WO2010137105A1 - Color tone change inhibitor for oxidative hair dye - Google Patents
Color tone change inhibitor for oxidative hair dye Download PDFInfo
- Publication number
- WO2010137105A1 WO2010137105A1 PCT/JP2009/059525 JP2009059525W WO2010137105A1 WO 2010137105 A1 WO2010137105 A1 WO 2010137105A1 JP 2009059525 W JP2009059525 W JP 2009059525W WO 2010137105 A1 WO2010137105 A1 WO 2010137105A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hair
- color tone
- sulfur
- oxidative
- oxidative hair
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/004—Preparations used to protect coloured hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/23—Sulfur; Selenium; Tellurium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
Definitions
- the present invention relates to a color tone change preventing agent for oxidative hair dyes, which prevents the color tone from changing when dyeing white hair dyed with a photosensitive hair dye containing silver with an oxidative hair dye. .
- Photosensitive hair dyes containing silver sulfate and citric acid that have recently been put into practical use are dyed gradually in about 3 days when exposed to sunlight, and as with normal hair care products, hair can be applied simply by applying it. Since the hair is dyed and there is no irritation or allergies, the number of customers who use it tends to increase gradually.
- This photosensitive hair dye is completed by the development of the present inventors, and Japanese Patent No. 3881688 is known as a prior art document.
- photosensitive hair dyes white hair by sunlight is that the silver ions contained in 0.5% to 1.0% in hair cream etc. are reduced to fine metal silver particles by light, and it adheres evenly to the hair This is because the hair looks dark brown.
- Photosensitive hair dyes for white hair dyeing using this principle have the effect of protecting the hair from UV rays and chemicals as silver fine particles are coated on the hair surface. However, it has a characteristic that does not easily fall.
- hair dyed with photosensitive hair dye is dyed with an oxidative hair dye to change the color tone for mood change, it may be dyed in a color different from the intended color tone or green.
- a part of the silver ions is reduced and converted to metallic silver.
- metallic silver remains attached to the hair, since silver ions are water-soluble, it is generally considered that the silver is completely washed away by washing the hair, and the cause of staining with green color has not been known for a long time. .
- an object of the present invention is for an oxidative hair dye that prevents a change in color tone by removing or inactivating silver ions remaining in hair dyed with a photosensitive hair dye. The object is to provide a color change preventing agent.
- the present inventors thought that the water-soluble silver ions were completely washed away by shampooing, but as a result of intensive research, a part of the silver ions were washed away, but a considerable amount of silver ions was It is found that the silver ions are firmly bound around the reduced metallic silver, being present in the form of silver ions in the hair, not being washed away while attached to the hair, If this residual silver ion can be inactivated or removed, it is assumed that there will be no change in color due to oxidative hair dye, and various reducing agents (vitamin C, hydroquinone, sodium thiosulfate, etc.) are made into aqueous solutions.
- the color tone change preventing agent for oxidative hair dye according to claim 1 is characterized by containing 0.01 to 5% of sulfur with respect to the total amount.
- the color tone change inhibitor for oxidative hair dyes according to claim 2 is characterized by containing 1 to 15% of alkanolamines based on the total amount.
- the color change inhibitor for oxidative hair dyes according to claim 3 is characterized by containing 0.01 to 5% sulfur and 1 to 15% alkanolamines based on the total amount.
- the color change inhibitor for oxidative hair dyes according to claim 4 is used for an aqueous solution, a hair lotion, a hair gel, a shampoo, a rinse, a treatment, a hair tonic, a hair liquid, a hair cream, a hair mousse, or a hair spray. To do.
- the sulfur of the color tone change inhibitor for oxidative hair dyes of the present invention is intended to change the silver ions remaining on the hair to silver sulfide, so that the hair does not become green even if the hair is dyed with the oxidative hair dye.
- the color tone is obtained, and the alkanolamines of the color tone change inhibitor for oxidative hair dyes can dissolve and remove silver ions remaining in the hair, so that even if the hair is dyed with an oxidative hair dye, The target color tone was not obtained because the color tone was not different.
- the color change inhibitor for oxidative hair dyes of the present invention can be used in aqueous solutions, hair lotions, hair gels, shampoos, rinses, treatments, hair tonics, hair liquids, hair creams, hair mousses, or hair sprays. Is big.
- Sulfur a color change inhibitor for oxidative hair dyes, reacts quickly with residual silver ions and silver to turn into silver sulfide, which is extremely stable and does not react with the dye components of oxidative hair dyes.
- the alkanolamines such as monoethanolamine and isopropanolamine, which are color tone change inhibitors for oxidative hair dyes, can prevent color tone change by dissolving and removing silver ions.
- These sulfur and alkanolamines can be included in aqueous solutions, shampoos, rinses, treatments, hair conditioners, and other hair styling products. Change can be prevented. Sulfur and alkanolamines may be used alone, or both may be used together.
- the sulfur content is 0.01 to 5% with respect to the total amount of the color change inhibitor for oxidative hair dyes
- the alkanolamine content is equal to the total amount of color change inhibitor for the oxidative hair dye.
- the change in color tone can be prevented by including 1 to 15%.
- the blending ratio of sulfur and alkanolamines is 0.01 to 5% sulfur and alkanolamines with respect to the total amount of the color change inhibitor for oxidative hair dyes. Including 1 to 15% of the color tone can prevent changes in color tone.
- the sulfur content was determined to be in the range of 0.01 to 5% of the total amount by the experiment described below.
- Several kinds of sulfur solutions with different concentrations are prepared, and the hair dyed with the photosensitive hair cream is washed with this, and after washing, a hair dye cream containing paraphenylenediamine is directly applied to the dried hair.
- silver ions When silver ions are present, the color changes immediately from blue to purple, but without silver ions, there is no change in color.
- the blending ratio of alkanolamines was determined to be in the range of 1 to 15% with respect to the total amount, and was determined by performing the same experiment described above.
- the alkanolamine concentration is 15% or more, the skin irritation becomes strong and the practicality becomes low, so the blending ratio of alkanolamines is appropriately in the range of 1 to 15% with respect to the total amount.
- Example 1 In a 10 kg stainless steel container, 0.12 kg of precipitated sulfur, 0.12 kg of powdered calcium oxide and 0.9 kg of purified water are taken and heated at 90 ° C. or more for 3 hours to dissolve sulfur. After cooling, the sulfur solution is filtered, and 7.77 kg of glycerin, 1 kg of fatty acid glucose ether and 0.09 kg of fragrance are added thereto, and water is adjusted to 10 kg. A yellow sulfur lotion of PH11 is obtained. Mix 5 ml of this sulfur lotion with a commercial shampoo, wash the hair dyed with photosensitive hair dye, and rinse well with a commercial rinse. Thereafter, even if the hair was dyed with an oxidative hair dye, it did not turn green and the intended color tone was obtained.
- Example 2 Purified water 72.05 kg, trimethylglycine 0.05 kg, concentrated glycerin 2.0 kg, stearyltrimethylammonium chloride 0.4 kg, ethanol 10.0 kg, monoethanolamine 10.0 kg, rose water 5.0 kg, phenoxyethanol in a 100 kg mixing tank 0.5 kg was added and stirred at 45 ° C. for 30 minutes to obtain 99.5 kg of a transparent treatment lotion.
- This treatment lotion was sprayed on the hair dyed with gray hair with a photosensitive hair dye, allowed to stand for 3 minutes and then shampooed. After that, even when dyed with an oxidative hair dye, it did not turn green.
- Example 3 In a 100 kg mixing tank, 70 kg of fatty acid glucose ether, 5 kg of polyethylene glycol / silicon oil derivative, 18.8 kg of purified water and 1.0 kg of 1,2 hexanediol are stirred and stirred at 60 ° C. to uniformly dissolve (phase A). In another container, take 3.0 kg of isopropanolamine and 0.2 kg of precipitated sulfur and stir at 60 ° C. for 30 minutes to dissolve the sulfur (phase B). Add Phase B and 2 kg of fragrance to Phase A to obtain a PH 9.5 sulfur shampoo. Even if the hair dyed with a photosensitive hair dye was washed with this sulfur shampoo and then dyed with an oxidative hair dye, the color tone did not appear abnormal, and the desired color tone was obtained.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Disclosed is a color tone change inhibitor for oxidative hair dyes, which is characterized by containing 0.01-5% of sulfur or 1-15% of an alkanolamine relative to the total amount of the inhibitor for the purpose of removing or deactivating silver ions remaining in grey hair dyed with a photosensitive hair dye.
Description
本発明は、銀を含む感光性染毛料で白髪染めされた毛髪を酸化染毛剤で染める際に、その色調が変化するのを防止する酸化染毛剤用色調変化防止剤に関する。
The present invention relates to a color tone change preventing agent for oxidative hair dyes, which prevents the color tone from changing when dyeing white hair dyed with a photosensitive hair dye containing silver with an oxidative hair dye. .
最近、実用化された硫酸銀とクエン酸を含む感光性の染毛料は、日光に当てれば３日程度で徐々に染まるもので、通常のヘアケア製品と同様に、手軽に塗っておくだけで毛髪が染毛され、刺激やアレルギーも無いことから利用する顧客が徐々に拡大する傾向にある。この感光性の染毛料は、本発明者等の開発により完成したもので、先行技術文献として特許第３８８１６８８号公報が知られている。
Photosensitive hair dyes containing silver sulfate and citric acid that have recently been put into practical use are dyed gradually in about 3 days when exposed to sunlight, and as with normal hair care products, hair can be applied simply by applying it. Since the hair is dyed and there is no irritation or allergies, the number of customers who use it tends to increase gradually. This photosensitive hair dye is completed by the development of the present inventors, and Japanese Patent No. 3881688 is known as a prior art document.
上記感光性染毛料が日光により白髪を染める原理は、ヘアクリーム等に０．５％～１．０％含有される銀イオンが光によって金属銀の微粒子に還元され、それが毛髪に均一に付着するために毛髪がダークブラウン等に見えることにある。この原理を利用した白髪染めの感光性染毛料は、銀微粒子が毛髪表面をコーティングするかの様に覆っているので、毛髪を紫外線や薬剤から守る作用を有し、また、一旦染まると洗髪しても容易には落ちない特徴を有するものである。
The principle that the above-mentioned photosensitive hair dyes white hair by sunlight is that the silver ions contained in 0.5% to 1.0% in hair cream etc. are reduced to fine metal silver particles by light, and it adheres evenly to the hair This is because the hair looks dark brown. Photosensitive hair dyes for white hair dyeing using this principle have the effect of protecting the hair from UV rays and chemicals as silver fine particles are coated on the hair surface. However, it has a characteristic that does not easily fall.
ところで、感光性染毛料で白髪染めした毛髪を気分転換のために色調を変えるのに酸化染毛剤で染めると、目的とする色調と異なる色や緑色等に染まることがあると指摘されている。上述したように、銀イオンを含むクリーム等を毛髪に塗り光が当たると銀イオンの１部は還元されて金属銀に変化するので、この金属銀が白髪染めの原因であるが、この後、洗髪すると金属銀は毛髪に付着したままであるが銀イオンは水溶性であるので、洗髪によって完全に洗い流されるものと一般的には考えられており、緑色等に染まる原因が長い間不明であった。
By the way, it has been pointed out that if hair dyed with photosensitive hair dye is dyed with an oxidative hair dye to change the color tone for mood change, it may be dyed in a color different from the intended color tone or green. As described above, when silver or other cream containing silver ions is applied to the hair and exposed to light, a part of the silver ions is reduced and converted to metallic silver. Then, although metallic silver remains attached to the hair, since silver ions are water-soluble, it is generally considered that the silver is completely washed away by washing the hair, and the cause of staining with green color has not been known for a long time. .
しかしながら、発明者等が鋭意研究した結果、銀イオンの１部は洗い流されてしまうが、かなりの量の銀イオンは毛髪に付着したままで洗い流されておらず毛髪に銀イオンの形で存在しているために、この残留銀イオンと酸化染毛剤の染料成分であるパラフェニレンジアミン誘導体、レゾルシン、ピロガロール等とが反応して発色することで色調の変化が起こることを見出した。そこで、酸化染毛剤で染毛する前に、毛髪に残留している上記銀イオンを取り去るか、又は、不活性化することができる物があれば色調変化が防止できることが判明した。
それ故に、本発明の課題は、感光性染毛料で白髪染めした毛髪に残留している銀イオンを、除去すること又は不活性化することで、色調が変化するのを防止する酸化染毛剤用色調変化防止剤を提供することにある。 However, as a result of intensive studies by the inventors, a part of silver ions is washed away, but a considerable amount of silver ions remain attached to the hair and are not washed away, and are present in the form of silver ions in the hair. Therefore, the present inventors have found that the color change occurs when the residual silver ions react with the paraphenylenediamine derivative, resorcin, pyrogallol and the like, which are dye components of the oxidative hair dye, to develop color. Thus, it has been found that the color change can be prevented if there is an object that can remove or inactivate the silver ions remaining on the hair before dyeing with an oxidative hair dye.
Therefore, an object of the present invention is for an oxidative hair dye that prevents a change in color tone by removing or inactivating silver ions remaining in hair dyed with a photosensitive hair dye. The object is to provide a color change preventing agent.
それ故に、本発明の課題は、感光性染毛料で白髪染めした毛髪に残留している銀イオンを、除去すること又は不活性化することで、色調が変化するのを防止する酸化染毛剤用色調変化防止剤を提供することにある。 However, as a result of intensive studies by the inventors, a part of silver ions is washed away, but a considerable amount of silver ions remain attached to the hair and are not washed away, and are present in the form of silver ions in the hair. Therefore, the present inventors have found that the color change occurs when the residual silver ions react with the paraphenylenediamine derivative, resorcin, pyrogallol and the like, which are dye components of the oxidative hair dye, to develop color. Thus, it has been found that the color change can be prevented if there is an object that can remove or inactivate the silver ions remaining on the hair before dyeing with an oxidative hair dye.
Therefore, an object of the present invention is for an oxidative hair dye that prevents a change in color tone by removing or inactivating silver ions remaining in hair dyed with a photosensitive hair dye. The object is to provide a color change preventing agent.
本発明者等は、洗髪により水溶性である銀イオンは完全に洗い流されるものと考えていたが、鋭意研究した結果、銀イオンの１部は洗い流されてしまうが、かなりの量の銀イオンは毛髪に付着したままで洗い流されておらず毛髪に銀イオンの形で存在しており、還元された金属銀の回りに銀イオンがしっかりと結合されている状態になっていることを見出して、この残留銀イオンを不活性化するか、又は取り除くことができれば酸化染毛剤による色調の変化は起こらないと仮定して、種々な還元剤（ビタミンＣ、ハイドロキノン、チオ硫酸ナトリウ等）を水溶液にして銀染色した毛髪に塗りつけたところ、ゆっくりと還元反応が起こり銀イオンを銀に還元することが分ったが、そのためには２４時間以上時間がかかることが判明したので実用的でないと判断し、その他の試薬を種々試した結果、イオウ及びアルカノールアミン類が色調の変化を防ぐことを見出し、鋭意研究して本発明を達成したものである。
The present inventors thought that the water-soluble silver ions were completely washed away by shampooing, but as a result of intensive research, a part of the silver ions were washed away, but a considerable amount of silver ions was It is found that the silver ions are firmly bound around the reduced metallic silver, being present in the form of silver ions in the hair, not being washed away while attached to the hair, If this residual silver ion can be inactivated or removed, it is assumed that there will be no change in color due to oxidative hair dye, and various reducing agents (vitamin C, hydroquinone, sodium thiosulfate, etc.) are made into aqueous solutions. When applied to silver-dyed hair, it was found that a slow reduction reaction occurred and silver ions were reduced to silver. An unsubstantial and determines, as a result of the other reagents were various tried, we found that sulfur and alkanolamines prevent the change in color tone is obtained by achieving the present invention conducted extensive research.
即ち、上記課題を解決するために、請求項１に係る酸化染毛剤用色調変化防止剤は、全量に対してイオウを０．０１～５％含むことを特徴とする。同様に、請求項２に係る酸化染毛剤用色調変化防止剤は、全量に対してアルカノールアミン類を１～１５％含むことを特徴とする。請求項３に係る酸化染毛剤用色調変化防止剤は、全量に対してイオウを０．０１～５％、アルカノールアミン類を１～１５％含むことを特徴とする。請求項４に係る酸化染毛剤用色調変化防止剤は、水溶液、ヘアローション、ヘアゲル、シャンプー、リンス、トリートメント、ヘアトニック、ヘアリキッド、ヘアクリーム、ヘアムース、又は、ヘアスプレーに用いることを特徴とする。
That is, in order to solve the above-mentioned problems, the color tone change preventing agent for oxidative hair dye according to claim 1 is characterized by containing 0.01 to 5% of sulfur with respect to the total amount. Similarly, the color tone change inhibitor for oxidative hair dyes according to claim 2 is characterized by containing 1 to 15% of alkanolamines based on the total amount. The color change inhibitor for oxidative hair dyes according to claim 3 is characterized by containing 0.01 to 5% sulfur and 1 to 15% alkanolamines based on the total amount. The color change inhibitor for oxidative hair dyes according to claim 4 is used for an aqueous solution, a hair lotion, a hair gel, a shampoo, a rinse, a treatment, a hair tonic, a hair liquid, a hair cream, a hair mousse, or a hair spray. To do.
本発明の酸化染毛剤用色調変化防止剤のイオウは、毛髪に残留している銀イオンを硫化銀に変えることで、酸化染毛剤で毛髪を染めても緑色にはならず目的とする色調が得られ、また、上記酸化染毛剤用色調変化防止剤のアルカノールアミン類は、毛髪に残留している銀イオンを溶解して除去することで、酸化染毛剤で毛髪を染めても色調が異なるものとはならず、目的とする色調が得られた。
本発明の酸化染毛剤用色調変化防止剤は、水溶液、ヘアローション、ヘアゲル、シャンプー、リンス、トリートメント、ヘアトニック、ヘアリキッド、ヘアクリーム、ヘアムース、又は、ヘアスプレーに用いることができ、利便性が大きい。 The sulfur of the color tone change inhibitor for oxidative hair dyes of the present invention is intended to change the silver ions remaining on the hair to silver sulfide, so that the hair does not become green even if the hair is dyed with the oxidative hair dye. The color tone is obtained, and the alkanolamines of the color tone change inhibitor for oxidative hair dyes can dissolve and remove silver ions remaining in the hair, so that even if the hair is dyed with an oxidative hair dye, The target color tone was not obtained because the color tone was not different.
The color change inhibitor for oxidative hair dyes of the present invention can be used in aqueous solutions, hair lotions, hair gels, shampoos, rinses, treatments, hair tonics, hair liquids, hair creams, hair mousses, or hair sprays. Is big.
本発明の酸化染毛剤用色調変化防止剤は、水溶液、ヘアローション、ヘアゲル、シャンプー、リンス、トリートメント、ヘアトニック、ヘアリキッド、ヘアクリーム、ヘアムース、又は、ヘアスプレーに用いることができ、利便性が大きい。 The sulfur of the color tone change inhibitor for oxidative hair dyes of the present invention is intended to change the silver ions remaining on the hair to silver sulfide, so that the hair does not become green even if the hair is dyed with the oxidative hair dye. The color tone is obtained, and the alkanolamines of the color tone change inhibitor for oxidative hair dyes can dissolve and remove silver ions remaining in the hair, so that even if the hair is dyed with an oxidative hair dye, The target color tone was not obtained because the color tone was not different.
The color change inhibitor for oxidative hair dyes of the present invention can be used in aqueous solutions, hair lotions, hair gels, shampoos, rinses, treatments, hair tonics, hair liquids, hair creams, hair mousses, or hair sprays. Is big.
酸化染毛剤用色調変化防止剤のイオウは、残留銀イオン及び銀と速やかに反応して硫化銀に変わり、この硫化銀は極めて安定で酸化染毛剤の色素成分とは反応しないこと、また、酸化染毛剤用色調変化防止剤のモノエタノールアミンやイソプロパノールアミン等のアルカノールアミン類は、銀イオンを溶解し、除去することで色調変化を防ぐことができる。これらのイオウとアルカノールアミン類は水溶液、シャンプー、リンス、トリートメント、ヘアコンディショナー、その他の整髪料に含ませることができ、これらの洗髪料を酸化染毛剤で染める前に使用することで、色調の変化を防ぐことができる。イオウ、アルカノールアミン類を単独で用いても良いし、両者を一緒に用いても良い。
Sulfur, a color change inhibitor for oxidative hair dyes, reacts quickly with residual silver ions and silver to turn into silver sulfide, which is extremely stable and does not react with the dye components of oxidative hair dyes. The alkanolamines such as monoethanolamine and isopropanolamine, which are color tone change inhibitors for oxidative hair dyes, can prevent color tone change by dissolving and removing silver ions. These sulfur and alkanolamines can be included in aqueous solutions, shampoos, rinses, treatments, hair conditioners, and other hair styling products. Change can be prevented. Sulfur and alkanolamines may be used alone, or both may be used together.
上記イオウの配合割合は酸化染毛剤用色調変化防止剤の全量に対して０．０１～５％含み、また、上記アルカノールアミン類の配合割合は酸化染毛剤用色調変化防止剤の全量に対して１～１５％含むことで色調の変化を防ぐことができる。そして、イオウとアルカノールアミン類を配合した場合には、イオウとアルカノールアミン類の配合割合は酸化染毛剤用色調変化防止剤の全量に対して、イオウを０．０１～５％、アルカノールアミン類を１～１５％含むことで色調の変化を防ぐことができる。
The sulfur content is 0.01 to 5% with respect to the total amount of the color change inhibitor for oxidative hair dyes, and the alkanolamine content is equal to the total amount of color change inhibitor for the oxidative hair dye. On the other hand, the change in color tone can be prevented by including 1 to 15%. When sulfur and alkanolamines are blended, the blending ratio of sulfur and alkanolamines is 0.01 to 5% sulfur and alkanolamines with respect to the total amount of the color change inhibitor for oxidative hair dyes. Including 1 to 15% of the color tone can prevent changes in color tone.
イオウの配合割合を全量に対して０．０１～５％の範囲としたのは、以下に述べる実験により決定した。濃度を変えたイオウ液を数種作り、感光性ヘアクリームで染色した毛髪をこれで洗い、洗浄後、乾燥させた毛髪にパラフェニレンジアミンを含む染毛クリームを直接塗る。銀イオンが存在すると青～紫色に直ちに変色するが、銀イオンが存在しないと色の変化は無い。この実験により変色を起こさない最小のイオウ濃度は０．０１％であることが判明した。イオウ濃度が５％以上になると臭いがきつくなり実用性が低くなるので、イオウの配合割合は全量に対して０．０１～５％の範囲が適切である。同様に、アルカノールアミン類の配合割合を全量に対して１～１５％の範囲としたのは、上記の同じ実験を行い決定した。アルカノールアミン類濃度が１５％以上になると皮膚への刺激が強くなり実用性が低くなるので、アルカノールアミン類の配合割合は全量に対して１～１５％の範囲が適切である。
The sulfur content was determined to be in the range of 0.01 to 5% of the total amount by the experiment described below. Several kinds of sulfur solutions with different concentrations are prepared, and the hair dyed with the photosensitive hair cream is washed with this, and after washing, a hair dye cream containing paraphenylenediamine is directly applied to the dried hair. When silver ions are present, the color changes immediately from blue to purple, but without silver ions, there is no change in color. This experiment revealed that the minimum sulfur concentration that would not cause discoloration was 0.01%. If the sulfur concentration is 5% or more, the odor becomes stiff and the practicality is lowered, so the sulfur content is suitably in the range of 0.01 to 5% with respect to the total amount. Similarly, the blending ratio of alkanolamines was determined to be in the range of 1 to 15% with respect to the total amount, and was determined by performing the same experiment described above. When the alkanolamine concentration is 15% or more, the skin irritation becomes strong and the practicality becomes low, so the blending ratio of alkanolamines is appropriately in the range of 1 to 15% with respect to the total amount.
（実施例１）
１０ｋｇステンレス容器に沈降イオウ０．１２ｋｇ、粉末状酸化カルシウム０．１２ｋｇ、精製水０．９ｋｇを取り９０℃以上で３時間加熱しイオウを溶解する。冷却後、イオウ溶液を濾過し、これにグリセリン７．７７ｋｇ、脂肪酸グルコースエーテル１ｋｇ及び香料０．０９ｋｇを加え、水を調整して１０ｋｇにする。ＰＨ１１の黄色のイオウローションが得られる。このイオウローション５ｍｌを市販のシャンプーに混ぜて、感光性染毛料で白髪染めした毛髪を洗い、市販のリンスでよくすすぐ。その後、酸化染毛剤で毛髪を染めても緑色にはならず、目的とする色調が得られた。 Example 1
In a 10 kg stainless steel container, 0.12 kg of precipitated sulfur, 0.12 kg of powdered calcium oxide and 0.9 kg of purified water are taken and heated at 90 ° C. or more for 3 hours to dissolve sulfur. After cooling, the sulfur solution is filtered, and 7.77 kg of glycerin, 1 kg of fatty acid glucose ether and 0.09 kg of fragrance are added thereto, and water is adjusted to 10 kg. A yellow sulfur lotion of PH11 is obtained. Mix 5 ml of this sulfur lotion with a commercial shampoo, wash the hair dyed with photosensitive hair dye, and rinse well with a commercial rinse. Thereafter, even if the hair was dyed with an oxidative hair dye, it did not turn green and the intended color tone was obtained.
１０ｋｇステンレス容器に沈降イオウ０．１２ｋｇ、粉末状酸化カルシウム０．１２ｋｇ、精製水０．９ｋｇを取り９０℃以上で３時間加熱しイオウを溶解する。冷却後、イオウ溶液を濾過し、これにグリセリン７．７７ｋｇ、脂肪酸グルコースエーテル１ｋｇ及び香料０．０９ｋｇを加え、水を調整して１０ｋｇにする。ＰＨ１１の黄色のイオウローションが得られる。このイオウローション５ｍｌを市販のシャンプーに混ぜて、感光性染毛料で白髪染めした毛髪を洗い、市販のリンスでよくすすぐ。その後、酸化染毛剤で毛髪を染めても緑色にはならず、目的とする色調が得られた。 Example 1
In a 10 kg stainless steel container, 0.12 kg of precipitated sulfur, 0.12 kg of powdered calcium oxide and 0.9 kg of purified water are taken and heated at 90 ° C. or more for 3 hours to dissolve sulfur. After cooling, the sulfur solution is filtered, and 7.77 kg of glycerin, 1 kg of fatty acid glucose ether and 0.09 kg of fragrance are added thereto, and water is adjusted to 10 kg. A yellow sulfur lotion of PH11 is obtained. Mix 5 ml of this sulfur lotion with a commercial shampoo, wash the hair dyed with photosensitive hair dye, and rinse well with a commercial rinse. Thereafter, even if the hair was dyed with an oxidative hair dye, it did not turn green and the intended color tone was obtained.
（実施例２）
１００ｋｇのミキシングタンクに精製水７２．０５ｋｇ、トリメチルグリシン０．０５ｋｇ、濃グリセリン２．０ｋｇ、塩化ステアリルトリメチルアンモニウム０．４ｋｇ、エタノール１０．０ｋｇ、モノエタノールアミン１０．０ｋｇ、ローズウォーター５．０ｋｇ、フェノキシエタノール０．５ｋｇを入れ、４５℃で３０分間撹拌し、透明なトリートメントローション９９．５ｋｇを得た。感光性染毛料で白髪染めを行った染毛に、このトリートメントローションをスプレーし、３分間放置した後シャンプーした。その後、酸化染毛剤で染色しても、緑に変色する事は無かった。 (Example 2)
Purified water 72.05 kg, trimethylglycine 0.05 kg, concentrated glycerin 2.0 kg, stearyltrimethylammonium chloride 0.4 kg, ethanol 10.0 kg, monoethanolamine 10.0 kg, rose water 5.0 kg, phenoxyethanol in a 100 kg mixing tank 0.5 kg was added and stirred at 45 ° C. for 30 minutes to obtain 99.5 kg of a transparent treatment lotion. This treatment lotion was sprayed on the hair dyed with gray hair with a photosensitive hair dye, allowed to stand for 3 minutes and then shampooed. After that, even when dyed with an oxidative hair dye, it did not turn green.
１００ｋｇのミキシングタンクに精製水７２．０５ｋｇ、トリメチルグリシン０．０５ｋｇ、濃グリセリン２．０ｋｇ、塩化ステアリルトリメチルアンモニウム０．４ｋｇ、エタノール１０．０ｋｇ、モノエタノールアミン１０．０ｋｇ、ローズウォーター５．０ｋｇ、フェノキシエタノール０．５ｋｇを入れ、４５℃で３０分間撹拌し、透明なトリートメントローション９９．５ｋｇを得た。感光性染毛料で白髪染めを行った染毛に、このトリートメントローションをスプレーし、３分間放置した後シャンプーした。その後、酸化染毛剤で染色しても、緑に変色する事は無かった。 (Example 2)
Purified water 72.05 kg, trimethylglycine 0.05 kg, concentrated glycerin 2.0 kg, stearyltrimethylammonium chloride 0.4 kg, ethanol 10.0 kg, monoethanolamine 10.0 kg, rose water 5.0 kg, phenoxyethanol in a 100 kg mixing tank 0.5 kg was added and stirred at 45 ° C. for 30 minutes to obtain 99.5 kg of a transparent treatment lotion. This treatment lotion was sprayed on the hair dyed with gray hair with a photosensitive hair dye, allowed to stand for 3 minutes and then shampooed. After that, even when dyed with an oxidative hair dye, it did not turn green.
（実施例３）
１００ｋｇのミキシングタンクに脂肪酸グルコースエーテル７０ｋｇ、ポリエチレングリコール・シリコンオイル誘導体５ｋｇ、精製水１８．８ｋｇ、１，２ヘキサンジオール１．０ｋｇを取り６０℃で撹拝し、均一溶解する（Ａ相）。別の容器にイソプロパノールアミン３．０ｋｇ、沈降イオウ０．２ｋｇを取り６０℃で３０分間撹拝し、イオウを溶解させる（Ｂ相）。Ａ相にＢ相及び香料２ｋｇを加えＰＨ９．５のイオウシャンプーを得る。感光性染毛料で白髪染めした毛髪をこのイオウシャンプーで洗い、その後、酸化染毛剤で染色しても色調に異常は現れず、目的とする色調が得られた。
(Example 3)
In a 100 kg mixing tank, 70 kg of fatty acid glucose ether, 5 kg of polyethylene glycol / silicon oil derivative, 18.8 kg of purified water and 1.0 kg of 1,2 hexanediol are stirred and stirred at 60 ° C. to uniformly dissolve (phase A). In another container, take 3.0 kg of isopropanolamine and 0.2 kg of precipitated sulfur and stir at 60 ° C. for 30 minutes to dissolve the sulfur (phase B). Add Phase B and 2 kg of fragrance to Phase A to obtain a PH 9.5 sulfur shampoo. Even if the hair dyed with a photosensitive hair dye was washed with this sulfur shampoo and then dyed with an oxidative hair dye, the color tone did not appear abnormal, and the desired color tone was obtained.
１００ｋｇのミキシングタンクに脂肪酸グルコースエーテル７０ｋｇ、ポリエチレングリコール・シリコンオイル誘導体５ｋｇ、精製水１８．８ｋｇ、１，２ヘキサンジオール１．０ｋｇを取り６０℃で撹拝し、均一溶解する（Ａ相）。別の容器にイソプロパノールアミン３．０ｋｇ、沈降イオウ０．２ｋｇを取り６０℃で３０分間撹拝し、イオウを溶解させる（Ｂ相）。Ａ相にＢ相及び香料２ｋｇを加えＰＨ９．５のイオウシャンプーを得る。感光性染毛料で白髪染めした毛髪をこのイオウシャンプーで洗い、その後、酸化染毛剤で染色しても色調に異常は現れず、目的とする色調が得られた。
(Example 3)
In a 100 kg mixing tank, 70 kg of fatty acid glucose ether, 5 kg of polyethylene glycol / silicon oil derivative, 18.8 kg of purified water and 1.0 kg of 1,2 hexanediol are stirred and stirred at 60 ° C. to uniformly dissolve (phase A). In another container, take 3.0 kg of isopropanolamine and 0.2 kg of precipitated sulfur and stir at 60 ° C. for 30 minutes to dissolve the sulfur (phase B). Add Phase B and 2 kg of fragrance to Phase A to obtain a PH 9.5 sulfur shampoo. Even if the hair dyed with a photosensitive hair dye was washed with this sulfur shampoo and then dyed with an oxidative hair dye, the color tone did not appear abnormal, and the desired color tone was obtained.
Claims (4)
- 全量に対してイオウを０．０１～５％含むことを特徴とする酸化染毛剤用色調変化防止剤。 A color tone change inhibitor for oxidative hair dyes characterized by containing 0.01 to 5% of sulfur with respect to the total amount.
- 全量に対してアルカノールアミン類を１～１５％含むことを特徴とする酸化染毛剤用色調変化防止剤。 A color tone change inhibitor for oxidative hair dyes characterized by containing 1 to 15% alkanolamines based on the total amount.
- 全量に対してイオウを０．０１～５％、アルカノールアミン類を１～１５％含むことを特徴とする酸化染毛剤用色調変化防止剤。 A color change inhibitor for oxidative hair dyes containing 0.01 to 5% sulfur and 1 to 15% alkanolamines based on the total amount.
- 水溶液、ヘアローション、ヘアゲル、シャンプー、リンス、トリートメント、ヘアトニック、ヘアリキッド、ヘアクリーム、ヘアムース、又は、ヘアスプレーに用いることを特徴とする請求項１乃至３の何れか一項に記載の酸化染毛剤用色調変化防止剤。 The oxidative dyeing according to any one of claims 1 to 3, which is used for an aqueous solution, a hair lotion, a hair gel, a shampoo, a rinse, a treatment, a hair tonic, a hair liquid, a hair cream, a hair mousse, or a hair spray. Color tone change inhibitor for hair.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2009/059525 WO2010137105A1 (en) | 2009-05-25 | 2009-05-25 | Color tone change inhibitor for oxidative hair dye |
| JP2009537433A JP4528357B1 (en) | 2009-05-25 | 2009-05-25 | Color change inhibitor for oxidative hair dyes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2009/059525 WO2010137105A1 (en) | 2009-05-25 | 2009-05-25 | Color tone change inhibitor for oxidative hair dye |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2010137105A1 true WO2010137105A1 (en) | 2010-12-02 |
Family
ID=42767879
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2009/059525 WO2010137105A1 (en) | 2009-05-25 | 2009-05-25 | Color tone change inhibitor for oxidative hair dye |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP4528357B1 (en) |
| WO (1) | WO2010137105A1 (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04187625A (en) * | 1990-11-22 | 1992-07-06 | Katsumi Mizumaki | Hair-dyeing agent containing silver halide |
| JPH0597635A (en) * | 1991-10-02 | 1993-04-20 | Bristol Mayers Sukuibu Kk | Method for treating hair |
| JPH06501699A (en) * | 1990-09-28 | 1994-02-24 | ザ、プロクター、エンド、ギャンブル、カンパニー | Improved shampoo composition |
| JPH1045547A (en) * | 1996-07-25 | 1998-02-17 | Hoyu Co Ltd | Hair-dyeing agent composition |
| JP2004107208A (en) * | 2002-09-13 | 2004-04-08 | Kanebo Ltd | Hair treatment composition |
| JP2005023024A (en) * | 2003-07-03 | 2005-01-27 | Kao Corp | Oxidation hair dye or bleaching agent composition |
| JP2005053889A (en) * | 2003-07-18 | 2005-03-03 | Tsutomu Kawada | Hair dyestuff |
| JP2005154348A (en) * | 2003-11-26 | 2005-06-16 | Lion Corp | Hair cosmetic |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0539211A (en) * | 1991-08-02 | 1993-02-19 | Shiseido Co Ltd | Reducing agent and cosmetic for human hair |
| JPH0873320A (en) * | 1994-09-06 | 1996-03-19 | Kao Corp | Hair restoring and growing agent |
| JPH0873324A (en) * | 1994-09-06 | 1996-03-19 | Kao Corp | Hair-tonic and hair-growing agent |
| JP3027302B2 (en) * | 1994-09-06 | 2000-04-04 | 花王株式会社 | Hair restoration / hair restoration |
| JP2000169344A (en) * | 1998-12-07 | 2000-06-20 | Hoyu Co Ltd | Pre-treating agent composition for acidic hair dye |
| JP2001261529A (en) * | 2000-03-22 | 2001-09-26 | Kowa Co | Hair cosmetic |
| JP2006052178A (en) * | 2004-08-13 | 2006-02-23 | Lion Corp | Hair cosmetic and hair-reinforcing/strengthening agent |
| JP2007169230A (en) * | 2005-12-26 | 2007-07-05 | Lion Corp | Hair-dressing agent composition |
-
2009
- 2009-05-25 JP JP2009537433A patent/JP4528357B1/en active Active
- 2009-05-25 WO PCT/JP2009/059525 patent/WO2010137105A1/en active Application Filing
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06501699A (en) * | 1990-09-28 | 1994-02-24 | ザ、プロクター、エンド、ギャンブル、カンパニー | Improved shampoo composition |
| JPH04187625A (en) * | 1990-11-22 | 1992-07-06 | Katsumi Mizumaki | Hair-dyeing agent containing silver halide |
| JPH0597635A (en) * | 1991-10-02 | 1993-04-20 | Bristol Mayers Sukuibu Kk | Method for treating hair |
| JPH1045547A (en) * | 1996-07-25 | 1998-02-17 | Hoyu Co Ltd | Hair-dyeing agent composition |
| JP2004107208A (en) * | 2002-09-13 | 2004-04-08 | Kanebo Ltd | Hair treatment composition |
| JP2005023024A (en) * | 2003-07-03 | 2005-01-27 | Kao Corp | Oxidation hair dye or bleaching agent composition |
| JP2005053889A (en) * | 2003-07-18 | 2005-03-03 | Tsutomu Kawada | Hair dyestuff |
| JP2005154348A (en) * | 2003-11-26 | 2005-06-16 | Lion Corp | Hair cosmetic |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2010137105A1 (en) | 2012-11-12 |
| JP4528357B1 (en) | 2010-08-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2446876B1 (en) | Hair dye dyeing hair product combination and its use method | |
| JP6179992B2 (en) | Decolorization method from oxidation dyeing | |
| RU2693477C2 (en) | Improved decolouration of dyed keratinous fibers | |
| CN101111213B (en) | Bodywashes containing additives | |
| JP2007517823A (en) | Oxidizing agent, especially in the form of a transparent gel | |
| JP2017519806A (en) | Improved decolorization of colored keratinous fibers | |
| JP2001158722A (en) | Hair treating agent | |
| JP2013542962A (en) | Use of tea polyphenols and / or brown dyes as dyes and their products | |
| JP2006282627A (en) | Stable composition for hair dye | |
| JP5561889B2 (en) | Active oxygen radical removing composition and hair-containing active oxygen radical removing agent containing the same | |
| WO2016026710A1 (en) | Cosmetic composition for keratin fibres | |
| JP4025698B2 (en) | Hair dye composition | |
| EP2101878B1 (en) | Hair straightening composition | |
| JPH07133216A (en) | External agent for preventing aging of skin | |
| US20030180241A1 (en) | Deodorant composition for permanent wave | |
| JP4528357B1 (en) | Color change inhibitor for oxidative hair dyes | |
| JPH0469324A (en) | Hair dye | |
| JP4542621B1 (en) | Photosensitive hair dye and method for producing the same | |
| WO2017141509A1 (en) | Photosensitive hair dye | |
| JP3012112B2 (en) | Coloring / perming agent and coloring / perming method | |
| CN107890436A (en) | A kind of cosmetics for whitening antioxidation | |
| JP5752656B2 (en) | How to use photosensitive hair dye containing silver ions | |
| JP5486106B1 (en) | Photosensitive hair dye composition using water-soluble complex consisting of silver oxide and amino acid, and photosensitive hair dye | |
| JPH03271214A (en) | Post-treating agent for cysteamine hair processing agent and method for processing hair | |
| TWI414315B (en) | Method of dyeing and re-dyeing hair |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| ENP | Entry into the national phase |
Ref document number: 2009537433 Country of ref document: JP Kind code of ref document: A |
|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 09845172 Country of ref document: EP Kind code of ref document: A1 |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| 122 | Ep: pct application non-entry in european phase |
Ref document number: 09845172 Country of ref document: EP Kind code of ref document: A1 |