Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
  • C08G64/20—General preparatory processes
  • C08G64/30—General preparatory processes using carbonates
  • C08G64/305—General preparatory processes using carbonates and alcohols
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
  • C08G64/02—Aliphatic polycarbonates
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
  • C08G18/40—High-molecular-weight compounds
  • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
  • C08G18/44—Polycarbonates
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
  • C08G64/02—Aliphatic polycarbonates
  • C08G64/0208—Aliphatic polycarbonates saturated
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
  • C08G64/20—General preparatory processes
  • C08G64/30—General preparatory processes using carbonates
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D169/00—Coating compositions based on polycarbonates; Coating compositions based on derivatives of polycarbonates

Definitions

• the present invention relates to a process for the preparation of aliphatic oligocarbonate polyols having terminal secondary hydroxyl groups by transesterification of organic carbonates with aliphatic polyols.
• oligocarbonate diols can be prepared from aliphatic polyols by reaction with phosgene, bis-chlorocarbonic acid esters, diaryl carbonates, cyclic carbonates or dialkyl carbonates. They are important precursors for the production of plastics, paints and adhesives. They are e.g. with isocyanates, epoxides, (cyclic) esters, acids or pressureure ⁇ reacted anhydrides.
• DE-A 101 56 896 discloses that polyols with secondary or tertiary hydroxyl groups can also be used for the preparation of aliphatic oligocarbonate polyols by transesterification of organic carbonates. None is described about a separate, stepwise feed of polyols with primary and those with secondary OH groups.
• oligocarbonate polyols having terminal secondary hydroxyl groups are of great interest as reactants for highly reactive (poly) isocyanates, for example in the preparation of aromatic polyisocyanate prepolymers or for controlling the urethanization reaction via different OH reactivities.
• the object of the present invention was therefore to provide an economically feasible process for preparing aliphatic oligocarbonate polyols having terminal secondary hydroxyl groups. This task could now be solved by the multi-stage process described below.
• the invention relates to a process for the preparation of aliphatic oligocarbonate polyols having secondary OH groups which have number-average molecular weights> 500 g / mol, in which
• the polymer thus formed is reacted with aliphatic polyols, which in each case have at least one secondary OH group per molecule, so that a product is obtained which contains on average> 5 mol% of secondary OH groups based on the sum of all having present OH groups.
• the polymer from stage A) preferably has on average less than 0.2 mol%, particularly preferably ⁇ 0.1 mol%, very particularly preferably 0-0.05 mol%, of OH groups.
• the oligocarbonate polyol obtained after step C) has a content of secondary OH groups based on the sum of all OH groups of preferably> 5 mol%, more preferably> 30 mol%, very particularly preferably 60-95 mol%.
• the oligocarbonate polyols obtained after step C) typically have average OH functionalities of> 1.80, preferably ⁇ 1.90, particularly preferably 1.90 to 5.0.
• organic carbonates for example, aryl, alkyl, alkylene carbonates or any desired mixtures thereof can be used in stage A).
• examples which may be mentioned are diphenyl carbonate (DPC), dimethyl carbonate (DMC), diethyl carbonate (DEC) and ethylene carbonate.
• DPC diphenyl carbonate
• DMC dimethyl carbonate
• DEC diethyl carbonate
• ethylene carbonate ethylene carbonate.
• Diphenyl carbonate dimethyl carbonate and diethyl carbonate used.
• diphenyl carbonate and dimethyl carbonate very particular preference is given to using diphenyl carbonate and dimethyl carbonate.
• Suitable aliphatic primary polyols are 1,4-butanediol, 1,5-pentanediol, 1,6-hexanediol, 1,7-heptanediol, 1,12-dodecanediol, cyclohexanedimethanol, 3-methyl-l, 5-pentanediol, 2, 4-diethyl-l, 5-pentanediol, bis (2-hydroxyethyl) ether, bis (6-hydroxyhexyl) ether, dimerdiol, trimethylolpropane, pentaerythritol or short-chain polyether polyols having primary hydroxyl groups and a number average molecular weight ⁇ 700 g / mol and mixtures thereof.
• aliphatic polyols having at least one secondary hydroxyl group which are used in step C) are typically compounds having 4 to 50 carbon atoms in the chain
• Polyols preferably have OH functionalities of 2 to 8, more preferably 2 to 4.
• Examples of such aliphatic polyols having at least one secondary hydroxyl group are 1,2-propanediol, 1,3-butanediol, 1,2-pentanediol, 1,3-petanediol, 1,4-pentanediol, 2,3-pentanediol, 2,4- Pentanediol, 1,2-hexanediol, 1,3-hexanediol, 1,4-hexanediol, 1,5-hexanediol, 2,3-hexanediol, 2,4-hexanediol, 2,5-hexanediol, 2,2,4-trimethylpentane -l, 3-diol, 2,2-bis (4-hydroxycyclohexyl) -propane, glucose, sorbitol, short-chain polyether polyols having secondary hydroxyl groups and a number average molecular weight
• Examples include the catalysts LiOH, Li 2 CO 3 , K 2 CO 3 , Mg 5 (OH) 2 (CO 3 ) 4 , titanium tetraalkoxides, dibutyltin dilaurate, dibutyltin oxide, bistributyltin oxide, yttrmm (HI) acetylacetonate and ytterbium (III) acetylacetonate called.
• transesterification catalysts preference is given to using Mg 5 (OH) 2 (CO 3 ) 4 , titanium tetraalcoholates, dibutyltin dilaurate, yttrium (IH) acerylacetonate and ytterbium (III) acetylacetonate.
• the erf ⁇ ndungswashe process is carried out at temperatures of typically 50 to 250 0 C, preferably 100 to 200 ° C and pressures of 0.01 to 10 bar (absolute), preferably 0.05 to 6 bar (absolute).
• Stage C) of the process according to the invention is carried out until the experimentally determined hydroxyl functionality has reached> 90%, preferably> 95% of the theoretical value.
• step C To accelerate the reaction in step C), it is possible to add again a transesterification catalyst and / or to drive the reaction at a pressure ⁇ 1013 mbar (absolute).
• the amount of organic carbonate or of the corresponding polyols used in step A) depends on the desired number average molecular weight (M n ) of the oligocarbonate polyol to be prepared.
• the organic carbonates in A) are always used in excess based on the existing primary OH groups of the polyols, so that even after step A) a substantially OH-free polymer can result with the above-mentioned OH group contents .
• the excess of the organic carbonate is 5 to 100 mol%, preferably 10 to 50 mol%, based on the necessary stoichiometry for the preparation of the theoretical OH-functional compound.
• the transesterification in stage A) of the process according to the invention of primary aliphatic polyol and organic carbonate can also be carried out in part steps, so that the organic carbonate is gradually added to the primary aliphatic polyol and, in the meantime, the by-product is removed at pressures below 1 bar (absolute) becomes. Likewise, a continuous addition of organic carbonate coupled with a continuous removal of the by-product is possible.
• the reaction time in step A) is 5 to 100 hours, preferably 10 to 80 hours.
• the reaction time in step C) is 1 to 50 hours, preferably 5 to 25 hours.
• the oligocarbonate polyols obtainable by the process according to the invention are particularly suitable for the production of coatings, dispersions, adhesions and sealings.
• the determination of the proportion of terminal secondary hydroxyl groups in the oligocarbonate diol, as well as the hydroxyl functionality was carried out by integral evaluation of ⁇ -NMR spectra of the corresponding products. In each case the ideal compound based on the selected stoichiometry was used as the target compound. First, the number average molecular weight (M n ) of each product was then calculated from the integrations of the proton resonances of the repeating units in the molecule. For this purpose, the signals of the methylene groups from the diols used were used, the methylene end group of the CH 2 -OH group of the oligocarbonatediol being used for standardization.
• the proportion of non-hydroxyl-functional end groups was determined via integration of the corresponding signals and normalization to the methylene end groups (essentially methyl ester and methyl ether groups).
• the sum of the molecular weight of the desired oligocarbonate diol and the molecular weight of the compounds having non-hydroxy-functional end groups (chain terminators) gives the total molecular weight.
• the proportions of chain terminators in the overall compound are calculated accordingly in mol%.
• the actual functionality to be determined represents the difference between theoretical maximum functionality and content of chain terminators.
• the proportion of terminal secondary hydroxyl groups was determined analogously.
• the hydroxyl number (OHN) was determined according to DIN 53240-2.
• the number average molecular weight (M n ) is calculated from the relationship between hydroxyl number and functionality.
• the viscosity was determined by means of a VISKOLAB LC-3 / ISO rotational viscometer from Physika, Germany in accordance with DIN EN ISO 3219
• the resulting oligocarbonate had a hydroxyl number of 0 and thus a hydroxyl concentration of ⁇ 0.05 mol%.

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• Chemical & Material Sciences (AREA)
• Organic Chemistry (AREA)
• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Materials Engineering (AREA)
• Engineering & Computer Science (AREA)
• Life Sciences & Earth Sciences (AREA)
• Wood Science & Technology (AREA)
• Polyesters Or Polycarbonates (AREA)
• Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
• Medicinal Preparation (AREA)
• Sealing Material Composition (AREA)
• Paints Or Removers (AREA)
• Adhesives Or Adhesive Processes (AREA)
• Particle Accelerators (AREA)
• Apparatus Associated With Microorganisms And Enzymes (AREA)
• Mechanical Pencils And Projecting And Retracting Systems Therefor, And Multi-System Writing Instruments (AREA)

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• 2004
  • 2004-07-01 DE DE102004031900A patent/DE102004031900A1/de not_active Withdrawn
• 2005
  • 2005-06-18 KR KR1020077002457A patent/KR20070036163A/ko not_active Withdrawn
  • 2005-06-18 AT AT05754717T patent/ATE458774T1/de not_active IP Right Cessation
  • 2005-06-18 PT PT05754717T patent/PT1765909E/pt unknown
  • 2005-06-18 WO PCT/EP2005/006602 patent/WO2006002787A1/de not_active Ceased
  • 2005-06-18 CN CN2005800225432A patent/CN1980979B/zh not_active Expired - Fee Related
  • 2005-06-18 CA CA002572487A patent/CA2572487A1/en not_active Abandoned
  • 2005-06-18 ES ES05754717T patent/ES2340048T3/es not_active Expired - Lifetime
  • 2005-06-18 DE DE502005009093T patent/DE502005009093D1/de not_active Expired - Lifetime
  • 2005-06-18 EP EP05754717A patent/EP1765909B1/de not_active Expired - Lifetime
  • 2005-06-18 JP JP2007519654A patent/JP2008505230A/ja active Pending
  • 2005-06-24 US US11/165,699 patent/US20060004176A1/en not_active Abandoned

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