WO2004015751A1 - 半導体ウェハ用研磨パッドの加工方法及び半導体ウェハ用研磨パッド - Google Patents
半導体ウェハ用研磨パッドの加工方法及び半導体ウェハ用研磨パッド Download PDFInfo
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- WO2004015751A1 WO2004015751A1 PCT/JP2003/010125 JP0310125W WO2004015751A1 WO 2004015751 A1 WO2004015751 A1 WO 2004015751A1 JP 0310125 W JP0310125 W JP 0310125W WO 2004015751 A1 WO2004015751 A1 WO 2004015751A1
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- WIPO (PCT)
- Prior art keywords
- polishing pad
- polishing
- semiconductor wafer
- groove
- processing
- Prior art date
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/36—Removing material
- B23K26/38—Removing material by boring or cutting
- B23K26/382—Removing material by boring or cutting by boring
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P52/00—Grinding, lapping or polishing of wafers, substrates or parts of devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/08—Devices involving relative movement between laser beam and workpiece
- B23K26/082—Scanning systems, i.e. devices involving movement of the laser beam relative to the laser head
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/08—Devices involving relative movement between laser beam and workpiece
- B23K26/0823—Devices involving rotation of the workpiece
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/36—Removing material
- B23K26/362—Laser etching
- B23K26/364—Laser etching for making a groove or trench, e.g. for scribing a break initiation groove
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/36—Removing material
- B23K26/40—Removing material taking account of the properties of the material involved
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B37/00—Lapping machines or devices; Accessories
- B24B37/11—Lapping tools
- B24B37/20—Lapping pads for working plane surfaces
- B24B37/24—Lapping pads for working plane surfaces characterised by the composition or properties of the pad materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24B—MACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
- B24B37/00—Lapping machines or devices; Accessories
- B24B37/11—Lapping tools
- B24B37/20—Lapping pads for working plane surfaces
- B24B37/26—Lapping pads for working plane surfaces characterised by the shape of the lapping pad surface, e.g. grooved
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/30—Organic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/30—Organic materials
- B23K2103/42—Plastics other than composite materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
- B23K2103/50—Inorganic materials other than metals or composite materials
Definitions
- the present invention relates to a method for processing a polishing pad for a semiconductor wafer and a polishing pad for a semiconductor wafer having grooves, recesses, through holes, etc. formed on the polishing surface side of the polishing pad by the method. More specifically, the present invention relates to a method of processing a polishing pad for a semiconductor wafer for forming an annular groove, a lattice-like groove, a spiral groove, a large number of concave portions, through holes, and the like on a polishing surface side.
- the polishing pad for a semiconductor wafer obtained by this method is used for chemical mechanical polishing of a semiconductor wafer or the like (hereinafter also referred to as “CMP”). Background art
- Polishing pads made of resin are often used for CMP processing of semiconductor wafers.
- an annular groove, a lattice-shaped groove, a spiral groove, or the like may be provided on the polishing surface side of the polishing pad for the purpose of holding a CMP slurry, temporarily storing polishing waste, and the like.
- This groove is formed by a method such as cutting or molding, and various improvements have been made in each method (for example, Japanese Patent Application Laid-Open No. 2002-11630).
- an annular groove is machined using a machining device having a lathe function, and the machining is performed by cutting a rotary plate into the groove with a positioning mechanism that sends the polishing pad in the groove pitch direction.
- Grooves of various shapes have high dimensional accuracy, low internal surface roughness, and homogeneity in order to uniformly polish the surface of the semiconductor wafer by CMP and obtain a polished surface with excellent flatness etc.
- CMP chemical mechanical polishing
- for conventional polishing pads made of resin foam fine cutting in the depth direction of the groove even when cutting using the processing equipment described above is performed. It is not easy to perform embedding.
- the polishing pad is not so thick, it may not be possible to form an annular or lattice-shaped groove having high dimensional accuracy such as width and depth on the entire surface thereof. Further, there is a problem that the surface roughness force S of the inner surface of the groove of the polishing pad after cutting increases.
- Japanese Patent Application Laid-Open No. 2001-186164 discloses a processing tool for forming a groove on the surface of a polishing pad made of a conventional resin foam. Disclosure of the invention
- the present invention solves the above-mentioned conventional problems.
- the polishing pad side of a specific composition which is not a resin foam, has a small surface roughness of an inner surface such as a groove and a high dimensional accuracy.
- a method of processing a polishing pad for a semiconductor wafer capable of forming grooves, recesses, through holes, and the like having a uniform cross-sectional shape, and generation of scratches and dishing when grooves are processed by this method and used in CMP. It is an object of the present invention to provide a polishing pad for a semiconductor wafer in which the polishing rate is suppressed.
- An object of the present invention is to achieve a polishing pad for a semiconductor wafer having a water-insoluble matrix containing a crosslinked polymer and water-soluble particles dispersed in the water-insoluble matrix.
- the polished surface is processed to form at least one kind of portion selected from a groove, a concave portion, and a guest hole whose inner surface has a surface roughness of 20 m or less.
- a polishing portion (polishing surface) of a solid polishing pad which is not a foam, is processed to form various shapes of grooves, concave portions and guest holes.
- the polishing pad processed in the present invention has the following properties on its polishing surface. That is, pores having a function of holding slurry during polishing and temporarily retaining polishing wastes are formed on the polished surface by the time of polishing. Therefore, the polishing pad processed in the present invention comprises a water-insoluble matrix and this water-insoluble matrix. And water-soluble particles dispersed in the elixir. The water-soluble particles come into contact with the slurry (aqueous dispersion containing a medium and a solid) during polishing, and are dissolved or swelled by the aqueous medium and desorbed. Then, the slurry is held in the pores formed by the desorption. Since this polishing pad is not a porous body (foamed body), its hardness and compressive strength are extremely large. When this polishing pad is processed, its surface roughness is extremely small and its dimensional accuracy can be further improved.
- the material constituting the "water-insoluble matrix” is not particularly limited, but is usually an organic material because it can be easily formed into a predetermined shape and property, and can impart appropriate hardness, appropriate porosity, and the like. Is used.
- the organic material include a thermoplastic resin, an elastomer, a rubber, and a curable resin (a thermosetting resin, a photocurable resin, etc., a resin cured by heat, light, or the like). More than one species can be used in combination.
- thermoplastic resins include 1,2-polybutadiene resin, ethylene-vinyl acetate copolymer, polyolefin resin such as polyethylene, polystyrene resin, polyacrylic resin ⁇ (meth) acrylate resin, etc. ⁇ , Vinyl ester resins (excluding acrylic resins), polyester resins, polyamide resins, fluororesins such as polyvinylidene fluoride, polycarbonate resins, and polyacetal resins.
- Elastomers include gen-based elastomers such as 1,2-polybutadiene, polyolefin-based elastomers (TPO), styrene-butadiene-styrene block copolymer (SBS), and hydrogenated block copolymers (SEBS)
- TPO polyolefin-based elastomers
- SBS styrene-butadiene-styrene block copolymer
- SEBS hydrogenated block copolymers
- Thermoplastic elastomers such as styrene-based elastomers, thermoplastic polyurethane-based elastomers (TPU), thermoplastic polyester-based elastomers (TPEE), polyamide-based elastomers (TPAE), etc., silicone-based elastomers — And fluorine-based elastomers.
- the rubber examples include conjugated rubbers such as butadiene rubber (high cis butadiene rubber, low cis butadiene rubber, etc.), isoprene rubber, styrene-butadiene rubber, styrene-isoprene rubber, etc., and acrylonitrile-butadiene rubber. Trityl rubber, acrylic rubber, ethylene-propylene rubber, ethylene-pro Other rubbers such as ethylene-Q-butane rubber and butyl rubber, such as pyrene-based rubber, and silicone rubber and fluorine rubber.
- conjugated rubbers such as butadiene rubber (high cis butadiene rubber, low cis butadiene rubber, etc.), isoprene rubber, styrene-butadiene rubber, styrene-isoprene rubber, etc., and acrylonitrile-butadiene rubber. Trityl rubber, acrylic rubber, ethylene-propylene rubber, ethylene-
- the durable resin examples include urethane resins, epoxy resins, acrylic resins, unsaturated polyester resins, polyurethane-urea resins, urea resins, silicon resins, phenol resins, vinyl ester resins, and the like. Is mentioned.
- these organic materials may have a functional group such as an acid anhydride group, a propyloxyl group, a hydroxyl group, an epoxy group, and an amino group.
- a functional group such as an acid anhydride group, a propyloxyl group, a hydroxyl group, an epoxy group, and an amino group.
- organic materials can be used alone or in combination of two or more.
- the water-insoluble matrix only needs to contain at least a crosslinked polymer. Therefore, these organic materials may be crosslinked polymers in which all are crosslinked, some may be crosslinked polymers, and the rest may be non-crosslinked polymers.
- a polishing pad By containing a cross-linked polymer, a polishing pad has a soft recovery force, and displacement due to shear stress applied to the polishing pad during polishing can be suppressed to a small value. Further, it is possible to effectively prevent the water-insoluble matrix from being excessively stretched during polishing and dressing, resulting in plastic deformation and filling of the pores, and excessive polishing of the polishing pad surface.
- the method of crosslinking is not particularly limited, and the crosslinking can be carried out by chemical crosslinking using an organic peroxide, sulfur, a sulfur compound or the like, radiation crosslinking by electron beam irradiation or the like.
- an organic peroxide is preferred because impurities such as sulfur are disliked in semiconductor polishing.
- organic peroxide examples include dicumyl peroxide, di-tert-butyl peroxide, getyl peroxide, diacetyl peroxide, diacyl peroxide, and the like. These can be used alone or in combination of two or more.
- the amount of the crosslinking agent used is preferably 5% by mass or less, more preferably 0.01 to 4% by mass, and particularly preferably 0.1% by mass based on the crosslinking polymer. 33% by mass.
- the cross-linked polymer among organic materials, cross-linked rubber, cured resin, cross-linked thermoplastic resin, cross-linked elastomer, and the like can be used.
- a crosslinked thermoplastic resin and a crosslinked elastomer are preferable because they are stable to strong acids and strong alkalis contained in many slurries and have little softening due to water absorption.
- crosslinked thermoplastic resin crosslinked 1,2-polybutadiene (hereinafter, referred to as “crosslinked PBD”) and a crosslinked ethylene-vinyl acetate copolymer (hereinafter, referred to as crosslinked EVAJ) are preferably used.
- crosslinked thermoplastic resins and crosslinked elastomers those crosslinked using an organic peroxide are particularly preferable.
- the content of these crosslinked polymers is 100% by mass, preferably 15% by mass or more, more preferably 20% by mass or more, and particularly preferably 30% by mass when the entire water-insoluble matrix is 100% by mass. % Or more.
- the entire water-insoluble matrix may be made of a crosslinked polymer (100% by mass of the crosslinked polymer). If the content of the crosslinked polymer in the water-insoluble matrix is less than 15% by mass, the effect of containing the crosslinked polymer may not be sufficiently exhibited.
- the water-insoluble matrix containing the cross-linked polymer is the elongation remaining after breaking when a test piece made of the water-insoluble matrix is broken at 80 ° C in accordance with JISK6251.
- “Residual elongation at break”) can be set to 100% or less. In other words, the total distance between the marked lines after breaking is less than twice the distance between the marked lines before breaking.
- This residual elongation at break is preferably 30% or less, more preferably 10% or less, and particularly preferably 5% or less. In addition, it is usually 0% or more. If the residual elongation at break exceeds 100%, fine pieces scraped or elongated from the polishing pad surface during polishing and dressing tend to easily block the pores, which is not preferable.
- the “residual elongation at break” refers to a dumbbell-shaped No. 3 test piece, a tensile speed of 500 mmZ, a test temperature of 800 in accordance with JISK 6251 “Tensile test method for vulcanized rubber”.
- JISK 6251 Teensile test method for vulcanized rubber.
- cross-linked FBD, cross-linked EVA, etc. are used as the cross-linked polymer
- Surface roughness of the inner surface such as a groove can be easily reduced to 20 zm or less.
- the inner surface of the groove or the like has a surface roughness of 20 mm or less, in addition to being able to prevent scratching, it also functions as a groove, a concave portion or a through-hole, in particular, a function of distributing slurry to a polishing surface, and a method of discharging waste material to the outside. The function of discharging wastewater is more efficiently exhibited.
- grooves, recesses, or through holes of various shapes are formed by a processing device to be described later, grooves having particularly high dimensional accuracy and having a stable shape can be easily formed, and the entire surface thereof can be easily formed. A polishing pad with excellent flatness can be obtained.
- water-soluble particles are particles that are released from the water-insoluble matrix by coming into contact with the aqueous dispersion slurry in the polishing pad. This desorption may be caused by dissolving by contact with water or the like contained in the slurry, or may be caused by swelling and gelation containing the water or the like. Further, the dissolution or swelling may be caused not only by water but also by contact with an aqueous mixed medium containing an alcohol-based solvent such as methanol.
- the water-soluble particles have the effect of increasing the pressing hardness of the polishing pad in the polishing pad and reducing the amount of pressing into the workpiece by pressing. That is, for example, by containing water-soluble particles, the polishing pad processed in the present invention can have a Shore D hardness of 35 or more, more preferably 50 to 90, and still more preferably 6 to 90. 0 to 85, usually 100 or less. When the Shore D hardness is 35 or more, the pressure that can be applied to the material to be polished can be increased, and the polishing rate can be improved accordingly. In addition, high polishing flatness is obtained. Therefore, it is particularly preferable that the water-soluble particles are solid bodies capable of securing sufficient indentation in the polishing pad.
- the material constituting the water-soluble particles is not particularly limited, and examples thereof include organic water-soluble particles and inorganic water-soluble particles.
- Organic water-soluble particles include sugars (polysaccharides such as starch, dextrin and cyclodextrin, lactose, mannitol, etc.), celluloses (hydroxypropylcellulose, methylcellulose, etc.), proteins, polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid And salts thereof, polyethylene oxide, water-soluble photosensitive resin, sulfonated polyisulfonated polyisoprene copolymer and the like. You.
- examples of the inorganic water-soluble particles include those formed from potassium acetate, potassium nitrate, potassium carbonate, potassium hydrogen carbonate, potassium chloride, potassium bromide, potassium phosphate, magnesium nitrate, and the like. These water-soluble particles can be formed by using one of the above materials alone or in combination of two or more. Further, it may be one kind of water-soluble particles made of a predetermined material, or two or more kinds of water-soluble particles made of different materials.
- the average particle size of the 7l-soluble particles is preferably from 0.5 to 500 / m, more preferably from 0.5 to 100 m, and still more preferably from 1 to 50 zm. That is, the size of the pore is preferably from 0.1 to 500 m, more preferably from 0.5 to: L 00 m, and still more preferably from 1 to 50; im. If the average particle size of the water-soluble particles is less than 0.1 zm, the size of the pores formed will be smaller than the abrasive grains used, and it tends to be difficult to obtain a polishing pad that can sufficiently hold the slurry. On the other hand, if it exceeds 500 im, the size of the formed pores becomes excessively large, and the mechanical strength and the polishing rate of the obtained polishing pad tend to decrease.
- the content of the water-soluble particles is the sum of the water-insoluble matrix and the water-soluble particles.
- it When it is set to be 0. 0% by volume, it is preferably 0.1 to 90% by volume, more preferably 0.5 to 60% by volume, and still more preferably 1 to 40% by volume. If the content of the water-soluble particles is less than 0.1% by volume, pores are not sufficiently formed on the polishing surface of the polishing pad, and the polishing rate tends to decrease. On the other hand, when the content of the water-soluble particles exceeds 90% by volume, it tends to be difficult to sufficiently prevent the water-soluble particles present inside the polishing pad from swelling or dissolving. Also, it becomes difficult to maintain the mechanical strength at an appropriate value.
- the water-soluble particles are water-soluble only when exposed to the surface layer of the polishing pad, absorb moisture inside the polishing pad, and do not swell.
- the water-soluble particles can have an outer shell that suppresses moisture absorption in at least a part of the outermost part.
- the outer shell may be physically adsorbed to the water-soluble particles, may be chemically bonded to the water-soluble particles, or may be in contact with the water-soluble particles by both.
- Examples of a material forming such an outer shell include an epoxy resin, a polyimide resin, a polyamide resin, and a silicone resin. The outer shell is formed only on a part of the water-soluble particles. However, the above effect can be sufficiently obtained.
- the polishing pad to be processed in the present invention includes a water-insoluble matrix and water-soluble particles, but may contain other compounding agents as necessary.
- the compounding agent include a compatibilizer, a filler, a surfactant, an abrasive, a softener, an antioxidant, an ultraviolet absorber, an antistatic agent, a lubricant, and a plasticizer. These may be one kind of each, or two or more kinds of each.
- the affinity between the water-insoluble matrix and the water-soluble particles and the dispersibility of the water-soluble particles in the water-insoluble matrix can be controlled.
- the compatibilizer include a water-soluble polymer having two or more functional groups selected from an acid anhydride group, a hydroxyl group, a hydroxyl group, an epoxy group, an oxazoline group, and an amino group in one molecule. And a coupling agent.
- the rigidity of the polishing pad can be improved.
- the filler include calcium carbonate, magnesium carbonate, talc, and clay.
- surfactant examples include cationic, anionic and nonionic surfactants.
- examples of the cationic surfactant include J3 aliphatic amine salt, aliphatic ammonium salt and the like.
- examples of the anionic surfactant include fatty acid salts, carboxylate salts such as alkyl ether carboxylate salts, sulfonic acid salts such as alkyl benzene sulfonate, alkyl naphthylene sulfonic acid, and Hiichisa refin sulfonate.
- sulfuric acid ester salts such as higher alcohol sulfates, alkyl ether sulfates, and polyoxyethylene alkylphenyl ether sulfates
- phosphate ester salts such as alkyl phosphate esters.
- nonionic surfactants include ether type such as polyoxyethylene alkyl ether, ether ester type such as polyoxyethylene ether of glycerin ester, polyethylene glycol fatty acid ester, glycerin ester and sorbine ester. Ester type and the like can be mentioned.
- abrasive grains examples include particles made of silica, alumina, ceria, zirconia, titania, and the like.
- water can be used instead of the slurry for chemical mechanical polishing.
- the oxidizing agent examples include hydrogen peroxide, peracetic acid, perbenzoic acid, organic peroxides such as tert-butyl diperoxide, permanganate compounds such as potassium permanganate, and dichromic acid.
- Dichromic acid compounds such as potassium; halogenic compounds such as potassium iodate; nitric compounds such as nitric acid and iron nitrate; perhalogen oxide compounds such as perchloric acid; persulfates such as ammonium persulfate; And heteropoly acids.
- hydrogen peroxide and organic peroxides whose decomposition products are harmless, and persulfates such as ammonium persulfate are particularly preferable.
- Examples of the above scratch inhibitor include biphenol, piperidyl, 2-vinylpyridine, 4-vinylpyridine, salicylaldoxime, ⁇ -phenylenediamine, m-phenylenediamine, catechol, o-aminophenol, thiourea, and N— Alkyl group-containing (meth) acrylamide, N-aminoalkyl group-containing (meth) acrylamide, 7-hydroxy-5-methyl-1,3,4-triazaindolidin, 5-methylene 1H-benzotriazole, phthalazine, melamine, 3-amino-5,6-dimethyl-1,2,4-triazine and the like.
- the above-mentioned pH adjuster is a component other than the above-mentioned compounding agents, and is a component which shows acidic or alkaline when contacted with water.
- Examples of the pH adjustment ⁇ ] include an acid, ammonia, and a hydroxide of an alkali metal.
- the acid examples include an organic acid and an inorganic acid.
- the organic acids include, but are not limited to, toluenesulfonic acid, dodecylbenzenesulfonic acid, isoprenesulfonic acid, gluconic acid, lactic acid, citric acid, tartaric acid, malic acid, glycolic acid, malonic acid, formic acid, oxalic acid, and succinic acid.
- Fumaric acid maleic acid, phthalic acid and the like.
- examples of the inorganic acid include nitric acid, hydrochloric acid, and sulfuric acid. These can be used alone or in combination of two or more.
- alkali metal hydroxide examples include sodium hydroxide, potassium hydroxide, rubidium hydroxide, cesium hydroxide and the like.
- the shape of the polishing pad to be processed is not particularly limited, but may be a disk shape, a belt shape, a mouth shape, or the like.
- the size of the polishing pad is not particularly limited, For example, in the case of a disk-shaped polishing pad, it is preferable that the diameter is 0.5 to 500 cm and the thickness is more than 0.1 mm and 100 mm or less.
- the method for obtaining such a polishing pad is not particularly limited.
- a polishing pad composition to be used as a polishing pad is obtained in advance, and this composition can be formed into a desired shape and processed into a polishing pad.
- the method for obtaining the composition for a polishing pad is not particularly limited, either, but it can be obtained by kneading a polymer that forms a water-insoluble matrix, water-soluble particles, and other additives with, for example, a kneader. .
- a kneader can be used.
- a kneading machine such as a roll, a mixer, a Banbury mixer, and an extruder (single-screw, multi-screw) can be used. It is to be noted that usually the kneading is carried out by heating to knead so as to facilitate processing, but it is preferable that the water-soluble particles are solid at the temperature at this time.
- the water-soluble particles can be dispersed at the above-mentioned preferable average particle size regardless of the degree of compatibility with the water-insoluble matrix. Therefore, it is preferable to select the type of the 7-soluble particles according to the processing temperature of the water-insoluble matrix to be used.
- grooves or the like can be formed on the polishing surface of the polishing pad by a processing method such as cutting (including turning) and laser processing. Of these, cutting is preferred.
- a circular table in which a horizontal suction face plate for mounting a polishing pad and adsorbing the polishing pad is provided so that the suction I hole communicates with the hole of the hollow center shaft;
- a drive mechanism that rotates the circular table and performs indexing and positioning; and a gantry-type column that is provided on the bed so that the crossrail can move in the X-axis direction perpendicular to the Z-axis across the circular table.
- a drive motor for moving and positioning each of the circular table, the gantry type column, the two saddles and the two turrets;
- a processing device comprising: a numerical controller that controls the drive motor;
- the crossrail is orthogonal to the Z-axis and the X-axis. It has one saddle mounted so as to be movable in the Y-axis direction, and is mounted on the saddle so as to be independently movable in the Z-axis direction, with the rotating tool on one side and the fixed tool on the other side.
- a processing device that is mounted on the saddle so as to be movable in the Z-axis direction and has one tool rest that can exchange a rotary tool and a fixed tool can be used.
- This processing apparatus can include the following components.
- Rotating tools groove milling cuts, drilling, etc.
- Figures 1 (a), (b) and (c) show the overall configuration of the device.
- the horizontal circular table 1 and bed 2 controlled by the C-axis have first and second horizontal guides 32 and 33 connected by cross rails 31. Guided by 41, 42.
- this device enables the gantry-type column 3 that is X-axis controlled by the synchronously driven screw shafts 51 and 52, and the two saddles 61 and 62 placed on the cross rail 31 to be commonly movable.
- screw shafts 53 and 54 parallel to the second guide for controlling each of them in the Y-axis. Further, there are provided motors 8 1, 8 2 for driving the tool rests 7 1, 7 2 placed on the saddles 6 1, 6 2 in the axial direction by screw shafts 5 5, 5 6. .
- FIG. 2 shows the cross section of the circular table 1 and the housing ⁇ , and the arrangement of the drive section of the circular table 1 and the suction blower 10 for generating a negative pressure for sucking the polishing pad 9 on the upper surface of the circular table 1.
- FIG. 3 shows a cross-section of a fixed member for positioning the index position of the circular table 1 before machining a groove or the like after the position of the circular table 1 is indexed by C-axis control.
- FIG. 4 shows an air flow path engraved on the circular table 1 in order to make the suction effect uniform.
- FIG. 5 shows the suction surface plate 11 of the circular table 1.
- the polishing pad 9 is uniformly sucked from the back surface, and the fine grooves and the through-holes are formed so that the polishing pad is not deformed by the stress at the time of processing the groove and the like.
- 2 shows the suction face plate 11 provided with the following.
- the circular table 1 in which the upper surface is covered with a suction surface plate 11 provided with air holes and grooves for sucking and fixing the polishing pad 9 and having a space formed therein, has a hole 1 in the shaft core.
- the end face of the hollow center shaft 12 through which air can pass through 21 becomes larger in diameter toward the top, and is supported and fixed integrally by its flange surface.
- the hollow center shaft 1 and 2 are fixed to the housing ⁇ by selecting the type, dimensions and accuracy class of the upper bearing and the lower bearing in order to reduce the runout of the outer diameter and the end face of the circular table 1.
- the housing ⁇ ⁇ is fixed to the bed 2.
- the hollow central shaft 12 is driven by a motor 83 for C-axis control, which is fixed to a seat with a conductive material attached to the lower end of the shaft.
- This drive may be performed by pulleys or by gears, or may be conducted by gears.
- the space between the blower 10 provided in the bed 2 and the lower end hole of the hollow central shaft 12 is set in a seat.
- the coupling is supported by a coupling 101 supported by a mounted support and a hose 102.
- the circular table 1 is indexed at a predetermined position by C-axis control, and is fixed at a predetermined position before machining a groove or the like. Therefore, the position is determined by the sensor 1 2 4 fixed to the protrusion 1 2 3 on the rotating disk 1 2 2 fixed to the hollow central shaft 1 2 Detect (see Figure 2).
- the position of every 45 ° can be detected by the arrangement of the sensors 124, and the machining is performed at a 90 ° turning position.
- a position fixing member 125 a bushing 126 with a tapered hole for positioning is provided at the indexing position on the lower surface of the circular table 1, and a tapered shaft 127a is provided at the tip on the bed 2.
- Positioning is performed using piston members 1 2 7.
- This biston member may be pneumatic, hydraulic, or electromagnetic.
- FIG. 4 shows the top surface of the circular table.
- the circular table 1 is preferably made of a light metal, such as an aluminum alloy, which is not easily thermally deformed so as to be able to start and stop quickly and to prevent distortion due to aging.
- the circular table 1 is provided with a plurality of air communication holes 1a that communicate with the hollow central shaft.
- the suction force decreases as the distance from the center of the hollow central shaft in the outer diameter direction decreases, so that the center side conduction groove 1b is wider than the outer conduction groove 1c so that the suction force reaches the outer edge region equally. It has been processed.
- the air conduction grooves Id are provided concentrically with different radii and are connected by radial conduction grooves 1b and 1c.
- FIG. 5 shows the suction face plate 11.
- (A) is a top view, and (b) is an enlarged sectional view of a suction hole and the like.
- suction holes 11a are uniformly formed on the upper surface of the P-contact surface plate 11, and the polishing pad 9 is sucked and fixed there.
- the suction face plate 11 is provided with suction holes 11a uniformly with a substantially equal pitch between the holes, and the diameter of the holes is determined by the thickness of the polishing pad so that the polishing pad 9 is not deformed by the suction force. The number is set.
- a conductive groove 11b connecting the adjacent suction holes 11a is provided on the upper surface of the P-faced plate 11, and the suction force is averaged.
- Fig. 6 (a) shows a front view of a gantry-type column 3 which is guided by a pair of first guides 41, 42 provided on a bed 2 with a center circular table 1 interposed therebetween, and is axially controlled. ) Shows the side of the gantry column 3.
- Fig. 7 (a) shows a pair of first guides 41 and 42 for guiding the gantry-type column 3 in the X-axis direction, and a pair of screw shafts whose axes are controlled.
- a plane showing the arrangement of 51 and 52, and (b) shows a side surface of a transmission system that controls the rotation of the pair of screw shafts 51 and 52 with one belt.
- a gantry-type column 3 composed of a right column 32, a left column 33, and a cross rail 31 is attached to the outside of a circular tray 1 provided at the center of the bed 2. It is composed of a right column 32 guided by a first guide 41 in parallel with the door 2 and a cross rail 31 erected between a left column 33 guided by a first guide 42. Further, in the side view of FIG. 6 (b), the gantry type column 3 is guided by a pair of first guides 41 and 42, and is movable on the circular table 1 in the X-axis direction.
- the gantry type column 3 can be integrally formed by welding or metal.
- Fig. 7 (a) is a plan view showing the upper surface of the X-axis guide of the gantry type column 3,
- FIG. 7 (b) is a rear view of the machine showing the X-axis drive system.
- a gland type column is formed by a screw shaft 51, a pole nut 21 and a screw shaft 52 and a ball nut 22 provided in parallel with the first guides 41 and 42 on the bed 2.
- 3 are guide rollers 38a, 38b via pulleys 35a, 36b, which are keyed to a pair of screw shafts 51, 52 from a pulley 35, , 39 Tension is adjusted and synchronous rotation is performed.
- the X-axis direction drive of the gantry type column 3 can also be performed by performing synchronous control operation of separate motors directly connected to the respective screw shafts.
- FIG. 6 (a) shows the front of the cross rail 31, which is shared by a pair of second guides in the Y-axis direction orthogonal to the Z-axis and the X-axis, and each position is controlled by a motor. Shows the front of the saddle of the system.
- Fig. 8 (a) is provided on the lower surface of the saddles 61 and 62 in Fig. 6 (a), and includes the second guides 43 and 44 for guiding the saddle, the screw shaft 54 and the saddle 62 for driving the saddle 61.
- FIG. 6 is a front view showing an arrangement of a driving screw shaft 53 with saddles 61 and 62 removed.
- FIG. 8 (b) is a front view of a conductive member relating to a motor M1 for controlling the Y-axis which drives the screw shaft 53 and a motor M2 for controlling the Y-axis which drives the screw shaft 54.
- the second guides 43 and 44 are provided in parallel on the side surface of the cross rail 31. Also provided on the underside of each of the saddles 61 and 62 The four linear bearings 37 guide the saddle in the Y-axis direction. Similarly, screw shafts 5 3 and 5 4 are provided on the side in parallel with the second guides 4 3 and 4 4, and each is driven by a motor (Y 1 axis) M 1 and a motor (Y 2 axis) M 2 Is done. Each rotation is screwed with each screw shaft 53, 54, and Y 1 axis control and ⁇ 2 axis control are individually performed by nuts 38a, 38b fixed to the lower surface of each saddle.
- the saddles 61 and 62 are controlled so as not to interfere. That is, when the types of the tools installed on the tool rests 71 and 72 provided on the saddle are different, either one of the saddles 61 and the saddle 62 is driven.
- a right tool post 71 is shown on the right saddle 61 on the side surface of the cross rail 31, and a left tool post 72 is shown on the left saddle 62.
- the rotating tool and the fixed tool are provided on the left and right turrets
- the same kind of tools with different cutting edge dimensions can be provided on the left and right turrets.
- the gantry type column 3 moves in the X-axis direction with the first guides 41 and 42
- the left saddle 62 moves in the Y-axis direction with the second guides 43 and 44
- the mode for controlling the position of the C-axis, X-axis, Y-axis and Z-axis in the polishing pad processing equipment is controlled by the numerical controller. Accurate and smooth positioning, incision and feed of minute units are commanded, and synchronization between axes is automated according to the machining program.
- the numerical controller pre-stores basic patterns such as grooves to be processed on the polishing pad, and specifies the corresponding pattern from those basic patterns to create a control axis work program and perform automatic processing. be able to.
- general control can be performed by sequencer control. In the case of the sequencer control, there is a limit in the level of permissible accuracy with respect to the position control and the feed or cut, but the apparatus configuration can be simplified and the cost can be reduced.
- a polishing pad When a polishing pad is cut, it is charged by friction and cutting powder is applied to the polishing pad etc. It adheres, and it is not easy to remove with only an air pro. Since resin, rubber, and the like are negatively charged, in the present invention, positive ions generated by corona discharge or the like can be neutralized by colliding with a polishing pad or the like during processing to remove cutting powder.
- the charging level of the polishing pad, etc. is easily affected by the material, hardness, processing conditions, room temperature and humidity, etc., but usually includes ions required for neutralization, assuming that processing conditions are kept constant. Air is blown to a polishing pad or the like. When multiple grooves are formed at the same time by arranging bytes in parallel, such as with a multi-blade tool, ions are evenly sprayed at the location where the cutting powder is generated, and almost all the cutting powder is efficiently removed. can do.
- Fixed tools include single and multi-edge tools for turning.
- Either a single-edged tool (bite) or a multi-edged tool can be used to machine an annular concentric groove.
- the blade width, cutting edge angle, rake angle, front clearance angle and side clearance angle of the cutting edge of the cutting tool can be appropriately selected depending on the material of the polishing pad and the like.
- a multi-edged tool with the same cutting edge as a single-edged tool and arranged side by side is used by mounting it on a tool post, machining efficiency will be greatly improved.
- the cutting device mounted on the tool post on the saddle is driven in the Z-axis direction by a drive source such as a piston cylinder, and cutting is performed by feeding the tool post.
- Rotary tool unit (groove milling cutter, drill)
- the blade angle, rake angle, blade width, and side cutting edge angle of the groove milling cutter can be appropriately selected according to the material of the polishing pad.
- the milling cutter may be used alone to machine each groove, or a unit tool in which a plurality of milling cutters are stacked at a predetermined pitch may be used. In the latter case, the processing efficiency can be greatly improved.
- the diameter of the drill, the length of the drill, and the number of cutting edges can be appropriately set depending on the shape of the groove and the like, the depth, and the like. If the cone angle at the tip of the drill is set to 55 to 65 °, the penetration of the cutting edge into the polishing pad becomes smooth.
- the polishing pad is preferably cut in advance into a disk having the same size as the suction face plate. If grooves are to be formed on a polishing pad smaller in diameter than the suction face plate, an annular disk should be formed in advance using the same material as the polishing pad and used to close unnecessary holes in the suction face plate. .
- the suction hole can be formed only in the portion of the suction face plate necessary for suction, and the suction area can be divided by partially blocking the conduction groove of the circular table inside.
- the polishing pad After placing the polishing pad, rotate the suction blower to fix the polishing pad, and input the C-axis rotation value in advance so that the turning speed is constant during the inner and outer peripheral processing of the polishing pad. Then, control the X axis position with the gantry type column, the Y 1 axis position with the right saddle, and the Z 1 position with the right turret, and move them to the initial position. Next, the diameter position of the concentric circle is input so as to be positioned on the Y1 axis by the number of the concentric circles, and the cutting amount of the cutting tool is programmed on the Z axis of the tool post. Preparation is completed by these inputs.
- the circular take-up is driven at a predetermined rotation speed, and the cutting of the byte is started.
- the machining of one concentric groove is completed by performing a small amount of incision a predetermined number of times.
- the right turret and the right saddle are sequentially moved to continue processing other concentric grooves, thereby forming grooves having a predetermined width, a predetermined number of lines, and the like.
- the cutting powder scatters and adheres to the tool, the inside of the machined groove, the upper surface of the polishing pad, and the like, and cannot be easily collected by an air pro alone. Therefore, it is preferable to provide an ion pro nozzle for removing cutting powder in the vicinity of the cutting blade, and to spray charged ions of opposite polarity to the polishing pad, the cutting powder and the blade in order to neutralize static electricity.
- the surface roughness (R a: hereinafter, referred to as “surface roughness”) of the inner surface of the groove or the like is set to 20 by sufficiently fixing the polishing pad using a specific processing table. im or less, more preferably 15 m or less, and still more preferably Preferably it can be 1 or less.
- a groove or the like with high dimensional accuracy can be formed. For example, if the target value of the groove width (in the case of a concave part, the minimum dimension in the planar direction) is 0.1 mm, the dimensional accuracy can be set to ⁇ 10% of the target value. . Further, when the target value of the depth of the groove or the concave portion is 0.1 mm, the accuracy can be set to ⁇ 10% with respect to the target value.
- groove spacing in the case of a concave part, the minimum dimension in the planar direction
- the target value of (the minimum distance between adjacent parts in the radial direction in a spiral groove or concave portion, etc.) is 0.05 mm, accuracy of ⁇ 10% can be achieved with respect to this target value.
- the pitch (described below), which is the sum of the width of the groove and the distance between adjacent grooves, is 0.15 mm, an accuracy of ⁇ 10% with respect to this target value shall be used. Can be.
- the target value is increased in any of the width, the depth, the interval, and the pitch, the dimensional accuracy can be further increased.
- the above surface roughness (Ra) is defined by the following formula (1).
- Each surface roughness is measured using a measuring instrument or the like that can measure the surface roughness in three different visual fields such as grooves of the polishing pad before use. It is the average value obtained by measuring the roughness and calculating from the three average surface roughness values obtained.
- Z is the height of the roughness surface
- Z a V is the average height of the roughness surface
- N is the number of measurement points.
- the above measuring device is not particularly limited.
- an optical surface roughness measuring device such as a three-dimensional surface structure analysis microscope, a scanning laser microscope, an electron beam surface morphology analyzer, and a contact surface roughness.
- a contact-type surface roughness measuring instrument such as a meter can be used.
- the dimensional accuracy can be obtained as an average value of three points measured for each of the width, the depth, the interval, and the pitch using a loupe with a scale, a set of laser three-dimensional measuring devices, or the like.
- a multi-flute turning tool for example, 10 to
- Efficient machining can also be performed using unit tools with 30 cutting tools arranged side by side.
- processing tool described below it is possible to obtain a polishing pad that is more excellent in accuracy with respect to a desired dimension.
- a milling cutter may be used in the above-described method, but a processing tool including a multi-blade unit having a plurality of blades protruding therefrom and a holder for fixing the multi-blade unit May be used.
- the “blade” (for example, B1 shown in FIG. 9) is a part of the multi-blade unit, and can form one groove on the polishing surface of the polishing pad with one blade.
- the blade angle (in FIG. 9) is preferably 15 to 50 °, more preferably 20 to 50 °, and further preferably 25 to 50 °.
- a °, front clearance angle (0 in Fig. 9 2) is preferably 65 to 20 °, is more favorable Mashiku is 60 to 20 °, more preferably fifty-five to twenty-five °, and, formed to the inner wall of the groove horizontal clearance angle abutting blade (0 in Fig. 9 3) is preferably 1 to 3 °, more preferably 1.
- the groove can be formed without the inner wall of the groove being peeled by the blade, and the surface roughness in the obtained groove can be suppressed to 20 / m or less.
- a sharp groove can be obtained with higher precision than in a case where the groove is formed by die molding, without the corners of the groove being rounded.
- both ends of the cutting edge of the blade contact the polishing pad at least at the start of cutting. Therefore, the cutting edge may have a curved shape such that the center portion is depressed with respect to both ends.
- the size of the blade is not particularly limited, and can be appropriately set in accordance with the size of the groove to be formed.
- the width of the blade is 0.1 to 10% wider than a desired groove width. It is preferable that More preferably, it is 1 to 7% wider, and still more preferably, it is 2 to 5% wider.
- the length of the blade is preferably 10 to 300% longer than the desired groove depth. It is more preferably 20 to 200% longer, and still more preferably 10 to 100% longer.
- the size of the groove is 0.1 mm or more (preferably 0.1-5 mm, more preferably 0.2-3 mm) and the depth is 0.1 mm or more (preferably 0.1-0.5 mm). 2.5 mm, more preferably 0.2-2. Omm), the width of the blade (L in FIG. 9) is preferably 0.1 mm or more, more preferably 0.15-5 25 mm, more preferably 0.2 to 3.15 mm, and the blade Is preferably 0.1 lmm or more, more preferably 0.11 to 7.5 mm, and even more preferably 0.26 to 4.0 mm.
- the material constituting the blade is not particularly limited, and for example, carbon steel, alloy steel, high-speed steel, cemented carbide, cermet, stellite, ultra-high pressure sintered body, other ceramics, and the like can be used.
- the “multi-blade unit” (for example, B 2 in FIGS. 10 to 14) has a plurality of the blades.
- This multi-blade unit can be a plate-like unit in which the blade is integrally formed on the main body as shown in FIG. Further, as shown in FIG. 11, the blades may be integrated using a fixture (such as a port B41 and a holding plate B42) so that the blades are aligned in the cutting direction. In this integration, as shown in FIG. 12, the distance between the adjacent cutting edges can be adjusted through a spacer or the like.
- the number of blades protruding from one multi-blade unit is not particularly limited, and may be two or more, for example, five or more, more preferably ten or more, and especially fifteen or more (usually 50 or less).
- the distance between the adjacent blades is not particularly limited. Normally, the force is preferably 0.05 mm or more. In some cases, it may be difficult to maintain the wall between the grooves.
- the blades are protruded from the multi-blade unit so that the distance between adjacent blades is 0.05 to 10 Oram. More preferably, it is further preferable that the projection is provided so that the distance between adjacent cutting edges is 0.1 to 10 mm.
- the pitch of the cutting edges (the sum of the distance between the adjacent cutting edges and the cutting width) is not particularly limited.
- it may be 0.15 mm or more, more preferably 0.15 to 105 mm, further preferably 0.3 to 13 mm, particularly preferably 0.5 to 2.2 mm. It is preferable that the force S is provided on both ends of the multi-blade unit.
- the “holder” (for example, B 3 shown in FIGS. 11 to 13) fixes the multi-blade unit.
- the multi-blade unit fixed to the holder can be fixed using a fixture (for example, a port B41 or a holding plate B42 shown in FIGS. 11 to 13) so as to be removable.
- a fixture for example, a port B41 or a holding plate B42 shown in FIGS. 11 to 13
- Such detachability makes it difficult to obtain the desired cutting performance due to wear of the blade, etc., or forms different grooves.
- a stable groove can be formed by replacing only the multi-blade unit.
- the number of multi-blade units that can be fixed to one holder is not particularly limited, and may be one, or two or more.
- the multi-blade unit may be fixed horizontally (see Fig. 13) in the groove cutting direction, or vertically (multi-blade) in the cutting direction. Units may be fixed).
- the number of grooves that can be cut at one time can be increased.
- the number of grooves that can be cut at one time can be increased by arranging the blades of each multi-blade unit so that they do not overlap in the cutting direction.
- the distance between the multi-blade units in the vertical direction, which is parallel to the cutting direction, can be adjusted by inserting a spacer between the multi-blade units. it can.
- the holders with the multi-blade units fixed as described above are arranged side by side in the cutting direction and a plurality of holders are attached to the processing tool. Can be increased.
- the cutting speed when forming grooves in the polishing pad with the above processing tool is not particularly limited.
- the peripheral speed is 200 mZ
- the feed is 0.05 mm or less per revolution.
- the surface roughness of the inner surface of the groove or the like can be made 20 m or less, more preferably 15 m or less, and still more preferably 10 m or less.
- grooves can be cut and formed with excellent dimensional accuracy.
- the dimensional accuracy can be set to ⁇ 10% of the target value.
- the accuracy can be set to ⁇ 10% with respect to the target value.
- the target value of the groove interval is 0.05 mm, the accuracy can be set to ⁇ 10% with respect to the target value.
- the pitch which is the sum of the width of the groove and the distance between adjacent grooves and the like, is 0.15 mm, it is possible to achieve an accuracy of ⁇ 10% with respect to this target value.
- the target value is increased in any of the width, the depth, the interval, and the pitch, the dimensional accuracy can be further increased.
- the surface roughness of the inner surface such as grooves Is less than 20 / zm, which means that there are no large irregularities. If there are large irregularities, particularly large convex portions (for example, formed by uncut portions generated during the formation of grooves) are detached during polishing, which causes scratches. Further, foreign matter formed when the detached convex portion is compressed due to pressure, frictional heat, or the like during polishing, or the detached convex portion interacts with polishing debris, solid content in slurry, or the like. Scratch may also occur due to foreign matter formed by the process. Also, at the time of dressing, these projections may come off and cause similar problems.
- the surface roughness is 20 / m or less, in addition to preventing scratches, it also functions as a groove and the like, particularly, a function of distributing slurry to the polishing surface and a function of discharging waste to the outside. Is exhibited more efficiently.
- a groove can be formed in a polishing pad in which no groove is formed and a groove is not formed. Can be additionally formed. Thus, the polishing pad can be used without waste.
- the grooves and recesses formed as described above open to the polishing surface side of the polishing pad. These grooves and recesses hold the slurry supplied during polishing and have the function of distributing the slurry more evenly to the polishing surface. In addition, it has a function of temporarily retaining waste such as polishing waste and used slurry generated by polishing and serving as a discharge path for discharging the waste to the outside.
- the pattern shape of the groove may be an annular shape, a lattice shape, a spiral shape, or the like, and may be a dot-shaped concave portion. A pattern combining two or more of these shapes may be used.
- its planar shape is not particularly limited, and may be, for example, a circle, a polygon (a triangle, a square, a pentagon, etc.), an ellipse, or the like.
- the number of grooves is two or more, and the arrangement of these grooves is not particularly limited. For example, a plurality of grooves are arranged in a concentric sinusoidal shape (see FIG. 15). ), A plurality of grooves arranged eccentrically (see Fig.
- a polishing pad in which a plurality of grooves are arranged concentrically is preferable, and a polishing pad in which concentric circles are arranged (a state in which a plurality of circular grooves are arranged concentrically) is more preferable.
- the polishing pad in which the grooves are concentrically arranged is superior to the above-mentioned functions as compared with other polishing pads.
- the concentric shape further enhances these functions, and the groove can be easily manufactured.
- the cross-sectional shape of the groove is not particularly limited.
- the size may be large, and the bottom side may be larger than the opening side, and may be U-shaped, V-shaped, or the like.
- the grooves When the grooves are in a lattice shape, they may be formed by one continuous groove, or may be formed by two or more discontinuous grooves.
- the planar shape of one pattern forming the lattice is not particularly limited, and may be various polygons.
- the polygon may be, for example, a square such as a square (see FIG. 17), a rectangle, a trapezoid, a rhombus (see FIG. 18), a triangle (see FIG. 19), a pentagon, a hexagon, or the like.
- the cross-sectional shape of the groove can be the same as that of the annular shape.
- the groove When the groove is spiral, the groove may be formed by one continuous groove (see FIG. 20) or may be formed by two spiral grooves having different spiral directions. (See Figure 21). Further, the groove may be composed of two spiral grooves having the same spiral direction, or may be composed of three or more spiral grooves having the same or different spiral directions.
- the cross-sectional shape of the groove can be the same as in the case of a ring or the like.
- the planar shape of the concave portion is not particularly limited, but may be, for example, a circle, a polygon (a triangle, a square, a pentagon, etc.), an ellipse, or the like. Further, the arrangement of the openings of the concave portions on the polishing surface is not limited, but is preferably provided evenly over the entire polishing surface. As a specific example of the polishing pad having the concave portion, a polishing pad in which a circular concave portion is uniformly opened on the polishing surface (see FIG. 22) can be cited. On the other hand, the cross-sectional shape of the recess is not particularly limited.
- the shape formed by the flat side surface and the bottom surface (the dimensions in the cross-sectional direction of the opening side and the bottom side may be the same,
- the opening side may be larger than the bottom side, and the bottom side may be larger than the opening side.
- the size of the groove or the recess is not particularly limited.
- the width of the groove (the minimum dimension of the opening in the case of the recess, F12 in FIG. 23) is preferably 0.1 mm or more, more preferably 0.1 l or more. 55 mm, more preferably 0.2-3 mm. It may be difficult to form grooves or recesses with the above width or minimum dimension less than 0.1 mm.
- the depth of the groove or the concave portion is preferably 0.1 mm or more, more preferably 0.1 to 2.5 mm, and still more preferably 0.2 to 2.0 mm. If the depth of the groove or the concave portion is less than 0.1 mm, the life of the polishing pad is excessively shortened, which is not preferable.
- the minimum distance between adjacent grooves or recesses is preferably 0.05 mm or more, more preferably 0.05 to 10 Omm, and still more preferably 0.1 to 1 Omm. It may be difficult to form a groove or the like in which this minimum distance is less than 0.05 mm.
- the pitch (P11 in FIG. 23), which is the sum of the width of the groove and the distance between the adjacent grooves, is preferably 0.15 mm or more, more preferably 0.15 to 105 mm, and still more preferably 0.
- the width or the like is 0.1 mm or more
- the depth is 0.1 mm or more and the minimum distance is 0.05 mm or more
- the width is 0.1 to 5 mm
- the depth is 0.1 More preferably, the minimum distance is 0.05 to 100 mm, and the width is 0.2.
- the depth is 0.2 to 2.0 mm and the minimum distance is 0.2 mm.
- the through-holes are opened on both the polishing surface side of the polishing pad and the opposite surface.
- the planar shape and the cross-sectional shape of the through-hole can be the same as those of the recess.
- the dimension in the cross section direction of one opening side and the other opening side may be the same, the dimension on the polished surface side may be large, and the dimension on the opposite surface side may be large.
- the minimum size of the opening, and the minimum distance and pitch between adjacent through holes when a plurality of through holes are provided, can be the same as those of the recess.
- the preferred range of the minimum dimension of the opening and the minimum distance between adjacent through holes is 003/010125
- the minimum size of the opening is 0.1 mm or more, the minimum distance between the adjacent through holes is 0.05 mm or more, and the minimum size of the opening is 0.1 to 5 mm. mm, minimum distance between adjacent through holes is 0.
- the minimum dimension of the opening is 0.2 to 3 mm, and the minimum distance between adjacent through holes is 0.1 to 10 mm. Better.
- the polishing pad processed as described above has a support layer on the non-polishing surface side, and can be used as a multilayer polishing pad.
- the multi-layer type polishing pad has the following modes: (1) a polishing layer having a groove or a concave portion having a planar shape, a lattice shape, a spiral shape, or the like that is open on the polishing surface side; With a support layer,
- polishing layer having a through-hole having a circular shape or the like having a circular shape when opened on the polishing surface side, and a support layer disposed on the non-polishing surface side of the polishing layer; (3) an opening on the polishing surface side
- polishing layer having at least two portions selected from grooves, concave portions, and through holes, and a support layer disposed on the non-polishing surface side of the polishing layer.
- the above-mentioned polishing pad can be used as the above-mentioned polishing layer.
- the polishing layer is bonded or bonded to another layer such as a support layer on the back surface side, so that the slurry does not flow through the through hole without being subjected to polishing.
- the characteristics of the support layer are not particularly limited, but are preferably softer than the polishing layer. By providing a softer support layer, even if the thickness of the polishing layer is thin (for example, 5 mm or less), it prevents the polishing layer from floating during polishing and the surface of the polishing layer from being curved. Polishing can be performed stably.
- the hardness of the support layer is preferably 90% or less, more preferably 80% or less, particularly 70% or less, and usually 10% or more, based on the hardness of the polishing layer. Further, the Shore D hardness is preferably 70 or less, more preferably 60 or less, further preferably 50 or less, and usually 1 or more.
- the support layer may be a porous body (foam) or a non-porous body.
- the planar shape is not particularly limited, and may be the same as or different from the polishing layer. Good.
- the planar shape of the support layer can be, for example, a circle, a polygon (a square, etc.), or the like.
- the thickness is not particularly limited, but may be, for example, 0.1 to 5 mm (more preferably, 0.5 to 2 mm).
- the material constituting the support layer is not particularly limited, but it is preferable to use an organic material because it can be easily formed into a predetermined shape and property and can impart a strong property.
- an organic material constituting a water-insoluble matrix in the polishing pad can be used.
- the organic material constituting the support layer may be a crosslinked polymer or a non-crosslinked polymer.
- the support layer may include only one layer, or may include two or more layers. Further, the support layer and the polishing layer may be laminated in direct contact with each other, or may be laminated via another layer. Further, the support layer may be bonded to the polishing layer or another layer with an adhesive, an adhesive (a bonding layer such as an adhesive tape) or the like, and is integrally bonded by being partially melted. Is also good.
- the polishing pad and the multilayer polishing pad may be provided with an end point detection window or the like. ;! For example, at a thickness of 2 mm, a wavelength of 100 to 3
- the transmittance of light of any wavelength between 100 nm is 0.1% or more (preferably 2% or more), or any of the wavelengths between 100 nm and 300 nm.
- a member having an integrated transmittance of 0.1% or more (preferably 2% or more) in the above wavelength range can be used.
- FIG. 1 shows the overall configuration of the processing apparatus, wherein (a) is a front view, (b) is a plan view, and (c) is a side view.
- FIG. 2 shows a cross section of the circular table 1 and the eight housing 3 and an arrangement of a driving section of the circular table 1 and a suction blower 10 for generating a negative pressure for sucking the polishing pad 9 on the upper surface of the circular table 1. It is a schematic diagram.
- FIG. 3 is a schematic diagram showing a cross section of a fixed member that positions the indexing position of the circular table 1 after the circular table 1 is C-axis controlled and the position is indexed and before the groove processing.
- FIG. 4 is a plan view showing the air flow path engraved on the circular table 1.
- FIG. 5 shows the suction face plate 11 of the circular table 1.
- A) is a plan view.
- B) is an enlarged schematic view showing the suction holes 11a and the like.
- FIG. 6 shows a gantry-type column 3 guided and guided by a pair of first guides 41, 42 provided on a bed 2 with a central circular table 1 interposed therebetween.
- A is a front view.
- B is a side view.
- Fig. 7 (a) is a plan view showing the arrangement of a pair of first guides 41, 42 for guiding the gantry-type column 3 in the X-axis direction and a pair of screw shafts 51, 52 that are axially controlled. It is.
- (b) is a side view of the conduction system that controls the rotation of the pair of screw shafts 51 and 52 with one belt.
- FIG. 8 shows (a) a second guide 43, 44 for guiding the saddles 61, 62, a screw shaft 54 for driving the saddle 61, and a screw shaft 53 for driving the saddle 62.
- FIG. 3 is a front view showing the arrangement of the vehicle without the saddles 6 1 and 6 2.
- (B) is a front view of the conductive member according to the Y-axis control motor 35 for driving the screw shaft 53 and the Y-axis control motor 36 for driving the screw shaft 54.
- FIG. 9 is an explanatory diagram for explaining angles at various points of a blade used in the processing method of the present invention.
- FIGS. 10A and 10B are diagrams illustrating an example of a multi-blade unit and a holder used in the processing method of the present invention.
- FIG. 10A is a schematic front view
- FIG. 10B is a schematic side view. is there.
- FIGS. 11A and 11B are diagrams illustrating another example of a multi-blade unit and a holder used in the processing method of the present invention.
- FIG. 11A is a schematic front view
- FIG. 11B is a schematic side view. It is.
- FIGS. 12A and 12B are diagrams illustrating still another example of a multi-blade unit and a holder used in the processing method of the present invention.
- FIG. 12A is a schematic front view
- FIG. 12B is a schematic side view.
- FIG. 12A is a schematic front view
- FIG. 12B is a schematic side view.
- FIG. 13 is a schematic diagram illustrating an example of a multi-blade unit, a holder, and the like used in the processing method of the present invention.
- FIG. 14 is an explanatory diagram illustrating the arrangement of holders used in the processing method of the present invention.
- FIG. 15 is a plan view of a polishing pad in which an annular concentric groove is formed on the polishing surface side.
- FIG. 16 is a plan view of a polishing pad in which an annular groove is eccentrically arranged on the polishing surface side.
- FIG. 17 is a plan view of a polishing pad in which lattice-shaped grooves having a square planar shape are formed on the polishing surface side.
- FIG. 18 is a plan view of a polishing pad in which lattice-shaped grooves having a rhombic planar shape are formed on the polishing surface side.
- FIG. 19 is a plan view of a polishing pad in which lattice-shaped grooves having a triangular planar shape are formed on the polishing surface side.
- FIG. 20 is a plan view of a polishing pad in which one continuous spiral groove is formed on the polishing surface side.
- FIG. 21 is a plan view of a polishing pad in which two spiral grooves having different spiral directions are formed on the polishing surface side.
- FIG. 22 is a plan view of a polishing pad in which concave portions having a circular planar shape are uniformly opened on the polishing surface side.
- FIG. 23 is a schematic diagram of a partial cross section including a groove, a concave portion, or a through hole of a polishing pad. Explanation of reference numerals
- 1 Circular table, 1 a: Air conduction hole, 1 b: Center side conduction groove, 1 c: Outer conduction groove, 1 d: Air conduction groove, 11: Suction face plate, 11 a; Suction hole 12b: hollow central shaft, 121: hole in shaft core, 122: disk, 123: protrusion, 124; sensor, 125: position fixing member, 126; bush with taper hole, 11b; 127a; taper shaft, 127; piston member, 2; bed, 21, 22; ball nut, 3; gantry column, 31; cross rail, 32, 33; left and right columns, 3
- Uncrosslinked 1,2-polybutadiene manufactured by JSR Corporation, product name “JSR RB 830J” 70 parts by mass
- uncrosslinked ethylene vinyl acetate copolymer manufactured by Tosoh Corporation, product name “Ultracene 630”
- Temperature control of 160 parts by mass and 40 parts by mass of ⁇ -cyclodextrin, a water-soluble particle manufactured by Yokohama International Bio-Laboratory Co., Ltd., product name “Dexipearl iS-100”, average particle diameter 20 m) Using a twin screw extruder.
- the surface roughness of the inner surface of this groove was 4. ljLim, and the variation in surface roughness was small.
- the dimensional accuracy was excellent with a width of ⁇ 6%, a depth of ⁇ 5%, and a pitch of ⁇ 5%.
- the surface roughness was measured using a three-dimensional surface structure analysis microscope (manufactured by Canon Inc., model “Zy go New View 5 ° 32”). The same applies to the following.
- polishing performance of the grooved polishing pad was evaluated as follows.
- Polishing pad polishing equipment SFT, model "Lapmaster LM-15"
- the slurry for chemical mechanical polishing manufactured by JSR Corporation, trade name: “CMS 1101”
- CMS 1101 chemical mechanical polishing
- the polishing rate was measured before and after polishing by an optical meter, and was calculated from these film thicknesses.
- the scratches were confirmed by observing the polished surface of the polished SiO 2 film wafer with an electron microscope. As a result, the polishing rate was 35 OnmZ minutes, and almost no scratch was observed.
- Polishing time 5 ⁇ 75 minutes (15% over polish)
- a polishing pad of the same size was prepared in the same manner as in Example 1, and the average value of the groove width was 0.5 mm and the average depth of the groove was 0.5 mm on the polishing surface side of the polishing pad by the method described in the above [2].
- a plurality of annular grooves with an average value of lmm and an average pitch of 1 mm were formed concentrically.
- the surface roughness of the inner surface of this groove was 5.2 zm, and the variation in surface roughness was small.
- the dimensional accuracy was excellent with a width of ⁇ 4%, a depth of ⁇ 5%, and a pitch of ⁇ 5%.
- the polishing speed, the presence or absence of scratches, was evaluated. As a result, the polishing rate was 30 Onm / min, almost no scratching was observed, the dating was 6 Onm, and the polished surface was excellent in flatness.
- the surface roughness of the inner surface of this groove was 3.8 m, and the variation in surface roughness was small.
- the dimensional accuracy was excellent with a width of ⁇ 3%, a depth of ⁇ 4%, and a pitch of ⁇ 4%.
- the polishing rate, the presence or absence of scratches, and dishing were evaluated in the same manner as in Example 1. As a result, the polishing rate was 40 Onm, the scratch was hardly recognized, the dating was 55 nm, and the polished surface was excellent in flatness.
- a polishing pad of the same size was produced in the same manner as in Example 3, and the average value of the groove width was 0.5 mm and the groove depth was on the polishing surface side of the polishing pad by the method described in the above [2].
- An annular groove with an average value of 1 mm and an average pitch of 1 mm is formed concentrically.
- the inner surface of this groove has a surface roughness of 5.5 jm, and the surface roughness is small.
- the dimensional accuracy was excellent because the width was 3% soil, the depth was 5% soil, and the pitch was 5% soil.
- the polishing rate, the presence or absence of scratches, and dishing were evaluated in the same manner as in Example 1. As a result, the polishing rate was 35 Onm / min, little scratching was observed, the dishing was 60 nm, and the polished surface was excellent in flatness. Comparative Example 1
- the average groove width was 0.25 mm by the method described in [2] above.
- a plurality of annular grooves with a mean groove depth of 0.4 mm and a mean pitch of 1.5 mm were formed concentrically.
- the surface roughness of the inner surface of this groove was as large as 355 m, and the variation of the surface roughness was very large.
- the dimensional accuracy was inferior with a width of 15% soil, a depth of 20% soil and a pitch of 12% soil.
- the polishing rate, the presence or absence of scratches, and the dishing were evaluated in the same manner as in Example 1. As a result, the polishing rate was 350 nm, many scratches were recognized, the dating was 150 n, and the polished surface was poor in flatness.
- the polishing pad obtained in Example 1 was processed by a processing tool provided with a plurality of holders each having a multi-blade unit shown in FIG. 10 so that the intervals between the blade edges were the same.
- the blade angle 0 of the formed blade was 45 °
- the front clearance angle 0 2 was 30 °
- the lateral clearance angle 0 3 of the blade abutting the inner wall of the groove was 2 °.
- the blade width L is 0.52 mm
- the distance between adjacent blade edges is 3.48 mm
- the blade length is 5 mm.
- the surface roughness of the inner surface of this groove was 4.1 m, and the variation in surface roughness was small. Excellent dimensional accuracy with width ⁇ 6%, depth ⁇ 5%, and pitch 5% 2003/010125
- the polishing pad obtained in Example 1 was processed in the same manner as in Example 5 to form concentric grooves.
- the blade angle 0 i of the formed blade is 30 °
- the front clearance angle ⁇ 2 is 50 °
- the lateral clearance angle ⁇ 3 of the blade in contact with the inner wall of the groove is 2 °
- the blade width L is 0.52 mm
- the distance between adjacent blade edges is 0.48 mm
- the blade length is 3 mm.
- the formed grooves had an average groove width of 0.5 mm, an average groove depth of lmm, and an average pitch of lmm.
- the surface roughness of the inner surface of this groove was 5.2 m, and the variation in surface roughness was small.
- the dimensional accuracy was excellent with a width of ⁇ 4%, a depth of ⁇ 5%, and a pitch of ⁇ 5%.
- the polishing rate, the presence or absence of scratches, and dishing were evaluated in the same manner as in Example 1. As a result, the polishing rate was 30 Onm, the scratch was hardly recognized, the dating was 6 Onm, and the polished surface was excellent in flatness.
- the polishing pad obtained in Example 3 was processed in the same manner as in Example 5 to form concentric grooves.
- the blade angle St of the formed blade was 30 °
- the front clearance angle 0 2 was 45 °
- the lateral clearance angle ⁇ 3 of the blade contacting the inner wall of the groove was 2 °
- the blade width L is 0.52 mm
- the distance between adjacent blade edges is 3.48 mm
- the blade length is 5 mm.
- the formed grooves had an average groove width of 0.5 mm, an average groove depth of 0.5 mm, and an average pitch of 4 mm.
- the surface roughness of the inner surface of this groove was 3.8 m, and the variation in surface roughness was small.
- the dimensional accuracy is excellent with a width of 3% for soil, a depth of ⁇ 4%, and a pitch of ⁇ 4%.
- the polishing rate, the presence or absence of scratches, and dishing were evaluated in the same manner as in Example 1. As a result, the polishing rate was 40 OnmZ, the scratch was hardly recognized, the dating was 55 nm, and the polished surface was excellent in flatness.
- the polishing pad obtained in Example 3 was processed in the same manner as in Example 5 to form concentric grooves.
- the blade angle 0 of the formed blade is 30 °
- the front clearance angle 0 2 is 50 °
- the lateral clearance angle ⁇ a of the blade contacting the inner wall of the groove is 2 °.
- the blade width L is 0.52 mm
- the distance between adjacent blade edges is 0.48 mm
- the blade length is 3 mm.
- the formed grooves had an average groove width of 0.5 mm, an average groove depth of lmm, and an average pitch of lmm.
- the surface roughness of the inner surface of this groove was 5.5 m, and the variation in surface roughness was small.
- the dimensional accuracy was excellent with a width of ⁇ 3%, a depth of ⁇ 5%, and a pitch of ⁇ 5%.
- the polishing rate, the presence or absence of scratches, and dishing were evaluated in the same manner as in Example 1. As a result, the polishing rate was 350 nm / min, almost no scratch was observed, the dating was 60 nm, and the polished surface was excellent in flatness. Comparative Example 2
- the polishing pad used in Comparative Example 1 was processed in the same manner as in Example 5 to form concentric grooves.
- the blade angle 0 i of the formed blade is 60 °
- the front clearance angle 0 2 is 20 °
- the lateral clearance angle e 3 of the blade abutting the inner wall of the groove is 60 °
- the formed grooves had an average groove width of 0.25 mm, an average groove depth of 0.4 mm, and an average pitch of 1.5 mm.
- the surface roughness of the inner surface of the groove was as large as 355 im, and the variation in the surface roughness was very large.
- the dimensional accuracy was inferior with a width of ⁇ 15%, a depth of ⁇ 20%, and a pitch of ⁇ 12%.
- the polishing rate and the presence of scratches were None and dishing were evaluated. As a result, the polishing rate was 350 II mZ min, many scratches were recognized, the dishing was 150 nm, and the polished surface was poor in flatness.
- the invention's effect was 350 II mZ min, many scratches were recognized, the dishing was 150 nm, and the polished surface was poor in flatness.
- the grooves in the polishing surface of the polishing pad, recess, D also can be easily and formed good accuracy through holes or the like, it is possible to reduce the surface roughness of the inner surface of the grooves, such as .
- a groove having a high dimensional accuracy and a uniform cross-sectional shape can be formed.
- a blade having a predetermined blade angle, a front clearance angle, and a side clearance angle of a blade abutting on the inner wall of the groove a multi-blade unit having a predetermined distance between adjacent blade edges is used.
- the formation of grooves can be performed efficiently and reliably, and the surface roughness can be reduced.
- it is suitable when the pattern shape of the groove is annular and concentric.
- polishing pad for a semiconductor wafer of the present invention when a semiconductor wafer or the like is polished, a polished surface excellent in flatness and the like can be formed.
- the polishing pad for a semiconductor wafer of the present invention is particularly useful in a semiconductor device manufacturing process.
- a semiconductor device manufacturing process For example, an STI process, a damascene process for forming metal wiring such as A to Cu, Al, Cu, W, etc. Damascene process for forming via plugs using GaN, dual damascene process for simultaneously forming these metal wirings and peer plugs, polishing interlayer insulating film (oxide film, low-k, BPSG, etc.), nitride film (TaN, TiN, etc.), a process of polishing polysilicon, bare silicon, and the like.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Mechanical Engineering (AREA)
- Plasma & Fusion (AREA)
- Manufacturing & Machinery (AREA)
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
- Mechanical Treatment Of Semiconductor (AREA)
Abstract
Description
Claims
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2004-7005815A KR20040074055A (ko) | 2002-08-08 | 2003-08-08 | 반도체 웨이퍼용 연마 패드의 가공 방법 및 반도체웨이퍼용 연마 패드 |
| DE60332313T DE60332313D1 (de) | 2002-08-08 | 2003-08-08 | Polierstück für ein verfahren zur bearbeitung von halbleiterwafern und polierstück für halbleiterwafer |
| US10/492,946 US20040266326A1 (en) | 2002-08-08 | 2003-08-08 | Method of machining semiconductor wafer-use polishing pad and semiconductor wafer-use polishing pad |
| EP03784605A EP1447841B1 (en) | 2002-08-08 | 2003-08-08 | Method of machining semiconductor wafer-use polishing pad and semiconductor wafer-use polishing pad |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002231943A JP2004071985A (ja) | 2002-08-08 | 2002-08-08 | 半導体ウェハ用研磨パッドの加工方法及び半導体ウェハ用研磨パッド |
| JP2002/231943 | 2002-08-08 | ||
| JP2002/311951 | 2002-10-25 | ||
| JP2002311951A JP2004146704A (ja) | 2002-10-25 | 2002-10-25 | 半導体ウェハ用研磨パッドの加工方法及び半導体ウェハ用研磨パッド |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2004015751A1 true WO2004015751A1 (ja) | 2004-02-19 |
Family
ID=31719853
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2003/010125 Ceased WO2004015751A1 (ja) | 2002-08-08 | 2003-08-08 | 半導体ウェハ用研磨パッドの加工方法及び半導体ウェハ用研磨パッド |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US20040266326A1 (ja) |
| EP (1) | EP1447841B1 (ja) |
| KR (2) | KR20060116036A (ja) |
| CN (1) | CN1309026C (ja) |
| DE (1) | DE60332313D1 (ja) |
| TW (1) | TWI228768B (ja) |
| WO (1) | WO2004015751A1 (ja) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108972383A (zh) * | 2018-08-03 | 2018-12-11 | 成都时代立夫科技有限公司 | 一种cmp沟槽加工定位方法及定位装置 |
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| US7247566B2 (en) * | 2003-10-23 | 2007-07-24 | Dupont Air Products Nanomaterials Llc | CMP method for copper, tungsten, titanium, polysilicon, and other substrates using organosulfonic acids as oxidizers |
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| US8251777B2 (en) * | 2005-06-30 | 2012-08-28 | Cabot Microelectronics Corporation | Polishing slurry for aluminum and aluminum alloys |
| USD553932S1 (en) * | 2005-08-19 | 2007-10-30 | Boler Jr Lewyn B | Buffing pad |
| US20070111644A1 (en) * | 2005-09-27 | 2007-05-17 | Spencer Preston | Thick perforated polishing pad and method for making same |
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| CN112643071A (zh) * | 2020-12-30 | 2021-04-13 | 南通欧雷德智能科技有限公司 | 一种除静电镜面刀盘 |
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2003
- 2003-08-07 TW TW092121691A patent/TWI228768B/zh not_active IP Right Cessation
- 2003-08-08 KR KR1020067022628A patent/KR20060116036A/ko not_active Withdrawn
- 2003-08-08 CN CNB038015676A patent/CN1309026C/zh not_active Expired - Fee Related
- 2003-08-08 US US10/492,946 patent/US20040266326A1/en not_active Abandoned
- 2003-08-08 KR KR10-2004-7005815A patent/KR20040074055A/ko not_active Ceased
- 2003-08-08 DE DE60332313T patent/DE60332313D1/de not_active Expired - Lifetime
- 2003-08-08 EP EP03784605A patent/EP1447841B1/en not_active Expired - Lifetime
- 2003-08-08 WO PCT/JP2003/010125 patent/WO2004015751A1/ja not_active Ceased
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001018164A (ja) * | 1999-07-08 | 2001-01-23 | Toho Engineering Kk | 半導体デバイス加工用硬質発泡樹脂溝付パッド及びそのパッド旋削溝加工用工具 |
| JP2001214154A (ja) * | 1999-11-25 | 2001-08-07 | Jsr Corp | 研磨パッド用組成物及びそれを用いた研磨パッド |
| JP2002011630A (ja) * | 2000-06-26 | 2002-01-15 | Toho Engineering Kk | 半導体cmp加工用パッドの細溝加工機械・加工用工具及び切削加工方法 |
| EP1201368A2 (en) | 2000-10-24 | 2002-05-02 | JSR Corporation | Composition for forming polishing pad, crosslinked body for polishing pad, polishing pad using the same and method for producing thereof |
| JP2002184730A (ja) * | 2001-11-02 | 2002-06-28 | Toho Engineering Kk | 半導体デバイス加工用硬質発泡樹脂溝付パッド及びそのパッド旋削溝加工用工具 |
Non-Patent Citations (1)
| Title |
|---|
| See also references of EP1447841A4 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108972383A (zh) * | 2018-08-03 | 2018-12-11 | 成都时代立夫科技有限公司 | 一种cmp沟槽加工定位方法及定位装置 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20040074055A (ko) | 2004-08-21 |
| TWI228768B (en) | 2005-03-01 |
| US20040266326A1 (en) | 2004-12-30 |
| CN1309026C (zh) | 2007-04-04 |
| KR20060116036A (ko) | 2006-11-13 |
| CN1592955A (zh) | 2005-03-09 |
| EP1447841A4 (en) | 2007-08-15 |
| EP1447841B1 (en) | 2010-04-28 |
| EP1447841A1 (en) | 2004-08-18 |
| TW200403741A (en) | 2004-03-01 |
| DE60332313D1 (de) | 2010-06-10 |
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