WO2004016624A3 - Verfahren zur herstellung endohedraler fullerene - Google Patents

Verfahren zur herstellung endohedraler fullerene Download PDF

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Publication number
WO2004016624A3
WO2004016624A3 PCT/DE2003/002501 DE0302501W WO2004016624A3 WO 2004016624 A3 WO2004016624 A3 WO 2004016624A3 DE 0302501 W DE0302501 W DE 0302501W WO 2004016624 A3 WO2004016624 A3 WO 2004016624A3
Authority
WO
WIPO (PCT)
Prior art keywords
fullerenes
production
endohedral
evaporation
carried out
Prior art date
Application number
PCT/DE2003/002501
Other languages
English (en)
French (fr)
Other versions
WO2004016624A2 (de
Inventor
Lothar Dunsch
Petra Georgi
Frank Ziegs
Heidi Zoeller
Original Assignee
Leibniz Inst Fuer Festkoerper
Lothar Dunsch
Petra Georgi
Frank Ziegs
Heidi Zoeller
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Leibniz Inst Fuer Festkoerper, Lothar Dunsch, Petra Georgi, Frank Ziegs, Heidi Zoeller filed Critical Leibniz Inst Fuer Festkoerper
Priority to AU2003250801A priority Critical patent/AU2003250801A1/en
Priority to CN038173980A priority patent/CN1671620B/zh
Priority to US10/519,696 priority patent/US20050232842A1/en
Priority to EP03787736A priority patent/EP1523450A2/de
Priority to JP2004528436A priority patent/JP4603358B2/ja
Priority to DE10393502T priority patent/DE10393502D2/de
Publication of WO2004016624A2 publication Critical patent/WO2004016624A2/de
Publication of WO2004016624A3 publication Critical patent/WO2004016624A3/de

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/15—Nano-sized carbon materials
    • C01B32/152—Fullerenes
    • C01B32/154—Preparation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Abstract

Die Erfindung betrifft ein Verfahren zur Herstellung endohedraler Fullerene in einem Lichtbogenreaktor durch Abbrennen von Graphitelektroden.Der Erfindung liegt die Aufgabe zugrunde, ein Verfahren zur Herstellung endohedraler Fullerene in einem Lichtbogenreaktor durch Abbrennen von Graphitelektroden zu schaffen, mit dem es möglich ist, die Fullerenausbeute wesentlich zu erhöhen.Das erfindungsgemäße Verfahren ist dadurch gekennzeichnet, dass das Abbrennen in einer Atmosphäre durchgeführt wird, die in einem Inertgas oder Inertgasgemisch eine aus mindestens zwei Elementen bestehende reaktive Gaskomponente enthält.Mit dem Verfahren wird in vorteilhafter Weise eine sehr hohe Fullerenausbeute von 50 bis 95% an endohedralem M3N-Cluster-Fulleren als Hauptprodukt erreicht. Das Verfahren ist mit geringem Aufwand und in einfacher Weise durchführbar und führt zu reproduzierbaren Ergebnissen.Die auf diese Weise hergestellten Fullerene können beispielsweise als Kontrastmittel für medizinische Untersuchungen eingesetzt werden.
PCT/DE2003/002501 2002-07-22 2003-07-21 Verfahren zur herstellung endohedraler fullerene WO2004016624A2 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
AU2003250801A AU2003250801A1 (en) 2002-07-22 2003-07-21 Method for the production of endohedral fullerenes
CN038173980A CN1671620B (zh) 2002-07-22 2003-07-21 用来制备内嵌富勒烯的方法
US10/519,696 US20050232842A1 (en) 2002-07-22 2003-07-21 Method for the production of endohedral fullerenes
EP03787736A EP1523450A2 (de) 2002-07-22 2003-07-21 Verfahren zur herstellung endohedraler fullerene
JP2004528436A JP4603358B2 (ja) 2002-07-22 2003-07-21 内包フラーレンの製造方法
DE10393502T DE10393502D2 (de) 2002-07-22 2003-07-21 Verfahren zur Herstellung endohedraler Fullerne

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10233566.4 2002-07-22
DE10233566 2002-07-22

Publications (2)

Publication Number Publication Date
WO2004016624A2 WO2004016624A2 (de) 2004-02-26
WO2004016624A3 true WO2004016624A3 (de) 2004-05-21

Family

ID=30010328

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2003/002501 WO2004016624A2 (de) 2002-07-22 2003-07-21 Verfahren zur herstellung endohedraler fullerene

Country Status (8)

Country Link
US (1) US20050232842A1 (de)
EP (1) EP1523450A2 (de)
JP (1) JP4603358B2 (de)
CN (1) CN1671620B (de)
AU (1) AU2003250801A1 (de)
DE (2) DE10301722B4 (de)
RU (1) RU2004137099A (de)
WO (1) WO2004016624A2 (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2008317422A1 (en) * 2007-10-22 2009-04-30 Luna Innovations Incorporated Metallofullerene contrast agents
US20090250661A1 (en) * 2008-01-18 2009-10-08 Stevenson Steven A Trimetallic Nitride Clusters Entrapped Within CnN Heteroatom Cages
CN101337668B (zh) * 2008-08-11 2013-10-23 彭汝芳 制备内嵌富勒烯的方法
DE102008043654A1 (de) 2008-11-11 2010-05-20 Leibniz-Institut Für Festkörper- Und Werkstoffforschung Dresden E.V. Diagnostisches und/oder therapeutisches Agens, Verfahren zu seiner Herstellung und Verwendung
CN102205958B (zh) * 2011-05-04 2013-01-23 中国科学技术大学 内嵌氮化物原子簇富勒烯的制备方法
CN104129775B (zh) * 2014-07-16 2015-12-30 苏州大学 一种内嵌钪氧化物团簇富勒烯的制备方法
CN106744814A (zh) * 2016-12-06 2017-05-31 河南科技学院 一种内嵌金属富勒烯的提取方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6303760B1 (en) * 1999-08-12 2001-10-16 Virginia Tech Intellectual Properties, Inc. Endohedral metallofullerenes and method for making the same

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US5300203A (en) * 1991-11-27 1994-04-05 William Marsh Rice University Process for making fullerenes by the laser evaporation of carbon
JPH05282938A (ja) * 1992-02-28 1993-10-29 Idemitsu Kosan Co Ltd 金属内包フラーレン類の製造方法
US5876684A (en) * 1992-08-14 1999-03-02 Materials And Electrochemical Research (Mer) Corporation Methods and apparati for producing fullerenes
JPH06199509A (ja) * 1993-01-07 1994-07-19 Nippon Telegr & Teleph Corp <Ntt> 超微粒子の安定化方法、グラファイトで包まれた超微粒子およびその製造方法
DE4335915A1 (de) * 1993-10-21 1995-04-27 Roggenkamp Karl Heinz Verfahren zur Erzeugung von Fullerenen und dotierten Buckmister Fullereren aus kohlenstoffhaltigen Granulaten und Stäuben und der Beigabe von Metallen oder seltenen Erden, wobei der zu verdampfende Rohstoff in einer tassenartigen hochtemperaturfesten Umhüllung sich befindet
JPH07189040A (ja) * 1993-12-27 1995-07-25 Nec Corp 円筒状黒鉛繊維の製造方法
JPH09309711A (ja) * 1996-03-18 1997-12-02 Toyo Tanso Kk 炭素クラスター、それを製造するための原料及びその炭素クラスターの製造方法
DE19627338A1 (de) * 1996-06-28 1998-01-02 Hahn Meitner Inst Berlin Gmbh Elektrode zur Herstellung von höheren Fullerenen nach dem Krätschmer-Huffman-Lichtbogenverfahren
AU5815698A (en) * 1997-01-13 1998-08-03 Brian Edward Jurczyk Method and apparatus for producing complex carbon molecules
JP2000159514A (ja) * 1998-11-26 2000-06-13 Univ Nagoya 金属内包フラーレンの製造方法
EP1286303A1 (de) * 2001-08-13 2003-02-26 Hitachi Europe Limited Quantenrechner

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6303760B1 (en) * 1999-08-12 2001-10-16 Virginia Tech Intellectual Properties, Inc. Endohedral metallofullerenes and method for making the same

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; FENG, LAI ET AL: "Isolation and characterization of the endohedral metallofullerene Tb3N@C8", XP002262359, retrieved from STN Database accession no. 137:209802 CA *
GAODENG XUEXIAO HUAXUE XUEBAO (2002), 23(6), 996-998, 2002 *
STEVENSON S ET AL: "Small-bandgap endohedral metallofullerenes in high yield and purity", NATURE, 2 SEPT. 1999, MACMILLAN MAGAZINES, UK, vol. 401, no. 6748, pages 55 - 57, XP002262357, ISSN: 0028-0836 *
TAGMATARCHIS NIKOS ET AL: "Isolation and spectroscopic study of a series of mono- and dierbium endohedral C82 and C84 metallofullerenes", J PHYS CHEM B;JOURNAL OF PHYSICAL CHEMISTRY B NOV 2000 ACS, WASHINGTON, DC, USA, vol. 104, no. 47, November 2000 (2000-11-01), pages 11010 - 11012, XP002262358 *

Also Published As

Publication number Publication date
AU2003250801A8 (en) 2004-03-03
RU2004137099A (ru) 2005-07-10
DE10301722B4 (de) 2009-12-10
DE10393502D2 (de) 2005-07-07
EP1523450A2 (de) 2005-04-20
CN1671620A (zh) 2005-09-21
CN1671620B (zh) 2010-05-26
WO2004016624A2 (de) 2004-02-26
US20050232842A1 (en) 2005-10-20
JP2005533745A (ja) 2005-11-10
JP4603358B2 (ja) 2010-12-22
AU2003250801A1 (en) 2004-03-03
DE10301722A1 (de) 2004-02-05

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