WO2003070445A1 - Systeme de decoration en couleurs - Google Patents

Systeme de decoration en couleurs Download PDF

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Publication number
WO2003070445A1
WO2003070445A1 PCT/EP2003/001604 EP0301604W WO03070445A1 WO 2003070445 A1 WO2003070445 A1 WO 2003070445A1 EP 0301604 W EP0301604 W EP 0301604W WO 03070445 A1 WO03070445 A1 WO 03070445A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
substrate
color
polymer
mold
Prior art date
Application number
PCT/EP2003/001604
Other languages
German (de)
English (en)
Inventor
Sven Jacobsen
Christian Kuckertz
Original Assignee
Wipak Walsrode Gmbh & Co. Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wipak Walsrode Gmbh & Co. Kg filed Critical Wipak Walsrode Gmbh & Co. Kg
Priority to AU2003210295A priority Critical patent/AU2003210295A1/en
Publication of WO2003070445A1 publication Critical patent/WO2003070445A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/10—Applying flat materials, e.g. leaflets, pieces of fabrics
    • B44C1/105—Applying flat materials, e.g. leaflets, pieces of fabrics comprising an adhesive layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
    • B29C45/14811—Multilayered articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
    • B44C3/02—Superimposing layers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
    • C08J5/125—Adhesives in organic diluents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • B29C45/14688—Coating articles provided with a decoration
    • B29C2045/14737—Coating articles provided with a decoration decorations printed on the insert by a digital imaging technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2633/00—Use of polymers of unsaturated acids or derivatives thereof for preformed parts, e.g. for inserts
    • B29K2633/04—Polymers of esters
    • B29K2633/08—Polymers of acrylic acid esters, e.g. PMA, i.e. polymethylacrylate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2715/00—Condition, form or state of preformed parts, e.g. inserts
    • B29K2715/006—Glues or adhesives, e.g. hot melts or thermofusible adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/002—Coloured
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/0026—Transparent

Definitions

  • the present invention relates to color decoration systems comprising a layer sequence of at least one transparent surface layer based on a polymer blend made of thermoplastic polyalkyl methacrylate and an elastomeric polymer component distributed therein, a color decoration layer applied thereon and a connecting layer made of plastic material which optionally adjoins the color decoration layer and which is exposed to heat with the addition of decorating substrate connects, and a protective layer of plastic, which may be arranged between the color decoration layer and the connecting layer, and which has a higher softening point than the plastic material of the connecting layer.
  • the object of the present invention was therefore to provide a color decoration system which does not have these disadvantages and is particularly suitable for decorating three-dimensional substrates which are preferably designed in contact with the color decoration system.
  • This object is achieved by making the color decor system according to the invention available.
  • the color decor system according to the invention has at least one layer sequence
  • a transparent surface layer based on a polymer blend of at least one thermoplastic polyalkyl methacrylate, optionally at least one thermoplastic polyalkyl acrylate and at least one elastomeric polymer, which is provided with
  • a connecting layer made of a plastic material that bonds to the substrate to be decorated
  • the transparent surface layer a) is preferably made of a polymer blend of up to 40% by weight, preferably from 15 to 30% by weight, based on the total amount of polymers, of an elastomeric polymer, preferably one elastomeric polymers that do not impair transparency, particularly preferably a crosslinked polybutyl acrylate.
  • thermoplastic polyalkyl methacrylate present in the polymer blend is preferably a polymethyl methacrylate and, if appropriate, up to 20% by weight, based on the thermoplastic polymer component, a poly-C2-C 4 -alkyl methacrylate or preferably a poly-C 1 -C 4 -alkyl acrylate, particularly preferably polybutyl acrylate.
  • the polymer blend therefore particularly preferably consists of polymethyl methacrylate, optionally up to 20% by weight, based on the thermoplastic polymer component, polybutyl acrylate and a crosslinked polybutyl acrylate.
  • layer a) preferably has UV absorber compounds for absorbing UV radiation, which are preferably chemically bound.
  • UV absorber compounds for absorbing UV radiation, which are preferably chemically bound.
  • organic UV absorber compounds such as. B. sterically hindered phenols, benzophenones, benzotriaxols, particularly preferably sterically hindered amine compounds such as so-called HALS compounds, which are each used in amounts such that at least 95%, preferably 98 to 99% of the UV radiation is absorbed.
  • the surface layer is transparent, so that the colored decoration layer is visible through this layer a.).
  • the color decorative layer b) is preferably printed on the layer a), it being possible to use the known printing inks, preferably based on polyvinyl chloride or polyvinyl butyrate as a binder.
  • Color decor is not only the application of a colored design for aesthetic reasons such.
  • This also includes the application of codes to secure, record and / or protect against unauthorized copying. You can do this in addition to Printing inks also correspondingly printable solutions as marking substances, such as. B. electrically conductive polymers or fluorescent pigments can be used.
  • the printing inks or the marking substances used are preferably in the form of solvent-containing systems which have, as solvents, customary solvents for printing inks, such as acetone or toluene.
  • the color decors, such as B. print images, advertising lettering and / or coding, are preferably applied by gravure or flexographic printing to layer a).
  • the layer c) which consists of a plastic material that connects to the substrate to be decorated under the action of heat, has the function of a connecting layer.
  • the softening point of the plastic material should preferably be at least 95 ° C, more preferably than the softening point of the substrate to be decorated in the range of 100 ° C, up to a temperature lying lower at most equal to, or preferably by at least 5 C C. If, therefore, the substrate to be decorated consists of a plastic material, layer c) should preferably consist of a polymer, the predominant part of which consists of the monomer units from which the plastic material of the substrate to be decorated is constructed. For example, an ethylene-propylene copolymer with a predominant proportion of propylene is mentioned as the plastic material, provided the substrate consists of polypropylene.
  • the color decor system according to the invention preferably has a further layer d) which is arranged as a protective layer between the color decor layer b) and the connecting layer c).
  • This protective layer is preferably based on a plastic that has a higher softening point than the plastic material of layer c), the so-called connecting layer.
  • This protective layer is preferably oriented at least monoaxially, particularly preferably biaxially.
  • Layer d) ensures that, in particular when decorating such substrates, only by back injection or back pressing of the Decorative systems are made with a polymeric substrate material, the color decorative layer is not damaged when softening the connecting layer.
  • Layer d) is preferably made of a polyester, an olefinic homo- or copolymer, preferably of polyethylene terephthalate, polypropylene, polyethylene or an ethylene / propylene copolymer, it being necessary to ensure that the softening point of the protective layer d) is at least 10 K higher than the softening point of the plastic of the connecting layer c). If the substrate to be decorated consists of plastic, the plastic of the protective layer d) can preferably be constructed from the same monomer units as the substrate polymer.
  • the color decor system according to the invention can furthermore each have an adhesion promoter layer between the layers b) and c) or b) and d) and / or d) and c).
  • adhesion promoter systems such as, for. B. an optionally solvent-containing two-component polyurethane adhesive or a polyacrylate adhesive or a maleic anhydride grafted polypropylene can be used.
  • the thickness of layer a) is preferably in the range from 10 to 150 ⁇ m, particularly preferably from 30 to 130 ⁇ m.
  • the thickness of the layer c) is preferably in the range from 20 to 500 ⁇ m, particularly preferably from 30 to 250 ⁇ m, very particularly preferably in the range from 30 to 100 ⁇ m. If layer d) is present, its thickness is preferably in the range from 8 to 300 ⁇ m, particularly preferably from 12 to 30 ⁇ m.
  • the transparent surface layer a) contain the abovementioned compounds for absorption of UV radiation, but also layer c) or d) and, if the layer b) and c) or layer b) and d are combined ) an adhesion promoter layer is used, in each case also this adhesion promoter layer (s), it being possible for the corresponding compounds, preferably also chemically, to be bound.
  • the polymer blend is made from at least one thermoplastic polyalkyl methacrylate, optionally a thermoplastic polyalkyl acrylate and a preferably homogeneously distributed elastomeric polymer, preferably a crosslinked polybutyl acrylate, preferably by extrusion or coextrusion, the transparent surface layer a) is produced.
  • This layer is with flexographic or gravure printing or with the help of another known printing process such.
  • the color decoration system according to the invention is intended to comprise the protective layer d), this is produced separately using customary processes, such as flat film extrusion or the film blowing process, preferably using monoaxial, particularly preferably biaxial stretching, and with the aid of a suitable adhesion promoter system onto the printed side and thus onto the color decoration layer b .) laminated. If layer d) is not to be present in the color decoration system according to the invention, layer c) is laminated onto the color decoration layer b), preferably again using a suitable adhesion promoter system.
  • connection layer c) is preferably produced separately by flat film extrusion or by extrusion according to the film blowing process and with the layer sequence a) and b) or a), b) and d) with the aid of a suitable adhesion promoter system, which preferably contains solvents.
  • layer c) can also be applied in the coating process.
  • the color decor system according to the invention is suitable for decorating substrates of any kind, such as substrates made of plastics, preferably polyamides, polyolefins, polyesters, such as. B. polyamide-6, polyamide-6,6, polyethylene, polypropylene, polyethylene terephthalate, polybutylene terephthalate, wood-based substrates, such as. B. chipboard, fibreboard, paper, provided that only the respective substrate with the layer c) connects permanently under the influence of heat.
  • the color decor system according to the invention is preferably suitable for Decorating substrates, particularly preferably three-dimensional substrates with a complicated design.
  • Another object of the present invention is therefore a substrate, decorated with a color decoration system according to the invention, preferably a molded plastic body, which was designed and simultaneously decorated by back injection or back pressing of the color decoration system according to the invention.
  • the color decor system according to the invention which preferably has a protective layer d
  • the surface layer a) is in direct contact with the wall of the mold and the connecting layer c) connects to the heated substrate material introduced into the mold and the decorated shaped body is removed from the mold after cooling.
  • the softened plastic of the substrate material is preferably introduced into the mold by injection molding or is connected to the color decoration system according to the present invention by back pressing in the mold.
  • polypropylene is particularly suitable as the substrate material and an ethylene / propylene copolymer as the plastic material of the layer c) or a polyethylene with a density of 0.92 to 0.98 g / cm 3 as the substrate material and an ethylene homo- as the plastic material of the connecting layer c) or copolymer with a softening point lower than the softening point of the polyethylene from which the substrate is made.
  • the present invention therefore furthermore relates to processes for decorating a preferably three-dimensional substrate by combining an inventive color decor system with the connecting layer c) with the Bring the substrate into contact so that the color decoration system is permanently connected to the substrate to be decorated via the layer c).
  • the substrate is preferably a continuous plate which decorates inline or a shaped body which is first formed in a mold and at the same time is decorated with the color decor system according to the invention.
  • the softening point of the polymers used corresponds to the Vicat softening temperature, which is defined and determined in accordance with ISO EN 306.
  • a 125 ⁇ m thick film made of a polymer blend made of polymethyl methacrylate and 15% by weight, based on the polymer components, of a crosslinked polybutyl acrylate is gravure printed with PVC-based printing inks.
  • the printed side is laminated with a 15 ⁇ m thick, biaxially oriented polypropylene (BOPP) film using a solvent-based 2-component polyurethane adhesive system.
  • BOPP biaxially oriented polypropylene
  • This pre-composite is bonded to a separately produced cast film made of propylene / ethylene copolymers (50 ⁇ m thick) using the solvent-based 2-component polyurethane adhesive system.
  • the above-described composite is connected to the above-described propylene / ethylene copolymer film using an acrylate-based adhesive system.
  • the preliminary composite described above is coated on the BOPP film side with a 50 ⁇ m thick ethylene / propylene copolymer layer.
  • the resulting groups are e.g. B. suitable for decoration by back injection with a homopolymeric propylene.
  • a pre-punched color decoration system according to the invention is placed in the opened injection mold of a conventional injection molding machine, pneumatically fixed and, after the mold has been closed, back-injected with a propylene homopolymer at 200 ° C.
  • the propylene / ethylene copolymer layer melts at least partially and thus enables an intimate connection of the color decoration layer with the substrate.
  • the decorated substrate is removed from the injection mold.
  • a 30 ⁇ m thick biaxially oriented polyethylene film (PE soaking point 124 ° C) is laminated onto the color decor using solvent-free 2-component PU laminating adhesive. This composite is coated with a layer of ethylene vinyl acetate copolymer with a softening point of 98 ° C as a connecting layer.
  • the color decor system according to the invention is placed in an injection mold in such a way that layer a) lies directly against the mold wall and layer c) combines with the polyethylene injected into the mold. After cooling, the PE substrate decorated in this way can be removed from the mold.
  • a 125 ⁇ m thick film made of a polymer blend of polymethyl methacrylate and and 15% by weight, based on the polymer components, of a cross-linked polybutyl acrylate is printed with a carbon design in flexographic printing, PVC-based printing inks being used.
  • This film is laminated with a 150 ⁇ m thick PET film (polyethylene terephthalate film) using a solvent-based, aliphatic 2-component PU adhesive.
  • This preliminary network is provided with a copolyamide layer, the connecting layer c) having been applied in a thickness of 25 ⁇ m on the PET side of the composite.
  • This composite is laminated to a medium-thick fibreboard (MDF) under the influence of heat at 95 ° C (softening point of the copolyamide approx. 75 ° C). You get a very scratch-resistant, high-gloss, weatherproof wood paneling.
  • MDF medium-thick fibreboard

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)

Abstract

La présente invention concerne un système de décoration en couleurs comprenant une série de couches comprenant au moins a) une couche superficielle transparente à base d'un mélange polymère composé d'au moins un polyalkyl méthacrylate thermoplastique, éventuellement d'au moins un polyalkyl acrylate thermoplastique, et d'au moins un polymère élastomère, ladite couche superficielle étant dotée b) d'une couche de décoration en couleurs, c) une couche de liaison constituée d'une matière plastique qui effectue la liaison avec le substrat à décorer par effet thermique, et d) éventuellement une couche protectrice à orientation de préférence biaxiale disposée entre la couche de décoration en couleurs b) et la couche de liaison c), ladite couche protectrice étant constituée d'une matière plastique qui a un point de ramollissement plus élevé que celui de la matière plastique constitutive de la couche c).
PCT/EP2003/001604 2002-02-22 2003-02-18 Systeme de decoration en couleurs WO2003070445A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003210295A AU2003210295A1 (en) 2002-02-22 2003-02-18 Colour decoration system

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2002107639 DE10207639A1 (de) 2002-02-22 2002-02-22 Farbdektorsystem
DE10207639.1 2002-02-22

Publications (1)

Publication Number Publication Date
WO2003070445A1 true WO2003070445A1 (fr) 2003-08-28

Family

ID=27674872

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2003/001604 WO2003070445A1 (fr) 2002-02-22 2003-02-18 Systeme de decoration en couleurs

Country Status (3)

Country Link
AU (1) AU2003210295A1 (fr)
DE (1) DE10207639A1 (fr)
WO (1) WO2003070445A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG120959A1 (en) * 2002-11-13 2006-04-26 Teikoku Printing Ink Mfg Insert-molded article, production method of the insert-molded article and ink

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009043042B4 (de) * 2009-09-28 2013-10-24 Allflex Folienveredelung Gmbh & Co. Kg Verfahren zur Herstellung bedruckter Verpackungen aus kaschiertem Folienmaterial sowie bedrucktes kaschiertes Folienmaterial für eine Verpackung

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5055346A (en) * 1988-08-30 1991-10-08 Frank Rohrbacher Thermoplastic acrylic polymer coated composite structure
EP0933183A1 (fr) * 1997-07-22 1999-08-04 Nissha Printing Co., Ltd. Feuille destinee a un decor moule a feuille metallique integree et procede de production de resine moulee presentant un tel decor, au moyen de ladite feuille
EP1120244A1 (fr) * 2000-01-26 2001-08-01 Atofina Film multicouche thermoformable pour la protection de substrats et objets obtenus
EP1123791A1 (fr) * 2000-02-10 2001-08-16 Dai Nippon Printing Co., Ltd. Feuille décorative pour le moulage décoratif dans le moule par injection, moulage décoratif et procédé de moulage décoratif dans le moule par injection

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3709229A1 (de) * 1987-03-20 1988-09-29 Roehm Gmbh Verklebbare dekorfolie aus polycarbonat-kunststoff
DE3817479A1 (de) * 1988-05-21 1989-11-30 Renolit Werke Gmbh Mehrschichtige oberflaechenfolie
IT1274037B (it) * 1994-07-29 1997-07-14 Graziola Spa Procedimento e dispositivo per la realizzazione di una rappresentazione grafica su oggetti realizzati con un polimero poliolefinico
DE29824038U1 (de) * 1998-12-23 2000-04-20 Leonhard Kurz GmbH & Co, 90763 Fürth Dekorfolie zum Hinterspritzen mit Kunststoff

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5055346A (en) * 1988-08-30 1991-10-08 Frank Rohrbacher Thermoplastic acrylic polymer coated composite structure
EP0933183A1 (fr) * 1997-07-22 1999-08-04 Nissha Printing Co., Ltd. Feuille destinee a un decor moule a feuille metallique integree et procede de production de resine moulee presentant un tel decor, au moyen de ladite feuille
EP1120244A1 (fr) * 2000-01-26 2001-08-01 Atofina Film multicouche thermoformable pour la protection de substrats et objets obtenus
EP1123791A1 (fr) * 2000-02-10 2001-08-16 Dai Nippon Printing Co., Ltd. Feuille décorative pour le moulage décoratif dans le moule par injection, moulage décoratif et procédé de moulage décoratif dans le moule par injection

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG120959A1 (en) * 2002-11-13 2006-04-26 Teikoku Printing Ink Mfg Insert-molded article, production method of the insert-molded article and ink

Also Published As

Publication number Publication date
AU2003210295A1 (en) 2003-09-09
DE10207639A1 (de) 2003-09-04

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