JP4528357B1 - Color change inhibitor for oxidative hair dyes - Google Patents
Color change inhibitor for oxidative hair dyes Download PDFInfo
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- JP4528357B1 JP4528357B1 JP2009537433A JP2009537433A JP4528357B1 JP 4528357 B1 JP4528357 B1 JP 4528357B1 JP 2009537433 A JP2009537433 A JP 2009537433A JP 2009537433 A JP2009537433 A JP 2009537433A JP 4528357 B1 JP4528357 B1 JP 4528357B1
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- 239000000118 hair dye Substances 0.000 title claims abstract description 61
- 230000001590 oxidative effect Effects 0.000 title claims abstract description 43
- 239000003112 inhibitor Substances 0.000 title claims abstract description 18
- 229910052709 silver Inorganic materials 0.000 claims abstract description 45
- 239000004332 silver Substances 0.000 claims abstract description 45
- -1 silver ions Chemical class 0.000 claims abstract description 29
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000011593 sulfur Substances 0.000 claims abstract description 26
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 26
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 16
- 239000002453 shampoo Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 239000010419 fine particle Substances 0.000 claims description 8
- 239000006071 cream Substances 0.000 claims description 7
- 239000006210 lotion Substances 0.000 claims description 7
- 238000011282 treatment Methods 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 238000004043 dyeing Methods 0.000 claims description 5
- 241000195940 Bryophyta Species 0.000 claims description 3
- 239000008266 hair spray Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 235000011929 mousse Nutrition 0.000 claims description 3
- 230000001256 tonic effect Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical class NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 2
- HXKKHQJGJAFBHI-UHFFFAOYSA-N 1-aminopropan-2-ol Chemical compound CC(O)CN HXKKHQJGJAFBHI-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- 229910052946 acanthite Inorganic materials 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 229940102253 isopropanolamine Drugs 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 2
- 229940056910 silver sulfide Drugs 0.000 description 2
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 150000003463 sulfur Chemical class 0.000 description 2
- 235000015961 tonic Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 229940015975 1,2-hexanediol Drugs 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010027940 Mood altered Diseases 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000007510 mood change Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229940079877 pyrogallol Drugs 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- 239000008132 rose water Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- YPNVIBVEFVRZPJ-UHFFFAOYSA-L silver sulfate Chemical compound [Ag+].[Ag+].[O-]S([O-])(=O)=O YPNVIBVEFVRZPJ-UHFFFAOYSA-L 0.000 description 1
- 229910000367 silver sulfate Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 229960000716 tonics Drugs 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/004—Preparations used to protect coloured hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
本発明の酸化染毛剤用色調変化防止剤は、感光性染毛料で白髪染めした毛髪に残留している銀イオンを、除去すること又は不活性化するために、全量に対してイオウを０．０１〜５％含む、又は、アルカノールアミン類を１〜１５％含むことを特徴とする。
【選択図】なしThe color change inhibitor for oxidative hair dyes of the present invention removes or inactivates silver ions remaining on the hair dyed with a photosensitive hair dye, so that sulfur is reduced to 0. It contains 01 to 5% or contains 1 to 15% alkanolamines.
[Selection figure] None
Description
本発明は、銀を含む感光性染毛料で白髪染めされた毛髪を酸化染毛剤で染める際に、その色調が変化するのを防止する酸化染毛剤用色調変化防止剤に関する。 The present invention relates to a color tone change preventing agent for an oxidative hair dye, which prevents a change in color tone when dyeing white hair dyed with a photosensitive hair dye containing silver with an oxidative hair dye.
最近、実用化された硫酸銀とクエン酸を含む感光性の染毛料は、日光に当てれば３日程度で徐々に染まるもので、通常のヘアケア製品と同様に、手軽に塗っておくだけで毛髪が染毛され、刺激やアレルギーも無いことから利用する顧客が徐々に拡大する傾向にある。この感光性の染毛料は、本発明者等の開発により完成したもので、先行技術文献として特許第３８８１６８８号公報が知られている。 Photosensitive hair dyes containing silver sulfate and citric acid that have recently been put into practical use can be dyed gradually in about 3 days when exposed to sunlight. Like normal hair care products, hair can be applied simply by applying it. Since the hair is dyed and there is no irritation or allergy, the number of customers who use it tends to increase gradually. This photosensitive hair dye is completed by the development of the present inventors, and Japanese Patent No. 3881688 is known as a prior art document.
上記感光性染毛料が日光により白髪を染める原理は、ヘアクリーム等に０．５％〜１．０％含有される銀イオンが光によって金属銀の微粒子に還元され、それが毛髪に均一に付着するために毛髪がダークブラウン等に見えることにある。この原理を利用した白髪染めの感光性染毛料は、銀微粒子が毛髪表面をコーティングするかの様に覆っているので、毛髪を紫外線や薬剤から守る作用を有し、また、一旦染まると洗髪しても容易には落ちない特徴を有するものである。 The principle that the above photosensitive hair dyes gray hair by sunlight is that silver ions contained in 0.5% to 1.0% in hair cream etc. are reduced to metallic silver fine particles by light, and it adheres uniformly to the hair This is because the hair looks dark brown. Photosensitive hair dyes for white hair dyeing using this principle have the effect of protecting the hair from UV rays and chemicals as silver fine particles are coated on the hair surface. However, it has a characteristic that does not easily fall.
ところで、感光性染毛料で白髪染めした毛髪を気分転換のために色調を変えるのに酸化染毛剤で染めると、目的とする色調と異なる色や緑色等に染まることがあると指摘されている。上述したように、銀イオンを含むクリーム等を毛髪に塗り光が当たると銀イオンの１部は還元されて金属銀に変化するので、この金属銀が白髪染めの原因であるが、この後、洗髪すると金属銀は毛髪に付着したままであるが銀イオンは水溶性であるので、洗髪によって完全に洗い流されるものと一般的には考えられており、緑色等に染まる原因が長い間不明であった。 By the way, it has been pointed out that when hair dyed with photosensitive hair dye is dyed with an oxidative hair dye to change the color tone for mood change, it may be dyed in a color different from the intended color tone or green. As described above, when silver or other cream containing silver ions is applied to the hair and exposed to light, a part of the silver ions is reduced and converted to metallic silver. Then, although metallic silver remains attached to the hair, since silver ions are water-soluble, it is generally considered that the silver is completely washed away by washing the hair, and the cause of staining with green color has not been known for a long time. .
しかしながら、発明者等が鋭意研究した結果、銀イオンの１部は洗い流されてしまうが、かなりの量の銀イオンは毛髪に付着したままで洗い流されておらず毛髪に銀イオンの形で存在しているために、この残留銀イオンと酸化染毛剤の染料成分であるパラフェニレンジアミン誘導体、レゾルシン、ピロガロール等とが反応して発色することで色調の変化が起こることを見出した。そこで、酸化染毛剤で染毛する前に、毛髪に残留している上記銀イオンを取り去るか、又は、不活性化することができる物があれば色調変化が防止できることが判明した。
それ故に、本発明の課題は、感光性染毛料で白髪染めした毛髪に残留している銀イオンを、除去すること又は不活性化することで、色調が変化するのを防止する酸化染毛剤用色調変化防止剤を提供することにある。
However, as a result of intensive studies by the inventors, a part of silver ions is washed away, but a considerable amount of silver ions remain attached to the hair and are not washed away, and are present in the form of silver ions in the hair. Therefore, the present inventors have found that the color change occurs when the residual silver ions react with the paraphenylenediamine derivative, resorcin, pyrogallol and the like, which are dye components of the oxidative hair dye, to develop color. Thus, it has been found that the color change can be prevented if there is an object that can remove or inactivate the silver ions remaining on the hair before dyeing with an oxidative hair dye.
Therefore, an object of the present invention is for an oxidative hair dye that prevents a change in color tone by removing or inactivating silver ions remaining in hair dyed with a photosensitive hair dye. The object is to provide a color change preventing agent.
本発明者等は、洗髪により水溶性である銀イオンは完全に洗い流されるものと考えていたが、鋭意研究した結果、銀イオンの１部は洗い流されてしまうが、かなりの量の銀イオンは毛髪に付着したままで洗い流されておらず毛髪に銀イオンの形で存在しており、還元された金属銀の回りに銀イオンがしっかりと結合されている状態になっていることを見出して、この残留銀イオンを不活性化するか、又は取り除くことができれば酸化染毛剤による色調の変化は起こらないと仮定して、種々な還元剤（ビタミンＣ、ハイドロキノン、チオ硫酸ナトリウム等）を水溶液にして銀染色した毛髪に塗りつけたところ、ゆっくりと還元反応が起こり銀イオンを銀に還元することが分ったが、そのためには２４時間以上時間がかかることが判明したので実用的でないと判断し、その他の試薬を種々試した結果、イオウ及びアルカノールアミン類が色調の変化を防ぐことを見出し、鋭意研究して本発明を達成したものである。 The present inventors thought that the water-soluble silver ions were completely washed away by shampooing, but as a result of intensive research, a part of the silver ions were washed away, but a considerable amount of silver ions was Finding that the silver ions are firmly attached around the reduced metallic silver, being present in the form of silver ions in the hair without being washed away while attached to the hair, the residual silver ion or inactivate, or change in color tone due to the hopefully oxidizing hair dye removing assume that does not occur, the aqueous solution of various reducing agents (vitamin C, hydroquinone, thiosulfate sodium, etc.) When it was applied to silver-dyed hair, it was found that a slow reduction reaction occurred and silver ions were reduced to silver. An unsubstantial and determines, as a result of the other reagents were various tried, we found that sulfur and alkanolamines prevent the change in color tone is obtained by achieving the present invention conducted extensive research.
即ち、上記課題を解決するために、請求項１に係る発明の酸化染毛剤用色調変化防止剤は、銀イオンが光によって金属銀の微粒子に還元される感光性染毛料で処理した毛髪に酸化染毛剤の使用前に用いる酸化染毛剤用色調変化防止剤であって、その全量に対してイオウを０．０１〜５重量％含むことを特徴とする。
同様に、請求項２に係る発明の酸化染毛剤用色調変化防止剤は、銀イオンが光によって金属銀の微粒子に還元される感光性染毛料で処理した毛髪に酸化染毛剤の使用前に用いる酸化染毛剤用色調変化防止剤であって、その全量に対してアルカノールアミン類を１〜１５重量％含むことを特徴とする。
請求項３に係る発明の酸化染毛剤用色調変化防止剤は、銀イオンが光によって金属銀の微粒子に還元される感光性染毛料で処理した毛髪に酸化染毛剤の使用前に用いる酸化染毛剤用色調変化防止剤であって、その全量に対してイオウを０．０１〜５重量％、アルカノールアミン類を１〜１５重量％含むことを特徴とする。
請求項４に係る発明の酸化染毛剤用色調変化防止剤は、水溶液、ヘアローション、ヘアゲル、シャンプー、リンス、トリートメント、ヘアトニック、ヘアリキッド、ヘアクリーム、ヘアムース、又は、ヘアスプレーに用いることを特徴とする。
That is, in order to solve the above-mentioned problems, the color tone change preventing agent for oxidative hair dye of the invention according to claim 1 is applied to hair treated with a photosensitive hair dye in which silver ions are reduced to metal silver fine particles by light. It is a color tone change preventing agent for oxidative hair dye used before use of oxidative hair dye, characterized by containing 0.01 to 5% by weight of sulfur with respect to the total amount thereof.
Similarly, the color tone change preventing agent for oxidative hair dye of the invention according to claim 2 is used before the oxidative hair dye is used on hair treated with a photosensitive hair dye in which silver ions are reduced to metal silver fine particles by light. It is a color tone change inhibitor for oxidative hair dyes used in the above, characterized in that it contains 1 to 15% by weight of alkanolamines based on the total amount.
The color change inhibitor for oxidative hair dye of the invention according to claim 3 is an oxidation used before use of oxidative hair dye on hair treated with a photosensitive hair dye in which silver ions are reduced to fine particles of metallic silver by light. It is a color tone change preventing agent for hair dyes, characterized by containing 0.01 to 5% by weight of sulfur and 1 to 15% by weight of alkanolamines based on the total amount.
The color change inhibitor for oxidative hair dye of the invention according to claim 4 is used for an aqueous solution, hair lotion, hair gel, shampoo, rinse, treatment, hair tonic, hair liquid, hair cream, hair mousse or hair spray. Features.
本発明の酸化染毛剤用色調変化防止剤のイオウは、毛髪に残留している銀イオンを硫化銀に変えることで、酸化染毛剤で毛髪を染めても緑色にはならず目的とする色調が得られ、また、上記酸化染毛剤用色調変化防止剤のアルカノールアミン類は、毛髪に残留している銀イオンを溶解して除去することで、酸化染毛剤で毛髪を染めても色調が異なるものとはならず、目的とする色調が得られた。
本発明の酸化染毛剤用色調変化防止剤は、水溶液、ヘアローション、ヘアゲル、シャンプー、リンス、トリートメント、ヘアトニック、ヘアリキッド、ヘアクリーム、ヘアムース、又は、ヘアスプレーに用いることができ、利便性が大きい。
The sulfur of the color tone change inhibitor for oxidative hair dyes of the present invention is intended to change the silver ions remaining on the hair to silver sulfide, so that the hair does not become green even if the hair is dyed with the oxidative hair dye. The color tone is obtained, and the alkanolamines of the color tone change inhibitor for oxidative hair dyes can dissolve and remove silver ions remaining in the hair, so that even if the hair is dyed with an oxidative hair dye, The target color tone was not obtained because the color tone was not different.
The color change inhibitor for oxidative hair dyes of the present invention can be used in aqueous solutions, hair lotions, hair gels, shampoos, rinses, treatments, hair tonics, hair liquids, hair creams, hair mousses, or hair sprays. Is big.
酸化染毛剤用色調変化防止剤のイオウは、残留銀イオン及び銀と速やかに反応して硫化銀に変わり、この硫化銀は極めて安定で酸化染毛剤の色素成分とは反応しないこと、また、酸化染毛剤用色調変化防止剤のモノエタノールアミンやイソプロパノールアミン等のアルカノールアミン類は、銀イオンを溶解し、除去することで色調変化を防ぐことができる。これらのイオウとアルカノールアミン類は水溶液、シャンプー、リンス、トリートメント、ヘアコンディショナー、その他の洗髪料に含ませることができ、これらの洗髪料を酸化染毛剤で染める前に使用することで、色調の変化を防ぐことができる。イオウ、アルカノールアミン類を単独で用いても良いし、両者を一緒に用いても良い。 Sulfur, a color change inhibitor for oxidative hair dyes, reacts quickly with residual silver ions and silver to turn into silver sulfide, which is extremely stable and does not react with the dye components of oxidative hair dyes. The alkanolamines such as monoethanolamine and isopropanolamine, which are color tone change inhibitors for oxidative hair dyes, can prevent color tone change by dissolving and removing silver ions. These sulfur and alkanolamines can be included in aqueous solutions, shampoos, rinses, treatments, hair conditioners, and other shampoos . By using these shampoos before dyeing with oxidative hair dyes, Change can be prevented. Sulfur and alkanolamines may be used alone, or both may be used together.
上記イオウの配合割合は酸化染毛剤用色調変化防止剤の全量に対して０．０１〜５％含み、また、上記アルカノールアミン類の配合割合は酸化染毛剤用色調変化防止剤の全量に対して１〜１５％含むことで色調の変化を防ぐことができる。そして、イオウとアルカノールアミン類を配合した場合には、イオウとアルカノールアミン類の配合割合は酸化染毛剤用色調変化防止剤の全量に対して、イオウを０．０１〜５％、アルカノールアミン類を１〜１５％含むことで色調の変化を防ぐことができる。 The blending ratio of the sulfur is 0.01 to 5% with respect to the total amount of the color change inhibitor for oxidative hair dye, and the blending ratio of the alkanolamines is based on the total amount of the color change inhibitor for the oxidative hair dye. On the other hand, a change in color tone can be prevented by including 1 to 15%. When sulfur and alkanolamines are blended, the blending ratio of sulfur and alkanolamines is 0.01 to 5% of sulfur and alkanolamines with respect to the total amount of the color change inhibitor for oxidative hair dyes. By including 1 to 15%, change in color tone can be prevented.
イオウの配合割合を全量に対して０．０１〜５％の範囲としたのは、以下に述べる実験により決定した。濃度を変えたイオウ液を数種作り、感光性ヘアクリームで染色した毛髪をこれで洗い、洗浄後、乾燥させた毛髪にパラフェニレンジアミンを含む染毛クリームを直接塗る。銀イオンが存在すると青〜紫色に直ちに変色するが、銀イオンが存在しないと色の変化は無い。この実験により変色を起こさない最小のイオウ濃度は０．０１％であることが判明した。イオウ濃度が５％以上になると臭いがきつくなり実用性が低くなるので、イオウの配合割合は全量に対して０．０１〜５％の範囲が適切である。同様に、アルカノールアミン類の配合割合を全量に対して１〜１５％の範囲としたのは、上記の同じ実験を行い決定した。アルカノールアミン類濃度が１５％以上になると皮膚への刺激が強くなり実用性が低くなるので、アルカノールアミン類の配合割合は全量に対して１〜１５％の範囲が適切である。 The ratio of sulfur to 0.01% to 5% of the total amount was determined by the experiment described below. Several kinds of sulfur solutions with different concentrations are prepared, and the hair dyed with the photosensitive hair cream is washed with this, and after washing, a hair dye cream containing paraphenylenediamine is directly applied to the dried hair. If silver ions are present, the color immediately changes from blue to purple, but if no silver ions are present, there is no color change. This experiment revealed that the minimum sulfur concentration that would not cause discoloration was 0.01%. When the sulfur concentration is 5% or more, the odor becomes stiff and the practicality is lowered, so the mixing ratio of sulfur is suitably in the range of 0.01 to 5% with respect to the total amount. Similarly, it was determined by performing the same experiment as described above that the blending ratio of the alkanolamines was in the range of 1 to 15% with respect to the total amount. When the concentration of alkanolamines is 15% or more, irritation to the skin becomes strong and the practicality becomes low.
（実施例１）
１０ｋｇステンレス容器に沈降イオウ０．１２ｋｇ、粉末状酸化カルシウム０．１２ｋｇ、精製水０．９ｋｇを取り９０℃以上で３時間加熱しイオウを溶解する。冷却後、イオウ溶液を濾過し、これにグリセリン７．７７ｋｇ、脂肪酸グルコースエーテル１ｋｇ及び香料０．０９ｋｇを加え、水を調整して１０ｋｇにする。ｐＨ１１の黄色のイオウローションが得られる。このイオウローション５ｍｌを市販のシャンプーに混ぜて、感光性染毛料で白髪染めした毛髪を洗い、市販のリンスでよくすすぐ。その後、酸化染毛剤で毛髪を染めても緑色にはならず、目的とする色調が得られた。
Example 1
In a 10 kg stainless steel container, 0.12 kg of precipitated sulfur, 0.12 kg of powdered calcium oxide and 0.9 kg of purified water are taken and heated at 90 ° C. or more for 3 hours to dissolve sulfur. After cooling, the sulfur solution is filtered, and 7.77 kg of glycerin, 1 kg of fatty acid glucose ether and 0.09 kg of fragrance are added thereto, and water is adjusted to 10 kg. A yellow sulfur lotion of pH 11 is obtained. Mix 5 ml of this sulfur lotion with a commercial shampoo, wash the hair dyed with photosensitive hair dye, and rinse well with a commercial rinse. Thereafter, even if the hair was dyed with an oxidative hair dye, it did not turn green and the intended color tone was obtained.
（実施例２）
１００ｋｇのミキシングタンクに精製水７２．０５ｋｇ、トリメチルグリシン０．０５ｋｇ、濃グリセリン２．０ｋｇ、塩化ステアリルトリメチルアンモニウム０．４ｋｇ、エタノール１０．０ｋｇ、モノエタノールアミン１０．０ｋｇ、ローズウォーター５．０ｋｇ、フェノキシエタノール０．５ｋｇを入れ、４５℃で３０分間撹拌し、透明なトリートメントローション９９．５ｋｇを得た。感光性染毛料で白髪染めを行った染毛に、このトリートメントローションをスプレーし、３分間放置した後シャンプーした。その後、酸化染毛剤で染色しても、緑に変色する事は無かった。
(Example 2)
Purified water 72.05 kg, trimethylglycine 0.05 kg, concentrated glycerin 2.0 kg, stearyltrimethylammonium chloride 0.4 kg, ethanol 10.0 kg, monoethanolamine 10.0 kg, rose water 5.0 kg, phenoxyethanol in a 100 kg mixing tank 0.5 kg was added and stirred at 45 ° C. for 30 minutes to obtain 99.5 kg of a transparent treatment lotion. This treatment lotion was sprayed on the hair dyed with gray hair with a photosensitive hair dye, allowed to stand for 3 minutes and then shampooed. After that, even when dyed with an oxidative hair dye, it did not turn green.
（実施例３）
１００ｋｇのミキシングタンクに脂肪酸グルコースエーテル７０ｋｇ、ポリエチレングリコール・シリコンオイル誘導体５ｋｇ、精製水１８．８ｋｇ、１，２ヘキサンジオール１．０ｋｇを取り６０℃で撹拌し、均一溶解する（Ａ相）。別の容器にイソプロパノールアミン３．０ｋｇ、沈降イオウ０．２ｋｇを取り６０℃で３０分間撹拌し、イオウを溶解させる（Ｂ相）。Ａ相にＢ相及び香料２ｋｇを加えｐＨ９．５のイオウシャンプーを得る。感光性染毛料で白髪染めした毛髪をこのイオウシャンプーで洗い、その後、酸化染毛剤で染色しても色調に異常は現れず、目的とする色調が得られた。
(Example 3)
100kg mixing tank fatty glucose ether 70 kg, polyethylene glycol silicon oil derivatives 5 kg, purified water 18.8 kg, was stirred at 60 ° C. takes 1,2-hexanediol 1.0 kg, uniformly dissolved (A phase). Another vessel isopropanolamine 3.0 kg, and 30 minutes stirred at 60 ° C. takes precipitated sulfur 0.2 kg, dissolved sulfur (B phase). Add Phase B and 2 kg of fragrance to Phase A to obtain a pH 9.5 sulfur shampoo. Even if the hair dyed with a photosensitive hair dye was washed with this sulfur shampoo and then dyed with an oxidative hair dye, the color tone did not appear abnormal, and the desired color tone was obtained.
Claims (4)
その全量に対してイオウを０．０１〜５重量％含むことを特徴とする酸化染毛剤用色調変化防止剤。A color change inhibitor for oxidative hair dye used before the use of oxidative hair dye on hair treated with a photosensitive hair dye in which silver ions are reduced to metallic silver fine particles by light,
A color change inhibitor for oxidative hair dyes, characterized in that it contains 0.01 to 5% by weight of sulfur with respect to the total amount.
その全量に対してアルカノールアミン類を１〜１５重量％含むことを特徴とする酸化染毛剤用色調変化防止剤。A color change inhibitor for oxidative hair dye used before the use of oxidative hair dye on hair treated with a photosensitive hair dye in which silver ions are reduced to metallic silver fine particles by light,
An agent for preventing a change in color tone for an oxidative hair dye, comprising 1 to 15% by weight of an alkanolamine based on the total amount of the alkanolamine.
その全量に対してイオウを０．０１〜５重量％、アルカノールアミン類を１〜１５重量％含むことを特徴とする酸化染毛剤用色調変化防止剤。A color change inhibitor for oxidative hair dye used before the use of oxidative hair dye on hair treated with a photosensitive hair dye in which silver ions are reduced to metallic silver fine particles by light,
0.01 to 5 wt% of sulfur relative to its total amount, oxidizing hair dye for color change preventing agent characterized by containing alkanolamines 1-15 wt%.
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