WO2005120826A1 - Récipient d'emballage, laminé d'emballage utilisation d'une impression en couleur - Google Patents

Récipient d'emballage, laminé d'emballage utilisation d'une impression en couleur Download PDF

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Publication number
WO2005120826A1
WO2005120826A1 PCT/SE2005/000888 SE2005000888W WO2005120826A1 WO 2005120826 A1 WO2005120826 A1 WO 2005120826A1 SE 2005000888 W SE2005000888 W SE 2005000888W WO 2005120826 A1 WO2005120826 A1 WO 2005120826A1
Authority
WO
WIPO (PCT)
Prior art keywords
colour
print
transparent
colour print
food product
Prior art date
Application number
PCT/SE2005/000888
Other languages
English (en)
Inventor
Linda Hall
Sara Ohlgren
Thomas Mattsson
Peter Öhman
Original Assignee
Tetra Laval Holdings & Finance S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tetra Laval Holdings & Finance S.A. filed Critical Tetra Laval Holdings & Finance S.A.
Priority to MXPA06013325A priority Critical patent/MXPA06013325A/es
Priority to EP05752157A priority patent/EP1768842A1/fr
Priority to BRPI0511644-9A priority patent/BRPI0511644A/pt
Priority to CA002569171A priority patent/CA2569171A1/fr
Priority to JP2007516428A priority patent/JP2008502547A/ja
Priority to US11/629,360 priority patent/US20080308564A1/en
Publication of WO2005120826A1 publication Critical patent/WO2005120826A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F1/00—Designs or pictures characterised by special or unusual light effects
    • B44F1/06—Designs or pictures characterised by special or unusual light effects produced by transmitted light, e.g. transparencies, imitations of glass paintings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F1/00—Designs or pictures characterised by special or unusual light effects
    • B44F1/06—Designs or pictures characterised by special or unusual light effects produced by transmitted light, e.g. transparencies, imitations of glass paintings
    • B44F1/066—Designs or pictures characterised by special or unusual light effects produced by transmitted light, e.g. transparencies, imitations of glass paintings comprising at least two transparent elements, e.g. sheets, layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44F—SPECIAL DESIGNS OR PICTURES
    • B44F1/00—Designs or pictures characterised by special or unusual light effects
    • B44F1/08—Designs or pictures characterised by special or unusual light effects characterised by colour effects
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/40—Applications of laminates for particular packaging purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
    • B65D75/52—Details
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/724—Permeability to gases, adsorption
    • B32B2307/7242—Non-permeable
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/70—Food packaging
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2203/00—Decoration means, markings, information elements, contents indicators

Definitions

  • the present invention relates to a flexible packaging container of a transparent packaging laminate, containing a coloured, liquid food product, the packaging container displaying, on a front and/or rear display surface, a colour print applied directly thereon.
  • the present invention also relates to a packaging laminate for the packaging container, as well as to the use of a colour print on such a packaging laminate.
  • a packaging container and a packaging laminate which obviate the above-discussed drawbacks and problems. It is a further object of the present invention to offer a flexible packaging container of a transparent packaging laminate containing a coloured, liquid food product, the packaging container displaying, on a front and/or rear display surface, a colour print directly applied thereon, the colour print giving a distinct and clear visible impression despite the impact of the coloured food product.
  • a flexible packaging container of a transparent packaging laminate containing a coloured, liquid food product the packaging container displaying, on a front and/or rear display surface, a colour print directly applied thereon, at least selected portions of said colour print being a transparent colour print which permits transparency for the food product and one or more colour shades in the transparent colour print being selected so that the visible impression thereof is enhanced or modified in cooperation with the colour of the food product proper.
  • the transparent colour print has an opacity of greater than 3, preferably greater than 4 and more preferably greater than 5.
  • An upper limit is in principle set by the value of a totally transparent film without colour print and, therefore, the opacity level is in practice at most 13, preferably at most 12 and most preferably at most 11.
  • the value 1 signifies total opacity and the higher the value, the greater will be the transparency.
  • the measurements are carried out using a reflectometer which measures in accordance with ISO 6504/AST E97/DLN 55984 and the opacity is calculated as the relationship between reflectance of a measurement object on a white background to reflectance of the measurement object on a black background with an angle of impingement of 45° and a reflection angle of 0°.
  • the transparent colour print constitutes a background for an artwork- or text print which is disposed on the same display surface.
  • the background which may be printed with different colour densities, permits the display of the coloured food product in a different and more attractive manner than prior art packages of transparent, flexible packaging laminate where a background is totally absent in order that the food product be visible in the regions between text/artwork.
  • the transparent colour print is a photographic print.
  • this be applied by means of a so-called process or screen printing technique, preferably with varying density between the half tone dots in order to obtain different colour intensities in one and the same artwork or one and the same background to artwork and/or text.
  • a so-called process or screen printing technique preferably with varying density between the half tone dots in order to obtain different colour intensities in one and the same artwork or one and the same background to artwork and/or text.
  • the entire colour spectrum can be obtained from four primary subtractive colours, viz. cyan, magenta, yellow and black.
  • printing inks are mixed in different shades and are applied. Examples of useable printing techniques are flexo, flexo process, off-set or rotogravure.
  • the transparent colour print forms a complete piece of artwork or part thereof.
  • a fruit, berry or vegetable representative artwork can be formed as a transparent colour print according to the present invention, in which event the visual impression of this printing ink is enhanced or modified in cooperation with the colour of the food product proper.
  • the front and/or rear display surface may also display colour print which is directly applied thereon in selected areas and which affords opacity, and preferably constitutes a text and/or a piece of artwork and preferably includes a subjacent white colour layer and an upper colour layer.
  • This print will then constitute a substantially opaque piece of artwork and/or text on a background of the transparent colour print according to the present invention.
  • the transparent colour print is applied at least on the front display surface of the package, while a transparent colour print or a transparent or opaque artwork or opaque text print is disposed on its rear display surface, so that the transparent colour print or artwork or text print on the rear display surface clearly appears through both the coloured food product proper, the front display surface and its transparent colour print.
  • an "aquarium effect" can for example be obtained, or information such as slogans, so-called “fortune cookies” etc. can be read through both the coloured food product, the front display surface and its transparent colour print.
  • said transparent colour print is of the same colour as the food product, but of a different shade, whereby the visual impression of the transparent colour print is enhanced in cooperation with the colour of the food product proper.
  • a visual impression with more life can be obtained from a blue coloured food product in a transparent packaging container with a blue, transparent colour print.
  • the colour print is moreover photographic and displays different degrees of colour density and or different shades of blue, water-like effects can, for example, be achieved including bubbles, foam, water swell or the like.
  • said transparent colour print is of a different colour than the food product, whereby the visual impression of the transparent colour print, in cooperation with the colour of the food product proper, is modified to a third colour.
  • a yellow food product such as orange juice
  • a red, transparent colour print of varying colour density gives an orange visual impression which, for example, may represent the citrus fruit.
  • a yellow product in a packaging container with a blue, transparent colour print makes a green visual impression.
  • the packaging laminate for the package according to the invention preferably includes a gas barrier layer.
  • thermosealable olefin polymer preferably includes an outside layer of thermosealable olefin polymer, a first gas barrier layer of SiOx, coated on a first polymer carrier layer, and a second gas barrier layer of SiOx, coated on a second polymer carrier layer, as well as an interjacent polymer layer of greater thickness in relation to each one of the surrounding layers which is laminated between the two gas barrier-coated carrier layers.
  • a well functioning packaging laminate of this type is described in PCT/SE2003/001750, whose contents are hereby incorporated herein by reference. However, the present invention is not restricted to being utilised in connection with such a laminate.
  • a transparent packaging laminate with low gas barrier properties in which event use is instead made of a preserving agent in the product.
  • Other variations of transparent packaging laminates are also conceivable.
  • One preferred variation of the package according to the invention consists of a flexible bag which is fold-formed at the bottom, preferably of portion size and with a hole for a drinking straw or an opening arrangement.
  • the packaging container according to the invention is a bag or a "standing bag” or the like and is durable on handling and distribution and resistant to moisture and oxygen gas during long-term storage, because of the high quality packaging laminate, which in turn also imparts a high level of quality to seals and enjoys excellent gas barrier properties.
  • a further crucial advantage in packaging containers produced from the packaging laminate according to the invention is that they withstand boiling or thawing by means of microwaves, as well as retorting.
  • Fig. 1 is a cross sectional view of a preferred laminated packaging material according to the present invention
  • Fig. 2 shows one preferred example of a packaging container which has been produced from the packaging laminate according to the present invention.
  • Fig. 1 thus shows a transparent packaging laminate 10 including a first and second carrier layer 11; 12 which are films of a preferably prefabricated film of polyester or polyamide, such as a moulded film or preferably a mono- or biaxially oriented polyethylene terephthalate (PET), polyethylene naphthenate (PEN) or polyamide (PA), on which coatings of a thin gas barrier layer of SiOx 13; 14 have been applied.
  • a transparent packaging laminate 10 including a first and second carrier layer 11; 12 which are films of a preferably prefabricated film of polyester or polyamide, such as a moulded film or preferably a mono- or biaxially oriented polyethylene terephthalate (PET), polyethylene naphthenate (PEN) or polyamide (PA), on which coatings of a thin gas barrier layer of SiOx 13; 14 have been applied.
  • PET polyethylene terephthalate
  • PEN polyethylene naphthenate
  • PA polyamide
  • PECVD plasma enhanced chemical vapour deposition
  • the two SiOx layers are preferably turned to face towards the interior of the laminate and thus face towards one another. Between the two carrier layers which are coated with gas barrier layer, an interjacent layer 15 is laminated.
  • the interjacent layer 15 may consist of a relatively rigid olefin polymer, such as, for example, high density polyethylene (HDPE) or polypropylene (PP), or alternatively of a polymer which is soft and/or has elastomeric properties, such as, for example, polyethylene of very low density (VLDPE) or polyethylene of ultra low density (ULDPE).
  • a relatively rigid olefin polymer such as, for example, high density polyethylene (HDPE) or polypropylene (PP)
  • PP polypropylene
  • PP polypropylene
  • PP polypropylene
  • a polymer which is soft and/or has elastomeric properties such as, for example, polyethylene of very low density (VLDPE) or polyethylene of ultra low density (ULDPE).
  • VLDPE very low density
  • ULDPE ultra low density
  • the interjacent layer 15 consists of a mixture of high density polyethylene (HDPE) and polyethylene of very low density (VLDPE) or poly
  • the interjacent layer 15 is built up from at least two, preferably three sublayers of high density polyethylene (HDPE) and polyethylene of very low density (VLDPE) or polyethylene of ultra low density (ULDPE).
  • the interjacent layer is thicker than any of the surrounding layers in the packaging laminate and thereby serves as a spacer element between the two carrier layer films of oriented polymer.
  • the thickness of the interjacent layer does not constitute more than from about 30 to about 55 % of the total thickness of the packaging laminate, more preferably from about 35 to about 50 %.
  • the thickness of the carrier layers constitutes from about 5 to about 20 %, more preferably from about 5 to about 15 % of the total packaging laminate.
  • thermosealable olefin polymer preferably a low density polyethylene (LDPE) or a linear low density polyethylene (LLDPE) is applied and also includes so-called metallocen catalysed LLDPE (m-LLDPE), i.e. LLDPE polymers catalysed by means of a single seat catalyst.
  • LDPE low density polyethylene
  • LLDPE linear low density polyethylene
  • m-LLDPE metallocen catalysed LLDPE
  • LLDPE metallocen catalysed LLDPE
  • Other examples of alternative polymers for the outside layer in the packaging wall may be a polyethylene of medium high density (MDPE) or polypropylene (PP).
  • thermosealable olefin polymer On the outside of that carrier layer 12 which will constitute the inside wall in a packaging container produced from the packaging laminate, there is applied at least one layer 17 of a thermosealable olefin polymer, preferably a layer of LDPE or more preferably a layer of LLDPE and most preferably a first sublayer 17a of LDPE and a second, outer sublayer 17b of LLDPE.
  • the outside layers 16, 17 are each applied in a quantity of from about 10 to about 25 ⁇ m in order to obtain optimum thermosealing properties in relation to cost efficiency.
  • a tie layer of adhesive polymers, tie layers and primers which are known in the art.
  • tie layers and primers are adapted to the specific choices of polymer in the different layers and may be selected from polyolefins and modified polyolefins, preferably polyethylene-based polymers, such as, for example, LDPE and modified LDPE.
  • polyethylene-based polymers such as, for example, LDPE and modified LDPE.
  • use is preferably made of a polyethylene base polymer which is inoculation modified by means of an unsaturated alkoxy silan compound as described in USPS 5,731,092 which is hereby incorporated herein by reference. See in particular column 1 line 39 to column 3 line 21 and Examples 1 and 2.
  • tie layers are homo- or copolymers of LDPE or inoculated copolymers of polyethylene, inoculated with monomers which include functional groups of carboxyl- or glycidyl type, such as acrylic monomers or maleic acid anhydride monomers (MAH), for example ethylene (meta) acrylic acid copolymers (E(M)AA), ethylene, glycidyl (meta) acrylate copolymers (EG(M)A) or MAH inoculated polyethylene (MAH-g-PE).
  • monomers which include functional groups of carboxyl- or glycidyl type, such as acrylic monomers or maleic acid anhydride monomers (MAH), for example ethylene (meta) acrylic acid copolymers (E(M)AA), ethylene, glycidyl (meta) acrylate copolymers (EG(M)A) or MAH inoculated polyethylene (MAH-g-PE).
  • E(M)AA ethylene
  • the colour print according to the present invention is applied in conjunction to layer 16 of a thermosealable olefin polymer on that side of the packaging laminate which will constitute the outside wall in a packaging container produced from the packaging laminate.
  • Fig. 1 shows three variations of where this colour print can be applied. Furthest to the right is shown the preferred embodiment that the colour print 26a is applied on the tie layer 20 (or direct on the carrier layer 11), whereafter the outside layer 16 is laid thereon. As a result, the colour print is protected against wear etc. by the layer 16. In the central illustration is shown a less preferred variation where the colour print 26b lies outside the outside layer 16.
  • Fig. 2a and 2b show a preferred example of a packaging container 25 containing a coloured, liquid food product, the packaging container having been produced from the packaging laminate 10 according to the present invention.
  • the packaging container is particularly suitable for small drink packages for direct use by means of a drinking straw or the like.
  • One such packaging container typically has a volume of about 330 ml or less, preferably from about 100 to about 250 ml, for example about 125 ml, 200 ml or about 250 ml. It may be a bag of any configuration whatever, but is preferably cuneiform 21 so that it is simple to handle and dimensionally stable when placed on a shelf in the food hall or on a table or the like. In order to realise such a "cuneiform" configuration, the bottom portion 22 of the package is formed so that the transverse thermoseal 24 in the bottom is concealed under the triangular corner flaps 23 which are folded and sealed against the bottom of the package.
  • the colour print 2a has a colour print directly applied on the packaging container on a front display surface 27, the colour print including artwork, for example in the form of an orange 28 with leaves 29, a background 30 and a text 31.
  • the orange artwork 28 is a transparent colour print according to the invention, suitably in a red shade.
  • an orange juice is yellow the visual impression of the artwork 28 will be modified to become orange, in cooperation with this yellow orange juice.
  • the orange leaves 29 are formed from a transparent colour print according to the invention, suitably in a blue shade. When the contents are, as was mentioned above, yellow, the visual impression of the artwork 29 will be modified in cooperation with this yellow orange juice, so that the orange leaves appear as green.
  • the background 30 is also formed from a transparent colour print according to the invention, for example with a yellow shade which is enhanced/intensified in cooperation with the yellow contents of the packaging container.
  • the text 31 on the packaging container 25 a is made from a colour print affording opacity, preferably including a subjacent white colour layer as well as an upper colour layer.
  • a hole 37 for a drinking straw is also shown on the packaging container 25 a.
  • the variation of the packaging container 25a in Fig. 2a also has a colour print
  • the colour print being a transparent colour print according to the invention, in this case with a blue shade and representing waves and bubbles.
  • the visual impression of the colour print will be enhanced/intensified in cooperation with these contents.
  • artwork 34 On the rear display surface 33 of the packaging container, there is disposed artwork 34, in this case a starfish which may be of opaque character and which clearly appears through both the coloured food product, the front display surface 27 and its transparent colour print 32.
  • the background 35 to the artwork 34 is also disposed on the rear display surface 33 and may consist of a transparent colour print according to the present invention, or may be a colour print of an opaque character which is also seen through both the coloured food product, the front display surface 27 and its transparent colour print 32, which can give an "aquarium-like" effect.
  • An opening arrangement 38 in this case a pull tab, is also shown on the packaging container 25b.

Abstract

La présente invention concerne un récipient d'emballage souple (25a, 25b) de laminé d'emballage transparent (10) contenant un produit alimentaire liquide coloré, ce récipient d'emballage affichant une impression de couleur (28, 29, 30, 31, 32, 34, 35, 36) directement appliquée sur une surface d'affichage avant (27) et/ou arrière (33). Des parties sélectionnées au moins de cette impression en couleur sont une impression de couleur transparente (28, 29, 30, 32, 34, 35) qui permet de voir en transparence le produit alimentaire et une ou plusieurs ombres de couleur dans cette impression de couleur transparente sont sélectionnées de sorte que l'impression visuelle de celle-ci est renforcée ou modifier par la coopération avec la couleur du produit alimentaire. Cette invention concerne aussi un laminé d'emballage destiné à ce récipient d'emballage ainsi que l'utilisation d'une impression de couleur sur ce laminé d'emballage.
PCT/SE2005/000888 2004-06-14 2005-06-10 Récipient d'emballage, laminé d'emballage utilisation d'une impression en couleur WO2005120826A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
MXPA06013325A MXPA06013325A (es) 2004-06-14 2005-06-10 Un recipiente de empaque, unidad laminar de empaque y el uso de una impresion a color.
EP05752157A EP1768842A1 (fr) 2004-06-14 2005-06-10 Récipient d'emballage, laminé d'emballage utilisation d'une impression en couleur
BRPI0511644-9A BRPI0511644A (pt) 2004-06-14 2005-06-10 recipiente de acondicionamento flexìvel, laminado de acondicionamento transparente flexìvel, e, uso de uma impressão colorida transparente diretamente aplicada em um laminado de acondicionamento transparente flexìvel
CA002569171A CA2569171A1 (fr) 2004-06-14 2005-06-10 Recipient d'emballage, lamine d'emballage utilisation d'une impression en couleur
JP2007516428A JP2008502547A (ja) 2004-06-14 2005-06-10 包装容器、包装積層体、及びカラープリントの使用
US11/629,360 US20080308564A1 (en) 2004-06-14 2005-06-10 Package Container, Packaging Laminate and the Use of a Colour Print

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE0401508A SE528075C2 (sv) 2004-06-14 2004-06-14 Förpackningsbehållare, förpackningslaminat och användning av ett färgtryck
SE0401508-7 2004-06-14

Publications (1)

Publication Number Publication Date
WO2005120826A1 true WO2005120826A1 (fr) 2005-12-22

Family

ID=32653592

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE2005/000888 WO2005120826A1 (fr) 2004-06-14 2005-06-10 Récipient d'emballage, laminé d'emballage utilisation d'une impression en couleur

Country Status (12)

Country Link
US (1) US20080308564A1 (fr)
EP (1) EP1768842A1 (fr)
JP (1) JP2008502547A (fr)
KR (1) KR20070036063A (fr)
CN (1) CN1960864A (fr)
AR (1) AR049226A1 (fr)
BR (1) BRPI0511644A (fr)
CA (1) CA2569171A1 (fr)
MX (1) MXPA06013325A (fr)
SE (1) SE528075C2 (fr)
WO (1) WO2005120826A1 (fr)
ZA (1) ZA200609970B (fr)

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BRPI0511644A (pt) 2008-01-02
MXPA06013325A (es) 2007-02-02
JP2008502547A (ja) 2008-01-31
SE528075C2 (sv) 2006-08-29
SE0401508D0 (sv) 2004-06-14
CN1960864A (zh) 2007-05-09
KR20070036063A (ko) 2007-04-02
ZA200609970B (en) 2008-10-29
US20080308564A1 (en) 2008-12-18
SE0401508L (sv) 2005-12-15
CA2569171A1 (fr) 2005-12-22
AR049226A1 (es) 2006-07-05

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