WO2006006164A2 - Procede de production de combustibles a partir de dioxyde de carbone capture - Google Patents

Procede de production de combustibles a partir de dioxyde de carbone capture Download PDF

Info

Publication number
WO2006006164A2
WO2006006164A2 PCT/IL2005/000739 IL2005000739W WO2006006164A2 WO 2006006164 A2 WO2006006164 A2 WO 2006006164A2 IL 2005000739 W IL2005000739 W IL 2005000739W WO 2006006164 A2 WO2006006164 A2 WO 2006006164A2
Authority
WO
WIPO (PCT)
Prior art keywords
fuel
reaction
khco
hydrogen
fuel cell
Prior art date
Application number
PCT/IL2005/000739
Other languages
English (en)
Other versions
WO2006006164A3 (fr
Inventor
Amnon Yogev
Eliyahu Gamzon
Original Assignee
Aytec Avnim Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aytec Avnim Ltd. filed Critical Aytec Avnim Ltd.
Priority to AU2005261273A priority Critical patent/AU2005261273A1/en
Priority to EP05758924A priority patent/EP1778583A2/fr
Priority to CA002579133A priority patent/CA2579133A1/fr
Priority to US11/631,967 priority patent/US20080072496A1/en
Publication of WO2006006164A2 publication Critical patent/WO2006006164A2/fr
Priority to IL180634A priority patent/IL180634A0/en
Publication of WO2006006164A3 publication Critical patent/WO2006006164A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/12—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon dioxide with hydrogen
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Definitions

  • the present invention relates to a method for capturing carbon dioxide from a gaseous mixture containing carbon dioxide, e.g., from the atmosphere, and subsequently using this carbon dioxide for the production of fuel.
  • Greenhouse gases include carbon dioxide, methane, nitrous oxide and water vapor. While greenhouse gases occur naturally in the atmosphere, human activities also produce greenhouse gas emissions and are responsible for creating new ones. Carbon dioxide (CO 2 ) is the most common greenhouse gas released by human activities, resulting from the extensive use of fossil fuel (coal, petroleum, natural gas). One of the main challenges modern civilization is facing is the increase of carbon dioxide in the atmosphere, affecting the greenhouse effect and global warming. Another problem arises from the extensive use of fossil fuel thus diminishing the global fuel reserves.
  • Renewable energy sources that capture their energy from existing flows of energy, from on-going natural processes, such as sunshine, wind, flowing water, biological processes and geothermal heat flows, can be used for generating electricity, and there is a growing demand for methods of producing fuel using electricity.
  • the present invention relates to a method for producing combustible fuels from a gaseous mixture containing carbon dioxide, which comprises:
  • the method of the present invention enables the production of combustible fuels, using as preferred starting material the highly available atmospheric carbon dioxide, and returning the CO 2 produced by fuel combustion to the atmosphere, thus maintaining the equilibrium of the CO 2 in the atmosphere.
  • the method is based on well known in the art reactions such as thermal catalytic and electrochemical reactions, utilizing the reversibility of these reactions and carrying out the reverse reaction by modifying the operating pressure and/or the electrical voltage supplied to the process.
  • the reaction between the CO 2 and K 2 CO 3 in step (i) may be performed by bubbling air in water through an aqueous solution of K 2 CO 3 or by spraying droplets of K 2 CO 3 in aqueous solution into a stream of air. In both methods, the atmospheric CO 2 reacts with the K 2 CO 3 to form KHCO 3 according to the following reaction:
  • the CO 2 is released by heating the KHCO 3 to a temperature sufficient to liberate the CO 2 , according to the following reaction, thus recycling the K 2 CO 3 : 2KHCO 3 + Heat ⁇ » K 2 CO 3 + H 2 O + CO 2
  • the CO 2 is released from the KHCO 3 obtained by an electrochemical process, according to the following reaction:
  • step (ii) is then reacted with hydrogen to produce combustible fuels, such as methane and methanol.
  • the reaction of CO 2 and hydrogen is conducted as a thermal catalytic reaction.
  • One possible thermal catalytic reaction is a reverse operation of methane reforming.
  • methane is brought into contact with (excess) steam at high temperature and pressure, typically 800-1000°C and 30-40 bar, over a catalyst, to produce a mixture of H 2 , CO and CO 2 .
  • the process is usually carried out in fixed bed or fluidized bed membrane reactors, using a Ni as the preferred catalyst, because of its low cost, or a noble metal catalyst such as Ru, RIi 5 Pd, Ir or Pt.
  • the reverse methane reforming according to the invention is carried in the same type of reactors and using the same catalysts as in steam methane reforming, but using pressures varying according to the characteristics of the specific process, said pressure being always higher than the pressure used for the methane reforming.
  • the reaction of CO 2 and hydrogen according to the invention is an electrochemical process, such as a reverse operation of a fuel cell.
  • a fuel cell is an electrochemical energy conversion device that converts the chemical energy of a fuel, e.g. hydrogen, and an oxidant, e.g. oxygen, to electrical energy and heat, without combustion.
  • the device is similar to a battery but, unlike a battery, the fuel cell is designed for continuous replenishment of the reactants consumed, i.e., the fuel and the oxidant are typically stored outside of the fuel cell and transferred into the fuel cell as the reactants are consumed. In a typical fuel cell, the fuel is consumed at the anode and the oxidizer is consumed at the cathode.
  • fuel cells are usually classified by the type of electrolyte they use, and include phosphoric acid- based, proton exchange membrane, solid polymer, molten carbonate, solid oxide, alkaline, direct methanol, regenerative, zinc-air and protonic ceramic fuel cells.
  • a hydrocarbon such as methane
  • a reverse operation of a fuel cell is carried out whereby electricity is supplied to a fuel cell containing CO 2 , that reacts with hydrogen formed in situ by electrolysis of water, thus producing the desired hydrocarbon, e.g. methane fuel.
  • the electrical voltage supplied to the process is determined based on the characteristics of the specific process performed but it is always higher than the electrical voltage generated in the opposite process, namely, the regular operation of the fuel cell.
  • the electrochemical process corresponds to an inverted direct methanol fuel cell (DMFC) and the fuel obtained is methanol.
  • DMFC direct methanol fuel cell
  • DMFCs are low-temperature fuel cells operating at temperatures of 30-130 0 C and using liquid methanol as the electrolyte, according to the reaction:
  • the central component of DMFCs is the membrane electrode assembly, composed of membrane, catalyst and diffusion layers.
  • the membrane may be a polymer with acid groups that are capable of splitting off protons and has them migrate through the membrane.
  • the diffusion layer passes the fuels to the catalyst layer and removes the combustion products.
  • the electrochemical reaction takes place, in which chemical energy is converted into electric energy.
  • the catalyst is provided with additives to apply it as a paste on a substrate, and it is usually based on a noble metal, such as platinum and platinum/ruthenium.
  • the catalysts used for the reverse operation of the DMFC are the same used in the regular operation mode of the methanol fuel cell, and other parameters such as temperature and electrical voltage supplied to the process are determined based on the characteristics of the specific process performed.
  • the electrochemical process corresponds to an inverted molten carbonate fuel cell (MCFC) and the fuel obtained is a hydrocarbon, such as methane.
  • MCFCs are high-temperature fuel cell operating at temperatures of 600- 650 0 C, and thus can achieve higher fuel-to-electricity and overall energy use efficiencies than low temperature fuel cells.
  • the electrolyte used in MCFCs is an alkali carbonate such as Na 2 CO 3 , K 2 CO 3 , Li 2 CO 3 or combinations thereof, that may be retained in a ceramic matrix, e.g. Of LiAlO 2 .
  • the alkali carbonates melt into a highly conductive molten salt with carbonate ions providing ionic conduction through the electrolyte matrix.
  • Nickel and nickel oxide are adequate to promote reaction on the anode and cathode, respectively, and expensive catalysts (noble metals) are not required.
  • the fuel consumed in MCFCs is usually a natural gas, mainly methane, and in this case methane and steam are converted into a hydrogen-rich gas inside the fuel cell stack (a process called "internal reforming").
  • the overall reaction performed within the cell is: CH 4 + O 2 - ⁇ CO 2 + 2H 2
  • the operating conditions for the reverse operation of the MCFC are similar to these in the regular operation mode of this cell.
  • the exact conditions, as well as the voltage supplied to the process, are determined based on the characteristics of the specific process performed.
  • the methane or methanol obtained by the method of the invention may later be converted into longer hydrocarbons, using known chemical reactions.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Inert Electrodes (AREA)

Abstract

L'invention concerne un procédé destiné à produire des combustibles à partir d'un mélange gazeux contenant du dioxyde de carbone. Ce procédé consiste (i) à capturer du CO2 à partir de ce mélange gazeux au moyen de K2CO3, d'où la formation de KHCO3, (ii) à libérer le CO2 à partir du KHCO, puis (iii) à produire un combustible à partir du CO2 libéré par réaction avec l'hydrogène.
PCT/IL2005/000739 2004-07-12 2005-07-12 Procede de production de combustibles a partir de dioxyde de carbone capture WO2006006164A2 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU2005261273A AU2005261273A1 (en) 2004-07-12 2005-07-12 Method for producing fuel from captured carbon dioxide
EP05758924A EP1778583A2 (fr) 2004-07-12 2005-07-12 Procede de production de combustibles a partir de dioxyde de carbone capture
CA002579133A CA2579133A1 (fr) 2004-07-12 2005-07-12 Procede de production de combustibles a partir de dioxyde de carbone capture
US11/631,967 US20080072496A1 (en) 2004-07-12 2005-07-12 Method for Producing Fuel from Captured Carbon Dioxide
IL180634A IL180634A0 (en) 2004-07-12 2007-01-10 Method for producing fuel from captured carbon dioxide

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US58686904P 2004-07-12 2004-07-12
US60/586,869 2004-07-12

Publications (2)

Publication Number Publication Date
WO2006006164A2 true WO2006006164A2 (fr) 2006-01-19
WO2006006164A3 WO2006006164A3 (fr) 2009-05-07

Family

ID=35784255

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IL2005/000739 WO2006006164A2 (fr) 2004-07-12 2005-07-12 Procede de production de combustibles a partir de dioxyde de carbone capture

Country Status (7)

Country Link
US (1) US20080072496A1 (fr)
EP (1) EP1778583A2 (fr)
KR (1) KR20070067676A (fr)
AU (1) AU2005261273A1 (fr)
CA (1) CA2579133A1 (fr)
RU (1) RU2007105092A (fr)
WO (1) WO2006006164A2 (fr)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008017838A1 (fr) * 2006-08-08 2008-02-14 Itm Power (Research) Ltd. Synthèse de combustible
WO2008041938A1 (fr) * 2006-10-06 2008-04-10 Morphic Technologies Aktiebolag (Publ) Procédé de fonctionnement d'une pile à combustible au méthanol, et pile à combustible au méthanol avec catalyseur d'anode comprenant du tellure
FR2912421A1 (fr) * 2007-02-14 2008-08-15 Charzat Claude Maurice Procede de production de substituts aux produits carbohydrogenes d'origine fossile,assurant le recyclage total du dioxyde de carbone issu de leur utilisation
EP2057253A1 (fr) * 2006-09-02 2009-05-13 Hydrocarbons Unlimited, LLC Système et procédé pour la synthèse d'hydrocarbure
GB2457929A (en) * 2008-02-28 2009-09-02 David James Benton Process to extract carbon dioxide from air
US8366966B2 (en) 2006-10-25 2013-02-05 Engineuity Research And Development Ltd. Methods and systems for producing energy from carbon dioxide
EP2638951A1 (fr) 2012-03-14 2013-09-18 Artan Holding Ag Conditionnement de gaz combiné
EP2695946A1 (fr) 2012-08-09 2014-02-12 Methapower Biogas GmbH Procédé et installation destinés à la fabrication de diméthyléther
WO2014027116A1 (fr) * 2012-08-17 2014-02-20 Antecy B.V. Procédé pour la conversion d'une charge de départ gazeuse en composés organiques liquides
US8672037B2 (en) 2008-08-13 2014-03-18 Schlumberger Technology Corporation Plug removal and setting system
US9115467B2 (en) 2010-08-01 2015-08-25 Virdia, Inc. Methods and systems for solvent purification
US9410216B2 (en) 2010-06-26 2016-08-09 Virdia, Inc. Sugar mixtures and methods for production and use thereof
US9476106B2 (en) 2010-06-28 2016-10-25 Virdia, Inc. Methods and systems for processing a sucrose crop and sugar mixtures
US9512495B2 (en) 2011-04-07 2016-12-06 Virdia, Inc. Lignocellulose conversion processes and products
US9617608B2 (en) 2011-10-10 2017-04-11 Virdia, Inc. Sugar compositions
US9663836B2 (en) 2010-09-02 2017-05-30 Virdia, Inc. Methods and systems for processing sugar mixtures and resultant compositions
US11078548B2 (en) 2015-01-07 2021-08-03 Virdia, Llc Method for producing xylitol by fermentation

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8614364B2 (en) 2005-07-06 2013-12-24 Inentec Inc. Renewable electricity conversion of liquid fuels from hydrocarbon feedstocks
JP5580837B2 (ja) 2009-01-29 2014-08-27 プリンストン ユニバーシティー 二酸化炭素の有機生成物への変換
US9249064B2 (en) 2009-11-20 2016-02-02 Cri, Ehf Storage of intermittent renewable energy as fuel using carbon containing feedstock
US8784661B2 (en) * 2010-02-13 2014-07-22 Mcallister Technologies, Llc Liquid fuel for isolating waste material and storing energy
US8328888B2 (en) 2010-02-13 2012-12-11 Mcalister Technologies, Llc Engineered fuel storage, respeciation and transport
US8845877B2 (en) 2010-03-19 2014-09-30 Liquid Light, Inc. Heterocycle catalyzed electrochemical process
US8500987B2 (en) 2010-03-19 2013-08-06 Liquid Light, Inc. Purification of carbon dioxide from a mixture of gases
US8721866B2 (en) 2010-03-19 2014-05-13 Liquid Light, Inc. Electrochemical production of synthesis gas from carbon dioxide
US8524066B2 (en) * 2010-07-29 2013-09-03 Liquid Light, Inc. Electrochemical production of urea from NOx and carbon dioxide
US8845878B2 (en) 2010-07-29 2014-09-30 Liquid Light, Inc. Reducing carbon dioxide to products
WO2012018699A2 (fr) 2010-07-31 2012-02-09 Myriant Corporation Procédé de fermentation amélioré utilisable en vue de la production d'acides organiques
US8568581B2 (en) 2010-11-30 2013-10-29 Liquid Light, Inc. Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide
US8961774B2 (en) 2010-11-30 2015-02-24 Liquid Light, Inc. Electrochemical production of butanol from carbon dioxide and water
US9090976B2 (en) 2010-12-30 2015-07-28 The Trustees Of Princeton University Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction
US8562811B2 (en) 2011-03-09 2013-10-22 Liquid Light, Inc. Process for making formic acid
AU2012278949A1 (en) 2011-07-06 2014-01-16 Liquid Light, Inc. Reduction of carbon dioxide to carboxylic acids, glycols, and carboxylates
BR112013033326A2 (pt) 2011-07-06 2017-01-31 Liquid Light Inc captura de dióxido de carbono e conversão para produtos orgânicos
US9056275B2 (en) 2011-08-18 2015-06-16 Arizona Board Of Regents, A Body Corporate Of The State Of Arizona Acting For An On Behalf Of Arizona State University Capture and release of carbon dioxide
WO2013112619A1 (fr) 2012-01-23 2013-08-01 Battelle Memorial Institute Appareil et procédés de séparation et/ou séquestration
CN110382667A (zh) 2016-12-23 2019-10-25 碳工程有限公司 从稀薄的二氧化碳源合成燃料的方法和系统
CN117255714A (zh) 2021-01-15 2023-12-19 碳回收国际公司 甲醇合成反应器

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3959094A (en) * 1975-03-13 1976-05-25 The United States Of America As Represented By The United States Energy Research And Development Administration Electrolytic synthesis of methanol from CO2
US4609440A (en) * 1985-12-18 1986-09-02 Gas Research Institute Electrochemical synthesis of methane
US4609441A (en) * 1985-12-18 1986-09-02 Gas Research Institute Electrochemical reduction of aqueous carbon dioxide to methanol
US20020025457A1 (en) * 1998-10-27 2002-02-28 Dodd Peter Jeremy Electrical energy storage

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4919910A (en) * 1988-08-17 1990-04-24 Church & Dwight Co., Inc. Process for the production of potassium bicarbonate

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3959094A (en) * 1975-03-13 1976-05-25 The United States Of America As Represented By The United States Energy Research And Development Administration Electrolytic synthesis of methanol from CO2
US4609440A (en) * 1985-12-18 1986-09-02 Gas Research Institute Electrochemical synthesis of methane
US4609441A (en) * 1985-12-18 1986-09-02 Gas Research Institute Electrochemical reduction of aqueous carbon dioxide to methanol
US20020025457A1 (en) * 1998-10-27 2002-02-28 Dodd Peter Jeremy Electrical energy storage

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2451999A (en) * 2006-08-08 2009-02-18 Itm Power Fuel synthesis
GB2451999B (en) * 2006-08-08 2012-03-07 Itm Power Research Ltd Fuel synthesis
WO2008017838A1 (fr) * 2006-08-08 2008-02-14 Itm Power (Research) Ltd. Synthèse de combustible
EP2057253A1 (fr) * 2006-09-02 2009-05-13 Hydrocarbons Unlimited, LLC Système et procédé pour la synthèse d'hydrocarbure
EP2057253A4 (fr) * 2006-09-02 2011-12-07 Hydrocarbons Unltd Llc Système et procédé pour la synthèse d'hydrocarbure
WO2008041938A1 (fr) * 2006-10-06 2008-04-10 Morphic Technologies Aktiebolag (Publ) Procédé de fonctionnement d'une pile à combustible au méthanol, et pile à combustible au méthanol avec catalyseur d'anode comprenant du tellure
US8366966B2 (en) 2006-10-25 2013-02-05 Engineuity Research And Development Ltd. Methods and systems for producing energy from carbon dioxide
FR2912421A1 (fr) * 2007-02-14 2008-08-15 Charzat Claude Maurice Procede de production de substituts aux produits carbohydrogenes d'origine fossile,assurant le recyclage total du dioxyde de carbone issu de leur utilisation
GB2457929A (en) * 2008-02-28 2009-09-02 David James Benton Process to extract carbon dioxide from air
US8672037B2 (en) 2008-08-13 2014-03-18 Schlumberger Technology Corporation Plug removal and setting system
US9410216B2 (en) 2010-06-26 2016-08-09 Virdia, Inc. Sugar mixtures and methods for production and use thereof
US9963673B2 (en) 2010-06-26 2018-05-08 Virdia, Inc. Sugar mixtures and methods for production and use thereof
US10752878B2 (en) 2010-06-26 2020-08-25 Virdia, Inc. Sugar mixtures and methods for production and use thereof
US10760138B2 (en) 2010-06-28 2020-09-01 Virdia, Inc. Methods and systems for processing a sucrose crop and sugar mixtures
US9476106B2 (en) 2010-06-28 2016-10-25 Virdia, Inc. Methods and systems for processing a sucrose crop and sugar mixtures
US11242650B2 (en) 2010-08-01 2022-02-08 Virdia, Llc Methods and systems for solvent purification
US9115467B2 (en) 2010-08-01 2015-08-25 Virdia, Inc. Methods and systems for solvent purification
US10240217B2 (en) 2010-09-02 2019-03-26 Virdia, Inc. Methods and systems for processing sugar mixtures and resultant compositions
US9663836B2 (en) 2010-09-02 2017-05-30 Virdia, Inc. Methods and systems for processing sugar mixtures and resultant compositions
US9512495B2 (en) 2011-04-07 2016-12-06 Virdia, Inc. Lignocellulose conversion processes and products
US10876178B2 (en) 2011-04-07 2020-12-29 Virdia, Inc. Lignocellulosic conversion processes and products
US11667981B2 (en) 2011-04-07 2023-06-06 Virdia, Llc Lignocellulosic conversion processes and products
US9845514B2 (en) 2011-10-10 2017-12-19 Virdia, Inc. Sugar compositions
US9617608B2 (en) 2011-10-10 2017-04-11 Virdia, Inc. Sugar compositions
US9976194B2 (en) 2011-10-10 2018-05-22 Virdia, Inc. Sugar compositions
US10041138B1 (en) 2011-10-10 2018-08-07 Virdia, Inc. Sugar compositions
EP2638951A1 (fr) 2012-03-14 2013-09-18 Artan Holding Ag Conditionnement de gaz combiné
EP2695946A1 (fr) 2012-08-09 2014-02-12 Methapower Biogas GmbH Procédé et installation destinés à la fabrication de diméthyléther
WO2014027116A1 (fr) * 2012-08-17 2014-02-20 Antecy B.V. Procédé pour la conversion d'une charge de départ gazeuse en composés organiques liquides
US11078548B2 (en) 2015-01-07 2021-08-03 Virdia, Llc Method for producing xylitol by fermentation

Also Published As

Publication number Publication date
US20080072496A1 (en) 2008-03-27
CA2579133A1 (fr) 2006-01-19
AU2005261273A1 (en) 2006-01-19
KR20070067676A (ko) 2007-06-28
EP1778583A2 (fr) 2007-05-02
RU2007105092A (ru) 2008-08-20
WO2006006164A3 (fr) 2009-05-07

Similar Documents

Publication Publication Date Title
US20080072496A1 (en) Method for Producing Fuel from Captured Carbon Dioxide
Laosiripojana et al. Reviews on solid oxide fuel cell technology
US9819038B2 (en) Fuel cell reforming system with carbon dioxide removal
RU2379795C2 (ru) Спиртовые топливные элементы прямого действия, использующие твердые кислотные электролиты
JPH11250922A (ja) １００℃を超える温度で動作するポリマー膜電気化学的電池
EP2719008A1 (fr) Système hybride à pile à combustible et moteur à gaz/diesel alternatif
KR100786462B1 (ko) 산소 공급기를 사용하는 개질기 및 이를 포함하는 연료전지시스템
US20230046387A1 (en) Method and plant for producing hydrogen
Barbir Review of hydrogen conversion technologies
Gupta et al. Solid oxide fuel cell: A review
CN112993267A (zh) 基于对称双阴极结构固体氧化物燃料电池的直接甲烷干重整发电方法
KR102439950B1 (ko) 암모니아 연료 적용 복합 연료전지 시스템
CN105702992B (zh) 一种基于熔融碳酸盐燃料电池合成氨的方法
Dong et al. Ion-conducting ceramic membranes for renewable energy technologies
Farooque et al. Carbonate fuel cell technology and materials
Rai et al. Fuel Cell Utilization for Energy Storage
KR20160007821A (ko) 우수한 연료 효율을 갖는 직접탄소 연료전지 시스템
KR20200085971A (ko) 발전 및 합성가스 동시 생산에 의한 co2 발생 저감 고체산화물 연료전지, 그 제조 방법 및 운전 조건
JPH0665060B2 (ja) 溶融炭酸塩型燃料電池発電システム
RU225231U1 (ru) Устройство получения энергии
JP2005166486A (ja) 直接型燃料電池システム
Ghouse Fuel Cells and Their Applications
KR20210081620A (ko) 직접 액상수소 운반체 연료전지 시스템
YILDIZ et al. Department of Chemistry Hacettepe University Ankara 06532 Turkey
WO2023147123A1 (fr) Systèmes et procédés de production d'efuels et de produits chimiques de plateforme à partir de sources de combustion de combustible à base de carbone

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KM KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NG NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): BW GH GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU LV MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

WWE Wipo information: entry into national phase

Ref document number: 11631967

Country of ref document: US

WWE Wipo information: entry into national phase

Ref document number: 180634

Country of ref document: IL

NENP Non-entry into the national phase

Ref country code: DE

WWW Wipo information: withdrawn in national office

Ref document number: DE

WWE Wipo information: entry into national phase

Ref document number: 2005261273

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 2005758924

Country of ref document: EP

Ref document number: 1020077003333

Country of ref document: KR

Ref document number: 2007105092

Country of ref document: RU

ENP Entry into the national phase

Ref document number: 2005261273

Country of ref document: AU

Date of ref document: 20050712

Kind code of ref document: A

WWP Wipo information: published in national office

Ref document number: 2005261273

Country of ref document: AU

WWE Wipo information: entry into national phase

Ref document number: 2579133

Country of ref document: CA

121 Ep: the epo has been informed by wipo that ep was designated in this application
WWP Wipo information: published in national office

Ref document number: 2005758924

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 11631967

Country of ref document: US