WO2005045924A1 - Technique avancee de formation de transistors a regions source et drain de hauteur differente - Google Patents

Technique avancee de formation de transistors a regions source et drain de hauteur differente Download PDF

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Publication number
WO2005045924A1
WO2005045924A1 PCT/US2004/031038 US2004031038W WO2005045924A1 WO 2005045924 A1 WO2005045924 A1 WO 2005045924A1 US 2004031038 W US2004031038 W US 2004031038W WO 2005045924 A1 WO2005045924 A1 WO 2005045924A1
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Prior art keywords
regions
semiconductor
semiconductor region
epitaxial growth
raised
Prior art date
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PCT/US2004/031038
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English (en)
Inventor
Ralf Van Bentum
Scott Luning
Thorsten Kammler
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Advanced Micro Devices, Inc.
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Publication date
Priority claimed from DE10351008A external-priority patent/DE10351008B4/de
Application filed by Advanced Micro Devices, Inc. filed Critical Advanced Micro Devices, Inc.
Priority to GB0607742A priority Critical patent/GB2422488B/en
Priority to JP2006537994A priority patent/JP2007528123A/ja
Priority to KR1020067008385A priority patent/KR101130331B1/ko
Publication of WO2005045924A1 publication Critical patent/WO2005045924A1/fr

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • H01L21/82Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
    • H01L21/822Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
    • H01L21/8232Field-effect technology
    • H01L21/8234MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
    • H01L21/823418MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type with a particular manufacturing method of the source or drain structures, e.g. specific source or drain implants or silicided source or drain structures or raised source or drain structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • H01L21/82Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
    • H01L21/822Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
    • H01L21/8232Field-effect technology
    • H01L21/8234MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
    • H01L21/8238Complementary field-effect transistors, e.g. CMOS
    • H01L21/823814Complementary field-effect transistors, e.g. CMOS with a particular manufacturing method of the source or drain structures, e.g. specific source or drain implants or silicided source or drain structures or raised source or drain structures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/665Unipolar field-effect transistors with an insulated gate, i.e. MISFET using self aligned silicidation, i.e. salicide
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66568Lateral single gate silicon transistors
    • H01L29/66613Lateral single gate silicon transistors with a gate recessing step, e.g. using local oxidation
    • H01L29/66628Lateral single gate silicon transistors with a gate recessing step, e.g. using local oxidation recessing the gate by forming single crystalline semiconductor material at the source or drain location

Definitions

  • the present invention generally relates to the fabrication of integrated circuits, and more particularly, to the formation of locally raised semiconductor regions, such as raised drain and source regions of field effect transistors having extremely shallow pn junctions. DESCRIPTION OF THE RELATED ART
  • CMOS complementary metal-oxide-semiconductor
  • a MOS transistor irrespective of whether an n-channel transistor or a p-channel transistor is considered, comprises so-called pn-junctions that are formed at an interface of highly doped drain and source regions with an inversely doped channel region disposed between the drain region and the source region.
  • the conductivity of the channel region is controlled by a gate electrode formed above the channel region and separated therefrom by a thin insulating layer.
  • the conductivity of the channel region depends on the dopant concentration, the mobility of the majority charge carriers, and on - for a given extension of the channel region in the transistor width direction - the distance between the source and drain region, which is also referred to as channel length.
  • the conductivity of the channel region substantially determines the characteristics of the MOS transistors.
  • the channel length represents a dominant design criterion and a size reduction thereof provides for an increased operating speed of the integrated circuits.
  • the depth of the source and drain regions with respect to an interface formed by the gate insulating layer and the channel region has to be decreased as the channel length is reduced so as to maintain the required controllability of the conductive channel.
  • the depth of the source and drain regions substantially determines the sheet resistance thereof, which may not be arbitrarily reduced by correspondingly increasing the dopant concentration in the source and drain regions, since an extremely high dopant concentration may give rise to increased leakage currents.
  • the dopants implanted into these regions at very high concentrations may not be completely activated by conventional rapid thermal anneal cycles without negatively affecting the overall dopant profile within the source and drain regions.
  • an increased dopant concentration requires higher temperatures and/or a prolonged duration of the corresponding anneal cycles, thereby, however, influencing the dopant profile forming the pn junctions by the inevitable thermal diffusion of the dopants, which finally may lead to a non-acceptable variation of the finally achieved channel length.
  • the conductivity thereof is frequently increased by forming a metal suicide of superior conductivity compared to a highly doped silicon.
  • the penetration depth of the metal silicide is restricted by the depth of the pn junctions, the improvement in conductivity in these regions is therefore coupled to the depth of the corresponding pn junctions.
  • a corresponding metal silicide is simultaneously formed on the gate electrode, wherein a shallow junction depth therefore also creates a very shallow metal silicide in the gate electrode, thereby providing only limited improvement in gaining superior gate electrode conductivity.
  • extremely shallow source and drain regions may be formed by raising the source and drain regions above the gate insulation layer/channel region interface and maintaining the drain-source dopant concentration at an acceptable level while providing for the possibility of forming highly conductive metal silicide regions without being restricted by the actual depth of the pn junctions due to the increased size of the raised drain and source regions.
  • Fig. la schematically shows a cross-sectional view of a field effect transistor 100 at an early manufacturing stage.
  • the transistor 100 comprises the substrate 101, for instance a bulk silicon substrate or an SOI (silicon on insulator) substrate including a buried insulating layer.
  • a substantially crystalline layer 102 is formed with a thickness that is appropriate for forming pn junctions and a channel region therein.
  • the transistor 100 may represent an SOI transistor with a thickness of the silicon layer 102 in the range of approximately 20-100nm.
  • a gate electrode 103 comprised of polysilicon, is formed above the silicon layer 102 and is separated therefrom by a gate insulation layer 104.
  • the gate insulation layer 104 may be formed in sophisticated devices by a nitrogen containing silicon dioxide layer with a thickness of approximately 0.6-4nm.
  • the residue 105 of an anti-reflective coating covers a top surface 103a of the gate electrode 103, while the sidewalls 103b thereof as well as the remaining surface of the silicon layer 102 are covered by an oxide liner 106.
  • the transistor 100 as shown in Fig. la may be formed in accordance with the following process flow.
  • the substrate 101 may be obtained by a manufacturer of respective substrates in the form of a silicon bulk substrate or in the form of an SOI substrate, wherein the SOI substrate may comprise a crystalline silicon layer that may be formed in accordance with well-established wafer bonding techniques.
  • the silicon layer 102 having the appropriate thickness may then be formed by corresponding process techniques, such as chemical mechanical polishing to thin a given silicon layer of an SOI substrate to a desired thickness and/or by epitaxial growth of silicon on the exposed surface of the SOI substrate or the bulk substrate.
  • the epitaxial growth technique of a semiconductor material is a deposition technique in which the deposited material layer forms a crystalline structure in conformity with the crystalline structure of the underlying material as long as the deposited material is able to form a lattice that is sufficiently similar in structure and lattice spacing to the lattice of the underlying material.
  • an insulating layer is formed having a thickness and a composition that are appropriate for forming the gate insulation layer 104.
  • oxidation and/or deposition techniques may be used as are well established in the art.
  • a polysilicon layer of appropriate thickness is deposited by low-pressure chemical vapor deposition.
  • an antireflective coating for instance comprised of silicon oxynitride, and a resist layer are deposited and are patterned by sophisticated photolithography so as to form an etch mask for a subsequent anisotropic etch process for patterning the gate electrode 103 from the deposited polysilicon layer.
  • the gate insulation layer 104 may be patterned and subsequently the oxide liner 106 may be formed by an appropriately designed oxidation process.
  • Fig. lb schematically shows the transistor 100 having formed thereon sidewall spacer elements 107 comprised of a material, such as silicon nitride, that exhibits a moderately high etch selectivity with respect to the underlying oxide liner 106 so that the spacers 107 may be readily removed after a selective epitaxial growth process.
  • the sidewall spacers 107 may be formed by well-established techniques including the deposition, for instance, by plasma-enhanced chemical vapor deposition, of a silicon nitride layer of a specified thickness and a subsequent anisotropic etch process, which reliably stops on and in the liner oxide 106, thereby leaving the spacers 107.
  • a width 107a of the spacer 107 is readily controllable by appropriately adjusting the thickness of the silicon nitride layer. Hence, a lateral extension of epitaxial growth regions adjacent to the gate electrode 103 is substantially determined by the spacer width 107a.
  • Fig. lc schematically shows the device 100 with selectively grown silicon regions 108 above the silicon layer 102, wherein a lateral distance of the regions 108 from the gate electrode 103 substantially corresponds to the spacer width 107a (cf. Fig. lb) plus the minimal thickness of the liner oxide 106.
  • the transistor 100 as shown in Fig. lc may be obtained by the following processes. Starting from the device as shown in Fig. lb, the liner oxide 106 is selectively etched so as to expose the silicon layer 102 at portions that are not covered by the spacers 107, the gate electrode 103, and any isolation structures (not shown).
  • the liner oxide 106 Before and/or after the removal of the liner oxide 106, well-established cleaning procedures may be carried out so as to remove oxide residues and other contaminants that may have accumulated in a surface region of the silicon layer 102. Thereafter, silicon is selectively grown on exposed portions of the silicon layer 102, thereby forming the silicon regions 108 with a specified thickness in conformity with design requirements. Thereafter, the spacer 107 is removed by a selective etch process, for instance, by using hot phosphoric acid, which exhibits an excellent etch selectivity to silicon dioxide and silicon. During this etch process, the residue 105 on top of the gate electrode 103 may also be removed. Thereafter, a conventional process sequence may be performed, as is the case for transistor devices without having the additional selectively grown silicon regions 108. That is, an appropriate number of sidewall spacers may be formed, followed by appropriately designed implantation sequences, so as to establish a required dopant profile in the silicon layer 102.
  • Fig. Id schematically shows the transistor 100 after the above mentioned transistor formation process using, for instance, three different sidewall spacers.
  • a first sidewall spacer 109 for instance comprised of silicon dioxide, is located adjacent to the oxide liner 106 and has an appropriate thickness for profiling the dopant concentration in the vicinity of the gate electrode 103 during a subsequent implantation sequence.
  • a second spacer 110 is located next to the first spacer 109 and separated therefrom by an additional liner 106a, followed by an oxide line 111 and a third spacer 112.
  • spacers 109 and 112 are appropriately selected so as to obtain the desired dopant extension regions 113 and the drain and source regions 114, thereby defining a channel region 115 between the extensions 113 with a specified channel length 116.
  • the liner 106 is typically etched off the surface portion of the semiconductor layer 102. Therefore, usually the additional liner 106a is deposited prior to the formation of spacer 110. If the first spacer 109 is comprised of silicon nitride the liner 106 is preserved during the anisotropic etch for forming the spacer 109, however, possibly with an inhomogeneous thickness owing to the etch induced damage.
  • the liner 106 may be removed and the additional liner 106a may also be deposited in this case.
  • the formation of the spacers 109, 110 and 112 may be accomplished by well- established spacer technologies, such as described with reference to the spacer 107, wherein the corresponding spacer width may be controlled by the corresponding deposition thicknesses of the respective spacer layers, for instance comprised of silicon nitride, wherein the first spacer 109 and the oxide liner 111 provide for the required etch selectivity in anisotropically patterning the spacers.
  • the above-described process flow enables the formation of required shallow pn junctions in the form of the extensions 113, while nevertheless providing for a low contact resistance to the drain and source regions 114 by providing the additional selectively grown silicon regions 108, which may be used to receive a highly conductive metal silicide, wherein the silicidation process does not adversely affect the extensions 113, nor is the silicidation process restricted by the depth of the extensions 113 and the drain and source regions 114.
  • the process flow described above provides for significant improvements in forming raised drain and source regions, there is still room for improvements with regards to process flexibility so as to enhance the device performance.
  • the gate electrode 103 is also heavily doped, thereby increasing the conductivity thereof.
  • boron is used as a dopant, which, however, exhibits a high difrusivity during anneal processes.
  • the maximum implantation energy for doping the source and drain regions 114 may not be selected as high as it would be desirable in view of obtaining a desired penetration depth in the drain and source regions 114, but instead the integrity of the gate insulation layer 104 and possibly of the channel region 115 with respect to diffusing and/or penetrating boron ions has to be taken into consideration when selecting the implantation parameters, thereby possibly compromising the drain and source characteristics.
  • the present invention is directed to a technique that enables the formation of epitaxially grown semiconductor regions with different heights and/or different dopant concentrations, wherein a high degree of compatibility with the conventional process flow is maintained.
  • Different heights of raised semiconductor regions may be obtained by masking one or more specified regions by means of an epitaxial growth mask while selectively exposing one or more other semiconductor regions during a first epitaxial growth process. Thereafter, one or more further semiconductor regions may be exposed and a second epitaxial growth process may be performed so as to further increase the previously formed epitaxial growth regions and newly growing epitaxial growth regions in the newly-exposed semiconductor regions. This sequence may be repeated if a plurality of differently dimensioned epitaxially grown semiconductor regions are required.
  • raised semiconductor regions may be formed that have different heights so as to more conform to device specific requirements.
  • raised semiconductor regions may be selectively formed by epitaxial growth, and thereafter one or more selected portions of these raised semiconductor regions may be selectively reduced in thickness, by for instance oxidizing the region so as to precisely reduce a height thereof by subsequently removing the oxidized portions.
  • a method comprises forming a first epitaxial growth mask that exposes a portion of a first semiconductor region while keeping a second semiconductor region covered. Then, a first raised semiconductor region is formed in the exposed portion of the first semiconductor region and a second epitaxial growth mask is formed above the second semiconductor region, wherein the second epitaxial growth mask exposes a portion of the second semiconductor region. Finally, a second raised semiconductor region is epitaxially grown in the exposed portion of the second semiconductor region.
  • the method further comprises introducing one or more dopant species while epitaxially growing at least one of the first and the second raised semiconductor regions.
  • a p-type dopant species is introduced into said second raised semiconductor region.
  • drain and source regions are formed in said second semiconductor region by implanting a p-type dopant species.
  • the method further comprises forming a metal silicide in said first and second raised semiconductor regions.
  • a height of at least one of the first and the second raised semiconductor regions is controlled during the epitaxial growth so as to adjust a distance of said metal silicide to a pn junction formed in said drain and source regions.
  • said first and second raised semiconductor regions have differing heights.
  • a method comprises epitaxially growing a first and a second raised semiconductor region above a first and a second semiconductor region, respectively, and forming an oxidation mask above the first raised semiconductor region.
  • the second raised semiconductor region is selectively oxidized to form an oxidized portion above the second raised semiconductor region.
  • the oxidized portion of the second raised semiconductor region is selectively removed.
  • forming an oxidation mask includes depositing a mask layer and selectively removing said mask layer from above said second semiconductor region.
  • At least one of said first and second semiconductor regions comprises a structural element extending above a surface of said first and second semiconductor regions.
  • said structural element comprises a gate electrode structure.
  • the method further includes forming a disposable sidewall spacer adjacent to said gate electrode structure prior to epitaxially growing said first and second raised semiconductor regions.
  • said step of selectively removing said oxidized portion of said second raised semiconductor region results in said first and second raised semiconductor regions having differing heights.
  • a semiconductor device comprises a first gate electrode formed above a first semiconductor region and separated therefrom by a first gate insulation layer.
  • a first raised drain and source region is formed and extends above the first gate insulation layer with a first height.
  • a second gate electrode is formed above a second semiconductor region and is separated therefrom by a second gate insulation layer.
  • a second raised drain and source region is formed and extends above the second gate insulation layer with a second height that differs from the first height.
  • said first and second semiconductor regions are located in a semiconductor layer formed on an insulating layer.
  • Figs. la-Id schematically show cross-sectional views of a conventional transistor device including raised drain and source regions during various manufacturing stages;
  • Figs. 2a-2e schematically show cross-sectional views of two different semiconductor regions during various manufacturing stages, wherein selectively raised semiconductor regions are formed having different heights above the first and second semiconductor regions in accordance with illustrative embodiments of the present invention.
  • Figs. 3a and 3b schematically illustrate a first and a second semiconductor region that receive raised epitaxial growth regions by a common epitaxial growth process, wherein the individual height is adjusted by a selective oxidation process.
  • the capacitance of source and drain junctions may require different values at different device locations, which may be taken into account by correspondingly adjusting the height of raised drain and source regions.
  • the position of the dopant species for defining the source and drain regions with respect to a semiconductor film, in which raised source and drain regions are formed may need to be addressed individually for different circuit elements and/or device regions.
  • a further design criterion is the distance of the silicide interface, usually formed to lower the contact resistivity of drain and source regions, with respect to either the position of the pn junction or with respect to the bottom portion of a semiconductor layer. Hence, this distance may be separately adjusted for various regions of a semiconductor substrate so as to individually enhance the device performance.
  • a p-channel transistor may require raised source and drain regions of reduced height so as to take into account the increased penetration depth and diffusivity of boron. Consequently, by means of the reduced height, the implantation parameters may be selected so as to avoid undue degradation of a gate insulation layer while nevertheless providing for an optimum dopant profile in the source and drain region having the reduced height.
  • a first and a second transistor element is referred to that are formed on respective semiconductor regions which are to receive epitaxially grown semiconductor regions.
  • the present invention should not be restricted to transistor elements, but may be readily applied to any circuit elements requiring the formation of selectively grown epitaxial growth regions of different characteristics; nor is the reference to two different semiconductor regions to be considered as restricting, as the embodiments disclosed herein may be readily applied to a plurality of different semiconductor areas requiring an individually adapted characteristic of the epitaxially grown semiconductor regions.
  • Fig. 2a schematically shows a cross-sectional view of a semiconductor device 200 at an early manufacturing stage.
  • the semiconductor device 200 comprises a substrate 201, which may represent any substrate that is suitable for forming circuit elements thereon.
  • the substrate 201 may represent a bulk semiconductor substrate, such as a silicon substrate, having formed thereon a semiconductor layer 202, such as a substantially crystalline silicon layer.
  • the substrate 201 may represent an insulating substrate, for instance any appropriate substrate having formed thereon an insulating layer, such as a silicon dioxide layer, on which is located the semiconductor layer 202, for example in the form of a crystalline layer.
  • the semiconductor layer 202 represents a crystalline silicon layer with a thickness of approximately 5-50nm that is formed on an insulating layer, often referred to as buried oxide.
  • the semiconductor device 200 further comprises a first device region 240a and a second device region 240b, which are separated from each other and electrically insulated by an isolation structure 220.
  • the isolation structure 220 may be provided in the form of a trench isolation structure that may extend down to the substrate 201 so as to substantially completely electrically insulate the first and second device regions 240a, 240b.
  • first and second device regions 240a, 240b are illustrated as neighboring device regions so as to form, for instance, a complementary pair of field effect transistors, whereas in other embodiments the first and second device regions 240a, 240b may represent areas that are significantly spaced apart from each other within a single chip area or are even located in different chip areas within the substrate 201. For instance, different areas of a semiconductor wafer may require the formation of differently dimensioned epitaxial growth regions so as to provide for integrated circuits having other performance characteristics compared to integrated circuits that are formed on other areas.
  • the first and second device regions 240a, 240b comprise gate electrodes 203a, 203b formed on respective gate insulation layers 204a, 204b.
  • respective liners 206a, 206b for instance comprised of silicon dioxide, are formed on sidewalls of the gate electrodes 203a, 203b and surface portions of the semiconductor layer 202.
  • a top surface of the gate electrodes 203a, 203b are covered by respective cover layers 205a, 205b, which may represent the residue of an anti- reflective coating.
  • a spacer layer 221, for instance comprised of silicon nitride, is formed above the first and second device regions 240a, 240b.
  • an etch mask 222 is formed over the semiconductor device 200 such that the second device region 240b is substantially completely covered so as to avoid or at least slow down a material removal of the spacer layer 221 in the second device region 240b during a subsequent anisotropic etch process.
  • a typical process flow for forming the semiconductor device 200 as shown in Fig. 2a may substantially include the same process steps as previously explained with referenced to Fig. la, wherein the formation of the isolation structure 220 may be accomplished by well-established photolithography, deposition and etch techniques. Furthermore, corresponding implantation cycles with respective masking steps may be performed so as to establish a desired vertical dopant profile in the semiconductor layer 202 for the first and second device regions 240a, 240b in accordance with the device specifications. In addition to the conventional process flow as described with reference to Fig.
  • the etch mask 222 for instance comprised of a resist material, is formed prior to a first anisotropic etch process so as to form sidewall spacers 207a from the spacer layer 221 in the first device region 240a.
  • Fig. 2b schematically shows the semiconductor device 200 after the completion of the anisotropic etch process, during which sidewall spacers 207a have been formed adjacent to the gate electrode 203a.
  • the etch mask 220 is removed and portions of the liner 206a in the first device region 240a are removed so as to expose surface portions 223a of the semiconductor layer 202.
  • the selective removal of the liner 206a may be accomplished by any appropriate etch procedure and, in particular embodiments when the liner 206a is comprised of silicon dioxide, may be achieved by a wet etch process using hydrogen fluoride (HF), whereby under-etch areas 224a may be created. Thereafter, suitable cleaning processes may be performed so as to remove any material residues from the exposed surface portions 223a and/or to remove any contaminants in a surface region of the semiconductor layer 202, wherein the remaining spacer layer 221 reliably maintains an integrity of the second device region 204b.
  • HF hydrogen fluoride
  • a first epitaxial growth process may be performed, wherein the remaining spacer layer 221 acts as a "global" epitaxial growth mask for the second device region 240b so as to avoid any semiconductor growth on the second device region 240b.
  • the sidewall spacers 207a and the cap layer 205a serve as a "local" growth mask and restrict the epitaxial growth to the surface portion 223a and to the underetch regions 224a that may have been formed during the partial removal of the liner 206a.
  • Fig. 2c schematically shows the semiconductor device 200 with an epitaxially grown semiconductor region 208a that is selectively grown in the first device region 240a.
  • a thickness or height of the epitaxially grown semiconductor region 208a is adjusted during the epitaxial growth process such that the growth process results, in combination with a further epitaxial growth process for forming an epitaxially grown semiconductor region in the second device region 240b, and possibly in combination with additional epitaxial steps when a plurality of differently dimensioned epitaxially grown semiconductor regions is to be formed, in the finally desired height of the semiconductor region 208a.
  • one or more dopant species may be introduced during the epitaxial growth of the semiconductor region 208a, thereby providing for an increased process flexibility in subsequent implantation steps for forming drain and source regions by ion implantation.
  • the initial height of the epitaxially grown semiconductor region 208a may range from approximately 1-10 nm.
  • a second etch mask 225 is illustrated that substantially covers the first device region 240a so as to substantially avoid any material removal and/or damage in the first device region 240a during a subsequent anisotropic etch process for patterning the remaining spacer layer 221 in the second device region 240b.
  • Fig. 2d schematically shows the device 200 after completion of the anisotropic etch process, resulting in the formation of sidewall spacers 207b adjacent to the gate electrode 203b. Moreover, the liner 206b is partially removed in the second device region 240b so as to expose the surface portions 223b of the semiconductor layer 202, wherein, depending on the removal process, underetch portions 224b may have been formed, as is also explained with reference to the first device region 240a.
  • a further (second) epitaxial growth process is performed, wherein the process parameters are selected so as to obtain a required height of an epitaxially grown region in the second device region 240b if this epitaxial growth process is the last process for the device 200.
  • the process parameters are selected so as to obtain an intermediate height, which in combination with the subsequent epitaxial growth, results in the finally desired height for the first and second device regions 240a, 240b and the further device region.
  • Fig. 2e schematically shows the device 200 after completion of the second epitaxial growth step to form raised semiconductor regions 218b adjacent to the gate electrode 203b and forming additional epitaxial growth regions 218a on top of the previously grown region 208a.
  • the combination of the epitaxially grown regions 208a, 218a results in a final thickness 219a that is larger than a corresponding final thickness 219b in the second device region 240b.
  • the second device region 240b may represent a p-channel transistor, wherein the reduced thickness 219b of the raised semiconductor regions 218b compared to the thickness 219a provides for the possibility to deeply implant boron ions into the semiconductor layer 202, while maintaining the superior performance of an n-channel transistor having the increased height 219a and nevertheless avoiding an undue degradation of the gate insulation layer 204b by penetrating and diffusing boron ions.
  • the respective heights 219a, 219b may be selected so as to individually adjust the overall capacitance of drain and source regions of the semiconductor devices, or to correspondingly adjust the distance between metal silicide regions, which are typically formed for enhancing the conductivity of source and drain regions still to be formed, and the bottom of the semiconductor layer 202.
  • the further manufacturing process may be resumed substantially in a similar way as is described with reference to Figs, lc and Id. That is, the spacers 207a, 207b and the cap layers 205a, 205b may be removed, for instance by hot phosphoric acid, and corresponding implantation cycles using corresponding spacers as required may be performed so as to obtain a desired dopant profile as is necessary for corresponding drain and source regions, including respective extension regions. Thereafter, corresponding metal silicide regions may be formed at least in the raised semiconductor regions 218a and 218b in accordance with design requirements.
  • the separation between two different device regions may not necessarily be represented by a trench isolation, but may simply be represented by any physical boundary, or may be simply defined by design requirements based on specific criteria, such as functionality of a circuit layout and the like.
  • the separation into the first and second device regions 240a, 240b is substantially obtained by the formation of the first and second etch masks 222, 225, wherein, owing to alignment errors due to the photolithography involved in forming the first and second etch masks 222, 225 may result in an intermediate region that may experience an anisotropic etch atmosphere during patterning of the sidewall spacers 207a and during patterning of the sidewall spacers 207b.
  • the liner 206a may advantageously be formed with an appropriate thickness so as to have the capability to withstand two anisotropic etch procedures substantially without exposing any underlying material layers to the anisotropic etch ambient.
  • the spacer layer 221 (cf. Fig. 2a) is anisotropically patterned in the first device region 240a while being covered in the second device region 240b, thereby acting as a "local" epitaxial growth mask in the first device region 240a in the form of the spacers 207a.
  • the non-patterned spacer layer 221_ serves as a "global" epitaxial growth mask in the second device region 240b (cf. Fig. 2b).
  • the spacer layer 221 may be patterned simultaneously in the first and second device regions 240a, 240b, similarly to the conventional approach, and after forming corresponding sidewall spacers 207a, 207b in the first and second device regions 240a, 240b, a corresponding etch mask, such as the mask 222, may be formed in one of these regions so that in a subsequent process for removing, for instance, the liner 206a, the corresponding liner 206b is maintained in the second device region 240b.
  • the liner 206b may then serve in the subsequent epitaxial growth process, in combination with the spacer 207b and the cover layer 205b, as a global growth mask, substantially preventing the epitaxial growth of semiconductor material on the second device region 206b.
  • the subsequent manufacturing process may then be continued as is described with reference to Fig. 2d.
  • the liner 206b is to act as an epitaxial growth mask, it may be advantageous to provide the liner 206a and 206b with an increased thickness compared to the conventional approach so as to substantially maintain the integrity of the liner 206b when corresponding cleaning processes are performed so as to remove any material residues from the exposed surface portions 223a (cf. Fig. 2b) prior to the first epitaxial growth process.
  • the adhesion characteristics of silicon to the liner material of the liner 206b may differ from the adhesion characteristics of the spacer layer 221, for instance comprised of silicon nitride, a corresponding adaptation of the epitaxial growth parameters may be required.
  • the temperature of the epitaxial growth process may be correspondingly adapted so as to substantially avoid any semiconductor deposition on the exposed liner 206b.
  • a semiconductor device 300 comprises a first device region 340a and a second device region 340b.
  • the first device region 340a comprises a gate electrode 303a formed above a semiconductor layer 302, which in turn is formed on an appropriate substrate 301.
  • a gate insulation layer 304a separates the gate electrode 303a from the semiconductor layer 302.
  • a disposable sidewall spacer 307a is formed near sidewalls of the gate electrode 303a and is separated therefrom by a liner 306a.
  • Epitaxially grown semiconductor regions 308a are formed adjacent to the disposable sidewall spacers 307a with a specified thickness or height 319.
  • the epitaxially grown regions 308a may include a liner 309a, for instance in the form of an oxidized portion.
  • the second device region 304b may comprise corresponding circuit components that are indicated by the same reference numerals, except for the letter "b".
  • the height of the epitaxially grown regions 308b is substantially the same as for the first device region 340a since the regions 308a and 308b are formed by a common epitaxial growth process. The same holds true for the liner 309b.
  • the device 300 comprises a mask layer 321, for instance comprised of silicon nitride, wherein a thickness of the mask layer 321 is selected so as to be able to substantially avoid or at least significantly reduce an oxidation of an underlying material when exposed to an oxidizing ambient.
  • the mask layer 321 may have a thickness of approximately less of lnm to several nm when comprised of silicon nitride.
  • an etch mask 322 is formed over the second device region 340b.
  • the etch mask 322 may be comprised of a resist layer or any other appropriate material having the capability to withstand a specified etch chemistry used for removing the mask layer 321 from the first device region 340a.
  • a typical process flow for forming the device 300 as shown in Fig. 3a may comprise the same processes as previously described with reference to Figs. 2a to 2e, so as to selectively form the epitaxial growth regions 308a, 308b.
  • the liner 309a, 309b may be formed by, for instance, oxidizing the device 300.
  • the mask layer 321 may be deposited, for instance by plasma-enhanced chemical vapor deposition, and subsequently the etch mask 322 may be formed by well-established photolithography.
  • the mask layer 321 may be selectively removed from the first device region 340a, for instance by a selective isotropic or anisotropic etch process that stops in or on the liner 309a.
  • the mask layer 321 is highly conformally deposited over the first device region 340a, the disposable spacers 307a and the cover layer 305a remain substantially intact if a substantially anisotropic etch recipe is applied for removing the mask layer 321.
  • a substantially anisotropic etch recipe is applied for removing the mask layer 321.
  • the thickness of the disposable spacer 307a is correspondingly increased by the etch process by the layer thickness of the mask layer 321. Since the thickness of the layer 321 may be selected to be relatively thin, the increase of the width of the disposable spacer 307a does not substantially affect the further processing.
  • the etch mask 322 is also removed and thereafter the device 300 is exposed to an oxidizing ambient, for instance, to an oxygen containing atmosphere at an elevated temperature so as to initiate a highly controllable selective oxidation process in the epitaxially grown region 308, while an oxidation of the regions 308b is substantially avoided or at least significantly slowed down by the remaining mask layer 321 preserved on the second device region 340b.
  • an oxidizing solution may be applied to the device 300, possibly after first removing the liner 309a, for instance by means of a wet chemical etch process on the basis of hydrogenated fluoride (HF).
  • Fig. 3b schematically shows the device 300 after the completion of the highly controllable selective oxidation process, wherein an oxidized portion 310a having a well-controlled thickness 311a has been formed above the epitaxially grown region 308a. Thereafter, the oxidized portion 310a may be removed or the thickness thereof may be reduced, for instance to a value that is similar to that of the liner 309b of the second device region 340b. The removal of the oxidized portion or the thickness reduction thereof may be accomplished by a wet etch process on the basis of, for example, HF.
  • the disposable spacers 307a and the cap layer 305a as well as the remaining mask layer 321 and the disposable spacers 307b and the cap layer 305b may be removed, for instance in a common etch process using hot phosphoric acid.
  • the liner 309b and possibly the remaining part of the oxidized portion 310a may be removed selectively to the underlying semiconductor material, thereby providing an epitaxially grown region 308a having an effective height 319a and providing a height 319b of the region 308b in the second device region 340b.
  • the selective oxidation process for forming the oxidized portion 310a exhibits a superior controllability compared to typical anisotropic or isotropic etch procedures, the finally obtained height 319a is adjustable with high precision so that corresponding device characteristics may be finely tuned.
  • the further process for completing the semiconductor device 300 may be conducted as previously explained with reference to Fig. 2b.
  • the present invention provides for an improved technique to form circuit elements having epitaxially grown semiconductor regions, the heights of which may be individually adjusted in two or more different device regions by selectively providing a global epitaxial growth mask or by selectively reducing a thickness of epitaxially grown regions. In some embodiments both methods may be combined so as to provide superior flexibility in adjusting the height of epitaxially grown regions in a plurality of device regions. Since epitaxially grown raised source and drain regions are currently considered a preferred technique for forming extremely scaled transistor devices, the present invention is particularly advantageous for devices of critical dimensions of approximately 90 nm or less.
  • the present invention relates to microelectronic structures and is therefore industrially applicable

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Ceramic Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)
  • Thin Film Transistor (AREA)

Abstract

Selon l'invention, la hauteur de régions à semi-conducteurs formées par épitaxie dans des dispositifs à semi-conducteurs extrêmement peu profondes peut être ajustée de manière individuelle pour des régions de dispositif différentes en ce qu'au moins deux étapes de formation épitaxiale peuvent être mises en oeuvre, un masque de formation épitaxiale supprimant sélectivement la formation d'une région à semi-conducteurs dans une région de dispositif spécifiée. Dans d'autres modes de réalisation, un procédé de formation épitaxiale commun peut être mis en oeuvre pour au moins deux régions de dispositif différentes, et un procédé d'oxydation sélective peut ensuite être mis en oeuvre sur des régions de dispositif différentes pour réduire avec précision la hauteur des régions à semi-conducteurs préalablement formées par épitaxie dans les zones sélectionnées.
PCT/US2004/031038 2003-10-31 2004-09-17 Technique avancee de formation de transistors a regions source et drain de hauteur differente WO2005045924A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB0607742A GB2422488B (en) 2003-10-31 2004-09-17 An advanced technique for forming transistors having raised drain and source regions with different height
JP2006537994A JP2007528123A (ja) 2003-10-31 2004-09-17 高さが異なる隆起したドレインおよびソース領域を有するトランジスタを形成するための先進技術
KR1020067008385A KR101130331B1 (ko) 2003-10-31 2004-09-17 서로 다른 높이를 갖는 융기 드레인 및 소스 영역들을구비한 트랜지스터를 형성하는 고급기술

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DE10351008.7 2003-10-31
DE10351008A DE10351008B4 (de) 2003-10-31 2003-10-31 Verfahren zur Herstellung von Transistoren mit erhöhten Drain- und Sourcegebieten mit unterschiedlicher Höhe sowie ein Halbleiterbauelement
US10/862,518 2004-06-07
US10/862,518 US7176110B2 (en) 2003-10-31 2004-06-07 Technique for forming transistors having raised drain and source regions with different heights

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WO2006118799A1 (fr) * 2005-05-03 2006-11-09 Advanced Micro Devices, Inc. Methodologie pour deposer une couche a croissance epitaxiale selective (seg) dopee pour des zones source/drain en relief

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Publication number Priority date Publication date Assignee Title
DE102005030583B4 (de) * 2005-06-30 2010-09-30 Advanced Micro Devices, Inc., Sunnyvale Verfahren zur Herstellung von Kontaktisolationsschichten und Silizidgebieten mit unterschiedlichen Eigenschaften eines Halbleiterbauelements und Halbleiterbauelement

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US20020005553A1 (en) * 2000-07-06 2002-01-17 Fumio Ootsuka Semiconductor integrated circuit device and a method of manufacturing the same
US20020158292A1 (en) * 2000-07-27 2002-10-31 Mitsubishi Denki Kabushiki Kaisha Method of making field effect transistor
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KR101130331B1 (ko) 2012-03-27
GB2422488B (en) 2008-02-13
GB0607742D0 (en) 2006-05-31
KR20060108641A (ko) 2006-10-18
JP2007528123A (ja) 2007-10-04

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