KR20070040757A - Cosmetic hair preparations - Google Patents

Abstract

By setting it as the hair cosmetic containing (A) polyphenols, the hair cosmetic containing (B) vegetable sterols, or (A) component, (C) cationic surfactant, and (D) specific partial esterification, Hair reinforcement and reinforcement can be aimed at. Coloring with time in a composition containing polyphenols can be suppressed by making it the hair cosmetics containing (A) component, a specific amidoamine compound, and (F) C2-C4 lower alcohol.

Polyphenols, vegetable sterols, hair, cationic surfactants, esters, amidoamines, alcohols.

Description

Hair cosmetics {COSMETIC HAIR PREPARATIONS}

The first invention is weakened by repetition of coloring and the like, reinforces and strengthens the hair with a globular shape, and prevents elongation when pulling the split hair, broken hair, ruptured hair, and hair. It is related with the hair cosmetic which is excellent in an effect and can provide the natural natural texture of hair.

2nd invention relates to the hair cosmetic which is excellent in the reinforcement and strengthening effect of damaged hair, and gives the outstanding moist feeling, suppleness, and handling property.

3rd invention relates to the hair cosmetic which contains the polyphenol which has a binding effect, etc. WHEREIN: It suppresses coloring of the composition over time, and provides the hair cosmetic which gives favorable usability to skin and hair.

As a method for repairing damaged hair by coloring and preventing cracked hair, broken hair, ruptured hair, and the like, a method of using polymer compounds or silicones is widely used (Japanese Patent Laid-Open No. 2000-44434). . In this method, by coating the hair, it is possible to cover or comb the hair with a split end so that the split hair is not easily formed. Moreover, the cosmetics which are effective for the hair which split off using the specific moisturizing plant extract are proposed (Japanese Patent Laid-Open No. 2000-53557).

However, since these techniques act on the surface of the hair and its vicinity, the effect is lost by, for example, washing with shampoo or the like, and the stickiness and feeling of adhesion are unnatural, unlike the natural texture of hair. Problems such as texture may occur. In addition, in the case of hair having a hair tip with a rounded shape by repeating the use of trendy hair dyes and perm agents, the effect of preventing the split hair and broken hair is not sufficient.

From the above, the hair cosmetics and hair reinforcement and reinforcement which are excellent in the reinforcement and strengthening effect of hair, such as the prevention of split hair, broken hair and ruptured hair even after washing the hair, and can give the natural natural texture of the hair It was requested.

In the improvement of handling property, the technique of suppressing spreading by sticking hairs together with polymers or fats and oils is proposed. However, there was a problem such as a finger not passing or stickiness. Moreover, cationic surfactants, silicones, and protein hydrolysates have been proposed as a texture improving agent against moisture degradation. However, there was no sufficient effect on the hair damaged by CMC (cell membrane complex) or matrix inside the hair due to severe damage such as bleaching. For this reason, the hair cosmetic which is more excellent in the repair effect of CMC (cell membrane complex) and a matrix was desired.

In addition, polyphenols and plant extracts containing them are widely used in hair cosmetics used for skin and hair for the purpose of obtaining astringent action, protein binding action and antioxidant action. However, polyphenols and plant extracts containing the same cause discoloration or precipitation in the composition, and there is a big problem in securing the quality of the composition.

Thus far, as a method for solving the above problems, a method using a porphyrin metal complex and an organic reducing agent in combination, a method using cysteine or sulfite, a method using a compound having two or more alcoholic hydroxyl groups, a method using sugar alcohol, and A method of using guanidine derivatives is proposed.

However, in the method using a porphyrin metal complex, since the coloring and coloring peculiar to this compound arise, it is not preferable. In the method using cysteine or sulfite, the odor peculiar to this compound occurs over time, which is not preferable as a hair cosmetic. In the method of using a compound having two or more alcoholic hydroxyl groups or using a sugar alcohol, a large amount of this substance must be blended in order to obtain a sufficient discoloration preventing effect, and it is problematic to feel the external feeling with stickiness. have. Moreover, since the method of using a guanidine derivative is also not enough in order to acquire the preferable feeling at the time of external use, improvement was desired. Moreover, although the method of making a gallic acid derivative (Japanese Unexamined-Japanese-Patent No. 2000-319116) is proposed in order to stabilize gallic acid, the desired effect is acquired when the refinement | purification degree is high, but it is industrially realistic because cost is required to obtain a high refinement degree. In addition, industrially available materials include a small amount of gallic acid, an intermediate, and the like, and therefore, the stabilization effect has been desired to be further improved.

Patent Document 1: Japanese Patent Application Laid-Open No. 2000-44434

Patent Document 2: Japanese Patent Application Laid-Open No. 2000-53557

Patent Document 3: Japanese Patent Application Laid-Open No. 2-6403

Patent Document 4: Japanese Patent Application Laid-Open No. 2001-172135

Patent Document 5: Japanese Patent Application Laid-Open No. 52-79031

Patent Document 6: Japanese Patent Application Laid-Open No. 2001-163764

Patent Document 7: Japanese Patent Application Laid-Open No. 2002-161026

The present invention repeatedly performs hair dyeing and perm, and has a hair with a rounded hair end, but has sufficient reinforcing and strengthening effect of hair such as cracked hair, broken hair, and ruptured hair prevention, and also hair original hair. It is a 1st object to provide the hair cosmetic which can give a natural texture.

A second object of the present invention is to provide a hair cosmetic which gives a touch such as moist feeling and softness and excellent handling property by repairing CMC (cell membrane complex) and matrix in damaged hair.

A third object of the present invention is to provide a hair cosmetic having excellent conditioning effect by suppressing coloring of the passage of time in a composition containing polyphenols and providing a good feeling to the hair.

By combining polyphenols and vegetable sterols, the inventors can prevent split hair and broken hair, and furthermore, by combining cationic surfactants, repeating hair and perm to form hair with a rounded hair tip. Even then, it was found that the natural hair texture before hair dyeing and perm can be restored without causing stickiness or adhesion.

Hair is largely divided from the outside into the cuticle (cuticle), the cortex (colltex) and the medulla (medula). The cuticle (cuticle) or cortex (colltex) contains CMC (cell membrane complex), and the cortex (colltex) contains matrix protein. When damages such as hair dye and perm damage the CMC (cell membrane complex) in the hair, oil components and moisture easily come off, and moisture disappears. If the matrix is partially damaged, the hair curls up, resulting in poor handling. As the damage progresses further, the elasticity or vitality of the hair is lost, and the softness is lost. The cross section is broom-shaped as shown in FIG.

The inventors of the present invention have esters and cationic surfactants in which polyhydric alcohols having r polyphenols and hydroxyl groups (r is 4 or more) partially esterified with s (2 ≦ s ≦ r-2) fatty acids having 8 or more carbon atoms It was found that by using the hair cosmetic containing, the handleability is good and the desirable touch before damage such as moist feeling and softness can be reproduced.

Furthermore, the present inventors found that by using polyphenols, a specific amidoamine compound, and a lower alcohol having 2 to 4 carbon atoms in combination, the discoloration of the composition can be suppressed and a hair cosmetic which gives a good feeling to the hair can be obtained. did.

That is, this invention provides the invention of following [1]-[3].

[One]. Hair cosmetics containing (A) polyphenols and (B) vegetable sterols.

[2]. (A) polyphenols, (C) cationic surfactant, and (D) polyhydric alcohols having r hydroxyl groups (r is 4 or more) and s (2≤s≤r-2) moieties of fatty acids having 8 or more carbon atoms Hair cosmetics containing esterified esterified products.

[3]. (A) Hair cosmetics containing polyphenols, (E) amidoamine compound represented by following General formula (1), and (F) C2-C4 lower alcohol.

(In formula, R <^1> represents a linear or branched C1-C25 alkyl group, alkenyl group, or a hydroxy alkyl group, R <^2> represents a C1-C3 alkylene group, and R <^3> represents a C1-C3 alkyl group. .)

Effects of the Invention

According to the first aspect of the invention, even if the hair has a rounded hair tip by repeating the hair dye or perm, the hair has a reinforcing and strengthening effect such as cracked hair, broken hair, and ruptured hair prevention. It is possible to provide a hair cosmetic and hair reinforcement and strengthening agent that can give a natural texture.

According to the second aspect of the present invention, a hair cosmetic that provides excellent moist feeling, softness, and handling properties can be provided by repairing the CMC (cell membrane complex) and the matrix in damaged hair.

According to the third aspect of the present invention, it is possible to provide a hair cosmetic having excellent conditioning effect by suppressing coloring over time in a composition containing polyphenols, giving a good feeling to the skin and hair.

1 is a scanning electron microscope (SEM) photograph showing unrepaired hair in an embodiment of the present invention.

2 is a scanning electron microscope (SEM) photograph showing repaired hair in an embodiment of the present invention.

To practice the invention  for Best  shape

1st invention is the hair cosmetics containing (A) polyphenols and (B) vegetable sterols.

(A) As polyphenols, tannic acid, a galotannic acid, a kebulic acid, a hamamellitanin, acetanin, a gallic acid, a galic acid hydrate, m-digalic acid, dihydrodigalic acid, a baronic acid, a keburic acid, a hexahydroxydiphenic acid And polyphenols and salts thereof, such as caffeic acid, p-coumaric acid, ferulic acid, citric acid, chlorogenic acid and rosemary acid, and derivatives thereof and salts of these derivatives. These can be used individually by 1 type or in combination of 2 or more types.

As (A) polyphenols, acidic polyphenols or derivatives thereof are preferable. An acidic polyphenol means having an acid dissociation group in a molecule | numerator. Specifically, gallic acid, tannic acid, kebulic acid, baronic acid, kebulic acid, hexahydroxydiphenic acid, caffeic acid, p-coumaric acid, ferulic acid, citric acid, chlorogenic acid, rosemary acid, etc. are mentioned.

Especially, as (A) polyphenols, the gallic acid represented by following General formula (2) or its derivative (s) is preferable.

(Wherein, R ⁴ represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, an amino group, or an alkyl group or alkenyl group having 1 to 18 carbon atoms, and R ⁵ , R ⁶ , and R ⁷ each independently represent a hydrogen atom); , A hydroxyl group, an alkoxy group having 1 to 18 carbon atoms, a polyoxyethylene group, a polyoxypropylene group, a monosaccharide residue, a disaccharide residue or an oligosaccharide residue, and at least one of R ⁵ , R ⁶ , and R ⁷ is a hydroxyl group.)

Examples of the gallic acid represented by the formula (2) or derivatives thereof include gallic acid, gallic acid propyl, and gallic acid glycosides such as gallic acid glucoside, gallic acid maltoside, and gallic acid mannoside, among which gallic acid glycosides are preferred. More specifically, as the gallic acid glycoside, gallic acid methyl ester-3-glucoside, gallic acid methyl ester-4-glucoside, gallic acid propyl ester-3-glucoside, gallic acid methyl ester-3-maltoside, gallic acid-3-glucose Galic acid glycosides, such as a seed and galic acid-3-maltoside, gallic acid disaccharide, such as a gallic acid methyl ester-3,5-diglucoside, a galic acid-3,4-diglucoside, and a galic acid-3,5-diglucoside Can be mentioned. Among these, the gallic acid diglycoside which has two sugars is preferable, and especially the gallic acid diglucoside is preferable.

Although the compounding quantity of polyphenols is not specifically limited, Usually, 0.001-10 mass% is preferable with respect to the hair cosmetic whole quantity, More preferably, it is 0.01-5 mass%, More preferably, it is 0.05-3 mass%.

(B) Vegetable sterols are those which use a plant as a starting material, and can be used individually by 1 type or in combination of 2 or more types. Specifically, phytosterol derivatives, such as (beta) -sitosterol, stigmasterol, campestrol, ergosterol, and phytosterol which is a mixture of these, ester, ether, glycoside, and alkylene oxide adduct of these, are mentioned.

Among these, the alkylene oxide adduct of phytosterol, especially the thing in which the alkylene oxide was added to (alpha) hydroxyl group is used suitably. As alkylene oxide, ethylene oxide, propylene oxide, butylene oxide are preferable, and among these, ethylene oxide is more preferable. As an ethylene oxide adduct (polyoxyethylene phytosterol) of a specific phytosterol, it is BPS-5, BPS-10, BPS-20, BPS-30, BPSH-25 (above a brand name, product made by Nikko Chemicals, Ltd.), a product Represents the number of moles of EO.), GENEROL-00 and GENEROL-22N (above trade names, manufactured by COGNIS).

Although the average added mole number of ethylene oxide is not specifically limited, 2-80 are preferable, More preferably, it is 3-70, More preferably, it is 4-60. If the added molar number is too small, uniform mixing may not be possible in the case of the aqueous formulation, and if too large, the desired effect may not be sufficiently expressed.

Although the compounding quantity of vegetable sterols is not specifically limited, Usually, 0.01-20 mass% is preferable with respect to the hair cosmetic whole quantity, More preferably, it is 0.05-15 mass%, More preferably, it is the range of 0.1-10 mass%. to be. If the blending amount is less than 0.01% by mass, the desired effect may be difficult to be obtained. If the blending amount is more than 20% by mass, stickiness may be generated, resulting in an undesirable texture as a hair cosmetic.

What is necessary is just to mix | blend the (C) cationic surfactant other than the said component to the hair cosmetic of this invention. The cationic surfactant is not particularly limited but may be amine salt, ammonium salt, guanidine salt, benzetonium salt, pyridinium salt, imidazolinium salt, pyrrolidone carboxylate salt, mono-N-long chain acyl basic amino acid lower alkyl ester Salts; and the like. These can be used individually by 1 type or in combination of 2 or more types.

The following are illustrated as cationic surfactants.

(1) Amine salts and ammonium salts represented by the following general formula (3)

(In formula, R <^8> , R <^9> , R <^10> and R <^11> represent a hydrogen atom, an alkyl group, an alkenyl group, a hydroxy alkyl group, a polyalkylene oxide group, or a benzyl group, respectively, One or two of them is C8-C8 an alkyl group of 24 linear or branched-chain, and an alkenyl group, or a hydroxyalkyl group, and the remainder as represents a hydrogen atom, a methyl group, an ethyl group, a benzyl group, a polyalkylene oxide, a poly alkylene _{oxide, -. (C 2 H 4} O ) is preferably a polyalkylene oxide group represented by _p H,-(C ₃ H ₆ O) _q H (where p and q are each an integer of 1 to 5.) X ^- is a chlorine ion, bromine ion or iodine ion Derived from inorganic or organic acids such as halogen ions, sulfuric acid, methyl sulfuric acid, ethyl sulfuric acid, acetic acid, pyrrolidonecarboxylic acid, glycolic acid, citric acid, tartaric acid, p-toluenesulfonic acid, pyroglutamic acid, higher fatty acids, acidic amino acids, and the like. Indicates an anion.)

(2) Guanidine salt represented by the following general formula (4)

(In formula, R <^12> is a C1-C21 linear or branched alkyl group or alkenyl group, A is a C1-C10 linear or branched alkylene group or alkenylene group, t is an integer of 1-5. When t is 2 or more, A in each block may be different from each other. X ⁻ is as described above.)

(3) Benzeothium salt represented by the following general formula (5)

Wherein R ¹² is the same as above, and R ¹³ and R ¹⁴ are each a hydrogen atom, a methyl group, an ethyl group, a benzyl group, or-(C ₂ H ₄ O) _p H or-(C ₃ H ₆ O) _q Polyalkylene oxide group represented by H (wherein p and q are each an integer of 1 to 5), B is a divalent hydrocarbon group having 1 to 10 carbon atoms, or-(C ₂ H ₄ O) _p -or-( C ₃ H ₆ O) _q- (wherein p and q each represent an integer of 1 to 5) X ^- is as described above.)

(4) a pyridinium salt represented by the following formula (6)

(In formula, R <^12> , X <^-> is the same as the above.)

(5) Imidazolinium salt represented by the following general formula (7)

(Wherein R ¹² , R ¹³ , R ¹⁴ and X ⁻ are the same as above).

Moreover, a mono-N-long-chain acyl basic amino acid lower (C1-C7) alkyl ester salt is mentioned as an amino acid type cationic surfactant. As a basic amino acid which comprises this compound, natural amino acids, such as ornithine, lysine, and arginine, are mentioned, for example. It is also possible to use synthetic amino acids such as α, γ-diaminobutyric acid. These may be optically active bodies or racemates. As this acyl group, it is a C8-C22 saturated or unsaturated fatty acid residue. These may be natural or synthesized. For example, single higher fatty acid residues such as lauroyl group, myristoyl group, palmitoyl group and stearoyl group, and natural mixed higher fatty acid residues such as palm oil fatty acid residue and tallow higher fatty acid residue can be used. As the lower alkyl ester component, methyl ester, ethyl ester, propyl ester, butyl ester, pentyl ester, hexyl ester, heptyl ester and octyl ester are suitable. Moreover, as a counter ion, the same thing as said X <^{-> is} mentioned.

More specifically, stearyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, behenyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, dioleyl dimethyl ammonium chloride, didecyl dimethyl ammonium chloride, amidobutyl guanidine laurate, Amidobutyl guanidine acetate, amidobutyl guanidine palmitate acetate, distearyl dimethyl ammonium sulfate, stearyl ethyl dihydroxy ethyl ammonium ethyl sulfate, N- palm oil fatty acid acyl L- arginine ethyl DL-pyrroli Toner carboxylate, dipolyoxyethylene oleyl methyl ammonium chloride, ethyl sulfate lanolin fatty acid aminopropyl ethyl dimethyl ammonium, etc. are mentioned. Among these, stearyl trimethyl ammonium chloride, distearyl dimethyl ammonium chloride, behenyl trimethyl ammonium chloride, dipolyoxyethylene oleyl methyl ammonium chloride, ethyl sulfate lanolin fatty acid aminopropyl ethyl dimethyl ammonium acetate amidobutyl guanidine acetate This is preferred.

Although the compounding quantity of a cationic surfactant is not specifically limited, Usually, it is 0.01-20 mass% with respect to hair cosmetic whole quantity, Preferably it is 0.1-15 mass%, More preferably, it is 0.1-10 mass%. If the blending amount is less than 0.01% by mass, the desired effect may be difficult to be obtained, and when the amount exceeds 20% by mass, an increase in the effect may not be expected and may be uneconomical.

In the hair cosmetic of the present invention, from the point of repair of the CMC (cell membrane complex) and the matrix, (D) polyhydric alcohols having r hydroxyl groups (r is 4 or more) and s fatty acids having 8 or more carbon atoms (2 ≦ s ≦ r) -2) It is good to mix partially esterified esterified product. (D) The esterified product which partially esterified the polyhydric alcohol which has r hydroxyl groups (r is four or more), and s (2 <= s <r-2) fatty acid of C8 or more fatty acid is demonstrated in detail later.

Although the compounding quantity of (D) component is not specifically limited, 0.01-10 mass% is preferable with respect to the hair cosmetic whole quantity, More preferably, it is 0.1-5 mass%, More preferably, it is 0.1-3 mass%. When there is too little compounding quantity, the effect of a favorable handling and a favorable texture may not be exhibited, and when too large, it may become a stickiness or a heavy finishing feeling.

In the hair cosmetic of the present invention, from the viewpoint of time-lapse color suppression in a composition containing (A) polyphenols, (E) an amidoamine compound represented by the following general formula (1) and (F) of 2 to 4 carbon atoms You can mix lower alcohols. (E) The amidoamine compound represented by following General formula (1) and (F) C2-C4 lower alcohol are demonstrated in detail later.

(Formula 1)

(In formula, R <^1> represents a linear or branched C1-C25 alkyl group, alkenyl group, or a hydroxyalkyl group, R <^2> represents a C1-C3 alkylene group, and R <^3> represents a C1-C3 alkyl group. .)

As for the compounding quantity of an amidoamine compound, 0.01-20 mass% is preferable with respect to hair cosmetic whole quantity, More preferably, it is the range of 0.1-5 mass%. If it is less than 0.01 mass%, sufficient coloring prevention effect may not be obtained, and when it exceeds 20 mass%, a usability may worsen. As for the compounding quantity of C2-C4 lower alcohol, 0.1-95 mass% is preferable with respect to hair cosmetic whole quantity, More preferably, it is 0.5-80 mass%, More preferably, it is the range of 1-50 mass%. If it is less than 0.1 mass%, sufficient coloring prevention effect may not be obtained, and when it exceeds 95 mass%, the solubility of polyphenols may worsen.

Hair cosmetics of the present invention, if desired, components other than those generally formulated into hair cosmetics, for example, nonionic surfactants, amphoteric surfactants, anionic surfactants, silicones, polymer compounds, amino acids, Protein hydrolyzate, metal blocker, alcohols other than the above, polyols, emulsions, ultraviolet absorbers, pH adjusters, antioxidants, oxidizing agents, reducing agents, alkali agents, pigments, antibacterial agents, fungicides and propellants can be blended.

When mix | blending a fragrance with the hair cosmetic of this invention, it conforms to the fragrance and fragrance composition of Unexamined-Japanese-Patent No. 2003-95895. Moreover, when mix | blending a fragrance and a fragrance composition with the hair cosmetic of this invention, it is preferable to mix | blend so that a fragrance and a fragrance composition may be 0.00001-50 mass% with respect to the hair cosmetic whole quantity of this invention, and it is mix | blended 0.0001-30 mass% more. .

The hair cosmetic of the present invention can be prepared by being used in various shapes such as liquid, cream, mist, foam, gel and wax. In addition, the preparation method of the hair cosmetic of this invention is not restrict | limited, It can prepare according to the conventional method of each shape, and can be used based on the conventional method of each formulation.

The hair cosmetic of the present invention can be applied as a shampoo, rinse, treatment, styling agent and the like. In particular, it is excellent in reinforcing and strengthening of hair such as cracked hair, broken hair, ruptured hair, and preventing stretching when the hair is pulled out. It is preferable to use, and hair cosmetics containing (A) polyphenols and (B) vegetable sterols are useful as a hair reinforcement and strengthening agent.

According to a second aspect of the invention, (A) polyphenols, (C) cationic surfactants, (D) polyhydric alcohols having r hydroxyl groups (r is 4 or more) and s fatty acids having 8 or more carbon atoms (2 ≦ s ≦ r-2) Hair cosmetics containing partially esterified esterified products.

As (A) polyphenols, the same thing as the above can be used.

Although the compounding quantity of (A) component in the case of 2nd invention is not specifically limited, 0.001-10 mass% is preferable with respect to hair cosmetic whole quantity, More preferably, it is 0.1-3 mass%. In addition, when mix | blending 2 or more types, the said compounding quantity is the total amount of the polyphenols to be used. If the blending amount is less than 0.001% by mass, the handling properties of the hair and the feel effect may not be exhibited, and if the amount exceeds 10% by mass, it may be stiff.

2nd invention makes (C) cationic surfactant essential, and (C) cationic surfactant can use the same thing as the above.

Although the compounding quantity of (C) component in the case of 2nd invention is not specifically limited, 0.01-10 mass% is preferable with respect to the hair cosmetic whole quantity, More preferably, it is 0.1-5 mass%, Especially preferably, it is 0.1-3 mass %to be. If the blending amount is less than 0.01% by mass, the effects of good handling properties and good texture may not be exhibited. If the blending amount exceeds 10% by mass, stickiness or heavy finish may be obtained.

The component (D) is an esterified product in which a polyhydric alcohol having r hydroxyl groups (r is 4 or more) and s (2 ≦ s ≦ r-2) partial esterifications of fatty acids having 8 or more carbon atoms. It will not specifically limit, if it is such an ester, It can be used individually by 1 type or in combination of 2 or more types. In the present invention, since the texture varies greatly depending on the number of fatty acids esterified, the number of fatty acids (s) is important. When the number of fatty acids (s) is less than 2, the stickiness peculiar to a polyhydric alcohol becomes large and the texture worsens. In addition, if the number of fatty acids (s) is larger than r-2, an oily feeling will appear and the slipperiness will become large. As described above, the balance between the number of hydroxyl groups (r) and the number (s) of esterified fatty acids is necessary for expressing a good texture. In order to obtain such a suitable balance, it is necessary to use a polyhydric alcohol having a hydroxyl group of 4 or more.

As such esterified product, For example, the polyglycerol fatty acid ester represented by following General formula (8), the polyoxyethylene sorbitan fatty acid ester represented by following General formula (9), and the polyoxyethylene pentaeryte represented by following General formula (10) Lithol fatty acid ester and the polyoxyethylene sorbitan fatty acid ester represented by following General formula (11) are mentioned. In the following formulas (8) to (11), R is a hydrogen atom or a fatty acid residue (COR ': R' is a fatty acid residue represented by a saturated or unsaturated hydrocarbon group) and has r hydroxyl groups (r is 4 or more). The polyhydric alcohol and fatty acid having 8 or more carbon atoms are suitably selected to be the esterified product of s pieces (2≤s≤r-2) partially esterified. m is preferably 0 to 30, and a to d are addition numbers of ethylene oxide groups.)

As polyglycerol fatty acid ester, tetrabehenic acid hexaglyceryl, distearate decaglyceryl, distearate triglyceryl, distearate pentaglyceryl, tristearate hexaglyceryl, tetrabehenic acid hexaglyceryl, pentaoleic acid hexa Glyceryl, diricinoleic acid hexaglyceryl, triricinoleic acid hexaglyceryl, tetraricinoleic acid hexaglyceryl, pentaricinoleic acid hexaglyceryl, hexaricinoleic acid hexaglyceryl, pentaoleic acid hexaglyceryl, triglyceride Decaglyceryl stearate, decaglyceryl trioleate, decaglyceryl pentastearic acid, decaglyceryl pentahydroxystearate, decaglyceryl pentaoleate, decaglyceryl heptatarate, decaglyceryl decastearate, decaol Lesca Decaglyceryl, Deca Macadamia Nut Oil Fatty Acids Decaglyceryl, Diricinoleic Acid Decaglycer The reel, the triscinoleic acid decaglyceryl, the tetraricinoleic acid decaglyceryl, the pentaricinoleic acid decaglyceryl, the hexaricinoleic acid decaglyceryl, the dioleic acid diglyceryl can be mentioned.

Examples of polyoxyethylene sorbitan fatty acid esters include tetraoleic acid POE (4) to (60) sorbet, dioleic acid POE (6) to (60) sorbet, trioleic acid POE (6) to (60) sorbet, distearate Acid POE (6)-(60) Sorbit, Tristearic acid POE (6)-(60) Sorbit, Tetrastearic acid POE (6)-(60) Sorbit, Dicaprylic acid POE (6)-(60 Sorbit, tricaprylic acid POE (6) to (60) sorbet, tetracaprylic acid POE (6) to (60) sorbet, dilauric acid POE (6) to (60) sorbet, Trira Urethane POE (6)-(60) Sorbit, Tetralauric Acid POE (6)-(60) Sorbit, Dimyritic Acid POE (6)-(60) Sorbit, Trimyric Acid POE (6) Sorbitan, tetramyritic acid POE (6) to (60) sorbet, dipalmitic acid POE (6) to (60) sorbet, tripalmitic acid POE (6) to (60) sorbet , Tetrapalmitic acid POE (6)-(60) sorbet, dioundecanoic acid POE (6)-(60) sorbet, trioundecanoic acid POE (6)-(60) sorbet, te Rounddecanoic acid POE (6)-(60) sorbet etc. are mentioned.

Examples of the polyoxyethylene pentaerythritol fatty acid ester include distearic acid POE (6) to (60) pentaerythritol, dilauric acid POE (6) to (60) pentaerythritol, and dicaprylic acid polyoxyethylene pentaerythritol ( 6) to (60), dioundecanoic acid polyoxyethylene pentaerythritol (6) to (60), dimyritic acid polyoxyethylene pentaerythritol (6) to (60), dipalmitic acid polyoxyethylene pentaerythritol (6)-(60), dioleic acid polyoxyethylene pentaerythritol (6)-(60), etc. are mentioned.

Examples of the polyoxyethylene sorbitan fatty acid esters include dioleic acid POE (6) to (60) sorbitan, distearate POE (6) to (60) sorbitan, dicaprylic acid POE (6) to (60) sorbitan, Dioundecanoic acid POE (6)-(60) sorbitan, dilauric acid POE (6)-(60) sorbitan, dimyritic acid POE (6)-(60) sorbitan, dipalmitic acid POE (6)- (60) Sorbitan, distearic acid POE (6) to (60) sorbitan, dibehenic acid POE (6) to (60) sorbitan, sesquistearic acid POE (6) to (60) sorbitan, sesqui Oleic acid POE (6)-(60) sorbitan, etc. are mentioned.

Among them, from the viewpoint of solubility, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene pentaerythritol fatty acid ester, and polyoxyethylene sorbitan fatty acid ester are preferable. Moreover, polyoxyethylene sorbitan fatty acid ester is preferable, and among these, tetraoleic acid polyoxyethylene (4) sorbet, tetraoleic acid polyoxyethylene (6) sorbet, tetraoleic acid polyoxyethylene (30) sorbet, tetraoleic acid poly Especially preferred are oxyethylene (40) sorbitan and tetraoleic acid polyoxyethylene (60) sorbet.

Although the compounding quantity of (D) component is not specifically limited, 0.01-10 mass% is preferable with respect to the hair cosmetic whole quantity, More preferably, it is 0.1-5 mass%, Especially preferably, it is 0.1-3 mass%. If the blending amount is less than 0.01% by mass, the effects of good handling properties and good texture may not be exhibited, and when it exceeds 10% by mass, stickiness or heavy finish may be obtained.

Moreover, from the point of time-dependent coloring suppression in the composition containing (A) polyphenols, (E) the amidoamine compound represented by following General formula (1), and (F) C2-C4 lower alcohol are mix | blended. Do it. (E) The amidoamine compound represented by following General formula (1) and (F) C2-C4 lower alcohol are demonstrated in detail later.

As for the compounding quantity of an amidoamine compound, 0.01-20 mass% is preferable with respect to hair cosmetic whole quantity, More preferably, it is the range of 0.1-5 mass%. If it is less than 0.01 mass%, sufficient coloring prevention effect may not be obtained, and when it exceeds 20 mass%, a usability may worsen. As for the compounding quantity of C2-C4 lower alcohol, 0.1-95 mass% is preferable with respect to hair cosmetic whole quantity, More preferably, it is 0.5-80 mass%, More preferably, it is the range of 1-50 mass%. If it is less than 0.1 mass%, sufficient coloring prevention effect may not be obtained, and when it exceeds 95 mass%, the solubility of polyphenols may worsen.

Moreover, similarly to 1st invention, the hair cosmetics of 2nd invention can mix | blend an appropriate amount the component generally mix | blended with the cosmetics for hair as desired.

When the fragrance is blended into the hair cosmetic of the present invention, the fragrance used is based on the fragrance and fragrance composition described in Japanese Patent Application Laid-Open No. 2003-267841. When the fragrance composition is blended, the fragrance composition is 0.00001 based on the total amount of the hair cosmetic. It is suitable to mix | blend so that it may become -50 mass%, More preferably, it mix | blends 0.0001-30 mass%.

The hair cosmetic of the present invention can be prepared based on the conventional method of the hair cosmetic. As a hair cosmetic, it can apply as a shampoo, rinse, a treatment, a styling agent, a hair growth agent, and a keratin fiber processing agent. In particular, since the hair cosmetic of the present invention has excellent CMC (cell membrane complex) and matrix repair (repair) effects, it is optimal as CMC (cell membrane complex) repair and repair agent and matrix repair agent, and has excellent moist feeling and flexibility. It can give a soft touch before damage and also excellent handling property.

3rd invention contains (A) polyphenols, (E) the amidoamine compound represented by following General formula (1), (F) hair cosmetics containing C2-C4 lower alcohol, (A) polyphenols A hair cosmetic containing (A) polyphenols, comprising (E) an amidoamine compound represented by the following formula (1) and (F) a lower alcohol having 2 to 4 carbon atoms in a hair cosmetic containing Color suppression method

(Formula 1)

(In formula, R <^1> represents a linear or branched C1-C25 alkyl group, alkenyl group, or a hydroxy alkyl group, R <^2> represents a C1-C3 alkylene group, and R <^3> represents a C1-C3 alkyl group. .)

As (A) polyphenols, the same thing as the above can be used.

As for the compounding quantity of polyphenols in the case of 3rd invention, 0.0001-5 mass% is preferable with respect to hair cosmetic whole quantity, More preferably, it is the range of 0.001-2 mass%. If it is less than 0.0001 mass%, sufficient effects, such as a convergence action, antioxidant action, and a protein binding action, may not be acquired, and when it exceeds 5 mass%, stickiness and stiffness may arise.

The amidoamine compound used by this invention is represented by following General formula (1), It can be used individually by 1 type or in combination of 2 or more types.

(Formula 1)

(In formula, R <^1> represents a linear or branched C11-C25, preferably 15-21 alkyl group, an alkenyl group, or a hydroxyalkyl group, R <^2> is a C1-C3 alkylene group, R <^3> is carbon number An alkyl group of 1 to 3 is represented.)

Examples of the amidoamine compound represented by the general formula (1) include lauric acid dimethylaminopropylamide, myristic acid dimethylaminopropylamide, palmitic acid dimethylaminopropylamide, stearic acid dimethylaminopropylamide, and behenic acid dimethylaminopropyl. Amide, dimethyl aminopropylamide, isostearic acid dimethylaminopropylamide, palm fatty acid dimethylaminopropylamide, palm fatty acid dimethylaminopropylamide, tallow fatty acid dimethylaminopropylamide, lauric acid diethylaminoethylamide, myristic acid di Ethylaminoethylamide, diethylaminoethylamide of palmitic acid, diethylaminoethylamide of stearic acid, diethylaminoethylamide of behenic acid, diethylaminoethylamide of oleic acid, diethylaminoethylamide of isostearic acid, palm fatty acid diethyl Aminoethylamide, Palm fatty acid diethylaminoethylamide, tallow fatty acid diethylaminoethylamide, lauric acid diethylaminopropylamide, myristic acid diethylaminopropylamide, palmitic acid diethylaminopropylamide, stearic acid diethylaminopropylamide Diethylaminopropylamide, behenic acid, diethylaminopropylamide, oleic acid diethylaminopropylamide, palm fatty acid diethylaminopropylamide, palm fatty acid diethylaminopropylamide, tallow fatty acid diethylaminopropylamide, and the like. Amidoamine compound etc. are mentioned. Among these, stearic acid dimethylaminopropylamide, stearic acid diethylaminoethylamide, behenic acid dimethylaminopropylamide, and isostearic acid dimethylaminopropylamide are used suitably.

It is preferable to neutralize the amidoamine compound of this invention using an acid, and to adjust and use pH. Examples of the acid include inorganic acids such as hydrochloric acid, sulfuric acid, nitric acid and phosphoric acid, and organic acids such as acetic acid, lactic acid, citric acid, malic acid, tartaric acid, glycolic acid, glutamic acid, succinic acid and alkyl sulfuric acid. Among these, hydrochloric acid, phosphoric acid, lactic acid, citric acid, and glycolic acid are more preferable from a viewpoint of a bad smell and an effect. Moreover, 2-6 are preferable and, as for pH (25 degreeC) of the hair cosmetics obtained by neutralization, 3-5 are more preferable.

As for the compounding quantity of an amidoamine compound, 0.01-20 mass% is preferable with respect to hair cosmetic whole quantity, More preferably, it is the range of 0.1-5 mass%. If it is less than 0.01 mass%, sufficient coloring prevention effect may not be obtained, and when it exceeds 20 mass%, a usability may worsen.

Examples of the lower alcohol having 2 to 4 carbon atoms used in the present invention include ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, 2-methyl-1-propanol, 2-methyl-2-propanol, and the like. have. These can be used individually by 1 type or in combination of 2 or more types.

As for the compounding quantity of C2-C4 lower alcohol, 0.1-95 mass% is preferable with respect to hair cosmetic whole quantity, More preferably, it is 0.5-80 mass%, More preferably, it is the range of 1-50 mass%. If it is less than 0.1 mass%, sufficient coloring prevention effect may not be obtained, and when it exceeds 95 mass%, the solubility of polyphenols may worsen.

What is necessary is just to mix | blend the (C) cationic surfactant with the hair cosmetic of this invention. As the (C) cationic surfactant, those mentioned above can be used. Although the compounding quantity of (C) component in the case of 3rd invention is not specifically limited, 0.01-10 mass% is preferable with respect to the hair cosmetic whole quantity, More preferably, it is 0.1-5 mass%, Especially preferably, it is 0.1-3 mass %to be. When the compounding amount is less than 0.01% by mass, the effects of good handling properties and good texture may not be exhibited, while when the amount exceeds 10% by mass, stickiness or heavy finish may be obtained.

Moreover, the hair cosmetics of 3rd invention can mix | blend an appropriate amount the component generally mix | blended with the cosmetics for hair as desired like 1st and 2nd invention.

When mix | blending a fragrance with the hair cosmetic of this invention, the fragrance | flavor used is based on the fragrance and fragrance composition of Unexamined-Japanese-Patent No. 2003-95895, The compounding quantity is 0.00001-50 mass with respect to the hair cosmetic whole quantity. It is preferable to mix | blend so that it may become%, More preferably, it mix | blends 0.0001-30 mass%.

As a hair cosmetic of this invention, a rinse, a styling agent, a hair conditioning agent, etc. are mentioned, It can be obtained by the conventional method of a formulation.

Hereinafter, although an Example and a comparative example are shown and this invention is demonstrated concretely, this invention is not limited to the following Example. In addition, in the following example, when there is no specification in particular, "%" of a composition shows the mass%. In addition, unless otherwise specified, pH measurement temperature is 25 degreeC.

Examples I-1 to 7 and Comparative Examples I-1 to 5

The hair cosmetic of the composition shown in Table 1, 2 was prepared according to the conventional method, and the following method evaluated. The results are written together in Tables 1 and 2.

<Evaluation Method>

Repeated use of the hair dye regularly (about 1 degree in January), and the damage to the hair, when applied after each hair cosmetics (3 to 5g) after drying, prevents split hair and broken hair, The natural texture recovery effect (no stickiness and adhesion) was evaluated, respectively, and the results were shown by the following criteria.

<Evaluation Criteria>

(Double-circle): 9-10 of 10 people answered that it was good

(Circle): 7-8 of 10 people answered that it was good

(Triangle | delta): 4-6 of 10 people answered that it was good

×: 0 to 3 people who answered that they were good

The raw material used by the Example in following Table 3 is shown.

Example I-8

Product made of dispenser type water

The water agent of the following prescription was prepared based on the conventional method, and it filled into the PET pump dispenser container which knead | mixed the ultraviolet absorber.

Composition mass (%)

Gallic acid-3,5-diglucoside 0.4

Gallic acid-3-glucoside 0.01

Polyoxyethylene (30) Phytosterol 1.0

Tetraoleic acid polyoxyethylene (40) sorbet 1.0

Stearate Dimethylaminopropyl Amido 0.4

Sodium sulfate 0.001

Lauryldimethylaminoacetic acid betaine 5.0

Stearyltrimethylammonium Chloride 3.0

POE (20) stearyl ether 3.0

N-vinylpyrrolidone-N, N-dimethylaminoethyl methacrylate0.5

N-methacryloyloxydiethyl-N, N-dimethylaminoethyl-α-

  N-methylcarboxy betaine methacrylic acid alkyl ester

  Copolymer 1.0

  (Brand name yukaformer 510, product made by Mitsubishi Kagaku Co., Ltd.)

Hydrolyzed Keratin 2.5

  (Brand name professional U alpha, Ichimaru Parker Co., Ltd. product)

Benzoic acid 0.1

Methylparaben 0.1

Sodium Pyrophosphate Anhydrous 0.05

Glycolic acid 0.2

Triethanolamine 1.0

Fragrance Composition A 0.1

Ethanol 20.0

Tablet balance

Total 100.0

Example I-9

Non-Aerosol Pump Foam

The foam formulation of the following prescription was prepared based on the conventional method, and it filled into the polypropylene pump foam container which knead | mixed the ultraviolet absorber. In addition, pH was adjusted to 4.5.

Composition mass (%)

Gallic acid-3,5-zimaltoside 0.8

Gallic acid-3-glucoside 0.015

Polyoxyethylene (40) Phytosterol 0.5

Tetraoleic acid polyoxyethylene (30) sorbet 1.5

Stearic Acid Dimethylaminopropylamide 0.8

Lauric acid sucrose ester 1.0

Acetic lauric acid amidobutylguanidine 1.0

3-methyl-1,3-butanediol 10.0

Silicone Emulsion 8.0

  (Brand name FZ-4188, Nippon Unicar Co., Ltd. product)

Amino Modified Silicone Emulsion 5.0

  (Brand name FZ-4672, Nippon Unicar Co., Ltd. product)

Polyoxyethylene (30) stearyl ether 0.6

Lauryldimethylamineoxide0.5

Vegetable Squalane 0.1

Water Soluble Collagen 1.0

  (Brand name Neptigen atelo type, Ichimaru parcos Co., Ltd. product)

Methylparaben 0.1

Benzalkonium Chloride 0.1

Citric Acid 0.5

Diethanolamine 1.0

Perfume Composition C 0.1

Ethanol 20.0

Purified water balance

 Total 100.0

Example I-10

Trigger hair treatment

The hair treatment of the following prescription was prepared based on the conventional method, and it filled in the trigger type container made from PET. In addition, pH was adjusted to 4.3.

Composition mass (%)

Gallic acid-3,5-diglucoside 1.0

Gallic acid-3-glucoside 0.012

Polyoxyethylene (60) Phytosterol 1.5

Gallic acid 0.001

Sodium sulfate 0.001

Lauryldimethylaminoacetic acid betaine 1.5

Stearyltrimethylammonium Chloride 2.0

Polyoxypropylene (9) diglyceryl ether 1.0

Propylene Glycol4.0

Polyoxyethylene-methyl polysiloxane copolymer 1.0

Hydrolyzed Silk Liquid 1.0

  (Brand name Silken G Soluble S, made in Ichimaru Parcos Co., Ltd.)

Hydroxypropyl Chitosan Liquid 1.0

  (Brand name Quito filter, Ichimaru Parcos made)

Methylparaben 0.05

Sodium Pyrophosphate Anhydrous 0.05

Benzoic Acid 0.05

Sodium benzoate 0.05

Monoethanolamine 0.5

Proper amount of citric acid

Sodium Citrate

Ethanol 20.0

Fragrance Composition D 0.05

Purified water balance

Total 100.0

Example I-11

The gel of the following prescription was prepared based on the conventional method, and it filled into the PET pump type container which mixed the ultraviolet absorber. In addition, pH was adjusted to 4.4 and the viscosity was adjusted to 1,500-3,000 Pa.s.

Composition mass (%)

Gallic acid-3,5-diglucoside 0.5

Gallic acid-3-glucoside 0.001

Polyoxyethylene (6) Phytosterol 0.5

Rothmarisan 0.5

Sodium sulfate O0.OO1

Stearyltrimethylammonium Chloride 2.5

Polyoxyethylene (40) hardening perm oil 3.0

Silicone Emulsion 5.0

(Brand name FZ-4188, Nippon Unicar Co., Ltd. product)

Polyoxyethylene-methyl polysiloxane copolymer 1.0

Chamomile X 1.0

Barpa Leaf X 1.0

Decaglyceryl Monoisostearate 2.0

Dihydroxybenzophenone 0.1

Monoethanolamine 0.5

Hydroxyethyl Cellulose

Methylparaben 0.1

Benzoic acid 0.2

Sodium Pyrophosphate Anhydrous 0.2

Sodium sulfite 0.1

Glycolic Acid

Dibutylhydroxytoluene 0.001

Ethanol 20.0

Fragrance Composition A 0.05

Purified water balance

Total 100.0

Example I-12

Pump Dispenser Hair Mist

The hair mist of the following prescription was prepared based on the conventional method, and it filled into the polyethylene pump dispenser container. In addition, pH was adjusted to 5.0.

Composition mass (%)

Gallic acid-3,5-diglucoside 0.5

Polyoxyethylene (4) Phytosterol 0.1

Tetraoleic acid polyoxyethylene (40) sorbet 1.5

Isostearic Acid Dimethylaminopropylamide 0.1

Tannic Acid 0.1

Sodium sulfate 0.001

N- palm oil fatty acid acyl L-arginine ethyl DL-pyrrolidone carboxylate

2.0

Stearyltrimethylammonium Chloride0.5

Diisostearate Decaglyceryl 2.0

Emulsified Wax * 5.0

70% sorbet 1.0

Birch X 1.0

Polyoxyethylene-methyl polysiloxane copolymer 0.5

Blueberry X 0.5

Methylparaben 0.3

Benzoic acid 0.2

Monoethanolamine 0.5

Proper amount of citric acid

Sodium Citrate

Fragrance Composition E 0.2

Ethanol 15.0

Purified water balance

Total 100.0

*: 5 parts of carnauba wax, 7 parts of polyoxyethylene (15) lauryl ether, and 88 parts of purified water were emulsified at 90 degreeC (average particle diameter 100mm).

Example I-13

Aerosol foam

The aerosol foam of the following prescription was prepared based on the conventional method. In addition, the container used the pressure-resistant cylinder made from aluminum.

Composition mass (%)

(Stock)

Gallic acid-3,5-diglucoside 1.0

Polyoxyethylene (25) Phytosterol 2.0

Sodium sulfate 0.005

Cationic Cellulose 0.4

  (Product name XK-503, product made by Lion Corporation)

Dipropylene Glycol 6.0

Stearyltrimethylammonium Chloride 2.5

Amino modified silicone 2.0

  (Product name SF8452C, product made by Toray Dow Corning Silicone Co., Ltd.)

Polyoxyethylene (60) hardened castor oil 2.0

Hydrolyzed Keratin 1.0

N- palm oil fatty acid acyl L-arginine ethyl dl-pyrrolidone carboxylate

0.5

Trimethyl glycine (trade name Aqua Dew AN-100, Ajinomoto Co., Ltd.)

0.5

Carboxyvinyl Polymer 0.5

Triethanolamine liquid (30% aqueous solution) 2.0

Siverter 1.0

Benzoic acid 0.2

Perfume Composition C 0.1

Ethanol 20.0

Purified water balance

Total Stock 92.0

(gas)

LPG Gas 8.0

Total 100.0

Example I-14

Hair wax

The hair wax of the following prescription was prepared based on the conventional method, and it filled into the polypropylene chair type container which knead | mixed the antistatic agent and the ultraviolet absorber.

Composition mass (%)

Gallic acid-3,5-diglucoside 2.0

Polyoxyethylene (30) Phytosterol 1.0

Salicylic Acid 0.1

Dimyristyl Dimethylammonium Chloride 3.0

Diisostearate Decaglycerol 5.0

Carboxyvinyl Polymer 0.5

Xanthan Gum 0.25

Water soluble solid silicone (brand name KF-6004, Shin-Etsukagaku Kogyo Co., Ltd. product)

2.0

Silicone Powder 1.0

  (Brand name Tos Pearl 2000B, product made by GE Toshiba Silicone Co., Ltd.)

Hydrolyzed Silk Liquid 0.5

  (Brand name Silken G Soluble S, made in Ichimaru parcos Co., Ltd.)

Vaseline 3.0

Squalane 2.0

Candelilla Wax 1.0

Apple X 2.0

Polyoxypropylene (14) diglyceryl 4.0

Methylparaben 0.1

Benzoic acid 0.2

Sodium sorbate 0.1

Esodium tetrasodium 0.05

Diethanolamine 1.0

Fragrance Composition B 0.05

Ethanol 5.0

Purified water balance

Total 100.0

Example I-15

Gel

The gel of the following prescription was prepared based on the conventional method, and it filled into the polypropylene tube container which knead | mixed the antistatic agent and the ultraviolet absorber.

Composition mass (%)

Gallic acid-3,5-diglucoside 0.5

Gallic acid-4-mannoside 0.02

Polyoxyethylene (40) Phytosterol 1.0

Stearyltrimethyl Ammonium Chloride 5.0

Alkyl Modified Carboxyvinyl Polymer 0.5

Xanthan Gum 0.25

Silicone paste (brand name KSG-21, Shin-Etsukagaku Kogyo KK) 5.0

Water soluble solid silicone (brand name KF-6004, Shin-Etsukagaku Kogyo Co., Ltd. product)

2.0

Silicone Powder 1.0

  (Brand name Tos Pearl 2000B, made by GE Toshiba Silicone Co., Ltd.)

Hydrolyzed Silk Liquid 0.5

Polyoxyethylene (20) Stearyl Ether 4.0

Methylparaben 0.1

Benzoic acid 0.3

Isophthalaldehyde 0.01

Benzalkonium Chloride 0.1

Triethanolamine 2.5

Fragrance Composition B 0.05

Ethanol 15.0

Purified water balance

Total 100.0

Example I-16

shampoo

The shampoo of the following prescription was prepared based on the conventional method, and was filled in the polypropylene pump container which knead | mixed the antistatic agent and the ultraviolet absorber.

Composition mass (%)

Methyl Gallate-3,5-diglucoside 0.5

Gallic acid propyl-3-mannoside 0.01

Polyoxyethylene (30) Phytosterol 0.3

Behenyltrimethylammonium chloride 0.5

Monoisostearic acid POE (30) hardening perm oil 1.0

Sodium sulfate 0.001

Sodium Lauryl Ether Sulfate 10.0

α-olefinsulfonic acid sodium 5.0

Fatty acid diethanolamide 5.0

Alkyl amidopropyl betaine 5.0

High Polymerization Dimethyl Silicone 3.0

  (Product name BY11-003, product made by Toray Dow Corning Silicone Co., Ltd.)

Cationic cellulose (brand name XK-503, Lion Corporation) 0.5

Distearic Acid Ethylene Glycol 2.0

Aloe x 0.2

Sodium benzoate 0.8

Monoethanolamine 1.5

Fragrance Composition A 0.05

Purified water balance

Total 100.0

Example I-17

Rinse

The rinse of the following prescription was prepared based on the conventional method, and was filled in the polypropylene pump container which knead | mixed the antistatic agent and the ultraviolet absorber.

Composition mass (%)

Gallic acid-3,5-diglucoside 0.5

Gallic acid-3-glucoside 0.02

Polyoxyethylene (40) Phytosterol 1.5

Stearyltrimethyl Ammonium Chloride 1.0

Distearyldimethylammonium Chloride0.5

Cetostearyl Alcohol 3.0

POE (5) stearyl ether 1.5

Floating Paraffin 1.0

Cyclomethicone 0.5

  (Product name DC246, product made by Toray Dow Corning Silicone)

Dimethyl Silicone 5.0

  (Brand name SH200-500cs, product made by Toray Dow Corning Silicon Co., Ltd.)

Mallow x 0.2

Methylparaben 0.1

Monoethanolamine 0.5

Sodium benzoate 0.4

Perfume Composition C 0.1

Purified water balance

Total 100.0

Example I-18

Hair cream

The following A oil phase part and B water phase part were melt | dissolved at 70 degreeC, respectively, A oil phase part was added to B water phase part, and it emulsified uniformly, C was added, cooling further, the cream of the following prescription was prepared, and it filled into the aluminum lynate tube. .

Composition mass (%)

(A upper part)

Squalane 5.0

Ethyl oleate 2.0

Myristic Octyldodecyl 1.5

Liquid Paraffin 1.0

Mono stearate polyethylene glycol (40EO) 3.0

Palm oil fatty acid sorbitan 2.0

Glycerin Monostearate 1.0

Cetostearyl Alcohol 1.0

Propylparaben 0.1

(B award part)

Gallic acid-3,5-dimaltoside 0.5

Gallic acid-4-maltoside 0.03

Polyoxyethylene (60) Phytosterol 0.5

Palmityltrimethylammonium Chloride 0.3

1,3-butylene glycol 2.5

Dipropylene Glycol 2.5

Monoethanolamine 0.5

Methylparaben 0.1

Sorbic acid0.1

Dipotassium glycylate acid 0.2

Gentiana X 0.1

Purified water balance

(C)

Fragrance Composition D 0.05

Total 100.0

Example I-19

Aerosol foam

The aerosol foam of the following prescription was prepared based on the conventional method, and it filled into the pressure-resistant container made from PET.

Composition mass (%)

(Stock)

Methyl Gallate-3,5-diglucoside 2.0

Methyl Gallate-3-Glucoside 0.005

Polyoxyethylene (30) Phytosterol 1.5

EO modified silicone 4.0

Pyroctonolamine 0.5

Ethyl oleate 3.0

Amphoteric Polymer 1.0

  (Brand name yukaformer 204, product made in Mitsubishi Kagaku)

Stearyltrimethyl Ammonium Chloride 0.5

POP (9) diglyceryl ether 1.5

Monooleic acid POE (20) sorbitan 0.5

Polyoxyethylene (30) stearyl ether 1.0

Monoethanolamine 2.5

Sorbic acid0.1

Benzoic acid 0.1

Fragrance Composition B 0.2

Ethanol 20.0

Purified water balance

Total 100.0

(gas)

LPG 10.0

DME 10.0

Total 100.0

In addition, fragrance composition A-E used by each said example conforms to fragrance composition A-E of Table 5-19 of Unexamined-Japanese-Patent No. 2003-95895.

As for Examples I-8 to 19, all of them were evaluated in the same manner as in Examples I-1 to 7, where the effects of preventing cracked hair and broken hair and a natural texture recovery effect were evaluated.

Examples II-1 to 7 and Comparative Examples II-1 to 12

The hair cosmetic of the composition shown to Tables 4 and 5 was prepared based on the conventional method, and evaluated by the following method. The results are written together in Tables 4 and 5.

[Assessment Methods]

Moist feeling, flexible, handling

20 panelists who damaged hair by hair dye or perm use 3g of hair cosmetics for less dry hair after towel drying, and before each use for moist feeling, softness and handling point of hair after use Compared. The results are shown based on the following evaluation criteria.

<Evaluation Criteria>

(Double-circle): More than 16 people in 20 answered that use after use is good

(Circle): 10-15 of 20 people answered that use after use is good

(Triangle | delta): 4-9 of 20 people answered that the use after use is favorable.

X: It was less than 3 names out of 20 that reply after use was good

CMC Natrix Repair Effect (Tensile Tester)

To 3 g of human hair bundles dyed with a commercially available bleaching agent, 0.2 g of a hair cosmetic was uniformly applied and naturally dried. Among them, ten were randomly picked out, and the unbroken number of ten was measured when pulled out at 100 g using a tensile tester (manufactured by Toyo Balwin).

CMC Natrix Repair Effect (SEM Observation)

To 3 g of human hair bundles dyed with a commercially available bleaching agent, 0.2 g of a hair cosmetic was uniformly applied and allowed to dry naturally. Among them, randomly picked out ten of them, using a tensile tester, pulled until the hair was broken, observed the broken spots by SEM (800 times), and repaired the hair condition shown in FIG. The state of the hair shown in the figure was made into the unrepaired hair, and it evaluated based on the following evaluation criteria.

<Evaluation Criteria>

○: 7 to 10 of 10 repaired hair

(Triangle | delta): 4-6 of 10 repaired hairs

×: 0 to 3 of 10 repaired hair

* 1: Product name SM8704C, product made by Toray Dow Corning Silicone Co., Ltd.

* 2: Product name promotion WK-H Seiwa Kase

The hair cosmetic of the following Examples 8-19 was prepared based on the conventional method of each formulation.

Example II-8 Hair Gel

Composition mass (%)

Gallic acid-3,5-diglucoside 1.0

Stearyltrimethyl Ammonium Chloride 3.0

Hydroxyethyl Cellulose 0.5

  (Brand name SE-900, Daisel Kagaku Kogyo Co., Ltd.)

Polyether modified silicone (manufactured by Shin-Etsu Chemical Co., Ltd., KF6012) 2.0

N-methacryloyloxyethyl N, N-dimethylaminoethyl-α-N-methylcarboxybetaine methacrylic acid alkyl ester copolymer 3.0

  (Brand name yukaformer 510, product made by Mitsubishi Kagaku Co., Ltd.)

Distearic acid triglyceryl 3.0

Polyoxyethylene (40) Cured Castor Oil 0.3

Dihydroxybenzophenone 0.1

Methylparaben 0.1

Triethanolamine 0.5

Spice A 0.2

Ethanol 10.0

Purified water balance

Total 100.0

Example II-9

Hair wax

Composition mass (%)

Gallic acid-3-glucoside 1.0

Tetraoleic acid polyoxyethylene (6) sorbet 3.0

Carboxyvinyl Polymer 0.5

  (Brand name Carbopol 940, good rich company made)

Benzalkonium Chloride 1.0

Xanthan Gum 0.3

EO modified silicone (brand name KF6004, Shin-Etsukagaku Kogyo Co., Ltd.) 2.0

Vaseline 3.0

Squalane 2.0

Candelilla Wax 1.0

Polyoxypropylene (9) diglyceryl ether 4.0

Dihydroxybenzophenone 0.1

Propylparaben 0.1

Methylparaben 0.3

Phenoxyethanol 0.5

Esodium tetrasodium 0.05

Triethanolamine 0.5

Ethanol 10.0

Spice B 0.2

Purified water balance

Total 100.0%

Example II-10

Hair Cream

Composition mass (%)

Gallic acid-3,5-diglucoside 1.0

Tristearic acid hexaglyceryl 3.0

Distearyldimethylammonium Chloride 3.0

Amino modified silicone 0.5

  (Brand name SM8704C, product made by Toray Dow Corning Silicone Co., Ltd.)

Methyl Polysiloxane (100,000 cst) 5.0

Liquid Paraffin 5.0

Paraffin Wax 3.0

Polyoxyethylene (40) hardening castor oil 2.0

3-methyl-1,3-butanediol 10.0

Dihydroxybenzophenone 0.1

Propylparaben 0.1

Methylparaben 0.3

Phenoxyethanol 0.5

Palm oil fatty acid sorbitan 2.0

Glycerin Monostearate 1.0

Propylene Glycol Monostearate 2.0

Triethanolamine 0.5

Ethanol 5.0

Spice C 0.2

Purified water balance

Total 100.0

Example II-11

Hair foam

Composition mass (%)

Gallic acid-3,5-diglucoside 1.0

Copper Gluconate 0.3

N-methacryloyloxyethyl N-methacrylic acid alkyl ester copolymer

3.0

  (Brand name yukaformer 204WL, DIA CHEMCO Co., Ltd.)

Polyether Modified Silicone 0.5

  (Product name KF6011, Shin-Etsukagaku Kogyo Co., Ltd. product)

3-methyl-1,3-butanediol 2.0

Tetrastearic acid polyoxyethylene (6) sorbet 3.0

Polyoxyethylene (60) Phytosterol 1.5

Stearic Acid Dimethylaminopropylamide 0.1

Stearyltrimethylammonium Chloride0.5

Methylparaben 0.3

Triethanolamine 0.1

Fragrance E 0.1

Ethanol 30.0

Liquefied Petroleum Gas 7.0

Purified water balance

Total 100.0

Example II-12

Hair foam

Composition mass (%)

Gallic acid-3,4-diglucoside 0.5

Zinc Gluconate 0.3

Polyether Modified Silicone 5.0

  (Product name KF6011, Shin-Etsukagaku Kogyo Co., Ltd. product)

3-methyl-1,3-butanediol 2.0

Cationized Cellulose 0.1

  (Product name LeoGuard GPS, product made by Lion Co., Ltd.)

N-palm fatty acid-L-glutamic acid 0.5

Cetyltrimethylammonium Chloride 1.0

Dioleic acid polyoxyethylene (8) erythritol 3.0

Polyoxyethylene (40) hardening castor oil 0.4

Methylparaben 0.3

Citric Acid 0.1

Spice D 0.1

Ethanol 20.0

Liquefied Petroleum Gas 7.0

Purified water balance

Total 100.0%

Example II-13

hair spray

[Stock]

Composition mass (%)

Gallic acid methyl ester-3,5-diglucoside 0.5

Iron Gluconate 0.3

Polyvinylpyrrolidone (K-30) 2.0

Tetraoleic acid polyoxyethylene (40) sorbet 3.0

Amino modified silicone 0.5

  (Brand name SM8704C, product made by Toray Dow Corning Silicone Co., Ltd.)

Cetyltrimethylammonium Chloride 1.0

Polyoxyethylene Cured Castor Oil (40) 0.5

Methylparaben 0.3

Spice B 0.1

Ethanol 90.0

Purified water balance

Stock solution 100.0

Furtherance(%)

The stock solution 50

Liquefied Petroleum Gas 30

Dimethyl ether 20

100 total

Example II-14

Hair water

Furtherance(%)

Gallic acid-3,5-diglucoside 1.0

Water Soluble Solid Silicone 0.5

  (Brand name KF6004, Shin-Etsukagaku Kogyo Co., Ltd.)

3-methyl-1,3-butanediol 2.0

Stearyltrimethylammonium Chloride0.5

Tetraoleic acid polyoxyethylene (60) sorbet 2.5

Polyoxyethylene (25) Phytosterol 1.0

Stearic Acid Dimethylaminopropylamide 0.4

Lauryldimethylamineoxide 0.2

Pyrrolidonecarboxylic acid sodium 1.0

Methylparaben 0.3

Glycolic acid 0.2

Sodium Pyrophosphate 0.3

Hydroxymethoxybenzophenonesulfonic acid0.1

Spice A 0.1

Ethanol 20.0

Purified water balance

Total 100.0

Example II-15

Wool

Composition mass (%)

Gallic acid-3-glucoside 1.0

Lauryltrimethylammonium Chloride 1.0

Amino Modified Silicone Emulsion 0.5

  (Brand name FZ4672, Nippon Unicar Co., Ltd. product)

Tristearic acid decaglyceryl 1.0

Monopentadecanoic Acid Glyceride 3.0

Acetic DL-α-Tocopherol 0.1

Palm oil fatty acid sorbitan 1.0

Sucrose myristic acid ester 0.5

Biotin 0.002

Succinic Acid 0.3

Frequent X 1.0

Hinokithiol 0.1

L-menthol 0.3

Spice B

99.5% ethanol balance

Total 100.0

Example II-16

Hair growth spray

Composition mass (%)

Gallic acid 3,5-diglucoside 1.0

Distearyldimethylammonium Chloride 1.0

Carboxyl Modified Silicone 1.0

  (Shin-Etsu Silicone, brand name X-22-3710, Shin-Etsukagaku Kogyo Co., Ltd. product)

Mono Pentadecanoic Acid Glyceride 1.0

Tetraoleic Acid POE (6) Sorbit 0.5

Amphoteric Polymer * 0.2

Ethyl oleate 0.1

Citric Acid 0.3

Sucrose Lauric Acid Ester 0.5

Spice A

L-menthol 0.1

99.5% ethanol balance

Total 100.0

N-methacryloylethyl N, N-dimethylammonium-α-N-methylcarboxybetaine alkyl methacrylate copolymer

Example II-17

shampoo

Composition mass (%)

Gallic acid-3,5-diglucoside 1

POE (3) lauryl ether sodium sulfate 15

Alkyldimethylamine Oxygen 2

POE alkyl ether 1

Diglyceryl Dioleate 1

POE Cured Pharma Oil 4 Fatty Acid Diethanolamide 5

POE Dioleate Methyl Glucoside 1

High Polymeric Methyl Polysiloxane / Polyether Modified Silicone Emulsion 3

(Shin-Etsu Silicone, brand name X-52-2262, Shin-Etsu Kagaku Kogyo Co., Ltd. product)

Wax 1

Cetostearyl alcohol 2

Cationized Cellulose 0.5

Copolymer of Dimethyldiallyl Ammonium Chloride, Acrylamide, Acrylic Acid

0.2

Pyroctonolamine 0.5

Benzalkonium Chloride 0.05

Glycerin 1

Butylene Glycol 0.5

Sodium sulfate 2

Sodium benzoate 1

Paraben 0.2

Methyl isothiazolinone and methylchloroisothiazolinone 0.01

Green No. 3 0.002

Spice A 0.5

Citric Acid 0.5

Purified water balance

Total 100.0

Example II-18

Hair conditioner

Composition mass (%)

Gallic acid-3,5-diglucoside 1.0

4-guanidinobutyllaurylamide 0.8

N- [3-alkyl (12,14) oxy-2-hydroxypropyl] -L-arginine 0.5

Polyethylene glycol (average molecular weight 5 million) 0.2

Behenic acid diethylaminoethylamide 0.2

Dimethyl Silicone (viscosity 1 million mm ² / s) 1.0

  (Product name SH200-1,000,000cs, product made by Toray Dow Corning Silicone Co., Ltd.)

Dimethyl silicone (viscosity 100,000 mm ² / s) 1.0

  (Product name SH200-100,000cs made in Toray Dow Corning Silicone Co., Ltd.)

Dimethyl Silicone (Viscosity 50mm ² / s) 1.0

  (Product name SH200-50cs, product made by Toray Dow Corning Silicone Co., Ltd.)

Diglycerin Isopalmitic Acid Ester Sebacic Acid Condensate 1.0

Glycine 0.7

Cetanol 1.5

Behenyl Alcohol 0.2

Oleyl Alcohol 0.3

Oleic Acid 0.2

Isostearic acid 0.2

Trimethylglycine 0.2

Arginine 0.3

Cysteine 0.3

Pentastearic Acid Hexaglyceryl 1.0

Monolauric sorbitan 0.1

Phosphoric Acid Proper Amount

Methyl paraoxybenzoate

Proper amount of paraoxybenzoic acid propyl

Spice B

Purified water balance

Total 100.0

pH3.4

Example II-19

Hair treatment

Composition mass (%)

Gallic acid-3-maltoside 1.0

Lauryltrimethylammonium Chloride 1.0

4-guanidinobutyllaurylamide 1.5

N-palm fatty acid acyl-L-arginine ester 0.5

Dimethyl silicone (viscosity 100,000 mm ² / s) 1.0

  (Product name SH200-100,00Ocs, product made by Toray Dow Corning Silicone Co., Ltd.)

Dimethylsilicone (viscosity 30mm ² / s) 1.5

  (Brand name SH200-30cs, product made by Toray Dow Corning Silicone Co., Ltd.)

Diglycerin Isopalmitic Acid Ester Sebacic Acid Condensate 1.5

Diglycerin Isotearic Acid Ester Sebacic Acid Condensate 0.7

Cetanol 1.5

Behenyl Alcohol 3.0

Stearyl Alcohol 2.0

Isostearic acid 0.2

Glycerin 3.0

Propylene Glycol 5.0

Diricinolic acid decaglyceryl 0.1

Monolauric sorbitan 0.1

Polyethylene glycol (average molecular weight 900,000) 0.4

Phosphoric Acid Proper Amount

Methyl paraoxybenzoate

Proper amount of paraoxybenzoic acid propyl

Spice B

Purified water balance

Total 100.0

Also about the said Examples II-8-19, all were evaluated about the moist feeling of a hair, softness, favorable handling property, and the repair effect of CMC and a matrix similarly to the said Example. In addition, the fragrance composition A-E used by the said Example and the comparative example is based on the fragrance composition A-E of Table 2-16 of Unexamined-Japanese-Patent No. 2003-267841.

Examples III-1 to 9 and Comparative Examples III-1 to 5

The hair lotion compositions shown in Tables 6 and 7 were prepared, and the color inhibitory effect and usability were evaluated by the following evaluation methods.

(1) Color inhibitory effect

The evaluation sample was placed in a colorless clear glass bottle having a capacity of 24 mL, and stored at 50 ° C. for 1 week. Ten evaluators evaluated this evaluation sample visually by the observation of the presence or absence of coloring under the tungsten lamp (500W), and determined the result in four steps according to the following evaluation criteria.

<Evaluation Criteria>

◎: The number of people of evaluator who said that there was not coloring 10

(Circle): The number of the evaluators who said there was no coloring is 7-9 people

(Triangle | delta): The number of the evaluators who said there was no coloring is 3-6 people

×: The number of people of evaluator who said that there was not coloring is less than two

(2) feeling

Ten evaluators applied the evaluation sample to hair or skin, evaluated the presence of stickiness or stiffness, and evaluated the evaluation results in four steps according to the following evaluation criteria. In addition, all the evaluators performed the hair color process.

<Evaluation Criteria>

(Double-circle): The number of the evaluators who said that there was no stickiness or stiffness is 9 or more

(Circle): The number of the evaluator who said there was no stickiness or stiffness 6-8 people

(Triangle | delta): The number of the evaluators who said that there was no stickiness or stiffness was 3-5 people.

X: The number of the evaluators who said that there was no stickiness and stiffness is less than two

Example III-10

The aerosol foam composition for styling of the following composition was prepared.

[pharmacy]

After mixing dimethyl polysiloxane and the component except liquefied petroleum gas, and filling this mixed liquid into the pressure-resistant aluminum barrel, dimethyl polysiloxane was filled and fixed with the aerosol valve. Finally, liquefied petroleum gas was filled to obtain a foaming agent.

Composition mass (%)

Cationized Cellulose * 2 0.2

N-palm fatty acid acyl-L-sodium glutamate * 3 0.2

Polyoxyethylene isostearyl ether * 4 0.7

Palmitic Acid Dimethylaminopropylamide 0.6

Dimethylpolysiloxane (100 mm ² / s) 3.0

Dimethylpolysiloxane (10 million mm ² / s) 1.0

Methyl Paraoxybenzoate 0.05

Tannic Acid * 5 0.3

Pyrrolidonecarboxylic acid sodium (50%) 0.4

Fragrance Composition B 0.05

Proper amount of L-lactic acid (adjusted to pH4.5)

Ethanol 15.0

Purified water balance

Liquefied Petroleum Gas (0.49 MPa) 7.0

Total 100.0

Example III-11

The aerosol foam composition for haircuts of the following compositions was prepared.

[pharmacy]

Components other than olive squalane, high polymerization methyl polysiloxane, sodium citrate, liquefied petroleum gas, and dimethyl ether were mixed, and then adjusted to pH 5.0 with sodium citrate to obtain a stock solution. After filling this undiluted | stock solution in the transparent pressure-resistant PET container, it filled with olive squalane and high polymerization methyl polysiloxane in order, and fixed it with the aerosol valve. Finally, it filled with liquefied petroleum gas and dimethyl ether in order, and obtained the foaming agent.

Composition mass (%)

Palm oil fatty acid dimethylaminopropylamide 0.3

3-methyl-1,3-butanediol 5.0

Olive Squalane 0.1

Polyoxyethylene stearyl ether * 6 0.2

Monopalmitic acid polyoxyethylene sorbitan * 7 0.4

Hamamelis extract * 8 0.5

High Polymeric Methyl Polysiloxane (Million mm ² / s) 1.5

Citric Acid 0.1

Sodium citrate (adjusted to pH 5.0)

Methyl paraoxybenzoate 0.15

Oxybenzone sulfonic acid 0.1

Ethanol 10.0

Purified water balance

Liquefied Petroleum Gas (0.29 MPa) 8.5

Dimethyl ether 1.5

Total 100.0

Example III-12

A barber aerosol foam agent of the following composition was prepared.

[pharmacy]

The following components were mixed and dissolved, and this mixed solution was filled in a non-aerosol-type pump foam container to obtain a non-aerosol foam.

Composition mass (%)

Diethylaminoethylamide stearate 1.0

Lauryldimethylamineoxide liquid * 9 0.5

Polyoxyethylene (30) Phytosterol * 44 1.5

Tetraoleic acid polyoxyethylene (40) sorbet 1.5

Cationic Polymer Compound * 10 1.0

Polyoxyethylene Cetyl Ether * 11 0.3

Amino Modified Silicone Emulsion * 12 2.5

Gallic acid-3,5-diglucoside * 1 0.5

Methyl paraoxybenzoate 0.1

Paraoxybenzoic Acid Profile 0.05

Oxybenzone sulfonic acid 0.1

Appropriate amount of DL-lactic acid (adjusted to pH4.0)

Perfume Composition C 0.15

Ethanol 23.0

Purified water balance

Total 100.0

Example III-13

The aerosol spray agent for hair care of the following composition was prepared.

[pharmacy]

The components except dimethyl ether were mixed and dissolved, and the mixed solution was filled in a pressure-resistant aluminum barrel, and then fixed with a tilting aerosol valve. Finally, dimethyl ether was filled to obtain an aerosol spray.

Composition mass (%)

DL-Pantothenyl Alcohol 0.5

Polyether Modified Silicone * 13 1.0

Behenic Acid Dimethylaminopropylamide 0.4

Gallic acid profile 0.1

Oxybenzone 0.1

Hydrolyzed Silk Liquid * 14 0.6

Hydroxypropyl Chitosan Liquid * 15 0.6

Phosphoric acid appropriate amount (adjusted to pH4.5)

Ethanol 10.0

Dimethyl ether 30.0

Purified water balance

Total 100.0

Example III-14

Gel for hair care of the following composition was prepared.

[pharmacy]

Hydroxyethyl cellulose was dispersed in propylene glycol, water was added and dissolved therein, and the remaining components were mixed. Furthermore, stirring was continued until the viscosity of the liquid came out. This composition was filled in a pump-type container and the gel was obtained.

Composition mass (%)

Hydroxyethyl Cellulose * 16 1.0

Stearic Acid Dimethylaminopropylamide 0.4

Palmitic Acid Dimethylaminopropylamide 0.2

Amino Modified Silicone Emulsion * 17 2.5

Polyoxypropylene (14) diglyceryl ether * 18 0.7

Propylene Glycol 3.0

Gallic acid-3,5-diglucosyl * 1 0.5

Rosemary Acid Modifier * 19 0.5

Citric Acid 0.1

Sodium Citrate 0.1

Sodium Pyrophosphate 0.05

Glycolic acid appropriate amount (adjusted to pH 4.0)

Fragrance Composition A 0.05

Dihydroxybenzophenone 0.05

Methyl paraoxybenzoate 0.1

Ethanol 25.0

Purified water balance

Total 100.0

Example III-15

The hair lotion agent of the following composition was prepared.

[pharmacy]

The following components were mixed and dissolved, and this composition was filled into a squeeze-type container having an outlet diameter of 2 mm to obtain a hair lotion agent.

Composition mass (%)

Dipropylene Glycol 1.5

Monoisostearic acid POE cured perm oil * 20 0.2

Polyoxyethylene (20) isostearyl ether * 21 0.5

Polyoxyethylene (30) Phytosterol * 44 0.1

Tetraoleic acid polyoxyethylene (40) sorbet 0.1

Stearic Acid Dimethylaminopropylamide 0.7

Dimethyl Silicone Emulsion * 22 0.8

Trimethylguricin * 23 0.3

Birch X * 24 1.0

Yukari X * 25 0.5

Black tea X * 26 0.5

Proper amount of L-gultamic acid (adjusted to pH 4.3)

Methyl paraoxybenzoate 0.1

Fragrance Composition E 0.3

Ethanol 15.0

Purified water balance

Total 100.0

Example III-16

The hair conditioner of the following composition was prepared.

[pharmacy]

In the state which heated (A) component to 80 degreeC and was stirring well, the mixed solution of (B) heated similarly to 80 degreeC was added stirring. It cooled to 50 degreeC, stirring this mixed solution, (C) component was added and the hair rinse agent was obtained. This emulsified average particle diameter was 2 micrometers, and the viscosity in 25 degreeC was 4.5 Pa.s when measured by the BL-type viscometer (No. 3 rotor, 12 rpm).

Composition mass (%)

(A)

Acetic lauric acid amidobutylguanidine * 27 0.1

Acetic acid myristic acid amido butyl guanidine * 28 0.1

N- [3-alkyl (12,14) oxy-2-

Hydroxypropyl] -L-arginine hydrochloride solution * 29 0.1

Polyethylene Glycol * 30 0.2

Behenic acid diethylaminoethylamide 0.8

Diglycerin Isopalmitic Acid Ester Sebacic Acid Condensate * 31 1.0

Phosphoric acid proper amount (adjusted to pH 3.4)

Cetanol 1.5

Behenyl Alcohol 0.2

Oleyl alcohol 0.3

Oleic Acid 0.2

Isostearic acid 0.2

Glyceryl Monostearate * 32 0.1

Monolauric sorbitan * 33 0.1

Paraoxybenzoic Acid Profile 0.3

Dimethyl silicone (million mm ² / s) 1.0

Dimethyl Silicone (100,000 mm ² / s) 1.0

Dimethyl Silicone (50mm ² / s) 1.0

(B)

Glycine 0.7

Trimethylglycine * 23 0.2

Arginine 0.3

Gallic acid-3,5-diglucosyl * 1 0.5

Methyl Paraoxybenzoate 0.3

Purified water balance

(C)

Ethanol 2.0

Fragrance Composition B 0.5

Total 100.0

Example III-17

The hair rinse agent of the following composition was prepared.

[pharmacy]

In the state which heated (A) component to 70 degreeC and was stirring well, the mixed solution of (B) heated similarly to 70 degreeC was added stirring. It cooled to 50 degreeC, stirring this mixed solution, and added (C) component to obtain the hair rinse agent. PH of this composition was 3.3 and the emulsified average particle diameter was 1 micrometer, and the viscosity in 25 degreeC was 5 Pa.s when it measured by the BL-type viscometer (No. 3 rotor, 12 rpm).

Composition mass (%)

(A)

Paradimethylaminobenzoic acid-2-ethylhexyl * 34 0.05

4-tert-butyl-4'-methoxy-dibenzoylmethane * 35 0.05

Myristic acid isostearyl 1.0

Amphoteric cargo of methacrylic acid ester copolymer * 36 1.5

Palmitic Acid Dimethylaminopropylamide 2.0

Stearyl Alcohol 4.0

Polyoxyethylene (20) hardening castor oil * 37 1.0

Glycolic Acid 0.15

Propylene Glycol 5.0

(B)

Hamamelis extract * 8 0.5

Purified water balance

(C)

Ethanol 3.0

Fragrance Composition A 0.3

Total 100.0

Reference Example III-1

The skin care lotion of the following composition was prepared.

[pharmacy]

(A) component except purified water was heated at 70 degreeC, and the state stirred well, and the purified water in (A) component heated at 70 degreeC was added with stirring. The mixture of (B) component was added to this mixed solution, and it cooled to 50 degreeC, stirring. The mixed solution which consists of a fragrance | flavor of (C) component and another component was added, and the composition was obtained. After filling this composition with a pressure-resistant aluminum cylinder, it fixed with an aerosol valve, and finally filled with nitrogen gas so that the container internal pressure in 25 degreeC might be 0.5 Mpa, and the lotion for skincare was obtained.

Composition mass (%)

(A) Monoisostearic acid decaglyceryl * 38 2.0

Vegetable Squalane * 39 3.0

Polyoxyethylene-methyl polysiloxane copolymer * 40 1.0

Diethylaminoethylamide Stearate 0.3

Isostearic acid octyldodecyl * 41 1.0

Citric Acid 0.1

dl-α- Tocopherol 0.1

Methyl Paraoxybenzoate 0.2

Purified water 30.0

(B)

Concentrated Glycerin 3.0

Xanthan Gum * 42 0.05

(C)

L-Proline 0.5

Gallic acid-3,5-diglucoside * 1 0.5

Sodium Hyaluronate * 43 0.05

Black tea X * 26 0.25

Sodium citrate (adjusted to pH 5.5)

Fragrance Composition C 0.05

Ethanol 5.0

Purified water balance

Total 100.0

The coloring inhibitory effect of Examples III-10-17 and the reference example 1 was favorable, neither stickiness nor stiffness, and all the usability was favorable.

The raw material (brand name) used by the said Example III is shown below.

* 1 Diglucosyl gallic acid (product made by Mitsui Chemical Co., Ltd.)

* 2 Leoguard KGP (product made by Lion Corporation)

* 3 Amisoft CS-11 (Ajinomoto Co., Ltd.)

* 4 EMALEX 1810 (made by Nihon Emulsion Co., Ltd.)

* 5 lexod P (product made in Ichimaru Parcos Co., Ltd.)

* 6 EMALEX 630 (made by Nihon Emulsion Co., Ltd.)

* 7 NIKKOL TP-10 (product of Nikko Chemicals)

* 8 PARCOLEX Hamamelis B (product made in Ichimaru Parcos Co., Ltd.)

* 9 AROMOX DM12D-W (C) (product made by Lion Arc Co., Ltd.)

* 10H.C, polymer 2L (product made by Osaka Yukikagaku Kogyo Co., Ltd.)

* 11 EMALEX 125 (made by Nihon Emulsion Co., Ltd.)

* 12 SM-8704C (Toray Dow Corning Silicone Co., Ltd. product)

* 13 SH3773 (product made by Toray Dow Corning Silicone Co., Ltd.)

* 14 Silken G Soluble S (product made in Ichimaru Parcos Co., Ltd.)

* 15 Quito Filmer (product made in Ichimaru Parcos Co., Ltd.)

* 16 HEC Daicel SE900 (made by Daisel Kagaku Kogyo Co., Ltd.)

* 17 FZ-4672 (made by Nippon Unica Co., Ltd.)

* 18 SY-DP14T (product made by Sakamoto Yakuhin Kogyo Co., Ltd.)

* 19 Rosemary acid modifier obtained in Preparation Example 1 of Japanese Patent Laid-Open No. 2003-300811.

* 20 EMALEX RWIS-120 (product made in Nihon Emulsion Co., Ltd.)

* 21 EMALEX 1820 (product made in Nihon Emulsion Co., Ltd.)

* 22 KM903 (Shin-Etsu Silicone, Shin-Etsukagaku Kogyo Co., Ltd.)

* 23 amino coat (product of Asahi Kasei Kogyo Co., Ltd.)

* 24 Birch extract (made by Maruzen Seiyaku Co., Ltd.)

* 25 eucalyptus extract (made by Koei Kogyo Co., Ltd.)

* 26 black tea liquid (product made in Ichimaru Parcos Co., Ltd.)

* 27 C12A4G (made by Rengo Corporation)

* 28 C1416A4G (made by Nippon Kayaku Co., Ltd.)

* 29 Ami safe LMA-60 (made by Ajinomoto Co., Ltd.)

* 30 polyox WSRN-60KCG (product made by Amakol Corporation)

* 31 Sarakos DGS16 (made by Nisshin OIL Co., Ltd.)

* 32 NIKKOL MGS-B (product made by Nikko Chemicals)

* 33 NIKKOL SL-10 (product of Nikko Chemicals Corporation)

* 34 Escarol 507 (manufactured by Van Dyk)

* 35 parsol 1789 (product made in ジ ー ボ ド ル ー ル company)

* 36 Yuka former AM75-201 (Mitsubishi Kagaku Corporation made)

* 37 EMALEX HC-20 (product of Nihon Emulsion Co., Ltd.)

* 38 NIKKOL Decaglyn 1-IS (product made by Nikko Chemicals, Inc.)

* 39 Phytoscualan (made by Sophim Co., Ltd.)

* 40 TSF4441 (product made by GE Toshiba Silicone Co., Ltd.)

* 41 1SOD (product made in Shin-Eikagaku Co., Ltd.)

* 42 Monato gum DA (made by Dainippon Seiyaku Co., Ltd.)

* 43 Bio hyaluronic acid (Ichimaru Parcos Co., Ltd. product)

* 44 GO-4V (6 moles of E0 addition), G0-430V (30 moles of E0 addition), GO-440V (40 moles of E0 addition), G0-460V (60 moles of E0 addition) (Nikko Chemicals ( subject)

* Fragrance compositions A to E correspond to fragrance compositions A to E described in Tables 5 to 19 of JP-A-2003-95895.

Claims (9)

(A) Polyphenols and (B) Vegetable sterols are contained. Hair cosmetics characterized by the above-mentioned. The hair cosmetic according to claim 1, wherein (B) the vegetable sterols are alkylene oxide adducts of phytosterols. (C) Cationic surfactant is contained further, The hair cosmetics of Claim 1 or 2 characterized by the above-mentioned. The polyhydric alcohol having r hydroxyl groups (r is 4 or more) and s (2≤s≤r-2) partial esterifications according to any one of claims 1 to 3 Hair cosmetics characterized in that it further contains one esterified product. The hair of any one of Claims 1-4 which further contains (E) the amidoamine compound represented by following General formula (1), and (F) C2-C4 lower alcohol. Cosmetics. (Formula 1)

(In formula, R <^1> represents a linear or branched C1-C25 alkyl group, alkenyl group, or a hydroxy alkyl group, R <^2> represents a C1-C3 alkylene group, and R <^3> represents a C1-C3 alkyl group. .) (A) polyphenols, (C) cationic surfactant, and (D) polyhydric alcohols having r hydroxyl groups (r is 4 or more) and s (2≤s≤r-2) moieties of fatty acids having 8 or more carbon atoms A hair cosmetic comprising an esterified esterified product. (A) Polyphenols, (E) Amidoamine compound represented by following General formula (1), and (F) C2-C4 lower alcohol, The hair cosmetics characterized by the above-mentioned. (Formula 1)

(In formula, R <^1> represents a linear or branched C1-C25 alkyl group, alkenyl group, or hydroxy alkyl group, R <^2> is a C1-C3 alkylene group, R <^3> is a C1-C3 alkyl group Indicates.) The hair cosmetic according to any one of claims 1 to 7, wherein the polyphenols (A) are gallic acid or a derivative thereof. (A) Polyphenols containing (E) the amidoamine compound represented by following General formula (1), and (F) C2-C4 lower alcohol to the hair cosmetic containing polyphenols, (A) Polyphenols characterized by the above-mentioned Color suppression method of the hair cosmetic containing. (Formula 1)

(In formula, R <^1> represents a linear or branched C1-C25 alkyl group, alkenyl group, or a hydroxy alkyl group, R <^2> represents a C1-C3 alkylene group, and R <^3> represents a C1-C3 alkyl group. .)

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