WO2004037744A1 - 多孔質ハニカム構造体の製造方法、及びハニカム成形体 - Google Patents
多孔質ハニカム構造体の製造方法、及びハニカム成形体 Download PDFInfo
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- WO2004037744A1 WO2004037744A1 PCT/JP2003/013428 JP0313428W WO2004037744A1 WO 2004037744 A1 WO2004037744 A1 WO 2004037744A1 JP 0313428 W JP0313428 W JP 0313428W WO 2004037744 A1 WO2004037744 A1 WO 2004037744A1
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- mass
- alkali metal
- silicon
- porous
- honeycomb
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2068—Other inorganic materials, e.g. ceramics
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0006—Honeycomb structures
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
- C04B38/0615—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances the burned-out substance being a monolitic element having approximately the same dimensions as the final article, e.g. a porous polyurethane sheet or a prepreg obtained by bonding together resin particles
- C04B38/062—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances the burned-out substance being a monolitic element having approximately the same dimensions as the final article, e.g. a porous polyurethane sheet or a prepreg obtained by bonding together resin particles the burned-out substance being formed in situ, e.g. by polymerisation of a prepolymer composition containing ceramic powder
- C04B38/0625—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances the burned-out substance being a monolitic element having approximately the same dimensions as the final article, e.g. a porous polyurethane sheet or a prepreg obtained by bonding together resin particles the burned-out substance being formed in situ, e.g. by polymerisation of a prepolymer composition containing ceramic powder involving a foaming step of the burnable material
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00793—Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24149—Honeycomb-like
Definitions
- the present invention relates to a method for manufacturing a porous honeycomb structure and an 82-cam molded body suitably used as, for example, a dust collection filter, and more particularly, to manufacturing a porous honeycomb structure having a high porosity.
- the present invention relates to a method for manufacturing a porous honeycomb structure, which can effectively prevent a crack from being generated in the porous honeycomb structure or collapse of the porous honeycomb structure due to its own weight, and a honeycomb formed body.
- a porous honeycomb structure made of ceramic with excellent corrosion resistance is used.
- a porous honeycomb structure made of ceramic has been used as a filter for dust collection used in high-temperature, corrosive gas atmospheres such as diesel particulate filter (DPF) that collects particulates discharged from diesel engines. It is preferably used.
- DPF diesel particulate filter
- an inlet end face B and an outlet end face C of a plurality of cells 23 of a porous honeycomb structure 21 are provided. Are alternately sealed by a sealing portion 22.
- the porous honeycomb structure having such a structure when the gas to be treated is introduced into the cell 23 from the end face B on the inlet side, the particulates are trapped in the partition wall 24 and permeate through the porous partition wall 24.
- treated gas G 2 which has flown into the cell 2 3 adjacent to it to be discharged from the outlet-side end face C, it is possible to obtain the treated gas G 2 from which particulate matter to be treated in the gas are separated.
- the porous honeycomb structure having a low pressure loss and a high porosity among the above-described porous 82-cam structures.
- the method for producing the plastic raw material is to knead a cordierite-forming raw material, water, a binder (organic binder such as methylcellose), a pore-forming agent (organic substance such as graphite), and the like to obtain a plasticized plastic raw material (this specification).
- a method for producing a porous honeycomb filter which is formed by molding, drying and firing the same is disclosed in, for example, Japanese Patent Application Laid-Open No. 2002-219913. See). According to such a manufacturing method, since the binder and the pore-forming agent are burned out and pores are formed when the molded body is sintered, it is possible to obtain a high-porosity porous honeycomb structure. it can.
- the present inventor has conducted intensive studies to solve the above-mentioned problems, and as a result, has found that the above object can be achieved by incorporating an alkali metal source into the kneaded clay to be formed, and completed the present invention. I let it. That is, the present invention provides the following method for producing a porous 82 structure and an 82 cam molded body.
- At least a raw material of aggregate particles made of non-oxide ceramic containing silicon and / or metallic silicon, water, an organic binder, a pore former, and an alkali metal source are mixed and kneaded to obtain a clay.
- the kneaded material is formed into a honeycomb shape having a plurality of cells serving as a fluid flow path, and is dried to obtain a honeycomb formed body.
- the honeycomb formed body is calcined to obtain a calcined body.
- the production of a porous honeycomb structure characterized by obtaining a porous honeycomb structure by firing the fired body. Construction method.
- the kneaded material contains the alkali metal source equivalent to 0.01 to 10 parts by mass in terms of alkali metal with respect to 100 parts by mass of the aggregate particle material.
- the aggregate particle material contains at least one component selected from the group consisting of silicon carbide, silicon nitride, and metallic silicon, and the total mass of the components is [1] above, which accounts for 50% by mass or more of the total mass, or
- the aggregate particle material contains at least one component selected from the group consisting of silicon carbide, silicon nitride, and metallic silicon, and the total mass of the components is equal to the amount of the aggregate particle material. [4] above, which accounts for 50% by mass or more of the total mass, or
- Fig. 1 is a schematic diagram showing an example of a dust collection filter using a porous honeycomb structure.
- FIG. 2 is a schematic diagram illustrating a “honeycomb shape” using an example of a porous honeycomb structure.
- FIG. 3 is a schematic diagram illustrating a method for evaluating the strength of the calcined body.
- the present inventor When developing the method for manufacturing a porous honeycomb structure of the present invention, the present inventor first generated cracks in the porous honeycomb structure when firing the formed body, or The reason why the honeycomb structure collapsed by its own weight was examined. As a result, the first reason is that, when firing a molded body, a large amount of binder and pore former burn and generate heat. The second reason is that, in the molded body before firing, the binder contained in the clay becomes a gel, and functions as a reinforcing agent for maintaining the mechanical strength of the molded body.
- a substance that functions as a reinforcing agent even after the binder is burned out is separately added to the kneaded clay to be formed. Specifically, it was decided that the kneaded clay to be formed should contain a metal source.
- the alkali metal source becomes hydroxide when dissolved in the water in the clay, and reacts with silica inevitably present on the surface of the non-oxide ceramic containing silicon to form alkali silicate glass (water glass).
- This alkali silicate glass functions as a reinforcing agent even after the binder is burned out, and can prevent a decrease in the mechanical strength of the molded article (and, consequently, the porous 82-cam structure). Therefore, a large amount of binder and pore former burn and generate heat, so that the temperature of the green body during firing rises rapidly, and even if a large thermal stress occurs, cracks are generated in the porous honeycomb structure. The situation can be effectively prevented. Further, even in a structure having a high porosity after the pore-forming agent has been burned off, it is possible to effectively prevent a situation in which the porous honeycomb structure collapses by its own weight.
- a non-oxide ceramic containing silicon is used.
- the raw material is made by mixing and kneading a raw material of aggregate particles composed of a metal and Z or metallic silicon, water, an organic binder, a pore-forming agent, and an alkali metal source.
- -Aggregate particles are particles that are the main constituents of the porous 82 cam structure (sintered body), and the aggregate particle raw material is the raw material.
- the raw material for aggregate particles in the present invention needs to include a non-oxide ceramic “containing silicon” and / or a metal “silicon” as an essential component.
- the aggregate particles need to contain a silica source capable of forming an alkali silicate glass by reacting with an alkali metal.
- the silica source is present in the form of a surface oxide film of the aggregate particles, and the substance having such a structure is a “containing silicon” non-oxide ceramic or metal “silicon”. This is because.
- metallic silicon is not a ceramic, but may be, for example, a constituent material of a Si—SiC sintered body using silicon carbide and metallic silicon as raw materials for aggregate particles.
- the raw material of the aggregate particles needs to contain non-oxide ceramic containing silicon and / or metallic silicon as essential components.
- silicon carbide, silicon nitride, and metal It is preferable that the material contains at least one component selected from the group consisting of silicon, and that the total weight of the components accounts for 50% by mass or more of the total mass of the aggregate particle material.
- the aggregate particle raw material of the present invention may contain components other than the non-oxide ceramic containing silicon and metallic silicon, and the content thereof may be 5 to the total mass of the aggregate particle raw material. It is preferably less than 0% by mass.
- the organic binder is an additive that becomes a gel in the molded body (clay) before firing, and functions as a reinforcing agent for maintaining the mechanical strength of the molded body. Therefore, as the binder, an organic polymer which can be gelled in a molded body (clay), for example, hydroxypropoxylmethylcellulose, hydroxypropylmethylcellulose, methylcellulose, hydroxyethylcellulose, lipoxylmethylcellulose, polyvinyl alcohol, etc. Can be suitably used.
- the pore-forming agent is an additive for increasing the porosity by forming a pore by burning out the molded body during firing, thereby obtaining a porous honeycomb structure having a high porosity. Therefore, as the pore-forming agent, an organic substance which is burned off when the molded body is fired, for example, Examples include roughite, wheat flour, starch, phenolic resin, polymethyl methacrylate, polyethylene, and polyethylene terephthalate. Among them, microcapsules made of a foamed resin (such as acrylic resin microcapsules) are particularly preferably used. be able to.
- microcapsules made of foamed resin are hollow, they can obtain a porous honeycomb structure with high porosity by adding a small amount, and generate less heat during firing and reduce the generation of thermal stress. There is an advantage that you can.
- the alkali metal source is an additive that functions as a reinforcing agent that binds the aggregate particles even after the binder is burned out.
- the alkali metal source dissolves in water in the clay to form a hydroxide, and includes a non-oxide ceramic containing silicon. It reacts with the amorphous silica inevitably present on the surface of the glass to form an alkali silicate glass, thereby exhibiting its function.
- the alkali metal source is not particularly limited as long as it can react with water and release alkali metal ions.
- the alkali metal sources such as inorganic salts of alkali metals such as oxides and hydroxides and fatty acid salts can be used. Organic salts.
- the kind of the alkali metal is not particularly limited, it is preferable that the alkali metal is an alkaline metal.
- the kneaded clay to be formed is such that the alkali metal source is equivalent to 0.01 to 10 parts by mass in terms of alkali metal with respect to 100 parts by mass of the aggregate particle material. And more preferably contains an alkali metal source equivalent to 0.02 to 5 parts by mass, equivalent to 0.3 to 1 part by mass. It is particularly preferred that the composition contains an alkali metal source.
- the obtained calcined body has a strength of at least 0.01 kg Z cm 2 or more in the calcining and main calcining steps.
- the content of the alkali metal is less than the above range, the effect of maintaining the mechanical strength of the calcined body after the burnout of the binder becomes insufficient.
- Alkali silicate glass formed by alkali metal although exerting the effect of maintaining mechanical strength This is not preferable in that the pores of the calcined body (and, consequently, the porous honeycomb structure) decrease in porosity.
- the kneaded material in the present invention needs to contain at least the above-mentioned aggregate particle raw material, water, an organic binder, a pore-forming agent, and an alkali metal source, and if necessary, a non-oxide containing silicon.
- Aggregate particle raw materials other than ceramic and metallic silicon, or other additives not specified as the above essential components may be contained.
- a dispersant for accelerating dispersion in water as a dispersion medium, a molding aid for improving moldability, and the like can be contained.
- the dispersant include ethylene glycol, dextrin, fatty acid stone, and polyalcohol.
- the additive contains an alkali metal, it is not necessary to separately add an alkali metal source since the additive can be a source of the alkali metal. Examples of such an additive include potassium laurate used as a molding aid.
- the above-mentioned aggregate particle material, water, organic binder, pore former, alkali metal source and the like are mixed and kneaded by, for example, a vacuum kneader to prepare a clay having an appropriate viscosity.
- the kneaded material prepared as described above is formed into a honeycomb shape having a plurality of cells serving as fluid flow paths, and dried to obtain a honeycomb formed body.
- honeycomb shape means, for example, that a plurality of cells 3 serving as fluid flow paths are partitioned by extremely thin partition walls 4 as in a porous honeycomb structure 1 shown in FIG. Means the shape that is formed.
- the overall shape of the honeycomb formed body is not particularly limited, and examples thereof include a cylindrical shape as shown in FIG. 2, a square pillar shape, a triangular pillar shape, and the like.
- the cell shape (cell shape in a cross section perpendicular to the cell formation direction) of the honeycomb formed body is not particularly limited. For example, in addition to a square cell as shown in FIG. 2, a hexagonal cell, a triangle, and the like. Examples of the shape include cells.
- the molding method is not particularly limited, and a conventionally known molding method such as extrusion molding, injection molding, and press molding can be used. A method of extruding the kneaded clay using a die having a desired cell shape, partition wall thickness, and cell density can be suitably used.
- the drying method is not particularly limited, and conventionally known drying methods such as hot air drying, microwave drying, dielectric drying, reduced pressure drying, vacuum drying, and freeze drying can be used. A drying method combining hot-air drying and microwave drying or dielectric drying is preferable in that drying can be performed uniformly.
- the honeycomb formed body of the present invention obtained as described above includes at least a non-oxide ceramic containing silicon and an aggregate particle material made of Z or metallic silicon, water, an organic binder, a pore former, and A honeycomb formed body formed of a clay containing an alkali metal source and formed into a honeycomb shape having a plurality of cells serving as fluid channels, and when the formed body is fired, the honeycomb formed body is formed into a porous honeycomb structure.
- This has the effect of effectively preventing the occurrence of cracks or the collapse of the porous honeycomb structure due to its own weight.
- the kneaded clay contains 0.1 to 10 parts by mass of an alkali metal in terms of alkali metal with respect to 100 parts by mass of the aggregate particle raw material, the effect is improved. Will be larger.
- the 82-cam molded body obtained as described above is calcined (degreasing) to obtain a calcined body.
- Calcination means an operation of burning and removing organic substances (binders, pore-forming agents, dispersants, etc.) in the compact.
- the combustion temperature of the binder is about 160 ° C. and the combustion temperature of the pore former is about 300 ° C. Therefore, the calcining temperature may be about 200 to 100 ° C.
- the calcination time is not particularly limited, but is usually about 1 to 10 hours.
- the calcined body obtained as described above is main-baked to obtain a porous honeycomb structure.
- the main firing is an operation for sintering and densifying the aggregate particle material in the calcined body to secure a predetermined strength. Since the firing conditions (temperature and time) vary depending on the type of the aggregate particle material, appropriate conditions may be selected according to the type of the aggregate particle material to be used. For example, when silicon carbide is used as a raw material for aggregate particles, it is preferable to bake at a temperature of 130 to 230 for about 1 to 5 hours. (Example)
- the average particle diameter of the aggregate particle material in the following Examples and Comparative Examples was measured by the X-ray transmission method using the Stokes liquid-phase sedimentation method as the measurement principle. The values of 50% and the particle diameter measured by an apparatus (for example, Shimadzu Sedigraph 5000-02 type) were used.
- a total of 100 parts by mass of 80 parts by mass of silicon carbide powder having an average particle size of 33. O ⁇ m and 20 parts by mass of metal silicon powder having an average particle size of 4.0 m was prepared. Then, to 100 parts by mass of the aggregate particle material, 0.45 parts by mass of potassium laurate (0.07 parts by mass in terms of alkali metal) was added as an alkali metal source, and further, methyl cellulose and organic binder were added. Hydroxypropyl methylcellulose, starch as a pore-forming agent, and an appropriate amount of water were added, mixed by a vacuum kneader, and kneaded to prepare a kneaded clay.
- honeycomb formed body was obtained.
- the overall shape of the obtained honeycomb formed body was a square cell having an end face (cell opening surface) of 35 mm ⁇ 35 mm, a length of 152 mm, and a cell shape of 1.15 mm ⁇ 1.15 mm square cell.
- the partition wall thickness was 310 / m
- the cell density was 46.5 cello cm 2 (300 cells / sq. Inch)
- the total number of cells was 576 cells.
- the kind and amount of the alkali metal source were 0.15 parts by mass of potassium laurate (0.02 parts by mass in terms of alkali metal: Example 2), 0.05 parts by mass of potassium hydroxide (0.05 parts by mass in terms of alkali metal). 03 parts by mass: Example 3), sodium hydroxide 0.05 parts by mass (calculated as alkali metal: 0.03 parts by mass: Example 4), potassium laurate 0 Example 1 was repeated except that 9 parts by mass (0.15 parts by mass in terms of alkali metal: Example 5) and 10 parts by mass of potassium hydroxide (7 parts by mass in terms of alkali metal: Example 6) were used. An 82 cam compact was obtained in the same manner as described above.
- a raw material for aggregate particles 100 parts by mass of metal silicon powder having an average particle diameter of 4.0 was prepared. Then, to 100 parts by mass of the aggregate particle material, 0.45 parts by mass of potassium laurate (0.07 parts by mass in terms of alkali metal) was added as an alkali metal source, and further, methyl cellulose and organic binder were added. Hydroxypropyl methylcellulose, starch as a pore-forming agent, and an appropriate amount of water were added, mixed by a vacuum kneader, and kneaded to prepare a clay. Thereafter, a honeycomb molded body was obtained in the same manner as in Example 1.
- a honeycomb formed body was obtained in the same manner as in Example 1 except that no alkali metal source was added.
- a calcined body was obtained by calcining (degreasing) at 400 ° C for 5 hours.
- Example 7 By firing at 50 for 2 hours, a porous honeycomb structure (silicon carbide sintered body) was obtained. Further, the calcined body of Example 7 was sintered in a nitrogen atmosphere at about 1450 ° C. for 2 hours to obtain a porous 82-cam structure (silicon nitride sintered body).
- each cell has the same cell shape, partition wall thickness, and cell density as those in Examples and Comparative Examples, A cube having an 82 cam structure with a side of 35 mm was extruded, dried and calcined by the same drying method and calcining method as in each of the examples and comparative examples to prepare test pieces.
- the strength of the calcined body was evaluated by applying a pressure to the test piece 31 by the pressing plate 32 in the direction of forming the cell 3 la and measuring the compressive strength. .
- the compressive strength was calculated by regarding the honeycomb structured cube as a solid body and dividing the maximum load by 35 ⁇ 35 (mm 2 ). The results are shown in Table 1.
- the state of the calcined body was evaluated by visually observing whether or not cracks occurred in the calcined body and whether or not the calcined body collapsed due to its own weight. The results are shown in Table 1.
- the porosity of the porous 82 cam structure was evaluated by measuring the porosity of the porous honeycomb structure by the mercury intrusion method. The results are shown in Table 1.
- Examples 1 to 7 The anti-fired body had a strength of at least 0.01 kg Z cm 2 or more, and the strength was improved as compared with the calcined body of Comparative Example 2. . Further, none of the calcined bodies of Examples 1 to 7 showed any crack generation or collapse due to their own weight. Further, the porous honeycomb structures of Examples 1 to 7 maintained the same porosity as the porous honeycomb structure of Comparative Example 1, and no decrease in the porosity was observed. In contrast, the calcined body of Comparative Example 1 could not prevent collapse due to its own weight. In addition, the calcined body of Comparative Example 2 had a strength of only 0.05 kg Zcm 2 and could not prevent cracks.
- the calcined body of Comparative Example 3 has a strength of 20 kg / cm 2 , and the strength is remarkably improved as compared with the calcined body of Comparative Example 1, and the occurrence of cracks and Although no collapse due to its own weight was observed, the porosity of the porous honeycomb structure of Comparative Example 3 was significantly lower than that of the porous honeycomb structure of Comparative Example 1. That is, the desired porous honeycomb structure having a high porosity (60% porosity) could not be obtained.
- the metal body for forming is made to contain an aluminum metal source. Therefore, when firing the formed body, the porous honeycomb is used. It is possible to effectively prevent the occurrence of cracks in the structure or the collapse of the porous honeycomb structure due to its own weight.
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Abstract
Description
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Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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DE60330588T DE60330588D1 (de) | 2002-10-23 | 2003-10-21 | Verfahren zur herstellung von poröser wabenstruktur und wabenkörper |
KR1020057006796A KR100649470B1 (ko) | 2002-10-23 | 2003-10-21 | 다공질 허니컴 구조체의 제조 방법 및 허니컴 성형체 |
AU2003273065A AU2003273065A1 (en) | 2002-10-23 | 2003-10-21 | Method for manufacturing porous honeycomb structure and honeycomb body |
US10/531,873 US20060057330A1 (en) | 2002-10-23 | 2003-10-21 | Method for manufacturing porous honeycomb structure and honeycomb body |
EP03754209A EP1555253B1 (en) | 2002-10-23 | 2003-10-21 | Method for manufacturing porous honeycomb structure and honeycomb body |
Applications Claiming Priority (2)
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JP2002308068A JP4571775B2 (ja) | 2002-10-23 | 2002-10-23 | 多孔質ハニカム構造体の製造方法、及びハニカム成形体 |
JP2002-308068 | 2002-10-23 |
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WO2004037744A1 true WO2004037744A1 (ja) | 2004-05-06 |
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US (1) | US20060057330A1 (ja) |
EP (1) | EP1555253B1 (ja) |
JP (1) | JP4571775B2 (ja) |
KR (1) | KR100649470B1 (ja) |
AU (1) | AU2003273065A1 (ja) |
DE (1) | DE60330588D1 (ja) |
PL (1) | PL207931B1 (ja) |
WO (1) | WO2004037744A1 (ja) |
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JP4954705B2 (ja) * | 2004-09-14 | 2012-06-20 | 日本碍子株式会社 | 多孔質ハニカムフィルター |
US8097203B2 (en) * | 2007-01-29 | 2012-01-17 | Corning Incorporated | Crosslinked green body articles and method of manufacturing porous ceramic articles therefrom |
KR20170001485A (ko) | 2015-06-26 | 2017-01-04 | 허정섭 | 세라믹스 압출성형용 유기바인더 조성물 및 이의 제조방법 |
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EP1170270A1 (en) * | 2000-01-17 | 2002-01-09 | Ngk Insulators, Ltd. | Honeycomb structure and method for manufacture thereof |
JP2002047069A (ja) * | 2000-07-31 | 2002-02-12 | Ngk Insulators Ltd | ハニカム構造体の製造方法 |
JP2002301323A (ja) * | 2001-04-04 | 2002-10-15 | Ngk Insulators Ltd | ハニカム型セラミックス質フィルター |
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JPS60255671A (ja) * | 1984-05-29 | 1985-12-17 | イビデン株式会社 | 高強度多孔質炭化ケイ素焼結体とその製造方法 |
US4824807A (en) * | 1987-06-01 | 1989-04-25 | Blount David H | Flexible alkali metal silicate glass products |
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US5914294A (en) * | 1996-04-23 | 1999-06-22 | Applied Ceramics, Inc. | Adsorptive monolith including activated carbon and method for making said monlith |
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WO2001058828A1 (fr) * | 2000-02-07 | 2001-08-16 | Ibiden Co., Ltd. | Substrat ceramique pour dispositif de production ou d'examen de semi-conducteurs |
DE10024038A1 (de) * | 2000-05-13 | 2001-11-22 | Dmc2 Degussa Metals Catalysts | Wabenkörper aus einem keramischen Material mit verbesserter radialer Druckfestigkeit |
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JP3799241B2 (ja) * | 2001-03-29 | 2006-07-19 | 日本碍子株式会社 | ハニカム構造体の製造方法 |
JP4307781B2 (ja) * | 2001-03-30 | 2009-08-05 | 日本碍子株式会社 | 炭化珪素質多孔体及びその製造方法 |
JP2003095768A (ja) * | 2001-09-18 | 2003-04-03 | Ngk Insulators Ltd | ハニカム構造体及びその製造方法 |
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2002
- 2002-10-23 JP JP2002308068A patent/JP4571775B2/ja not_active Expired - Fee Related
-
2003
- 2003-10-21 EP EP03754209A patent/EP1555253B1/en not_active Expired - Fee Related
- 2003-10-21 AU AU2003273065A patent/AU2003273065A1/en not_active Abandoned
- 2003-10-21 PL PL375708A patent/PL207931B1/pl unknown
- 2003-10-21 US US10/531,873 patent/US20060057330A1/en not_active Abandoned
- 2003-10-21 KR KR1020057006796A patent/KR100649470B1/ko active IP Right Grant
- 2003-10-21 DE DE60330588T patent/DE60330588D1/de not_active Expired - Lifetime
- 2003-10-21 WO PCT/JP2003/013428 patent/WO2004037744A1/ja active Application Filing
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EP1170270A1 (en) * | 2000-01-17 | 2002-01-09 | Ngk Insulators, Ltd. | Honeycomb structure and method for manufacture thereof |
JP2002047069A (ja) * | 2000-07-31 | 2002-02-12 | Ngk Insulators Ltd | ハニカム構造体の製造方法 |
JP2002301323A (ja) * | 2001-04-04 | 2002-10-15 | Ngk Insulators Ltd | ハニカム型セラミックス質フィルター |
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CN112221251A (zh) * | 2020-09-29 | 2021-01-15 | 潘锡丹 | 一种陶瓷过滤板成型加工方法 |
Also Published As
Publication number | Publication date |
---|---|
JP4571775B2 (ja) | 2010-10-27 |
KR20050075364A (ko) | 2005-07-20 |
JP2004142979A (ja) | 2004-05-20 |
PL375708A1 (en) | 2005-12-12 |
DE60330588D1 (de) | 2010-01-28 |
PL207931B1 (pl) | 2011-02-28 |
KR100649470B1 (ko) | 2006-11-28 |
US20060057330A1 (en) | 2006-03-16 |
AU2003273065A1 (en) | 2004-05-13 |
EP1555253A4 (en) | 2007-07-04 |
EP1555253A1 (en) | 2005-07-20 |
EP1555253B1 (en) | 2009-12-16 |
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