WO2005097961A1 - Composition detergente - Google Patents

Composition detergente Download PDF

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Publication number
WO2005097961A1
WO2005097961A1 PCT/SE2005/000384 SE2005000384W WO2005097961A1 WO 2005097961 A1 WO2005097961 A1 WO 2005097961A1 SE 2005000384 W SE2005000384 W SE 2005000384W WO 2005097961 A1 WO2005097961 A1 WO 2005097961A1
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WO
WIPO (PCT)
Prior art keywords
silane
dispersion
detergent
acid
silica particles
Prior art date
Application number
PCT/SE2005/000384
Other languages
English (en)
Inventor
Peter Greenwood
Hans Lagnemo
Original Assignee
Akzo Nobel N.V.
Eka Chemicals Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel N.V., Eka Chemicals Ab filed Critical Akzo Nobel N.V.
Priority to CN2005800099656A priority Critical patent/CN1938413B/zh
Priority to BRPI0509106A priority patent/BRPI0509106B1/pt
Priority to CA2562256A priority patent/CA2562256C/fr
Priority to AT05722230T priority patent/ATE471365T1/de
Priority to EP05722230A priority patent/EP1733015B1/fr
Priority to JP2007507268A priority patent/JP4970246B2/ja
Priority to DE602005021868T priority patent/DE602005021868D1/de
Priority to AU2005230956A priority patent/AU2005230956B2/en
Publication of WO2005097961A1 publication Critical patent/WO2005097961A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0013—Liquid compositions with insoluble particles in suspension
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D11/00—Special methods for preparing compositions containing mixtures of detergents
    • C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/162—Organic compounds containing Si

Definitions

  • Detergent composition The present invention relates to a detergent composition comprising silane- modified silica particles.
  • Background of the invention Detergent compositions are currently being used in many cleaning applications including cleaning of hard and soft surfaces e.g. textile, and many other applications in household and industrial use.
  • US patent application 2002/0111287 A1 discloses a method of providing a detergent composition comprising hydrophilic silicate-containing particles.
  • these kinds of detergent compositions are not always sufficiently stable and may be liable to precipitation over time which of course is detrimental to the cleaning effect.
  • the invention relates to a method of preparing an aqueous detergent dispersion comprising mixing at least one silane compound, colloidal silica particles, and a detergent to form an aqueous detergent dispersion comprising silanized colloidal silica particles.
  • This method can be performed without environmental hazard and health problems for process operators handling the components of the forming aqueous detergent dispersion.
  • the mixing of silane and colloidal silica particles is preferably carried out continuously, preferably at a temperature from about 20 to about 95, more preferably from about 50 to about 75, and most preferably from about 60 to about 70 °C.
  • silane is slowly added to the silica particles under vigorous agitation at a temperature of about 60 °C and at a controlled rate, which suitably is from about 0.01 to about 100, preferably from about 0.1 to about 10, more preferably from about 0.5 to about 5, and most preferably from about 1 to about 2 silane molecules per nm 2 colloidal silica surface area (on the colloidal silica particles) and hour.
  • the addition of silane can be continued for any suitable time depending on the addition rate, amount of silane to be added, and degree of desired silanisation. However, the addition of silane is preferably continued for about 5 hours, more preferably for about 2 hours until a suitable amount of silane has been added.
  • the amount of added siiane to the colloidal silica particles suitably is from about 0.1 to about 6, preferably from about 0.3 to about 3, and most preferably from about 1 to about 2 silane molecules per nm 2 surface area of the colloidal silica particles.
  • silane may be particularly important when preparing highly concentrated silanized silica sol dispersions having a silica content up to about 80 wt%.
  • the silica content suitably is from about 20 to about 80, preferably from about 25 to about 70, and most preferably from about 30 to about 60 wt%.
  • colloidal silica particles and silane are mixed in a weight ratio of silane to silica of from about 0.01 to about 1.5, more preferably from about 0.05 to about 1 , and most preferably from about 0.1 to about 0.5.
  • the silane compound(s) is diluted before mixing it with the colloidal silica particles, preferably with water to form a premix of silane and water, suitably in a weight ratio of from about 1 :8 to about 8:1 , preferably from about 3:1 to about 1 :3, and most preferably from about 1.5:1 to about 1 :1.5.
  • the resulting silane-water solution is substantially clear and stable and easy to mix with the colloidal silica particles.
  • the mixing preferably continues from about 1 second to about 30 minutes, preferably from about 1 minute to about 10 minutes after the addition of silane stopped.
  • no organosiloxane or silicone are admixed in the aqueous dispersion for preparing a silicone coat on any silica particles or silane-modified silica particles
  • the mixing according to the invention may be carried out at a pH from about 1 to about 13, preferably from about 6 to about 12, more preferably from about 7.5 to about 11 , and most preferably from about 9 to about 10.5.
  • stable particularly in the context of a “stable dispersion” is meant a stable compound, mixture or dispersion that does not substantially gel or precipitate within a period of preferably at least about 2 months, more preferably at least about 4 months, and most preferably at least about 5 months at normal storage in room temperature, i.e.
  • the relative increase in viscosity of the dispersion two months after the preparation thereof is lower than about 100%, more preferably lower than about 50%, and most preferably lower than about 20%.
  • the relative increase in viscosity of the dispersion four months after the preparation thereof is lower than about 200%, more preferably lower than about 100%, and most preferably lower than about 40%o.
  • Colloidal silica particles also referred to as silica sols herein, may be derived from e.g. precipitated silica, micro silica (silica fume), pyrogenic silica (fumed silica) or silica gels with sufficient purity, and mixtures thereof.
  • colloidal silica particles and silica sols according to the invention may be modified and can contain other elements such as amines, aluminium and/or boron, which can be present in the particles and/or the continuous phase.
  • Boron-modified silica sols are described in e.g. US 2,630,410.
  • the aluminium modified silica particles suitably have an Al 2 0 3 content of from about 0.05 to about 3 wt%, preferably from about 0.1 to about 2 wt%.
  • the procedure of preparing an aluminium modified silica sol is further described in e.g. "The Chemistry of Silica", by Her, K. Ralph, pages 407-409, John Wiley & Sons
  • the colloidal silica particles suitably have an average particle diameter ranging from about 2 to about 150 nm, preferably from about 3 to about 50 nm, and most preferably from about 5 to about 40 nm.
  • the colloidal silica particles have a specific surface area from about 20 to about 1500, preferably from about 50 to about 900, and most preferably from about 70 to about 600 m 2 /g.
  • the colloidal silica particles preferably have a narrow particle size distribution, i.e. a low relative standard deviation of the particle size.
  • the relative standard deviation of the particle size distribution is the ratio of the standard deviation of the particle size distribution to the mean particle size by numbers.
  • the relative standard deviation of the particle size distribution preferably is lower than about 60 % by numbers, more preferably lower than about 30 % by numbers, and most preferably lower than about 15 % by numbers.
  • the colloidal silica particles are suitably dispersed in an aqueous solvent, suitably in the presence of stabilising cations such as K + , Na + , Li + , NH + , organic cations, primary , secondary, tertiary, and quaternary amines, or mixtures thereof so as to form an aqueous silica sol.
  • stabilising cations such as K + , Na + , Li + , NH + , organic cations, primary , secondary, tertiary, and quaternary amines, or mixtures thereof so as to form an aqueous silica sol.
  • dispersions comprising organic solvents, e.g.
  • aqueous silica sols without any further solvents are preferably used.
  • the colloidal silica particles are negatively charged.
  • the silica content in the sol is from about 20 to about 80, preferably from about 25 to about 70, and most preferably from about 30 to about 60 wt%. The higher the silica content, the more concentrated the resulting silanized colloidal silica dispersion.
  • the pH of the silica sol suitably is from about 1 to about 13, preferably from about 6 to about 12, and most preferably from about 7.5 to about 11. However, for aluminium-modified silica sols, the pH suitably is from about 1 to about 12, preferably from about 3.5 to about 1 1.
  • the silica sol preferably has an S-value from about 20 to about 100, more preferably from about 30 to about 90, and most preferably from about 60 to about 90. It has been found that dispersions with an S-value within these ranges can improve the stability of the resulting dispersion.
  • the S-value characterises the extent of aggregation of colloidal silica particles, i.e. the degree of aggregate or microgel formation.
  • the S-value has been measured and calculated according to the formulas given in J. Phys. Chem. 60(1956), 955-957 by Her, R.K. & Dalton, R.L.
  • the S-value depends on the silica content, the viscosity, and the density of the colloidal silica particles.
  • a high S-value indicates a low microgel content.
  • the S-value represents the amount of Si ⁇ 2 in percent by weight present in the dispersed phase of e.g. a silica sol.
  • the degree of microgel can be controlled during the production process as further described in e.g. US 5368833.
  • the silane compounds can form stable covalent siloxane bonds (Si-O-Si) with the silanol groups or be linked to the silanol groups, e.g. by hydrogen bondings, on the surface of the colloidal silica particles.
  • Si-O-Si stable covalent siloxane bonds
  • the silica particles are surface-modified.
  • Suitable silane compounds include tris-(thmethoxy)silane, octyl triethoxysilane, methyl triethoxysilane, methyl trimethoxysilane; isocyanate silane such as tris-[3- (trimethoxysilyl)propyl]isocyanurate; gamma-mercaptopropyl trimethoxysilane, bis-(3- [triethoxysilyl]propyl)poIysulfide, beta-(3,4-epoxycyclohexyl)-ethyl trimethoxysilane; silanes containing an epoxy group (epoxy silane), glycidoxy and/or a glycidoxypropyl group such as gamma-glycidoxypropyl trimethoxysilane, gamma-glycidoxypropyl methyldiethoxysilane, (3-glycidoxypropyl)trimethoxy silane
  • silanes which may be used in the present invention.
  • the most preferred silanes are epoxy silanes and silane compounds containing a glycidoxy or glycidoxypropyl group, particularly gamma-glycidoxypropyitrimethoxysilane and/or gamma glycidoxypropyltmethyldiethoxysilane.
  • detergent all ingredients the detergent may be made up of and which may be present in the prepared aqueous detergent dispersion. This may include surfactants, builders, co-builders, fillers, enzymes, pH regulators, ' hydrophilising agents, optical brighteners, anti-dye transition agents such as e.g.
  • bleaching chemicals such as e.g. hydrogen peroxide, activators, complexing agents, softening agents, perfumes, viscosity modifiers and other ingredients typically used in liquid detergents.
  • bleaching chemicals such as e.g. hydrogen peroxide, activators, complexing agents, softening agents, perfumes, viscosity modifiers and other ingredients typically used in liquid detergents.
  • any detergent ingredients as mentioned in WO01/83662,- US 6617303, EP 929639, WO
  • the detergent is added after the silanized or silane-modified silica particles have formed.
  • the detergent is preferably mixed with the silanized colloidal silica particles at room temperature.
  • the preferred detergent ingredients mixed with the silane-modified silica particles will in the following be described more in detail.
  • the detergent i.e. the total weight of the detergent ingredients is mixed to yield a total detergent content in the formed aqueous detergent dispersion of about 2 to about 80 wt%.
  • the total detergent content in the aqueous detergent dispersion is preferably from about 2 to about 10, most preferably from about 2 to about 5 wt%.
  • the total detergent content in the aqueous detergent dispersion is preferably from about 50 to about 80, most preferably from about 60 to about 70 wt%. According to yet another embodiment, the total detergent content in the aqueous detergent dispersion is preferably from about 30 to about 50, most preferably from about 40 to about 50 wt%.
  • the surfactants or interface-active substances may be anionic, non-ionic, cationic, amphoteric, and/or zwitterionic surfactants. Suitable anionic surfactants of the sulphonate type are preferably the known (C 9 - C ⁇ 3 )-alkylbenzenesulphonates, alpha-olefinsulphonates and alkanesulphonates.
  • esters of sulpho fatty acids or the disalts of alpha-sulpho fatty acids are also suitable.
  • anionic surfactants are sulphated fatty acid glycerol esters, which are mono-, di- and triesters and mixtures thereof, as are obtained during the preparation by esterification by 1 mol of monoglycerol with 1 to 3 mol of fatty acid or in the transesterification of triglycerides with 0.3 to 2 mol of glycerol.
  • Suitable alkyl sulphates are, in particular, the sulfuric monoesters of (C 12 -C 18 )-fatty alcohols, such as lauryl alcohol, myhstyl alcohol, cetyl alcohol or stearyl alcohol, and the fatty alcohol mixtures obtained from coconut oil, palm oil and palm kernel oil which may additionally comprise fractions of unsaturated alcohols, e.g. oleyl alcohol.
  • Further suitable anionic surfactants may for example be selected from alcohol- ethoxysulphates, alkali metal sarcosinates or alkyl ester sulfonates. Suitable further anionic surfactants are, in particular, soaps.
  • Saturated fatty soaps such as the salts of lauric acid, myhstic acid, palmitic acid, stearic acid, hydrogenated erucic acid and behenic acid, and, in particular, soap mixtures derived from natural fatty acids, e.g. coconut, palm kernel or tallow fatty acids, are suitable.
  • the anionic surfactants can be in the form of their sodium, potassium or ammonium salts, and in the form of soluble salts of organic bases, such as mono-, di- or triethanolamine.
  • the anionic surfactants are preferably in the form of their sodium or potassium salts, in particular in the form of the sodium salts.
  • Particularly preferred nonionic surfactants are alkyl alkoxylates, gluconamides and alkyl polyglycosides.
  • alkyl alkoxylates preference is given to using ethoxylated alcohols.
  • Preferred ethoxylated alcohols include, for example, Cn-alcohols having 3, 5, 7, 8 and 11 EO units, (C 12 -C ⁇ 5 )-alcohols having 3, 6, 7, 8, 10 or 13 EO units, (C 1 -C 5 )-alcohols having 4, 7 or 8 EO units, (C ⁇ 6 -C 18 )-alcohols having 8, 11 , 15, 20, 25, 50 or 80 EO units and mixtures thereof.
  • the degrees of ethoxylation given are statistical average values which may be an integer or a fractional number for a specific product.
  • fatty alcohol-EO/PO adducts such as, for example, the .RTM.Genapol grades 3970, 2909 and 2822 from Clariant GmbH.
  • Suitable surfactants are polyhydroxy fatty acid amides of the formula R 2 -CO-N(R 3 )-Z, in which R 2 CO is an aliphatic acyl radical having 6 to 22 carbon atoms, R 3 is hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms and Z is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 hydroxyl groups.
  • alkyl glycosides of the formula RO(G) x can be used, in which R is a primary straight-chain or methyl-branched, in particular methyl-branched in the 2-position, aliphatic radical having 8 to 22, preferably 12 to 18, carbon atoms, and G is a glycose unit having 5 or 6 carbon atoms, preferably glucose.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any desired number between 1 and 10; preferably 1.2 to 1.4.
  • alkoxylated preferably ethoxylated or ethoxylated and propoxylated, fatty acid alkyl esters, preferably having 1 to 4 carbon atoms in the alkyl chain.
  • suitable cationic surfactants are quaternary ammonium compounds, cationic polymers and emulsifiers of the type used in hair care preparations and also in fabric conditioners.
  • Cationic surfactants include the ammonium surfactants such as alkyldimethylammonium halogenides, and those surfactants having the formula [R 2 (OR 3 ) y ][R 4 (OR 3 ) y ] 2 R 5 N + X " wherein R 2 is an alkyl or alkyl benzyl group having from about 8 to about 18 carbon atoms in the alkyl chain, each R 3 is selected from the group consisting of -CH 2 CH 2 -, -CH 2 CH(CH 3 )-, -CH 2 CH(CH 2 OH)-, -CH 2 CH 2 CH 2 -, and mixtures thereof; each R 4 is selected from the group consisting of C C 4 alkyl, C C hydroxyalkyl, benzyl, ring structures formed by joining the two R 4 groups, -CH 2 CHOHCHOHCOR 6 CHOH- CH 2 OH wherein R 6 is any hexose or hexose polymer having a molecular
  • R 4 or is an alkyl chain wherein the total number of carbon atoms of R 2 plus R 5 is not more than about 18; each y is from 0 to about 10 and the sum of the y values is from 0 to about
  • Ampholytic surfactants can be incorporated into the detergent dispersion. These surfactants can be broadly described as aliphatic derivatives of secondary or tertiary amines, or aliphatic derivatives of heterocyclic secondary and tertiary amines in which the aliphatic radical can be straight chain or branched.
  • One of the aliphatic substituents contains at least about 8 carbon atoms, typically from about 8 to about 18 carbon atoms, and at least one contains an anionic water-solubilizing group, e.g. carboxy, sulfonate, sulfate. See U.S. Patent No.
  • Zwitterionic surfactants can also be incorporated into the detergent dispersion. These surfactants can be broadly described as derivatives of secondary and tertiary amines, derivatives of heterocyclic secondary and tertiary amines, or derivatives of quaternary ammonium, quaternary phosphonium or tertiary sulfonium compounds. See U.S. Patent No. 3,929,678 to Laughlin et al., issued December 30, 1975 at column 19, line 38 through column 22, line 48 for examples of zwitterionic surfactants.
  • Ampholytic and zwitterionic surfactants are generally used in combination with one or more anionic and/or nonionic surfactants.
  • the builders are preferably crystalline alumino silicates, alkali metal carbonates, bicarbonates, sesquicarbonates, phosphates such as alkali metal orthophosphates, alkali metal pyro phosphates and alkali metal polyphosphates such as tripolyphosphates, ammonium, crystalline phyllosilicates, crystalline alkali metal silicates without a layer structure and/or X-ray amorphous alkali metal silicates, zeolites such as Zeolite A (e.g.
  • Zeolite 4A Zeolite 4A
  • Zeolite B Zeolite P
  • Zeolite X Zeolite X
  • Zeolite HS Zeolite MAP
  • silicates such as crystalline layered disilicates (e.g. of the formula NaMSI x+ ⁇ yH 2 O wherein M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to 20), amorphous disilicates (e.g. BritesilTM), polycarboxylates, citrates, sulphates, borates or mixtures thereof.
  • Organic detergent builders preferred for the purposes of the present invention include a wide variety of polycarboxylate compounds.
  • polycarboxylate refers to compounds having a plurality of carboxylate groups, preferably at least 3 carboxylates.
  • Polycarboxylate builder can generally be added to the dispersion in acid form, but can also be added in the form of a neutralized salt. When utilized in salt form, alkali metals, such as sodium, potassium, and lithium, or alkanolammonium salts are preferred.
  • alkali metals such as sodium, potassium, and lithium, or alkanolammonium salts are preferred.
  • Included among the polycarboxylate builders are a variety of categories of useful materials.
  • One important category of polycarboxylate builders encompasses the ether polycarboxylates.
  • a number of ether polycarboxylates have been disclosed for use as detergent builders. Examples of useful ether polycarboxylates include oxydisuccinate, as disclosed in Berg, U.S. Patent 3,128,287, issued April 7, 1964, and Lamberti et al., U.S.
  • a specific type of ether polycarboxylates useful as builders in the present invention also include those having the general formula: CH(A)(COOX)-CH(COOX)-O-
  • Mixtures of these builders are especially preferred for use herein. Particularly preferred are mixtures of TMS and TDS in a weight ratio of TMS to TDS of from about 97:3 to about 20:80. These builders are disclosed in U.S. Patent 4,663,071 , issued to Bush et al., on May 5, 1987.
  • Suitable ether polycarboxylates also include cyclic compounds, particularly alicyclic compounds, such as those described in U.S. Patents 3,923,679; 3,835,163; 4,158,635; 4,120,874 and 4,102,903.
  • ether hydroxypolycarboxylates represented by the structure: HO-[C(R)(COOM)-C(R)(COOM)-O] n -H wherein M is hydrogen or a cation wherein the resultant salt is water- soluble, preferably an alkali metal, ammonium or substituted ammonium cation, n is from about 2 to about 15 (preferably n is from about 2 to about 10, more preferably n averages from about 2 to about 4) and each R is the same or different and selected from hydrogen, C ⁇ _ alkyl or C substituted alkyl (preferably R is hydrogen).
  • Still other ether polycarboxylates include copolymers of maleic anhydride with ethylene or vinyl methyl ether, 1 , 3, 5-trihydroxy benzene-2, 4, 6-trisulphonic acid, and carboxymethyloxysuccinic acid.
  • Organic polycarboxylate builders also include the various alkali metal, ammonium and substituted ammonium salts of polyacetic acids. Examples include the sodium, potassium, lithium, ammonium and substituted ammonium salts of ethylenediamine tetraacetic acid, and nitrilotriacetic acid.
  • polycarboxylates such as mellitic acid, succinic acid, oxydisuccinic acid, polymaleic acid, benzene 1 ,3,5-tricarboxylic acid, and carboxymethyloxysuccinic acid, and soluble salts thereof.
  • Citrate builders e. g., citric acid and soluble salts thereof (particularly sodium salt) are polycarboxylate builders of particular importance for heavy duty liquid detergent formulations, but can also be used in granular dispersions.
  • Other carboxylate builders include the carboxylated carbohydrates disclosed in U.S. Patent 3,723,322, Diehl, issued March 28, 1973.
  • Also suitable in the detergent ingredients of the present invention are the 3,3- dicarboxy-4- oxa-1 ,6-hexanedioates and the related compounds disclosed in U.S. Patent 4,566,984, Bush, issued January 28, 1986.
  • Useful succinic acid builders include the C 5 - C 20 alkyl succinic acids and salts thereof.
  • a particularly preferred compound of this type is dodecenylsuccinic acid.
  • Alkyl succinic acids typically are of the general formula R- CH(COOH)CH 2 (COOH) i.e., derivatives of succinic acid, wherein R is hydrocarbon, e.g., C-io- C 20 alkyl or alkenyl, preferably C ⁇ -C 16 or wherein R may be substituted with hydroxyl, sulfo, sulfoxy or sulfone substituents, all as described in the above-mentioned patents.
  • the succinate builders are preferably used in the form of their water-soluble salts, including the sodium, potassium, ammonium and alkanolammonium salts.
  • succinate builders include: laurylsuccinate, myristylsuccinate, palmitylsuccinate, 2- dodecenylsuccinate (preferred), 2- pentadecenylsuccinate, and the like. Laurylsuccinates are the preferred builders of this group, and are described in European Patent Application 0,200,263, published November 5, 1986.
  • useful builders also include sodium and potassium carboxymethyloxymalonate, carboxymethyloxysuccinate, cis-cyclo-hexane- hexacarboxylate, cis- cyclopentane-tetracarboxylate, water-soluble polyacrylates (these polyacrylates having molecular weights to above about 2,000 can also be effectively utilized as dispersants), and the copolymers of maleic anhydride with vinyl methyl ether or ethylene.
  • suitable polycarboxylates are the polyacetal carboxylates disclosed in U.S. Patent 4,144,226, Crutchfield et al., issued March 13, 1979.
  • polyacetal carboxylates can be prepared by bringing together, under polymerization conditions, an ester of glyoxylic acid and a polymerization initiator. The resulting polyacetal carboxylate ester is then attached to chemically stable end groups to stabilize the polyacetal carboxylate against rapid depolymerization in alkaline solution, converted to the corresponding salt, and added to a surfactant.
  • Polycarboxylate builders are also disclosed in U.S. Patent 3,308,067, Diehl, issued March 7, 1967. Such materials include the water-soluble salts of homo- and copolymers of aliphatic carboxylic acids such as maleic acid, itaconic acid and methylenemalonic acid.
  • Other organic builders known in the art can also be used. For example, monocarboxylic acids, and soluble salts thereof, having long chain hydrocarbyls can be utilized. These would include materials generally referred to as "soaps." Chain lengths of
  • C.o-C 20 are typically utilized.
  • the hydrocarbyls can be saturated or unsaturated.
  • carboxylic acids are citric acid, adipic acid, succinic acid, glutaric acid, malic acid, tarta c acid, maleic acid, fumaric acid, sugar acids, aminocarboxylic acids, nitrilotri acetic acid (NTA), providing its use is not ecologically unsafe, and mixtures thereof.
  • Preferred salts are the salts of the polycarboxylic acids, such as citric acid, adipic acid, succinic acid, glutaric acid, tartahc acid, sugar acids and mixtures thereof.
  • the acids per se may also be used.
  • the acids also typically have the property of an acidifying component and, hence, also serve to establish a relatively low and mild pH value in detergents.
  • Citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and mixtures thereof are particularly mentioned in this regard.
  • the hydrophilizing agents are preferably selected from ethanol, n- or i- propanol, butanols, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, propylene glycol methyl, ethyl or propyl ether, dipropylene glycol monomethyl or monoethyl ether, diisopropylene glycol monomethyl or monoethyl ether, methoxy, ethoxy or butoxythglycol, 1 -butoxyethoxy-2- propanol, 3-methyl-3- methoxybutanol, propylene glycol t-butyl ether, alcohols, more particularly C 1-4 alkanols, glycols, polyethylene glycols, preferably with a molecular weight of 100 to 100, 000 and more particularly in the
  • H 2 O 2 which is a preferred bleaching agent and compounds yielding H 2 O 2 in water which serve as bleaching agents, sodium perborate tetrahydrate, sodium perborate monohydrate and sodium percarbonate are particularly important.
  • Other useful bleaching agents are, for example, persulfates and mixed salts with persulfates, such as the salts commercially available as CAROAT®, peroxypyrophosphates, citrate perhydrates and H 2 O 2 -yielding peracidic salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid, diperdodecanedioic acid or phthaloiminoperacids, such as phthaliminopercaproic acid.
  • Bleach systems which may be included in the detergent are preferably active chlorine carriers and/or organic or inorganic active oxygen carriers, bleach activators (e.g. TAED, TAGU, SNOBS (sodium nonoyl benzene sulphonate), PAG (penta acetyl glucose) or diacylated diperoxy carboxylic acids, bleach catalysts, enzymes for removing discolorations, perborates and/or percarbo nates.
  • the pH regulators are preferably sodium carbonate, citric acid, sodium citrate and/or bicarbonate.
  • the detergent may also comprise enzymes.
  • Enzymes suitable for use in the dispersion are enzymes from the class of oxidases, proteases, lipases, cutinases, amylases, pullulanases. cellulases, hemicellulases, xylanases and peroxidases and mixtures thereof, for example proteases, such as BLAP®, Optimase®, Opticlean®,
  • Termamyl® Amylase-LT®, Maxamyl®, Duramyl® and/or Purafect® OxAm
  • lipases such as Lipoiase®, Lipomax®, Lumafast® and/or Lipozym®
  • cellulases such as Celluzyme® and/or Carazeme®.
  • the enzymes optionally used may be adsorbed onto supports and/or encapsulated in membrane materials to protect them against premature inactivation.
  • the invention also relates to an aqueous detergent dispersion obtainable from the method as defined herein.
  • the invention also relates to an aqueous detergent dispersion comprising silanized colloidal silica particles and a detergent as described herein.
  • the detergent and the silanized silica particles are preferably homogeneously dispersed in the aqueous phase.
  • the aqueous detergent dispersion may comprise up to about 80, preferably from about 0.01 to about 20, more preferably from about 0.1 to about 10, and most preferably from about 0.3 to about 5 wt% (dry) silica.
  • the aqueous detergent dispersion suitably has a detergent content from about 2 to about 80 wt%.
  • the preferred detergent contents are as described herein.
  • the stability of the dispersion facilitates the handling and application thereof in any use since it allows for storage and need not be prepared on site immediately before usage.
  • the dispersion is substantially aqueous dispersion.
  • a suitable organic solvent miscible with water may be comprised in the substantially aqueous dispersion in an amount from about 1 to about 20, preferably from about 1 to about 10, and most preferably from about 1 to about 5 volume percent of the total dispersion volume. This is due to the fact that for some applications, a certain amount of organic solvents may be present without any detrimental environmental effects.
  • the dispersion may contain besides silanized colloidal silica particles also, at least to some extent, non-silanized colloidal silica particles depending on the size of the silica particles, weight ratio of silane to silica, type of silane compound, reaction conditions etc.
  • at least about 40 of the colloidal silica particles are silanized
  • the dispersion may comprise besides silane in the form of silane groups or silane derivatives bound or linked to the surface of the silica particles also at least to some extent freely dispersed unbound silane compounds.
  • At least about 40 preferably, at least about 60, more preferably at least about
  • the silane compounds are bound or linked to the surface of the silica particles.
  • at least about 1 % by number of the silanol surface groups on the colloidal silica particles are capable of binding or linking to silane groups on the siiane compounds, preferably at least about 5 %, more preferably at least about 10 %, even more preferably at least about 30 %, and most preferably at least about 50 % bind or link to a silane group.
  • the weight ratio of the total silane content to the total silica content in the dispersion is from about O.01 to about 1.5, more preferably from about 0.05 to about 1 , and most preferably from about 0.1 to about 0.5.
  • the total content of silica comprises silica in modified silanized silica particles and non-modified silica particles which also may be present in the prepared dispersion.
  • the total content of silane is based on all freely dispersed silane and all linked or bound silane groups or derivatives.
  • the detergent dispersion can be used for the treatment of hard surfaces, but also for the treatment of fibre and textile surfaces.
  • Hard surfaces are, in particular, surfaces encountered in the home, i.e. surfaces of stone, ceramics, wood, plastics, metals, such as stainless steel, incl. floor coverings, such as carpets, etc.
  • the cleaner dispersion can be of different types; e.g. glass cleaners, all purpose cleaners, bath cleaners, kitchen cleaners etc.
  • Textile surfaces include any synthetic and natural textiles, the particles used in accordance with the invention preferably being used for the treatment of cotton and cotton/wool blends in e.g. for the pretreatment and aftertreatment of textiles and for the washing of textiles.
  • the particles may also be used for textile treatment in the textile industry, in which case they may be used both for the permanent and for the temporary treatment of textiles.
  • the detergent dispersion is preferably also used as hand dishwashing detergents, machine dishwashing detergents, machine dishwashing cleaners and rinse aids.
  • the detergent dispersion may also be further used as automobile and paint cleaners for manual use and for automatic use in car washes.
  • the detergent dispersion may also be used in anti-soil treatment for e.g. coil-coating.
  • Table 1 lists the liquid detergents used in the following examples.
  • the particle size D p for each sol in table 2 is based on the specific surface area on the non-modified sol for each particle size respectively.
  • Example 1 The colloidal silica dispersions as listed in table 2 were added to the liquid detergents as listed in table 1 under good agitation in accordance with table 3. The amount of detergent, to which the colloidal silica dispersion is added, is 100 g if not stated otherwise. The stability is controlled initially and finally after one month's storage at 55 °C for precipitation and separation (inhomogeneous sample). The stability was controlled by optical inspection. Table 3: Detergent dispersions and stability
  • Example 2 The performance of the silane modified sols in the detergent application had the same technical effect as can be seen from table 4 below.
  • 1.5 g silica sol aqueous product was added to 100 g Ajax Double Action (glass cleaner) at good agitation at room temperature. The cleaner was then used as described in the method below.
  • Exterior windows were used in the test. The detergents (with the silica sol) were sprayed onto vertical windows and the surplus was then removed by a rubber scraper. The windows were let to dry for 5 minutes. Standard soil (Krefeld) solution (1 %) was sprayed onto a part of the cleaned window. Water was also sprayed onto another part of the cleaned window. The spread and wetting of the soil were studied (spread and soil release).

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Woven Fabrics (AREA)

Abstract

L'invention concerne un procédé de préparation d'une dispersion détergente aqueuse consistant à mélanger au moins un composé de silane, des particules de silice colloïdales et un détergent, de manière à former une dispersion détergente aqueuse renfermant des particules de silice colloïdales silanisées. Ladite invention a aussi pour objet une dispersion pouvant être obtenue par ce procédé et l'utilisation associée.
PCT/SE2005/000384 2004-04-08 2005-03-16 Composition detergente WO2005097961A1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
CN2005800099656A CN1938413B (zh) 2004-04-08 2005-03-16 洗涤剂组合物
BRPI0509106A BRPI0509106B1 (pt) 2004-04-08 2005-03-16 método para a preparação de dispersão detergente aquosa, dispersão aquosa, e uso da dispersão
CA2562256A CA2562256C (fr) 2004-04-08 2005-03-16 Dispersion aqueuse de detergent comprenant des particules de silice colloidale silanisee
AT05722230T ATE471365T1 (de) 2004-04-08 2005-03-16 Waschmittel
EP05722230A EP1733015B1 (fr) 2004-04-08 2005-03-16 Composition detergente
JP2007507268A JP4970246B2 (ja) 2004-04-08 2005-03-16 洗剤組成物
DE602005021868T DE602005021868D1 (de) 2004-04-08 2005-03-16 Waschmittel
AU2005230956A AU2005230956B2 (en) 2004-04-08 2005-03-16 Detergent composition

Applications Claiming Priority (2)

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EP04445047.6 2004-04-08
EP04445047 2004-04-08

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WO2005097961A1 true WO2005097961A1 (fr) 2005-10-20

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BR (1) BRPI0509106B1 (fr)
CA (1) CA2562256C (fr)
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ES (1) ES2347447T3 (fr)
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WO (1) WO2005097961A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2154111A1 (fr) 2008-07-10 2010-02-17 Cognis IP Management GmbH Silicate soluble et son utilisation
WO2012080197A1 (fr) 2010-12-16 2012-06-21 Akzo Nobel Chemicals International B.V. Composition de dégraissage provoquant peu de stries
WO2012012349A3 (fr) * 2010-07-17 2012-07-05 Enginuity Worldwide, LLC Nouveaux procédés pour améliorer des caractéristiques de surface
WO2013064358A1 (fr) 2011-11-01 2013-05-10 Unilever N.V. Produit de nettoyage pour le verre

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6316574B2 (ja) * 2013-11-21 2018-04-25 アズビル株式会社 粒子検出装置及び粒子の検出方法
JP6316573B2 (ja) * 2013-11-21 2018-04-25 アズビル株式会社 粒子検出装置及び粒子の検出方法
CN103666874A (zh) * 2013-11-22 2014-03-26 南通信一服饰有限公司 一种织物用油漆清洗剂
CN107418784A (zh) * 2017-05-30 2017-12-01 花舜 一种多用途洗涤剂

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US2920045A (en) * 1955-09-06 1960-01-05 Colgate Palmolive Co Heavy duty liquid detergent compositions
US4801401A (en) * 1986-03-08 1989-01-31 Henkel Kommanditsegellschaft auf Aktien Process for the production of a foam inhibitor mixture
WO1999036359A1 (fr) * 1998-01-14 1999-07-22 Dendreon Corporation Procede de fabrication de silice colloidale silanisee
US20020111287A1 (en) * 2000-12-12 2002-08-15 Clariant Gmbh Laundry detergents and cleaners comprising microdisperse silicate-containing particles
US20020192367A1 (en) * 2001-04-30 2002-12-19 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Fabric care compositions

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JPH10310406A (ja) * 1997-03-12 1998-11-24 Catalysts & Chem Ind Co Ltd 有機化合物修飾無機化合物ゾル

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2920045A (en) * 1955-09-06 1960-01-05 Colgate Palmolive Co Heavy duty liquid detergent compositions
US4801401A (en) * 1986-03-08 1989-01-31 Henkel Kommanditsegellschaft auf Aktien Process for the production of a foam inhibitor mixture
WO1999036359A1 (fr) * 1998-01-14 1999-07-22 Dendreon Corporation Procede de fabrication de silice colloidale silanisee
US20020111287A1 (en) * 2000-12-12 2002-08-15 Clariant Gmbh Laundry detergents and cleaners comprising microdisperse silicate-containing particles
US20020192367A1 (en) * 2001-04-30 2002-12-19 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Fabric care compositions

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2154111A1 (fr) 2008-07-10 2010-02-17 Cognis IP Management GmbH Silicate soluble et son utilisation
WO2012012349A3 (fr) * 2010-07-17 2012-07-05 Enginuity Worldwide, LLC Nouveaux procédés pour améliorer des caractéristiques de surface
WO2012080197A1 (fr) 2010-12-16 2012-06-21 Akzo Nobel Chemicals International B.V. Composition de dégraissage provoquant peu de stries
WO2013064358A1 (fr) 2011-11-01 2013-05-10 Unilever N.V. Produit de nettoyage pour le verre

Also Published As

Publication number Publication date
EP1733015A1 (fr) 2006-12-20
BRPI0509106B1 (pt) 2016-07-26
CA2562256A1 (fr) 2005-10-20
AU2005230956B2 (en) 2008-02-14
CA2562256C (fr) 2012-05-29
ES2347447T3 (es) 2010-10-29
BRPI0509106A (pt) 2007-08-28
AU2005230956A1 (en) 2005-10-20
EP1733015B1 (fr) 2010-06-16
JP4970246B2 (ja) 2012-07-04
CN1938413B (zh) 2010-06-23
TW200535237A (en) 2005-11-01
ATE471365T1 (de) 2010-07-15
DE602005021868D1 (de) 2010-07-29
CN1938413A (zh) 2007-03-28
TWI304093B (en) 2008-12-11
JP2007532713A (ja) 2007-11-15

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