JP5486106B1 - Photosensitive hair dye composition using water-soluble complex consisting of silver oxide and amino acid, and photosensitive hair dye - Google Patents
Photosensitive hair dye composition using water-soluble complex consisting of silver oxide and amino acid, and photosensitive hair dye Download PDFInfo
- Publication number
- JP5486106B1 JP5486106B1 JP2013088351A JP2013088351A JP5486106B1 JP 5486106 B1 JP5486106 B1 JP 5486106B1 JP 2013088351 A JP2013088351 A JP 2013088351A JP 2013088351 A JP2013088351 A JP 2013088351A JP 5486106 B1 JP5486106 B1 JP 5486106B1
- Authority
- JP
- Japan
- Prior art keywords
- hair dye
- amino acid
- photosensitive
- photosensitive hair
- silver oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K33/00—Medicinal preparations containing inorganic active ingredients
- A61K33/24—Heavy metals; Compounds thereof
- A61K33/38—Silver; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/434—Luminescent, Fluorescent; Optical brighteners; Photosensitizers
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Cosmetics (AREA)
Abstract
【課題】本発明は、矛盾する関係にある染毛性と保存安定性に優れ、様々な色調で染毛可能な感光性染毛料を提供する。
【解決手段】酸化銀とアミノ酸からなる水溶性酸化銀−アミノ酸錯体を含有する感光性染毛料組成物。
【選択図】図１An object of the present invention is to provide a photosensitive hair dye which is excellent in hair dyeing property and storage stability in contradictory relations and capable of hair dyeing in various colors.
A photosensitive hair dye composition containing a water-soluble silver oxide-amino acid complex comprising silver oxide and an amino acid.
[Selection] Figure 1
Description
本発明は、染毛性、保存安定性に優れ、様々な色調で染毛可能なイオウ臭のしない感光性染毛料組成物に関する。 The present invention relates to a photosensitive hair dye composition which is excellent in hair dyeability and storage stability, and can be dyed in various colors and does not have a sulfur odor.
感光性染毛料は、２００５年に出願人らが販売を開始した。感光性染毛料は、クリームやジェル、ローションといった多様な剤形にできること、髪に塗って太陽光等を浴びるだけで簡単に染まること、１〜２ヶ月染色が維持できること、アレルギーや髪の損傷の原因となるジアミン誘導体を含まないことから市場に受け入れられている。 The photosensitive hair dye was sold by the applicants in 2005. Photosensitive hair dyes can be made into various dosage forms such as creams, gels and lotions, can be easily dyed just by applying them to the sun and exposed to sunlight, etc. It is accepted by the market because it does not contain causative diamine derivatives.
感光性染毛料は水中の銀イオンが光によって還元され、析出した金属銀の微粒子が毛髪表面上に吸着されて発色するので、水溶性の銀塩を使う必要がある。
水に良く溶ける銀塩としては硝酸銀が知られているが、硝酸銀は医薬品原料であるため、日本国では化粧品には使用出来ない。そこで特許文献１で、本発明者らは難溶性ではあるが、２０℃で８００ｍｇ／１００ｍｌまで溶解する硫酸銀に着目し、硫酸銀とクエン酸との組み合わせで、着色性の良い感光性染毛料を提案している。
また、特許文献２では、（ａ）硫酸銀、乳酸銀、及びクエン酸銀からなる群より選ばれる１種または２種以上の銀塩、及び（ｂ）キレート剤を含有する染毛料、特許文献３では硫酸銀と、アルカノールアミン類が混合された感光性染毛料が提案されている。
Photosensitive hair dyes need to use water-soluble silver salts because silver ions in water are reduced by light and the deposited fine particles of metallic silver are adsorbed on the hair surface to develop color.
Silver nitrate is known as a silver salt that dissolves well in water, but since silver nitrate is a raw material for pharmaceuticals, it cannot be used in cosmetics in Japan. Therefore, in Patent Document 1, the present inventors pay attention to silver sulfate which is hardly soluble but dissolves up to 800 mg / 100 ml at 20 ° C., and a photosensitive hair dye having a good coloring property by a combination of silver sulfate and citric acid. Has proposed.
Further, in Patent Document 2, (a) one or more silver salts selected from the group consisting of silver sulfate, silver lactate, and silver citrate, and (b) a hair dye containing a chelating agent, Patent Documents No. 3 proposes a photosensitive hair dye in which silver sulfate and alkanolamines are mixed.
これら従来の硫酸銀、乳酸銀、クエン酸を使用する染毛料は水溶液中の銀塩が不安定で、遮光チューブの中でも徐々に黒く変色してしまう。
また、従来の感光性染毛料は、染毛を繰り返す事で色を濃くすることはできるが、やや赤みをおびたライトブラウンの色調でしか発色できない。赤みを軽減するために、イオウ末（コロイドイオウ）を配合しているが、使用時のイオウ臭が強く、髪についたイオウ臭は数回の洗髪でも落ちにくい。
In these conventional hair dyes using silver sulfate, silver lactate and citric acid, the silver salt in the aqueous solution is unstable and gradually turns black in the light shielding tube.
Moreover, the conventional photosensitive hair dye can darken the color by repeating the hair dyeing, but can only develop a color with a slightly reddish light brown color tone. In order to reduce redness, it contains sulfur powder (colloidal sulfur), but it has a strong sulfur odor when used, and the sulfur odor on the hair is difficult to remove even after several washes.
本発明は、染毛性、保存安定性に優れ、様々な色調で染毛可能なイオウ臭のしない感光性染毛料組成物を提供する。 The present invention provides a photosensitive hair dye composition which is excellent in hair dyeability and storage stability and does not have a sulfur odor and can be dyed in various colors.
酸化銀とアミノ酸とからなる水溶性の錯体を含む感光性染毛料組成物を用いることにより、様々な色調で染毛可能なイオウ臭のしない感光性染毛料組成物を実現した。主な構成は次のとおりである。 By using a photosensitive hair dye composition containing a water-soluble complex composed of silver oxide and an amino acid, a photosensitive hair dye composition capable of being dyed in various colors and having no sulfur odor was realized. The main components are as follows.
第１の発明の感光性染毛料組成物は、酸化銀とアミノ酸とからなる水溶性の酸化銀−アミノ酸錯体を含み、前記アミノ酸がメチオニン、アスパラギン、グルタミン、リシン、ヒスチジン、アスパラギン酸、グルタミン酸から選ばれるもので、単独又は複数の組み合わせで使用されることを特徴とする。第２の発明の感光性染毛料組成物は、酸化銀濃度が０．１ｗｔ％〜１．５ｗｔ％、アミノ酸濃度が０．１ｗｔ％〜４．５ｗｔ％であり、前記アミノ酸はメチオニン、アスパラギン、グルタミン、リシン、ヒスチジン、アスパラギン酸、グルタミン酸から選ばれるもので、単独又は複数の組み合わせで使用されることを特徴とする。第３の発明の感光性染毛料組成物は、さらにコロイドイオウを含まないことを特徴とする。第４の発明の感光性染毛料は上記いずれかの感光性染毛料組成物からなることを特徴とする。第５の発明の感光性染毛料は、さらに剤形がローション、トニック、ジェル、クリーム、乳液、ムース、ヘアトリートメント、リンスのいずれか一つであることを特徴とする。 Photosensitive hair dye composition of the first invention, silver oxide water-soluble consisting of silver oxide and an amino acid - comprises amino acid complexes, the amino acid methionine, asparagine, glutamine, lysine, histidine, aspartic acid, or glutamic acid And is used alone or in combination. The photosensitive hair dye composition of the second invention has a silver oxide concentration of 0.1 wt% to 1.5 wt% and an amino acid concentration of 0.1 wt% to 4.5 wt%, and the amino acids are methionine, asparagine, glutamine , lysine, histidine, aspartic acid, those selected or glutamic acid, et al., characterized in that it is used alone or in multiple combinations. The photosensitive hair dye composition of the third invention is characterized by not containing colloidal sulfur. The photosensitive hair dye of 4th invention consists of one of the said photosensitive hair dye compositions, It is characterized by the above-mentioned. The photosensitive hair dye of the fifth invention is further characterized in that the dosage form is any one of lotion, tonic, gel, cream, emulsion, mousse, hair treatment and rinse.
本発明により、染毛性と保存安定性とに優れる感光性染毛料組成物が得られた。染毛性と保存安定性とは、反応性と安定性という関係にあり、両立が難しい性質であるが、本発明の水溶性の錯体を用いることにより、双方の要請を満足することができた。また、アミノ酸の選択によりカッパーブラウンからアッシュ系まで種々の色調で染毛することができ、不快臭のするコロイドイオウを配合する必要のない感光性染毛料組成物が得られた。 According to the present invention, a photosensitive hair dye composition excellent in hair dyeability and storage stability was obtained. Hair dyeability and storage stability are in a relationship between reactivity and stability and are difficult to achieve at the same time, but by using the water-soluble complex of the present invention, both requirements could be satisfied. . Further, a photosensitive hair dye composition that can dye hair in various colors from copper brown to ash based on the selection of amino acids and does not need to contain unpleasant odor colloidal sulfur was obtained.
以下に、本発明を詳細に説明する。
本発明は、酸化銀とアミノ酸とからなる水溶性の錯体中の銀イオンの毛髪への強い吸着性と錯体の光安定性を利用した感光性染毛料組成物及び感光性染毛料に関する。
The present invention is described in detail below.
The present invention relates to a photosensitive hair dye composition and a photosensitive hair dye that utilize the strong adsorptivity of silver ions in a water-soluble complex composed of silver oxide and an amino acid to hair and the light stability of the complex.
本発明では、硫酸銀、乳酸銀、クエン酸銀などの水溶性銀や難溶性銀を使用する代わりに、従来使用されていない不溶性の酸化銀を銀イオンの供給源として使用する。
酸化銀（Ａｇ２Ｏ）は水に対する溶解性が２０℃で１．７ｍｇ／１００ｍｌ、８０℃で５．５ｍｇ／１００ｍｌであり、実質的に水不溶性である。水不溶性のため、皮膚腐食性、刺激性の知見はない。また、慢性毒性、変異原性、生殖毒性、催寄形成などについての知見もなく、従来の酸化染毛剤と比較して安全性は高い。
本発明の組成物中の酸化銀濃度は、保存安定性、発色性の点から、０．１ｗｔ％〜１．５ｗｔ％であることが好ましい。
In the present invention, insoluble silver oxide, which has not been used conventionally, is used as a source of silver ions, instead of using water-soluble silver such as silver sulfate, silver lactate, and silver citrate, or hardly soluble silver.
Silver oxide (Ag 2 O) has a solubility in water of 1.7 mg / 100 ml at 20 ° C. and 5.5 mg / 100 ml at 80 ° C., and is substantially insoluble in water. There is no knowledge of skin corrosion and irritation due to water insolubility. In addition, there is no knowledge of chronic toxicity, mutagenicity, reproductive toxicity, host formation, etc., and safety is high compared to conventional oxidative hair dyes.
The silver oxide concentration in the composition of the present invention is preferably 0.1 wt% to 1.5 wt% from the viewpoint of storage stability and color developability.
酸化銀０．９ｇと表１に示したアミノ酸１．２ｇとを水９７．９ｇに混合して錯体を形成したところ、溶解性、安定性の面から表２に示したアミノ酸を使用した錯体が感光性染毛料として適していた。 When a complex was formed by mixing 0.9 g of silver oxide and 1.2 g of the amino acid shown in Table 1 with 97.9 g of water, a complex using the amino acid shown in Table 2 was obtained from the viewpoint of solubility and stability. It was suitable as a photosensitive hair dye.
同様の方法により、Ｎ−アセチルシステイン、Ｎ−アセチルメチオニン、及び、グルタミン酸の分子内縮合反応生成物であるピログルタミン酸を用いて錯体を形成させたところ、Ｎ−アセチルシステインは溶解性、安定性が悪く、不適であったが、Ｎ−アセチルメチオニン、及びピログルタミン酸を用いた錯体は感光性染毛料として適していた。 When a complex was formed using pyroglutamic acid, which is an intramolecular condensation reaction product of N-acetylcysteine, N-acetylmethionine, and glutamic acid, by the same method, N-acetylcysteine has solubility and stability. Although it was bad and unsuitable, the complex using N-acetylmethionine and pyroglutamic acid was suitable as a photosensitive hair dye.
本発明において使用するアミノ酸は、酸化銀と安定した錯体を形成し、水溶解性に優れるものであれば表２に示したアミノ酸、Ｎ−アセチルメチオニン、ピロリドンカルボン酸に限定されることなく、アセチル化、メチル化、アミド化、カルボキシル化、ホルミル化、ヒドロキシル化、分子内縮合等したアミノ酸誘導体や、非天然アミノ酸も使用することができる。また、複数種の酸化銀とアミノ酸とからなる水溶性の錯体を組み合わせて使用することもできる。 The amino acid used in the present invention is not limited to the amino acids, N-acetylmethionine, and pyrrolidonecarboxylic acid shown in Table 2 as long as they form a stable complex with silver oxide and have excellent water solubility. Amino acid derivatives obtained by hydration, methylation, amidation, carboxylation, formylation, hydroxylation, intramolecular condensation, and unnatural amino acids can also be used. In addition, a water-soluble complex composed of a plurality of types of silver oxide and an amino acid can be used in combination.
酸化銀に対するアミノ酸の配位数は、アミノ酸の種類によってそれぞれ異なり、それぞれのアミノ酸の配位数に基づき配合量を決定する。通常酸化銀１モルに対してアミノ酸２〜３モルである。本組成物中において、アミノ酸の濃度は、酸化銀濃度次第ではあるが、通常０．１ｗｔ％〜４．５ｗｔ％である。 The coordination number of amino acids with respect to silver oxide varies depending on the type of amino acid, and the blending amount is determined based on the coordination number of each amino acid. Usually 2 to 3 moles of amino acid per mole of silver oxide. In this composition, the amino acid concentration is usually 0.1 wt% to 4.5 wt%, although it depends on the silver oxide concentration.
本発明の組成物は、錯体形成に使用するアミノ酸の選択、組合せにより赤みをおびたライトブラウンのみならず、カッパーブラウンからアッシュ系まで種々の色調で染毛することができる。コロイドイオウを配合せずにブラウンに着色できるので、イオウ臭のしない感光性染毛料を得ることができる。 The composition of the present invention can be dyed in various colors from not only reddish light brown but also copper brown to ash based on the selection and combination of amino acids used for complex formation. Since it can be colored brown without blending colloidal sulfur, a photosensitive hair dye without sulfur odor can be obtained.
本発明の組成物には他の成分として、化粧品や染毛剤の配合成分として一般的に用いられる、界面活性剤、保湿剤、防腐剤、色素、香料等を適宜配合することができる。 In the composition of the present invention, as other components, surfactants, moisturizers, preservatives, dyes, fragrances and the like that are generally used as ingredients for cosmetics and hair dyes can be appropriately blended.
感光性染毛料は、光感度が高いほど染毛性に優れ、光感度が低いほど保存安定性に優れるため、染毛性と保存安定性とは矛盾する関係にある。
本発明にかかる感光性染毛料は染毛性と保存安定性という両性質に優れている。すなわち、本発明の感光性染毛料は、髪に塗って光を照射すると素早く発色するが、プラスチック上に塗った場合は、光を照射してもしばらくは着色せず白いままである。これは、髪に塗ると発色現象が起こり、容器中では安定に保存されるという、染毛料として極めて好ましい性質である。この性質が発現する詳細な原理は不明であるが、本発明者らは次の様に推測している。
Since the photosensitive hair dye has higher hair sensitivity, the higher the photosensitivity, and the lower the photosensitivity, the better the storage stability. Therefore, the hair dyeability and the storage stability are contradictory.
The photosensitive hair dye according to the present invention is excellent in both properties of hair dyeability and storage stability. That is, the photosensitive hair coloring material of the present invention quickly develops color when applied to hair and irradiated with light, but when applied onto plastic, it remains white without being colored for a while even when irradiated with light. This is a very preferable property as a hair dye, in which a coloring phenomenon occurs when applied to hair and it is stably stored in a container. Although the detailed principle by which this property is expressed is unknown, the present inventors speculate as follows.
本来、銀イオンの錯体は光に対して安定である。例えば、銀アンミン錯体や銀とチオ硫酸ナトリウムとの錯体は、水溶液中で安定であり、光を照射しても黒化しない。
酸化銀とアミノ酸とからなる水溶性の錯体も、その水溶液に光を照射しても黒くならない。しかしながら、酸化銀とアミノ酸とからなる水溶性の錯体はその結合力がゆるいため、毛髪表面の様に強いマイナス電荷に接近すると錯体中のＡｇ＋イオンがこの強いマイナス電荷に引き寄せられて錯体が崩壊する。錯体が崩壊するとＡｇ＋イオンは光により容易に還元されて銀微粒子となり発色するため染毛性に優れる。また、プラスチック等の表面には錯体を崩壊させるほどのマイナス電荷が存在しないため、容器中では錯体が安定して存在し保存安定性に優れる。
Naturally, silver ion complexes are stable to light. For example, a silver ammine complex or a complex of silver and sodium thiosulfate is stable in an aqueous solution and does not blacken even when irradiated with light.
A water-soluble complex composed of silver oxide and amino acid does not turn black even when the aqueous solution is irradiated with light. However, the water-soluble complex consisting of silver oxide and amino acid has a loose binding force, so when approaching a strong negative charge like the hair surface, Ag + ions in the complex are attracted to this strong negative charge and the complex collapses. To do. When the complex is disintegrated, Ag + ions are easily reduced by light to form silver fine particles and develop color, and thus have excellent hair dyeing properties. In addition, since there is no negative charge on the surface of plastic or the like that can cause the complex to collapse, the complex is stably present in the container and is excellent in storage stability.
本発明の感光性染毛料組成物は、ローション、トニック、ジェル、クリーム、乳液、ムース、ヘアトリートメント、リンス等の剤形にして、感光性染毛料とすることができる。 The photosensitive hair dye composition of the present invention can be made into a photosensitive hair dye in a dosage form such as lotion, tonic, gel, cream, emulsion, mousse, hair treatment, rinse and the like.
次に、本発明を実施例に基づいて、さらに具体的に説明するが、本発明はこれらのみに限定されるものではない。 Next, the present invention will be described more specifically based on examples, but the present invention is not limited to these examples.
（実施例１）
酸化銀と上記表２に示した７種のアミノ酸とから、酸化銀０．６ｗｔ％、アミノ酸１．２ｗｔ％、水９８．２ｗｔ％の酸化銀とアミノ酸とからなる水溶性の錯体溶液を作成した。この溶液をテストローションとして白髪人毛に塗布、光照射を行い染色テストを行ったところ、カッパーブラウン、ライトブラウン、ブラウン、ダークブラウン、アッシュの色調に染まった。染色状態を図１に示す。
暗色系の色調となるヒスチジン、メチオニン、リシンとの錯体を使用すれば、コロイドイオウを配合せずに赤みのないブラウンに染毛することができた。
また、前記テストローションとして使用した酸化銀−メチオニン錯体溶液をポリエチレンシート上に塗布し、同様の条件で染色テストを行ったところ、白色のままであった。
Example 1
From the silver oxide and the seven amino acids shown in Table 2 above, a water- soluble complex solution composed of 0.6% by weight of silver oxide, 1.2% by weight of amino acid and 98.2% by weight of water and silver oxide and amino acid was prepared. . This solution was applied as a test lotion to human hair with gray hair and was subjected to a dyeing test by light irradiation. As a result, it was dyed in the colors of copper brown, light brown, brown, dark brown and ash. The dyeing state is shown in FIG.
By using a complex with histidine, methionine, and lysine, which has a dark color tone, it was possible to dye reddish brown without adding colloidal sulfur.
Further, when the silver oxide-methionine complex solution used as the test lotion was applied on a polyethylene sheet and subjected to a dyeing test under the same conditions, it remained white.
（実施例２）
１５０ｋｇ容量の真空乳化釜に水（８０．５ｋｇ）、酸化銀（０．６ｋｇ）、Ｌ−メチオニン（１．０ｋｇ）を入れ、ゆっくり撹拌しながら温度を８０℃まで上げた。そこに、ステアリン酸グリセリル（１．０ｋｇ）、セテアレス−２０（０．５ｋｇ）、ステアレス−２０（０．５ｋｇ）、ステアリン酸ソルビタン（１．０ｋｇ）、ステアリン酸ＰＥＧ−４５（１．０ｋｇ）、ステアリン酸ＰＥＧ−７５（０．４ｋｇ）を入れて完全に溶解させた。
別の容器にジメチコン−シクロメチコン混合物を１１．５ｋｇとセタノール２．０ｋｇとを入れ、８０℃まで温度を上げて溶解させた。
(Example 2)
Water (80.5 kg), silver oxide (0.6 kg), and L-methionine (1.0 kg) were placed in a 150 kg vacuum emulsifier, and the temperature was raised to 80 ° C. while stirring slowly. There, glyceryl stearate (1.0 kg), ceteares-20 (0.5 kg), steareth-20 (0.5 kg), sorbitan stearate (1.0 kg), PEG-45 stearate (1.0 kg), PEG-75 stearate (0.4 kg) was added and completely dissolved.
In a separate container, 11.5 kg of dimethicone-cyclomethicone mixture and 2.0 kg of cetanol were placed and dissolved by raising the temperature to 80 ° C.
真空乳化釜のホモミキサーを働かせながら、上記別の容器の内容物を徐々に加え乳化させたのち、４０℃まで冷却し、９８ｋｇの感光性ヘアクリームを得た。
この感光性ヘアクリーム０．５ｇを、１．０ｇの白髪人毛に均一に塗り、晴天日に室内の自然光下に４時間静置した後、シャンプーでよく洗浄したところ、ダークブラウンに染まった。
また、この感光性ヘアクリームは保存安定性に優れており、遮光チューブ中で４ヶ月経過しても変色は見られなかった。
While working the homomixer of the vacuum emulsification pot, the contents of the other container were gradually added and emulsified, and then cooled to 40 ° C. to obtain 98 kg of photosensitive hair cream.
0.5 g of this photosensitive hair cream was uniformly applied to 1.0 g of gray human hair, allowed to stand for 4 hours under natural light in a room on a sunny day, washed well with shampoo, and dyed dark brown.
Moreover, this photosensitive hair cream was excellent in storage stability, and no discoloration was observed even after 4 months in the light shielding tube.
（実施例３）
２００ｋｇ容量の真空乳化釜に水（８７．７ｋｇ）、酸化銀（０．７ｋｇ）、Ｌ−ヒスチジン（１．９ｋｇ）を取り、８０℃に加熱して溶解した。これに（アクリロイルジメチルタウリンアンモニウム／ビニルピロリドン）コポリマー（０．８ｋｇ）を加えて溶解させた。
別の容器にセテアレス−２０（０．１ｋｇ）、ステアレス−２０（０．８ｋｇ）、ドデカン（５．０ｋｇ）、テトラデカン（２．０ｋｇ）、ジメチコン（１．０ｋｇ）を入れ、８０℃まで温度を上げて溶解させた。
(Example 3)
Water (87.7 kg), silver oxide (0.7 kg), and L-histidine (1.9 kg) were placed in a 200 kg vacuum emulsifier and dissolved by heating to 80 ° C. To this was added (acryloyldimethyltaurate ammonium / vinylpyrrolidone) copolymer (0.8 kg) and dissolved.
In a separate container, put Cetheless-20 (0.1 kg), Steareth-20 (0.8 kg), Dodecane (5.0 kg), Tetradecane (2.0 kg), Dimethicone (1.0 kg), and raise the temperature to 80 ° C. Raised to dissolve.
真空乳化釜のホモミキサーを働かせながら、上記別の容器の内容物を徐々に加え乳化させたのち、４０℃まで冷却し、９５ｋｇの感光性ジェルクリームを得た。
この感光性ジェルクリーム０．５ｇを、１．０ｇの白髪人毛に均一に塗り、晴天日に室内の自然光下に２時間静置した後、シャンプーでよく洗浄したところ、ダークブラウンに染まった。
この感光性ジェルクリームも保存安定性にすぐれており、遮光チューブ中で６ヶ月経過しても変色は見られなかった。
The contents of the other container were gradually added and emulsified while the vacuum emulsifier homomixer was working, and then cooled to 40 ° C. to obtain 95 kg of photosensitive gel cream.
0.5 g of this photosensitive gel cream was evenly applied to 1.0 g of gray human hair, allowed to stand for 2 hours under natural light in a room on a sunny day, washed well with shampoo, and dyed dark brown.
This photosensitive gel cream was also excellent in storage stability, and no discoloration was observed even after 6 months in the light shielding tube.
Claims (5)
物。 3. The photosensitive hair dye composition according to claim 1 or 2, which does not contain colloidal sulfur.
リンスのいずれか一つである請求項４に記載の感光性染毛料。 The dosage form is lotion, tonic, gel, cream, milky lotion, mousse, hair treatment,
The photosensitive hair dye according to claim 4, which is one of rinses.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013088351A JP5486106B1 (en) | 2013-04-19 | 2013-04-19 | Photosensitive hair dye composition using water-soluble complex consisting of silver oxide and amino acid, and photosensitive hair dye |
| KR1020140037978A KR101497583B1 (en) | 2013-04-19 | 2014-03-31 | Photosensitive hair colorant using silver oxide-amino acid complex, and composition thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2013088351A JP5486106B1 (en) | 2013-04-19 | 2013-04-19 | Photosensitive hair dye composition using water-soluble complex consisting of silver oxide and amino acid, and photosensitive hair dye |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP5486106B1 true JP5486106B1 (en) | 2014-05-07 |
| JP2014210740A JP2014210740A (en) | 2014-11-13 |
Family
ID=50792171
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013088351A Active JP5486106B1 (en) | 2013-04-19 | 2013-04-19 | Photosensitive hair dye composition using water-soluble complex consisting of silver oxide and amino acid, and photosensitive hair dye |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP5486106B1 (en) |
| KR (1) | KR101497583B1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017145212A (en) * | 2016-02-17 | 2017-08-24 | 株式会社アウラ | Photosensitive hair dye |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007246467A (en) * | 2006-03-17 | 2007-09-27 | Yurika:Kk | One-part type hair dye utilizing optical energy |
| JP2008280321A (en) * | 2007-05-10 | 2008-11-20 | Sun Naturan's:Kk | Hair dye and production method thereof |
| JP2010155783A (en) * | 2008-12-26 | 2010-07-15 | Cosmetics Roorando Kk | Hair dye |
| JP2012144438A (en) * | 2011-01-06 | 2012-08-02 | Nippon Soda Co Ltd | Scalp hair cosmetic |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101254504B1 (en) * | 2010-03-08 | 2013-04-19 | 동성제약주식회사 | The preparation method of a hairdye |
-
2013
- 2013-04-19 JP JP2013088351A patent/JP5486106B1/en active Active
-
2014
- 2014-03-31 KR KR1020140037978A patent/KR101497583B1/en active IP Right Grant
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007246467A (en) * | 2006-03-17 | 2007-09-27 | Yurika:Kk | One-part type hair dye utilizing optical energy |
| JP2008280321A (en) * | 2007-05-10 | 2008-11-20 | Sun Naturan's:Kk | Hair dye and production method thereof |
| JP2010155783A (en) * | 2008-12-26 | 2010-07-15 | Cosmetics Roorando Kk | Hair dye |
| JP2012144438A (en) * | 2011-01-06 | 2012-08-02 | Nippon Soda Co Ltd | Scalp hair cosmetic |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017145212A (en) * | 2016-02-17 | 2017-08-24 | 株式会社アウラ | Photosensitive hair dye |
| WO2017141509A1 (en) * | 2016-02-17 | 2017-08-24 | 株式会社アウラ | Photosensitive hair dye |
| CN108697605A (en) * | 2016-02-17 | 2018-10-23 | 株式会社雅邬乐 | Photosensitive hair dye |
| TWI658838B (en) * | 2016-02-17 | 2019-05-11 | 雅鄔樂股份有限公司 | Photosensitive hair dye |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101497583B1 (en) | 2015-03-02 |
| JP2014210740A (en) | 2014-11-13 |
| KR20140125718A (en) | 2014-10-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1201718C (en) | Hair dyeing composition | |
| KR101352007B1 (en) | A mordant and hair dyeing products containing the same | |
| KR101363383B1 (en) | Hair dye, dyeing hair product combination and its use method | |
| JP2006348011A (en) | Hair dye | |
| JPH01308218A (en) | Hair dyeing composition | |
| JPH05339134A (en) | Hair dye | |
| WO2015186817A1 (en) | Hair-dye composition | |
| TW201600117A (en) | Hair dye composition | |
| JP4184385B2 (en) | One-component hair dye using light energy | |
| JP5486106B1 (en) | Photosensitive hair dye composition using water-soluble complex consisting of silver oxide and amino acid, and photosensitive hair dye | |
| JP2013095734A (en) | Hair dye and hair dyeing method | |
| JP5562514B2 (en) | Two-part hair treatment | |
| JP6624628B1 (en) | Hair dye | |
| EP1889603A2 (en) | Hair dye | |
| CN114668681A (en) | Keratin fiber dyeing composition and dyeing method | |
| CN115297829A (en) | Hair dye | |
| JP6164543B1 (en) | Photosensitive hair dye | |
| KR20210041905A (en) | A hair or scalp cleansing composition containing tannic acid, water-soluble metal salt | |
| JP7444602B2 (en) | How to dye hair | |
| JPH04247019A (en) | Aqueous gradually progressive hair dyeing agent containing soluble sulfur source and amphoteric surface active agent | |
| KR101457488B1 (en) | Method for using of photosensitive hair colorant contained silver ion dying hair without projecting light | |
| JP5752656B2 (en) | How to use photosensitive hair dye containing silver ions | |
| JPH01311012A (en) | Hair dye composition | |
| JP2019182774A (en) | Photosensitive hair dye | |
| JP2016160260A (en) | Hair dye composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20130813 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140204 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140220 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5486106 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |