WO2005066262A1 - Filled composite - Google Patents

Filled composite Download PDF

Info

Publication number
WO2005066262A1
WO2005066262A1 PCT/US2004/043827 US2004043827W WO2005066262A1 WO 2005066262 A1 WO2005066262 A1 WO 2005066262A1 US 2004043827 W US2004043827 W US 2004043827W WO 2005066262 A1 WO2005066262 A1 WO 2005066262A1
Authority
WO
WIPO (PCT)
Prior art keywords
composite
glass bubbles
coupling agent
strength
psi
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2004/043827
Other languages
English (en)
French (fr)
Inventor
Andrew S. D'souza
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Priority to DE200460006170 priority Critical patent/DE602004006170T2/de
Priority to US10/585,022 priority patent/US20070116942A1/en
Priority to EP04815825A priority patent/EP1709115B1/en
Priority to JP2006547535A priority patent/JP2007517128A/ja
Publication of WO2005066262A1 publication Critical patent/WO2005066262A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
    • C08K5/1535—Five-membered rings
    • C08K5/1539—Cyclic anhydrides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C08K7/28—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249971—Preformed hollow element-containing

Definitions

  • the present invention relates to a filled thermoplastic resin composite.
  • fillers into thermoplastic resin compositions to adjust the physical properties of the resultant compositions (often referred to as "composites” or “filled composites”) such as reduce the density thereof, or reduce cost by reducing the proportion of relatively expensive resin with cheaper materials.
  • known fillers include solid particulates such as titanium dioxide, glass, etc.
  • hollow particles such as hollow glass bubbles.
  • glass bubbles have often been used to successfully reduce density of the final composite, in many cases the glass bubbles are crushed during manipulation of the composite, thereby impairing the desired reduction in density.
  • resin composites containing glass bubbles have often exhibited undesirable loss of desired physical properties such as tensile strength.
  • Non-reinforcing fillers can be defined as any particle with an aspect ratio (length over diameter) less than 2. It is assumed that the loss in mechanical strength is due primarily to the filler causing a disruption of the polymer chains and also due to the inefficient bonding between the polymer and the filler; where the bond strength is assumed to be less than the tensile strength of the polymer chains themselves.
  • Illustrative examples of filled resin composites are disclosed in U.S. Patent No. 3,769,126 (Kolek), 4,243,575 (Myers et al.), 4,923,520 (Anzai et al), and 5,695,851
  • a composite of the invention comprises a thermoplastic olefin, e.g., polypropylene, polyethylene, polybutylene, polystyrene, and copolymers thereof, containing maleic anhydride and glass bubbles.
  • a silane coupling agent or titanate coupling agent e.g., aminosilanes such as aminopropyltriethoxysilane ("APS") or N-2-
  • the glass bubbles should exhibit a crush strength of at least 3,000 PSI to withstand many extrusion operations. In some embodiments, they will preferably exhibit a crush strength of at least 18,000 PSI to withstand injection molding as well as extrusion operations. The strength of the glass bubbles is typically measured using ASTM D3102-
  • the present invention may be used with commercially available glass bubble fillers for use in resin composites.
  • the bubbles are of the high strength variety such as
  • ScotchliteTM Glass Bubbles S60HS which are soda-lime-borosilicate glass. These bubbles exhibit an isostatic crush strength of 18,000 psi, density of 0.60 g/cc, and average diameter of about 30 microns.
  • Articles can be made with composites of the invention by injection molding, extrusion, and other known methods for forming articles from thermoplastic polymers.
  • Tensile Modulus was determined following ASTM Test Method D-638 and is reported in Mpa.
  • Elongation at Break Elongation at Break was determined following ASTM Test Method D-638 and is reported as %.
  • Notched Izod Impact Strength was determined following ASTM Test Method D-256 and is reported in J/cm.
  • a twin screw extruder (Berstorff Ultra Glide; screw diameter 25mm; length to diameter ratio was 36:1; screw speed ranged from 200-250 rpm; temperature set points ranged from 200°F-575°F (93°C-302°C), while the actual values range from 148°F-575°F

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Glass Compositions (AREA)
PCT/US2004/043827 2003-12-30 2004-12-30 Filled composite Ceased WO2005066262A1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE200460006170 DE602004006170T2 (de) 2003-12-30 2004-12-30 Gefüllter verbundwerkstoff
US10/585,022 US20070116942A1 (en) 2003-12-30 2004-12-30 Filled composite
EP04815825A EP1709115B1 (en) 2003-12-30 2004-12-30 Filled composite
JP2006547535A JP2007517128A (ja) 2003-12-30 2004-12-30 充填複合材

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53334803P 2003-12-30 2003-12-30
US60/533,348 2003-12-30

Publications (1)

Publication Number Publication Date
WO2005066262A1 true WO2005066262A1 (en) 2005-07-21

Family

ID=34748890

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/043827 Ceased WO2005066262A1 (en) 2003-12-30 2004-12-30 Filled composite

Country Status (7)

Country Link
US (1) US20070116942A1 (https=)
EP (1) EP1709115B1 (https=)
JP (1) JP2007517128A (https=)
CN (1) CN1902276A (https=)
AT (1) ATE360662T1 (https=)
DE (1) DE602004006170T2 (https=)
WO (1) WO2005066262A1 (https=)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007297432A (ja) * 2006-04-28 2007-11-15 Tokyo Printing Ink Mfg Co Ltd 断熱性樹脂組成物
WO2008090235A3 (en) * 2007-02-28 2008-09-25 Solvay Advanced Polymers Llc Thermoplastic compositions containing microspheres
CN1919915B (zh) * 2005-08-26 2010-10-13 海尔集团公司 用于冰箱上的改性聚丙烯材料及其制造方法
CN101020772B (zh) * 2006-02-16 2010-11-17 现代摩比斯株式会社 聚丙烯复合组合物
CN101305042B (zh) * 2005-11-10 2012-05-02 3M创新有限公司 经填充的聚合物复合材料
US10696831B2 (en) 2015-08-13 2020-06-30 3M Innovative Properties Company Polyolefin composition comprising hollow glass microspheres

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100004381A1 (en) * 2006-12-13 2010-01-07 Avakian Roger W Functionalized translucent compounds
BR112013005527B1 (pt) 2010-09-08 2020-10-13 3M Innovative Properties Company classificação de microesferas ocas de vidro, compósito compreendendo a mesma, e seu método para produção.
JP5542733B2 (ja) * 2011-04-22 2014-07-09 日立アプライアンス株式会社 樹脂成形体，掃除機配管および掃除機
KR101307231B1 (ko) 2011-09-22 2013-10-02 박종순 자동차 내, 외장재용 재활용 복합 폴리프로필렌
EP2935444B1 (en) 2012-12-20 2019-09-18 3M Innovative Properties Company Composite particles including a fluoropolymer, methods of making, and articles including the same
EP3090022B1 (en) 2013-12-30 2018-09-05 3M Innovative Properties Company Poly(methylpentene) composition including hollow glass microspheres and method of using the same
WO2015103099A1 (en) 2013-12-30 2015-07-09 3M Innovative Properties Company Polyolefin composition including hollow glass microspheres and method of using the same
US10494525B2 (en) 2015-02-27 2019-12-03 3M Innovative Properties Company Polyamide composition including hollow glass microspheres and articles and methods relating to the same
KR20220009981A (ko) 2019-05-15 2022-01-25 쓰리엠 이노베이티브 프로퍼티즈 컴파니 입자들을 상호 연결하는 중합체성 요소를 포함하는 필름

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1110930A (en) * 1966-04-13 1968-04-24 Monsanto Co Polymeric composition and process of preparation
US3769126A (en) * 1970-01-30 1973-10-30 Westinghouse Electric Corp Resinous-microsphere-glass fiber composite
EP0336780A2 (en) * 1988-04-08 1989-10-11 Mitsui Petrochemical Industries, Ltd. Thermoplastic resin or elastomer composition having excellent paint adhesion and laminate comprising layer of said thermoplastic elastomer and polyurethane layer
EP0436198A2 (en) * 1989-12-21 1991-07-10 OSi Specialties, Inc. Process for the production of glass fiber reinforced composite material
EP0508303A1 (en) * 1991-04-09 1992-10-14 Idemitsu Kosan Company Limited Thermoplastic resin composition
US5597522A (en) * 1992-06-19 1997-01-28 Shell Research Limited Method of making polyolefin/filler composite materials

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3365315A (en) * 1963-08-23 1968-01-23 Minnesota Mining & Mfg Glass bubbles prepared by reheating solid glass partiles
US4243575A (en) * 1979-07-25 1981-01-06 General Electric Company Filled thermoplastic resin compositions
GB8320086D0 (en) * 1983-07-26 1983-08-24 Ciba Geigy Ag Spherical fused silica
JP2574168B2 (ja) * 1988-05-20 1997-01-22 チッソ株式会社 プロピレン重合体組成物
AU659314B2 (en) * 1992-06-19 1995-05-11 Shell Internationale Research Maatschappij B.V. Polyolefin/filler composite materials and their use
JPH06172591A (ja) * 1992-12-10 1994-06-21 Nippon Petrochem Co Ltd 軽量・高剛性樹脂組成物
JPH06178385A (ja) * 1992-12-10 1994-06-24 Nippon Petrochem Co Ltd 電気音響変換器
JPH06340782A (ja) * 1993-05-31 1994-12-13 Nippon Petrochem Co Ltd 無機微小中空体含有樹脂組成物
EP0696621B1 (en) * 1994-02-02 2000-10-11 Mitsubishi Rayon Co., Ltd. Coating composition and surface-coated molding produced therewith
EP1221464B1 (en) * 2001-01-09 2007-09-26 Sumitomo Wiring Systems, Ltd. Resin composition, method of making it and electrical wire covered with it
JP2004169049A (ja) * 2002-11-15 2004-06-17 Polyplastics Co 環状オレフィン系樹脂成形品表面への金属複合方法及び金属複合化環状オレフィン系樹脂成形品

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1110930A (en) * 1966-04-13 1968-04-24 Monsanto Co Polymeric composition and process of preparation
US3769126A (en) * 1970-01-30 1973-10-30 Westinghouse Electric Corp Resinous-microsphere-glass fiber composite
EP0336780A2 (en) * 1988-04-08 1989-10-11 Mitsui Petrochemical Industries, Ltd. Thermoplastic resin or elastomer composition having excellent paint adhesion and laminate comprising layer of said thermoplastic elastomer and polyurethane layer
EP0436198A2 (en) * 1989-12-21 1991-07-10 OSi Specialties, Inc. Process for the production of glass fiber reinforced composite material
EP0508303A1 (en) * 1991-04-09 1992-10-14 Idemitsu Kosan Company Limited Thermoplastic resin composition
US5597522A (en) * 1992-06-19 1997-01-28 Shell Research Limited Method of making polyolefin/filler composite materials

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1919915B (zh) * 2005-08-26 2010-10-13 海尔集团公司 用于冰箱上的改性聚丙烯材料及其制造方法
CN101305042B (zh) * 2005-11-10 2012-05-02 3M创新有限公司 经填充的聚合物复合材料
CN101020772B (zh) * 2006-02-16 2010-11-17 现代摩比斯株式会社 聚丙烯复合组合物
JP2007297432A (ja) * 2006-04-28 2007-11-15 Tokyo Printing Ink Mfg Co Ltd 断熱性樹脂組成物
WO2008090235A3 (en) * 2007-02-28 2008-09-25 Solvay Advanced Polymers Llc Thermoplastic compositions containing microspheres
US8362114B2 (en) 2007-02-28 2013-01-29 Solvay Advanced Polymers, L.L.C. Thermoplastic compositions containing microspheres
US10696831B2 (en) 2015-08-13 2020-06-30 3M Innovative Properties Company Polyolefin composition comprising hollow glass microspheres

Also Published As

Publication number Publication date
CN1902276A (zh) 2007-01-24
EP1709115B1 (en) 2007-04-25
JP2007517128A (ja) 2007-06-28
EP1709115A1 (en) 2006-10-11
DE602004006170T2 (de) 2008-01-10
US20070116942A1 (en) 2007-05-24
ATE360662T1 (de) 2007-05-15
DE602004006170D1 (de) 2007-06-06

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