WO2003064542A1 - Agent de melange de pigments actif amphiphile - Google Patents

Agent de melange de pigments actif amphiphile Download PDF

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Publication number
WO2003064542A1
WO2003064542A1 PCT/CN2003/000097 CN0300097W WO03064542A1 WO 2003064542 A1 WO2003064542 A1 WO 2003064542A1 CN 0300097 W CN0300097 W CN 0300097W WO 03064542 A1 WO03064542 A1 WO 03064542A1
Authority
WO
WIPO (PCT)
Prior art keywords
pigment
combination formulation
amphiphilic
amphiphilic active
active
Prior art date
Application number
PCT/CN2003/000097
Other languages
English (en)
Chinese (zh)
Inventor
Wenfei Wu
Original Assignee
Wenfei Wu
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wenfei Wu filed Critical Wenfei Wu
Publication of WO2003064542A1 publication Critical patent/WO2003064542A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/06—Artists' paints

Definitions

  • the invention relates to a pigment formulation.
  • the invention provides a pigment formulation which can be used for a combination of various oily, water-based pigment powders and solvents.
  • the amphiphilic active pigment combination formulation of the present invention is composed of the following weight percentage ingredients: non-ionic surfactant 5.5-9%, ionic surfactant 8.5-12%, propylene glycol 3-5%, glycerol 2_6%, seaweed Sodium 13-20%, sodium fatty acid 1-2%, antioxidant 3.5-6%, antifoaming agent 2-4%, polyvinyl alcohol 2-4%> preservative 2_7%, active CaC0 3 2-6%, The mass percentage concentration is 28-35% of 10% alkali solution.
  • amphiphilic active pigment combination formulation of the present invention not only has amphiphilic blending properties, but also can be used for various pigment powders, solubilizers, auxiliaries, and corresponding formulations to formulate Chinese painting pigments, watercolor pigments, gouache pigments, oil paints, etc. .
  • Amphiphilic active pigment combination formulation consisting of the following weight percent components: fluorenyl phenol polyoxyethylene ether 7.5%, ⁇ -sulfo fatty acid methyl ester sodium salt (MES) 10.5%, propylene glycol 4.5%, glycerol 5%, seaweed Sodium 16
  • alkylphenol polyoxyethylene ether is a non-ionic surfactant, which makes pigment dispersibility good
  • the molecular structural formula of ⁇ -sulfo fatty acid methyl ester sodium salt (MES) is as follows: It is an ionic surfactant containing hydrophilic groups and lipophilic groups, which allows two different pigments to obtain a uniform dispersion system and improve color brightness.
  • the Chinese pigment system has poor hydrophilicity and large sediment, or The separation of Chinese painting pigments from other immiscible pigments can be solved by MES.
  • Propylene glycol is used as a humectant; Glycerin is used as an anti-skinning agent; Sodium alginate is used as a plasticizer to increase the viscosity to make the film soft, increase the adhesion of the pigment to the adherend, and increase the toughness of the film; Sodium fatty acid can improve the adhesion
  • the surface affinity of the material prevents the aging silicone emulsion from having a defoaming effect;% 6-Di-tert-butyl-4 methylphenol (BHT) is an antioxidant that prevents drying and delays oxidative polymerization; polyvinyl alcohol reinforces the paper To prevent color fading and enhance the aging resistance of paintings; NaOH solution is used to adjust the pH and alkalinity of solvents; fennel essential oil makes pigments have insect and deodorant functions; preservatives are methyl ester, propyl ester, and NaN 3 by weight percentage 3 : 1: 1 is obtained by mixing.
  • agent A The amphiphilic active pigment combination formulation obtained in Example 1 is hereinafter referred to as agent A;
  • B% 72% active CaC0 3 , 23% ZnO and 5% fennel powder mixture is hereinafter referred to as B agent;
  • agent A, agent B and the organic or inorganic pigment powder are mixed at a weight ratio of 1 1: 5 to obtain a watercolor pigment, and 1.1 :: 3.5: 5 mixed with a gouache pigment.
  • agent A The amphiphilic active pigment combination formulation obtained in Example 1 is hereinafter referred to as agent A;
  • agent C A mixture of 6% by weight of hydrocarbon ethyl cellulose, 85% acrylic acid and 9% fennel essential oil is hereinafter referred to as agent C;
  • agent A The above-mentioned agent A, agent C and the organic or inorganic pigment powder are mixed at a weight ratio of 1.1: 2: 5 to obtain a propylene pigment.
  • Example 4 The above-mentioned agent A, agent C and the organic or inorganic pigment powder are mixed at a weight ratio of 1.1: 2: 5 to obtain a propylene pigment.
  • agent A The amphiphilic active pigment combination formulation obtained in Example 1 is hereinafter referred to as agent A;
  • D agent A mixture of 76% linseed oil, 15% turpentine and 9% fennel essential oil by weight, hereinafter referred to as D agent;
  • the above-mentioned agents A, D and the organic or inorganic pigment powder are mixed in a weight ratio of 1.1: 2: 5 to obtain an oil paint.
  • the amphiphilic pigment combination formulation of the present invention is not limited to the above-mentioned use, and it can also be mixed with the recycled waste powder at a weight ratio of 1.1: 5 to prepare a recycled pigment.
  • Recycled waste can be ground into powders such as dried melon peels, beans, tea residues, and flowers.
  • the color of the recycled pigment is mainly derived from the color of the above-mentioned recycled waste powder. , Beautiful color.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne un agent de mélange de pigments actif amphiphile constitué des ingrédients suivants : 5,5-9 % en poids de tensioactif non ionique, 8,5-12 % en poids de tensioactif ionique, 3-5 % en poids de propylène glycol, 2-6 % en poids de glycérol, 13-20 % en poids d'alginate de sodium, 1-2 % en poids de sel sodique d'acide gras, 3,5-6 % en poids d'antioxydant, 2-4 % en poids d'agent antimousse, 2-4 % en poids d'alcool polyvinylique, 2-7 % en poids d'agent de conservation, 2-6 % en poids de CaCo3 actif, 28-35 % en poids d'une solution alcaline présentant une concentration de 10 % en pour cent massique. Cet agent de mélange possède non seulement une propriété de mélange amphiphile le rendant utile dans diverses poudres pigmentaires, mais permettent aussi de former un pigment pour peinture chinoise, un pigment pour aquarelle, un pigment pour poudre aqueuse, un pigment pour peinture à l'huile par combinaison avec un cosolvant, un adjuvant, etc..
PCT/CN2003/000097 2002-01-29 2003-01-29 Agent de melange de pigments actif amphiphile WO2003064542A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN02114799.X 2002-01-29
CNB02114799XA CN1164694C (zh) 2002-01-29 2002-01-29 双亲活性颜料组合配剂

Publications (1)

Publication Number Publication Date
WO2003064542A1 true WO2003064542A1 (fr) 2003-08-07

Family

ID=4743301

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2003/000097 WO2003064542A1 (fr) 2002-01-29 2003-01-29 Agent de melange de pigments actif amphiphile

Country Status (2)

Country Link
CN (1) CN1164694C (fr)
WO (1) WO2003064542A1 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100411887C (zh) * 2004-12-17 2008-08-20 深圳市深蓝德精细化工科技有限公司 一种画笔
CN100445956C (zh) * 2004-12-24 2008-12-24 鸿富锦精密工业（深圳）有限公司 外围设备互连总线除错装置及方法
CN101845246B (zh) * 2010-06-10 2012-01-18 宋健 一种易擦洗的水粉涂鸦艺术颜料和制造方法
CN102286223B (zh) * 2011-06-21 2015-04-22 宁波工程学院 一种儿童绘画用颜料组合物及制备方法
CN102417747A (zh) * 2011-11-07 2012-04-18 吴江市冰心文教用品有限公司 一种国画颜料的制作方法
CN103160152B (zh) * 2011-12-14 2015-07-29 苏州欢颜电气有限公司 一种速干型红色水粉颜料及其生产方法
CN105017829A (zh) * 2015-06-30 2015-11-04 河南行知专利服务有限公司 一种用于美术设计的生物环保颜料
CN105907147A (zh) * 2016-05-03 2016-08-31 南阳理工学院 一种含有光催化剂的油画颜料及其制备方法
CN110713740A (zh) * 2018-07-11 2020-01-21 刘静琳 一种环保清香型颜料
CN110577763B (zh) * 2019-09-17 2021-09-24 华东理工大学 一种留香持久的油画颜料及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4500362A (en) * 1982-11-15 1985-02-19 Fuji Photo Film Co., Ltd. Process for preparing aqueous dispersion of pigment

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4500362A (en) * 1982-11-15 1985-02-19 Fuji Photo Film Co., Ltd. Process for preparing aqueous dispersion of pigment

Also Published As

Publication number Publication date
CN1362455A (zh) 2002-08-07
CN1164694C (zh) 2004-09-01

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