Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
  • B29B9/00—Making granules
  • B29B9/02—Making granules by dividing preformed material
  • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
  • B29B9/00—Making granules
  • B29B9/02—Making granules by dividing preformed material
  • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
  • B29B9/065—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion under-water, e.g. underwater pelletizers
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
  • B01J2/20—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by expressing the material, e.g. through sieves and fragmenting the extruded length
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
  • B29B7/00—Mixing; Kneading
  • B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
  • B29B7/58—Component parts, details or accessories; Auxiliary operations
  • B29B7/582—Component parts, details or accessories; Auxiliary operations for discharging, e.g. doors
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
  • B29B7/00—Mixing; Kneading
  • B29B7/80—Component parts, details or accessories; Auxiliary operations
  • B29B7/82—Heating or cooling
  • B29B7/823—Temperature control
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
  • B29B7/00—Mixing; Kneading
  • B29B7/80—Component parts, details or accessories; Auxiliary operations
  • B29B7/82—Heating or cooling
  • B29B7/826—Apparatus therefor
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
  • B29B9/00—Making granules
  • B29B9/02—Making granules by dividing preformed material
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
  • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
  • B29C48/05—Filamentary, e.g. strands
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
  • B29C48/25—Component parts, details or accessories; Auxiliary operations
  • B29C48/30—Extrusion nozzles or dies
  • B29C48/345—Extrusion nozzles comprising two or more adjacently arranged ports, for simultaneously extruding multiple strands, e.g. for pelletising
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C31/00—Handling, e.g. feeding of the material to be shaped, storage of plastics material before moulding; Automation, i.e. automated handling lines in plastics processing plants, e.g. using manipulators or robots
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
  • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
  • B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
  • B29C48/04—Particle-shaped
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
  • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
  • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
  • B29K2995/0012—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular thermal properties
  • B29K2995/0013—Conductive

Definitions

• the present invention relates to improved underwater melt pelletizer dies containing a highly thermally conductive pathway. More particularly, the present invention relates to such dies having such pathways extending from the die's heating source to the vicinity of the exits of the die holes, and is insulated from the cooling medium at the exits of the die holes, and together with processes using such dies.
• Thermoplastics are very important items of commerce. Typically they are formed into various parts and shapes by melt forming, that is melting of the TP, forming it while molten into a shape and then cooling the TP to a solid to "fix" it in that shape. In most melt forming machines, the TP is fed in the form of a pellet or granule, typically in the size range of 0.1 to about 0.6 cm (longest dimension). In order for most melt forming machines to work efficiently, it is preferred that the pellets or granules be free flowing and have a reasonably uniform size. Many types of apparatuses have been developed to pelletize TPs.
• Such an apparatus should preferably produce uniform and readily flowing pellets, at low cost.
• One such type of pelletizing apparatus is the so-called "underwater melt pelletizer” (UMP) or cutter, see for instance U.S. Patents 2,918,701 and 3,749,539.
• UMP underwater melt pelletizer
• UMPs have been particularly useful for cutting TPs that have relatively low melting points and or do not otherwise freeze (solidify) readily. This is because as the molten TP exits the die plate it is exposed to liquid water, which is relatively cool. Upon contacting the water the TP tends to freeze rapidly.
• Patent 3,749,539 describes a UMP die whose • nozzles and body may be made from “nickel 200". This alloy is reported to have a thermal conductivity of about 70 W/m°K. However there is no insulating member at the end of the die hole.
• U.S. Patent 4,678,423 describes a UMP die what has nozzles which have a thermal conductivity of about 60 W/m°K or more. The thermal conductivity of the rest of the die body is not specified, the ends of the nozzles near the exit surface are thermally insulated from the rest of the die body, and the tips of the nozzles at the exit face are not insulated.
• U.S. Patent 4,728,276 describes an "Underwater Pelletizer" with die holes having a reverse taper.
• U.S. Patent 4,752,196 describes a UMP die having some insulation near the tips of the nozzles. However the die described does not have a relatively highly thermally conductive path from the heat source to the inner surface of the die holes, and the insulation is arranged differently than herein.
• Japanese Patent Application 5-253997 describes a die whose holes have a reverse taper. The purpose of these holes appears to be minimization of die drips and their degradation, possibly with cutters which are not UMPs. It is therefore an object of the present invention to provide an apparatus suitable for polymer pelletization which minimizes the potential for the freezing of polymer.
• a feature of the present invention is the strategic incorporation of thermally conductive materials into such apparatus to facilitate polymer flow.
• An advantage of the present invention is the attendant savings in cost and time through more efficient and consistent operation of the UMP's equipped with such apparatus.
• a die for the underwater melt pelletization of polymers comprising, a die body, comprising, a first part having a tensile yield strength of less than about 200 MPa and a heat conduction of 50 W/m°K or more, and a second part having a tensile yield strength of more than about 250 MPa and a heat conduction of less than 50 W/m°K, and, and wherein said second part is configured to support said first part against stresses normally present when said die is in operation.
• This invention also concerns a die assembly for the underwater melt pelletization of polymers, comprising: (a) a die body comprising one or more thermally conductive materials having a first heat conduction of about 50 W/m°K or more, said die body having an entrance face and an exit face; (b) one or more polymer die holes disposed within said die body, each having an interior surface, extending between said entrance face and said exit face; (c) means for heating said die body; (d) one or more insulating members in contact with said exit face and which have a second heat conduction of about 20 W/m°K or less and have a first side in contact with said exit face and an opposite first exterior side, and having first holes colinear with said polymer die holes to allow said polymer to flow through said insulating members; and (e) one or more first wear resistant members in contact with said first exterior sides of said insulating members and having an second exterior side and second holes colinear with said polymer die holes to allow said polymer to flow through said first wear resistant members; or (f) alternative
• Figure la and related section X-X shows a die plate of the present invention made from a material with a relatively high thermal conductivity.
• Figures lb and lc show, respectively, a die insert holder and a die insert for the die plate of Figure la.
• Figure 2 and related section A-A thereof shows a die plate and assembly of the present invention, made from a combination of a relatively low thermal conductivity material and a relatively high thermal conductivity material .
• Figure 3 shows a cross section of a die plate of the present invention, made from a combination of a relatively low thermal conductivity material and a relatively high thermal conductivity material.
• Figure 4 illustrates a die hole with a reverse taper.
• the UMP dies described herein have a "pathway" which is relatively highly thermally conductive from the heating source of the die to the vicinity of the .(inner) die hole surfaces at the exit face of the die, that is the side or face at which the polymer exits from the die.
• This pathway is made of materials, for example metals and metal alloys, which have relatively high thermal conductivities.
• Each of the high thermal conductivity materials has a heat conduction of 50 W/m°K or more, preferably about 80 W/m°K or more, very preferably about 100 W/m°K or more, and especially preferably about 300 W/m°K.
• Such materials are known, and some of them have the strength to be the only primary material from which the mold is made and still withstand the stresses that typical UMP dies must withstand, especially pressure on the die face from the pressurized molten polymer.
• Such materials include nickel 200 with a heat conduction of 70 W/m°K and a tensile strength at yield 146 MPa, and GlidCop® Grade AL-15 Dispersion Strengthened Copper, (OMG Americas, Research Triangle Park, NC 27709 USA) with a heat conduction of 365 W/m°K and a tensile strength at yield of 250+ MPa, and Grade AL-60 with a heat conduction of 322 W/m°K and a tensile strength at yield of 400+ MPa.
• Figure la shows a front view of a die in accordance with the invention, together with a cross section (XX) of this die.
• the die has a die body 1, having entrance face (surface) 2, exit face (surface) 3, eight cavities (for electric heaters) 4, bolt holes (for mounting 1) namely 5 and 6, 2 cavities (for mounting thermocouples) 7, and eight die holes 8.
• Shown in Figure lb is a die hole insert holder 9, which fits into 8.
• FIG. lc Shown in Figure lc is a die insert 10 which fits into 9. By having separate pieces for 9 and 10 the effective diameter of the die hole may be readily changed.
• molten polymer enters 10 in the vicinity of 2 and flows through 10 to the vicinity of 3, and exits 10 near 3.
• the materials for all of 1, 9, and 10 should have a relatively high thermal conductivity, >50 W/m°K.
• 1 and/or 9 may be made from GlidCop® AL-15, and/or nickel 200.
• 10 not only have a relatively high thermal conductivity, but also be relatively abrasion resistant, and (high thermal conductivity) tungsten carbide (60-170 W/m°K) is suitable for this use.
• It's main construction members are a relatively high strength but relatively low thermal conductivity plate 21, a second plate having a relatively low strength but relatively high thermal conductivity 22, a collar 23 (which is usually of relatively high strength but need not have a high thermal conductivity) to help hold the assembly together, and relatively strong mounting hole liners 24.
• These parts of the die may be joined by "temporary" mechanical means such as bolts (not shown), but are preferably permanently joined together by welding and/or brazing, shown by regions 25 and 26.
• 21 and 23 may be steel or stainless steel, and may be joined by welding.
• 22, which may be copper, or a copper or aluminum alloy, may be brazed to both 21 and 23.
• the mounting holes 27 may be drilled and the mounting hole liners 24 (which may be stainless steel or steel pipe or tubing) brazed and/or welded to the assembly. Then the assembly may be further machined to form the other cavities and holes needed.
• the die body 28 when joined together, are known as the "die body" 28.
• 28 has an entrance face 29 and an exit face 30.
• Running through 28 between faces 29 and 30 are multiple die holes 31, which towards 30 each have mounted in them a die insert 32.
• the material for the die insert should have a relatively high thermal conductivity and preferably have good abrasion resistance, and tungsten carbide may be used.
• the end of 32 near 30 is covered in this case by a layer of tungsten carbide 33, which in turn is covered by a layer of titanium carbide 34.
• 33 and 34 contain holes which are colinear with each of 31, so the polymer may flow completely through the die apparatus to the outer face of 34.
• 33 is simply a way of extending the surface around the die hole to a convenient plane upon which 34 may rest.
• 34 in this instance is a combined thermal insulator and wear resistant surface, and can be made for example from titanium carbide (7-15 W/m°K) .
• bolts and clips, 35 for holding the electrical heaters (not shown) in place, three thermocouple wells 36, and (in section A-A thereof) the flow direction in the die apparatus of the molten polymer.
• an optional "can” 37 which is filled with air or under vacuum which acts to insulate the hot die from excessive heat loss to the cooling water in areas where the knives do not contact the die assembly and where there are no die holes in the vicinity.
• 37 may be, and is preferably, made of a material which does not have a relatively high thermal conductivity.
• Figure 2 shows all of the essential features, and some nonessential features of the presently described die. For instance it clearly shows a highly thermally conductive path from the heat source (electrical heaters) to the inside surfaces of the die holes, particularly in the vicinity of the exit face 30 of the apparatus.
• the die shown in Figure 2 is an example of a die made from a combination of a relatively highly thermally conductive (>50 W/m°K) material which is relatively structurally weak (tensile strength at yield of ⁇ 250 MPa) , with a material with a relatively low thermal conductivity ( ⁇ 50 W/m°K, preferably ⁇ 30 W/m°K, and especially preferably ⁇ 10 W/m°K) , but with a relatively high tensile strength at yield, > 250 MPa, preferably >1000 MPa) .
• the structurally strong materials provides the strength for the die to withstand the stresses on it during operation, while the highly thermally conductive materials provides better operability for the die, especially for higher melting and/or fast freezing TPs.
• Materials with relatively low thermal conductivities ( ⁇ 30 W/m°K) but with relatively high tensile yield strengths include carbon steels, tool steels, stainless steels, and the like. All of these are generally suitable for parts such as 21.
• various copper and copper alloys, aluminum and aluminum alloys, silver and silver alloys, gold and gold alloys, and platinum and platinum alloys are suitable for use as the high thermal conductivity low tensile yield strength materials.
• Such specific high thermal conductivity materials include beryllium copper (116-208 W/m°K) , brass (116 W/m°K) , copper (400 W/m°K) , and bronze (178 W/m°K) .
• the parts of the die body made from these two materials may be held together in the proper configuration for the die in any known way, for example they may be held together mechanically by bolts or other fasteners, by collars or other forms of clamps, or they may be more permanently held together as by welding and/or brazing.
• the higher strength material is welded together and the high thermal conductivity material is brazed to the high strength material.
• FIG 3 Another die with a strong but relatively low thermal conductivity material and a relatively highly thermally conductive but relatively weak material is shown on Figure 3 in which the strong material "supports" the relatively highly thermally conductive material in a somewhat structurally different way.
• Figure 3 shows a cross section of a die of this invention which is similar to the cross section shown in Figure 2.
• the major difference between Figures 2 and 3 is the arrangement of the low and high strength parts of the die plate.
• the die in Figure 3 has a low thermal conductivity but high yield strength member 61, which in this instance "wraps around" the edge of high thermal conductivity (but low yield strength) member 62.
• these parts of the die may be joined by "temporary" mechanical means such as bolts (not shown), but are preferably permanently joined together by welding and/or brazing.
• 61 may be steel or stainless steel
• 62 which may be copper, or a copper or aluminum alloy, may be brazed to 61.
• the mounting holes 67 may be drilled and the mounting hole liners 64 (which may be stainless steel or steel pipe or tubing) brazed and/or welded to the assembly. Then the assembly may be further machined to form the other cavities and holes needed.
• 68 has an entrance face 69 and an exit face 70.
• the member 62 has extending from it "nozzles" 63 which may be concentric with 71 to provide a high thermal conductivity path to the exit face end of 71.
• nozzles There are corresponding holes in 61 to accommodate each of 63.
• Running through 68 between faces 69 and 70 are multiple die holes 71, which each have mounted in them a die insert 72 (as earlier introduced in Figure lc as 10) .
• the material for the die insert should have a relatively high thermal conductivity and preferably have good abrasion resistance, and tungsten carbide may be used.
• the end of 72 near 70 is covered in this instance by a layer of tungsten carbide 73, which in turn is covered by a layer of titanium carbide 74.
• 73 and 74 contain holes which are colinear with each of 71, so the polymer may flow completely through the die apparatus to the outer face of 74.
• 73 is simply a way of extending the surface around the die hole to a convenient plane upon which 74 may rest.
• 74 in this instance is a combined thermal insulator and wear resistant surface, and can be made for example from titanium carbide (7-15 W/m°K) .
• Also shown in Figure 3 is one of the heater wells 75, and the flow direction in the die apparatus of the molten polymer.
• a “melted”, “molten” or “liquid” polymer herein is meant a polymer having a temperature at or above its highest melting point, or if the polymer has no melting point (is amorphous) then has a temperature at or above its highest glass transition temperature.
• Melting points and glass transition temperatures are measured by method ASTM Method D3418. Melting points are taken as the maximum of the melting endotherm, and glass transition temperatures are taken as the midpoint of the transition. Melting points and glass transition temperatures are measured on a second heat.
• Molten polymers may be "forced" through the die and die holes by any number of methods well known in the art, for instance using an extruder or a pump such as a gear pump or a screw pump, pressurizing the molten polymer above ambient pressure (as with gas pressure above a partially filled tank of molten polymer) , or using gravity induced flow.
• the die may be heated by any method known in the art. For instance it may be heated by: a hot fluid (s) (gas and/or liquid) circulating through the die such as saturated or superheated steam, hot oils of various kinds, and Dowtherm® and similar materials; or by electrical heaters either within the die body or on the outside, for instance external band heaters or internal cartridge heaters.
• a hot fluid gas and/or liquid
• Any polymer which is solid above 0°C, preferably above 50°C, and may be melted can be cut by the present die.
• the melt viscosity of the polymer is preferably in a range where the molten polymer may be reasonably easily forced through the die holes.
• polyesters such as poly (alkylene terephthalates) such as poly (ethylene terephthalate) , poly (1, 3-propylene terephthalate) , poly (1, 4-butyleneterephthalate) , poly (alkylene isophthalates/terephthalates) , poly (alkylene 2,6- naphthalates) such as poly (ethylene 2, 6-napthtalate) , copolymer of terephthalic acid, 1, 4-cyclohexanedimethanol and copolyesters thereof; polyamides such as nylon-6, nylon-6,6, ; polyolefins such as polyethylene, polypropylene, polystyrene, copolymers of ethylene and ⁇ - olefins, especially linear -olefins, copolymers of ethylene with (meth) acrylate esters and/or methacrylic and/or acrylic acids and salts thereof, and copolymers of
• Blends of two or more of these and/or other individual polymers and/or polymer types may also be used.
• the polymers which are used in the present process may contain any additives which are normally added to thermoplastics polymers, such as fillers, reinforcing agents, pigments, antioxidants, plasticizers, brightening agents, antiozonants, dyes, and stabilizers.
• Useful specific materials include glass in the form of fiber, microspheres, milled glass, and ground fibers, clay(s), mica, talc, and other minerals, carbon (graphitic and nongraphitic) in the form of powder, fiber and fibrils, organic fibers, fibrils and fibrids such as aramids and liquid crystalline polymer fibers, titanium dioxide, powdered metals, short lengths of metal wires and fibers, and powdered organic materials such as thermoset polymers. These materials may be present in conventional amounts in these compositions.
• the dies described herein have reverse taper die holes.
• reverse taper die holes is meant that the die hole at the (polymer) exit side of the die plate is wider in diameter than along the rest of the die hole and tapers to a smaller size hole as one goes from the exit face of the die plate towards the (polymer) entrance face of the die plate.
• These die holes need not taper throughout the length of the die hole, but must taper on the die plate exit side. Typically the depth of the taper will be at least about 3 to about 5 cm.
• depth of taper is meant the length along the axis of the hole (e.g. length of section 86 in Fig. 4) .
• FIG. 4 A cross-section of part of a die plate showing a reverse tapered die hole is illustrated in Figure 4.
• the die plate 81 has an exit face 82, where the polymer (not shown) exits the die (hole) , and an entrance face 83 where the (molten) polymer enters the die hole 84.
• 84 is straight over part of its length, zone 85, and has a reverse taper over part of its length, zone 86.
• the tapered portion has a "taper angle" 88.
• Other parts of the die or die assembly which may be present are not shown.
• the holes through these materials are colinear with 84, and also preferably have a reverse taper. If these surface materials are very thin, not having a reverse taper will not significantly affect the performance of the die. While not critical it is preferred that the taper angle is at least 0.1°, more preferably at least about 0.2°, especially preferably at least about 0.5°, and very preferably at least about 1.0°. It is also preferred that the taper angle is about 10° or less, more preferably 5° or less, and especially preferably about 3.0° or less. It is to be understood that any minimum and maximum taper angles given above may be combined to give a preferred taper angle range.
• the TP compositions to be cut may contain materials other than just polymer (s). Some of these other materials such as glass or Ti0 2 may be very hard and/or abrasive, and would rapidly cause excessive wear in die holes especially in many softer materials such as copper or aluminum alloys. In such cases it may be preferred to line the die holes with inserts of a more abrasion resistant and/or harder materials. This insert material should also have a relatively high thermal conductivity, >30 W/m°K, and preferably have higher conductivities as preferred for the highly thermally conductive material of the die body.
• Useful abrasion resistant materials for the orifices include tungsten carbide (60-170 W/m°K) .
• a preferred insert material is tungsten carbide. Such an insert is shown in Figure lc.
• the present die may be operated much like previous UMP dies, except the combination of features described herein allow for easier operation of the die, especially with polymer having a higher melting point or glass transition temperature, as appropriate. Information on UMPs and their operation can be found in U.S. Patents 2,918,701, 3,749,539, 4,678,423, 4,728,276, 4,752,196,
• the heat source of the die such as electrical heaters or steam, for instance, there is a substantial highly thermally conductive path to the interior surfaces of the die holes themselves, especially at and near the exit surface of the die.
• the heat source is capable of transferring a sufficient amount of heat to the highly thermally conductive part of the die body, this energy is efficiently transferred to the polymer in the die hole, and the vicinity of the die hole, especially near the exit side is kept warm enough so the polymer in the die hole does not freeze.
• the highly thermally conductive die body portion at the exit of the die hole is protected from excessive heat loss (cooling) , and subsequent freezing of the polymer, by the thermal insulator near that exit.
• the use of the present dies offers one or more of advantages over prior art dies. Operability, the ability to start and maintain operation of a UMP, particularly with a high melting and/or rapid freezing polymer is much improved. With some polymers and prior art dies, operability was often improved by raising the temperature of the water, particularly >60°C. This resulted in increased safety concerns for the operators (possibility of burns from the hot water) , and often increased moisture content in the polymer pellets produced.
• the present dies typically allow the use of cooler water, lessening safety concerns. In some instances pellets with decreased moisture content are produced. As noted above, UMCs having the present dies may be started up more easily, particularly when the dies have reverse tapered die holes.
• This die was identical in all material respects to the die shown in Figure 1, and has an overall diameter of 22.86 cm and 4.21 cm thick.
• the die was bolted to the extruder end.
• the eight die holes were fitted with insert holders such as 9, which in turn could be fitted with die inserts such as 10, or be plugged so that less than 8 dies holes were in operation.
• the insert holder and inserts were also made of 360 Brass.
• the die was also equipped with a layer of thermal insulation over the exit end of the die holes similar to 33 in Figure 2 which was made from titanium carbide.
• the taper angle, 88 was 2°
• a zone similar to 85 was 5.14 cm long (including the transition which was a 120° angle)
• a zone similar to 86 was 1.27 cm long.
• Die B This die was made from GlidCop® Grade AL- 15. This die body was similar in all material respects to the die body shown in Figure 1, and has an overall diameter of 22.86 cm and was 6.35 cm thick. The die was bolted to the extruder end. The eight equally spaced die holes were fitted with die inserts such as 10, or be plugged so that less than 8 dies holes were in operation. The die inserts were made of tungsten carbide. The die was also equipped with a layer of thermal insulation over the exit end of the die holes similar to 33 in Figure 2 which was made from titanium carbide with a carbon steel backplate. Total thickness of the titanium carbide and the backplate was 4.75 mm.
• the taper angle, 88 was 2°, a zone similar to 85 was 6.13 cm long with a taper (not reverse taper) angle of 1.724°, and a zone similar to 86 was 6.99 mm long, including the thickness of the titanium carbide and steel backplate layers (the die holes through the thickness of these layers also had the reverse taper) .
• the diameter was 5.54 mm, and at the exit end (at the outside face of the titanium carbide) it was 3.94 mm in diameter.
• Die C This die was identical to Die B except for the following. Total thickness of the titanium carbide and the backplate was 6.35 mm, equally divided between the steel backplate and titanium carbide layer.
• the inserts were made of soft brass 360, which necessitated them being changed frequently.
• the taper angle, 88 was 2°
• a zone similar to 85 was 5.14 cm long (including a transition section with an angle of 120°)
• a zone similar to 86 was 5.53 ram long, including the thickness of the titanium carbide and steel backplate layers (the die holes through the thickness of these layers also had the reverse taper) .
• the diameter was 5.08 mm
• the exit end at the outside face of the titanium carbide it was 5.08 mm in diameter.
• certain polymers were used, and these are described in Table 1. All these polymers are available from E. I. DuPont de Nemours & Co., Inc., Wilmington, DE, USA. Table 1
• LCP1 a copolymer made from hydroquinone/4, 4' - biphenol/terephthalic acid/2, 6-napthalene dicarboxylic acid/4-hydroxybenzoic acid, 50/50/70/30/320 molar parts.
• LCP2 the polymer of LCPl plus 30 weight percent glass fiber.
• LCP3 a copolymer made from 3 parts 4,4'- biphenol, 37 parts ethylene glycol, 40 parts terephthalic acid and 60 parts 4-hydroxybenzoic acid, all parts are molar parts.
• the polymer feed extruder was started and polymer feed to the extruder was initiated.
• a diverter valve on the exit end polymer feed extruder which had been set to divert molten polymer from the pelletizer, was now set so that molten polymer was fed to the pelletizer (die) and at this point pelletization started.
• polymer feed was started it was started at a reduced rate and then ramped up to the final desired rate.
• startup even though the die was in the circulating water, went smoothly, although startup pressures were not always recorded.
• Example 2 The pressure needed to start the flow of polymer through the die using this simplified startup procedure is given in Table 2, as is the steady state pressure during pelletization, the number of die holes used, the die and cooling water temperatures, and the polymer used. All the examples in Table 2 were considered successful. Startup (as outlined above) went well, and the pellets produced were uniform enough and of an acceptable shape for commercial sale. The pelletizing run for each example ended when it was desired to stop, and not from any process or equipment problems. In addition in Comparative Example D (examples with Die A are comparative only because Die A is made from a relatively weak material - otherwise the results can be directly compared with dies of this invention) and Example 1 the pellet size and/or other conditions of the pelletization were varied and the resulting pellets were measured for moisture.
• Comparative Example E a commercially available die of the prior art was also run and the moisture content of the pellets measured.
• the polymer used was Zytel® 70G35
• the die body was steel and the die hole liner was thermally insulated ceramic.
• the dies were heated by electrical resistance heaters, and the final die hole diameter (meaning the size of the die hole with the die hole liner in place) in Dies A and C was 3.18 mm in diameter, the final die hole diameter in Die B was 3.94 mm, and the final die hole diameter in the commercial die was 4.57 mm.

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• 2004
  • 2004-07-20 US US10/894,798 patent/US7226553B2/en not_active Expired - Fee Related
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