WO2004100901A2 - Compositions cosmetiques en emballages pour doses uniques - Google Patents

Compositions cosmetiques en emballages pour doses uniques Download PDF

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Publication number
WO2004100901A2
WO2004100901A2 PCT/EP2004/004870 EP2004004870W WO2004100901A2 WO 2004100901 A2 WO2004100901 A2 WO 2004100901A2 EP 2004004870 W EP2004004870 W EP 2004004870W WO 2004100901 A2 WO2004100901 A2 WO 2004100901A2
Authority
WO
WIPO (PCT)
Prior art keywords
acid
copolymer
cosmetic composition
peg
cosmetic
Prior art date
Application number
PCT/EP2004/004870
Other languages
German (de)
English (en)
Inventor
Anett S�LZER
Markus Danne
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Priority to EP04731580A priority Critical patent/EP1663117A1/fr
Publication of WO2004100901A2 publication Critical patent/WO2004100901A2/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D37/00—Sachet pads specially adapted for liquid toiletry or cosmetic substances
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/002—Aftershave preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00—Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • A45D40/24—Casings for two or more cosmetics
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87—Application Devices; Containers; Packaging
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits

Definitions

  • the present invention relates to cosmetic compositions, in particular hair treatment agents, which are present as a flowable, pasty, liquid or gel-like preparation, or as a powder, as granules or as shaped articles.
  • the present invention further relates to a method for treating skin, nails and keratin fibers with these cosmetic compositions.
  • Cosmetics for the care and maintenance of the natural functions of skin and hair are becoming increasingly important.
  • the changed consumer habits and fashion trends contribute to this.
  • the intensive use of tanning salons has a lasting impact on the structure of skin and hair by UV light.
  • These impairments are shown on the skin and hair, for example, by a loss of elasticity.
  • Refatting substances are used to avoid stimulating sebum production during cleaning.
  • UV protection agents and vitamins such as vitamin E are said to reduce the adverse effects of UV light.
  • Protein hydrolyzates are used to balance the internal structure of the skin and hair. With plant and algae extracts, for example, the moisture balance of skin and hair can be influenced.
  • cosmetic active ingredients are increasingly used in agents for cleaning and maintaining surfaces such as glass, porcelain, leather, textiles, floors of all kinds in the household and in trade, in order not to put additional strain on the skin of the user of such products.
  • Hand dishwashing detergents with nourishing additives such as proteins or lipid-replenishing substances are available on the market.
  • the cause of irritation to the skin, nails or hair is not the cosmetic agent as such, but rather individual ingredients in the respective compositions. This is particularly often the case for the preservatives contained in the cosmetic products. If all the precautions can still be taken by the manufacturer of the agents for a germ-free production during the manufacture and packaging of the cosmetic agents, the cosmetic agent in question is generally contaminated with germs at the latest by the consumer during the use of the same container, which often extends over weeks , For a long time, therefore, consumers have had an almost unfulfilled desire for cosmetic preparations free of preservatives.
  • hair waxes usually contain vegetable, animal or mineral waxes as a shaping component and are offered as solid formulations, usually in relatively large jars. For use, a certain amount is removed from the jar, then rubbed in the hand and spread over the hair. These hair waxes, based on natural raw materials, ensure a good hold of the hair with a strong shine. Nevertheless, the hair waxes on the market cannot yet fully satisfy the wishes of the users with regard to simple application and easy distribution on the hair. Precise, simple and consistently reproducible dosing is also a problem here. Often too much or too little product is removed from the usual crucibles and tubes.
  • the cosmetic product should be easy to remove in full for each application individually and without residual losses, and should be easy and easy to carry and use in the required amount at any time.
  • the cosmetic composition which can be in the form of a flowable, pasty, liquid or gel-like preparation, or as a powder, as granules or as a shaped body, is introduced into a single-serving pack, the single-serving pack comprising a container part , which has a cup-like Ausfo ⁇ Vietnamese with an opening and a closure flange, which the opening as at least substantially radially projecting outwardly collar surrounds, and wherein the disposable portion pack further comprises a cover which is connected to the closure flange of the container part and closes the opening of the container part and which is formed by a removable or peelable and / or push-through closure film.
  • the main advantage is that it is particularly user-friendly for the consumer in several ways.
  • the cosmetic composition is available in precisely portioned amounts for each application and can be removed quickly and completely by the consumer in a particularly simple manner. For this he only needs to pull off or press in the sealing film and can take the exactly metered amount of the cosmetic agent through the then opened opening of the container part. Losses in the removal of the last remaining quantities from larger tubes or crucibles no longer occur.
  • the consumer can only carry the cosmetic products in the amount actually required, so that the problems associated with transporting large containers back and forth are eliminated.
  • the application-related properties of the cosmetic product expected by the consumer are retained in full even in the case of small containers which advantageously contain the amount of the respective cosmetic product packaged for each application.
  • cosmetic compositions dosed according to the invention in single-dose packs can be free of preservatives.
  • blister packs or skin packs and serve in the pharmaceutical and ecotrophological field as containers for accommodating corresponding products such as capsules, dragees, tablets, active ingredient balls, etc.
  • a push-through pack contains the lumpy product within the container part, the opening of which is sealed by the sealing film. The product is thus protected against environmental influences such as moisture and dirt and gives the consumer the guarantee of the durability and original condition of the packaged product.
  • a wide variety of configurations are used, for example, in the pharmaceutical industry for packaging tablets, coated tablets or suppositories.
  • condensed milk is packaged in such packaging.
  • a single-serving package is understood to be a so-called "unit-dose packaging".
  • One-portion packs such as four-edge seals are expressly not according to the invention in the sense of the present invention.
  • packaging sachets, tubular bags, stand-up pouches, tubes or small jars as packaging, which are distributed to consumers in particular as product samples.
  • shampoos or bath additives are packaged, for example.
  • this packaging has the considerable disadvantage that it is often difficult to open it, especially with wet hands in the bathroom, and above all it cannot be completely emptied.
  • a blister pack for cosmetics is known from Japanese patent application No. 11180467 A, but here the cosmetic compositions are first packaged in a large number of separate containers, which in turn are then used in a blister pack. The consumer must therefore open at least two packages in order to access the cosmetic composition, which significantly reduces comfort and precludes simple and quick handling, for example in the shower. In addition, problems can also arise here with the desired complete emptying of the individual containers.
  • German patent application DE 43 01 010 AI to fill cosmetic products in portions in sachets, preferably in linen sachets.
  • Such bags which are used here as a bath additive for consumers with dermatological problems, are expressly not the subject of the present invention, since not only problems with complete emptying occur here, but also general handling, in particular when opening the bags, is difficult.
  • foil packs with an absorbent insert are known from German utility model DE 202 03 811 U1, the insert being impregnated with a flowable or spreadable cosmetic agent.
  • So-called disposable make-up sets are also known, for example, from DE 38 74 714 T2, which can be packaged as trial castings in blister packs.
  • an additional distribution member is required as an applicator for applying the cosmetic make-up product, which is packaged together with the make-up agent.
  • the packaging is therefore particularly complex due to an additional constriction zone to be provided between the distribution element and the handle of the distribution element, and it requires additional space for the distribution element, which is no longer available for the make-up agent.
  • the make-up agent is contained in the distribution element as an additional body, so that this type of packaging is also not suitable for powdered, granular or solid cosmetic products.
  • the two utility models DE 201 02 282 Ul and DE 299 13 844 Ul disclose packaging for cosmetic or pharmaceutical products, the packaging each comprising applicator means for applying the product.
  • these packages are much more complex and therefore more expensive to manufacture and more difficult to handle for the consumer.
  • the consumer has to bend the packaging in order to break open a delivery channel specially shaped for this purpose. The removal then takes place as with a tube with the ones already listed Disadvantages with regard to a desirable complete emptying.
  • the removal opening in the application base for the product which can only be used in liquid or paste form is spatially separated from the product chamber, so that a connection area to an additionally required distribution chamber is necessary.
  • Both the connection area and the distribution chamber must be formed separately, which requires a particularly complex and expensive construction of the packaging.
  • handling by the consumer is also relatively cumbersome and difficult, which makes it impossible to use this packaging in the sense of the present invention.
  • German patent DE 42 39 082 Cl a device for absorbing fragrant fragrances such as perfume is known from German patent DE 42 39 082 Cl, which, however, does not permit controlled removal of the product filled therein. Rather, only the smallest quantities of perfume can be filled here, which should be released in an undefined manner to the surroundings, in particular to the clothing of the consumer, when the container is destroyed. Use in the sense of the present invention is therefore also not possible with this device.
  • the packaging according to the present invention is a structurally simple and therefore inexpensive to produce single-use pack, in which not only liquid, flowable, gel-like or pasty cosmetic preparations, but also cosmetic products in the form of powder, granules or solid moldings in the desired amount have it packed.
  • the disposable portion pack has a container part with a cup-like shape, the consumer can remove the respective product from the container part without any problems.
  • the consumer can also easily open the single-use portion pack, since the opening of the container part is completely surrounded by a collar-shaped closure flange to which the closure film is attached, which can either be peeled off to open it or pressed in.
  • the sealing film can be used not only for solid cosmetic moldings, but also for flowable, gel-like, Granular or powdered cosmetic products can be pushed through, so that when the consumer presses them onto the container part, which is at least flexible in this case, it is pressed through the cosmetic composition to the outside.
  • the container part of the single-serving pack is preferably provided with specific contours for the formation of one or more folding lines, which are designed and arranged in such a way that a narrowing the opening for the exit of a lumpy product is avoided.
  • the weak points in the container part formed by the kink lines at the same time reduce the effort required to push through the base area in the direction of the opening, so that even sensitive, lumpy products can be optimally dispensed with such push-through packaging.
  • the weak points in the container part formed by the kink lines at the same time reduce the effort required to push through the base area in the direction of the opening, so that even sensitive, lumpy products can be optimally dispensed with such push-through packaging.
  • the cosmetic composition contains at least one natural or synthetic polymer, the polymer or the polymers preferably being contained in an amount of 0.01 to 30% by weight of the total cosmetic composition.
  • Polymeric compounds are widely used in cosmetic products and are becoming increasingly important. They have numerous functions and effects, often they are themselves multifunctional and show several desired effects for the cosmetic product in question in a single structure.
  • polymers can thicken cosmetic products, which means, for example, that they can bind water and thus build up viscosity.
  • bound water in cosmetic products also means a reduction in water activity, which can be important for the contamination of the product in question. If the activity of the free water is too low, germs can no longer dissolve and develop in it.
  • the agent in question then does not need to be preserved, or at least significantly less.
  • Polymers are used, for example, in hair setting formulations.
  • An attractive looking hairstyle is now generally considered an indispensable part of a well-groomed exterior. Due to current fashion trends, hairstyles are always considered chic, which for many hair types can only be built up using certain setting agents or can be maintained for a longer period of time;
  • These setting agents which are usually polymeric compounds, can be incorporated into conventional hair cleaners or conditioners. In many cases, however, it is advantageous to use them in the form of special agents such as hair fixers, hair gels, hair waxes or hair sprays.
  • a flowable or liquid cosmetic composition it is particularly advantageous if it has a viscosity in the range from 100 mPas to 10 5 mPas.
  • the teaching according to the invention can also be applied to cosmetic products with a viscosity of below 100 mPas or above 10 5 mPas.
  • the cosmetic composition is in the form of a powder, granule or solid, it is particularly advantageous if it contains at least one dissolution accelerator.
  • the single-serving pack has a cup-like container part which is formed from a film, in particular deep-drawn.
  • the container part can also be cast or injection molded, for example to achieve greater strength.
  • the opening is round, preferably circular, oval or elliptical and that at least the side walls, preferably also the bottom area, of the cup-like shape of the container part are exclusively round, in particular rotationally symmetrical.
  • Such round or rounded Shapes facilitate the complete removal of a cosmetic product. It is particularly advantageous to design the cup-like shape of the container part at least in a lower part at least approximately as a segment of a hollow sphere or as a segment of a hollow ellipsoid of revolution.
  • the container part can be at least approximately hemispherical.
  • the consumer can also remove flowable, gel-like or powder-like cosmetic products particularly easily and without problems from the container part, since no straight surfaces or corners make removal difficult.
  • other shapes can also be considered for the cup-like shaping of the container part.
  • the cup-like shape can also be designed with an oval or elliptical base area or cross-sectional area.
  • the shape of the cup-like shape of the container part is preferably adapted to the shape of the cosmetic molded body, and straight walls and angular shapes can also be used
  • the wall of the cup-like shape of the container part can also comprise an area which is at least approximately in the form of a hollow cylinder or a hollow truncated cone.
  • a conical shape which can be connected in particular above a bottom of the container part in the form of a hollow spherical segment, allows the cosmetic product to be removed easily and completely.
  • closure flange of the container part is designed with straight side edges and in particular with rounded corners. This configuration enables a simple connection of several single-serving packs to one another even with a round opening and round designs of the cup-like shape of the container part.
  • the opening have an area of 1 to 20 cm 2 , preferably 6 to 12 cm 2 . In particular if this surface is round, the consumer can easily remove the product from the cup-like shape of the container part with one or two fingers.
  • the cosmetic composition is present in an amount with a weight between 0.1 and 40 g, preferably between 3 and 12 g and / or with a volume between 0.1 and 40 ml, preferably between 3 and 12 ml is introduced.
  • This amount represents a sufficient dosage for an application, especially in the case of shampoos or hair styling products.
  • a metal foil, in particular aluminum foil, possibly in a multilayer composite foil, which has a thickness of 0.05 to 0.5 mm, is preferably proposed for the closure foil of the single-portion pack according to the invention.
  • the sealing film from plastic film, in particular a PE film, a PET film, a PVC film or a multilayer film, for example made of PE / PP, PE / aluminum, PET / aluminum, PE / PET / Aluminum, PP / PET PE, PET / aluminum / PE or PET / aluminum / PP.
  • the wall of the cup-like shape of the container part can advantageously have a thickness of 0.2 to 1.5 mm, preferably 0.5 to 1 mm.
  • the container part can be formed from a plastic film, possibly in a multilayer composite film.
  • a PE film or a PVC film is particularly suitable for this, but a metal film can also be used.
  • the wall of the cup-like shape of the container part has approximately three to four times the thickness of the sealing film.
  • Both the films forming the container parts and the closure films as long as they are designed as plastic films, can generally be distinguished between water-insoluble and water-soluble films. Both types of film can be used equally.
  • Water-insoluble films are made from, for example, PVC, PE, PP, and mixtures of PE and polystyrene. Water-soluble films are produced, for example, from polyvinyl alcohol, starch, cellulose, gelatin (with appropriate reactive internals).
  • the sealing foil mentioned is of course in particular the metal foil already mentioned above, in particular an aluminum foil as a water-insoluble foil.
  • the cup-like shape of the container part is formed from a transparent or transparent material.
  • the consumer can recognize the degree of filling of the single-serving sachet and the optical quality of the cosmetic composition.
  • different colors of the cosmetic composition can also be recognized and used for differentiation purposes.
  • a transparent or transparent film for the sealing film.
  • both the cup-like shape of the container part and the closure film can be formed from an opaque material.
  • the closure film is integrally connected to the closure flange over the entire circumference of the opening by an adhesion promoter and / or by a sealing connection and / or welded connection.
  • the closure flange preferably has at least one edge region in which it is not connected to the region of the overlying closure film designed as a tear-open tab. With such a peel-off packaging, the sealing film is pulled upwards to open it. In any case, however, the sealing film is tightly connected to the sealing flange before opening, so that the single-serving pack is sealed, in particular airtight.
  • closure film be roughened and / or coated, in particular rubberized, on one or both sides at least in an area designed as a tear-open tab
  • the disposable portion pack according to the invention can advantageously also be a blister pack, which can in particular be a printed and / or peelable blister pack.
  • the single-serving pack can be designed as a push-through packaging or press-through packaging, the packaging mentioned here being designed in such a way that the compositions to be accommodated are each accommodated in a separate receptacle of a container part of the packaging.
  • the present invention it is provided to combine several single-serving packs with a cosmetic composition to form a packaging unit, two or more single-serving packs being arranged next to one another in at least one row and being connected to one another via their sealing flanges.
  • the cup-like shapes of the container parts point in the same direction.
  • the single-serving portion packs can be arranged next to one another in a plurality of rows parallel to one another, a particularly preferred combination comprising six single-serving portion packs in two rows of three packs each.
  • Each single-serving pack contains a cosmetic composition.
  • the individual single-serving packs are detachably connected to one another in a manner known per se by means of predetermined breaking points so that the individual units can be easily separated from one another.
  • the consumer can For example, divide the amount of cosmetic product required for a short trip and take it with you, saving weight and space.
  • Different cosmetic compositions can preferably be contained in the interconnected single-use packs of a packaging unit.
  • a shampoo can be packaged in a first row of single-serving packs arranged one behind the other and a hair conditioner in a second row of single-serving packs arranged one behind the other, which is arranged next to the first row.
  • the consumer thus has the advantage of a classic "2 in 1" shampoo, that is to say hair cleaning and care, but not in a recipe with the disadvantages known to the person skilled in the art, but rather a full-fledged hair shampoo and a full-fledged care product in one package for successive use.
  • other combinations of cosmetic compositions in this form are also conceivable, for example hair care and hair styling, UV skin protection agents and compliment-sun care, facial cleansing and facial care, etc.
  • the closure film and / or the cup-like shape of the container part are formed from a transparent or transparent material, it is particularly advantageous if the different cosmetic compositions have different colors. Additionally or alternatively, however, the closure films for the different cosmetic compositions can also be colored differently.
  • the present invention furthermore relates to a kit comprising at least one single-use portion pack with a cosmetic composition and / or at least one packaging unit of the type described above, an outer packaging preferably consisting of plastic, cardboard or cardboard being provided, in which the single-use portion pack (s) and / or packaging unit (s) held or complete is or are included. Instructions for use can preferably also be included in the kit.
  • the repackaging is formed by a flat envelope with two mutually opposite side walls, between which the sealing flanges of several single-serving packs are received, in particular by a packaging unit, one side wall containing a plurality of openings, through each of which a cup-like shape of the A portion of a single-serving pack protrudes through the container.
  • This type of repackaging represents a product presentation that is particularly appealing to the consumer, especially if the exposed shapes of the individual proton packs are transparent or translucent.
  • the envelope itself can be printed in.
  • the sealing films are additionally protected against unintentional opening.
  • the present invention further relates to a method for the cosmetic treatment of skin, nails or keratin-containing fibers, wherein one or more single servings of a cosmetic composition are taken from a single-serving pack of the type described above and are optionally dissolved in a medium to form the preparation, and wherein disposable portion according to the invention or optionally the preparation is applied to the skin, the nails or the keratin fibers and optionally rinsed off again after a contact time.
  • the present invention also relates to a method for producing a single-serving portion or for producing a packaging unit of the type described above, which comprises the steps of deforming a thermoformed film, filling the container part thus produced with a cosmetic composition, which is in the form of flowable, pasty, liquid or gel-like Composition, or as a powder, as granules or as a molded body, the sealing, preferably sealing with a sealing film and for the final shaping and / or for separating the individual portion packs comprises a punching process.
  • a cosmetic composition which is in the form of flowable, pasty, liquid or gel-like Composition, or as a powder, as granules or as a molded body
  • the sealing preferably sealing with a sealing film and for the final shaping and / or for separating the individual portion packs comprises a punching process.
  • FIG. 1 cross section through a first embodiment of a single-portion pack according to the invention
  • FIG. 2 top view of the single-serving pack from FIG. 1,
  • FIG. 3 three-dimensional view of the single-serving pack from FIG. 1,
  • FIG. 4 cross section through an embodiment variant designed as a packaging unit of 6 single-serving packs according to the invention
  • FIG. 5 top view of the packaging unit from FIG. 4,
  • FIG. 6 three-dimensional view of the packaging unit from FIG. 4,
  • FIG. 7 three-dimensional view of a packaging unit filled with a cosmetic gel
  • Figure 8 Repackaging for the packaging unit from Figures 4 to 7.
  • the disposable portion pack 1 has a container part 2 deep-drawn from a transparent plastic film and a cover made of an aluminum film Sealing film 3.
  • the container part 2 has a cup-like shape 4 with a circular opening 5 lying at the top and a substantially square sealing flange 6 with rounded corners 7, which surrounds the opening 5 in the plane of the opening 5 as a radially projecting collar.
  • the closure film 3 is connected over the entire circumference of the opening 5 to the closure flange 6 of the container part 2 in order to tightly close the opening 5 of the container part 2.
  • the sealing film 3 can be pulled off upwards (peel-off).
  • the cup-like shape 4 of the container part 2 is essentially hemispherical, so that the consumer can remove the cosmetic composition K contained therein without any problems.
  • the predominant lower part 8 of the cup-like shape 4 of the container part 2 is convex in the form of a segment of a hollow sphere, at the upper edge of which a concavely curved, rotationally symmetrical region 9 adjoins the closure flange 6.
  • each single-serving pack 1 is combined to form a coherent packaging unit 10, each single-serving pack 1 each containing a cosmetic composition K.
  • the single-serving packs 1 are arranged in two rows of three pieces, each being detachably connected to one another via the edges 11 of their closure flanges 6.
  • the contact lines of the contiguous edges are designed with a punch 12 as a predetermined breaking point for the simple separation of the individual single-use packs 1.
  • FIGS. 2 and 3 as well as 5 and 6, the tear-open tabs 13 for peeling up the individual disposable portions 1, which are not connected to the closure flange 6 underneath, can be seen particularly well.
  • the surfaces of the packagings 1 and 10 can be printed on both the top 14 or front and on the bottom 15 or back according to all the usual methods known to those skilled in the art.
  • FIG. 7 shows a packaging unit 10 filled with a cosmetic agent K in the form of a gel
  • this packaging consisting of a packaging-forming plastic film provided with six molded cup-like receiving troughs 4 and a closure film 3 closing the receiving troughs 4, and the gel K in the Receiving troughs 4, protected by the sealing film 3, is arranged.
  • the cup-like receiving troughs 4 consist of a transparent or transparent plastic, through which the cosmetic compositions K packed therein can be recognized.
  • the single-serving packs 1 or the packaging units 10 themselves can in turn be packaged in corresponding packaging, which are known to those skilled in the art as such. It is also possible according to the invention in this repackaging to provide the buyer with a detailed description of the ingredients and instructions for using the cosmetic compositions K. According to the invention, it is also possible for these repackaging to contain single-serving packs with several different cosmetic compositions K. In particular, this is also an equivalent alternative according to the invention to a blister card with different cosmetic compositions on this one blister card itself.
  • FIG. 8 shows a particularly preferred repackaging 16 for a packing unit 10 according to FIGS. 4 to 7. It is formed by a flat envelope with two opposite side walls 17a and 17b, between which the sealing flanges 6 of a packaging unit 10 or the blister card of a blister packaging can be received.
  • the side wall 17a contains six circular openings 18, through which a cup-like shape 4 of a single-portion pack 1 can protrude.
  • the cosmetic composition K according to the invention for packaging in single-serving packs 1 is described below.
  • the individual components of the composition K are, of course, based on the type of cosmetic composition K to be packed.
  • any cosmetic composition K be it a shampoo, a shower bath, a facial cleanser, a hair treatment to rinse out, a hair treatment to stay the hair, a hair fixative, a hair wax, a hair gel, a skin cream, etc. are suitable.
  • Cosmetic compositions which are usually used by the consumer in amounts of 0.1 g to 40 g per individual application and which are not mixed directly with other cosmetic compositions to achieve special effects are particularly suitable. Therefore, cosmetic compositions for the reductive or oxidative treatment of skin, nails or keratin fibers are possible in principle within the meaning of the invention, but are less suitable.
  • cosmetic products which are distributed to consumers in small packages such as bags or jars, for example as product samples, are not according to the invention.
  • cosmetic compositions K which have been pressed into shaped bodies, are a particular embodiment of the present invention.
  • a first embodiment of the present invention are cosmetic compositions which are in liquid form. These are particularly well suited if they have a viscosity in the range from 10 mPas to 1,000,000 mPas. Depending on the final viscosity of the cosmetic compositions, the viscosity of the compositions is measured using the customary and known methods at 25.degree. The measurement methods to be used for a shampoo or an O / W emulsion or a W / O emulsion are known to the person skilled in the art. In this connection, reference should be made, for example, to the DL standard 53015 in its entirety.
  • the person skilled in the art will set the required viscosity using the methods customary for the respective cosmetic formulations.
  • the viscosity can be adjusted using electrolytes such as NaCl, MgSO 4) citrate, phosphate, etc.
  • electrolytes such as NaCl, MgSO 4
  • special thickening substances or substance mixtures such as fatty alcohol alkoxylates, alkoxylated glycerol fatty acid esters etc. is also familiar to the person skilled in the art.
  • natural and synthetic polymers are increasingly used for the targeted adjustment of viscosities in cosmetic preparations. Polymers in particular are often used in cosmetic preparations because they are often multifunctional. Multifunctional means that the use of a polymeric raw material in a composition K fulfills several functions at the same time.
  • the polymer (G) according to the invention can be both a setting and / or film-forming polymer and a polymer with conditioning or conditioning and / or thickening properties.
  • it can also be advantageous to formulate at least one finishing and / or at least one film-forming, setting polymer and / or at least one thickening polymer.
  • Polymers are understood to mean both natural and synthetic polymers which can be anionic, cationic, amphoteric or non-ionic.
  • Film-forming polymers are understood to mean those polymers which, when dried, leave a continuous film on the skin, hair or nails.
  • film formers can be used in a wide variety of cosmetic products such as, for example, face masks, make-up, hair fixatives, hair sprays, hair gels, hair waxes, hair treatments, shampoos or nail varnishes.
  • Examples of common film formers are Abies Balsamea (Balsam Canada) Resin, Acetylenediurea / Formaldehyde / Tosylamide Crosspolymer, Acrylamide / Ammonium Acrylate Copolymer, Acrylamides Copolymer, Acrylamides / DMAPA Acrylates / Methoxy PEG Methacrylate Copolymer, Acrylamide / Sodium Acrylate Copolymer, Acrylamidopropyltrimonium Chloride / Acrylamide Copolymer,
  • Acrylamidopropyltrimonium Chloride / Acrylates Copolymer Acrylates / Acetoacetoxyethyl Methacrylate Copolymer, Acrylates / Acrylamide Copolymer, Acrylates / Ammonium Methacrylate Copolymer, Acrylates / Behenyl Methacrylate / Dimethicone Methacrylate Copolymer, Acrylates / t-Butylacrylamide Copolymer, Acrylates Copolymer, Acrylates / Diacetoneacrylamideone Copolymer, Acrylates / Dimeth Copolymer, acrylates / dimethicone methacrylate copolymer, acrylates / dimethiconol acrylate copolymer, acrylates / dimethylaminoethyl methacrylate copolymer,
  • Polianthes Tuberosa Extract Polyacrylamide, Polyacrylamidomethylpropane Sulfonic
  • Adipate / IPDI copolymer polydimethylaminoethyl methacrylate, polyester-1, polyester-2,
  • Polyester-3 Polyethylacrylate, Polyethylene, Polyethylene Naphthalate, Polyethylene
  • Terephthalates polyethylglutamates, polyethyl methacrylates, polyglucuronic acid,
  • Methacrylates polyoxyisobutylene / methylene urea copolymer, polyoxymethylene
  • Trimethylsiloxysilicate / Dimethiconol Crosspolymer Trimethylsiloxysilylcarbamoyl Pullulan, Triticum Vulgäre (Wheat) Protein, Tromethamine Acrylates / Acrylonitrogens Copolymer, VA / Butyl Maleate / Isobornyl Acrylate Copolymer, VA / Crotonates Copolymer, VA / Crotonates / Methacryloxybenzophenone,
  • Polymers that fix the hair contribute to the hold and / or build-up of the hair volume, the fullness of the hairstyle.
  • Film-forming polymers and gums are therefore generally typical substances for hair treatment agents such as hair setting agents, hair foams, hair waxes and hair sprays.
  • Substances which further impart hydrophobic properties to the hair are preferred here because they reduce the tendency of the hair to absorb moisture, that is to say water. This reduces the sagging of the hair strands and thus ensures a long-lasting hair style build-up and maintenance.
  • the so-called curl retention test is often used as a test method for this.
  • Examples of common setting polymers are acrylamides / ammonium acrylate copolymers, acrylamides / DMAPA acrylates / methoxy PEG methacrylate copolymers, acrylamidopropyltrimonium chlorides / acrylamides copolymers,
  • Acrylamidopropyltrimonium Chloride / Acrylates Copolymer Acrylates / Acetoacetoxyethyl Methacrylate Copolymer, Acrylates / Acrylamide Copolymer, Acrylates / Ammonium Methacrylate Copolymer, Acrylates / t-Butylacrylamide Copolymer, Acrylates Copolymer, Acrylates / C 1-2 Succinates / Hydroxyacrylates Copolymer, Acrylates / Lauryl
  • Amodimethicone Copolymer Acrylates / Stearyl Acrylate / Ethylamine Oxide Methacrylate Copolymer, Acrylates / VA Copolymer, Acrylates / VP Copolymer, Adipic Acid / Diethylenetriamine Copolymer, Adipic Acid / Dimethylaminohydroxypropyl Diethylenetriamine Copolymer, Adipic Acid Epoxypropyl Diethylenetriamine Copolymer, Adophicid Acid / Acid / Acid / Trimethylolpropane Copolymer, AUyl Stearate / VA Copolymer, Aminoethyl Acrylate Phosphate / Acrylates Copolymer, Aminoethylpropanediol-Acrylates / Acrylamide Copolymer,
  • the emulsion-stabilizing polymers are also among the preferred polymers according to the invention. These are understood to mean polymers which significantly support the build-up and stabilization of emulsions (O / W and W / O as well as multiple emulsions). Surfactants and emulsifiers are of course the main ones. Components, however, the stabilizing polymers contribute to a reduction in the coalescence of the emulsified droplets by positively influencing the continuous or the disperse phase. This positive Influencing can be due to electrical repulsion, an increase in viscosity or film formation on the droplet surface.
  • polymers examples include acrylamide / sodium acryloyldimethyltaurate copolymer, acrylates / aminoacrylates / C 10-30 alkyl PEG-20 itaconate copolymer, acrylates / Cl0-30 alkyl acrylate cross polymer, acrylates / stearyl methacrylate copolymer, acrylates / vinyl isodecanoate cross polymer, alcaligenes polysaccharides, AUyl Methacrylates Crosspolymer, Ammonium Acryloyldimethyltaurate / Beheneth-25 Methacrylate Crosspolymer, Ammonium Acryloyldimethyltaurate / Vinyl Formamide Copolymer, Ammonium Alginate, Ammonium Phosphatidyl Rapeseedate, Ammonium Polyacrylate, Ammonium Polyacryloyldimethyl Taurate, Ammonium Shellacate, Arachidyl Alcoholum, Bentomethoxoxymethyl, Ben
  • Polymers can increase the viscosity of aqueous and non-aqueous phases in cosmetic preparations.
  • aqueous phases their viscosity-increasing function is based on their solubility in water or their hydrophilic nature. They are used in both surfactant and emulsion systems.
  • Another way to increase the viscosity of cosmetic products is to thicken the non-aqueous phase, the lipid phase of the cosmetic products.
  • polymers are used which are not water-soluble but compatible with lipids. They are also used for the gel formation of cosmetic products with a high lipid content.
  • Divinyldimethicone / Dimethicone Crosspolymer Dodecanedioic Acid / Cetearyl Alcohol / Glycol Copolymer, Ethylcellulose, Ethylene / Acrylic Acid Copolymer, Ethylene / Acrylic Acid / VA Copolymer, Ethylenediamine / Dimer Tallate Copolymer Bis- Hydrogenated Tallow Amide, Ethyleneediamine / Stearyl Dimer, Ethylene Diledoleate Stearyl Dimer Tallate Copolymer, Ethylene / Octene Copolymer, Ethylene / Propylene Copolymer, Ethylene / Propylene / Styrene Copolymer, Euphorbia Cerifera (Candelilla) Wax, Hydrogenated Butylene Ethylene / Styrene Copolymer, Hydrogenated Ethylene / Propylene / Styrene Copolymer, Hydrogenated Japan
  • Suspension aids facilitate the distribution of solids in liquids.
  • the polymers cover the surface of the solid particles by adsorption and thereby change the surface properties of the solids.
  • these polymers are listed below: Acrylates Copolymer, Acrylates / Methoxy PEG-15 Methacrylate Copolymer, Acrylates / Vinyl Isodecanoate Crosspolymer, Acrylates / VP Copolymer, Acrylic Acid / Acrylamidomethyl Propane Sulfonic Acid Copolymer, Ammonium Styrene / Acrylates Copolymer, Ammonium VA / Acrylates Copolymer, Bentonite, Biotite, Calcium Lignosulfonate, Com Starch / Acrylamide / Sodium Acrylate Copolymer, C6-14 Perfluoroalkylethyl Acrylate / HEMA Copolymer, Diallyloxyneohe
  • Phosphonobutanetricarboxylic Acid Polyacrylamidomethylpropane Sulfonic Acid, Polycaprolactone, Polyethylacrylate, Polyhydroxystearic Acid,
  • the antistatic effect of polymers is another essential function for cosmetic products.
  • the electrical potential of the surfaces of the substrates treated with cosmetic agents skin, nails and keratin fibers is influenced.
  • the effect referred to as the "fly-away effect” and based on the electrostatic repulsion of the hair fibers is reduced in this way.
  • the skin feeling is influenced in this way.
  • Acrylamidopropyltrimonium Chloride / Acrylates Copolymer AMP-Isostearoyl Gelatin / Keratin Amino Acids / Lysine Hydroxypropyltrimonium Chloride, Benzyltrimonium Hydrolyzed Collagen, Caesalpinia Spinosa Hydroxypropyltrimonium Chloride, Cocamidopropyldimonium Hydroxypropyl Hydrolyzedagen, Cocodimonium Hydroxypropyl Hydrodimonium Hydrolyimonagen Casein Hydroxypropyl Hydrolyzed Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Silk, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl Silk Amino Acids, Dimethicone Hydroxypropyl Trimon
  • Polyquaternium- 12 Polyquaternium- 13, Polyquaternium- 14, Polyquaternium- 15, Polyquaternium- 16 Polyquaternium- 17, Polyquaternium- 18, Polyquaternium- 19, Polyquaternium-20 Polyquaternium-22, Polyquaternium-24, Polyquaternium-27, Polyquaternium 29, Polyquaternium-30, Polyquaternium-31, Polyquaternium-32, Polyquaternium-33, Polyquaternium-34, Polyquaternium-35, Polyquaternium-36, Polyquaternium-37, Polyquaternium-39, Polyquaternium-43, Polyquaternium-44, Polyquaternium-45, Polyquaternium-46 , Polyquatemium-48,
  • Polysilicone-1 Polyvinyl Imidazolinium Acetate, PPG-2 Cocamine, PPG-9 Diethylmonium Chloride, PPG-25 Diethylmonium Chloride, PPG-40 Diethylmonium Chloride, PPG-2 Hydrogenated Tallowamine, PPG-24-PEG-21 Tallowaminopropylamine, PPG-2 Tallowamine , PPG-3 Tallow Aminopropylamine, Propyltrimonium Hydrolyzed Collagen, Propyltrimonium Hydrolyzed Soy Protein, Propyltrimonium Hydrolyzed Wheat Protein, Quaternium-8, Quaternium-14, Quatemium-15, Quaternium-16, Quaternium-18, Quatemium-18 Methosulfate, Quatemium-22, Quatemium-24, Quatemium-26, Quatemium-27, Quatemium-30, Quatemium-33, Quaternium-43, Quaternium-45, Quaternium-51, Quatern
  • Cationic polymers (G1) are understood to mean polymers which have a group in the main and / or side chain which can be “temporary” or “permanent” cationic. According to the invention, polymers which have a cationic group irrespective of the pH of the composition are referred to as "permanently cationic". These are usually polymers that contain a quaternary nitrogen atom, for example in the form of an ammonium group. Preferred cationic groups are quaternary ammonium groups. In particular, those polymers in which the quaternary ammonium group is bonded via a Cl-4 hydrocarbon group to a main polymer chain composed of acrylic acid, methacrylic acid or their derivatives have proven to be particularly suitable.
  • R 1 -H or -CH 3
  • R 2 , R 3 and R 4 are independently selected from C 1-4 alkyl, alkenyl or hydroxyalkyl groups
  • m 1, 2, 3 or 4
  • R 1 stands for a methyl group
  • R 2 , R 3 and R 4 stand for methyl groups
  • m has the value 2.
  • Suitable physiologically compatible counteripens X " are, for example, halide ions, sulfate ions, phosphate ions, methosulfate ions and organic ions such as lactate, citrate, tartrate and acetate ions.
  • halide ions in particular chloride, are preferred.
  • a particularly suitable homopolymer is, if desired crosslinked, poly (methacryloyloxyethyltrimethylammonium chloride) with the INCI name Polyquaternium-37.
  • the crosslinking can be carried out with the aid of polyolefinically unsaturated compounds, for example divinylbenzene, tetraallyloxyethane, methylene bisacrylamide, diallyl ether, polyallyl polyglyceryl ether, or AUyl ether of sugars or sugar derivatives such as erythritol, pentaerythritol, arabitol, mannitol, sorbitol, sucrose or sucrose.
  • Methylene bisacrylamide is a preferred crosslinking agent.
  • the homopolymer is preferably used in the form of a non-aqueous polymer dispersion which should not have a polymer content below 30% by weight.
  • a non-aqueous polymer dispersion which should not have a polymer content below 30% by weight.
  • Such polymer dispersions are available under the names Salcare ® SC 95 (approx. 50% polymer content, further components: mineral oil (INCI name: Mineral Oil) and tridecyl-polyoxypropylene-polyoxyethylene ether (INCI name: PPG-1-Trideceth- 6)) and Salcare ® SC 96 (approx.
  • Copolymers with monomer units of the formula (Gl-I) preferably contain acrylamide, methacrylamide, C 1- alkyl acrylate and C-alkyl methacrylate as non-ionic monomer units. Among these nonionic monomers, acrylamide is particularly preferred. As in the case of the homopolymers described above, these copolymers can also be crosslinked.
  • a preferred copolymer according to the invention is the crosslinked acrylamide-methacryloyloxyethyltrimethylammonium chloride copolymer.
  • quaternized cellulose derivatives such as are available under the names of Celquat ® and Polymer JR ® commercially.
  • the compounds Celquat ® H 100, Celquat ® L 200 and Polymer JR ® 400 are preferred quaternized cellulose derivatives,
  • honey for example the commercial product Honeyquat ® 50,
  • cationic guar derivatives such as, in particular, the products sold under the trade names Cosmedia ® Guar and Jaguar ® ,
  • - polysiloxanes with quaternary groups such as the commercially available products Q2-7224 (manufacturer: Dow Corning; a stabilized Trimethylsilylamo- dimethicone), Dow Coming ® 929 Emulsion (containing a hydroxylamino-modi fied silicone, which is also known as amodimethicone ), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ® -Quat 3270 and 3272 (manufacturer: Th. Goldschmidt), diquaternary polydimethylsiloxanes, Quatemium-80),
  • Vinylpyrrolidone-vinylimidazolium methochloride copolymers as are offered under the names Luviquat ® FC 370, FC 550, FC 905 and HM 552,
  • Polyquaternium 2 Polyquaternium 17, Polyquaternium 18 and Polyquaternium 27 polymers with quaternary nitrogen atoms in the main polymer chain.
  • cationic polymers are the so-called "temporarily cationic" polymers. These polymers usually contain an amino group which, at certain pH values, is present as a quaternary ammonium group and is therefore cationic.
  • chitosan and its derivatives, such as 101 are freely available commercially, for example under the trade names Hydagen CMF ®, Hydagen HCMF ®, Kytamer ® PC and Chitolam ® NB /.
  • preferred cationic polymers are cationic cellulose derivatives and chitosan and its derivatives, in particular the commercial products Polymer ® JR 400, Hydagen ® HCMF and Kytamer ® PC, cationic guar derivatives, cationic honey derivatives, in particular the commercial product Honeyquat ® 50, cationic Alkylpolyglycodside according to DE-PS 44 13 686 and polymers of the type Polyquatemium-37.
  • cationized protein hydrolyzates are to be counted among the cationic polymers, the underlying protein hydrolyzate being derived from animals, for example from collagen, milk or keratin, from plants, for example from wheat, corn, rice, potatoes, soy or almonds, from marine life forms, for example from fish collagen or algae, or biotechnologically obtained protein hydrolyzates.
  • the protein hydrolysates on which the cationic derivatives according to the invention are based can be obtained from the corresponding proteins by chemical, in particular alkaline or acidic hydrolysis, by enzymatic hydrolysis and or a combination of both types of hydrolysis.
  • the hydrolysis of proteins usually results in a protein hydrolyzate with a molecular weight distribution of approximately 100 daltons up to several thousand daltons.
  • Preferred cationic protein hydrolyzates are those whose underlying protein content has a molecular weight of 100 to 25,000 Daltons, preferably 250 to 5000 Daltons.
  • Cationic protein hydrolyzates also include quaternized amino acids and their mixtures. The quaternization of the protein hydrolyzates or the amino acids is often carried out using quaternary ammonium salts such as, for example, N, N-dimethyl-N- (n-alkyl) -N- (2-hydroxy-3-chloro-n-propyl) ammonium halides.
  • the cationic protein hydrolyzates can also be further derivatized.
  • Typical examples of the cationic protein hydrolyzates and derivatives according to the invention are those under the F CI names in the "International Cosmetic Ingredient Dictionary and Handbook" (seventh edition 1997, The Cosmetic, Toiletry, and Fragrance Association 1101 17 th Street, NW, Suite 300, Washington, DC 20036-4702) and commercially available products: Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimopnium Hydroxypropyl Hydrolyzed Casein, Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hydrolyzed Hair Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Protein Hydroxypropyl Hydrolyzed Silk, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocod
  • the plant-based cationic protein hydrolyzates and derivatives are very particularly preferred.
  • the anionic polymers (G2) are, inter alia, anionic polymers which. Have carboxylate and or sulfonate groups.
  • anionic monomers from which such polymers can consist are acrylic acid, methacrylic acid, crotonic acid, maleic anhydride and 2-acrylamido-2-methylpropanesulfonic acid.
  • the acidic groups can be present in whole or in part as sodium, potassium, ammonium, mono- or triethanolammonium salt.
  • Preferred monomers are 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid.
  • Anionic polymers which contain 2-acrylamido-2-methylpropanesulfonic acid as the sole or co-monomer have proven to be particularly effective, the sulfonic acid group being able to be present in whole or in part as the sodium, potassium, ammonium, mono- or triethanolammonium salt ,
  • the Homopoiymer of 2-acrylamido-2-methyl propane sulfonic acid which is available for example under the name Rheothik ® l 1-80 is commercially.
  • copolymers of at least one anionic monomer and at least one nonionic monomer are preferred.
  • anionic monomers reference is made to the substances listed above.
  • Preferred nonionic monomers are acrylamide, methacrylamide, acrylic acid ester, methacrylic acid ester, vinyl pyrrolidone, vinyl ether and vinyl ester.
  • Preferred anionic copolymers are acrylic acid-acrylamide copolymers and in particular polyacrylamide copolymers with monomers containing sulfonic acid groups.
  • a particularly preferred anionic copolymer consists of .70 to 55 mol% of acrylamide and 30 to 45 mol% of 2-acrylamido-2-methylpropanesulfonic acid, the sulfonic acid group being wholly or partly as sodium, potassium, ammonium, mono- or triethanolammonium salt is present.
  • This copolymer can also be crosslinked, the crosslinking agents preferably being polyolefinically unsaturated compounds such as tetraallyloxyethane, allyl sucrose, allylpentaerythritol and methylene bisacrylamide.
  • Such a polymer is contained in the commercial product Sepigel ® 305 from SEPPIC.
  • the use of this compound, which in addition to the polymer component contains a hydrocarbon mixture (C ⁇ 3 -C ⁇ 4 isoparaffin) and a nonionic emulsifier (Laureth-7), has proven to be particularly advantageous in the context of the teaching according to the invention.
  • a compound with isohexadecane and sold under the name Simulgel ® 600 Polysorbate-80 sodium acryloyldimethyltaurate copolymers have proven effective as in the present invention particularly.
  • anionic homopolymers are uncrosslinked and crosslinked polyacrylic acids. Allyl ethers of pentaerythritol, sucrose and propylene can be preferred crosslinking agents. Such compounds are for example available under the trademark Carbopol ® commercially.
  • Copolymers of maleic anhydride and methyl vinyl ether are also color-preserving polymers.
  • a crosslinked with 1,9-decadiene maleic acid-methyl vinyl ether copolymer is available under the name Stabileze® ® QM.
  • Anionic polymers which are also suitable according to the invention include a .:
  • Vinyl acetate / crotonic acid copolymers such as are commercially available for example under the names Resyn ® (National Starch), Luviset ® (BASF) and Gafset ® (GAF).
  • Vinylpyrrolidone / vinyl acrylate copolymers obtainable for example under the trade name Luviflex ® (BASF).
  • a preferred polymer is that available under the name Luviflex VBM-35 ® (BASF) vinylpyrrolidone / acrylate terpolymers.
  • Acrylic acid / ethyl acrylate / N-tert-butyl acrylamide tepolymers which are sold, for example, under the name Ultrahold ® strict (BASF).
  • Amphoteric polymers (G3) can also be used as polymers.
  • amphoteric polymers includes both those polymers which contain both free amino groups and free -COOH or SO 3 H groups in the molecule and are capable of forming internal salts, as well as zwitterionic polymers which in the Molecule contain quaternary ammonium groups and -COO " - or -SO 3 " groups, and summarized those polymers which contain -COOH or SO 3 H groups and quaternary ammonium groups.
  • amphopolymer suitable is that available under the designation Amphömer ® acrylic resin which is a copolymer of ethyl methacrylate tert-butylamino, N- (1,1,3,3-tetramethylbutyl) -acrylamide and two or more monomers from the group Acrylic acid, methacrylic acid and their simple esters.
  • Amphömer ® acrylic resin which is a copolymer of ethyl methacrylate tert-butylamino, N- (1,1,3,3-tetramethylbutyl) -acrylamide and two or more monomers from the group Acrylic acid, methacrylic acid and their simple esters.
  • amphoteric polymers which can be used according to the invention are the compounds mentioned in British Patent Application 2 104 091, European Patent Application 47 714, European Patent Application 217 274, European Patent Application 283 817 and German Patent Application 28 17 369.
  • Further suitable zwitterionic polymers are methacroylethylbetaine / methacrylate copolymers, which are available under the name Amersette® ® (AMERCHOL).
  • Amphoteric polymers which are preferably used are those polymers which essentially consist of one another
  • A is the anion of an organic or inorganic acid
  • these compounds can be used both directly and in salt form, which is obtained by neutralizing the polymers, for example with an alkali metal hydroxide.
  • an alkali metal hydroxide for example, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium carbonate, sodium sulfate, sodium sulfate, sodium sulfate, sodium sulfate ion, are very particularly preferred ; Acrylamido-propyl-trimethyl-ammonium chloride is a particularly preferred monomer (a).
  • Acrylic acid is preferably used as monomer (b) for the polymers mentioned.
  • the agents according to the invention can contain nonionic polymers (G4).
  • Suitable nonionic polymers are for example:
  • Vinylpyrrolidone / Vinylester copolymers as are marketed, for example under the trademark Luviskol ® (BASF).
  • Luviskol ® VA 64 and Luviskol ® VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are also preferred nonionic polymers.
  • Cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and methyl hydroxypropylcellulose, as they are for example sold under the trademark Culminal® ® and Benecel ® (AQUALON).
  • Siloxanes These siloxanes can be both water-soluble and water-insoluble. Both volatile and non-volatile siloxanes are suitable, non-volatile siloxanes being understood to mean those compounds whose boiling point is above 200 ° C. at normal pressure.
  • Preferred siloxanes are polydialkylsiloxanes, such as, for example, polydimethylsiloxane, polyalkylarylsiloxanes, such as, for example, polyphenylmethylsiloxane, ethoxylated polydialkylsiloxanes and polydialkylsiloxanes which contain amine and / or hydroxyl groups.
  • the preparations used contain several, in particular two different polymers of the same charge and / or each contain an ionic and an amphoteric and / or non-ionic polymer.
  • the polymers (G) are preferably present in the agents used according to the invention in amounts of 0.01 to 30% by weight, based on the total agent. Amounts from 0.01 to 25, in particular from 0.01 to 15% by weight are particularly preferred.
  • the third component of the combination according to the invention is a cosmetic active ingredient.
  • the selection of the active ingredient concerned depends on the desired effect which is to be achieved with the molded body.
  • the active ingredient groups described below are preferably selected according to the invention.
  • the first group of active ingredients is fat (D).
  • Fat substances are to be understood as meaning fatty acids, fatty alcohols, natural and synthetic waxes, which can be present both in solid form and in liquid form in aqueous dispersion, and natural and synthetic cosmetic oil components.
  • Linear and / or branched, saturated and / or unsaturated fatty acids having 6 to 30 carbon atoms can be used as fatty acids (DI).
  • Fatty acids with 10-22 carbon atoms are preferred.
  • isostearic as the commercial products Emersol ® 871 and Emersol ® 875
  • Isopalmitic acids such as the commercial product Edenor ® IP 95, as well as all other fatty acids sold under the trade names Edenor ® (Cognis).
  • fatty acids are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, aradoelic acid, elaaloic acid Behenic acid and eraic acid, as well as their technical mixtures, which are obtained, for example, in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from Roelen's oxosynthesis or in the dimerization of unsaturated fatty acids.
  • the fatty acid cuts which are obtainable from coconut oil or palm oil are usually particularly preferred; the use of stearic acid is generally particularly preferred.
  • the amount used is 0.1-15% by weight, based on the total agent.
  • the amount is preferably 0.5-10% by weight, with amounts of 1-5% by weight being very particularly advantageous.
  • Saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C 6 -C 30 , preferably C 10 -C 22 and very particularly preferably C 12 -C 22 carbon atoms can be used as fatty alcohols (D2).
  • the fatty alcohols derive from preferably natural fatty acids, and it can usually be assumed that they are obtained from the esters of the fatty acids by reduction.
  • suitable according to the invention are those fatty alcohol cuts which are produced by reducing naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or fatty acid esters resulting from their transesterification products with corresponding alcohols, and thus a Make a mixture of different fatty alcohols.
  • Such substances are, for example, under the names Stenol ® , for example Stenol ® 1618 or Lanette ® , for example Lanette ® O or Lorol ® , for example Lorol ® C8, Lorol ® C14, Lorol ® C18, Lorol ® C8-18, HD-Ocenol ® , Crodacol ® , e.g.
  • wool wax alcohols such as those commercially available under the names Corona ® , White Swan ® , Coronet ® or Fluilan ® , can also be used.
  • the fatty alcohols are used in amounts of 0.1-30% by weight, based on the entire preparation, preferably in amounts of 0.1-20% by weight.
  • Solid paraffins or isoparaffins, carnauba waxes, beeswaxes, candelilla waxes, ozokerites, ceresin, walnut, sunflower wax, fruit waxes such as apple wax or citras wax, microwaxes made of PE or PP can be used according to the invention as natural or synthetic waxes (D3).
  • Such waxes are available, for example, from Kahl & Co., Trittau.
  • the amount used is 0.1-50% by weight, based on the total agent, preferably 0.1
  • the natural and synthetic cosmetic oil bodies (D4) which can increase the effect of the active ingredient according to the invention include, for example:
  • oils examples include sunflower oil, olive oil, soybean oil, rapeseed oil, almond oil, jojoba oil, orange oil, wheat germ oil, peach seed oil and the liquid components of coconut oil.
  • Other triglyceride oils such as the liquid portions of beef tallow and synthetic triglyceride oils are also suitable.
  • the compounds are available as commercial products l, 3-di- (2-ethyl-hexyl) -cyclohexane (Cetiol ® S), and di-n-octyl ether (Cetiol ® OE) may be preferred.
  • Ester oils are understood to mean the esters of C 6 -C 30 fatty acids with C -C 30 fatty alcohols.
  • the monoesters of fatty acids with alcohols having 2 to 24 carbon atoms are preferred.
  • Examples of fatty acid moieties in the esters are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, Isotridecan- acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, Benzenic acid and eraic acid, as well as their technical mixtures, which occur, for example, in the cleavage of natural fats and oils, in the oxidation of aldehydes from Roelen's o
  • fatty alcohol fractions in the ester oils are isopropyl alcohol, capron alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaololyl alcohol, elaolyl alcohol, elaolyl alcohol Gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures, which are obtained, for example, in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from Roelen's oxosynthesis and as a monomer fraction in the dimerization of unsaturated fatty alcohols.
  • isopropyl myristate IPM Rilanit ®
  • isononanoic acid C16-18 alkyl ester Cetiol ® SN
  • 2-ethylhexyl palmitate Cegesoft ® 24
  • stearic acid-2-ethylhexyl ester Cetiol ® 868
  • cetyl oleate glycerol triesters caprylate
  • KPK fatty alcohol caprinate / caprylate Cetiol ® LC
  • n-butyl stearate Oleyleracat
  • isopropyl palmitate Rosanit ® IPP
  • oleyl oleates Cetiol ®
  • hexyl laurate Cetiol ® A
  • di-n -butyl adipate Cetiol ® B
  • myrist IPM Rilanit ®
  • Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecylacelate as well as diol esters such as ethylene glycol dioleate, ethylene glycol di-isotridecanoate, propylene glycol di (2- ethylhexanoate), propylene glycol di-isostearate, propylene glycol di-pelargonate, butanediol di-isostearate, neopentyl glycol dicaprylate,
  • Fatty acid partial glycerides are monoglycerides, diglycerides and their technical mixtures. When using technical products, small quantities of triglycerides may still be present due to the manufacturing process.
  • the partial glycerides preferably follow the formula (D4-I),
  • R 1 , R 2 and R 3 independently of one another represent hydrogen or a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22, preferably 12 to 18, carbon atoms, with the proviso that at least one of these grapples represents one Acylrest and at least one of these Grappen stands for hydrogen.
  • the sum (m + n + q) represents 0 or numbers from 1 to 100, preferably 0 or 5 to 25.
  • R 1 preferably represents an acyl radical and R 2 and R 3 represents hydrogen and the sum (m + n + q) is 0.
  • Typical examples are mono- and / or diglycerides based on caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid , Linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and their technical mixtures. Oleic acid non-glycerides are preferably used.
  • the amount of natural and synthetic cosmetic oil bodies used in the agents used according to the invention is usually 0.1-30% by weight, based on the total agent, preferably 0.1-20% by weight, and in particular 0.1-15% by weight. -%.
  • the total amount of oil and fat components in the agents according to the invention is usually 0.5-75% by weight, based on the total agent. Quantities of 0.5-35% by weight are preferred according to the invention.
  • the combination of the combination according to the invention with surfactants (E) has also proven to be advantageous.
  • the agents used according to the invention contain surfactants.
  • surfactants is understood to mean surface-active substances which form adsorption layers on surfaces and interfaces or can aggregate in volume phases to form micelle colloids or lyotropic mesophases.
  • anionic surfactants consisting of a hydrophobic residue and a negatively charged hydrophilic head group
  • amphoteric surfactants which carry both a negative and a compensating positive charge
  • cationic surfactants which in addition to a hydrophobic residue have a positively charged hydrophilic group
  • nonionic surfactants which have no charges but strong dipole moments and are highly hydrated in aqueous solution.
  • Suitable anionic surfactants (E1) in preparations according to the invention are all anionic surface-active substances suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. B. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group with about 8 to 30 carbon atoms.
  • the molecule can contain glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups.
  • suitable anionic surfactants are, in each case in the form of the sodium, potassium lium and ammonium as well as the mono-, di- and trialkanolammonium salts with 2 to 4 carbon atoms in the alkanol group,
  • Alkyl sulfates and alkyl polyglycol ether sulfates of the formula RO (CH 2 -CH 2 O) x -OSO 3 H, in which R is a preferably linear alkyl group with 8 to 30 C atoms and x 0 or 1 to 12,
  • Esters of tartaric acid and citric acid with alcohols which are adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols having 8 to 22 carbon atoms,
  • R 1 is preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms
  • R 2 is hydrogen, a radical (CH 2 CH 2 O) n R I or X
  • n is a number from 1 to 10
  • X is hydrogen, an alkali or alkaline earth metal or NR 3 RR 5 R 6 , with R 3 to R 6 independently of one another representing hydrogen or a Cl to C4 hydrocarbon radical, is sulfated fatty acid alkylene glycol ester of the formula (El -II).
  • R 7 CO (AlkO) n SO 3 M (El -II) in the R CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical with 6 to 22 C atoms, alk for CH 2 CH 2 , CHCH 3 CH 2 and / or CH CHCH 3 , n stands for numbers from 0.5 to 5 and M stands for a cation as described in DE-OS 197 36 906.5, • monoglyceride sulfates and monoglyceride ether sulfates of the formula (III)
  • Typical examples of monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride as well as their ethylene oxide adducts or their formulated with sulfuric acid trioxide.
  • Monoglyceride sulfates of the formula (III) are preferably used, in which R 8 CO represents a linear acyl radical having 8 to 18 carbon atoms, as described, for example, in EP-Bl 0 561 825, EP-Bl 0 561 999, DE -Al 42 04 700 or by AKBiswas et al. in J.Am.Oil.Chem.Soc. 37, 171 (1960) and FUAhmed in J.Am.Oil.Chem.Soc. 67, 8 (1990),
  • Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids with 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule, sulfobemsemic acid and dialkyl esters with 8 to 18 carbon atoms in the alkyl group and sulfosuccinic acid mono-alkylpolyoxyethyl ester up to 18 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups, monoglycer disulfates, alkyl and alkenyl ether phosphates as well as protein fatty acid condensates.
  • Zwitterionic surfactants are surface active compounds which contain at least one quaternary um distr in the molecule Ammom 'and at least one -COO H - or -SO 3 H group carry.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example coconut alkyl dimethylammomumglycinate, N-acylaminopropyl-N, N-dimethylammpniumglycinate,.
  • cocoacylaminopropyl dimethylammonium glycinate for example the cocoacylaminopropyl dimethylammonium glycinate, and 2-alkyl-3-carboxymethyl-3-hydroxyethyl imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethyl hydroxyethylcarboxymethylglycinate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known under the INCI name Cocamidopropyl Betaine.
  • Ampholytic surfactants (E3) are understood to mean those surface-active compounds which, in addition to a C 8 -C 24 -alkyl or -acyl group, contain at least one free amino group and at least one -COOH or -SO 3 H group in the molecule and for formation inner salts are capable.
  • suitable ampholytic surfactants are N-alkylglycine, N-alkylpropionic acid, N-alkylaminobutyric acid, N- alkyliminodipropionic acid, N-hydroxyethyl-N-alkylamidopropylglycine, N-
  • Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethyl aminopropionate and C 12 - 8 - sarcosine.
  • Nonionic surfactants (E4) contain, for example, a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether group as hydrophilic groups. Such connections are, for example
  • R ! CO represents a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms
  • R 2 represents hydrogen or methyl
  • R 3 represents linear or branched alkyl radicals having 1 to 4 carbon atoms
  • w represents numbers from 1 to 20
  • Hydroxy mixed ethers as described, for example, in DE-OS 19738866, Sorbitan fatty acid esters and addition products of ethylene oxide onto sorbitan fatty acid esters such as, for example, the polysorbates,
  • R represents an alkyl or alkenyl radical having 4 to 22 carbon atoms
  • G represents a sugar radical having 5 or 6 carbon atoms
  • p represents numbers from 1 to 10. They can be obtained according to the relevant procedures in preparative organic chemistry. Representative of the extensive literature here is the review by Biermann et al. in Starch /force 45, 281 (1993), B. Salka in Cosm.Toil. 108, 89 (1993) and J. Kahre et al. in S ⁇ FW Journal Issue 8, 598 (1995).
  • the alkyl and alkenyl oligoglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably from glucose.
  • the preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides.
  • the index number p in the general formula (E4-1T) indicates the degree of oligomerization (DP), ie the distribution of mono- and oligoglycosides, and stands for a number between 1 and 10.
  • the value p for a certain alkyl oligoglycoside is an analytically determined arithmetic parameter, which usually represents a fractional number.
  • Alkyl and / or alkenyl oligoglycosides with an average degree of oligomerization p of 1.1 to 3.0 are preferably used. From an application point of view, preference is given to those alkyl and / or alkenyl oligoglycosides whose degree of oligomerization is less than 1.7 and is in particular between 1.2 and 1.4.
  • the alkyl or alkenyl radical R 4 can be derived from primary alcohols having 4 to 11, preferably 8 to 10, carbon atoms. Typical examples are butanol, capronic alcohol, caprylic alcohol, capric alcohol and Undecyl alcohol and their technical mixtures, such as those obtained in the hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelen's oxosynthesis.
  • the alkyl or alkenyl radical R 15 can also be derived from primary alcohols having 12 to 22, preferably 12 to 14, carbon atoms.
  • Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol and their technical mixtures, which can be obtained as described above.
  • R 5 CO for an aliphatic acyl radical having 6 to 22 carbon atoms
  • R 6 for hydrogen, an alkyl or hydroxyalkyl radical with 1 to 4 carbon atoms
  • [Z] for a linear or branched polyhydroxyalkyl radical with 3 to 12 carbon atoms and 3 to 10 hydroxyl groups stands.
  • the fatty acid N-alkylpolyhydroxyalkylamides are known substances which are usually obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and. subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride can be obtained. With regard to the processes for their production, reference is made to US Pat. Nos.
  • the fatty acid N-alkylpolyhydroxyalkylamides are preferably derived from reducing sugars having 5 or 6 carbon atoms, in particular from glucose.
  • the preferred fatty acid N-alkylpolyhydroxyalkylamides are therefore fatty acid N-alkylglucamides as represented by the formula (E4-JV):
  • the preferred fatty acid N-alkylpolyhydroxyalkylamides used are glucamides of the formula (E4-JV) in which R 8 is hydrogen or an alkyl group and R 7 CO is the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, Stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, arachic acid, gadoleic acid, behenic acid or erucic acid or their technical mixtures.
  • R 8 is hydrogen or an alkyl group
  • R 7 CO is the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmoleic acid, Stearic acid, isostearic acid, oleic acid, elaidic acid, petrose
  • Fatty acid N-alkylglucamides of the formula (E4-IV) which are obtained by reductive amination of glucose with methylamine and subsequent acylation with lauric acid or C12 / 14 coconut fatty acid or a corresponding derivative are particularly preferred.
  • the polyhydroxyalkylamides can also be derived from maltose and palatinose.
  • alkylene oxide adducts with saturated linear fatty alcohols and fatty acids, each with 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid, have proven to be preferred nonionic surfactants. Preparations with excellent properties are also obtained if they contain fatty acid esters of ethoxylated glycerol as nonionic surfactants.
  • the alkyl radical R contains 6 to 22 carbon atoms and can be either linear or branched. Primary linear and methyl-branched aliphatic radicals in the 2-position are preferred. Such alkyl radicals are, for example, 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. 1-Octyl, 1-decyl, 1-lauryl, 1-myristyl are particularly preferred. Using So-called "oxo alcohols" as starting materials predominate compounds with an odd number of carbon atoms in the alkyl chain.
  • nonionic surfactants are the sugar surfactants. These can be present in the agents used according to the invention preferably in amounts of 0.1-20% by weight, based on the total agent. Amounts of 0.5-15% by weight are preferred, and amounts of 0.5-7.5% by weight are very particularly preferred.
  • the compounds with alkyl groups used as surfactant can each be uniform substances. However, it is generally preferred to use native vegetable or animal raw materials in the production of these substances, so that substance mixtures with different alkyl chain lengths depending on the respective raw material are obtained.
  • both products with a "normal” homolog distribution and those with a narrowed homolog distribution can be used.
  • “Normal” homolog distribution is understood to mean mixtures of homologs which are obtained as catalysts from the reaction of fatty alcohol and alkylene oxide using alkali metals, alkali metal hydroxides or alkali metal alcoholates.
  • narrow homolog distributions are obtained if, for example, hydrotalcites, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates are used as catalysts. The use of products with a narrow homolog distribution can be preferred.
  • the surfactants (E) are used in amounts of 0.1-45% by weight, preferably 0.5-30% by weight and very particularly preferably 0.5-25% by weight, based on the total agent used according to the invention .
  • Cationic surfactants (E5) can also be used according to the invention:
  • Typical examples of cationic surfactants are, in particular, tefraalkylammonium compounds, amidoamines or esterquats.
  • Preferred quaternary ammonium compounds are ammonium halides, in particular chlorides and bromides, such as alkyltrimethylammonium ammoriiumchloride, dialkyldimethylammonium chloride and Trialkylmethylammonium-, for example cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, stearyldimethylammoniumchlprid di-, lauryldimethylammonium chloride, lauryl dimethylbenzyl ammonium chloride, tricetyl methyl ammonium chloride, hydroxyethyl Hydroxycetyl Dimmonium chlorides, as well as those available under the designations DSfCI Quatemium-27 and Quaternium-83 known imidazolium compounds.
  • the long alkyl chains of the above-mentioned surfactants preferably have 10 to 18 carbon atoms.
  • Ester quats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element.
  • R 14 CO stands for an acyl radical with 6 to 22 carbon atoms
  • R 15 and R 16 independently of one another for hydrogen or R 14 CO
  • ester quats that can be used in the context of the invention are products based on caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, isostearic acid, stearic acid, oleic acid, elaidic acid, arachic acid, behenic acid and eraic acid and their technical mixtures, such as they occur, for example, in the splitting of natural fats and oils.
  • technical C ⁇ 2 are / ⁇ 8 cocofatty acids and, in particular partly hydrogenated Q o / t s tallow or palm oil fatty acids and elaidic C 16/18 -Fett- sections acid used.
  • the fatty acids and the triethanolamine can be used in a molar ratio of 1.1: 1 to 3: 1 to produce the quaternized esters.
  • an application ratio of 1.2: 1 to 2.2: 1, preferably 1.5: 1 to 1.9: 1 has proven to be particularly advantageous.
  • the preferred ester quats are technical mixtures of mono-, di- and tri-esters with an average degree of esterification of 1.5 to 1.9 and are derived from technical C] 6/18 - tallow or palm fatty acid (iodine number 0 to 40) from.
  • quaternized fatty acid triethanolamine ester salts of the formula (E5-I) have proven to be particularly advantageous in which R 14 CO for an acyl radical having 16 to 18 carbon atoms, R 15 for R 15 CO, R 16 for hydrogen, R 17 for a methyl group , ml, m2 and m3 for 0 and Y for methyl sulfate.
  • quaternized ester salts of fatty acids with diethanolalkylamines of the formula (E5-II) are also suitable as ester quats.
  • R 18 CO for an acyl radical with 6 to 22 carbon atoms
  • R 19 for hydrogen or R 18 CO
  • R 20 and R 21 independently of one another for alkyl radicals with 1 to 4 carbon atoms
  • m5 and m.6 in total for 0 or numbers from 1 to 12
  • Y again represents halide, alkyl sulfate or alkyl phosphate.
  • ester quats there are also substances in which the ester bond is replaced by an amide bond and which preferably follow the formula (E5-TV) based on diethylene triamine,
  • R 27 CO represents an acyl radical with 6 to 22 carbon atoms
  • R 29 and R 30 independently of one another for alkyl radicals with 1 to 4 carbon atoms
  • amide ester quats are available on the market, for example, under the Incroquat® (Croda) brand.
  • Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyl dialkylamines.
  • Such products are sold, for example, under the trademarks Stepantex ® , Dehyquart ® and Armocare ® .
  • the alkylamidoamines are usually produced by amidation of natural or synthetic fatty acids and fatty acid cuts with dialkylaminoamines.
  • An inventively particularly suitable compound from this group is that available under the name Tegoamid ® S 18 commercially stearamidopropyl dimethylamine.
  • the cationic surfactants (E5) are preferably present in the agents used according to the invention in amounts of 0.05 to 10% by weight, based on the total agent. Amounts. from 0.1 to 5% by weight are particularly preferred.
  • Anionic, nonionic, zwitterionic and / or amphoteric surfactants and mixtures thereof can be preferred according to the invention.
  • the effect of the combination according to the invention can be increased by emulsifiers (F).
  • Emulsifiers bring about the formation of water- or oil-stable adsorption layers at the phase interface, which protect the dispersed droplets against coalescence and thus stabilize the emulsion.
  • emulsifiers are therefore made up of a hydrophobic and a hydrophilic part of the molecule. Hydrophilic emulsifiers preferably form O / W emulsions and hydrophobic emulsifiers preferably form W / O
  • An emulsion is to be understood as a droplet-like distribution (dispersion) of a liquid in another liquid with the expenditure of energy to create stabilizing phase interfaces by means of surfactants.
  • the selection of these emulsifying surfactants or emulsifiers depends on the
  • Emulsifiers which can be used according to the invention are, for example
  • alkyl (oligo) glucosides for example the commercially available product Montanov ® 68,
  • Sterols are understood to mean a group of steroids which have a hydroxyl group on the C atom 3 of the steroid structure and are isolated both from animal tissue (zoosterols) and from vegetable fats (phytosterols). Examples of zoosterols are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. Sterols, the so-called mycosterols, are also isolated from mushrooms and yeasts.
  • glucose phospholipids include primarily the glucose phospholipids, e.g. as lecithins or phosphididylcholines from e.g. Egg yolks or plant seeds (e.g. soybeans) are understood.
  • Fatty acid esters of sugars and sugar alcohols such as sorbitol
  • Poiyglycerinderivate such as polyglycerol poly-12-hy- droxystearat (Dehymuls ® PGPH commercial product)
  • compositions according to the invention preferably contain the emulsifiers in amounts of 0.1-25% by weight, in particular 0.5-15% by weight, based on the total composition.
  • compositions according to the invention can preferably contain at least one nonionic emulsifier with an HLB value of 8 to 18, according to the 10th edition, Georg Thieme Verlag Stuttgart, New York, in Römpp-Lexikon Chemie (Ed. J. Falbe, M. Regitz). (1997), page 1764, contain the definitions listed. nonionic Emulsifiers with an HLB value of 10-15 can be particularly preferred according to the invention.
  • Protein hydrolyzates and / or amino acids and their derivatives may also be present in the preparations used according to the invention.
  • Protein hydrolyzates are product mixtures that are obtained by acidic, basic or enzymatically catalyzed breakdown of proteins (proteins).
  • the term protein hydrolyzates according to the invention. total hydrolyzates as well as individual amino acids and their derivatives as well as mixtures of different amino acids are understood.
  • polymers constructed from amino acids and amino acid derivatives are furthermore to be understood under the term protein hydrolyzates. The latter include, for example, polyalanine, polyasparagine, polyserine, etc.
  • L-alanyl-L-proline polyglycine, glycyl-L-glutamine or D / L-methionine-S-methylsulfonium chloride.
  • ß-amino acids and their derivatives such as ß-alanine, anthranilic acid or hippuric acid can also be used according to the invention.
  • the molecular weight of the protein hydrolyzates which can be used according to the invention is between 75, the molecular weight for glycine, and 200,000, preferably the molecular weight is 75 to 50,000 and very particularly preferably 75 to 20,000 daltons.
  • protein hydrolyzates of plant, animal, marine or synthetic origin can be used.
  • Animal protein hydrolyzates are, for example, elastin, collagen, keratin, silk and milk protein protein hydrolyzates, which can also be in the form of salts.
  • Such products are, for example, under the trademarks Dehylan ® (Cognis), Promois ® (Interorgana), Collapuron ® (Cognis), Nutrilan ® (Cognis), Gelita-Sol ® (Deutsche Gelatine Fabriken Stoess & Co), Lexein ® (Inolex) and Kerasol ® (Croda) sold.
  • protein hydrolysates of plant origin e.g. B. soy, almond, pea, potato and wheat protein hydrolyzates.
  • Such products are, for example, under the trademarks Gluadin ® (Cognis), DiaMin ® (Diamalt), Lexein ® (inolex), Hydrosoy ® (Croda), Hydrölupin ® (Croda), Hydrosesame ® (Croda), Hydrotritium ® (Croda) and Crotein ® (Croda) available.
  • protein hydrolyzates amino acid mixtures obtained in some other way can optionally be used in their place.
  • derivatives of protein hydrolyzates for example in the form of their fatty acid condensation products. Such products are sold, for example, under the names Lamepon ® (Cognis), Lexein ® (Inolex), Crolastin ® (Croda) or Crotein (Croda).
  • the protein hydrolyzates or their derivatives are contained in the agents used according to the invention preferably in amounts of 0.1 to 10% by weight, based on the total agent. Amounts of 0.1 to 5% by weight are particularly preferred.
  • the action of the active compounds (A) can be increased by UV filters (I).
  • the structure and physical properties of the UV filters to be used according to the invention are not subject to any general restrictions. Rather, all UV filters that can be used in the cosmetics sector are suitable, the absorption maximum of which lies in the UVA (315-400 ⁇ m), in the UVB (280-315 nm) or in the UVC ( ⁇ 280 nm) range. UV filters with an absorption maximum in the UVB range, in particular in the range from approximately 280 to approximately 300 nm, are particularly preferred.
  • the UV filters used according to the invention can be selected, for example, from substituted benzophenones, p-aminobenzoic acid esters, diphenylacrylic acid esters, cinnamic acid esters, salicylic acid esters, benzimidazoles and o-aminobenzoic acid esters.
  • UV filters which can be used according to the invention are 4-amino-benzoic acid, N, N, N-trimethyl-4- (2-oxobom-3-ylidenemethyl) aniline-methyl sulfate, 3,3,5-trimethyl-cyclohexyl-salicylate (homosalates ), 2-Hydroxy-4-methoxy-benzophenone (Benzophenone-3; Uvinul ® M 40, Uvasorb ® MET, Neo Heliopan ® BB, Eusolex ® 4360), 2-phenylbenzimidazole-5-sulfonic acid and its potassium, sodium and triethanolamine salts (phenylbenzimidazole sulfonic acid; Parsol ® HS; Neo Heliopan ® Hydro), 3 , 3 '- (1,4-phenylenedimethylene) -bis (7,7-dimethyl-2-oxobicyclo- [2.2.1] hept-l-yl-methanesulfonic
  • Phenylenedimethylene -bis (7,7-dimethyl-2-oxobicyclo- [2.2.1] hept-l-yl-methanesulfonic acid) and their salts, l- (4-tert-butylphenyl) -3 - (4-methoxyphenyl) propane-1,3-dione, ⁇ -
  • 2-hydroxy-4-methoxy-benzophenone, 2-phenylbenzimidazole-5-sulfonic acid and their potassium, sodium and triethanolamine salts, l- (4-tert-butylphenyl) -3- (4-methoxyphenyl) are very particularly preferred -propan-l, 3-dione, 4-methoxycinnamic acid-2-ethylhexyl ester and 3- (4'-methylbenzylidene) -D, L-camphor.
  • Preferred UV filters are those whose molar extinction coefficient at the maximum absorption is above 15,000, in particular above 20,000.
  • water-insoluble compound has, in the context of the teaching according to the invention, the higher activity than those water-soluble compounds which differ from it by one or more additional ionic groups.
  • water-insoluble are UV filters which do not dissolve in water at 20 ° C. by more than 1% by weight, in particular not more than 0.1% by weight.
  • these compounds should be at least 0.1, in particular at least 1% by weight soluble in conventional cosmetic oil components at room temperature). The use of water-insoluble UV filters can therefore be preferred according to the invention.
  • those UV filters are preferred which have a cationic grappe, in particular a quaternary ammonium group.
  • UV filters have the general structure U - Q.
  • the structural part U stands for a Grappe absorbing UV rays.
  • this grappe can be derived from the known UV filters mentioned above, which can be used in the cosmetics sector, in which a group, generally a hydrogen atom, of the UV filter is replaced by a cationic group Q, in particular with a quaternary amino function.
  • Structural parts U which are derived from cinnamic acid amide or from N, N-dimethylamino-benzoic acid amide are preferred according to the invention.
  • the structural parts U can in principle be selected so that the absorption maximum of the UV filter can be both in the UVA (315-400 nm) and in the UVB (280-315 nm) or in the UVC ( ⁇ 280 nm) range.
  • UV filters with an absorption maximum in the UVB range in particular in the range from approximately 280 to approximately 300 nm, are particularly preferred.
  • the structural part U is preferably selected such that the molar extinction coefficient of the UV filter at the absorption maximum is above 15,000, in particular above 20,000.
  • the structural part Q preferably contains a quaternary ammonium group as the cationic group.
  • this quaternary ammonium group can be directly connected to the structural part U, so that the structural part U is one of the four substituents of the positively charged nitrogen atom.
  • one of the four substituents on the positively charged nitrogen atom is preferably a grappe, in particular an alkylene group with 2 to 6 carbon atoms, which functions as a connection between the structural part U and the positively charged nitrogen atom.
  • the Grappe Q advantageously has the general structure - (CH 2 ) X -N + R 1 R 2 R 3 X " , in which x stands for an integer from 1 to 4, R 1 and R 2 independently of one another stand for C 1 - -alkyl groups, R 3 stands for a C]. 22 -alkyl group or a benzyl group and X " for a physiologically compatible anion.
  • x preferably represents the number 3, R 1 and R 2 each for a methyl group and R 3 either for a methyl group or a saturated or unsaturated, linear or branched hydrocarbon chain having 8 to 22, in particular 10 to 18, carbon atoms.
  • Physiologically acceptable anions are, for example, inorganic anions such as halides, in particular chloride, bromide and fluoride, sulfate ions and phosphate ions, and organic anions such as lactate, citrate, acetate, tarfrate, methosulfate and tosylate.
  • inorganic anions such as halides, in particular chloride, bromide and fluoride, sulfate ions and phosphate ions
  • organic anions such as lactate, citrate, acetate, tarfrate, methosulfate and tosylate.
  • Two preferred UV filters with cationic groups are the commercially available compounds cinnamic acid frimethylammoniumchlorid (Incro- quat ® UV-283) and dodecyl tosylate (Escalol ® HP 610). ,
  • the teaching according to the invention also includes the use of a combination of several UV filters.
  • the combination of at least one water-insoluble UV filter with at least one UV filter with a cationic group is preferred.
  • the UV filters (I) are usually present in the agents used according to the invention in amounts of 0.1-5% by weight, based on the total agent. Amounts of 0.4-2.5% by weight are preferred.
  • the effect of the combination according to the invention can be further increased by a 2-pyrrolidinone-5-carboxylic acid and its derivatives (J).
  • Another object of the invention is therefore the use of the active ingredient in combination with derivatives of 2-pyrrolidinone-5-carboxylic acid.
  • the sodium, potassium, calcium, Magnesium or ammonium salts in which the ammonium ion in addition to hydrogen carries a 4 -Alkylgrappen to three Ci-C.
  • the sodium salt is very particularly preferred.
  • the amounts used in the agents according to the invention are 0.05 to 10% by weight, based on the total agent, particularly preferably 0.1 to 5 and in particular 0.1 to 3% by weight.
  • active ingredient (A) with vitamins, provitamins and vitamin precursors and their derivatives (K) has also proven to be advantageous.
  • Vitamins, pro-vitamins and vitamin precursors which are usually assigned to groups A, B, C, E, F and H are preferred according to the invention.
  • the Grappe of the substances called vitamin A include retinol (vitamin A) and 3,4-didehydroretinol (vitamin A 2 ).
  • the ß-carotene is the provitamin of retinol.
  • vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as palmitate and acetate come into consideration as vitamin A components.
  • the preparations used according to the invention preferably contain the vitamin A component in amounts of 0.05-1% by weight, based on the entire preparation.
  • the vitamin B grappa or the vitamin B complex include a.
  • Vitamin B 2 (riboflavin)
  • nicotinic acid and nicotinamide are often listed under this name. According to the invention, preference is given to nicotinic acid amide, which is preferably present in the agents used according to the invention in amounts of 0.05 to 1% by weight, based on the total agent.
  • panthenol and / or pantolactone is preferably used.
  • Derivatives of panthenol which can be used according to the invention are, in particular, the esters and ethers of panthenol and cationically derivatized panthenols. Individual representatives are for example, the panthenol triacetate, the panthenol monoethyl ether and its monoacetate and the cationic panthenol derivatives disclosed in WO 92/13829.
  • the compounds of the vitamin Bs type mentioned are preferably present in the agents used according to the invention in amounts of 0.05-10% by weight, based on the total agent. Amounts of 0.1-5% by weight are particularly preferred.
  • - Vitamin B 6 pyridoxine, pyridoxamine and pyridoxal).
  • Vitamin C (ascorbic acid). Vitamin C is preferably used in the agents used according to the invention in amounts of 0.1 to 3% by weight, based on the total agent. Use in the form of the palmitic acid ester, the glucosides or phosphates can be preferred. Use in combination with tocopherols may also be preferred.
  • Vitamin E tocopherols, especially ⁇ -tocopherol.
  • Tocopherol and its derivatives which include in particular the esters such as acetate, nicotinate, phosphate and succinate, are preferably present in the agents used according to the invention in amounts of 0.05-1% by weight, based on the total agent ,
  • Vitamin F usually means essential fatty acids, in particular linoleic acid, linolenic acid and arachidonic acid.
  • Vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexa- hydrothienol [3,4-f] imidazole-4-valeric acid, for which the trivial name biotin has now become established.
  • Biotin is contained in the agents used according to the invention preferably in amounts of 0.0001 to 1.0% by weight, in particular in amounts of 0.001 to 0.01% by weight.
  • the agents used according to the invention preferably contain vitamins, provitamins and vitamin precursors from grappa A, B, E and H. Panthenol, pantolactone, pyridoxine and its derivatives as well as nicotinamide and biotin are particularly preferred.
  • extracts are usually produced by extracting the entire plant. In individual cases, however, it may also be preferred to produce the extracts exclusively from flowers and / or leaves of the plant.
  • the extracts from green tea, oak bark, nettle, witch hazel, hops, chamomile, burdock root, horsetail, linden flowers, almond, aloe vera, coconut, mango, apricot, lime, wheat, kiwi, melon, orange, grapefruit, sage, are particularly preferred.
  • the excerpts from green tea, almond, aloe vera, coconut, mango, apricot, lime, wheat, kiwi and melon are particularly suitable for the use according to the invention.
  • Alcohols and mixtures thereof can be used as extractants for the production of the plant extracts mentioned.
  • alcohols lower alcohols such as ethanol and isopropanol, but in particular polyhydric alcohols such as ethylene glycol and propylene glycol, are preferred, both as the sole extracting agent and in a mixture with water.
  • Plant extracts based on water / propylene glycol in a ratio of 1:10 to 10: 1 have proven to be particularly suitable.
  • the plant extracts can be used both in pure and in diluted form. If they are used in diluted form, they usually contain about 2 to 80% by weight of active substance and, as a solvent, the extractant or mixture of extractants used in their extraction.
  • mixtures of several, in particular two, different plant extracts in the agents according to the invention may be preferred.
  • penetration aids and / or swelling agents are present. These auxiliaries ensure better penetration of active ingredients into the keratin fiber or help swell the keratin fiber.
  • urea and urea derivatives include, for example, urea and urea derivatives, guanidine and its derivatives, arginine and its derivatives, water glass, imidazole and its derivatives, histidine and its derivatives, benzyl alcohol, glycerol, glycol and glycol ethers, propylene glycol and propylene glycol ethers, for example propylene glycol monoethyl ether, carbonates, hydrocarbonates gene carbonates, diols and triols, and in particular 1,2-diols and 1,3-diols such as 1,2-propanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-dodecanediol, 1,3-propanediol , 1,6-hexanediol, 1,5-pentanediol, 1,4-butanediol.
  • short-chain carboxylic acids can additionally support the combination according to the invention.
  • Short-chain carboxylic acids and their derivatives for the purposes of the invention are understood to mean carboxylic acids which can be saturated or unsaturated and / or straight-chain or branched or cyclic and / or aromatic and / or heterocyclic and have a molecular weight of less than 750.
  • the short-chain carboxylic acids in the context of the invention can have one, two, three or more carboxy groups.
  • carboxylic acids having several carboxy groups preference is given to carboxylic acids having several carboxy groups, in particular di- and tricarboxylic acids.
  • the carboxy groups can be present in whole or in part as an ester, acid anhydride, lactone, amide, imidic acid, lactam, lactim, dicarboximide, carbohydrazide, hydrazone, hydroxam, hydroxime, amidine, amidoxime, nitrile, phosphonic or phosphate ester.
  • the carboxylic acids according to the invention can of course be substituted along the carbon chain or the ring structure.
  • the substituents of the carboxylic acids according to the invention include, for example, C1-C8-alkyl, C2-C8-alkenyl, aryl, aralkyl and aralkenyl, hydroxymethyl, C2-C8-hydroxyalkyl, C2-C8-hydroxyalkenyl, Aminomethyl, C2-C8 aminoalkyl, cyano, formyl, oxo, thioxo, hydroxy, mercapto, amino, carboxy or imino groups.
  • Preferred substituents are Cl-C8-alkyl, hydroxymethyl, hydroxy, amino and carboxy groups. Substituents in the ⁇ position are particularly preferred.
  • substituents are hydroxyl, alkoxy and amino groups, it being possible for the amino function to be further substituted by alkyl, aryl, aralkyl and / or alkenyl radicals.
  • preferred carboxylic acid derivatives are the phosphonic and phosphate esters.
  • carboxylic acids are formic acid, acetic acid, propionic acid, butyric acid, isobutyric acid, valeric acid, isovaleric acid, pivalic acid, oxalic acid, malonic acid, succinic acid, glutaric acid, glyceric acid, Glyoxylic acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, propiolic acid, crotonic acid, isocrotonic acid, elaidic acid, maleic acid, fumaric acid, muconic acid, citraconic acid, mesaconic acid, camphoric acid, benzoic acid, o, m, p-phthalic acid, naphthoic acid, hydrolic acid, toluic acid, toluic acid, toluic acid, hydrate acid, Cinnamic acid, isonicotinic acid, nicotinic acid, bicarbamic acid, 4,4'-dicyan
  • n a number from 4 to 12 and one of the two groups X and Y for a COOH group and the other for hydrogen or a methyl or Ethyl radical
  • dicarboxylic acids of the general formula (NI) which additionally carry 1 to 3 methyl or ethyl substituents on the cyclohexene ring
  • German patent specification 22 50 055 discloses the use of these dicarboxylic acids in liquid soap compositions.
  • deodorising agents are known which contain zinc or magnesium salts of these dicarboxylic acids.
  • 35 03 618 means for washing and rinsing the hair are known from the German Offenlegungsschrift, in which by adding this Dicarboxylic acids a noticeably improved hair cosmetic effect of the water-soluble ionic polymers contained in the agent is obtained.
  • German published patent application 197 54 053 agents for hair treatment are known which have nourishing effects.
  • the dicarboxylic acids of the formula (N-I) can be prepared, for example, by reacting polyunsaturated dicarboxylic acids with unsaturated monocarboxylic acids in the form of a Diels-Alder cyclization ring.
  • a polyunsaturated fatty acid is usually used as the dicarboxylic acid component.
  • the linoleic acid accessible from natural fats and oils is preferred.
  • Acrylic acid but also e.g. Methacrylic acid and crotonic acid preferred.
  • Diels-Alder reactions usually produce mixtures of isomers in which one component is present in excess. According to the invention, these isomer mixtures can be used just like the pure compounds.
  • those dicarboxylic acids which differ from the compounds of the formula (NI) by 1 to 3 methyl or ethyl substituents on the cyclohexyl ring or formally from these compounds by addition of one molecule of water can also be used according to the invention to form the double formation of the cyclohexene ring.
  • the dicarboxylic acid (mixture) which results from the reaction of linoleic acid with acrylic acid has proven to be particularly effective according to the invention. It is a mixture of 5- and 6-carboxy-4-hexyl-2-cyclohexen-l-octanoic acid.
  • Such compounds are commercially available under the designations Westvaco Diacid 1550 Westvaco Diacid ® ® 1595 (manufacturer: Westvaco).
  • hydroxycarboxylic acids and in this case in particular the dihydroxy, trihydroxy and polyhydroxycarboxylic acids and also the dihydroxy, trihydroxy and polyhydroxydi, tri and polycarboxylic acids together with the active ingredient (A).
  • the hydroxycarboxylic acid esters and the mixtures of hydroxycarboxylic acids and their esters as well as polymeric hydroxycarboxylic acids and their esters can be particularly preferred.
  • Preferred hydroxycarboxylic acid esters are, for example, full esters of glycolic acid, lactic acid, malic acid, tartaric acid or citric acid.
  • hydroxycarboxylic acid esters are esters of ⁇ -hydroxypropionic acid, tartronic acid, D-gluconic acid,. sugar acid, mucic acid or glucuronic acid.
  • Suitable alcohol components of these esters are primary, linear or branched aliphatic alcohols with 8-22 C atoms, for example fatty alcohols or synthetic fatty alcohols.
  • the esters of C12-C15 fatty alcohols are particularly preferred.
  • Esters of this type are commercially available, eg under the trademark Cosmacol® ® EniChem, Augusta Industriale.
  • Particularly preferred polyhydroxy polycarboxylic acids are polylactic acid and poly-tartaric acid and their esters.
  • a particularly diverse and interesting group of cosmetic active ingredients are polyhydroxy compounds.
  • Polyhydroxy compounds as an active ingredient with the other components according to the invention can therefore be particularly preferred.
  • Polyhydroxy compounds in the sense of the invention are understood to mean all substances which have the definition in Römpp's Lexikon der Chemie, Version 2.0 of the CD-ROM edition from 1999, Verlag Georg Thieme, meet. Accordingly, polyhydroxy compounds are understood to mean organic compounds with at least two hydroxy groups. For the purposes of the present invention, this includes in particular:
  • Polyols with at least two hydroxy groups and with a carbon chain of 2 to 30 carbon atoms such as trimethylolpropane
  • monosaccharides with 3 to 8 carbon atoms such as, for example, triosen, tefrosen, pentoses, hexoses, heptoses and octoses, these also being in the form of aldoses, ketoses and / or lactoses and protected by customary -OH known in the literature - and -NH - protective groups, such as, for example, the triflate group, the trimethylsilyl group or acyl groups, and furthermore in the form of the methyl ether and as a phosphate ester,
  • oligosaccharides with up to 50 monomer units these also in the form of aldoses, ketoses and / or lactoses and protected by customary OH and NH protecting groups known in the literature, such as the triflate group, the trimethylsilyl group or acyl groups as well as in the form of the methyl ether and as a phosphate ester.
  • Very particularly preferred polyols of the present invention are polyols having 2 to 12 carbon atoms in the molecular structure. These polyols can be straight-chain, branched, cyclic and or unsaturated. The hydroxy groups are very particularly preferably adjacent at the end or separated from one another by the rest of the chain.
  • polystyrene resin examples include polyethylene glycol up to a molecular weight of up to 1000 daltons, neopentyl glycol, partial glycerol ether with a molecular weight of up to 1000 daltons, 1,2-propanediol, 1,3-propanediol, glycerol, 1,2-butanediol , 1,3-butanediol, 1,4-butanediol, 1,2,3-butanetriol, 1,2,4-butanetriol, pentanediols, for example 1,2-pentanediol, 1,5-pentanediol, hexanediols, 1,2- Hexanediol, 1,6-hexanediol, 1,2,6-hexanetriol, 1,4-cyclo-hexanediol, 1,2-cyclo-hexanediol, heptane
  • Sorbitol, inositol, mannitol, tetrites, pentites, hexites, threitols, erythritol, adonites, arabitol, xylitol, dulcitol, erythrose, threose, arabinose, ribose, xylose, lyxose, glucose, galactose, mannose are further examples of the polyols according to the invention.
  • polyols (B) are in the compositions in concentrations of from 0.01% by weight to 20% by weight, preferably from 0.05% by weight to 15% by weight and very particularly preferably in amounts of 0, 1% by weight contain up to 10% by weight.
  • non-ionic polymers such as, for example, vinyl pyrrolidone-vinyl acrylate copolymers, polyvinyl pyrrolidone and vinyl pyrrolidone / vinyl acetate copolymers and polysiloxanes,
  • - Thickeners such as agar agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, for.
  • B. bentonite or fully synthetic hydrocolloids such.
  • hair-conditioning compounds such as phospholipids, for example soy lecithin, egg lecithin and cephalins, and silicone oils,
  • Solvents and intermediates such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerin and diethylene glycol,
  • Fatty alcohols in particular linear and / or saturated fatty alcohols with 8 to 30 carbon atoms,
  • paraffin oils such as paraffin oils, vegetable oils, e.g. B. sunflower oil, orange oil, almond oil, wheat germ oil and peach seed oil as well Phospholipids, for example soy lecithin, egg lecithin and cephalins,
  • anti-dandruff agents such as piroctone olamine, zinc omadine and climbazol
  • - opacifiers such as latex, styrene / PVP and styrene / acrylamide copolymers
  • Pearlescent agents such as ethylene glycol mono- and distearate and PEG-3 distearate,
  • Propellants such as propane-butane mixtures, N 2 O, dimethyl ether, CO 2 and air,
  • the cosmetic compositions are in the form of solid or powdered shaped bodies.
  • the molded body according to the invention also contains at least one dissolution accelerator.
  • dissolution accelerator encompasses gas-developing components, pre-formed and enclosed gases, disintegrants and mixtures thereof.
  • dissolution accelerator, mold detonating agent, disintegrating agent or disintegrating agent is to be understood as meaning substances which are added to tablets in order to accelerate their disintegration when brought into contact with water or other solvents. Overviews can be found, for example, in J.Pharm.Sci. 61 (1972), Römpp Chemilexikon, 9th edition, volume 6, p.
  • gas-developing components are used as dissolution accelerators. Upon contact with water, these components react with one another to form gases in situ, which generate a pressure in the tablet which causes the tablet to disintegrate into smaller particles.
  • suitable acids Mono-, di- or trivalent acids with a pK a value of 1.0 to 6.9 are preferred.
  • Preferred acids are citric acid, malic acid, maleic acid, malonic acid, itaconic acid, tartaric acid, oxalic acid, glutaric acid, glutamic acid, lactic acid, fumaric acid, glycolic acid and mixtures thereof.
  • Citric acid is particularly preferred.
  • citric acid in particle form, the particles having a diameter below 100 ⁇ m, in particular less than 700 ⁇ m, very particularly preferably less than 400 ⁇ m.
  • suitable acids are the homopolymers or copolymers of acrylic acid, maleic acid, methacrylic acid or itaconic acid with a molecular weight of 2,000 to 200,000. Homopolymers of acrylic acid and copolymers of acrylic acid and maleic acid are particularly preferred.
  • Preferred bases according to the invention are alkali metal silicates, carbonates, hydrogen carbonates and mixtures thereof. Metasilicates, bicarbonates and carbonates are particularly preferred, bicarbonates are very particularly preferred.
  • Sodium or potassium salts of the above bases are particularly preferred.
  • These gas-generating components are preferably contained in the dyeing moldings according to the invention in an amount of at least 10% by weight, in particular at least 20% by weight.
  • the gas is pre-formed or enclosed, so that when the dissolution of the molded body begins, the gas development begins and the further dissolution accelerates.
  • suitable gases are air, carbon dioxide, N 2 O, oxygen and / or other non-toxic, non-combustible gases.
  • disintegration aids are incorporated into the shaped bodies as dissolution accelerators in order to shorten the disintegration times.
  • Swelling disintegration aids are, for example, synthetic polymers such as polyvinylpyrrolidone (PVP) or natural polymers or modified natural products such as cellulose and starch and their derivatives, alginates or casein derivatives.
  • PVP polyvinylpyrrolidone
  • Disintegrants based on cellulose are used as preferred disintegrants in the context of the present invention, so that preferred molded bodies such a disintegrant based on cellulose in amounts of 0.5 to 50% by weight, preferably 3 to 30% by weight, based on the total molded body contain.
  • Pure cellulose has the formal gross composition (C 6 H ⁇ o ⁇ 5) n and, formally speaking, is a ß-1,4-polyacetal of cellobiose, which in turn is made up of two molecules of glucose.
  • Suitable celluloses consist of approximately 500 to 5000 glucose units and consequently have average molecular weights of 50,000 to 500,000.
  • Cellulose-based disintegrants which can be used in the context of the present invention are also cellulose derivatives which can be obtained from cellulose by polymer-analogous reactions.
  • Such chemically modified celluloses include, for example, products from esterifications or etherifications in which hydroxy hydrogen atoms have been substituted.
  • celluloses in which the hydroxyl groups have been replaced by functional groups which are not bound via an oxygen atom can also be used as cellulose derivatives.
  • the group of cellulose derivatives includes, for example, alkali celluloses, carboxymethyl cellulose (CMC), cellulose esters and ethers and aminocelluloses.
  • the cellulose derivatives mentioned are preferably not used as the only cellulose-based disintegrant, but are used in a mixture with cellulose.
  • the content of cellulose derivatives in these mixtures is preferably below 50% by weight, particularly preferably below 20% by weight, based on the cellulose-based disintegrant. Pure cellulose which is free of cellulose derivatives is particularly preferably used as the cellulose-based disintegrant.
  • the cellulose used as disintegration aid cannot be used in finely divided form, but can be converted into a coarser form, for example granulated or compacted, before being added to the premixes to be treated.
  • the particle sizes of such disintegrants are usually above 200 ⁇ m, preferably at least 90% by weight between 300 and 1600 ⁇ m and in particular at least 90% by weight between 400 and 1200 ⁇ m.
  • the disintegration auxiliaries according to the invention are available commercially for example under the name of Arbocel ® from Rettenmaier.
  • a preferred disintegration aid is, for example, Arbocel ® TF-30-HG.
  • Microcrystalline cellulose is preferably used as a cellulose-based disintegrant or as a component of this component.
  • This microcrystalline cellulose is obtained by partial hydrolysis of celluloses under conditions which only attack and completely dissolve the amorphous areas (approx. 30% of the total cellulose mass) of the celluloses, but leave the crystalline areas (approx. 70%) undamaged.
  • a Subsequent disaggregation of the microfine celluloses resulting from the hydrolysis yields the microcrystalline celluloses which have primary particle sizes of approximately 5 ⁇ m and can be compacted, for example, into granules with an average particle size of 200 ⁇ m.
  • Suitable microcrystalline cellulose is available commercially for example under the trade name Avicel ®.
  • disintegrants that may be present within the meaning of the invention, such as Kollidon, alginic acid and their alkali salts, amorphous or also partially crystalline layered silicates (bentonites), polyacrylates, polyethylene glycols are, for example, the publications WO 98/40462 (Rettenmaier), WO 98/55583 and WO 98/55590 (Unilever) and WO 98/40463, DE 19709991 and DE 19710254 (Henkel). Reference is expressly made to the teaching of these writings.
  • the disintegrants obtainable by the process according to the invention can be present in the molded body in a macroscopically freighted manner, homogeneously distributed, but from a microscopic point of view they form zones of increased concentration due to the production process.
  • the accelerated dissolution of the molded body can also be achieved according to the invention by pre-granulating the other components of the molded body.
  • the shaped bodies according to the invention in addition to the release accelerator, they contain a mixture of starch and at least one saccharide.
  • the use of disaccharides according to this embodiment is preferred.
  • Said mixture is preferably in a weight ratio of starch and the saccharides used from 10: 1 to 1:10, particularly preferably from 1: 1 to 1:10, very particularly preferably from 1: 4 to 1: 7 in the molded body.
  • the disaccharides used are preferably selected from lactose, maltose, sucrose, trehalose, turanose, gentiobiose, melibiose and cellobiose. Lactose, maltose and sucrose are particularly preferably used, and lactose is very particularly preferably used in the shaped articles according to the invention.
  • the starch-disaccharide mixture is contained in the molded body in an amount of 5 to 60% by weight, preferably 20 to 40% by weight, based on the mass of the entire molded body.
  • Another essential component of the molded body according to the invention can be builders.
  • Typical examples of builders which are suitable as an optional component are zeolites, water glasses, phyllosilicates, phosphates and polycarboxylates.
  • the fine crystalline, synthetic and bound water-containing zeolite which is frequently used as a detergent builder is preferably zeolite A and / or P.
  • zeolite P for example, zeolite MAP (R) (commercial product from Crosfield) is particularly preferred.
  • zeolite X and mixtures of A, X and / or P and Y are also suitable.
  • zeolite A cocrystallized sodium / potassium aluminum silicate
  • VEGOBOND AX ® commercial product from Condea Augusta SpA
  • the zeolite can be used as a spray-dried powder or as an undried stabilized suspension that is still moist from its production.
  • the zeolite in the event that the zeolite is used as a suspension, it can contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3% by weight, based on zeolite, of ethoxylated C 12 -C 8 fatty alcohols with 2 to 5 ethylene oxide groups , C 12 -C 14 fatty alcohols with 4 to 5 ethylene oxide groups or ethoxylated isotridecanols.
  • Suitable zeolites have an average particle size of less than 10 ⁇ m (volume distribution; measurement method: Coulter Counter). and preferably contain 18 to 22 wt .-%, in particular 20 to 22 wt .-% of bound water.
  • Suitable substitutes or partial substitutes for phosphates and zeolites are crystalline, tikfb '-shaped sodium silicates of general formula NaMSi x ⁇ 2X + RYH 2 O, where M is sodium or hydrogen, x is a number from 1.9 to 4 and y is a number from 0 to Is 20 and preferred values for x are 2, 3 or 4.
  • Such crystalline layered silicates are described, for example, in European patent application EP 0164514 AI.
  • Preferred crystalline layered silicates of the formula given are those in which M represents sodium and x assumes the values 2 or 3.
  • both ß and ⁇ -sodium disilicate Na 2 Si 2 O 5 -yH 2 O is also preferred, ⁇ -sodium disilicate being obtainable, for example, by the process described in international patent application WO 91/08171.
  • Further suitable layered silicates are known, for example, from patent applications DE 2334899 AI, EP 0026529 AI and DE 3526405 AI. Their usability is not limited to a special composition or structural formula. However, smectites, in particular bentonites, are preferred here. Suitable layered silicates, which belong to the group of water-swellable smectites, are, for example, those of the general formulas
  • the layered silicates can also contain hydrogen, alkali, alkaline earth ions, in particular Na + and Ca 2+ .
  • the amount of water of hydration is usually in the range from 8 to 20% by weight and depends on the swelling condition or the type of processing.
  • Usable layered silicates are known for example from US 3,966,629, US 4,062,647, EP 0026529 AI and EP 0028432 AI.
  • Layered silicates are preferably used which are largely free of calcium ions and strongly coloring iron ions due to an alkali treatment.
  • the preferred builder substances also include amorphous sodium silicates with a module Na 2 O: SiO 2 from 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2, 6, which are delayed release.
  • the delay in dissolution compared to conventional amorphous sodium silicates can have been caused in various ways, for example by surface treatment, compounding, compaction / compression or by overdrying.
  • the term “amo ⁇ h” is also understood to mean “roentgenamo ⁇ h”.
  • silicates are not sharp in X-ray diffraction experiments X-ray reflections, as are typical for crystalline substances, provide at most one or more maxima of the pleased X-rays, which have a width of several degree units of the diffraction angle.
  • it can very well lead to particularly good builder properties if the silicate particles deliver washed-out or even sharp diffraction maxima in electron diffraction experiments.
  • This is to be integrated in such a way that the products have microcrystalline areas of size 10 to a few hundred nm, values up to max. 50 nm and in particular up to max. 20 nm are preferred.
  • Such so-called X-ray silicates which also have a delay in dissolution compared to conventional water glasses, are described, for example, in German patent application DE 4400024 AI.
  • Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and over-dried x-ray silicates.
  • the generally known phosphates can also be used as builder substances, provided that such use should not be avoided for ecological reasons.
  • the sodium salts of orthophosphates, pyrophosphates and in particular tripolyphosphates are particularly suitable. Their content is generally not more than 25% by weight, preferably not more than 20% by weight, in each case based on the finished composition. In some cases it has been shown that tripolyphosphates in particular, even in small amounts up to a maximum of 10% by weight, based on the finished agent, in combination with other builder substances lead to a synergistic improvement in the secondary washing ability.
  • Usable organic builders that come into question as co-builders are, for example, the polycarboxylic acids that can be used in the form of their sodium salts, such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids, aminocarboxylic acids, nitrilotriacetic acid (NTA), provided that such use is used for ecological reasons is not objectionable, and mixtures of these.
  • Preferred salts are the salts of polycarboxylic acids such as citric acid, adipic acid, succinic acid, glutaric acid, tartaric acid, sugar acids and mixtures of these. The acids themselves can also be used.
  • the effect typically also has the property of an acidifying component and thus also serves to set a lower and milder pH of detergents or cleaning agents.
  • Citric acid, succinic acid, glutaric acid, adipic acid, gluconic acid and any mixtures thereof can be mentioned in particular.
  • dextrins for example oligomers or polymers of carbohydrates, which can be obtained by partial hydrolysis of starches.
  • the hydrolysis can be carried out by customary, for example acid or enzyme-catalyzed, processes. It is preferably hydrolysis products with average molecular weights in. Range from 400 to 500,000.
  • DE dextrose equivalent
  • Both maltodextrins with a DE between 3 and 20 and dry glucose sirape with a DE between 20 and 37 as well as so-called yellow dextrins and white dextrins with higher molar masses in the range from 2,000 to 30,000 can be used.
  • a preferred dextrin is described in British patent application GB 9419091 A1 ,
  • the oxidized derivatives of such dextrins are their reaction products with oxidizing agents which are capable of oxidizing at least one alcohol function of the saccharide ring to the carboxylic acid function.
  • Such oxidized dextrins and processes for their preparation are known, for example, from European patent applications EP 0232202 AI, EP 0427349 AI, EP 0472042 AI and EP 0542496 AI as well as international patent applications WO 92/18542, WO 93/08251, WO 93/16110, WO 94 / 28030, WO 95/07303, WO 95/12619 and WO 95/20608 are known.
  • An oxidized oligosaccharide according to German patent application DE 19600018 AI is also suitable.
  • a product oxidized at C 6 of the saccharide ring can be particularly advantageous.
  • Suitable cobuilders are oxydisuccinates and other derivatives of disuccinates, preferably ethylenediamine disuccinate.
  • glycerol disuccinates and glycerol trisuccinates such as those are particularly preferred
  • Suitable amounts are 3 to 15% by weight in zeolite-containing and / or silicate-containing formulations.
  • organic cobuilders are, for example, acetylated hydroxycarboxylic acids or their salts, which may also be in lactone form and which contain at least 4 carbon atoms and at least one hydroxy group and a maximum of two acid groups.
  • Such cobuilders are described, for example, in international patent application WO 95/20029.
  • Suitable polymeric polycarboxylates are, for example, the sodium salts of polyacrylic acid or polymethacrylic acid, for example those with a relative molecular weight of 800 to 150,000 (based on acid and measured in each case against polystyrene sulfonic acid).
  • Suitable copolymeric polycarboxylates are, in particular, those of acrylic acid with methacrylic acid and of acrylic acid or methacrylic acid with maleic acid. Copolymers of acrylic acid with maleic acid which contain 50 to 90% by weight of acrylic acid and 50 to 10% by weight of maleic acid have proven to be particularly suitable.
  • the relative molecular weight, based on free acids, is generally 5,000 to 200,000, preferably 10,000 to 120,000 and in particular 50,000 to 100,000 (measured in each case against polystyrene sulfonic acid).
  • the (co) polymeric polycarboxylates can either be in the form of a powder or be used as an aqueous solution, 20 to 55% by weight aqueous solutions being preferred.
  • Granular polymers are usually subsequently mixed into one or more basic granules.
  • biodegradable polymers composed of more than two different monomer units, for example those which, according to DE 4300772 A1, as monomers salts of acrylic acid and maleic acid and vinyl alcohol or vinyl alcohol derivatives or according to DE 4221381 C2 as monomer salts Acrylic acid and 2-alkylallylsulfonic acid as well as sugar derivatives.
  • Further preferred copolymers are those which are described in German patent applications DE 4303320 AI and DE 4417734 AI and which preferably have acrolein and acrylic acid / acrylic acid salts or acrolein and vinyl acetate as monomers.
  • polyacetals which can be obtained by reacting dialdehydes with polyolcarboxylic acids which have 5 to 7 carbon atoms and at least 3 hydroxyl groups, for example as described in European patent application EP 0280223 A1.
  • Preferred polyacetals are obtained from dialdehydes such as glyoxal, glutaraldehyde, terephthalaldehyde and mixtures thereof and from polyol carboxylic acids such as gluconic acid and / or glucoheptonic acid.
  • the final preparations of the shaped bodies can also contain inorganic salts as fillers or fillers, such as sodium sulfate, which is preferably present in amounts of 0 to 10, in particular 1 to 5% by weight, based on the composition.
  • inorganic salts such as sodium sulfate, which is preferably present in amounts of 0 to 10, in particular 1 to 5% by weight, based on the composition.
  • the consumer may like the coloring agent according to the invention with a stimulant such as e.g. Connect confectionery.
  • a stimulant such as e.g. Connect confectionery.
  • this association particularly in children, means that oral intake or swallowing of the molded body cannot be ruled out.
  • the shaped articles according to the invention therefore contain a bitter substance in order to prevent swallowing or accidental ingestion.
  • Bitter substances which are soluble in water at 20 ° C. to at least 5 g 1 are preferred.
  • the ionogenic bitter substances have proven to be superior to the nonionic ones.
  • Ionogenic bitter substances preferably consisting of more organic cation (s) and organic anion (s) are therefore preferred for the preparations according to the invention.
  • Quaternary ammonium compounds which contain an aromatic group both in the cation and in the anion are particularly suitable as bitter substances.
  • One such compound is commercially available for example under the trademark Bifrex ® and with indigenous stin ® available benzyldiethyl ((2,6-Xylylcarbamoyl) methyl) ammonium benzoate. This compound is also known as Denatonium Benzoate.
  • the bitter substance is contained in the moldings according to the invention in amounts of 0.0005 to 0.1% by weight, based on the moldings. Quantities of 0.001 to 0.05% by weight are particularly preferred.
  • these preparations can in principle contain all further components known to those skilled in the art for such cosmetic products.
  • auxiliaries and additives are, for example, nonionic polymers such as, for example, vinylpyrrolidone-inyl acrylate copolymers, polyvinylpyrrolidone and vinylpyrrolidone / vinyl acetate copolymers and polysiloxanes,
  • - Thickeners such as agar agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, for.
  • B. bentonite or fully synthetic hydrocolloids such.
  • hair-conditioning compounds such as phospholipids, for example soy lecithin, egg lecithin and cephalins, and silicone oils,
  • Solvents and intermediates such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerin and diethylene glycol, symmetrical and asymmetrical, linear and branched dialkyl ethers with a total of between 12 to 36 carbon atoms, in particular 12 to 24 carbon atoms, such as, for example, di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, di-n- undecyl ether and di-n-dodecyl ether, n-hexyl-n-octyl ether, n-octyl-n-decyl ether, n-decyl-n-undecyl ether, n-undecyl-n-dodecyl ether and n-hexyl-n-undecyl ether as well as di- tert-butyl ether,
  • active ingredients that improve fiber structure in particular mono-, di- and oligosaccharides, such as, for example, glucose, galactose, fractose, fructose and lactose,
  • paraffin oils such as paraffin oils, vegetable oils, e.g. B. sunflower oil, orange oil, almond oil, wheat germ oil and peach seed oil as well
  • Phospholipids for example soy lecithin, egg lecithin and cephalins,
  • quaternized amines such as methyl 1-alkylamidoethyl-2-alkylimidazolinium methosulfate,
  • Anti-dandruff agents such as piroctone olamine, zinc omadine and climbazal,
  • Complexing agents such as EDTA, NTA, ⁇ -alaninediacetic acid and phosphonic acids, swelling and penetration substances such as primary, secondary and tertiary phosphates,
  • - opacifiers such as latex, styrene / PVP and styrene / acrylamide copolymers
  • Pearlescent agents such as ethylene glycol mono- and distearate and PEG-3 distearate,
  • thioglycolic acid and its derivatives thiolactic acid, cytamine, thio malic acid and ⁇ -mercaptoethanesulfonic acid
  • Propellants such as propane-butane mixtures, N 2 O, dimethyl ether, CO 2 and air,
  • the shaped bodies according to the invention can take on any geometric shape, such as, for example, concave, convex, biconcave, biconvex, cubic, tefragonal, orthorhombic, cylindrical, spherical, segment-like, disk-shaped, tetrahedral, dodecahedral, octahedral, conical, pyramidal, seven-ellipsoid, five and octagonal-prismatic and rhombohedral shapes.
  • Completely irregular base areas such as arrow or animal shapes, trees, clouds, etc. can also be realized.
  • the design as a table, the bar or bar shape, cubes, cuboids and corresponding spatial elements with flat side surfaces and in particular cylindrical configurations with a circular or oval cross section and molded bodies with spherical geometry are preferred according to the invention. Shaped bodies in the form of spherical geometry are particularly preferred.
  • the cylindrical design covers the form of presentation from the tablet to compact cylinder pieces with a ratio of height to diameter greater than 1. If the basic shaped body has corners and edges, these are preferably rounded. As an additional optical differentiation, an embodiment with rounded corners and chamfered (“chamfered”) edges is preferred.
  • the portioned compacts can each be designed as separate individual elements that correspond to the predetermined dosage of the cosmetic active ingredients.
  • Training the portioned compacts as tablets in cylindrical or cuboid form can be expedient, a diameter / height ratio in the range from about 0.5: 2 to 2: 0.5 being preferred.
  • Commercial hydraulic presses, eccentric presses or rotary presses are suitable devices, in particular for the production of such compacts.
  • the preferred spatial shape of the molded bodies according to the invention has a rectangular base area, the height of the molded bodies being smaller than the smaller rectangular side of the base area. Rounded corners are preferred with this offer.
  • Another preferred molded body that can be produced has a plate-like or plate-like structure with alternately thick long and thin short segments, so that individual segments of this "bar" at the predetermined breaking points, which represent the short thin segments, are broken off and portioned in this way can be used.
  • This principle of the "bar-shaped" shaped body can also be realized in other geometric shapes, for example vertically standing triangles, which are connected to one another only on one of their sides along the side.
  • the shaped bodies according to the invention contain at least two cosmetic active ingredients, it can be advantageous in a further embodiment not to address the various components exclusively to form a uniform tablet.
  • tablets are obtained with tableting which have several layers, that is to say at least two layers. It is also possible for these different layers to have different dissolution rates. This can result in advantageous application properties of the molded body. If, for example, components are contained in the molded bodies that mutually influence each other negatively, it is possible to integrate one component in the more rapidly soluble layer and to incorporate the other component in a more slowly soluble layer, so that the components are not already in the process of dissolving react with each other.
  • the layer structure of the molded body can take place in a stack-like manner, with the inner layer (s) already loosening at the edges of the molded body when the outer layers have not yet been completely removed.
  • the stack axis can be arranged as desired to the tablet axis. In the case of a cylindrical tablet, for example, the stacking axis can be parallel or perpendicular to the height of the cylinder.
  • the inner layer (s) is completely covered by the layer (s) lying further outwards, which prevents the premature dissolution of components of the inner layer (s). en) leads.
  • Shaped bodies in which the layers are coated with the different active substances are preferred. For example, let a layer (A) be completely encased by layer (B) and this in turn completely encased by layer (C). Shaped bodies may also be preferred, in which e.g. the layer (C) is completely encased by the layer (B) and this in turn is completely encased by the layer (A).
  • the bodies to be coated can, for example, be sprayed with aqueous solutions or emulsions, or else they can be coated using the process of melt coating.
  • the (trough) shaped bodies produced according to the invention can be provided with a coating in whole or in part. Processes in which there is an aftertreatment in the application of a coating layer to the molded body surface (s) in which the filled cavity (s) are located or in the application of a coating layer to the entire molded body are preferred according to the invention. After molding, the molded bodies have a high stability. The breaking strength of cylindrical shaped bodies can be determined via the measured variable of the diamefral breaking load. This can be determined according to
  • ⁇ stands for diametral fracture stress (DFS) in Pa
  • P is the force in N that leads to the pressure exerted on the molded body, which causes the molded body to break
  • D is the molded body diameter in meters and t the height of the molded body.
  • the molded articles of the present invention preferably have a density of 0.3 g / cm 3 to 2.0 g / cm 3 , in particular of 0.5 g / cm 3 to 1.1 g / cm 3 .
  • the molded body according to the invention can consist of a molded body, which is described per se by the term “basic molded body” and is produced by known tabletting processes, and which has a depression.
  • the basic molded body is preferably produced first, and the further molded part is applied to or introduced into this basic molded body in a further work step.
  • the resulting product is referred to below with the generic term "Muldenformkö ⁇ er” or "Muldentablette".
  • the basic shaped body can in principle assume all realizable spatial shapes.
  • the spatial shapes already mentioned are particularly preferred.
  • the shape of the trough can be chosen freely, whereby shaped bodies are preferred according to the invention, in which at least one trough is a concave, convex, cubic, tetragonal, orthorhombic, cylindrical, spherical, segment-like, disk-shaped, tefrahedral, dodecahedral, octahedral, conical, pyramidal, ellipsoid , pentagonal, hexagonal and octagonal prismatic and rhombohedral shape.
  • Completely irregular trough shapes such as arrow or animal shapes, trees, clouds, etc. can also be used will be realized.
  • troughs with rounded corners and edges or with rounded corners and touched edges are preferred.
  • the size of the trough in comparison to the entire molded body depends on the intended use of the molded body.
  • the size of the trough can vary depending on whether a smaller or larger amount of active substance is to be contained in the second part.
  • molded bodies are preferred in which the weight ratio of basic molded bodies to trough filling is in the range from 1: 1 to 100: 1, preferably from 2: 1 to 80: 1, particularly preferably from 3: 1 to 50: 1 and in particular from 4 : 1 to 30: 1.
  • Molded bodies are preferred here in which the surface of the pressed-in trough filling makes up I to 25%, preferably 2 to 20%, particularly preferably 3 to 15% and in particular 4 to 10% of the total surface area of the filled basic molded body.
  • the overall molded body has dimensions of 20 x 20 x 40 mm and thus a total surface area of 40 cm 2 , trough fillings are preferred, one
  • the trough filling and the basic molded body are preferably colored to be optically distinguishable.
  • trough tablets have application-technical advantages on the one hand due to the different solubilities of the different areas and on the other hand due to the separate storage of the active substances in the different molded body areas.
  • Molded bodies in which the pressed-in trough filling dissolves more slowly than the basic molded body are preferred according to the invention.
  • the solubility of the well filling can be varied in a targeted manner on the one hand by the incooration of certain constituents, on the other hand, the release of certain ingredients from the well filling can lead to advantages in the application process.
  • the molded articles according to the invention are first produced by dry mixing the constituents, which may be wholly or partially pregranulated, and then providing information, in particular feeding them into tablets, whereby known methods can be used.
  • the premix is compacted in a so-called die between two punches to form a solid compressed product. This process, which is briefly referred to below as tableting, is divided into four sections: metering, compression (elastic deformation), plastic deformation and ejection.
  • the premix is introduced into the die, the filling quantity and thus the weight and the shape of the resulting molded body being determined by the position of the lower punch and the shape of the pressing tool.
  • the constant metering, even at high mold throughputs, is preferably achieved by volumetric metering of the premix.
  • the upper punch touches the premix and lowers further towards the lower punch.
  • the particles of the premix are pressed closer together, the void volume within the filling between the punches continuously decreasing. From a certain position of the upper punch (and thus from a certain pressure on the premix) the plastic deformation begins, in which the particles flow together and the molded body is formed.
  • the premix particles are also crushed and sintering of the premix occurs at even higher pressures.
  • the phase of elastic deformation is shortened more and more, so that the resulting shaped bodies can have more or less large cavities.
  • the finished molded article is pressed out of the die by the lower punch and transported away by subsequent transport devices. At this point in time, only the weight of the molded body is finally determined, since the compacts can still change their shape and size due to physical processes (stretching, crystallographic effects, cooling, etc.).
  • Tableting takes place in commercially available tablet presses, which can in principle be equipped with single or double punches. In the latter case, not only is the upper stamp used to build up pressure, the lower stamp also moves towards the upper stamp during the pressing process, while the upper stamp presses down.
  • eccentric tablet presses are preferably used, in which the stamp or stamps are fastened to an eccentric disc, which in turn is mounted on an axis with a certain rotational speed. The movement of these stamps is comparable to the way a conventional four-stroke engine works.
  • the pressing can take place with one upper and one lower stamp, but several stamps can also be attached to one eccentric disk, the number of die holes being correspondingly increased.
  • the throughputs of eccentric presses vary depending on the type from a few hundred to a maximum of 3000 tablets per hour.
  • rotary tablet presses are selected in which a larger number of matrices are arranged in a circle on a so-called die table.
  • the number of matrices varies between 6 and 55 depending on the model, although larger matrices are also commercially available.
  • Each die on the die table is assigned an upper and lower punch, with the pressing pressure being active only by the upper or lower die.
  • Lower stamp but can also be built up by both stamps.
  • the die table and the stamps move about a common vertical axis, the stamps being brought into the positions for filling, compression, plastic deformation and ejection by means of rail-like curved tracks during the rotation.
  • Rotary presses can also be equipped with two filling shoes to increase the throughput, whereby only a semicircle has to be run through to produce a tablet.
  • several filling shoes are arranged one behind the other without the lightly pressed first layer being ejected before further filling.
  • jacket and dot tablets can also be produced in this way, which have an onion-shell-like structure, the top side of the core or the core layers not being covered in the case of the dot tablets and thus remaining visible.
  • Rotary tablet presses can also be equipped with single or multiple tools so that, for example, an outer circle with 50 and an inner circle with 35 holes can be used simultaneously for pressing. The throughputs of modern rotary tablet presses survey over one million molded articles per hour.
  • Plastic coatings, plastic inserts or plastic stamps are also proven to be advantageous, with the upper and lower punches being designed to be rotatable if possible. In the case of rotating punches, a plastic insert can generally be dispensed with. The stamp surfaces should be electropolished here.
  • Tableting machines suitable within the scope of the present invention are available, for example, from Apparatebau Holzwarth GbR, Asperg, Wilhelm Fette GmbH, Schwarzenbek, Farm Instruments Company, Houston, Texas (USA), Hofer GmbH, Weil, Hörn & Noack Pharrnatechnik GmbH, Worms, EVIA Ve ⁇ ackungssysteme GmbH Viersen, KJLIAN, Cologne, KOMAGE, Kell am See, KORSCH Pressen AG, Berlin, and Romaco GmbH, Worms.
  • Other providers include Dr. Herbert Pete, Vienna (AT), Mapag Maschinenbau AG, Bern (CH), BWI Manesty, Lfve ⁇ ool (GB), I.
  • the process for producing the molded body is not limited to the fact that only a particulate premix is pressed into a molded body. Rather, the method can also be expanded to the effect that multilayer molded bodies are produced in a manner known per se by preparing two or more premixes which are pressed together. In this case, the premix which has been filled in first is gently pre-pressed to get a smooth upper surface which runs parallel to the mold body bottom, and after filling in the second premix is finished to form the finished mold body. In the case of three-layer or multi-layer molded bodies, a further preliminary treatment is carried out after each premix addition, before the molded body is finally finished after adding the last premix.
  • the particulate composition can be pressed into the trough analogously to the production of the basic shaped bodies on tablet presses.
  • a procedure is preferred in which the basic molded body is first produced with a trough, then filled and then re-pressed. This can be done by ejecting the basic molded article from a first tablet press, filling and transporting it into a second tablet press, in which the final addressing takes place.
  • the endve ⁇ ressung can also be done by pressure rollers that roll over the molded body located on a conveyor belt.
  • the shaped bodies according to the invention can be packed after manufacture, the use of certain packaging systems having proven particularly useful since these packaging systems on the one hand increase the storage stability of the ingredients, but on the other hand also significantly improve the long-term adhesion of the trough filling.
  • packaging system always denotes the primary packaging of the molded articles, ie the packaging that is in direct contact with the surface of the molded article on its inside.
  • An optional Secondary packaging is not subject to any requirements, so that all common materials and systems can be used here.
  • Packaging systems which have only a low moisture permeability are preferred according to the invention. In this way, the molded body according to the invention can be used. get a longer period of time, even if, for example, hygroscopic components are used in the molded body.
  • Packaging systems are particularly preferred which have a moisture vapor transmission rate of 0.1 g / m 2 / day to less than 20 g / m 2 / day if the packaging system is stored at 23 ° C. and a relative equilibrium moisture content of 85%.
  • the specified temperature and humidity conditions are the test conditions that are specified in the DL standard 53122, whereby according to DIN 53122 minimal deviations are permitted (23 ⁇ 1 ° C, 85 ⁇ 2% relative humidity).
  • the moisture vapor permeability rate of a given packaging system or material can be determined by further standard methods and is, for example, also in the ASTM standard E-96-53T ("Test for measuring Water Vapor transmission of Materials in Sheet form") and in the TAPPI standard T464 m-45 ("Water Vapor Permeability of Sheet Materials at high temperature an Humidity").
  • the measuring principle of current methods is based on the water absorption of anhydrous calcium chloride, which is stored in a container in the appropriate atmosphere, the container being closed at the top with the material to be tested.
  • the moisture vapor permeability rate can be determined from the surface of the container which is closed with the material to be tested (permeation surface), the weight gain of the calcium chloride and the exposure time
  • the relative equilibrium humidity is 85% at 23 ° C. when measuring the moisture vapor transmission rate in the context of the present invention.
  • the absorption capacity of air for water vapor increases with the temperature up to a respective maximum content, the so-called saturation content, and is given in g / m 3 . For example, 1 m 3 of air at 17 ° is saturated with 14.4 g of water vapor, at a temperature of 11 ° there is saturation with just 10 g of water vapor.
  • the relative equilibrium humidity of 85% at 23 ° C can, for example, be adjusted to +/- 2% RH in laboratory chambers with moisture control depending on the device type. adjust exactly. Even over saturated solutions of certain salts, constant and well-defined relative air humidities form in closed systems at a given temperature, which are based on the phase equilibrium between the partial pressure of the water, saturated solution and soil body.
  • the combinations of molded body and packaging system can of course in turn be packaged in secondary packaging, for example cardboard boxes or trays, with no further requirements having to be made of the secondary packaging.
  • secondary packaging is therefore possible, but not necessary.
  • the packaging system encloses one or more molded bodies. It is preferred according to the invention either to design a shaped body in such a way that it comprises an application unit of the colorant, and to individually pack this shaped body, or the number of shaped bodies in one Packing packaging unit, which in total comprises an application unit.
  • This principle can of course be expanded, so that combinations according to the invention can also contain three, four, five or even more shaped bodies in one packaging unit.
  • two or more molded bodies in a packaging can have different compositions. In this way it is possible to spatially separate certain components from one another, for example in order to avoid stability problems.
  • the packaging system of the combination according to the invention can consist of a wide variety of materials and can take on any external shape.
  • packaging systems are preferred in which the packaging material is light in weight, easy to process and inexpensive and ecologically compatible.
  • the packaging system consists of a sack or pouch made of single-layer or laminated paper and / or plastic film.
  • the shaped bodies can be unsorted, i.e. as a loose fill, be filled into a bag made of the materials mentioned.
  • These packaging systems can then - again preferably sorted - be optionally packed in packaging, which underlines the compact form of the molded article.
  • the sacks or bags made of single-layer or laminated paper or plastic film which are preferably used as a packaging system, can be designed in a wide variety of ways, for example as a blown-up bag without a central seam or as a bag with a central seam, which is sealed by heat (hot fusion), adhesives or adhesive tapes become.
  • Single-layer bag or sack materials are the known papers, which may or may not be impregnated, and plastic films, which may or may not be co-extruded.
  • plastic which can be used as a packaging system in the context of the present invention are given, for example, in Hans Domininghaus "The plastics and their properties", 3rd edition, VDI Verlag, Düsseldorf, 1988, page 193.
  • Figure 111 shown there also provides information on the water vapor permeability of the materials mentioned.
  • wax-coated papers in the form of cardboard boxes as packaging systems for the molded articles in addition to the films or papers mentioned, it is preferred in the context of the present invention if the packaging system does not include boxes made of wax-coated paper.
  • the packaging system is designed to be resealable.
  • a reclosable tube made of glass, plastic or metal as the packaging system.
  • the hair length unit can be defined in the instructions for use as 10 cm hair length per shaped body.
  • the consumer is then able to control the dosage according to his individual hair length in a targeted manner via the number of shaped bodies used.
  • Packaging systems which have a microperforation can also be implemented according to the invention with preference.
  • a second object of the invention is a method for the cosmetic treatment of skin, nails or fibers containing keratin, in which (1) one or more disposable portions (A) according to the invention are removed from the packaging and, if appropriate, dissolved in a medium (M) to form the preparation (AM),
  • the disposable portion (A) according to the invention or optionally the preparation (AM) is applied to the skin, the nails or the keratin fibers and
  • this medium (M) is preferably a cosmetic gel or a cosmetic O / W emulsion or a cosmetic W / O emulsion.
  • the medium (M) has a viscosity of 500-50000 mPa-s, particularly preferably 500-25000 mPa-s, very particularly preferably 500-
  • Rinsing after an exposure time means that preparation (A) or (AM) is applied to the skin, nails or keratin fibers, where it has its intended effect, cleaning, care, etc. and after an exposure time is rinsed off again.
  • the exposure time is usually in the range of a few seconds to 1 hour and depends on the type of cosmetic. However, this is known to the person skilled in the art.
  • a rinse-off hair care product will remain on the keratin fibers or hair after an exposure time in the range from 1 minute (hair rinse) to 45 minutes (intensive hair treatment).
  • the exposure time can be varied by changing the temperature, for example by using a drying hood or a hair dryer. Temperatures between 20 ° C and 45 ° C measured on the skin, nails or keratin fibers can occur. Examples
  • Examples 1 and 2 are each packed in a single-use package, the other examples in quantities of 5.0 g to 30.0 g.
  • the single-use packs can consist of only a single container, or can be connected to one another on a card made of cardboard, plastic, etc. to form several, preferably up to 30, single-use packs lined up together.
  • Gluadin ® W 40 Hydroyzed Wheat Gluten, Cognis, 40% active in water 0.5%
  • Gluadin ® WQ Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein
  • the tablet is dissolved in 50 ml water in a cup or small bowl.
  • a viscous gel forms, which can be applied to the keratin fibers as usual.
  • Luviskol ® K30 5.0% Dehyquart ® L80, Cognis 0.5%
  • the tablet can be foamed into a foam by hand with the addition of water and then applied to the keratin fibers as usual.
  • CETIOL HE ® (Cognis) polyol fatty acid esters Glyceryl PEG -7 3.0
  • EMULGADE ® SE mixture of glyceryl stearate (and) 4.0
  • CETIOL ® LC (Cognis) caprylic / Coco-CaprylHencee / caprate 5.0
  • Viscosity (mPas), Brook.RVF, 23 ° C, Sp.TE, 4 rpm, 150000 with Helipath Rich night care
  • LANETTE ® O Cetylstearyl Alcohol Cetearyl Alcohol 4.0
  • CETIOL ® J 600 Liquid Wax Ester Oleyl Eracate 4.0
  • CETIOL ® V Cognis) Decyl Oleic Acid Decyl Oleate 4.0
  • CETIOL ® OE Di-n-octyl ether Dicaprylyl Ether 4.0 Myritol ® 318 (Cognis) caprylic / Caprylic / Capric 3.5
  • Capric acid triglyceride triglycerides Baysilon ® M 350 (Bayer) Dimethicone 0.5 COPHEROL ® F 1300 RRR- ( ⁇ ) tocopherol tocopherol 1.0 (Cognis) water ad 100 glycerol 86% 3.0 Carbopol ® 981 2% carbomer 10.0 KOH 20% 0.3 LIPOCUTLN ® (Cognis) Aqua (and) lecithin 5.0
  • Viscosity mPas
  • Brookfield RVF 23 ° C
  • Sp.TE 4 rpm
  • Viscosity (mPas), Brookfield RVF, 23 ° C, spindle TE, 4 rpm, with Helipath approx. 200000
  • Zincum ® N 29 (from zinc stearate Zinc Stearate 1.0
  • CETIOL ® OE (Cognis) Di-n-octyl ether Dicaprylyl Ether 3.0
  • Viscosity mPas
  • Brookfield RVF, 23 ° C, spindle TE, 4
  • CETIOL ® OE (Cognis) Di-n-octyl ether Dicaprylyl Ether 5.0
  • EUTANOL ® G (Cognis) 2-octyldodecanol octyldodecanol 17.0 (Guerbet alcohol)
  • CETIOL ® S (Cognis) hydrocarbon dioctylcyclohexane 9.0
  • LANETTE ® O (Cognis) Cetylstearyl Alcohol Cetearyl Alcohol 3.0
  • EUTANOL ® G (Cognis) 2-octyldodecanol octyldodecanol 0.2 (Guerbet alcohol)
  • CETIOL ® J 600 Liquid wax ester Oleyl Eracate 0.1
  • Viscosity mPas
  • Brookfield RVF 23 ° C, spindle 5, 10 rpm 6800
  • CETIOL ® J 600 (Cognis) liquid wax ester oleyl erucate 0.5
  • Viscosity mPas
  • Brookfield RVF 23 ° C
  • spindle 4 10 rpm 6700
  • Emulsifier methosulfates (and)
  • Dehyquart ® L 80 (Cognis) mixture of esterquat dicocoylethyl 0.9 and propylene glycol (approx. Hydroxyethylmonium
  • LANETTE ® O (Cognis) Cetylstearyl Alcohol Cetearyl Alcohol 3.5
  • LANETTE ® O (Cognis) Cetylstearyl Alcohol Cetearyl Alcohol 4.0
  • LANETTE ® O (Cognis) Cetylstearyl Alcohol Cetearyl Alcohol 4.0
  • Viscosity (mPas), Brook.RVF, 23 ° C, spindle 4, 10 rpm 4400
  • CUTLNA ® MD (Cognis) mixture of mono- and glyceryl stearate 5.0 diglycerides of palmitic and stearic acid
  • CETIOL ® V (Cognis) oleic acid decyl ester Decyl Oleate 5.0
  • Viscosity (mPas), Brookfield RFT, 23 ° C, column 4, 10 rpm 6300
  • Viscosity (mPas), Brookfield RVF, 23 a C, spindle 4, 10 rpm 8500
  • Viscosity (mPas), Brookfield RVF, 23 ° C, spindle 4, 10 rpm 3900
  • Viscosity (mPas), Brook.RVF, 23 ° C, spindle 4, 10 rpm 4100

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  • Epidemiology (AREA)
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PCT/EP2004/004870 2003-05-16 2004-05-07 Compositions cosmetiques en emballages pour doses uniques WO2004100901A2 (fr)

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DE10322290 2003-05-16
DE10322290.1 2003-05-16
DE10330247A DE10330247A1 (de) 2003-05-16 2003-07-03 Kosmetische Zusammensetzung in Einmalportionspackungen
DE10330247.6 2003-07-03

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005030017A1 (de) * 2005-06-27 2007-01-04 Beiersdorf Ag Emulsion mit Repellentien
DE102005030015A1 (de) * 2005-06-27 2007-01-11 Beiersdorf Ag Insektenschutzmittel
DE102005030016A1 (de) * 2005-06-27 2007-01-11 Beiersdorf Ag Hautfreundliches Insektenabwehrmittel
DE102005033844A1 (de) * 2005-07-20 2007-02-01 Beiersdorf Ag Insektenabwehrmittel mit Langzeitwirkung

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004062429A1 (de) * 2004-12-20 2006-06-29 Henkel Kgaa Wirkstoffgemische zur Restrukturierung keratinischer Fasern
DE102016217186A1 (de) * 2016-09-09 2018-03-15 Henkel Ag & Co. Kgaa Tensidhaltige Oxidationsmittelzusammensetzungen in Verpackungen aus Sperrschicht-Folien III
DE102016217175A1 (de) * 2016-09-09 2018-03-15 Henkel Ag & Co. Kgaa Tensidhaltige Oxidationsmittelzusammensetzungen in Verpackungen aus Sperrschicht-Folien
GB2561377A (en) * 2017-04-12 2018-10-17 Brown Philip Pack of disposable wipes
DE212019000438U1 (de) * 2018-12-03 2021-08-03 Contripro A.S. Ein biologisch aktives Präparat enthaltendes Kit
CN110025004B (zh) * 2019-05-22 2022-02-11 广西壮族自治区农业科学院 一种马铃薯干米粉及其制备方法
DE102021206380A1 (de) * 2021-06-22 2022-12-22 Beiersdorf Aktiengesellschaft Feste und pulverförmige Formulierungen

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005030017A1 (de) * 2005-06-27 2007-01-04 Beiersdorf Ag Emulsion mit Repellentien
DE102005030015A1 (de) * 2005-06-27 2007-01-11 Beiersdorf Ag Insektenschutzmittel
DE102005030016A1 (de) * 2005-06-27 2007-01-11 Beiersdorf Ag Hautfreundliches Insektenabwehrmittel
DE102005033844A1 (de) * 2005-07-20 2007-02-01 Beiersdorf Ag Insektenabwehrmittel mit Langzeitwirkung

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DE10330247A1 (de) 2004-12-02

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