WO2005066597A1 - Multiplexing rotary spectrometer - Google Patents
Multiplexing rotary spectrometer Download PDFInfo
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- WO2005066597A1 WO2005066597A1 PCT/US2004/037826 US2004037826W WO2005066597A1 WO 2005066597 A1 WO2005066597 A1 WO 2005066597A1 US 2004037826 W US2004037826 W US 2004037826W WO 2005066597 A1 WO2005066597 A1 WO 2005066597A1
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- spectrometer
- electromagnetic radiation
- optical bandpass
- detector
- coupled
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/46—Measurement of colour; Colour measuring devices, e.g. colorimeters
- G01J3/50—Measurement of colour; Colour measuring devices, e.g. colorimeters using electric radiation detectors
- G01J3/51—Measurement of colour; Colour measuring devices, e.g. colorimeters using electric radiation detectors using colour filters
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J1/00—Photometry, e.g. photographic exposure meter
- G01J1/10—Photometry, e.g. photographic exposure meter by comparison with reference light or electric value provisionally void
- G01J1/20—Photometry, e.g. photographic exposure meter by comparison with reference light or electric value provisionally void intensity of the measured or reference value being varied to equalise their effects at the detectors, e.g. by varying incidence angle
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/02—Details
- G01J3/0205—Optical elements not provided otherwise, e.g. optical manifolds, diffusers, windows
- G01J3/0213—Optical elements not provided otherwise, e.g. optical manifolds, diffusers, windows using attenuators
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01J—MEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRARED, VISIBLE OR ULTRAVIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
- G01J3/00—Spectrometry; Spectrophotometry; Monochromators; Measuring colours
- G01J3/46—Measurement of colour; Colour measuring devices, e.g. colorimeters
- G01J3/50—Measurement of colour; Colour measuring devices, e.g. colorimeters using electric radiation detectors
- G01J3/51—Measurement of colour; Colour measuring devices, e.g. colorimeters using electric radiation detectors using colour filters
- G01J3/513—Measurement of colour; Colour measuring devices, e.g. colorimeters using electric radiation detectors using colour filters having fixed filter-detector pairs
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N2021/3129—Determining multicomponents by multiwavelength light
- G01N2021/3133—Determining multicomponents by multiwavelength light with selection of wavelengths before the sample
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/314—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry with comparison of measurements at specific and non-specific wavelengths
- G01N2021/3159—Special features of multiplexing circuits
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/314—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry with comparison of measurements at specific and non-specific wavelengths
- G01N2021/3166—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry with comparison of measurements at specific and non-specific wavelengths using separate detectors and filters
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/314—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry with comparison of measurements at specific and non-specific wavelengths
- G01N2021/317—Special constructive features
- G01N2021/3174—Filter wheel
Definitions
- This invention relates to multiplexing rotary spectrometers, and more particularly to multiplexing rotary spectrometers employing a scheme by which each of a plurality of optical bandpass filters is oriented in alignment with each of a plurality of input ports carrying electromagnetic radiation to the spectrometer.
- FIG. 1 depicts a rotary spectrometer 100 having ten input ports 101, 103, and 105, only three of which are depicted.
- a first source of electromagnetic radiation 102 is coupled to a first input port 101 via an optical waveguide
- a second source of electromagnetic radiation 104 is coupled to a second input port 103, and so on.
- each source 102, 104, 106 need not be embodied as a lamp.
- the sources 102, 104, 106 may be embodied as an LED, a laser, or any other source of electromagnetic emission.
- each of the input ports 101, 103, and 105 may actually be coupled to a single source.
- a rotary spectrometer may be coupled to as many sources as it has input ports and to as few as a single source (and any number in between).
- various embodiments of rotary spectrometers are depicted as being used in a setting in which each input port is coupled to a different source. As just explained, this is for explanatory purposes only and is not an essential part of the invention.
- a rotating body (not depicted) houses ten optical bandpass filters 108,
- the rotating body may also house one or more neutral density filters 114 and 116, which are aligned with the optical bandpass filters 108 and 110.
- the neutral density filters 114 and 116 may be aligned either in front of, or in back of, their respective bandpass filters 108 and 110.
- the rotating body is actuated under the control of a motor (not depicted). Rotation of the body causes the optical bandpass filters 108, 110, and 112 to come into alignment with the input ports 101, 103, or 105.
- optical bandpass filter 108 is in alignment with a first input port 101, which carries electromagnetic radiation from a first source of electromagnetic radiation 102.
- optical bandpass filter 110 is in alignment with a second input port 103, which carries electromagnetic radiation from a second source of electromagnetic radiation 104, and so on.
- electromagnetic radiation is emitted from the first source 102 and is carried by an optical waveguide (not depicted) to the first input port 101.
- the electromagnetic radiation propagates from the input port 101 to the optical bandpass filter 108 in alignment therewith.
- the optical bandpass filter 108 is a device that allows electromagnetic radiation within a passband to pass through, while attenuating electromagnetic radiation falling outside of the passband.
- Other types of filters include cut filters that can pass radiation below or above a particular wavelength (i.e., a highpass or lowpass filter).
- the source of electromagnetic radiation may be a lamp, which may be used, for example, in a production, lab, or pilot-scale line to cure a substance.
- the lamp may exhibit a characteristic wavelength-energy profile, meaning that due to the chemical composition of the lamp, a relatively great amount of energy is carried on certain wavelengths, while a relatively scarce amount of energy is carried on other wavelengths.
- a neutral density filter 114 and 116 may be placed in alignment with an optical bandpass filter 108 and 110 having a passband that includes wavelengths expected to carry a relatively great amount of energy. After propagation through the optical bandpass filter 108, 110, and 112, the electromagnetic radiation propagates toward, and is incident upon, a photoelectric element (not depicted), which reacts to incident electromagnetic radiation by exhibiting an electrical voltage.
- the voltage exhibited across the photoelectric element is approximately proportional to the intensity of the electromagnetic incident upon it.
- the photoelectric element is coupled to a detection circuit 118, 120, and 122, which amplifies the signal and may optionally digitize the signal for delivery to a computer system (not depicted).
- the detection circuits 118, 120, and 122 amplify their respective input signals in accordance with a gain factor, which may be selected, for example, by adjustment of a potentiometer interposed in the feedback path of an operational amplifier.
- One complete rotation of the body housing the optical bandpass filters 108, 110, and 112 and neutral density filters 114 and 116 achieves the effect of taking one measurement of each source 102, 104, and 106 at the wavelength ranges determined by the passbands of each of the bandpass filters 108, 110, 112.
- the computer system may be used, for example, to display information related to the intensity of electromagnetic radiation within the bandpass ranges exhibited by the bandpass filters 108, 110, and 112.
- the above-described system should be designed so that the detection circuits 118, 120, and 122 utilize gain factors that are as large as possible without providing occasion for the detection circuits 118, 120, and 122 to saturate.
- Adherence to such a principle ensures that the greatest resolution of measurement is yielded from the analog-to-digital converters interposed between the detection circuits 118, 120, and 122 and the computer (the analog-to-detection circuits may be embedded within the detection circuits 118, 120, and 122, as described above).
- the process of choosing an appropriate gain factor for each detection circuit 118, 120, and 122 is tedious. For example, consider the process of selecting an appropriate gain factor for the first detection circuit 118.
- the first bandpass filter 118 is indirectly optoelectrically coupled to the first source 102, which emits electromagnetic radiation having an intensity, I, which may be measured in eN/(area)(sec).
- the electromagnetic radiation propagates through the neutral density filter 114 that is in alignment with the first input port 101, whereupon all wavelengths are attenuated approximately equally by a factor, K A , meaning that the intensity exhibited at the output of the neutral density filter is equal to I7K A . Thereafter, the electromagnetic radiation is filtered by the first bandpass filter 108, so that only wavelengths falling within the passband are permitted to pass.
- the intensity of the electromagnetic radiation is equal to I A K A , where I A represents the intensity of electromagnetic radiation within the passband of the first bandpass filter 108.
- I A represents the intensity of electromagnetic radiation within the passband of the first bandpass filter 108.
- the electromagnetic radiation is incident upon a photoelectric element (not depicted), whereupon it is converted into a voltage and amplified by a gain factor, GA, meaning that the output voltage of the first detection circuit is equal to [GA] [I A K A ].
- GA gain factor
- the photoelectric element is described as converting incident electromagnetic radiation into a voltage.
- a photoelectric element may convert incident electromagnetic radiation into an electrical current, as well.
- Such photoelectric elements are included within the scope of the invention.
- photoelectric elements are described herein as converting incident electromagnetic radiation into a votlage, although conversion into a current is equally within the scope of the invention.
- the gain factor should be selected so as to be as large as possible without providing occasion for the detection circuit 118 to saturate, the following condition should be satisfied:
- FIG. 2 depicts the spectrometer of FIG. 1 , after the body has been rotated so as to bring the tenth bandpass filter 112 into alignment with the first input port 101.
- the first bandpass filter 118 is indirectly optoelectrically coupled to the first source 102, which emits electromagnetic radiation having an intensity, I.
- the electromagnetic radiation from the first source 102 propagates to the tenth bandpass filter 112, whereupon it is filtered, so that only wavelengths falling within the passband are permitted to pass.
- the intensity of the electromagnetic radiation is equal to , where Ij represents the intensity of electromagnetic radiation within the passband of the tenth bandpass filter 112.
- the electromagnetic radiation is incident upon a photoelectric element (not depicted), whereupon it is converted into a voltage and amplified by a gain factor, G A , meaning that the output voltage of the first detection circuit is equal to [G A ][I J ].
- condition 2 differs from condition 1, illustrating the point that the appropriate gain factor is a function the orientation of the body housing the optical bandpass filters. Since there are as many conditions to be satisfied as there are optical bandpass filters housed in the body (i.e., ten conditions in the case of the spectrometer depicted in FIGs. 1 and 2), the gain factor must be set in light of each of the conditions.
- the gain factor is chosen by rotating the body to each of the positions and setting the gain factor to the greatest value that is consistent with each of the conditions.
- the gain factor arrived at may be particularly unsuitable for bandpass filters having a bandpass range that passes wavelengths upon which the source emits relatively little energy. For such wavelengths, the selected gain results in a condition whereby only a fraction of the quantization range of the analog-to-digital converter is used. This leads to low-resolution measurement and enhanced susceptibility to noise, qualities that are inimical to proper functioning of a spectrometer.
- neutral density filters (which are included for the sake of rendering the intensities of the electromagnetic radiation incident upon the various photoelectric elements into roughly similar range) has a drawback.
- Neutral density filters inhibit radiation that could otherwise be used to improve the accuracy and precision of the instrument from reaching the photoelectric elements — a result inimical to the goal of accuracy and precision.
- a gain factor may be selected in a simple manner, and yet may be suitable for any position of the body housing the optical bandpass filters.
- neutral density filters There further exists a need for elimination of neutral density filters.
- a spectrometer may include a plurality of optical bandpass filters housed on a first body that rotates under the control of a motor.
- the spectrometer may also include a plurality of detector circuits. Each detector circuit may be permanently optoelectrically coupled to a single optical bandpass filter.
- a spectrometer may include a plurality of input ports. Each input port may be arranged to receive an optical waveguide carrying electromagnetic radiation.
- the spectrometer may also include a plurality of optical bandpass filters, which are housed on a first body that rotates under the control of a motor so that each optical bandpass filter may be brought into alignment with each input port.
- the spectrometer may include a plurality of detector circuits disposed on a second body that rotates with the first body. Each detector circuit may be optoelectrically coupled to one of the plurality of optical bandpass filters, thereby resulting in each detector circuit being dedicated to responding to a range of wavelengths determined by the bandpass filter to which it is optoelectrically coupled.
- a method of selecting a gain factor of a detector circuit in a spectrometer may be obtained.
- the spectrometer may include a plurality of input ports, a plurality of optical bandpass filters, and a plurality of the detector circuits. Each input port may be arranged to receive an optical waveguide carrying electromagnetic radiation.
- Each optical bandpass filter may be movable so that it may be brought into alignment with any given input port.
- Each of the detector circuits may be optoelectrically coupled to one optical bandpass filters.
- the method for selecting the gain factors in such a spectrometer may include supplying electromagnetic radiation from a source, along one of the optical fibers, to one of the optical bandpass filters. Next, electromagnetic radiation that has passed through the one optical bandpass filter is incident upon a photoelectric element. The photoelectric element creates an electric signal having a current or voltage amplitude approximately in proportion to the intensity of the electromagnetic radiation impinging upon the photoelectric element. Next, the electric signal is supplied to the detector circuit that is coupled to the one optical bandpass filter, thereby creating a detector output signal in approximate proportion to the electric signal.
- a method of manufacturing an article that is exposed to electromagnetic radiation during at least one phase of manufacture may include bringing a substance to a source of electromagnetic radiation, wherein the substance is in a first state. The substance is exposed to the electromagnetic radiation, causing the substance to transition to a second state. The source of electromagnetic radiation is monitored with a spectrometer having a plurality of optical bandpass filters housed on a first body that rotates under the control of a motor and a plurality of detector circuits. Each detector circuit is permanently optoelectrically coupled to a single optical bandpass filter.
- Figure 1 depicts a customary rotary spectrometer having ten input ports.
- Figure 2 depicts the spectrometer of Figure 1, after the body has been rotated so as to bring the tenth bandpass filter into alignment with the first input port .
- Figure 3 depicts a rotary spectrometer having N input ports, according to one embodiment of the present invention.
- Figure 4 depicts the spectrometer of Figure 3, after the body has been rotated so as to bring the first bandpass filter into alignment with the second input port.
- Figure 5 depicts a method by which a gain factor for a detection circuit in a rotary bandpass filter may be selected, according to one embodiment of the present invention.
- Figure 6 depicts an embodiment of a rotary spectrometer according to the present invention.
- FIG. 3 depicts a rotary spectrometer 300 having N input ports 302, 304, and 306, only three of which are shown.
- Optical waveguides carry 308, 310, and 312 electromagnetic radiation from each of the N sources 314, 316, and 318 to each of the N input ports 302, 304, and 306.
- N is shown as being equal to ten in FIG. 3, N may take on any value, in principle.
- a first rotating body (not shown in FIG. 3, but depicted in FIGs. 6 and 7) houses N optical bandpass filters 320, 322, and 324.
- each of the optical bandpass filters 320, 322, and 324 may be brought into alignment with each of the input ports 302, 304, and 306.
- each of the optical bandpass filters 320, 322, and 324 has a unique passband, although this is not required.
- each of the sources 314, 316, and 318 of electromagnetic radiation are typically of similar chemical composition and emit electromagnetic radiation with an adjustable intensity. Generally, the intensity levels of the sources 314, 316, and 318 are selected in concert with the orientation of the waveguides transporting the electromagnetic radiation so that intensity levels carried along the waveguides are not radically different from input port to input port.
- a rotary spectrometer may be coupled as many sources as it has input ports and to as few as a single source (and any number in between).
- various embodiments of rotary spectrometers are depicted as being used in a setting in which each input port is coupled to a different source. As just explained, this is for explanatory purposes only and is not an essential part of the invention.
- a photoelectric element (not shown in FIG. 3, but depicted in FIGs. 6 and 7) is optically coupled to each bandpass filter 320, 322, and 324.
- the photoelectric elements are coupled to their respective optical bandpass filters in such a way that rotation of the body does not interrupt the optical and/or electrical connection between the photoelectric elements and their respective optical bandpass filters 320, 322, and 324.
- a coupling that exhibits this quality is referred to as a "permanent" coupling herein.
- One example of a permanent coupling scheme is as follows: the photoelectric elements are housed within a second rotating body that rotates with a first body housing the optical bandpass filters 320, 322, and 324. By virtue of the mutual rotation of the two bodies, the photoelectric elements are kept in alignment with their respective optical bandpass filters 320, 322, and
- a detection circuit 326, 328, and 330 is permanently electrically coupled to a corresponding photoelectric element.
- the detection circuits 326, 328, and 330 may be disposed on the same body that houses the photoelectric elements.
- the detection circuits 326, 328, and 330 rotate with the photoelectric elements, meaning that their electrical connection is easily maintained despite rotation of the photoelectric elements.
- the permanence of the couplings between the optical bandpass filters 320, 322, and 324, and their corresponding photoelectric elements and detection circuits 326, 328, and 330 greatly simplifies the process of selecting gain factors for the detection circuits 326, 328, and 330. The following calculations illustrate this point.
- the first bandpass filter 118 is indirectly optoelectrically coupled to the first source 314, which emits electromagnetic radiation having an intensity, L . .
- the electromagnetic radiation propagates to a first bandpass filter 320 whereupon it is filtered, so that only wavelengths falling within the passband are permitted to pass.
- the intensity of the electromagnetic radiation is equal to II A , where IIA represents the intensity of electromagnetic radiation within the passband of the first bandpass filter 320.
- the electromagnetic radiation is incident upon a photoelectric element (not depicted), whereupon it is converted into a voltage and amplified by a gain factor, G A , meaning that the output voltage of the first detection circuit 326 is equal to [G A ][I I.A ]-
- G A gain factor
- max output may be multiplied by a safety factor (e.g., 80%) to accommodate variation in intensity of electromagnetic radiation emission from the sources 314, 316 and 318, such variations occurring either over time or occurring from input source to input source.
- a safety factor e.g., 80%
- the condition to be satisfied changes insubtantially with rotation of the body housing the optical bandpass filters 320, 322, and 324.
- FIG. 4 depicts the spectrometer of FIG. 3, after the body has been rotated so as to bring the first bandpass filter 320 into alignment with the second input port 304.
- the first bandpass filter 320 is indirectly optoelectrically coupled to the second source 316, which emits electromagnetic radiation having an intensity, I 2 .
- the electromagnetic radiation from the second source 316 propagates to the first bandpass filter 320, whereupon it is filtered, so that only wavelengths falling within the passband are permitted to pass.
- the intensity of the electromagnetic radiation is equal to I 2A , where I 2 A represents the intensity of electromagnetic radiation within the passband of the first bandpass filter 320.
- the electromagnetic radiation is incident upon a photoelectric element (not depicted), whereupon it is converted into a voltage and amplified by a gain factor, G A , meaning that the output voltage of the first detection circuit
- max output may be multiplied by a safety factor (e.g., 80%) to accommodate variation in intensity of electromagnetic radiation emission from the sources 314, 316 and 318, such variations occurring either over time or occurring from input source to input source.
- a safety factor e.g., 80%
- condition 4 is substantially similar to condition 3, due to the fact that Ii ⁇ l 2 (meaning that II A ⁇ I 2A )- Because each of the conditions is substantially similar to one another, the need for neutral density filters is eliminated, and no neutral density filters are included in the embodiments depicted in FIGs. 3-8. Further, the need to rotate the body housing the optical bandpass filters 320, 322, and 324 to each of its N positions before selecting the gain factors is also eliminated.
- the gain factors may be selected by implementing a simple process with the body housing the optical bandpass filters remaining in any one of the N positions.
- Another advantage of the scheme presented in FIGs. 3 and 4 is that the presence of neutral density filters is eliminated altogether. Consequently, the entirey of electromagnetic radiation falling within the passband of the optical filter through which it passes is incident upon the photoelectric element and is converted into a voltage or current that is amplified and used for measurement. Thus, accuracy and precision of the spectrometer is improved. Of course, there is an additional advantage in cost savings that are concomitant with elimination of parts.
- FIG. 5 depicts a method by which a gain factor for a detection circuit in a rotary bandpass filter may be selected. The method of FIG.
- electromagnetic radiation (referred to as "light” in FIG. 5, although the electromagnetic radiation maybe of any wavelength, in principle) is emitted from the source and is guided via an optical waveguide to an input port.
- the electromagnetic radiation propagates from the input port to the bandpass filter that is aligned therewith, as shown in operation 502.
- the electromagnetic radiation is then filtered by the optical bandpass filter, so that only wavelengths falling within the passband are permitted to pass.
- the electromagnetic radiation is incident upon a photoelectric element, whereupon it is converted into a voltage, as shown in operation 504.
- the voltage is amplified by a tunable gain factor.
- the gain is adjusted, as shown in operation 508, so that the output voltage of the detector circuit is equal to a specified level.
- the specified level may be equal to the maximum voltage level of the linear region of the detector circuit.
- the specified voltage level may be equal to the aforementioned level multiplied by a safety factor, such as a safety factor of 70%, 80%, or 90%.
- a safety factor such as a safety factor of 70%, 80%, or 90%.
- the method discussed with reference to FIG. 5 does not require rotation of the body housing the optical bandpass filters. Further, the method results in selection of a gain factor that is employed by a detector circuit that amplifies signals falling always within the same range of wavelengths (because the detector circuit is permanently coupled to a particular optical bandpass filter).
- FIG. 6 depicts an embodiment of a rotary spectrometer according to the present invention.
- the spectrometer includes input ports 600-606, which may be embodied as apertures in a plate 608, dimensioned so as to hold fast optical waveguides carrying electromagnetic radiation from a set of sources.
- the spectrometer of FIG. 6 is depicted as having four input ports 600-606, in principle the spectrometer may include any number of input ports.
- a first body 610 is juxtaposed to the plate 608 housing the input ports 600-606.
- the body 610 houses four optical bandpass filters 612-618.
- the body 610 is rotatable under the control of a motor 620.
- the motor is able to rotate the body 610 so that any one of its optical bandpass filters 612-618 is aligned with any of the input ports.
- the input ports 600-606 and bandpass filters 612-618 are arranged in identical patterns, so that if a given bandpass filter 612-618 is aligned with a given input port 600-606, then every bandpass filter 612-618 is aligned with an input port 600-606.
- a second body 622 is juxtaposed to the first body 610.
- the second body 610 houses four photoelectric elements 624-630 and four detector circuits 632-638.
- detector circuits 632-638 may include a gross gain factor adjustment mechanism, a fine gain factor adjustment mechanism, and a dark current neutralizing adjustment mechanism.
- Dark current refers to current flowing from the photoelectric elements 624-630, even in the presence of no incident electromagnetic radiation from the sources.
- An offset may be employed to effectively subtract this quantity from the output of the photoelectric elements 624-630. This offset is referred to as a "dark current neutralizing factor".
- Photoelectric elements 624-630 may be either active or passive.
- the second body 622 rotates with the first body, so that the photoelectric elements 624-630 remain coupled to their respective optical bandpass filters 612-618.
- the first photodiode 624 remains always aligned with the first optical bandpass filter 612.
- the second photodiode 626 remains always aligned with the second optical bandpass filter 614, and so on.
- One scheme for ensuring that the second body 622 rotates with the first body 610 is to interpose a rigid coupling member 640 between the two bodies 610 and 622, so that they are physically attached. Thus, rotation of the first body 610 causes rotation of the second body 622.
- the second body 622 may be under the control of a second motor 642 that is controlled to turn in accordance with the first motor 620.
- Other schemes for causing the second body 622 to turn with the first body 610 are contemplated herein and are within the scope of this application.
- a slip ring 644 is interposed between the second body
- the slip ring 644 permits one or more electrical connections to be maintained although electrical pathways on one side of the slip ring are in motion (i.e., the electrical pathways on the second body-side may be in motion), while the electrical pathways on the other side are static (i.e., the electrical pathways on the computer-side are static).
- the outputs of the detector circuits 632-638 may be coupled to the computer system 646.
- Additional signal processing circuitry may be interposed between the detector circuits 632-638 and the computer system 646, so as to , render the signals processable by the computer 646.
- a power supply 648 may also be coupled to the detector circuits 632-638 and/or the photoelectric elements 624-630.
- FIG. 7 depicts another embodiment of a rotary spectrometer according to the present invention.
- the spectrometer includes input ports 700- 706.
- a first body 710 is juxtaposed to the plate 708 housing the input ports 700-706.
- the body 710 houses four optical bandpass filters 712-718.
- the body 710 is rotatable under the control of a motor 720.
- a second body 722 is juxtaposed to the first body 710.
- the second body 722 houses four photoelectric elements 724-730.
- the second body 722 rotates with the first body, so that the photoelectric elements 724-730 remain coupled to their respective optical bandpass filters 712-718.
- the first photoelectric element 724 remains always aligned with the first optical bandpass filter 712.
- the second photodiode 726 remains always aligned with the second optical bandpass filter 714, and so on.
- One scheme for ensuring that the second body 722 rotates with the first body 710 is to interpose a rigid coupling member 740 between the two bodies 710 and 722, so that they are physically attached.
- the second body 722 may be under the control of a second motor 742 that is controlled to turn in accordance with the first motor 720.
- a slip ring 744 is interposed between the second body 722 and a stationary body 748 that houses four detector pircuits 732-738.
- the outputs of the rotatable photoelectric elements 712-718 maybe coupled to the stationary detector circuits 732-738.
- the outputs of the detector circuits 732-738 are coupled to a computer system 746.
- Additional signal processing circuitry may be interposed between the detector circuits 732-738 and the computer system 746, so as to render the signals processable by the computer 746.
- a power supply 750 may also be coupled to the photoelectric elements 724-730 via the slip ring 744.
- FIG. 8 depicts an embodiment of a spectrometer according to the invention.
- the spectrometer includes a base plate 800 to which a fiber optic mounting plate 802 is attached.
- the fiber optic mounting plate 802 contains ten recessed apertures 804 into which bulkheads 806 are place.
- a bulkhead 806 is a structure with a plate-like head through which peripheral holes are defined, and an elongated hollow stem that is mounted centrally to the plate-like head.
- the bulkheads are mounted within the recessed apertures 804 via screws 808 that extend through the peripheral holes defined in the plate-like head.
- the bulkheads 806 are oriented with their stem pointing toward the fiber optic mounting plate 802.
- Optical fibers that carry electromagnetic radiation from one or more sources are housed within the hollow stem of the bulkhead 806 (i.e., each bulkhead corresponds to an input port of the spectrometer).
- a servomotor 810 is mounted to the outside of the fiber optic mounting plate 802.
- the spindle of the motor mates with a chassis hub 812, so that the chassis hub 812 rotates when the spindle rotates.
- a circular component chassis 814 is, in turn, mounted to the chassis hub 812.
- the spindle rotation of the motor 810 causes the circular component chassis 814 to rotate, as well.
- the circular component chassis 814 contains apertures 816 that house optical bandpass filters (not depicted).
- the motor can cause any of the apertures 816 to align with any of the optical fibers housed in any of the bulkheads
- a printed circuit board 818 is mounted to the circular component chassis 814 via screws 820 located along the periphery of the printed circuit board 818.
- the printed circuit board 818 has photoelectric elements (not depicted) mounted thereto, such that they are aligned with the optical bandpass filters housed in the circular component chassis 814.
- Detector circuits are disposed on the printed circuit board 818, as well. The detector circuits and photoelectric elements function as described with reference to the previous figures.
- a drive pin 821 extends between the printed circuit board 818 and a slip ring mounting plate 822.
- the drive pin 821 is fastened to the printed circuit board 818 by a drive pin receiver 824, and is fastened to the rotating member of the slip ring 826 (which extends partially through the slip ring mounting plate 822) by a slip ring drive clamp 828.
- the rotating member of the slip ring 826 rotates as well.
- the slip ring mounting plate 822 couples to a slip ring mounting plate base 830 via dowel pins 832 that protrude from the surface 833 of the base 830.
- the base 830 has elongated channels 834 running along opposite edges thereof.
- Screws 836 extend through the channels and into the chassis base plate 800, thereby mating the slip ring mounting plate base 830 to the chassis base plate 800.
- the base 830 may be slid back and forth along the longitudinal axis of the chassis base plate 800.
- a cover 838 fits over the region between the fiber optic mounting plate 802 and the slip ring mounting plate 822, thereby shielding the photoelectric elements from stray electromagnetic radiation.
- the embodiments described with reference to FIGs. 1-8 may be used in a method of manufacturing an article that is exposed to electromagnetic radiation during at least one phase of manufacture. First, the substance is brought in a first state, such as an uncured state, to a source of electromagnetic radiation, such as a lamp.
- the substance is exposed to the electromagnetic radiation from the source, so that the substance transitions to a second state, such as a cured or semi-cured state.
- a second state such as a cured or semi-cured state.
- the source of electromagnetic radiation is monitored by a spectrometer according to any of the embodiments described above.
- the spectrometer may have a plurality of optical bandpass filters housed on a first body that rotates under the control of a motor and a plurality of detector circuits. Each detector circuit may be permanently optoelectrically coupled to a single optical bandpass filter.
- the intensity of electromagnetic radiation delivered from the source may be controlled based upon the measurements arrived at by such a spectrometer.
- Various modifications and alterations of this invention will become apparent to those skilled in the art without departing from the scope and spirit of this invention, and it should be understood that this invention is not to be unduly limited to the illustrative embodiments set forth herein.
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- Spectroscopy & Molecular Physics (AREA)
- General Physics & Mathematics (AREA)
- Biochemistry (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Spectrometry And Color Measurement (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT04810844T ATE462121T1 (de) | 2003-12-19 | 2004-11-12 | Multiplexendes drehspektrometer |
| BRPI0417806-8A BRPI0417806A (pt) | 2003-12-19 | 2004-11-12 | espectrÈmetro, e, métodos para selecionar um fator de ganho de um circuito detector em um espectrÈmetro e para fabricar um artigo que é exposto a radiação eletromagnética durante pelo menos uma fase de fabricação |
| EP04810844A EP1695052B1 (en) | 2003-12-19 | 2004-11-12 | Multiplexing rotary spectrometer |
| JP2006545642A JP2007514953A (ja) | 2003-12-19 | 2004-11-12 | 多重回転スペクトロメータ |
| DE602004026216T DE602004026216D1 (de) | 2003-12-19 | 2004-11-12 | Multiplexendes drehspektrometer |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/741,237 US7113282B2 (en) | 2003-12-19 | 2003-12-19 | Multiplexing rotary spectrometer |
| US10/741,237 | 2003-12-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2005066597A1 true WO2005066597A1 (en) | 2005-07-21 |
Family
ID=34678088
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2004/037826 Ceased WO2005066597A1 (en) | 2003-12-19 | 2004-11-12 | Multiplexing rotary spectrometer |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7113282B2 (https=) |
| EP (1) | EP1695052B1 (https=) |
| JP (1) | JP2007514953A (https=) |
| AT (1) | ATE462121T1 (https=) |
| BR (1) | BRPI0417806A (https=) |
| DE (1) | DE602004026216D1 (https=) |
| WO (1) | WO2005066597A1 (https=) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009505152A (ja) * | 2005-08-18 | 2009-02-05 | グルコスタッツ・システム・プライヴェト・リミテッド | 波長の選択のための装置 |
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| US7679745B2 (en) * | 2006-11-21 | 2010-03-16 | Neptec Optical Solutions | Time-resolved fluorescence spectrometer for multiple-species analysis |
| NL1033815C2 (nl) * | 2007-05-07 | 2008-11-10 | Friesland Brands Bv | Werkwijze en inrichting voor het bereiden van kaas uit melk. |
| US8049894B2 (en) * | 2007-10-05 | 2011-11-01 | Lightwaves 2020, Inc. | Multiple wavelength optical analyzer device |
| CN101419156B (zh) * | 2007-10-23 | 2012-12-05 | 深圳迈瑞生物医疗电子股份有限公司 | 分光光度检测方法与装置以及检测系统 |
| CN101419240B (zh) * | 2007-10-23 | 2013-07-17 | 深圳迈瑞生物医疗电子股份有限公司 | 样本分析装置和样本分析方法 |
| JP5527858B2 (ja) * | 2008-11-18 | 2014-06-25 | コーニンクレッカ フィリップス エヌ ヴェ | フィルタホイール分光計 |
| US9291506B2 (en) * | 2010-01-27 | 2016-03-22 | Ci Systems Ltd. | Room-temperature filtering for passive infrared imaging |
| FI128285B (en) | 2014-06-27 | 2020-02-28 | Metso Automation Oy | Multichannel optical measurement unit, multichannel optical detector unit and related measurement method |
| FR3046879B1 (fr) * | 2016-01-20 | 2022-07-15 | Ulis | Procede de fabrication d'un detecteur de rayonnement electromagnetique a micro-encapsulation |
| KR102289043B1 (ko) * | 2017-07-25 | 2021-08-10 | 삼성전자주식회사 | 스펙트럼 측정 장치 및 방법 |
| WO2021171905A1 (ja) * | 2020-02-28 | 2021-09-02 | パナソニックIpマネジメント株式会社 | 撮像装置 |
| KR20230072260A (ko) | 2021-11-17 | 2023-05-24 | 삼성전자주식회사 | 분광 분석 장치, 이를 이용한 분광 분석 방법 및 이를 포함하는 반도체 메모리 장치의 제조 방법 |
| JP2024101182A (ja) * | 2023-01-17 | 2024-07-29 | 株式会社島津製作所 | 光学的測定装置及び液体クロマトグラフシステム |
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Also Published As
| Publication number | Publication date |
|---|---|
| EP1695052B1 (en) | 2010-03-24 |
| EP1695052A1 (en) | 2006-08-30 |
| JP2007514953A (ja) | 2007-06-07 |
| DE602004026216D1 (de) | 2010-05-06 |
| ATE462121T1 (de) | 2010-04-15 |
| BRPI0417806A (pt) | 2007-04-10 |
| US20050134854A1 (en) | 2005-06-23 |
| US7113282B2 (en) | 2006-09-26 |
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