propanol, 2-methyl-2-propanol and the like. Can be mentioned. These may be used alone or in appropriate combination of two or more.

 [0069] The blending amount of the lower alcohol having 2 to 4 carbon atoms is preferably 0.1 to 95% by mass, more preferably 0.5 to 80% by mass, and still more preferably 1 to the total amount of the hair and cosmetics. The range is ˜50 mass%. When the amount is less than 1% by mass, a sufficient anti-coloring effect may not be obtained. When the amount exceeds 95% by mass, the solubility of polyphenols may be deteriorated.

 [0070] (C) A cationic surfactant may be added to the hair cosmetic composition of the present invention! (C) Cationic surfactants similar to those described above can be used. The blending amount of component (C) in the case of the third invention is not particularly limited, but it is preferably 0.01 to 5% by weight, more preferably 0.1 to 5% by weight, based on the total amount of the hair and cosmetics. Particularly preferred is 0.1 to 3% by mass. If the blending amount is less than 0.01% by mass, the effect of good unity and feel may not be exhibited, and if it exceeds 10% by mass, it may result in stickiness or a heavy finish.

 [0071] Further, in the hair cosmetic composition of the third invention, as in the first and second inventions, an appropriate amount of components generally blended into the hair cosmetic composition can be blended as desired.

 [0072] When the fragrance is blended in the hair cosmetic composition of the present invention, the fragrance used is in accordance with the fragrance and fragrance composition described in JP-A-2003-95895, and the blending amount thereof is It is preferable that the fragrance composition is blended in an amount of 0.0001 to 50% by mass, more preferably 0.0001 to 30% by mass, based on the total amount of the material.

 [0073] Examples of the hair cosmetic composition of the present invention include rinses, hair styling agents, hair conditioning agents, and the like, and can be obtained by a conventional method of preparation.

 Example

[0074] [0075] Hereinafter, the present invention will be specifically described with reference to examples and comparative examples, but the present invention is not limited to the following examples. In the following examples, unless otherwise specified, “%” in the composition indicates mass%. Unless otherwise specified, the pH measurement temperature is 25 ° C.

 [Example I 1-7, Comparative Example I 1-5]

 Hair cosmetics having the compositions shown in Tables 1 and 2 were prepared according to conventional methods and evaluated by the following methods. The results are also shown in Tables 1 and 2.

[0077] Evaluation Method>

 10 Japanese female panelists who use hair dyes regularly (about once a month) and feel that their hair is hurt. ) Was evaluated for the effect of preventing split ends and cut hair, and the effect of restoring natural texture (no stickiness, no stickiness) when dried.

 Evaluation criteria>

 ◎: 9 out of 10 respondents answered good: LO name

 ○: 7 to 8 out of 10 respondents

 △: 4-6 out of 10 responded good

 X: 0 to 3 out of 10 responded good

[0078] [Table 1]

[0079] [Table 2] Comparative example

 Composition (%)

 1 2 3 4 5

 POE (30) phytosterol 0.5

 (A) POE (5) Phytosterol

 Phytosterol 0.5

 (B) gallic acid galcoside 0.5

 Gallic acid 0.5

 (O stearyltrimethylammonium chloride 0.5 0.5 0.5 0.5 0.5 human "oxyloxyl cellulose 0.5 0.5 0.5 0.5 0.5

 Other ethanol 10.0 10.0 10.0 10.0 10.0 Pure water Remainder

 100.0

 Split hair · Cut hair prevention effect Δ Δ Δ X X

 Evaluation

 Natural texture recovery effect Δ X O Δ Δ

 [0080] Table 3 below shows the raw materials used in the examples.

[0081] [Table 3]

 [Example I 8]

 Dispenser type water agent

 PE prepared with the following formulation of water based on conventional methods and kneaded with UV absorber

T pump dispenser container was filled.

 Composition Mass (%)

 Gallic acid 3, 5 Didarcoside 0.4

 Gallic acid 3 Darcoside 0. 01

 Polyoxyethylene (30) phytosterol 1.0

 Tetraoleic acid polyoxyethylene (40) sorbit 1.0

 Stearic acid dimethylaminopropylamide 0.4

 Sodium sulfate 0. 001

 Lauryldimethylaminoacetate betaine 5.0

Stearyl trimethyl ammonium chloride 3.0 POE (20) stearyl ether 3.0

 N Vinylpyrrolidone N, N Dimethylaminoethyl metatalylate 0.5

N-methacryloyloxyjetyl N, N dimethylaminoethyl.

 N MethylcarboxybetaineMethyl methacrylate alkyl ester

 Copolymer 1. 0

 (Product name Yuka Former 510, manufactured by Mitsubishi Chemical Corporation)

Hydrolyzed keratin 2.5

 (Product name Proticute U Alpha, manufactured by Ichimaru Falcos)

 0. 1

Methylparaben 0.1

Sodium pyrophosphate anhydrous 0.05

Glycolic acid 0.2

Trietanoramine 1.0

Fragrance composition A 0. 1

Ethanore 20. 0

purified water

Total 100. 0

 [Example I 9]

Non-aerosol pump foam

 A foam agent having the following formulation was prepared according to a conventional method and filled into a polypropylene pump foam container into which an ultraviolet absorber was kneaded. The pH was adjusted to 4.5.

Composition Mass (%)

Gallic acid 3,5-dimaltoside 0.8

Gallic acid-3-Dalcoside 0. 015

Polyoxyethylene (40) phytosterol 0.5

Polyoxyethylene tetraoleate (30) sorbit 1.5

Stearic acid dimethylaminopropylamide 0.8

Lauric acid sucrose ester 1.0 Lauric acid amidobutyl darazine 1.0

 3-methyl-1,3 butanediol 10.0

Silicone emulsion 8

(Product name: FZ— 4188, manufactured by Nippon Tunica)

Amino-modified silicone emulsion 5.0

(Product name: FZ— 4672, manufactured by Nippon Tunica)

Polyoxyethylene (30) stearyl ether 0.6

Lauryldimethylamine oxide 0.5

Plant squalene 0. 1

Water-soluble collagen 1.0

(Brand name Neptigen Genotype, manufactured by Ichimaru Falcos)

Methylparaben 0.1

Benzalkonium chloride 0. 1

Quenic acid 0.5

Diethanolamine 1.0

Fragrance composition C 0. 1

Ethanore 20. 0

Purified water balance

Total 100. 0

 [Example I 10]

Trigger type hair treatment

 A hair treatment with the following prescription was prepared based on a conventional method and filled into a trigger type container made of PET. The pH was adjusted to 4.3.

Composition Mass (%)

Gallic acid 3, 5 Didarcoside 1. 0

Gallic acid 3 Glucoside 0.012 Polyoxyethylene (60) phytosterol 1.5

Gallic acid 0.001 Sodium sulfate 0. 001

Lauryldimethylaminoacetate betaine 1.5

Stearyl trimethyl ammonium chloride 2.0 Propylene glycol 4.0

Polyoxyethylene 'methylpolysiloxane copolymer 1.0

Hydrolyzed silk solution 1. 0

(Brand name Silk Gen G Solvel S, manufactured by Ichimaru Falcos)

Hydroxypropyl chitosan solution 1. 0

 (Product name: Chitofilmer, manufactured by Ichimaru Falcos)

Methylparaben 0. 05

Sodium pyrophosphate anhydrous 0.05

Benzoic acid 0. 05

Sodium benzoate 0. 05

Monoethanolanolamine 0.5

Quenic acid

Sodium quenate

Ethanore 20. 0

Fragrance composition D 0. 05

Purified water balance

Total 100. 0

 [Example I 11]

 A jewel of the following formulation was prepared based on a conventional method, and filled into a PET pump type container into which an ultraviolet absorber was kneaded. The pH is adjusted to 4.4 and the viscosity is 1,500-3, OOOPa-

5--Didalcoside

Darcoside Polyoxyethylene (6) phytosterol 0.5 rosmarinic acid 0.5

Sodium sulfate 0.001 Salt-stearyltrimethylammonium 2.5 Polyoxyethylene (40) hydrogenated castor oil 3.0 Silicone emulsion 5.0

 (Product name: FZ— 4188, manufactured by Nippon Tunica)

Polyoxyethylene 'methylpolysiloxane copolymer 1. 0

Bi Bamboo Leaf Extract 1. 0

Decaglyceryl monoisostearate 2.0 Dihydroxybenzophenone 0.1 Monoethanolamine 0.5

Hydroxyethyl cellulose Appropriate amount Methylparaben 0.1

Benzoic acid 0.2

Sodium pyrophosphate anhydrous 0.2 Sodium sulfite 0.1

Glycolic acid

Dibutinorehydroxytonolene 0.001 Ethanol 20.0

Fragrance composition A 0. 05

Purified water balance

Total 100. 0

 [Example I 12]

Pump dispenser hair mist

A hemist of the following formulation was prepared according to a conventional method, and filled into a polyethylene pump dis- The pH was adjusted to 5.0. Composition Mass (%)

Gallic acid 3,5-didarcoside 0.5

Polyoxyethylene (4) phytosterol 0.1

Tetraoleic acid polyoxyethylene (40) sorbit 1.5

Isostearic acid dimethylaminopropylamide 0.1

Tannic acid 0.1

Sodium sulfate 0. 001

N-coconut oil fatty acid acyl-L-arginine ethyl DL-pyrrolidone carboxylate

 2. 0

Stearyl trimethylammonium chloride 0.5

Decaglyceryl diisostearate2.0

Wax emulsion * 5. 0

 70% Sorbit M Night 1.0

Birch extract 1. 0

Polyoxyethylene 'methylpolysiloxane copolymer 0.5 Benolberry extract 0.5

Methylparaben 0.3

Benzoic acid 0.2

Monoethanolanolamine 0.5

Quenic acid

Sodium quenate

Fragrance composition E 0.2

Ethanore 15. 0

Purified water balance

Total 100. 0

 *: 5 parts of carnauba wax, 7 parts of polyoxyethylene (15) lauryl ether and 88 of purified water were emulsified at 90 ° C (average particle diameter lOOnm).

[Example I 13] Aerosol foam

 An aerosol foam having the following formulation was prepared based on a conventional method. The container used was a pressure can made of aluminum.

Composition Mass (%)

 (Stock solution)

Gallic acid 3, 5 Didarcoside 1. 0

Polyoxyethylene (25) phytosterol 2.0

Sodium sulfate 0. 005

Cationized cellulose 0.4

 (Product name XK—503, manufactured by Lion Corporation)

Dipropylene glycol 6.0

Stearyl chloride trimethylammonium chloride 2.5

Amino-modified silicone 2. 0

 (Product name: SF8452C, manufactured by Toray Dow Coung 'Silicone Co., Ltd.)

Polyoxyethylene (60) hydrogenated castor oil 2. 0

Hydrolyzed keratin 1.0

 N Palm oil fatty acid acyl L Arginine ethyl DL pyrrolidone carboxylate

 0.5

Trimethylglycine (trade name Aquadeyu AN—100, manufactured by Ajinomoto Co., Inc.) 0.5 Canoleboxybininore polymer 0.5

Triethanolamine solution (30% aqueous solution) 2.0

Shea fat 1.0

 0.2

Fragrance composition C 0. 1

Ethanore 20. 0

Purified water balance

Stock solution total 92.0

(gas) LPG gas 8.0 Total 100.0

 [Example I 14]

Hair wax

 A hair wax having the following formulation was prepared according to a conventional method, and filled in a polypropylene jar type container into which an antistatic agent and an ultraviolet absorber were kneaded.

Composition Mass (%)

Gallic acid 3, 5 Didarcoside 2. 0

Polyoxyethylene (30) phytosterol 1.0

Salicylic acid 0.1

Dimyristyldimethylammonium chloride 3.0

Decaglyceryl diisostearate5.0

Canoleboxyvininole polymer 0.5

Xanthan gum 0.25

Water-soluble solid silicone (trade name KF—6004, manufactured by Shin-Etsu Chemical Co., Ltd.) 2.0 Silicone powder 1.0

 (Product name Tospearl 2000B, manufactured by GE Toshiba Silicones Co., Ltd.)

Hydrolyzed silk solution 0.5

 (Brand name Silk Gen G Solvel S, manufactured by Ichimaru Falcos)

Vaseline 3.0

Squalane 2.0

Candelilla Roo 1. 0

Apple extract 2.0

Poly 4.0

Methylparaben 0.1

 0.2

Sodium sorbate 0.1

Edetate Tetrasodium 0. 05 Diethanolamine 1.0

Fragrance composition B 0. 05

Ethanol 5.0

purified water

Total 100. 0

 [Example I 15]

Jill

 A jewel having the following formulation was prepared according to a conventional method, and filled into a polypropylene tube container into which an antistatic agent and an ultraviolet absorber were kneaded.

Composition Mass (%)

Gallic acid 3,5-didarcoside 0.5

Gallic acid 4 Mannoside 0. 02

Polyoxyethylene (40) phytosterol 1.0

Stearyl chloride trimethylammonium chloride 5.0

Alkyl-modified carboxybule polymer 0.5

Xanthan gum 0.25

Silicone paste (trade name KSG-21, manufactured by Shin-Etsu Chemical Co., Ltd.) 5.

Water-soluble solid silicone (trade name KF—6004, manufactured by Shin-Etsu Chemical Co., Ltd.) 2

Silicone powder 1.0

 (Product name Tospearl 2000B, manufactured by GE Toshiba Silicones Co., Ltd.)

Hydrolyzed silk solution 0.5

Polyoxyethylene (20) stearyl ether 4.0

Methylparaben 0.1

Benzoic acid 0.3

Isophthalanolenodehydrate 0.1

Benzalkonium chloride 0. 1

卜 Liethanolamine 2.5

Fragrance composition B 0. 05 Ethanore 15. 0

Summary 7k

Total 100. 0

 [Example I 16]

Shampoo

 A shampoo having the following formulation was prepared according to a conventional method, and filled into a polypropylene pump container into which an antistatic agent and an ultraviolet absorber were kneaded.

Composition Mass (%)

Methyl gallate-3,5-didarcoside 0.5

Propyl gallate 3 Mannoside 0. 01 Polyoxyethylene (30) phytosterol 0. 3

Beryl trimethyl ammonium chloride 0.5

Monoisostearic acid POE (30) hydrogenated castor oil 1.0

Sodium sulfate 0. 001

Sodium lauryl ether sulfate 10.0

Sodium a-olefin sulfonate 5.0

Fatty acid diethanolamide 5.0

Alkylamidopropylbetaine 5.0

Highly polymerized dimethyl silicone 3.0

 (Brand name BY11—003, Toray 'Dowcoung' manufactured by Silicone Co., Ltd.)

Cationic cellulose (trade name XK-503, manufactured by Lion Corporation) 0.5 Ethylene glycol distearate 2.0

Aloe extract 0.2

Sodium benzoate 0.8

Monoethanolanolamine 1.5

Fragrance composition A 0. 05

Purified water balance

 A

σ DOO PI 100. 0 [Example I 17]

Rinse

 A rinse having the following formulation was prepared based on a conventional method and filled into a polypropylene pump container into which an antistatic agent and an ultraviolet absorber were kneaded.

Composition Mass (%)

Gallic acid 3,5-didarcoside 0.5

Gallic acid 3 Darcoside 0. 02

Polyoxyethylene (40) phytosterol 1.5

Stearyl chloride trimethylammonium 1. 0 cetostearyl alcohol 3.0

 POE (5) Stearyl ether 1.5

Liquid paraffin 1. 0

Cyclomethi = 3 0.5

(Product name: DC246, Toray 'Dowcoung' manufactured by Silicone Co., Ltd.)

Dimethyl silicone 5.0

(Product name: SH200—500cs, manufactured by Toray / Dowcoung / Silicone)

Zeniai extract 0.2

Methylparaben 0.1

Monoethanolanolamine 0.5

Sodium benzoate 0.4

Fragrance composition C 0. 1

Purified water balance

Total 100. 0

 [Example I 18]

Hair cream

Dissolve the following A oil phase part and B aqueous phase part at 70 ° C respectively, add the A oil phase part to the B aqueous phase part to uniformly emulsify, and further cool C while cooling, Prepare the cream Filled Lumi laminated tube.

Composition Mass (%)

(A oil phase)

Squalene 5.0 Ethyl oleate 2.0 Otyldodecyl myristate 1.5 Liquid paraffin 1. 0 Polyethylene glycol monostearate (40EO) 3.0 Palm oil fatty acid sorbitan 2. 0 Glycerol monostearate 1.0 Cetostearyl Alcohol 1.0 Propylparaben 0.1

(B water phase)

Gallic acid 3, 5 Dimaltoside 0.5 0.5 Gallic acid-4 Maltoside 0.03 Polyoxyethylene (60) phytosterol 0.5 0.5 Salt-palmityltrimethylammonium 0.3

1, 3 Butyleneglycolanol 2.5 Dipropylene glycol 2.5 Monoethanolamine 0.5 Methylparaben 0.1 Sonorebic acid 0.1 Dipotassium glycyrrhizinate 0.2 Gentian extract 0.1 Purified water remainder (C)

Material composition D 0. 05 Total 100. 0 [Example I 19]

Airzone reform

An aerosol foam of the following formulation was prepared according to a conventional method and filled into a pressure-resistant container made of PET.

Composition Mass (%)

 (Stock solution)

Methyl gallate-3,5 didarcoside 2.0

Methyl gallate-3-Dalcoside 0.005 Polyoxyethylene (30) phytosterol 1.5

 EO-modified silicone 4.0

Pirotaton Olamine 0.5

Ethyl oleate 3.0

Amphoteric polymer 1.0

 (Product name Yuka Former 204, manufactured by Mitsubishi Chemical Corporation)

Stearyl trimethylammonium chloride 0.5

 POP (9) Diglyceryl ether 1.5

Monooleic acid POE (20) sorbitan 0.5

Polyoxyethylene (30) stearyl ether 1.0

Monoethanolanolamine 2.5

Sonorebic acid 0.1

Benzoic acid 0.1

Fragrance composition B 0. 2

Ethanol 20.0

Purified water balance

Total 100. 0 (gas)

 LPG 10.0

 DME 10._0 _

 A doo

OBI 100. 0 [0094] The perfume compositions A to E used in each of the above examples are listed in JP-A-2003-95895.

The fragrance compositions A to E described in 5 to 19 are applied.

[0095] Regarding Example I-8 to 19, in the same manner as Example I-1 to Example 7 above, when the effect of preventing split ends / breaking hair, natural texture, and recovery were evaluated, the deviation was also good. It was.

[0096] [Example II 1-7, Comparative Example II 1-12]

 Hair cosmetics having the compositions shown in Tables 4 and 5 were prepared based on conventional methods and evaluated by the following methods. The results are also shown in Tables 4 and 5.

[0097] [Evaluation Method]

 Moist feeling, suppleness, good quality

 20 panelists whose hair was damaged by the hair dye perm were used on freshly-dried hair after tail-drying 3g of hair and cosmetics, and the moisture and suppleness of the hair after use were consolidated. Each item of goodness was compared with that before use. The results are shown based on the following evaluation criteria.

 Evaluation criteria>

 ◎: 16 or more of 20 respondents said that after use was better

 〇: 10-15 out of 20 respondents said that better after use

 △: 4-9 out of 20 respondents said that after use was better

 X: Less than 3 of 20 respondents said that after use was better

[0098] CMC. Matrix repair effect (Tensile testing machine)

 To 3 g of a human hair bundle dyed with a commercially available bleaching agent, 0.2 g of a hair cosmetic was evenly applied and naturally dried. Ten of the medium forces were picked at random, and the number of chopped! / Of 10 was counted when pulled at 1 OOg using a tensile tester (manufactured by Toyo Baldwin).

[0099] CMC. Matrix repair effect (SEM observation)

To 3 g of a human hair bundle dyed with a commercially available bleaching agent, 0.2 g of a hair cosmetic was evenly applied and naturally dried. Ten of the medium forces are also taken at random, and are pulled using a tensile tester until the hair is cut. The cut portion is observed with SEM (800 times), and the hair condition shown in Fig. 2 is repaired. The hair condition shown in Fig. 1 was evaluated as unrepaired hair based on the following evaluation criteria. Evaluation criteria>

 ○: Repaired hair 7-10 out of 10 △: Repaired hair 4-6 out of 10 X: Repaired hair 0-10 out of 10 [0100] [Table 4]

[0101] [Table 5]

 * 1: Product name SM8704C, manufactured by Toray 'Dowcoung' Silicone Co., Ltd.

 * 2: Product name Promois WK—H Seiwa Kasei Co., Ltd.

 The following hair preparations of Examples 8 to 19 were prepared based on the conventional methods for each preparation.

 [Example Π-8] Go to Ajiel

Composition Mass (%)

Gallic acid 3, 5 Didarcoside 1. 0

Stearyl trimethyl ammonium chloride 3.0

Hydroxy cetenorerose 0.5

 (Product name SE-900, manufactured by Daicel Engineering Co., Ltd.)

Polyether-modified silicone (manufactured by Shin-Etsu Chemical Co., Ltd., KF6012) 2.0

N-methacryloyloxychetyl N, N dimethylaminoethyl-α- Ν-methylcarboxybetaine 'methacrylic acid alkyl ester copolymer 3.0

(Product name Yuka Former 510, manufactured by Mitsubishi Chemical Corporation) Triglyceryl distearate 3.0 Polyoxyethylene (40) hydrogenated castor oil 0.3 Dihydroxybenzophenone 0.1 Methyl paraben 0.1 Triethanolamine 0.5 Perfume A 0.2 Ethanol 10.0

Purified water balance

 Total 100. 0

 [Example II 9] Hair wax

Composition Weight (%) Gallic acid 3 Dalcoside 1.0 Polyoxyethylene (6) sorbitol tetraoleate 3.0 Canoloxixi vinole polymer 0.5

(Product name: Carbopol 940, manufactured by Goodrich)

Benzalkonium chloride 1. 0 Xanthan gum 0. 3

EO-modified silicone (trade name KF6004, manufactured by Shin-Etsu Chemical Co., Ltd.) 2.0 Petrolatum 3.0 Squalane 2. 0 Candelilla wax 1.0 Dipropylbenzophenone 0.1 Propyl paraben 0.1 Methyl paraben 0.3 Enoxyethanol 0.5 tetrasodium edetate 0.05 0.05 Liethanolamine 0.5 Ethanol 10. 0 Fragrance B 0.2 Purified water balance

 Total 100. 0%

 [Example II 1 10] Hair cream

Composition Weight (%) Gallic acid 1,3,5-didarcoside 1.0 Hexaglyceryl tristearate 3.0 Distearyldimethylammonium chloride 3.0 Amino-modified silicone 0.5 (trade name SM8704C, Toray 'Dow Coung' Silicone Co., Ltd.) Methyl polysiloxane (100,000 est) 5.0 Liquid paraffin 5. 0 Paraffin wax 3. 0 Polyoxyethylene (40) hydrogenated castor oil 2.0

3-Methyl-1,3-butanediol 10.0 Dihydroxybenzophenone 0.1 Propylparaben 0.1 Methylparaben 0.3 Phenoxyethanol 0.5 Palm oil fatty acid sorbitan 2.0 Monoglyceryl monostearate 1.0 Mono Propylene glycol stearate 2.0 卜 Liethanolamine 0.5 Ethanol Nore 5. Perfume C 0.2 Purified water balance

Total 100. 0 [Example II 11] Hair foam

 Composition Mass (%) Gallic acid 3, 5 Didarcoside 1.0 Copper copper dalconate 0.3

 Ν—Methacryloyloxetyl Ν Methacrylic acid alkyl ester copolymer 3.0

(Product name Yuka Former 204WL, manufactured by Diachem Co., Ltd.)

 Polyether modified silicone 0.5

 (Product name: KF6011, manufactured by Shin-Etsu Chemical Co., Ltd.)

 3-methyl-1,3 butanediol 2.0 polyoxyethylene (6) sorbitol tetrastearate 3.0 polyoxyethylene (60) phytosterol 1.5 dimethylaminopropylamide stearate 0.1 stearyltrimethylammonium chloride 0.5 Methylparaben 0.3

 卜 Liethanolamine 0.1

 Fragrance E 0. 1

 Ethanore 30. 0

 Liquefied petroleum gas 7.0

 Purified water balance

 Total 100. 0

[Example II 12] Hair foam

 Composition Weight (%) Gallic acid 3, 4 Didarcoside 0.5 Zinc dalconate 0.3

 Polyether-modified silicone 5.0

 (Product name: KF6011, manufactured by Shin-Etsu Chemical Co., Ltd.)

3-Methyl-1,3 butanediol 2. 0 Cationized cellulose 0.1 (Product name: Leo Guard GPS, manufactured by Lion Corporation)

 N Palm oil fatty acid L Glutamic acid 0.5 Cetyltrimethylammonium chloride 1.0 Polyoxyethylene (8) erythritol dioleate 3.0 Polyoxyethylene (40) hydrogenated castor oil 0.4 Methyl paraben 0.3 Quenic acid 0 1 Fragrance D 0. 1 Ethanol No. 20. 0 Liquefied petroleum gas 7.0 Balance of purified water

 Total 100. 0%

 [Example II 13] Hair spray

[Undiluted solution]

Composition Mass (%) Gallic acid methyl ester 3, 5-didarcoside 0.5 Iron dalconate 0.3 Polyvinylpyrrolidone (K-30) 2. 0 Polyoxyethylene (40) sorbitol tetraoleate 3.0 Amino-modified silicone 0 5 (Brand name SM8704C, manufactured by Toray 'Dowcoung' Silicone Co., Ltd.) Cetyltrimethylammonium chloride 1.0 Polyoxyethylene hydrogenated castor oil (40) 0.5 Methyl paraben 0.3 Fragrance B 0.1 Ethanore 90 . 0

Purified water balance

Stock solution meter 100. 0 Composition (%) Above stock solution 50 Liquefied petroleum gas 30 Dimethyl ether 20 Total 100

[Example II 14] Hair water

 Composition (%) Gallic acid 3, 5 Didarcoside 1.0 Water-soluble solid silicone 0.5

(Product name: KF6004, Shin-Etsu Chemical Co., Ltd.)

 3-methyl-1,3 butanediol 2.0 stearyltrimethylammonium chloride 0.5 polyoxyethylene (60) sorbitol tetraoleate 2.5 polyoxyethylene (25) phytosterol 1.0 dimethylaminopropyl stearate Amide 0.4 Lauryldimethylamine oxide 0.2 Sodium pyrrolidone carboxylate 1.0 Methyl paraben 0.3 Glyconore acid 0.2 Sodium pyrophosphate 0.3 Hydroxy benzophenone sulfonic acid 0.1 Perfume A 0.1 Ethanol 20. 0 Purified water balance 100. 0

 [Example II 15] Hair nourishing agent

Composition Weight (%) Gallic acid 3 Darcoside 1.0 Salt lauryltrimethylammonum 1.0 amino modified silicone emulsion 0.5 (trade name FZ4672, manufactured by Nippon Car Co., Ltd.)

Decaglyceryl tristearate 1.0 Monoglyceride monopentadecanoate 3.0 Acetic acid DL α Tocopherol 0.1 Coconut oil fatty acid sorbitan 1. 0 Sucrose myristic acid ester 0.5 Piotine 0. 002 Succinic acid 0. 3 Assembly extract 1.0 Hinokichionore 0. 1

L—Menthol No. 0.3 Fragrance 適 Appropriate amount

99. 5% Etanolore balance 100.0

 [Example II 16] Hair growth spray

Composition Mass (%) Gallic acid 3, 5 Didarcoside 1.0 Carboxyl-modified silicone 1.0 (Shin-Etsu Silicone, trade name X—22-3710, manufactured by Shin-Etsu Chemical Co., Ltd.) Monopentadecanoic acid glyceride 1.0 Tetraoleic acid ΡΟΕ (6) Sorbit 0.5 amphoteric polymer 0.2 ethyl oleate 0.1 citrate 0.3 sucrose laurate 0.5 Fragrance A

 L—Menthol 0.

 Total 100. 0

 * N—Methacryloylethyl N, N dimethylammo-α α Ν—Methylcarboxibine / alkyl methacrylate copolymer

 [Example Π- Composition Weight (%)

Gallic acid 3, 5 Didarcoside 1

ΡΟΕ (3) Sodium lauryl ether sulfate 15

Alkyldimethylamine oxide 2

ΡΟΕ Alkyl ether 1

Diglyceryl dioleate 1

Hardened castor oil 4

Fatty acid diethanolamide 5

Methyldarcoside ΡΟΕ dioleate 1

Highly Polymerized Methyl Polysiloxane ΖPolyether Modified Silicone Emulsion 3 (Shin-Etsu Silicone, trade name X—52—2262, manufactured by Shin-Etsu Chemical Co., Ltd.)

Wax 1

Cetostearyl alcohol 2

Cationized cellulose 0.5

Copolymer of dimethyldiallyl ammonium chloride, acrylamide and acrylic acid

 0.2

Pirotaton Olamine 0.5

Benzalkonium chloride 0. 05

Glycerin 1

Butylene Gliconole 0.5

Sodium sulfate 2 Sodium benzoate 1

Paraben 0.2

Methyl isothiazoline on 'Methyl black isothiazoline on 0. 01 Green 3 0. 002

Fragrance A 0.5

Quenic acid 0.5

Purified water balance

 Total 100. 0

 [Example Π—18] Hair conditioner

Composition] (%) Gallic acid 3,5-didarcoside 0

4 Guadinobutyl laurylamide 0.8

 N— [3 alkyl (12, 14) oxy 2 hydroxypropyl] L—Argy

 0.5

Polyethylene glycol (average molecular weight: 5 million) 0.2 Behethyl-ethyl acetate ethyl ester 0.2 Dimethyl silicone (viscosity 1 million mm ² Zs) 1.0

(Product name SH200—1,000, OOOcs, manufactured by Toray Dow Cowing Co., Ltd. Silicone) Dimethyl silicone (viscosity 100,000 mm ² / s) 1.0

(Product name SH200—100, OOOcs Toray 'Dowcoung' manufactured by Silicone Co., Ltd.) Dimethyl silicone (viscosity 50mm ² Zs) ―. 0

 (Product name SH200-50cs, manufactured by Toray Dow Cowing Silicone Co., Ltd.) Diglycerin Isopalmitate Sebacic Acid Condensate 0 Glycine 0.7

Cetanore 1.5

Benorenoreconorre 0.2 oleinorenoreconolele 0.3 Oleic acid 0.2 Isostearic acid 0.2 Trimethylglycine 0.2

Anoleginin 0.3

Sistine 0.3

Hexaglyceryl pentastearate1.0 sorbitan monolaurate0.1 phosphoric acid

Methyl noroxybenzoate Appropriate amount Propyl paraoxybenzoate Appropriate amount Perfume B Appropriate

Cum balance

 Total 100. 0

pH 3.4

 [Example II—19] Hair treatment

Composition Mass (%) Gallic acid 1 3-Maltoside 1. 0 Salt lauryltrimethylammonium 1.0

4-Guanidinobutyllaurylamide 1.5

N—coconut oil fatty acid L-arginine ester 0.5 dimethyl silicone (viscosity 100,000 mm ² / s) 1.0

(Product name SH200—100,000cs, Toray 'Dowcoung' manufactured by Silicone Co., Ltd.) Dimethyl silicone (viscosity 30mm ² Zs)

(Product name SH200-30cs, manufactured by Toray, Dowco, Silicone Co., Ltd.) Diglycerin isopalmitate sebacic acid condensate 1.5 Diglycerin isostearic acid sebacic acid condensate 0.7 Cetanorore 1.5

Behe / Rarenoconoren 3.0 Stearyl alcohol 2.0 Isostearic acid 0.2

 Glycerin 3.0

 Propylene glycol 5.0

 Decaglyceryl diricinoleate 0.1

 Sorbitan monolaurate 0.1

 Polyethylene glycol (average molecular weight 900,000) 0.4

 Phosphoric acid

 Methyl paraoxybenzoate

 Propyl paraoxybenzoate

 Fragrance B appropriate amount

 Purified water balance

 Total 100. 0

 [0114] In Examples VIII-8-19, as in the case of the above examples, the moisture feeling, suppleness, cohesiveness, and CMC and matrix repair effects of hair were evaluated. Note that the fragrance compositions A to E used in the above Examples and Comparative Examples conform to the fragrance compositions A to E described in Tables 2 to 16 of JP-A-2003-267841.

[Examples III 1-9, Comparative Examples III 1-5]

 Hair lotion compositions shown in Tables 6 and 7 were prepared, and the coloring inhibition effect and usability were evaluated by the following evaluation methods.

[0116] (1) Coloring suppression effect

 The evaluation sample was placed in a colorless transparent glass bottle with a capacity of 24 mL and stored at 50 ° C. for 1 week. Ten evaluators visually evaluated the evaluation samples under a tungsten lamp (500 W) for the presence or absence of coloring, and the results were judged in four stages according to the following evaluation criteria.

 Evaluation criteria>

 ◎: Number of evaluators who did not have coloring

 〇: 7 to 9 evaluators who do not have coloring

 Δ: 3 to 6 evaluators who did not have coloring

X: The number of evaluators who did not have coloring is 2 or less (2) Usability

 Ten evaluators applied the evaluation samples to the hair or skin, evaluated the presence or absence of stickiness or wrinkle, and evaluated the evaluation results in four stages according to the following evaluation criteria. All evaluators performed hair color treatment.

Evaluation criteria>

 ◎: There are 9 or more evaluators who are not sticky or stiff.

 〇: The number of evaluators who were not sticky or wrinkled was 6-8

 Δ: 3 to 5 evaluators with no stickiness or wrinkle

 X: The number of evaluators who did not feel sticky or stiff was 2 or less

[Table 6]

[Table 7]

Implementation ί ¾ III 例 ί Comparative Example III

8 9 1 2 3 4 5 Gallic acid monohydrate-0.005 0.005 0.01 0.005--Gallic acid-3,5- succinic acid * 1 1.0 0.4 1.0 Stearic acid methylaminoph. Oral pyramide-0.8--0.4 0.5 -"Henic acid" methylaminoda P-pyramide '3.0------Ethanol 5.0 10.0 10.0 30.0 10.0 10.0

Hydrochloric acid 0.27 0.08 0.001 0.04 0.04

 Purified water Remainder Remainder Remainder Remainder Remainder Remainder Remainder Muto 100.0 100.0 100.0 100.0 100.0 100.0 100.0

 H 3.5 3.4 3.1 3.4 3.4 3.7 3.1 Anti-coloring effect ◎ ◎ X X Δ ◎ △ No stickiness ○ ◎ ◎ X Δ ○ ○ No stickiness ◎ ◎ X X ○ X X

[Example m-10]

 An aerosol foam composition for hair styling having the following composition was prepared.

 [Preparation Method] Components other than dimethylpolysiloxane and liquid petroleum gas were mixed, and this mixed solution was filled into a pressure resistant aluminum can, and then filled with dimethylpolysiloxane and clinched with an aerosol valve. Finally, liquid petroleum gas was filled to obtain a foam agent.

Composition Mass (%)

Cationized cellulose * 2 0.2

N Palm oil fatty acid acyl-L Sodium glutamate * 3 0.2 Polyoxyethylene isostearyl ether * 4 0.7

Palmitic acid dimethylaminopropylamide 0.6

Dimethylol polysiloxane (100mm ² Zs) 3.0

Dimethylol polysiloxane (10 million mm ² / s) 1.0

Methyl paraoxybenzoate 0. 05

Tannic acid 5 0. 3

Sodium pyrrolidonecarboxylate (50%) 0.4

Fragrance composition B 0. 05

 L Lactic acid appropriate amount (adjusted to pH 4.5)

Ethanore 15. 0

Purified water balance Liquefied petroleum gas (0.49 MPa) 7.0

 Total 100. 0

 [0120] [Example III 11]

 An aerosol foam composition for hair styling having the following composition was prepared.

 [Preparation Method] Components other than olive squalane, highly polymerized methylpolysiloxane, sodium citrate, liquefied petroleum gas, and dimethyl ether were mixed, and then adjusted to pH 5.0 with sodium citrate to obtain a stock solution. This stock solution was filled into a transparent pressure-resistant PET container, filled with olive screen and highly polymerized methylpolysiloxane in this order, and clinched with an aerosol valve. Finally, liquid petroleum gas and dimethyl ether were charged in this order to obtain a foam agent.

 Composition Mass (%)

 Palm oil fatty acid dimethylaminopropylamide 0.3

 3-methyl-1,3 butanediol 5.0

 Olivesk lantern 0. 1

 Polyoxyethylene stearyl ether * 6 0.2

 Polyoxyethylene sorbitan monopalmitate * 7 0. 4

 Hamelis extract * 8 0.5

Highly polymerized methylpolysiloxane (1 million mm ² Zs) 1.5

 Quenic acid 0.1

 Sodium quenate appropriate amount (adjusted to pH 5.0)

 Methyl paraoxybenzoate 0.15

 Oxybenzonesulfonic acid 0.1

 Ethanol 10.0

 Purified water balance

 Liquefied petroleum gas (0.29MPa) 8.5

 Dimethyl ether 1.5

 Total 100. 0

 [0121] [Example III 12]

A non-aerosol foam preparation for hair styling having the following composition was prepared. [Preparation Method] The following components were mixed and dissolved, and this mixed solution was filled in a non-aerosol-type pump foam container to obtain a non-aerosol foam.

Composition Mass (%)

Stearic acid jetylaminoethylamide 1.0

Lauryldimethylamine oxide solution * 9 0.5

Polyoxyethylene (30) phytosterol * 44 1.5

Tetraoleic acid polyoxyethylene (40) sorbit 1.5

Cationic polymer compound * 10 1. 0

Polyoxyethylene cetinoleatenole * 11 0. 3

Amino-modified silicone emulsion * 12 2.5

Gallic acid 3, 5 Didarcoside * 1 0. 5

Methyl noroxybenzoate 0.1

Propyl paraoxybenzoate 0. 05

Oxybenzonesulfonic acid 0.1

DL Lactate appropriate amount (adjusted to pH 4.0)

Fragrance composition C 0. 15

Ethanore 23. 0

Purified water balance

Total 100. 0

 [Example III 13]

 An aerosol spray for hair care having the following composition was prepared.

 [Preparation Method] Components other than dimethyl ether were mixed and dissolved, and this mixed solution was filled in a pressure resistant aluminum can and then clinched with a tilt type aerosol valve. Finally, dimethyl ether was filled to obtain an aerosol spray.

Composition

 DL—Pantotenyl alcohol

Polyether modified silicone * 13

Behenic acid dimethylaminopropylamide Propyl gallate 0.1

Age xibenzone 0.1

Hydrolyzed silk solution * 14 0.6

Hydroxypropyl chitosan solution * 15 0.6

Phosphoric acid appropriate amount (adjusted to pH 4.5)

Ethanol 10.0

Dimethyl ether 30.0

Purified water balance

Total 100.0

 [Example ΠΙ—14]

 A jeweler for hair care having the following composition was prepared.

 [Preparation Method] Hydroxyethyl cellulose was dispersed in propylene glycol, and water was added to dissolve it, and then the remaining components were mixed. Stirring was continued until the liquid became more viscous. This composition was filled in a pump-type container to obtain a jeweler.

Composition Mass (%)

Hydroxy echenoresenorelose * 16 1.0

Stearic acid dimethylaminopropylamide 0.4

Palmitic acid dimethylaminopropylamide 0.2

Amino-modified silicone emulsion * 17 2.5

Polyoxypropylene (14) diglyceryl ether * 18 0.7

Propylene glycol 3.0

Gallic acid 3, 5 Didarcosyl * 1 0.5

Crude rosmarinic acid * 19 0.5

Quenic acid 0.1

Sodium quenate 0.1

Sodium pyrophosphate 0.05

Glycolic acid appropriate amount (adjusted to pH 4.0)

Fragrance composition A 0.05 Dihydroxybenzophenone 0. 05 Methyl noroxybenzoate 0.]

 Ethanol 25.0

 Purified water balance

 Total 100. 0

 [0124] [Example III 15]

 A hair lotion preparation having the following composition was prepared.

 [Preparation Method] The following components were mixed and dissolved, and this composition was filled into a squeeze container having a discharge port diameter of 2 mm to obtain a hair lotion.

 Composition Mass (%)

 Dipropylene glycol 1.5

 Monoisostearic acid POE hydrogenated castor oil * 20 0.2

 Polyoxyethylene (20) isostearyl ether * 21 0.5

 Polyoxyethylene (30) phytosterol * 44 0. 1

 Tetraoleic acid polyoxyethylene (40) sorbit 0.1

 Dimethylaminopropylamide stearate 0.7

 Dimethyl silicone emulsion * 22 0. 8

 Trimethinoreglicin water 23 0. 3

 Syracano extract * 24 1. 0

 Eucalyptus extract * 25 0. 5

 Black tea extract 26 0. 5

 L Glutamic acid Appropriate amount (adjusted to pH 4.3) Methyl parabenzoate 0.1

 Fragrance composition E 0. 3

 Ethanol 15.0

 Purified water balance

 Total 100. 0

[0125] [Example III 16] A hair rinse agent having the following composition was prepared.

 [Preparation Method] While the component (A) was heated to 80 ° C. and stirred well, the mixed solution of (B) that was also heated to 80 ° C. was added with stirring. The mixed solution was cooled to 50 ° C. with stirring, and component (C) was added to obtain a hair rinse. The emulsified average particle size was 2 m, and the viscosity at 25 ° C was 4.5 Pa's as a result of measurement with a BL type viscometer (3 rotor, 12 rpm).

Composition Mass (%)

 (A)

Lauric acid amidobutyl darazine * 27 0. 1

Acetyl myristate palmitate amidobutyldardine * 28 0. 1

 N— [3-Alkyl (12,14) oxy-2-

Hydroxypropyl] —L-arginine hydrochloride solution * 29 0. 1

Polyethylene glycol * 30 0.2

Behenic acid jetylaminoethylamide 0.8

Diglycerin isopalmitic acid ester sebacic acid condensate * 31 1. 0 Phosphoric acid appropriate amount (adjusted to pH 3.4)

Cetanore 1.5

Behe-Noranoreconole 0.2

Oleno Leano Recone No 0.3

Oleic acid 0.2

Isostearic acid 0.2

Glyceryl monostearate * 32 0. 1

Sorbitan monolaurate Water 33 0. 1

Propyl paraoxybenzoate 0.3

Dimethyl silicone (1 million mm ² Zs) 1.0

Dimethyl silicone (100,000 mm ² Zs) 1.0

Dimethyl silicone (50mm ² Zs) 1.0

(B) Glycine 0.7

Trimethylglycine * 23 0.2

Anoleginin 0.3

Gallic acid 3, 5 Didarcosyl * 1 0

Methyl paraoxybenzoate 0.

Purified water balance

(C)

Ethanore 2.0

Material composition B 0.5

 100. 0

 [Example ΠΙ—17]

 A hair rinse agent having the following composition was prepared.

 [Preparation Method] While the component (A) was heated to 70 ° C. and stirred well, the mixed solution of (B) that was also heated to 70 ° C. was added with stirring. The mixed solution was cooled to 50 ° C. with stirring, and component (C) was added to obtain a hair rinse. The pH of this composition was 3.3, the average emulsion particle size was: m, and the viscosity at 25 ° C was 5 Pa's as a result of measurement with a BL type viscometer (No. 3 rotor, 12 rpm).

Composition Mass (%)

 (A)

2-Ethylhexyl paradimethylaminobenzoate * 34 0. 05 4—tert Butyl-4'-methoxydibenzoylmethane * 35 0. 05

Isostearyl myristate 0

Amphoteric product of methacrylate ester copolymer * 36 ―. 5 Palmitic acid dimethylaminopropylamide 2.0

Stearyl alcohol 4.0

Polyoxyethylene (20) hydrogenated castor oil * 37 1. 0

Glycolic acid 0.15

Propylene glycolate 5.0 (B)

Hamelis extract * 8 0.5

Purified water balance

(C)

Ethanol 3.0

Material composition A 0 ^ 3

Total 100. 0

 [Reference example ΠΙ— 1]

 A skin care lotion having the following composition was prepared.

 [Preparation Method] Excluding Purified Water While the component (A) was heated to 70 ° C. and stirred well, the purified water in the component (A) that was also heated to 70 ° C. was added with stirring. To this mixed solution, the mixture of component (B) was added and cooled to 50 ° C. with stirring. A mixed solution comprising the fragrance of component (C) and other components was added to obtain a composition. After filling this composition into a pressure resistant aluminum can, it was clinched with an aerosol valve, and finally filled with nitrogen gas so that the internal pressure of the container at 25 ° C. was 0.5 MPa, to obtain a skin care lotion.

Composition Mass (%)

 (A)

Decaglyceryl monoisostearate * 38 2. 0

Plant squalene * 39 3. 0

Polyoxyethylene 'methylpolysiloxane copolymer * 40 1. 0 Jetylaminoethylamide stearate 0.3

Otachidodecyl isostearate * 41 1. 0

Quenic acid 0.1

dl—α—Tocopherol 0.1

Methyl paraoxybenzoate 0.2

Purified water 30. 0

 (Β)

Concentrated glycerin 3.0 Xanthan gum * 42 0.05

(C)

 L Proline 0.5

Gallic acid 3, 5 Didarcoside * 1 0.5

Hyanorelon acid sodium water 43 0.05

Black tea extract 26 0.25

Sodium quenate appropriate amount (adjusted to pH 5.5)

Fragrance composition C 0.05

Ethanol 5.0

Purified water balance

Total 100.0

 In Examples m-io to i7 and Reference Example 1, the coloration suppressing effect was good, and there was no stickiness or stiffness, and the feeling of use was good.

 The raw materials (trade names) used in the above Example IV are shown below.

* 1 Zidalcosyl gallic acid (Mitsui Chemicals, Inc.)

* 2 Leo Guard KGP (manufactured by Lion Corporation)

* 3 Amisoft CS—11 (Ajinomoto Co., Inc.)

* 4 EMALEX 1810 (manufactured by Nippon Emulsion Co., Ltd.)

* 5 Lexode P (—Made by Maru Falcos)

* 6 EMALEX 630 (Nippon Emulsion Co., Ltd.)

* 7 NIKKOL TP-10 (Nikko Chemicals)

* 8 Falco Rex Hamamelis B (Made by Maru Falcos)

* 9 ALOMOTTAS DM12D— W (C) (manufactured by Lion. Akuzo Co., Ltd.)

* 10 H. C. Polymer 2L (Osaka Organic Chemical Co., Ltd.)

* 11 EMALEX125 (Nippon Emulsion Co., Ltd.)

* 12 SM-8704C (Toray 'Dowcoung' manufactured by Silicone Co., Ltd.)

* 13 SH3773 (Toray Dowco Jung made by Silicone Co., Ltd.)

* 14 SILKGEN G Solvel S (Made by Maru Falcos) * 15 Quitofilmer (Ichimaru Falcos Co., Ltd.)

 * 16 HEC Daicel SE900 (manufactured by Daicel Chemical Industries)

 * 17 FZ-4672 (made by Nippon Tunica)

 * 18 SY-DP14T (Sakamoto Pharmaceutical Co., Ltd.)

 * 19 Crude rosmarinic acid product obtained in Preparation Example 1 of JP2003-300811

* 20 EMALEX RWIS—120 (Nippon Emulsion Co., Ltd.)

 * 21 EMALEX 1820 (manufactured by Nippon Emulsion Co., Ltd.)

 * 22 KM903 (Shin-Etsu Silicone, manufactured by Shin-Etsu Chemical Co., Ltd.)

 * 23 Amino Coat (Asahi Kasei Corporation)

 * 24 Birch extract (manufactured by Maruzen Pharmaceutical Co., Ltd.)

 * 25 Eucalyptus extract (manufactured by Koei Kogyo Co., Ltd.)

 * 26 Black tea liquid (Ichimaru Falcos Co., Ltd.)

 * 27 C12A4G (manufactured by Rengo)

 * 28 C1416A4G (Nippon Kayaku Co., Ltd.)

 * 29 Ami Safe LMA-60 (Ajinomoto Co., Inc.)

 * 30 Polyox WSRN— 60KCG (Amacor)

 * 31 Saracos DGS16 (Nisshin Oilio Co., Ltd.)

 * 32 NIKKOL MGS-B (manufactured by Nikko Chemicals)

 * 33 NIKKOL SL-10 (Nikko Chemicals Co., Ltd.)

 * 34 S Power Roll 507 (Van Dyk)

 * 35 Northol 1789 (Gibodan Rule)

 * 36 Yuka Former AM75-201 (Mitsubishi Chemical Corporation)

 * 37 EMALEX HC—20 (Nippon Emulsion Co., Ltd.)

 * 38 NIKKOL Decaglyn l—IS (Nikko Chemicals Co., Ltd.)

 * 39 Huitsk ヮ ran (manufactured by Sophim)

 * 40 TSF4441 (GE Toshiba Silicone Co., Ltd.)

 * 41 ISOD (Shinei Chemical Co., Ltd.)

* 42 Monato Gum DA (Dainippon Pharmaceutical Co., Ltd.) * 43 Bio hyaluronic acid (Ichimaru Falcos Co., Ltd.)

 * 44 GO-4V (6 moles with EO), GO-430V (30 moles with EO), GO-440V (40 moles with EO), GO-460V (with EO) 60 moles)

(Nikko Chemicals Co., Ltd.)

* The fragrance compositions A to E are in accordance with the fragrance compositions A to E described in Tables 5 to 19 of JP-A-2003-95895.

Claims

The scope of the claims

 [1] A hair cosmetic composition containing (A) polyphenols and (B) plant sterols.

 [2] (B) The hair cosmetic composition according to claim 1, wherein the plant sterol is an alkylene oxide adduct of phytosterol.

[3] The hair cosmetic composition according to claim 1 or 2, further comprising (C) a cationic surfactant.

[4] Furthermore, (D) a polyhydric alcohol having ¾: hydroxyl groups (r is 4 or more), fatty acids with 8 or more carbon atoms and power (2≤ s≤r—2) Claims 1 to 3 containing

V, slippery hair cosmetic according to item 1.

[5] The method according to any one of claims 1 to 4, further comprising (E) an amidoamine compound represented by the following general formula (1), and (F) a lower alcohol having 2 to 4 carbon atoms. Hair makeup.

 [Chemical 1]

R— C-N-R--N (1)

 II I

O H

(In the formula, R ¹ represents a linear or branched alkyl group having 11 to 25 carbon atoms, an alkyl group, or a hydroxyalkyl group, R ² is an alkylene group having 1 to ³ carbon atoms, and R ³ is carbon. Represents an alkyl group of the number 1 to 3.)

 [6] (A) Polyphenols, (C) Cationic surfactant, (D) s polyhydric alcohol having r hydroxyl groups (r is 4 or more) and fatty acid having 8 or more carbon atoms ( 2≤ s≤r— 2) Hair cosmetics containing partially esterified esterified products.

[7] A hair cosmetic comprising (A) a polyphenol, (E) an amidoamine compound represented by the following general formula (1), and (F) a lower alcohol having 2 to 4 carbon atoms. .

 [Chemical 2]

R— C-N-R--N (1)

II I \ R ³

 O H

(In the formula, R ¹ represents a linear or branched alkyl group having 11 to 25 carbon atoms, an alkyl group, or a hydroxyalkyl group, R ² is an alkylene group having 1 to ³ carbon atoms, and R ³ is carbon. Represents an alkyl group of the number 1 to 3.)

[8] The hair cosmetic composition according to any one of claims 1 to 7, wherein the (A) polyphenols are gallic acid or a derivative thereof.

 [9] (E) A hair cosmetic composition containing polyphenols is blended with (E) an amidoamine compound represented by the following general formula (1) and (F) a lower alcohol having 2 to 4 carbon atoms. (A) A method for suppressing coloring of hair cosmetics containing polyphenols.

 [Chemical 3]

R ¹ — C good N (1)

II I \ R ³

 O H

(In the formula, R ¹ represents a linear or branched alkyl group having 11 to 25 carbon atoms, an alkyl group, or a hydroxyalkyl group, R ² is an alkylene group having 1 to ³ carbon atoms, and R ³ is carbon. Represents an alkyl group of the number 1 to 3.)