WO2004069407A1 - Procede de fabrication d'un catalyseur et procede de fabrication d'hydrocarbures et de leurs derives oxygenes utilisant ce procede - Google Patents

Procede de fabrication d'un catalyseur et procede de fabrication d'hydrocarbures et de leurs derives oxygenes utilisant ce procede Download PDF

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Publication number
WO2004069407A1
WO2004069407A1 PCT/RU2003/000568 RU0300568W WO2004069407A1 WO 2004069407 A1 WO2004069407 A1 WO 2004069407A1 RU 0300568 W RU0300568 W RU 0300568W WO 2004069407 A1 WO2004069407 A1 WO 2004069407A1
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WO
WIPO (PCT)
Prior art keywords
fact
paragraphs
different
catalyst
mixture
Prior art date
Application number
PCT/RU2003/000568
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English (en)
Russian (ru)
Inventor
Izabella Shenderovna Itenberg
Valentin Nikolaevich Parmon
Anatoly Gennadyevich Sipatrov
Alexandr Alexandrovich Khasin
Galina Konstantinovna Chermashentseva
Tamara Mihailovna Yuryeva
Original Assignee
Institut Kataliza Imeni G.K. Boreskova Sibirskogo Otdeleniya Rosiiskoi Akademii Nauk
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Institut Kataliza Imeni G.K. Boreskova Sibirskogo Otdeleniya Rosiiskoi Akademii Nauk filed Critical Institut Kataliza Imeni G.K. Boreskova Sibirskogo Otdeleniya Rosiiskoi Akademii Nauk
Priority to AU2003296280A priority Critical patent/AU2003296280A1/en
Publication of WO2004069407A1 publication Critical patent/WO2004069407A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/835—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead

Definitions

  • the low cost is the low-cost active component in the unit of sales, and is also less than 50
  • the task solved by this invention is in the form of a method for the efficient utilization of hydrocarbon emissions and of 30 gas consumption 1.
  • High temperature of the catalytic body not less than 1 ⁇ / (m ⁇ ); 5 4. High gas permeability of the catalytic body - not less than 5 10 "15 m 2 ;
  • catalytically active agent here is taken a part of the phase, including the phase that contains the inactive metal (potassium, is non-ferrous, doesn’t consume iron,
  • the content of the active metal in the well-known condition of the phase must be more than 5 wt. %, preferably, - 8 to 30 wt. %
  • a catalytically active agent may be purchased One of the previously described methods of planting methods ( ⁇ ⁇ réelle 53. 5397806, ⁇ 07 ⁇ 001/04, 03/14/95), ⁇ transaction rings (4960801, ⁇ 07 ⁇ 13 04/00/01 , 09/23/86) or another well-known or original method. It is preferable that the phase of the active metal, 5 processed in the process, has a pre-sized particle size of 6-7 to 9-11 nm.
  • An important property is also the possibility of forming a reliable contact between the parts of a stable agent at the stage
  • sales agent means a phase or
  • the granules that make up the ⁇ , B, ⁇ and D products must be less than 300 cm. It is, however, preferable that they are sized for mixed particles.
  • the thickness of the plate can be up to a millimeter to 1 m;
  • the optimal size is divided from the technological parameters of the method of use and conditions
  • the commercial processing of the body of the catalytic converter can be carried out in one or two stages. For this, it is essential to complete
  • the processing unit was operated in a source of hydrogen or hydrogen.
  • the temperature control unit must be higher than the Amman temperature range (i.e., a range of 0.5 from the absolute melting point), which is an integral part of the
  • the main components of the proposed product range are the high level of activity of the unit for the sale of gas
  • the task is also solved by the method of production of hydrocarbons and / or their oxygen-derived from the synthesis gas, using the above-used catalyst.
  • 10 converters have a size of less than 250 microns.
  • B - bulk metal with a particle size of less than 50 microns.
  • BROWN ⁇ the first basic equipment for copper Cu 2 ( ⁇ ) 2 ⁇ (malachite).
  • a mixture of the B and B powders for the production of the Bulk batch is at a ratio of 3: 2 wt. daley. COMPLETION OF THE COMPUTER DIRECTOR BY USING THE TEST
  • a mixture of products ⁇ and ⁇ is at a ratio of 9:11 wt. Compaction of the mixture of ⁇ and ICS Play and the application of the disk format with a diameter of 15 mm and a height of 6 mm are prevented by working at a pressure of 3000 kG / cm 2 .
  • the industrial processing is carried out in two stages - in the case of a unit with a temperature of 550 ° ⁇ and in a case of a temperature of 650 ° ⁇ .
  • the catalytic converter has the following phase composition: metallic copper + metallic bronze, which is secured by analuminism
  • ⁇ a ⁇ ali ⁇ iches ⁇ ie is ⁇ y ⁇ aniya ⁇ v ⁇ dya ⁇ in ⁇ chn ⁇ m ⁇ ea ⁇ e, ⁇ i s ⁇ s ⁇ ave ⁇ ea ⁇ tsi ⁇ nn ⁇ y mixture S ⁇ 30% ⁇ b., ⁇ 2 60% ⁇ b., ⁇ 10% ⁇ b., A pressure of 0.1 ⁇ i ⁇ Pa ⁇ em ⁇ e ⁇ a ⁇ u ⁇ e and 210 ° C. P ⁇ ⁇ ea ⁇ tsi ⁇ nn ⁇ y mixture ⁇ us ⁇ ayu ⁇ che ⁇ ez ⁇ el ⁇ ⁇ a ⁇ aliza ⁇ a ⁇ rectdite infringement ⁇ a ⁇ rectdite .
  • the body of the catalytic converter is excluded
  • This hydroprocessor is able to be converted in a way to process in the form of a product in the form of an active metal
  • the product also contains particles with a size of less than 150 microns.
  • the catalytic converter has the following phase composition: metallic copper + metallic bronze, which is inhibited by anesthetics
  • the basic parameters of the obtained catalysts are given in Table 1.
  • the catalytic properties of the obtained catalysts are shown in Table 2.
  • this product is a part of an active metal (nickel) and a combined oxide ⁇ - ⁇ . According to the data on the consumption of the amount of active metal (nickel), the oxygen (the contact with the product was a change in weight), the loss of weight is a little more than 32%. Grains that have been produced have a size of less than 150 microns.
  • the processing unit is supplied to one stage - in the case of hydrogen at 5 ° C and a temperature of 650 ° C.
  • the body of the catalyst has the following phase composition: metallic copper + metallic nickel, which is stored in the ignition mixture,
  • the basic parameters of the obtained catalysts are given in Table 1.
  • the catalytic properties of the obtained catalysts are shown in Table 2.
  • the catalytic converter prepares a similar example of 1, but in the form of an attempt to use the product, the amount of salted meat is 90% (90%).
  • a mixture of the B and C powders for the production of the Bulk D products comes in a ratio of 4: 3 wt. daley.
  • the catalytic converter has the following phase composition: copper alloy with tin + metallic copper + metallic, non-alloyed
  • Table 1 The basic parameters of the resulting catalytic conversion are shown in Table 1.
  • Example 5 The catalyst is prepared in a similar manner to Example 1, but in the form of a powder, they use a copper hydroxide solution of Si ( ⁇ ) 2 with a particle size of less than 50 millimeters.
  • a mixture of the B and B powders for the production of the Bulk batch is at a ratio of 25 3: 2 wt. daley.
  • the body of the catalytic converter has the following phase composition: metallic copper + metallic copper, which is secured by anaerobic inflammation 30
  • the basic parameters of the obtained catalysts are given in Table 1.
  • the catalytic properties of the obtained catalysts are shown in Table 2. 6.
  • the body of the catalytic converter has the following phase composition: metallic copper + metallic copper, which is secured by anaerobic inflammation
  • Example 7 The catalyst prepares a similar example to Example 1, but a mixture. Bulk B and ⁇ for the production of the Bulk plant are in a ratio of 2: 1 wt. more, and the mixture of the products ⁇ and the company comes in a ratio of 2: 3 wt. daley. 20 After the thermal treatment, the catalytic converter has the following phase composition: metallic copper + metallic bronze, which is inhibited by ananalysis The basic parameters of the obtained catalysts are given in Table 1. The catalytic properties of the obtained catalysts are shown in Table 2.
  • the catalyst prepares the analogous example 1, but a mixture of the powders and the mixture in the ratio of 1: 2 wt. daley.
  • the basic parameters of the obtained catalysts are given in Table 1.
  • the catalytic properties of the obtained catalysts are shown in Table 2.
  • Example 9 The catalyst provides a similar example to 2, but the body of 30 is a concentrate of commercialization that is free of charge.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)

Abstract

L'invention se rapporte aux catalyseurs de fabrication d'hydrocarbures et notamment de carburants synthétiques liquides, d'oléfines, d'hydrocarbures solides ainsi que de leurs dérivés oxygénés, par exemple, d'alcools à base d'un mélange de CO et d'hydrogène. L'invention permet de fabriquer un catalyseur efficace et de mettre en oeuvre un procédé de fabrication d'hydrocarbures et de leurs composés oxygénés au moyen dudit catalyseur. Le catalyseur est fabriqué à partir de poudres d'un agent à activité catalytique, d'un agent conducteur de chaleur et d'un agent de formation de pores, avec une granulométrie inférieure à 300 micromètres, de la manière suivante: on mélange les poudres de l'agent conducteur de chaleur et de l'agent de formation de pores, on mélange la poudre ainsi obtenue à un agent à activité catalytique, on condense le mélange ainsi obtenu et on confère au corps du catalyseur la forme voulue, puis on effectue le traitement thermique du corps du catalyseur.
PCT/RU2003/000568 2003-02-10 2003-12-19 Procede de fabrication d'un catalyseur et procede de fabrication d'hydrocarbures et de leurs derives oxygenes utilisant ce procede WO2004069407A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003296280A AU2003296280A1 (en) 2003-02-10 2003-12-19 Method for producing a catalyst and method for producing hydrocarbons and the oxygen-containing derivatives thereof using said catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2003103899/04A RU2227067C1 (ru) 2003-02-10 2003-02-10 Способ приготовления катализатора и способ получения углеводородов и их кислородсодержащих производных с его использованием
RU2003103899 2003-02-10

Publications (1)

Publication Number Publication Date
WO2004069407A1 true WO2004069407A1 (fr) 2004-08-19

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PCT/RU2003/000568 WO2004069407A1 (fr) 2003-02-10 2003-12-19 Procede de fabrication d'un catalyseur et procede de fabrication d'hydrocarbures et de leurs derives oxygenes utilisant ce procede

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AU (1) AU2003296280A1 (fr)
RU (1) RU2227067C1 (fr)
WO (1) WO2004069407A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011053192A2 (fr) 2009-10-29 2011-05-05 Limited Liability Company "Infra Technologies" Catalyseur pour la synthèse d'hydrocarbures à partir de co et de h2 et procédé de préparation dudit catalyseur

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2458736C1 (ru) * 2011-05-10 2012-08-20 Учреждение Российской академии наук Институт катализа им. Г.К. Борескова Сибирского отделения РАН Катализатор и способ получения углеводородов из монооксида углерода и водорода (варианты)
CN115845854A (zh) * 2022-11-28 2023-03-28 高潞空气化工产品(上海)能源科技有限公司 一种高导热性耐高温催化剂及其制备方法和用途

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0510770A2 (fr) * 1991-04-23 1992-10-28 Shell Internationale Researchmaatschappij B.V. Procédé pour la fabrication d'hydrocarbures
US5716899A (en) * 1993-10-15 1998-02-10 Corning Incorporated Pore-impregnated body and method of producing same
EP0857513A1 (fr) * 1997-01-30 1998-08-12 AGIP PETROLI S.p.A. Composition catalytique utile dans la réaction de type Fischer Tropsch
US6117814A (en) * 1998-02-10 2000-09-12 Exxon Research And Engineering Co. Titania catalysts their preparation and use in fischer-tropsch synthesis
RU2161067C2 (ru) * 1995-08-04 2000-12-27 Аджип Петроли С.П.А. Способ получения катализатора для конверсии синтез-газа, композиция, катализатор и способ синтеза газа

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0510770A2 (fr) * 1991-04-23 1992-10-28 Shell Internationale Researchmaatschappij B.V. Procédé pour la fabrication d'hydrocarbures
US5716899A (en) * 1993-10-15 1998-02-10 Corning Incorporated Pore-impregnated body and method of producing same
RU2161067C2 (ru) * 1995-08-04 2000-12-27 Аджип Петроли С.П.А. Способ получения катализатора для конверсии синтез-газа, композиция, катализатор и способ синтеза газа
EP0857513A1 (fr) * 1997-01-30 1998-08-12 AGIP PETROLI S.p.A. Composition catalytique utile dans la réaction de type Fischer Tropsch
US6117814A (en) * 1998-02-10 2000-09-12 Exxon Research And Engineering Co. Titania catalysts their preparation and use in fischer-tropsch synthesis

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011053192A2 (fr) 2009-10-29 2011-05-05 Limited Liability Company "Infra Technologies" Catalyseur pour la synthèse d'hydrocarbures à partir de co et de h2 et procédé de préparation dudit catalyseur

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Publication number Publication date
AU2003296280A1 (en) 2004-08-30
RU2227067C1 (ru) 2004-04-20

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