WO2004035131A2 - Procede et revetement pour proteger des plantes cultivees - Google Patents

Procede et revetement pour proteger des plantes cultivees Download PDF

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Publication number
WO2004035131A2
WO2004035131A2 PCT/IL2003/000842 IL0300842W WO2004035131A2 WO 2004035131 A2 WO2004035131 A2 WO 2004035131A2 IL 0300842 W IL0300842 W IL 0300842W WO 2004035131 A2 WO2004035131 A2 WO 2004035131A2
Authority
WO
WIPO (PCT)
Prior art keywords
cover
fungicide
impregnated
crop
crops
Prior art date
Application number
PCT/IL2003/000842
Other languages
English (en)
Other versions
WO2004035131A3 (fr
Inventor
Avner Barazani
Original Assignee
Makhteshim Chemical Works Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Makhteshim Chemical Works Ltd. filed Critical Makhteshim Chemical Works Ltd.
Priority to AU2003274638A priority Critical patent/AU2003274638A1/en
Publication of WO2004035131A2 publication Critical patent/WO2004035131A2/fr
Publication of WO2004035131A3 publication Critical patent/WO2004035131A3/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24—Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • B65D81/28—Applications of food preservatives, fungicides, pesticides or animal repellants
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38—Packaging materials of special type or form
    • B65D65/42—Applications of coated or impregnated materials

Definitions

  • the present invention relates to the field of pest control in crops. Particularly, the present invention relates to a method and a cover for protecting crops.
  • said covering is a plastic bag of polymeric material which is wrapped around the crop in need of protection. This method is predominantly employed in the cultivation of bananas and plantains.
  • a bag impregnated with an insecticide chlorpyrifos is sold by Makhteshim-Agan Industries Ltd. under the name Pyritilene®.
  • Said bag provides improved protection to the crop by creating an atmosphere of chlorpyrifos vapor in the bag and around the crop, hence exterminating insects on the crop and in the vicinity thereof.
  • Said coverings additionally protect the crop against mechanical damage which may result for example from strong winds and leaves of the tree brushing against the crop.
  • the covering further provides protection against ultra violet radiation and further elemental hazards such as extreme weather conditions including strong winds and hail.
  • WO 02/35930 in the name of the present applicant, discloses a sheet for pest control, which is constructed of multi-layers and contains at least an herbicide. Said sheet cannot be used in accordance to the present invention due to the herbicidal content of said sheet.
  • U.S. Patent No. 5,326,777 discloses a method of protecting plastics from fungi by the blending of a synergistic mixture of tebuconazole and carbendazim with the starting materials required for polymerization. However, said method is intended for protecting plastic and does not provide for protection of crop.
  • U.S. Patent No. 4,888,175 discloses a package made of a plastic sheet having a biocidal agent, 10,10-oxybisphenoxarasine, dissolved or dispersed within the sheet so that the biocidal agent inhibits bacterial or viral activity in the soil and root structure which is wrapped by said plastic.
  • said sheet is not suitable for protecting crops against fungal attack and insects.
  • the prior art provides an effective method and cover for protecting crops against insects.
  • Methods for protecting crops against fungal attack include dusting or spraying the crop with effective fungicides.
  • dusting or spraying the crop when it is protected with a cover such as a bag would require the removal of the cover prior to the application and then covering the crop after application. To treat the crop accordingly would be cumbersome and not practical. Thus said treatment is not practiced.
  • the damages from various fungal pathogens to crops which are covered with a protective cover cause a reduction in yield which results in financial damage.
  • a further objective of the present invention is to provide a method for protecting crop against pests including phytotoxic fungi. It is another objective of the present invention to provide a composition comprising a polymer and a fungicide which are suitable for the preparation of polymeric covers for protecting crop.
  • the present invention provides a cover for crops which provides protection of the crop against fungi, wherein said cover is of polymeric material which is impregnated with at least one fungicide.
  • said covering may further be impregnated with additional pesticides selected from among fungicides and insecticides.
  • said cover may comprise of an inner and outer layer, wherein only the inner layer is impregnated with a fungicide, and optionally a further pesticide.
  • a method for protecting crops against pre-harvest and post-harvest attack of fungal diseases comprising of covering the crop with the protective covering of the present invention.
  • a further aspect of the present invention provides compositions comprising a polymer and a fungicide (hereinafter “master batch”) which are suitable for the preparation of the polymeric covers of the present invention.
  • pesticides as used throughout the description includes fungicides and insecticides.
  • crop it is meant, vegetables, fruits or the plants on which they grow.
  • the method of the present invention is based on creating an atmosphere of pesticide vapor in the volume encompassed by the cover surrounding the crop. It has now been surprisingly found that certain pesticides which when applied by dusting or spraying may have phytotoxic effects on the crop or may affect the taste of the crop, are not phytotoxic and do not affect the crop when applied according to the method of the present invention.
  • a method for protecting crops against fungal diseases comprising of covering the crop with the protective cover of the present invention so that the volume surrounding the crop in the cover is filled with vapor of the fungicide which is released from the impregnated polymeric material of the cover.
  • the crop is covered with a protective cover which is impregnated with at least one fungicide and at least one additional pesticide, said pesticide being an insecticide.
  • the volume surrounding the crop in the protective cover contains fungicidal and insecticidal vapor which protects the crop from fungal diseases and insects.
  • the blossoms on a banana tree from which the fruit develops are covered with a bag constructed of polymeric material which is impregnated with at least one fungicide. Fungicidal vapor which is slowly released from the bag, fills the bag and thus protects the fruit from fungal diseases. Impregnating the bag with prochloraz will particularly be effective for protecting bananas from Pyricularia grisea without affecting the taste of the fruit nor displaying any phytotoxic effects.
  • the bananas are wrapped with a bag which is impregnated with prochloraz and chlorpyrifos so that the bananas are protected from fungal diseases and insects.
  • the present method can be applied for pre-harvest and post-harvest protection to a wide variety of crops.
  • the crop e.g. the fruit or cluster of fruit
  • a protective cover of the present invention preferably from the blossom stage.
  • Preferred crops for which the present method may be applied for pre-harvest protection include: bananas, plantains, dorians, dates, citrus fruit, mango, avocado and pawpaws.
  • the present method when applied for post-harvest protection of crops, comprises of covering the crop or the container in which the crop is stored, with a protective cover of the present invention.
  • Preferred crops for the post-harvest application of the method of the present invention include: bananas, plantains, dorians, citrus fruit, papaya, mangos, stone fruit, pome fruit, avocados, grapes, melons, pineapples, pawpaws, strawberries, dates, mushrooms, eggplants and onions.
  • Non-limiting examples of phytopathogenic fungi which may controlled according to the present method include: pyricularia grisea, venturia inaequalis, colletotrichum gloeosporioides, glomerella cingulata, diplodia spp., monilinia laxa, colletrotichum spp., hypomyces tosellus, mycogone perniciose, verticillium fungicola, alternaria porri, botrytis allii, botrytis squamosa, alternaria alternate, dothiorella aromatica, botryodiplodia theobromae, penicillium expansum, penicillium spp., colletotrichum musae, trachyspaera fruitigena , botrytis cinera, diplodia, penicillium digitatum, penicillium italicum, ceratocystis paradoxa, botrytis.
  • fungicides and insecticides may be employed in the present method in accordance to the particular fungi and pest which is to be controlled.
  • Preferred fungicides include: N-propyl-N-[2-(2,4,6-trichlorophenoxy)ethyl] lH-imidazole- 1 - carboxamide (prochloraz); ( ⁇ )-l-[2-(2,4-dichlorophenyl)-2-(2-propenyloxy)ethyl]-lH- imidazole (imazalil); ( ⁇ )- ⁇ -butyl- ⁇ -(2,4-dichorophenyl)-lH-l,2,4-triazole-l-ethanol (hexaconazole); methyl[l-[(butylamino)carbonyl]-lH-benzimidazol-2-yl]carbamate (benomyl); ( ⁇ )- ⁇ -[2-(4-chlorophenyl)ethyl
  • Preferred insecticides include: C,0-diethyl-O-3,5,6-trichloro-2- pyridinyl)phophorothioate (chlorpyrifos); 0, 0-diethyl-0-[6-methyl-2-(l-methylethyl)-4- pyrimidinyl) phosphorothioate (diazinon); pyrethroids; and neonicotinoids.
  • chlorpyrifos C,0-diethyl-O-3,5,6-trichloro-2- pyridinyl)phophorothioate
  • chlorpyrifos chlorpyrifos
  • pyrethroids phosphorothioate
  • neonicotinoids neonicotinoids
  • a protective cover for protecting crops against fungi, wherein said cover is constructed of polymeric material which is impregnated with at least one fungicide.
  • the cover is constructed in the form of a bag, sleeve or sheet.
  • the size of the cover and the contents of pesticides may be controlled in accordance to the crop in need of protection and the pest or fungi which are to be eradicated and against which protection is sought.
  • the material of which the protective cover is constructed contains
  • the material of the protective cover contains 0.1% to 2%> of at least one fungicide and 0.1 % to 2% of at least one insecticide.
  • the protective cover is constructed of a single layer polymeric material in the form of a bag or sleeve, wherein said polymeric material is impregnated with at least one fungicide.
  • the protective cover is constructed of a single layer polymeric material in the form of a bag or sleeve, wherein said polymeric material is impregnated with at least one fungicide and at least one insecticide.
  • a bag constructed of polymeric material which is impregnated with prochloraz.
  • said bag is impregnated with prochloraz and chlorpyrifos, such that said bag contains 0.1% to 2% and 0.1% to 2%> prochloraz and chlorpyrifos, respectively.
  • a protective cover for crop which is constructed of polymeric material, comprising an inner and outer layer, wherein only the inner layer is impregnated with at least one fungicide.
  • the inner layer may further be impregnated with additional pesticides.
  • the outer layer functions as a protective layer so that the person coming in contact with the cover does not come in contact with the pesticides which are impregnated in the inner layer of the cover.
  • the material of the inner layer may contain 0.1% to 2% of at least one fungicide and 0 to 2% of at least one insecticide.
  • the protective cover may be impregnated with various fungicides and insecticides in accordance to the particular fungi and pest which is to be controlled.
  • Preferred fungicides include: prochloraz, imazalil, hexaconazole, benomyl, tebuconazole, fenbuconazole, thiabendazole, myclobutanil and strobilurins.
  • Preferred insecticides include: chlorpyrifos, diazinon, pyrethroids and neonicotinoids.
  • the protective cover may be constructed of many types of polymeric material.
  • Non- limiting examples of polymers suitable for the construction of the protective cover are homopolymers and copolymers of polyolefines selected from a group comprising of low density polyethylene (LDPE), low linear density polyethylene (LLDPE), high density polyethylene (HDPE), polypropylene (PP), ethylene vinyl acetate (EVA), ethylene methyl acrylate (EMA), derivatives or mixtures and blends thereof.
  • LDPE low density polyethylene
  • LLDPE low linear density polyethylene
  • HDPE high density polyethylene
  • PP polypropylene
  • EVA ethylene vinyl acetate
  • EMA ethylene methyl acrylate
  • impregnation it is meant that the pesticide is included within the polymeric matrix.
  • Impregnation of the fungicide and pesticide in the polymeric material is accomplished by mixing the fungicide or pesticide with raw polymeric material, which is the raw material from which the polymeric cover is constructed (hereinafter "pre-mix"), prior to the final stage of constructing the cover.
  • the pre-mix may come in the form of pellettes, melt, resin or solution.
  • Mixing the pre-mix with a fungicide or pesticide provides the master batch, said master batch being a further aspect of the present invention.
  • Processing the master batch to construct the protective cover provides a cover wherein the fungicide or pesticide is impregnated in the polymeric material of the cover. Processing of the master batch may be carried out according to various known methods in the art such as extrusion.
  • the master batch may be processed with additional resins in order to form the protective cover.
  • the ratio between the master batch and additional resins may be controlled so that the desired percentage of pesticide in the protective cover is achieved.
  • the master batch of the present invention contains 5% to 50% of at least one fungicide.
  • the master batch may contain at least one additional insecticide in the amount
  • the master batch contains 5% to 50% prochloraz. In yet a further embodiment the master batch contains 5% to 50% prochloraz, and 5% to 50% chlorpyrifos.
  • the pesticide impregnated in the protective cover is slowly released from the polymeric material.
  • the rate of release of the pesticide from the polymeric material is controlled so that substantially most of the pesticide is released from the polymeric material by the end of the period of time for which protection is sought. Said period may be the growing season until the crop is harvested, the time of storage and transportation of the harvested crop, or a combination of both said periods.
  • the rate of release of the pesticide from the polymeric material may be controlled by the amount and type of anti-block filler additives and type of polymer from which the polymeric material is prepared. Said additives described hereinafter. Other methods of controlling the rate of release may be employed as may appreciated by the skilled artisan.
  • the pre-mix and master batches of the present invention may further comprise additives that are intended for achieving the desired properties of the protective cover.
  • the group of additives which are well known from the prior art comprises u.v. absorbents; anti-blocks which are based on amorphous and crystalline silicates; slip agents selected from among amides, oleamide, stearamide and derivatives thereof; lubricants selected from among polyolefine waxes, PE waxes and PP waxes and metal stearates; and anti-oxidants.
  • Other additives may be applied as may be appreciated by the skilled artisan.
  • the present invention presents the following advantages:
  • the cover provides constant fungi control after application of the cover without the need to reapply fungicides.
  • the method provides a safe mode of fungicide application. The fungicides are released slowly into the air surrounding the crop creating a cloud of fungicide vapor around the crop. Hence the exposure of people working in the field is minimal. This is in comparison to other application methods which involve handling, mixing of toxic chemicals and spraying or other methods of application of these chemicals. The spraying creates a hazardous mist which may be harmful to the person working in the field and to the environment.
  • the method provides post-harvest fungicidal protection during transportation of the crop.
  • post harvest reapplication of fungicides before transportation is reduced or eliminated. This is particularly important when residue levels of pesticides in the crop need to maintained very low.
  • the present invention provides a method of application of prochloraz to bananas and other sensitive crops that does not affect the taste of the crops while other methods of application of prochloraz does affect the taste of the banana and the crop and thus are not recommended.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Food Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)

Abstract

L'invention concerne un revêtement protecteur, polymère, destiné à réguler les maladies fongique dans des plantes cultivées, ledit revêtement étant imprégné d'au moins un fongicide et éventuellement de fongicides ou d'insecticides supplémentaires. Selon un aspect supplémentaire de l'invention, un procédé permet de protéger les plantes cultiver avant et/ou après la récolte. L'invention concerne également une composition polymère comprenant un polymère et un fongicide, qui peut être utilisée dans la préparation d'un revêtement protecteur.
PCT/IL2003/000842 2002-10-18 2003-10-16 Procede et revetement pour proteger des plantes cultivees WO2004035131A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003274638A AU2003274638A1 (en) 2002-10-18 2003-10-16 Method and cover for protecting crops

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IL15236702A IL152367A0 (en) 2002-10-18 2002-10-18 Method and cover for protecting crops
IL152367 2002-10-18

Publications (2)

Publication Number Publication Date
WO2004035131A2 true WO2004035131A2 (fr) 2004-04-29
WO2004035131A3 WO2004035131A3 (fr) 2004-06-03

Family

ID=29765072

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IL2003/000842 WO2004035131A2 (fr) 2002-10-18 2003-10-16 Procede et revetement pour proteger des plantes cultivees

Country Status (5)

Country Link
AR (1) AR041665A1 (fr)
AU (1) AU2003274638A1 (fr)
IL (1) IL152367A0 (fr)
PA (1) PA8586701A1 (fr)
WO (1) WO2004035131A2 (fr)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0101102A2 (fr) * 1982-07-21 1984-02-22 Janssen Pharmaceutica N.V. Prévention du flétrissement fongique des produits alimentaires, en particulier des fruits récoltés
EP0142658A1 (fr) * 1983-10-15 1985-05-29 Gesellschaft für Strahlen- und Umweltforschung mbH (GSF) Support en matière organique avec des produits actifs intégrés
US4666706A (en) * 1985-11-21 1987-05-19 The Dow Chemical Company Delayed release insecticidal composition and method of making same
EP0514578A1 (fr) * 1989-11-28 1992-11-25 Showa Denko Kabushiki Kaisha Matériaux contenant de l'hinokitiol pour maintenir la fraîcheur des aliments et méthode de maintenir la fraîcheur des aliments
US5554373A (en) * 1993-11-05 1996-09-10 Seabrook; Samuel G. Compositions containing anti-microbial agents and methods for making and using same
WO1998014073A2 (fr) * 1996-10-03 1998-04-09 E.I. Du Pont De Nemours And Company Feuil thermoplastique d'emballage alimentaire conferant une resistance anti-fongique aux aliments qu'il contient
WO1999009824A1 (fr) * 1997-08-22 1999-03-04 Cryovac, Inc. Materiaux d'emballage pesticides
WO2002035930A2 (fr) * 2000-11-01 2002-05-10 Makhteshim Chemical Works Ltd. Feuille de destruction des parasites
WO2002046063A1 (fr) * 2000-12-08 2002-06-13 Polymer Group, Inc. Enveloppe protectrice de produits agricoles

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL52177A (en) * 1977-05-27 1979-11-30 Israel Mini Agricult Seal-packaging of comestibles with high density polyethylene
JPS5822121B2 (ja) * 1979-12-12 1983-05-06 柴田屋加工紙株式会社 果実育成袋
JPH05117120A (ja) * 1991-10-23 1993-05-14 Sumitomo Seika Chem Co Ltd 着果青果物用防虫防黴材

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0101102A2 (fr) * 1982-07-21 1984-02-22 Janssen Pharmaceutica N.V. Prévention du flétrissement fongique des produits alimentaires, en particulier des fruits récoltés
EP0142658A1 (fr) * 1983-10-15 1985-05-29 Gesellschaft für Strahlen- und Umweltforschung mbH (GSF) Support en matière organique avec des produits actifs intégrés
US4666706A (en) * 1985-11-21 1987-05-19 The Dow Chemical Company Delayed release insecticidal composition and method of making same
EP0514578A1 (fr) * 1989-11-28 1992-11-25 Showa Denko Kabushiki Kaisha Matériaux contenant de l'hinokitiol pour maintenir la fraîcheur des aliments et méthode de maintenir la fraîcheur des aliments
US5554373A (en) * 1993-11-05 1996-09-10 Seabrook; Samuel G. Compositions containing anti-microbial agents and methods for making and using same
WO1998014073A2 (fr) * 1996-10-03 1998-04-09 E.I. Du Pont De Nemours And Company Feuil thermoplastique d'emballage alimentaire conferant une resistance anti-fongique aux aliments qu'il contient
WO1999009824A1 (fr) * 1997-08-22 1999-03-04 Cryovac, Inc. Materiaux d'emballage pesticides
WO2002035930A2 (fr) * 2000-11-01 2002-05-10 Makhteshim Chemical Works Ltd. Feuille de destruction des parasites
WO2002046063A1 (fr) * 2000-12-08 2002-06-13 Polymer Group, Inc. Enveloppe protectrice de produits agricoles

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
DATABASE CA [Online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; I.K.KNIGHTS: "Developments in the use of prochloraz fr tropical fruit disease control" retrieved from STN-INTERNATIONAL Database accession no. 106:174884 CA XP002275825 & BRITISH CROP PROTECTION CONFERENCE -- PESTS AND DISEASES, PROCEEDINGS, no. 1, 1986, pages 331-338, *
DATABASE CA [Online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; retrieved from STN-INTERNATIONAL Database accession no. 134:322064 ca XP002275826 & RO 115 486 A (S.C.CHIMCOMPLEX) 30 March 2000 (2000-03-30) *
DATABASE CABA [Online] S.JOHNSON: "An insecticide-treated polyethylene cover protects banana bunches" retrieved from STN-INTERNATIONAL Database accession no. 75:15564 CABA XP002275824 & HACIENDA, vol. 70, no. 3, 1975, pages 22-25, *
DATABASE WPI Section Ch, Week 197934 Derwent Publications Ltd., London, GB; Class A17, AN 1979-63139B XP002275828 & ZA 7 802 762 A (ISRAEL MIN AGRIC), 10 April 1979 (1979-04-10) *
DATABASE WPI Section Ch, Week 198134 Derwent Publications Ltd., London, GB; Class C03, AN 1981-61356D XP002275829 & JP 56 083407 A (SHIBATAYA KAKOSHI KK), 8 July 1981 (1981-07-08) *
DATABASE WPI Section Ch, Week 199324 Derwent Publications Ltd., London, GB; Class A97, AN 1993-191408 XP002275827 & JP 05 117120 A (SUMITOMO SEIKA CHEM CO LTD), 14 May 1993 (1993-05-14) *

Also Published As

Publication number Publication date
AU2003274638A8 (en) 2004-05-04
PA8586701A1 (es) 2005-02-04
AR041665A1 (es) 2005-05-26
AU2003274638A1 (en) 2004-05-04
IL152367A0 (en) 2003-05-29
WO2004035131A3 (fr) 2004-06-03

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