WO2004041785A1 - Procede de preparation de vinylpyridine a partir de picoline sur des zeolites modifies - Google Patents
Procede de preparation de vinylpyridine a partir de picoline sur des zeolites modifies Download PDFInfo
- Publication number
- WO2004041785A1 WO2004041785A1 PCT/IB2002/004653 IB0204653W WO2004041785A1 WO 2004041785 A1 WO2004041785 A1 WO 2004041785A1 IB 0204653 W IB0204653 W IB 0204653W WO 2004041785 A1 WO2004041785 A1 WO 2004041785A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- picoline
- zsm
- vinylpyridine
- catalyst
- modified
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
Definitions
- the main objective of the present invention is to provide a process for the synthesis of vinylpyridines over modified zeolites in a heterogeneous eco-friendly method.
- Another objective ⁇ of the present invention is to provide a process for the preparation of 2-vinylpyridine in high yield and high selectivity.
- the present invention provides an improved process for the preparation of vinylpyridine from corresponding picoline over modified zeolite catalyst in vapour phase which comprises reacting picoline with formaldehyde with a molar ratio of formaldehyde to . picoline in the range of 1:1. to 4:1, at a temperature ranging between 200°
- one of the reactant picoline is selected from 2-picoline and 4-picoline.
- the precursor to modify ZSM-5 catalyst by potassium ion or other elements is varied like KO l Bu, KOH, KF, KNO 3 , K 3 PO 4 and KOAc to improve the yield ,and selectivity of vinylpyridine.
- the calcination temperature of modified zeolite is varied from 400°C to ⁇ 7:0Q?C.'
- the experimental conditions are as explained in Example-15.
- the weight of calcium was 3wt% in ZSM-5 catalyst.
- the liquid product selectivity of 4-vinylpyridine was 83.9% at 37.2% conversion of 4-picoline during i
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/IB2002/004653 WO2004041785A1 (fr) | 2002-11-06 | 2002-11-06 | Procede de preparation de vinylpyridine a partir de picoline sur des zeolites modifies |
EP02779826A EP1565439A1 (fr) | 2002-11-06 | 2002-11-06 | Procede de preparation de vinylpyridine a partir de picoline sur des zeolites modifies |
JP2004549391A JP4545593B2 (ja) | 2002-11-06 | 2002-11-06 | 変性ゼオライト上でピコリンからビニルピリジンを製造する方法 |
AU2002343158A AU2002343158A1 (en) | 2002-11-06 | 2002-11-06 | Process for the preparation of vinylpyridine from picoline over modified zeolites |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/IB2002/004653 WO2004041785A1 (fr) | 2002-11-06 | 2002-11-06 | Procede de preparation de vinylpyridine a partir de picoline sur des zeolites modifies |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004041785A1 true WO2004041785A1 (fr) | 2004-05-21 |
Family
ID=32310070
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2002/004653 WO2004041785A1 (fr) | 2002-11-06 | 2002-11-06 | Procede de preparation de vinylpyridine a partir de picoline sur des zeolites modifies |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1565439A1 (fr) |
JP (1) | JP4545593B2 (fr) |
AU (1) | AU2002343158A1 (fr) |
WO (1) | WO2004041785A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112028817A (zh) * | 2019-12-18 | 2020-12-04 | 上海中西三维药业有限公司 | 一种2-乙烯基吡啶的制备方法 |
CN112108177A (zh) * | 2020-09-11 | 2020-12-22 | 北京弗莱明科技有限公司 | 一种乙烯基氮苯的制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3316929A1 (de) * | 1983-05-09 | 1984-11-15 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von styrol und ethylbenzol aus toluol |
WO2002034720A1 (fr) * | 2000-10-20 | 2002-05-02 | Reilly Industries, Inc. | Procede de preparation d'heterocycles portant des substituants vinyliques |
-
2002
- 2002-11-06 EP EP02779826A patent/EP1565439A1/fr not_active Withdrawn
- 2002-11-06 WO PCT/IB2002/004653 patent/WO2004041785A1/fr active Application Filing
- 2002-11-06 AU AU2002343158A patent/AU2002343158A1/en not_active Abandoned
- 2002-11-06 JP JP2004549391A patent/JP4545593B2/ja not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3316929A1 (de) * | 1983-05-09 | 1984-11-15 | Hoechst Ag, 6230 Frankfurt | Verfahren zur herstellung von styrol und ethylbenzol aus toluol |
WO2002034720A1 (fr) * | 2000-10-20 | 2002-05-02 | Reilly Industries, Inc. | Procede de preparation d'heterocycles portant des substituants vinyliques |
Non-Patent Citations (7)
Title |
---|
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; ARCHIER, D. ET AL: "Lateral-chain methylation of toluene over boron and/or zinc modified cesium-X zeolite", XP002233944, retrieved from STN Database accession no. 123:8888 * |
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KONOVAL'CHIKOV, O. D. ET AL: "Simultaneous production of ethylbenzene and styrene", XP002233942, retrieved from STN Database accession no. 73:110317 * |
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; MOON, S. K. ET AL: "Influence of methanol-decomposition in the side-chain alkylation of toluene with methanol", XP002233945, retrieved from STN Database accession no. 109:210601 * |
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; WU, CHUANCHANG ET AL: "Relationship between the acid-base properties of zeolite surface and the activity of side-chain alkylation of toluene with methanol", XP002233943, retrieved from STN Database accession no. 111:235517 * |
GAODENG XUEXIAO HUAXUE XUEBAO (1989), 10(4), 383-6 * |
HWAHAK KONGHAK (1987), 25(6), 601-6 * |
PROC. INT. ZEOLITE CONF., 9TH (1993), MEETING DATE 1992, VOLUME 2, 525-34. EDITOR(S): VON BALLMOOS, RONALD;HIGGINS, JOHN B.; TREACY, MICHAEL M. J. PUBLISHER: BUTTERWORTH-HEINEMANN, BOSTON, MASS. * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112028817A (zh) * | 2019-12-18 | 2020-12-04 | 上海中西三维药业有限公司 | 一种2-乙烯基吡啶的制备方法 |
CN112028817B (zh) * | 2019-12-18 | 2023-10-03 | 上海中西三维药业有限公司 | 一种2-乙烯基吡啶的制备方法 |
CN112108177A (zh) * | 2020-09-11 | 2020-12-22 | 北京弗莱明科技有限公司 | 一种乙烯基氮苯的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
AU2002343158A1 (en) | 2004-06-07 |
JP4545593B2 (ja) | 2010-09-15 |
EP1565439A1 (fr) | 2005-08-24 |
JP2006515569A (ja) | 2006-06-01 |
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