WO2005034627A1 - Composition pesticide - Google Patents

Composition pesticide Download PDF

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Publication number
WO2005034627A1
WO2005034627A1 PCT/JP2004/015460 JP2004015460W WO2005034627A1 WO 2005034627 A1 WO2005034627 A1 WO 2005034627A1 JP 2004015460 W JP2004015460 W JP 2004015460W WO 2005034627 A1 WO2005034627 A1 WO 2005034627A1
Authority
WO
WIPO (PCT)
Prior art keywords
bacillus
dichloro
benzene
trifluoromethylpyridine
pests
Prior art date
Application number
PCT/JP2004/015460
Other languages
English (en)
Japanese (ja)
Inventor
Shigeru Saito
Shinji Isayama
Original Assignee
Sumitomo Chemical Company, Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Company, Limited filed Critical Sumitomo Chemical Company, Limited
Publication of WO2005034627A1 publication Critical patent/WO2005034627A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/20—Bacteria; Substances produced thereby or obtained therefrom
    • A01N63/22—Bacillus
    • A01N63/23—B. thuringiensis

Definitions

  • the present invention relates to a pesticidal composition, more specifically, 3,5-dichloro-11- (3,3-dichloro-2-propenyloxy) -4- [3- (5-trifluoromethylpyridine).
  • the present invention relates to a pesticidal composition containing (2-yloxy) propyloxy] benzene and an insecticidal protein of Bacillus thuringiesis.
  • 1,5-Dichrolic 1- (3,3-dichloro-2-propenyloxy) -4- [3- (5-trifluoromethylpyridine-2-yloxy) propyloxy] benzene may have insecticidal activity It is known (W096 / 1190.9).
  • Insecticidal protein of [3- (5-trifluoromethylpyridine-1-2-yloxy) propyloxy] benzene (hereinafter sometimes referred to as the present compound) and Bacillus thuringiesis (hereinafter referred to as Bacillus thuringiesis)
  • Bacillus thuringiesis A pest control composition characterized by containing (hereinafter, referred to as the present composition). Sometimes. );
  • a pesticidal composition comprising: (Bacillus thuringiesis) an insecticidal protein;
  • insecticidal protein is a Bacillus thuringi esis culture, a viable cell, or a spore, the cell has been killed by heat or chemical means, or the cell of the cell.
  • a pest control method which comprises applying an effective amount of both Bacillus thuringiesis and a pesticidal protein to a plant, a pest or a habitat of a pest to be protected;
  • the compound used as one active ingredient in the composition of the present invention has the following formula (1)
  • the present protein used as another active ingredient in the composition of the present invention is not particularly limited as long as it is an insecticidal protein of Bacillus thuringiesis.
  • proteins are naturally produced by bacteria belonging to Bacillus th uringiesis. Among them, for example, among them, for example, among them, for example, among them, for example, kurstaki, aisawai, tenebrionis (tenebrionis), japonensis-buibu ( japonensis Buibui). It is preferably used in the composition of the present invention.
  • this protein may be produced by a bacterium belonging to Bacillus thuringiesis which exists in nature, and may be a transformant produced by a conventional genetic engineering technique. (Eg, Escherichia coli, Bacillus subtilis, plants, etc.).
  • a gene having a nucleotide sequence encoding the amino acid sequence of the present protein (hereinafter sometimes referred to as the present gene) used for producing such a transformant, (1) naturally occurring It may be a gene that has been cloned from existing genes, or (2) deletion, substitution or partial deletion of some bases in the base sequence of a gene that has been cloned from naturally occurring genes.
  • It may be a gene into which the addition is artificially introduced [that is, a gene obtained by subjecting a naturally-occurring gene to a mutation treatment (partial mutation introduction treatment, mutation treatment, etc.)], or It may be a gene that has been synthetically synthesized.
  • the microorganisms as described above may be isolated from nature or purchased from a strain preservation organization, etc., and artificially purified from such microorganisms according to ordinary microbiological or genetic engineering techniques. It may be produced in a special way.
  • Bacteria belonging to Bacillus thuringiesis the presence or absence of insecticidal proteins in the bacteria is determined by, for example, biological activity.
  • Bacteria belonging to Bacillus thuringiensis may be selected by confirming according to an evaluation method, a microscopic observation method, or the like.
  • the present protein used in the composition of the present invention may be the protein itself as it is, for example, a culture of Bacillus thuringiesis, a viable cell, a spore, or a bacterium that is killed by heat or chemical means. It may be a fungus treated, or a pesticidal protein contained in a crushed product of the fungus.
  • a general bacterium culture medium, a normal bouillon liquid medium, and the like can be mentioned. Any medium can be used.
  • a culture containing bacteria belonging to Bacillus thuringiesis and a product thereof, which has been cultured using the above-described medium is centrifuged and / or dried together with the medium, and the present invention is performed. It can be used as the present protein, which is the other active ingredient of the composition.
  • the insecticidal protein itself isolated from the culture according to a known method may be used as it is as the present protein.
  • the molecular weight of this protein is generally tens of thousands to several hundred thousand daltons.
  • This protein is released together with spores in the form of crystalline material when bacteria belonging to Bacillus thuringiesis that have undergone a predetermined number of divisions are disrupted.
  • a commercially available BT preparation may be used, and preferably, Dipole (registered trademark) (Sumitomo Chemical Co., Ltd.), Esmarck (registered trademark) (Sumitomo) Chemical Industry Co., Ltd.), Flowpack (registered trademark) (Sumitomo Chemical Co., Ltd.), Zentari (registered trademark) (Sumika Takeda Agrochemical Co., Ltd.), Novodor (registered trademark) (Valent Biosciences co.), Buoy Hunter (registered trademark) (Sumitomo Chemical Co., Ltd .: Business transferred from Kupo Yu Biotech on December 12, 2003), Design (registered trademark) (Thermo Trilogy co.), Etc.
  • the composition of the present invention can be used for controlling pests (for example, insects and harmful mites) in a wide range of agricultural and horticultural industries.
  • pests for example, insects and harmful mites
  • Hemiptera Insects such as the brown beetle (Laodelphax striatellus), the brown beetle (Nil aparvata lugens), the stag beetle (Sogatella furcifera), the black-tailed tuna 3n / ⁇ f (Nep otettix cincticeps), and the cyca midea Aphids such as leafhoppers, Aphis gossypii, Aphid aphids (Myzus persicae), and aphids, Lippaphis pserudobrassicae; stink bugs; Bemisia tabaci), whiteflies such as Bemisia argent ifo Hi, beetles, dung beet
  • Lepidopteran insect pests Chilo suppressalis, Cnaphalocroci s medinalis, Ostrinia nubilalis, Parapediasia teierrella, etc., and Spodoptera litura.
  • Toto Spodoptera exigua
  • Atoto Pseudaletia separata
  • Totoga Memestra brasicae
  • Tamanaya sword Agrotis ipsilon
  • Iraksaginjiba Trichoplusia ni
  • Tamanaginpa Autographa nigrisigna sp.
  • Helicoveira spp. Airis spp., Etc., White butterfly, Pieris rapae crucivora, White butterfly, Adoxophyes onmai, Apple cocoa Kumonhamaju (Adoxophyes orana fasciata), Nashihimenshi (Grapholita mo lest a), Codling Moss (Cy dia pomonella), toads such as
  • Diptera pests Ligustrum flies (Liriomyza trifolii), Nasal flies (Lir) iomyza bryoniae), tomato nomomoglino ⁇ e (Li riomyza sat ivae), omenasuji hamogrinoe (Liriomyza as terivora), namoglieno (Chromatomyia hort icol a), etc. , Anopheles, Mussidae, Musca domestica, Black flies, Drosophila, Anopheles, Thysanidae, Fruit flies, Drosophila, Drosophila, Aphids, Bubu, Dwarfs
  • Coleopteran pests beetles, scarab beetles, weevils, beetles, ladybirds, beetles, beetles, etc.
  • Thrips of the order Thrips palmi Thrips palmi, etc., genus Frankliniella, such as Franklin iniel la occidental is, Sci l tothrips dorsal is And others of the genus Siltthrips, such as
  • Hymenopteran pests wasps, squirrels, wasps, etc.
  • Pests of the order Coleoptera Wild flea
  • Termite pests termites such as the termite (Ret icul i termes speratus) and the termite (Coptotermes formosanus)
  • composition of the present invention are not particularly limited, but include cabbage, Chinese cabbage, Chinese cabbage, Japanese radish, broccoli, lettuce, spinach, tomato, eggplant, bell pepper, capsicum, kiyuri, watermelon, melon, asparagus.
  • the mixing ratio of the present compound and the present protein may be any mixing ratio that provides a synergistic effect.
  • a weight ratio of 1: 10000 to 10000: 1 may be used.
  • the present compound and the present protein may be used as a mixture without adding any other component, but usually, the mixture is further mixed with a solid carrier, a liquid carrier, Oils, emulsions, water-dispersible powders, water-dispersible granules, suspensions in water It is preferably used as various preparations such as powders, granules, aerosols, microcapsules, heat fumigants, poison baits and the like. These preparations usually contain the composition of the present invention as an active ingredient in an amount of about 0.01 to 95% by weight.
  • solid carrier used in the formulation examples include clays (kaolin clay, diatomaceous earth, bentonite, fubasami clay, acid clay, etc.), synthetic hydrous silicon oxide, talc, ceramics, other inorganic minerals ( Fine powders and granular materials such as sericite, quartz, sulfur, activated carbon, calcium carbonate, hydrated silica, etc., and chemical fertilizers (ammonium sulfate, phosphorous ammonium, ammonium nitrate, urea, salt ammonium, etc.).
  • clays kaolin clay, diatomaceous earth, bentonite, fubasami clay, acid clay, etc.
  • synthetic hydrous silicon oxide talc
  • ceramics other inorganic minerals
  • fine powders and granular materials such as sericite, quartz, sulfur, activated carbon, calcium carbonate, hydrated silica, etc.
  • chemical fertilizers ammonium sulfate, phosphorous ammonium, ammonium nitrate, urea, salt ammonium
  • liquid carrier examples include water, alcohols (methanol, ethanol, etc.), ketones (acetone, methyl ethyl ketone, etc.), and aromatic hydrocarbons (toluene, xylene, etc.). , Ethylbenzene, methylnaphthalene, etc.), non-aromatic hydrocarbons (hexane, cyclohexane, kerosene, gas oil, etc.), esters (ethyl acetate, butyl acetate, etc.), nitriles (acetonitrile, isoptyronitrile) ), Ethers (diisopropyl ether, dioxane, etc.), acid amides (N, N-dimethylformamide, N, N-dimethylacetoamides), halogenated hydrocarbons (dichloromethane, trichloroethane, carbon tetrachloride, etc.) ), Dimethylsulfoxide, vegetable oils (
  • gaseous carrier that is, the propellant
  • the gaseous carrier include, for example, CFC gas, butane gas, liquefied petroleum gas, dimethyl ether, and carbon dioxide gas.
  • surfactants include alkyl sulfates, alkyl sulfonates, alkyl aryl sulfonates, alkyl aryl ethers and polyoxyethylene compounds, polyethylene glycol ethers, polyhydric alcohol esters, and sugars. Alcohol derivatives and the like.
  • auxiliaries include, for example, casein, gelatin, sugars (starch, arabia gum, cellulose derivatives, alginic acid, etc.), lignin derivatives, bentonite, synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, Acrylic acid, etc.), PAP (isopropyl isopropyl phosphate), BHT (2,6-di-tert-butyl-4 monomethylphenol), BHA (2-teri-butyl-4-methoxyphenol and 3-tert-butyl-4) -Methoxyphenol), vegetable oils, mineral oils, surfactants, fatty acids, fatty acid esters and the like.
  • Base materials for poison bait include, for example, bait ingredients such as cereal flour, vegetable oil, sugar, and crystalline cellulose; antioxidants such as dibutylhydroxytoluene and nordihydroguaiaretic acid; preservatives such as dehydroacetic acid; and pepper powder. And inducing flavors such as cheese flavor, evening onion flavor and the like.
  • Suspension in water ⁇ Floables such as emulsions in water usually contain about 1 to 75% by weight of the active ingredient compound and about 0.5 to 15% by weight of a suspending aid (for example, protective colloid or thixotrope). About 0 to 10% by weight of auxiliary agents (eg, antifoaming agent, anti-foaming agent, stable) Agents, spreading agents, penetration aids, antifreezing agents, preservatives, antifungal agents, etc.).
  • auxiliary agents eg, antifoaming agent, anti-foaming agent, stable
  • composition of the present invention can also be prepared by formulating each active ingredient by the above-mentioned formulation technique, and then mixing these formulations. That is, the composition of the present invention may be prepared by mixing a composition prepared in advance with the present compound and a composition prepared in advance with the present protein, depending on the form of the preparation. Also, both can be mixed or used at the time of application.
  • composition of the present invention thus formulated is used as it is or after being diluted with water or the like. It is also possible to mix or use other insecticides, acaricides, nematicides, fungicides, herbicides, plant growth regulators, synergists, fertilizers, soil conditioners, animal feeds, etc. it can.
  • the composition of the present invention is applied to pests, habitats of pests, plants to be protected from pests, and the like. At that time, when the composition of the present invention is formulated into an emulsion, a water-dispersible powder, a water-dispersible granule, a flowable or the like, the composition is usually diluted with water or the like before treatment.
  • the effective amount or application amount of the present composition is generally about at 1 0 0 O m 2 application rate per 0. L ⁇ 1 0 0 0 g.
  • the active ingredient for controlling pests is applied in the form of granules, dusts, oils, etc., it is usually sufficient to apply the active ingredient as it is without any dilution so that the above effective amount or application amount is obtained. .
  • the active ingredient for controlling pests is applied after diluting the emulsion, wettable powder, wettable granule, flowable, etc. in water, dilute it with water so that the above effective amount or application rate is achieved. And then apply.
  • the application concentration of the composition of the present invention is usually about 1 to 100 0 ppm can be raised.
  • the above effective amount or application amount depends on the type of drug product, application period, application place, application method, type of pest, degree of damage, etc., and should be selected as appropriate by increasing or decreasing without affecting the above range. Can be.
  • the “BT culture” described below is defined as a spore suspension 100 1 containing 1 ⁇ 10 3 viable spores per liter of a bacterium belonging to Bacillus thuringiesis, and 50 Om Inoculate a sterilized L-broth liquid medium (100 ml) in a 1-volume flask, shake culture (15 Orpm) for about 2 to 5 days at 25 ° C, and then obtain The spores derived from bacteria belonging to Bacillus thuringiesis and the insecticidal protein were recovered from the culture broth by centrifugation and dried to obtain a culture (ie, one of the present proteins). Form).
  • test solutions diluted to the respective predetermined concentrations were prepared. After injecting artificial feed (about 2 g) into the bottom of a plastic cup (30 ml capacity), 0.2 ml of the test solution was treated. After air-drying for about 2 hours after the treatment, one second-instar larva of the test insect (Heliothis virescens) was released (20 repetitions). Five days after the treatment, the mortality was calculated, and the mortality was corrected by the following formula to calculate the mortality (%).
  • Design® Bacillus tlmr in giensis var. Aizawai strain GC91 (conjugant) Wettable granules preparation, manufactured by Thermo Trilogy Corporation
  • Insecticidal rate (%) 100 X (M t— Mc) / (100— Mc)
  • Test Example 2 Leaf dipping test on Spodoptera litura
  • a 10% emulsion of this compound is mixed with a BT bacteria preparation: Flowback (registered trademark) (Bacillus thuringiensis var. Aizawai), a dry-flowable preparation, manufactured by Sumitomo Chemical Co., Ltd.) and diluted with water.
  • a test solution was prepared by adding a spreading agent (special Reno-1: manufactured by Nippon Agrochemical Co., Ltd.) to the diluted solution diluted to a concentration of 1/5000 of the diluted solution.
  • the cabbage leaves at the 5th to 8th leaf stage of the pot plant were cut out and immersed in the test solution for 60 seconds.
  • Insecticidal rate (%) 100 X (M t -Mc) / (100 -Mc)
  • the present invention can provide a pest control composition which can provide a synergistic effect higher than the additive effect obtained by simply mixing and can reduce the amount of drug used.

Abstract

La présente invention concerne une composition pesticide caractérisée en ce qu'elle contient du 3,5-dichloro-1-(3,3-dichloro-2-propényloxy)-4-[3-(5-trifluorométhylpyridine-2-yloxy)propyloxy]benzène et une protéine insecticide de Bacillus thuringiesis.
PCT/JP2004/015460 2003-10-15 2004-10-13 Composition pesticide WO2005034627A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2003354762 2003-10-15
JP2003-354762 2003-10-15

Publications (1)

Publication Number Publication Date
WO2005034627A1 true WO2005034627A1 (fr) 2005-04-21

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ID=34431193

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Application Number Title Priority Date Filing Date
PCT/JP2004/015460 WO2005034627A1 (fr) 2003-10-15 2004-10-13 Composition pesticide

Country Status (3)

Country Link
CN (1) CN100577009C (fr)
TW (1) TWI329001B (fr)
WO (1) WO2005034627A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101669472A (zh) * 2009-10-13 2010-03-17 深圳诺普信农化股份有限公司 一种增效农药组合物

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4844415A (fr) * 1971-10-14 1973-06-26
JPH09151172A (ja) * 1994-10-14 1997-06-10 Sumitomo Chem Co Ltd ジハロプロペン化合物、その用途およびその製造中間体

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4844415A (fr) * 1971-10-14 1973-06-26
JPH09151172A (ja) * 1994-10-14 1997-06-10 Sumitomo Chem Co Ltd ジハロプロペン化合物、その用途およびその製造中間体

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101669472A (zh) * 2009-10-13 2010-03-17 深圳诺普信农化股份有限公司 一种增效农药组合物

Also Published As

Publication number Publication date
TWI329001B (en) 2010-08-21
CN100577009C (zh) 2010-01-06
CN1893824A (zh) 2007-01-10
TW200518676A (en) 2005-06-16

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